JP2007262383A - Resin composition for cleaning plastic molding machine - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an inexpensive resin composition for cleaning a plastic molding machine having a slight irritant smell and high cleaning effects and rich in general-purpose properties without deteriorating cleaning effects even at a temperature of ≥300°C by reutilizing a used cross-linked polyethylene resin. <P>SOLUTION: The resin composition for cleaning the molding machine is obtained as follows. Kneading of 100 pts.wt. of a high-density polyethylene resin (A) with one or more kinds selected from 20-150 pts.wt. of a pulverized material (B) of the cross-linked polyethylene such as an electric wire coating waste material, 5-50 pts.wt. of an inorganic filler (C), 5-25 pts.wt. of a surfactant (D) and 1-35 pts.wt. of an alkali metal carbonate (E) is carried out and the kneaded material is then extruded. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a cleaning resin composition for removing additives such as a resin, a filler, a colorant, and the like remaining in a cylinder and a nozzle of the molding machine after completion of plastic extrusion molding or injection molding by the molding machine. More specifically, a crushed product of a crosslinked polyethylene resin waste and one or more selected from inorganic fillers, surfactants, alkali metal carbonates and polytetrafluoroethylene resins are blended with thermoplastic resins. And a resin composition for cleaning a plastic molding machine.

  In plastic extrusion molding or injection molding processing, various measures are taken to eliminate the influence of the preceding resin or resin composition when changing the type or brand of resin or resin composition used. In particular, when molding colored resins, when switching from dark-colored varieties such as blue and black to light-colored varieties such as white, disassembly and cleaning of the molding machine and co-washing in the molding machine with general-purpose resin or recycled resin For example, it has been forced to perform complicated operations such as the above and a cleaning operation with long-time production suspension. Accordingly, as a method for solving these problems, a cleaning resin composition for cleaning the inside of a molding machine has been developed.

For example, a product obtained by pulverizing a polymethylmethacrylate resin is commercially available, and there is a method of removing this molding resin remaining in the molding machine by putting it in a molding machine hopper. May decompose and generate an irritating odor, deteriorating the working environment.
In addition, for the purpose of improving workability, a technique has been proposed in which an alkylbenzene sulfonate is mixed with a thermoplastic resin and melt-kneaded with an extrusion kneader to obtain a cleaning resin composition. However, there are cases in which the cleaning effect is insufficient with the proposed cleaning resin composition. (Patent Document 1)

There is also a proposal to manufacture a pellet-shaped resin composition containing 50 to 85% by weight of a detergent using a surfactant and an inorganic substance, and blend it with a general-purpose thermoplastic resin such as polystyrene or polypropylene for use in washing. However, even in the proposed cleaning resin composition, there are cases where the cleaning effect is insufficient. (Patent Document 2)
A cleaning agent using a polyethylene resin having a gel fraction of 5 to 25% alone or in combination with a surfactant has also been proposed, but the cleaning effect of this proposal may be insufficient. (Patent Document 3)

Further, a detergent composition comprising a pulverized polyester resin molded product, a surfactant and a thermoplastic resin has been proposed. However, in this proposal, the cleaning ability may be reduced at a high temperature of 300 ° C. or higher. (Patent Document 4)
On the other hand, cross-linked polyethylene resin is widely used for electric wire covering materials, floor heating pipes, foam materials and the like. However, since the waste material does not melt even when heated, reuse has not progressed.
Japanese Examined Patent Publication No. 6-24724 Japanese Patent Publication No. 7-53377 JP 2002-210748 A JP 11-227000 A

  An object of the present invention is to recycle a used cross-linked polyethylene resin, a plastic molding machine that has little irritating odor, has a high cleaning effect, is inexpensive and versatile, and does not deteriorate the cleaning effect even in a temperature range exceeding 300 ° C. It is providing the resin composition for washing | cleaning.

  The present inventor has found that the pulverized product of the crosslinked polyethylene resin waste material does not melt even when heated, is soft compared to a metal material such as a cylinder or screw, and the crosslinked polyethylene resin has adhesion to the metal material. As a result of intensive studies to utilize this characteristic, the crushed product of the crosslinked polyethylene resin waste material (B) as the main component, the inorganic filler (C), the interface with respect to the thermoplastic resin (A). And a resin composition comprising at least one selected from activator (D) and alkali metal carbonate (E), and also includes four components (A) to (D) as essential components Further, the above-mentioned problems can be remarkably solved by a resin composition comprising a polytetrafluoroethylene resin (F) as an essential component with respect to the resin composition. Heading, we have reached the completion of the present invention.

  That is, the present invention is based on 100 parts by weight of the thermoplastic resin (A), 20 to 150 parts by weight of a pulverized product of a crosslinked polyethylene resin waste material as a main component (B) and 5 to 50 parts by weight of an inorganic filler (C). A resin composition comprising 5 to 25 parts by weight of a surfactant (D) and 1 to 35 parts by weight of an alkali metal carbonate (E), and (A) to ( A resin composition comprising the four components D) as essential components, and further comprising 0.05 to 10 parts by weight of a polytetrafluoroethylene resin (F) as an essential component with respect to the resin composition. I will provide a.

  According to the resin composition for cleaning a plastic molding machine according to the present invention, by using a cross-linked polyethylene waste material and combining it with a kind of additive having a synergistic effect, the cleaning operation is remarkably improved, and the cleaning operation is performed. Waste can be reduced. In addition, it exhibits high detergency and easy replacement from the cleaning of polyolefin resin at about 200 ° C. to the temperature range exceeding 300 ° C. like PPS resin. As a result, it is possible to effectively utilize the waste polyethylene cross-linked polyethylene resin, which is industrial waste, and to reduce the amount of plastic waste generated from the cleaning work because of the high cleaning capability, contributing to environmental conservation.

  Embodiments of the present invention will be described in detail. As the thermoplastic resin (A) referred to in the present invention, general-purpose resins such as polyethylene resin, polypropylene resin, polystyrene resin, styrene-acrylonitrile resin, acrylonitrile-butadiene-styrene copolymer are used. More preferably, a polyethylene resin having a chemical structure similar to that of the crosslinked polyethylene resin is optimal.

  Cross-linked polyethylene resin waste pulverized material (B) includes used wire covering materials, floor heating pipe materials, cross-linked polyethylene resin molded products such as foams, and cross-linked polyethylene resin waste generated at the manufacturing stage thereof. A pulverized product of such a crosslinked polyethylene resin waste material having a maximum length of about 0.05 to 10 mm, more preferably about 0.1 to 3 mm is used. When the maximum length is 0.05 mm or less or 10 mm or more, workability is poor when the composition is melt-kneaded. The addition amount is 20 to 150 parts by weight, more preferably 40 to 100 parts by weight. When the addition amount is less than 20 parts by weight, the melt viscosity of the cleaning agent when heated and melted is small and the cleaning ability is low. Moreover, when adding more than 150 weight part, when manufacturing a composition with a melt-kneading method, a screw load will become large and manufacture will become difficult.

  Inorganic filler (C) is bentonite, talc, mica, clay, zeolite, wollastonite, kaolin, perlite, diatomaceous earth, calcium carbonate, magnesium hydroxide, calcium hydroxide, aluminum hydroxide, hydrotalcite, oxidation Magnesium, calcium oxide, zinc oxide and the like are used alone or in combination of two or more. In particular, organic montmorillonite in which a quaternary ammonium cation is attached to the crystal surface of the clay mineral montmorillonite is preferable. The addition amount is 5 to 50 parts by weight, more preferably 10 to 40 parts by weight. When the added amount is less than 5 parts by weight, the function of physically removing the resin residue remaining before the filler adheres to the cylinder and screw in the molding machine is weak, and the cleaning ability is low. Moreover, when it adds more than 50 weight part, although the washing | cleaning capability is high, a cylinder and a screw are damaged and mechanical abrasion is brought about.

  As the surfactant (D), any type of nonionic, anionic, cationic, and nonionic types may be used. Specifically, linear alkylbenzene sulfonate, stearic acid, and the like are preferably used. This addition amount is 5 to 25 parts by weight, more preferably 10 to 20 parts by weight. When the addition amount is less than 5 parts by weight, the synergistic effect of the cleaning effect by this surfactant is small. Moreover, when it adds more than 25 weight part, a washing | cleaning effect does not increase in proportion to the addition amount.

Alkali metal carbonate (E) is sodium hydrogencarbonate, sodium sesquicarbonate, sodium carbonate, etc., and these are used individually or in combination of 2 or more types. The addition amount is 1 to 35 parts by weight, preferably 6 to 20 parts by weight. When the addition amount is less than 1 part by weight, the synergistic effect of the cleaning effect by the alkali metal carbonate is small. Moreover, when it adds more than 35 weight part, a washing | cleaning effect does not increase in proportion to the addition amount.
The increase in the cleaning effect due to the addition of the alkali metal carbonate is presumed to increase the cleaning effect by making the system of the cleaning agent alkaline with a small amount of water adhering to the resin during the cleaning operation of the cylinder and the nozzle part.

  The polytetrafluoroethylene resin (F) is abbreviated as PTFE, which is most frequently used among fluororesins, and is particularly preferably in the form of powder. For example, pulverization of raw PTFE tape or the like Recycled products can also be suitably used. The addition amount is preferably 0.05 to 10 parts by weight. Here, this polytetrafluoroethylene resin (F) mainly acts as a viscosity modifier. By adding an appropriate amount, the viscosity of the resin composition is increased moderately, and the cylinder and screw are washed more slowly and reliably. It becomes possible to do.

  In the present invention, various additives such as an antioxidant and a heat stabilizer can be blended in accordance with the demands of the field of use within a range that does not impair the object of the present invention.

Next, a method for kneading and producing the resin composition according to the present invention as a cleaning agent for a plastic molding machine will be described.
The cleaning agent of the present invention comprises a thermoplastic resin (A), a pulverized product of a crosslinked polyethylene resin (B), an inorganic filler (C), a surfactant (D), an alkali metal carbonate (E), polytetrafluoro Ethylene resin (F) is weighed at a predetermined ratio and premixed using a V mixer, tumbler, ribbon blender, etc., and then heated, melted and kneaded with a uniaxial or biaxial kneading extruder, kneader, Banbury mixer, etc. Then, it can be obtained by cutting into pellets or pulverizing into indefinite shapes. However, the method for kneading and producing the cleaning resin composition of the present invention is not limited to the above method.

Hereinafter, the present invention will be described specifically by way of examples.
Example 1
High-density polyethylene resin (MI = 20) (A) 100 parts by weight, 63.6 parts by weight of the pulverized product (B) obtained by pulverizing the cross-linked polyethylene of the wire coating waste material to 0.2 to 2.5 mm with a plastic pulverizer, 18.2 parts by weight of linear alkylbenzene sodium sulfonate (D) was weighed and mixed with a V mixer. Then, the mixture was extruded with a twin-screw extruder at a cylinder temperature of 200 ° C. to 240 ° C. and a screw rotation speed of 175 RPM to form pellets, which were used as cleaning agents. Next, in order to evaluate the effect of the cleaning agent, using a 75-ton injection molding machine, the molding cylinder temperature is 230 ° C. to 250 ° C. First, a black polypropylene resin product is molded, and after the molding is finished, the cylinder is pulled and a screw is used. Rotate to drain the previous material completely open. Thereafter, 500 g of the cleaning agent produced here was poured into the molding machine, the screw was rotated in an open state, and the cleaning operation was performed until the cleaning agent disappeared. Subsequently, the polystyrene resin is put into the molding machine to form a 100 × 100 × 3 mm flat plate, and the total amount of the molded product including the sprue and runner part of the entire shot of the molding shot until the whole becomes a transparent plate Compared. The molding cylinder temperature was 230 ° C to 250 ° C. In the case of this example, the total weight of all shots until becoming a transparent plate was 230 g, and thereafter, a completely transparent polystyrene resin flat plate could be formed.

(Example 2)
High-density polyethylene resin (MI = 20) (A) 100 parts by weight, 63.6 parts by weight of the pulverized product (B) obtained by pulverizing the cross-linked polyethylene of the wire coating waste material to 0.2 to 2.5 mm with a plastic pulverizer, 18.2 parts by weight of organic bentonite (C) was weighed and mixed with a V mixer. And the mixture was pelletized with the biaxial extruder similarly to Example 1, and the cleaning agent was produced. Subsequently, in order to evaluate the effect of the cleaning agent, it evaluated by the same method as Example 1. In the case of this example, the total weight of all shots until becoming a transparent plate was 292 g, and thereafter, a completely transparent polystyrene resin flat plate could be formed.

(Example 3)
High-density polyethylene resin (MI = 20) (A) 100 parts by weight, 63.6 parts by weight of the pulverized product (B) obtained by pulverizing the cross-linked polyethylene of the wire coating waste material to 0.2 to 2.5 mm with a plastic pulverizer, 18.2 parts by weight of sodium sesquicarbonate (E) was weighed and mixed with a V mixer. Then, the mixture was extruded with a twin-screw extruder at a cylinder temperature of 200 ° C. to 240 ° C. and a screw rotation speed of 175 RPM to form pellets, which were used as cleaning agents. Subsequently, in order to evaluate the effect of the cleaning agent, it evaluated by the same method as Example 1. In the case of this example, the total weight of all shots until becoming a transparent plate was 287.2 g, and thereafter, a completely transparent polystyrene resin flat plate could be formed.

Example 4
High-density polyethylene resin (MI = 20) (A) 100 parts by weight, 70 parts by weight of pulverized product (B) obtained by pulverizing cross-linked polyethylene of wire coating waste material to 0.2 to 2.5 mm with a plastic pulverizer, organic bentonite 20 parts by weight of (C) and 10 parts by weight of linear alkylbenzene sodium sulfonate (D) were weighed and mixed with a V mixer. Then, the mixture was extruded with a twin-screw extruder at a cylinder temperature of 200 ° C. to 240 ° C. and a screw rotation speed of 175 RPM to form pellets, which were used as cleaning agents. Subsequently, in order to evaluate the effect of the cleaning agent, it evaluated by the same method as Example 1. In the case of this example, the total weight of all shots until becoming a transparent plate was 274 g, and thereafter, a completely transparent polystyrene resin flat plate could be formed.

(Example 5)
High-density polyethylene resin (MI = 20) (A) 100 parts by weight, 70 parts by weight of the pulverized product (B) obtained by pulverizing the cross-linked polyethylene of the wire coating waste material to 0.2 to 2.5 mm with a plastic crusher 10 parts by weight of sodium alkylbenzene sulfonate (D) and 20 parts by weight of sodium sesquicarbonate (E) were weighed and mixed with a V mixer. Then, the mixture was extruded with a twin-screw extruder at a cylinder temperature of 200 ° C. to 240 ° C. and a screw rotation speed of 175 RPM to form pellets, which were used as cleaning agents. Subsequently, in order to evaluate the effect of the cleaning agent, it evaluated by the same method as Example 1. In the case of this example, the total weight of all shots until becoming a transparent plate was 279 g, and thereafter a completely transparent polystyrene resin flat plate could be formed.

(Example 6)
High-density polyethylene resin (MI = 20) (A) 100 parts by weight, 70 parts by weight of pulverized product (B) obtained by pulverizing cross-linked polyethylene of wire coating waste material to 0.2 to 2.5 mm with a plastic pulverizer, organic bentonite 10 parts by weight of (C), 10 parts by weight of linear alkylbenzene sodium sulfonate (D) and 10 parts by weight of sodium sesquicarbonate (E) were weighed and mixed with a V mixer. Then, the mixture was extruded with a twin-screw extruder at a cylinder temperature of 200 ° C. to 240 ° C. and a screw rotation speed of 175 RPM to form pellets, which were used as cleaning agents. Subsequently, in order to evaluate the effect of the cleaning agent, it evaluated by the same method as Example 1. In the case of this example, the total weight of all shots until becoming a transparent plate was 267 g, and thereafter, a completely transparent polystyrene resin flat plate could be formed.

(Example 7)
High-density polyethylene resin (MI = 20) (A) 100 parts by weight, 40 parts by weight of pulverized product (B) obtained by pulverizing cross-linked polyethylene of wire coating waste material to 0.2 to 2.5 mm with a plastic pulverizer, organic bentonite 30 parts by weight of (C), 10 parts by weight of linear alkylbenzene sodium sulfonate (D) and 20 parts by weight of sodium sesquicarbonate (E) were weighed and mixed with a V mixer. Then, the mixture was extruded with a twin-screw extruder at a cylinder temperature of 200 ° C. to 240 ° C. and a screw rotation speed of 175 RPM to form pellets, which were used as cleaning agents. Subsequently, in order to evaluate the effect of the cleaning agent, it evaluated by the same method as Example 1. In the case of this example, the total weight of all shots until becoming a transparent plate was 184 g, and thereafter, a completely transparent polystyrene resin flat plate could be formed.

(Comparative Example 1)
100 parts by weight of the same polyethylene resin as in Example 1 was mixed with 100 parts by weight of an acrylic detergent (Taiho Kogyo Co., Ltd.) to obtain a detergent. And the mixture was evaluated by the same method using the injection molding machine similar to Example 1. FIG. In the case of this comparative example, the total weight of all shots until becoming a transparent plate was 319 g, and thereafter, a completely transparent polystyrene resin flat plate could be formed.

(Comparative Example 2)
100 parts by weight of the same polyethylene resin as in Example 1 was mixed with 100 parts by weight of the pulverized cross-linked polyethylene resin used in the example, and similarly melt extruded and pelletized. And it evaluated by the method similar to Example 1 by using the pellet as a washing | cleaning agent. In the case of this comparative example, the total weight of all shots until becoming a transparent plate was 461 g, and thereafter, a completely transparent polystyrene resin flat plate could be formed.

(Comparative Example 3)
100 parts by weight of the same polyethylene resin as in Example 1 was mixed with 100 parts by weight of a pulverized product of the same crosslinked polyethylene resin and 3 parts by weight of linear alkylbenzene sodium sulfonate, and melt extruded to produce pellets. And it evaluated similarly to Example 1 by using the pellet as a cleaning agent. In the case of this comparative example, the total weight of all shots until becoming a transparent plate was 379 g, and thereafter, a completely transparent polystyrene resin flat plate could be formed.

(Example 8)
In evaluating the cleaning agent produced in Example 1, the cleaning effect was evaluated when the previous material was a black product of glass fiber reinforced PPS resin and the next molding material was a natural product of the same material. The cylinder temperature of the injection molding machine in this case was 320 ° C. to 340 ° C., and the method was the same as in Example 1. However, the total weight of the number of shots changed to the color of the molded product of the natural product is displayed, and in this example, the total weight of all shots was 265 g.

Example 9
In evaluating the cleaning agent produced in Example 6, the cleaning effect was evaluated when the previous material was a black product of glass fiber reinforced PPS resin and the next molding material was a natural product of the same material. The cylinder temperature of the injection molding machine in this case was 320 ° C. to 340 ° C., and the method was the same as in Example 1. However, the total weight of the number of shots changed to the color of the molded product of the natural product is displayed, and in this example, the total weight of all shots was 177 g.

(Example 10)
High-density polyethylene resin (MI = 4.5) (A) 100 parts by weight, 45.5 wt. Parts, calcium carbonate (C) 23.6 parts by weight, linear alkylbenzene sodium sulfonate (D) 9.1 parts by weight, polytetrafluoroethylene resin (F) 3.6 parts by weight, respectively, V mixer Mixed with. Then, the mixture was extruded with a twin-screw extruder at a cylinder temperature of 200 to 240 ° C. and a screw rotation speed of 175 RPM to form pellets, which were used as cleaning agents. Subsequently, in order to evaluate the effect of the cleaning agent, it evaluated by the same method as Example 1. In the case of this example, the total weight of all shots until becoming a transparent plate was 210 g, and thereafter, a completely transparent polystyrene resin flat plate could be formed.

Claims (3)

  20 to 150 parts by weight of a crushed product of a crosslinked polyethylene resin as a main component (B), 5 to 50 parts by weight of an inorganic filler (C), and a surfactant (D) with respect to 100 parts by weight of the thermoplastic resin (A) 1) or more selected from 5 to 25 parts by weight and 1 to 35 parts by weight of an alkali metal carbonate (E), and a resin composition for cleaning a plastic molding machine.   20 to 150 parts by weight of a pulverized product (B) of a crosslinked polyethylene resin as a main component, 5 to 50 parts by weight of an inorganic filler (C) and a surfactant (D) with respect to 100 parts by weight of the thermoplastic resin (A) And 5 to 25 parts by weight of a resin composition for cleaning a plastic molding machine.   The resin composition for cleaning a plastic molding machine according to claim 1 or 2, further comprising 0.05 to 10 parts by weight of a polytetrafluoroethylene resin (F).