JP2007302649A6 - Inhibitors of grain and food protection against straw - Google Patents
Inhibitors of grain and food protection against straw Download PDFInfo
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Abstract
【課題】新規で廉価な黴阻止剤を提供すること。
【解決手段】５５容量％以下のプロピオン酸水溶液；約４〜約６にｐＨを調整する量の塩基、及び可溶化剤を含む改良した効力の黴阻止剤組成物。
【選択図】 なしA novel and inexpensive wrinkle inhibitor is provided.
An improved potency inhibitor composition comprising 55% by volume or less of an aqueous propionic acid solution; an amount of base that adjusts the pH to about 4 to about 6;
[Selection figure] None
Description
本発明は、概して、黴阻止剤に関し、さらに詳細には、黴に対する穀物及び食料の保護用の改良したプロピオン酸系阻止剤に関する。この独特の黴阻止剤製剤はプロピオン酸の塩及び可溶化剤を組み合わせる。 The present invention relates generally to wrinkle inhibitors, and more particularly to improved propionic acid-based inhibitors for the protection of cereals and foods against wrinkles. This unique wrinkle inhibitor formulation combines a salt of propionic acid and a solubilizer.
環境中の微生物の広範囲に及ぶ発生及び繁殖が穀物や食料成分を含む有機物質の分解をもたらす。穀類はエネルギーと動物食餌中のタンパク質の重要な源を構成する。悪気候条件下で、原材料を管理することは、許容できる食料品質を維持するために重要である。穀物は、貯蔵中に発生するマイコトキシン化合物を生じさせる黴を発生させる可能性がある。穀物中の高水分は黴やマイコトキシンの発生を促進させる。 The widespread outbreak and propagation of microorganisms in the environment results in the degradation of organic substances including grains and food ingredients. Cereals constitute an important source of energy and protein in animal diets. Managing raw materials under adverse climatic conditions is important to maintain acceptable food quality. Cereals can generate cocoons that give rise to mycotoxin compounds that occur during storage. High moisture in the grain promotes the generation of straw and mycotoxins.
プロピオン酸系黴阻止剤は、黴に対する穀物や動物飼料の保護のために費用効果的で効率の高い製品として広く受け入れられる。プロピオン酸は、合衆国連邦農務省(United States Federal Department of Agriculture:USFDA)により安全食品として公認されている(Generally Recognized As Safe:GRAS)。多くの企業は、食料産業の種々のニーズのために様々なプロピオン酸系黴阻止剤製品を提供している。これらの製品の殆どが非常に高濃度のプロピオン酸を含有し、黴阻止剤を施用するのに使用される設備や処置した食料及び穀物を取り扱う及び貯蔵する設備を腐食させる可能性がある。 Propionic acid-based wrinkle inhibitors are widely accepted as cost-effective and efficient products for the protection of grain and animal feed against wrinkles. Propionic acid is certified as a safe food (Generally Recognized As Safe: GRAS) by the United States Federal Department of Agriculture (USFDA). Many companies offer a variety of propionic acid-based wrinkle inhibitor products for different needs of the food industry. Most of these products contain very high levels of propionic acid and can corrode equipment used to apply the wrinkle inhibitor and equipment that handles and stores treated food and grains.
したがって、良好な黴阻止特性を持ちしかもサブストレート(substrate)に対して改良した展性を持つ低価格の黴阻止剤に対する必要性がある。本発明の製剤は、より廉価で、約４を超えるｐＨを示し、市場にある既存の製品よりもプロピオン酸の量が少ない。 Therefore, there is a need for a low cost anti-wrinkle agent that has good anti-wrinkle properties and improved malleability to the substrate. The formulations of the present invention are less expensive, exhibit a pH above about 4, and have a lower amount of propionic acid than existing products on the market.
本発明は、穀物及び食料における黴を阻止するための製剤からなる。当該製剤はプロピオン酸を基礎とし、ｐＨ上昇用塩基、可溶化剤、及びエッセンシャルオイルを含む。プロピオン酸の量は、公知のプロピオン酸系黴阻止剤よりも少ない。良好な展性特性を持つ（すなわち、高ＨＬＢ数）可溶化剤を製剤中に含有し、保護されるサブストレート全体せわたって製剤の分布を改良する。エッセンシャルオイル、好ましくは、桂皮油が、製剤中に含まれる。桂皮油は抗微生物特性を示し、製剤の腐食性を減少させる。製剤は一層減少させた量の主要活性成分（プロピオン酸）を有し、驚いたことに、黴阻止時に一層有効である。可溶化剤の添加は製剤の黴阻止特性を増強する。 The present invention consists of a formulation for preventing wrinkles in cereals and food. The formulation is based on propionic acid and contains a pH raising base, a solubilizer, and an essential oil. The amount of propionic acid is less than known propionic acid-based wrinkle inhibitors. Solubilizers with good malleability properties (ie high HLB numbers) are included in the formulation to improve the distribution of the formulation across the protected substrate. An essential oil, preferably cinnamon oil, is included in the formulation. Cinnamon oil exhibits antimicrobial properties and reduces the corrosivity of the formulation. The formulation has a reduced amount of the main active ingredient (propionic acid) and, surprisingly, is more effective at preventing sputum. The addition of solubilizers enhances the wrinkle prevention properties of the formulation.
図面の簡単な説明
図１は、二酸化炭素生成試験を使用するトウモロコシの試料で増殖した黴に対するラウリル硫酸ナトリウムの作用を示す図表である。
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a chart showing the effect of sodium lauryl sulfate on straw grown on corn samples using the carbon dioxide production test.
図２は、二酸化炭素生成試験を使用するトウモロコシの試料で増殖した黴に対する異なる濃度のラウリル硫酸ナトリウムを用いて黴阻止剤製剤の作用を示す図表である。
図３は、Ｍｕｃｏｒ、Ａｓｐｅｒｇｉｌｌｕｓ及びＰｅｎｉｃｉｌｌｉｕｍ種に対する可溶化剤を含有する黴阻止剤製剤及び可溶化剤を含有しない黴阻止剤製剤の作用を示す図表である。
FIG. 2 is a chart showing the effect of a koji inhibitor formulation with different concentrations of sodium lauryl sulfate on koji grown on corn samples using a carbon dioxide production test.
FIG. 3 is a chart showing the action of a wrinkle inhibitor formulation containing a solubilizing agent and a solubilizing agent formulation not containing a solubilizing agent against Mucor , Aspergillus and Penicillium species.
プロピオン酸系黴阻止剤は、中和していない形態又は一種以上の塩基と組み合わせた状態のいずれかのプロピオン酸を含有する黴阻止剤である。
本発明の黴阻止剤においてプロピオン酸を中和するのに使用する塩基はアルカリ元素の水酸化物があり、具体的には、水酸化アンモニウム、水酸化カリウム、水酸化カルシウム及び水酸化ナトリウム等があり、好ましくは、水酸化アンモニウムである。
Propionic acid-based wrinkle inhibitors are wrinkle inhibitors that contain either propionic acid in an unneutralized form or in combination with one or more bases.
The base used to neutralize propionic acid in the soot inhibiting agent of the present invention is an alkali element hydroxide, specifically, ammonium hydroxide, potassium hydroxide, calcium hydroxide, sodium hydroxide, etc. Yes, preferably ammonium hydroxide.
本発明の製剤中に含まれる可溶化剤には、高ＨＬＢ数の界面活性剤があり、好ましくは７を超え、具体的には、アニオン界面活性剤があり、より具体的には、Ｎ−セチル−Ｎ−エチルモルホリニウムエトサルフェート、Ｎ−ソヤ−Ｎ−エチルモルホリニウムエトサルフェート、ポリオキシエチレンソルビタンモノラウレート、ポリオキシレンラウリルエーテル、オレイン酸ナトリウム、オレイン酸カリウム、及びラウリル硫酸ナトリウム等がある。 Solubilizers included in the formulations of the present invention include high HLB number surfactants, preferably greater than 7, specifically anionic surfactants, and more specifically N- Cetyl-N-ethylmorpholinium etosulphate, N-soya-N-ethylmorpholinium etosulphate, polyoxyethylene sorbitan monolaurate, polyoxylen lauryl ether, sodium oleate, potassium oleate, sodium lauryl sulfate, etc. There is.
本発明の製剤に含まれるエッセンシャルオイルには、レモングラス油、パルマローザ油、丁子油、桂皮油、ユーカリ油、セージ油、タイム油、及びカッシア油等がある。 The essential oils contained in the preparation of the present invention include lemongrass oil, palmarosa oil, clove oil, cinnamon oil, eucalyptus oil, sage oil, thyme oil, cassia oil and the like.
（実施例１）
材料及び方法
使用する総ての化学品及び試薬は工業等級だった。総ての試験は二回行った。
(Example 1)
Materials and Methods All chemicals and reagents used were technical grade. All tests were performed twice.
二酸化炭素生成方法を、製剤の効力を評価するための方法として使用するために選択した。試験のために飼料用トウモロコシ試料を使用した。トウモロコシの１５０ｇ試料を採取し、試料の水分を１６％に調整した。１ｋｇ／Ｔｏｎに等しい用量で黴阻止剤を試料に加えた。次いで、試料を徹底的に混合した。未処置試料をコントロールとして使用した。試料を滅菌５００ｍｌガラス瓶に入れた。各容器を入口バルブと出口バルブの双方を備えた加工キャップで密にスクリュー締めした。２５℃で容器をインキュベートした。頭部空間の二酸化炭素濃度を、理研計器（日本、東京）製赤外線ガス分析計(Model RI-555)を使用して二日毎に測定した。二酸化炭素濃度を時間に対してプロットし、濃度曲線下面積を計算した。 The carbon dioxide production method was selected for use as a method for evaluating the efficacy of the formulation. Forage corn samples were used for testing. A 150 g sample of corn was taken and the sample moisture was adjusted to 16%. A sputum inhibitor was added to the sample at a dose equal to 1 kg / Ton. The sample was then thoroughly mixed. An untreated sample was used as a control. Samples were placed in sterile 500 ml glass bottles. Each container was tightly screwed with a processing cap equipped with both inlet and outlet valves. The container was incubated at 25 ° C. The carbon dioxide concentration in the head space was measured every two days using an infrared gas analyzer (Model RI-555) manufactured by Riken Keiki (Tokyo, Japan). The carbon dioxide concentration was plotted against time and the area under the concentration curve was calculated.
例にＭｕｃｏｒ、Ａｓｐｅｒｇｉｌｌｕｓ及びＰｅｎｉｃｉｌｌｉｕｍの三種の黴を使用のために選択した。Ｍｕｃｏｒ種の試料を腐敗パンから単離した。他の２種の微生物、具体的に、Ａｓｐｅｒｇｉｌｌｕｓ ｆｌａｖｕｓ ＡＴＣＣ２４１２５及びＰｅｎｉｃｉｌｌｉｕｍ ｃｈｒｙｓｏｇｅｎｕｍ ＡＴＣＣ４８９０８をアメリカン・タイプ・カルチャー・コレクション(American Type Culture Collection)（バージニア州、マナッサス）から入手した。 For example, three corals of Mucor , Aspergillus and Penicillium were selected for use. A sample of Mucor species was isolated from spoiled bread. Two other microorganisms were obtained from the American Type Culture Collection (Manassas, Va.), Specifically Aspergillus flavus ATCC 24125 and Penicillium chrysogenum ATCC 48908.
ディスク拡散法を使用して異なる製剤を評価し、比較した。Ｂｅｃｔｏｎ Ｄｉｃｋｉｎｓｏｎ ａｎｄ Ｃｏｍｐａｎｙ ＵＳＡからポテトデキストロース寒天(Potato Dextrose Agar:PDA)を入手した。寒天平板（直径１４ｃｍ）を調製し、室温に設定した。懸濁液中のＰｅｎｉｃｉｌｌｉｕｍ、Ａｓｐｅｒｇｉｌｌｕｓ及びＭｕｃｏｒの胞子濃度を、それぞれ、１．７２５×１０７、１．４５×１０６及び２．８５×１０６だった。続いて、試験した微生物の胞子懸濁液を各３００μＬ容量をＰＤＡ固体培地平板上に広げた。滅菌紙ディスク（直径６ｍｍ）を乾燥した培養済み平板上に置き、１５μＬの各試験物質を当該ディスク上にゆっくりと加えた。続いて、平板を２５℃で４８時間インキュベートした。阻止領域の直径を測定し、報告した。 Different formulations were evaluated and compared using the disk diffusion method. Potato Dextrose Agar (PDA) was obtained from Becton Dickinson and Company USA. An agar plate (diameter 14 cm) was prepared and set at room temperature. The spore concentrations of Penicillium , Aspergillus and Mucor in the suspension were 1.725 × 10 7 , 1.45 × 10 6 and 2.85 × 10 6 , respectively. Subsequently, 300 μL of each spore suspension of the tested microorganisms was spread on a PDA solid medium plate. A sterile paper disc (6 mm diameter) was placed on a dried cultured plate and 15 μL of each test substance was slowly added onto the disc. Subsequently, the plates were incubated at 25 ° C. for 48 hours. The diameter of the blocking area was measured and reported.
結果及び考察
新規製品組成物：新規な製品製剤は約２５％〜５５％、好ましくは３５％〜４０％の量のプロピオン酸、約ｐＨ４〜約ｐＨ６に製剤のｐＨを調整する量の塩基（普通、５％〜２５％、好ましくは、アルカリ元素のヒドロキシド、具体的には、水酸化アンモニウム、水酸化カルシウム及び水酸化ナトリウムであり、最も好ましくは水酸化アンモニウムである）、約０．１％〜約２０％、好ましくは、１％〜１０％の量の可溶化剤（ＨＬＢ数が７を超え、最も好ましくは、１７を超える、好ましくは、アニオン界面活性剤）、並びに残量の水を含む。当該製剤は、約０．０１〜約２％、最も好ましくは、約０．１〜約０．５％のエッセンシャルオイルも含むことができる。好適な実施態様製剤の詳細を表１に示す。
Results and Discussion New Product Composition: The new product formulation is about 25% to 55%, preferably 35% to 40% propionic acid in an amount to adjust the formulation pH to about pH 4 to about pH 6 (usually normal 5% to 25%, preferably alkali element hydroxides, specifically ammonium hydroxide, calcium hydroxide and sodium hydroxide, most preferably ammonium hydroxide), about 0.1% About 20%, preferably 1% to 10% of solubilizer (HLB number greater than 7, most preferably greater than 17, preferably anionic surfactant), as well as residual water. Including. The formulation may also contain about 0.01 to about 2%, most preferably about 0.1 to about 0.5% essential oil. Details of preferred embodiment formulations are shown in Table 1.
二酸化炭素試験：二酸化炭素試験は、黴阻止剤の効力を測定するように設計した促進微生物安定試験である。より多くの二酸化炭素生成がより高い黴増殖を示す。効力の高い黴阻止剤はこの試験ではより少ない二酸化炭素を生成し黴から試料を保護する。図１は、水中、１％、５％及び１０％のラウリル硫酸ナトリウム並びにネガティブコントロール（トウモロコシ試料のみ）を使用する二酸化炭素からの結果を示す。 Carbon dioxide test : The carbon dioxide test is an accelerated microbial stability test designed to measure the efficacy of sputum inhibitors. More carbon dioxide production indicates higher spider growth. High potency soot inhibitors produce less carbon dioxide in this test and protect the sample from soot. FIG. 1 shows the results from carbon dioxide using 1%, 5% and 10% sodium lauryl sulfate in water and a negative control (corn sample only).
図１から、ラウリル硫酸ナトリウムで処置したトウモロコシ試料は未処置トウモロコシ試料（ネガティブコントロール）と同じかそれよりも多い二酸化炭素を生成したことが分かる。これらのデータは、トウモロコシへのラウリル硫酸ナトリウムの単独添加が黴増殖を阻止するのに有効でなく、事実上黴増殖を促進し得るということを示した。 It can be seen from FIG. 1 that the corn sample treated with sodium lauryl sulfate produced the same or more carbon dioxide as the untreated corn sample (negative control). These data indicated that the addition of sodium lauryl sulfate alone to corn was not effective in preventing cocoon growth and could effectively promote cocoon growth.
図２は、異なる濃度のラウリル硫酸ナトリウム（ＳＬＳ）を含有する提唱した黴阻止剤製剤を使用する二酸化炭素から得られた結果を示す。表２は、実験に使用した製剤の詳細を示す。 FIG. 2 shows the results obtained from carbon dioxide using the proposed sputum inhibitor formulation containing different concentrations of sodium lauryl sulfate (SLS). Table 2 shows details of the formulations used in the experiments.
結果は、処置試料に比較して、未処置トウモロコシ試料は１０及び１３日目において顕著により高い量の二酸化炭素を生成したことを示した（図２）。ラウリル硫酸ナトリウムを含有する製剤で処置した試料は改良した黴阻止特性を示した。ラウリル硫酸ナトリウム単独では黴成長を阻止するのに有効でないが（図１）、ポジティブコントロールと組み合わせた場合、ラウリル硫酸ナトリウムが製剤の黴阻止特性を増強することに注意することは重要である。 The results showed that the untreated corn sample produced significantly higher amounts of carbon dioxide at 10 and 13 days compared to the treated sample (FIG. 2). Samples treated with formulations containing sodium lauryl sulfate exhibited improved wrinkle inhibition properties. While sodium lauryl sulfate alone is not effective in inhibiting wrinkle growth (FIG. 1), it is important to note that sodium lauryl sulfate enhances the wrinkle-inhibiting properties of the formulation when combined with a positive control.
ディスク拡散法：図３は、Ａｓｐｅｒｇｉｌｌｕｓ ｆｌａｖｕｓ、Ｍｕｃｏｒ 種、及びＰｅｎｉｃｉｌｌｉｕｍ ｃｈｒｙｓｏｇｅｎｕｍについてのディスク拡散法からの結果を示す。表１に示した最終製剤並びに表２に示したポジティブコントロール及びポジティブコントロール＋１％ラウリル硫酸ナトリウムをこのディスク拡散法に付した。結果は、ラウリル硫酸ナトリウムを含有する製剤がラウリル硫酸ナトリウムを含有しない製剤よりも優れた性能を示したことを示す。 Disc Diffusion Method : FIG. 3 shows the results from the disc diffusion method for Aspergillus flavus, Mucor species, and Penicillium chrysogenum. The final formulation shown in Table 1 and the positive control and positive control + 1% sodium lauryl sulfate shown in Table 2 were subjected to this disk diffusion method. The results show that the formulation containing sodium lauryl sulfate performed better than the formulation containing no sodium lauryl sulfate.
結論
新規な低価格黴阻止剤は、プロピオン酸、水酸化アンモニウム、水及びラウリル硫酸ナトリウムを組み合わせる。ラウリル硫酸ナトリウムの添加は製剤の黴阻止性能を増強する。作用の特定の理論により拘束されないが、本発明の製剤の驚くほど高い効果は、黴の阻止のために施用されるサブストレート一面に製品の改良された分配によりもたらされると思われる。
CONCLUSION A new low cost wrinkle inhibitor combines propionic acid, ammonium hydroxide, water and sodium lauryl sulfate. The addition of sodium lauryl sulfate enhances the wrinkle prevention performance of the formulation. While not being bound by a particular theory of action, it is believed that the surprisingly high effect of the formulations of the present invention is brought about by an improved distribution of the product over the substrate applied for the prevention of wrinkles.
上記の記載は本発明の例証的実施態様を構成する。本明細書で記載した前記実施態様及び方法は、当業者の能力、経験及び好みに基づいて変動し得る。一定の順序で方法の工程を単に挙げたが、必ずしも、当該方法の工程の順序に制限にされない。前述の記述及び図面は単に本発明の説明と例証であり、本発明は、特許請求の範囲がそう制限する以外は、制限されない。本発明を開示された当業者は、意図された特許請求の範囲から逸脱しないで、修正及び変動をなすことができる。 The above description constitutes an exemplary embodiment of the invention. The embodiments and methods described herein may vary based on the ability, experience and preference of those skilled in the art. Although the method steps are merely listed in a certain order, they are not necessarily limited to the order of the method steps. The foregoing description and drawings are merely illustrative and illustrative of the invention, and the invention is not limited except as by the appended claims. Those skilled in the art who have disclosed the invention can make modifications and variations without departing from the intended scope of the claims.
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| SG200603191-8 | 2006-05-11 | ||
| SG200603191-8A SG137704A1 (en) | 2006-05-11 | 2006-05-11 | Inhibitors for the protection of grain and feed against mold |
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|---|---|---|---|---|
| EP2301368A1 (en) * | 2009-09-08 | 2011-03-30 | Mars, Incorporated | Composition for prevention against spoilage by microorganisms and uses and products related thereto |
| JP2013194010A (en) * | 2012-03-21 | 2013-09-30 | Kitakyushu Foundation For The Advancement Of Industry Science & Technology | Antifungal agent and antifungal method for rush using the same, and rush product subjected to antifungal treatment |
| CN107258895B (en) * | 2017-06-23 | 2020-03-24 | 中南林业科技大学 | Litsea cubeba oil-based preservative and fresh-keeping composition |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1505388A (en) * | 1975-11-27 | 1978-03-30 | Bp Chem Int Ltd | Acid salt solutions |
| JPH06279208A (en) * | 1992-05-18 | 1994-10-04 | Givaudan Roure Internatl Sa | Antiseptic system |
| AU666415B2 (en) * | 1993-01-27 | 1996-02-08 | Dsm Ip Assets B.V. | A fungicide composition to prevent the growth of mould on foodstuff and agricultural products |
| FI103704B (en) * | 1996-07-19 | 1999-08-31 | Kemira Chemicals Oy | Antimicrobial composition, method of preparation and use thereof |
| KR19990084262A (en) * | 1998-05-02 | 1999-12-06 | 신형태 | Livestock feed using food waste and its manufacturing method |
| KR100313710B1 (en) * | 1999-08-02 | 2001-11-26 | 이태일 | Contamination Eliminating Agent For Animal Feedstuff |
| AU2001241632A1 (en) * | 2000-02-28 | 2001-09-12 | The Procter And Gamble Company | Acidic antimicrobial compositions for treating food and food contact surfaces and methods of use thereof |
| KR100368691B1 (en) * | 2001-07-06 | 2003-01-24 | Rnl Life Science Co | Sterilization composition containing anionic surfactant |
| KR100532163B1 (en) | 2003-03-31 | 2005-11-29 | 조석형 | Formulation for antibacterial and deodorante agent |
| KR100561008B1 (en) | 2005-01-31 | 2006-03-17 | (주)애드바이오텍 | Deodorizer having anti-bacterial activity |
| JP2006276032A (en) * | 2006-06-08 | 2006-10-12 | Toshiba Corp | Method and system for pipe testing |
-
2006
- 2006-05-11 SG SG200603191-8A patent/SG137704A1/en unknown
- 2006-08-31 KR KR1020060083726A patent/KR100828841B1/en active IP Right Grant
- 2006-10-10 JP JP2006276032A patent/JP2007302649A/en active Pending
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2012
- 2012-09-10 JP JP2012198790A patent/JP2013028617A/en active Pending
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