JP2007261865A - Mold form for sulfur formed body and sulfur formed body production method - Google Patents

Mold form for sulfur formed body and sulfur formed body production method Download PDF

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JP2007261865A
JP2007261865A JP2006088312A JP2006088312A JP2007261865A JP 2007261865 A JP2007261865 A JP 2007261865A JP 2006088312 A JP2006088312 A JP 2006088312A JP 2006088312 A JP2006088312 A JP 2006088312A JP 2007261865 A JP2007261865 A JP 2007261865A
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sulfur
bottom plate
steam
plate portion
side plate
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JP4820970B2 (en
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Minoru Kurakake
稔 倉掛
Hideyuki Horii
秀之 堀井
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Japan Petroleum Energy Center JPEC
Eneos Corp
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Petroleum Energy Center PEC
Nippon Oil Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a mold form for forming a sulfur solidified body by cooling and solidifying a molten sulfur-containing material poured into a cavity surrounded by a bottom plate part and side plate parts, and to provide a production method for forming the sulfur solidified body by using the mold form. <P>SOLUTION: The mold form 1 is used for forming the sulfur solidified body by cooling and solidifying the molten sulfur-containing material poured into the cavity C surrounded by the bottom plate part 5 and side plate parts 2, 3, 4 arranged in a standing state in the peripheral part of the bottom plate part 5. At least the bottom plate part 5 of the bottom plate part 5 and the side plate parts 2, 3, 4 is formed to have a double structure in order to provide a steam chamber 7. Rapid cooling of the sulfur-containing material poured into the cavity C is prevented by heating an inner member of at least the bottom plate part 5 of the bottom plate part 5 and the side plate parts 2, 3, 4 by supplying steam into the steam chamber 7 from a steam inlet 8 and at the same time, discharging steam from a steam outlet 9. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、底板部及び側板部により囲まれたキャビティー内に流し込まれた溶融状態の硫黄含有資材を冷却固化させて硫黄固化体を成形するための型枠、及びこの型枠を用いて硫黄固化体を成形する製造方法に関する。なお、以下において、硫黄成形体と表記した場合は、硫黄固化体を意味するものとする。   The present invention relates to a mold for cooling and solidifying a sulfur-containing material in a molten state poured into a cavity surrounded by a bottom plate and a side plate, and forming a sulfur solidified body, and using this mold, sulfur The present invention relates to a manufacturing method for forming a solidified body. In addition, in the following, when it describes with a sulfur molded object, it shall mean a sulfur solidified body.

一般に、土木用、建設用の資材として、骨材をセメントで結合させたコンクリートが用いられている。これに対して、近年、常温では固体でありおよそ119℃〜159℃に加熱されると溶融するという硫黄の性質に着目し、この硫黄に所定の試料を配合して、土木用、建設用の資材の一つとして利用することが試みられている。上記硫黄を使用した硫黄含有資材は、セメントを使用する通常のコンクリートに比べて高強度で遮水性に優れ、かつ耐酸性の高い材料として知られている。そして、硫黄含有資材は、通常のコンクリートと仕上がりや取り扱いが見かけ上類似していることから、固化したものは硫黄コンクリート又は硫黄固化体と呼ばれることがある(例えば、特許文献1参照)。   In general, concrete in which aggregates are bonded with cement is used as a material for civil engineering and construction. On the other hand, in recent years, paying attention to the property of sulfur that is solid at room temperature and melts when heated to about 119 ° C to 159 ° C, a predetermined sample is blended with this sulfur, and it is used for civil engineering and construction. Attempts have been made to use it as one of the materials. The sulfur-containing material using sulfur is known as a material having high strength, excellent water barrier properties, and high acid resistance as compared with ordinary concrete using cement. And since a sulfur containing material is apparently similar in finish and handling to normal concrete, the solidified material is sometimes referred to as sulfur concrete or sulfur solidified material (see, for example, Patent Document 1).

ここで、硫黄は着火性を有しており危険物扱いであるので、現場で溶融し打設固化して施工することが困難である。このような状況を改善するために、溶融硫黄に添加剤として硫黄改質剤を混合してその硫黄を変性し、改質硫黄を製造することが試みられている。また、この改質硫黄と微粉末とを混合して溶融状態の改質硫黄中間資材を製造すること、及び、この改質硫黄中間資材と骨材とを混合しこれを固化させて改質硫黄固化体を製造することが試みられている(例えば、特許文献2参照)。
特開2004−160693号公報 特開2005−82475号公報
Here, since sulfur has an ignitability and is handled as a dangerous material, it is difficult to melt and cast and solidify it on site. In order to improve such a situation, it has been attempted to produce modified sulfur by mixing a sulfur modifier as an additive with molten sulfur to modify the sulfur. Also, the modified sulfur and fine powder are mixed to produce a molten modified sulfur intermediate material, and the modified sulfur intermediate material and aggregate are mixed and solidified to form modified sulfur. Attempts have been made to produce solidified bodies (see, for example, Patent Document 2).
Japanese Patent Laid-Open No. 2004-160693 JP 2005-82475 A

そして、上述のような溶融状態の硫黄含有資材(又は改質硫黄中間資材)を冷却固化させて硫黄固化体(又は改質硫黄固化体)を成形するには、所定の形状をした型枠内に上記硫黄含有資材を流し込んで冷却固化させていた。   Then, in order to cool and solidify the molten sulfur-containing material (or modified sulfur intermediate material) as described above to form a sulfur solidified body (or modified sulfur solidified body), the mold has a predetermined shape. The above sulfur-containing material was poured into and cooled and solidified.

しかし、溶融状態の硫黄含有資材は、硫黄の固化温度(約119℃)を下回った時点で固化し始めて、通常のコンクリート以上の高強度まで固化する。従来、溶融状態の硫黄含有資材が固化する際には、型枠内に流し込まれたときにその型枠と接した部分が急激に冷やされるために、型枠を外した脱型後の硫黄固化体の表面に荒れを生じるなどの問題があった。   However, the molten sulfur-containing material starts to solidify at a point below the solidification temperature of sulfur (about 119 ° C.) and solidifies to a strength higher than that of ordinary concrete. Conventionally, when a molten sulfur-containing material is solidified, when it is poured into the mold, the portion in contact with the mold is rapidly cooled, so the sulfur solidification after demolding after removing the mold There were problems such as roughening of the body surface.

そこで、本発明は、このような問題点に対処し、底板部及び側板部により囲まれたキャビティー内に流し込まれた溶融状態の硫黄含有資材の急冷を防止して、硫黄固化体の表面に荒れが生じにくい硫黄成形体用型枠、及び硫黄成形体の製造方法を提供することを目的とする。   Therefore, the present invention addresses such problems and prevents quenching of the molten sulfur-containing material poured into the cavity surrounded by the bottom plate portion and the side plate portion, and on the surface of the sulfur solidified body. An object of the present invention is to provide a mold for a sulfur molded body that is not easily roughened and a method for producing the sulfur molded body.

上記目的を達成するために、第1の発明による硫黄成形体用型枠は、底板部及びこの底板部の周縁に立設された側板部により囲まれたキャビティー内に流し込まれた溶融状態の硫黄含有資材を冷却固化させて硫黄固化体を成形する型枠であって、上記底板部及び側板部のうち少なくとも底板部を二重構造として蒸気室を設け、この蒸気室内に蒸気入口から蒸気を供給すると共に蒸気出口から蒸気を排出させることで、上記底板部及び側板部のうち少なくとも底板部の内側部材を加熱し、上記キャビティー内に流し込まれた硫黄含有資材の急冷を防止するようにしたものである。   In order to achieve the above-mentioned object, the sulfur molded body mold according to the first invention is in a molten state poured into a cavity surrounded by a bottom plate portion and a side plate portion standing on the periphery of the bottom plate portion. A mold for cooling and solidifying a sulfur-containing material to form a sulfur solidified body, wherein a steam chamber is provided with at least the bottom plate portion of the bottom plate portion and the side plate portion as a double structure, and steam is supplied into the steam chamber from a steam inlet. By supplying and discharging steam from the steam outlet, at least the inner member of the bottom plate portion of the bottom plate portion and the side plate portion is heated to prevent rapid cooling of the sulfur-containing material poured into the cavity. Is.

このような構成により、硫黄固化体を成形する型枠の底板部及び側板部のうち少なくとも底板部を二重構造として蒸気室を設け、この蒸気室内に蒸気入口から蒸気を供給すると共に蒸気出口から蒸気を排出させることで、上記底板部及び側板部のうち少なくとも底板部の内側部材を加熱し、キャビティー内に流し込まれた硫黄含有資材の急冷を防止する。   With such a configuration, a steam chamber is provided with at least the bottom plate portion of the bottom plate portion and the side plate portion of the mold for forming the sulfur solidified body as a double structure, and steam is supplied into the steam chamber from the steam inlet and from the steam outlet. By discharging the steam, at least the inner member of the bottom plate portion of the bottom plate portion and the side plate portion is heated, and the sulfur-containing material poured into the cavity is prevented from being rapidly cooled.

また、上記底板部及び側板部の両方を二重構造として蒸気室を設け、この蒸気室内に蒸気入口から蒸気を供給すると共に蒸気出口から蒸気を排出させることで、上記底板部及び側板部の両方の内側部材を加熱するようにしてもよい。これにより、硫黄固化体を成形する型枠の底板部及び側板部の両方を二重構造として蒸気室を設け、上記底板部及び側板部の両方の内側部材を加熱する。   Moreover, both the bottom plate part and the side plate part are provided with a steam chamber having a double structure, and both the bottom plate part and the side plate part are supplied to the steam chamber from the steam inlet and discharged from the steam outlet. The inner member may be heated. Thus, both the bottom plate portion and the side plate portion of the mold for molding the sulfur solidified body are provided with a dual structure to provide a steam chamber, and the inner members of both the bottom plate portion and the side plate portion are heated.

さらに、上記蒸気室が設けられた底板部及び側板部の外側部材の背面には、断熱材層を設けてもよい。これにより、蒸気室が設けられた底板部及び側板部の外側部材の背面に設けられた断熱材層によって、硫黄固化体を成形する型枠の底板部及び側板部の温度低下を抑える。   Furthermore, you may provide a heat insulating material layer in the back surface of the outer member of the baseplate part and side plate part in which the said steam chamber was provided. Thereby, the heat-insulating material layer provided in the back surface of the outer member of the bottom plate part and the side plate part provided with the steam chamber suppresses the temperature drop of the bottom plate part and the side plate part of the mold for forming the sulfur solidified body.

次に、第2の発明による硫黄成形体の製造方法は、底板部及びこの底板部の周縁に立設された側板部のうち少なくとも底板部を二重構造として蒸気室を設けた型枠の該蒸気室内に蒸気入口から蒸気を供給すると共に蒸気出口から蒸気を排出させ、上記底板部及び側板部のうち少なくとも底板部の内側部材を予備加熱するステップと、上記型枠の底板部及び側板部により囲まれたキャビティー内に溶融状態の硫黄含有資材を流し込むステップと、上記蒸気室内に供給する蒸気を徐々に少なくし、又は止めて上記キャビティー内の硫黄含有資材を徐冷するステップと、上記キャビティー内の硫黄含有資材が冷却固化して成形された硫黄固化体を上記型枠から取り出すステップと、を行うものである。   Next, a method for producing a sulfur molded body according to a second aspect of the present invention is directed to a mold having a steam chamber with at least a bottom plate portion of a bottom plate portion and side plate portions erected on the periphery of the bottom plate portion. Supplying steam from the steam inlet into the steam chamber and discharging steam from the steam outlet, preheating at least the inner member of the bottom plate portion of the bottom plate portion and the side plate portion, and by the bottom plate portion and the side plate portion of the mold Pouring a molten sulfur-containing material into the enclosed cavity, gradually reducing or stopping the steam supplied to the steam chamber, and gradually cooling the sulfur-containing material in the cavity; and Removing the sulfur solidified material formed by cooling and solidifying the sulfur-containing material in the cavity from the mold.

このような方法により、底板部及びこの底板部の周縁に立設された側板部のうち少なくとも底板部を二重構造として蒸気室を設けた型枠の該蒸気室内に蒸気入口から蒸気を供給すると共に蒸気出口から蒸気を排出させ、上記底板部及び側板部のうち少なくとも底板部の内側部材を予備加熱し、上記型枠の底板部及び側板部により囲まれたキャビティー内に溶融状態の硫黄含有資材を流し込み、上記蒸気室内に供給する蒸気を徐々に少なくし、又は止めて上記キャビティー内の硫黄含有資材を徐冷し、上記キャビティー内の硫黄含有資材が冷却固化して成形された硫黄固化体を上記型枠から取り出すことで、硫黄固化体を製造する。   By such a method, steam is supplied from the steam inlet to the steam chamber of the mold frame in which at least the bottom plate portion of the bottom plate portion and the side plate portions erected on the periphery of the bottom plate portion has a double structure and the steam chamber is provided. In addition, the steam is discharged from the steam outlet, and at least the inner member of the bottom plate portion of the bottom plate portion and the side plate portion is preheated, and the molten sulfur-containing content is contained in the cavity surrounded by the bottom plate portion and the side plate portion of the formwork. Pour the material, gradually reduce or stop the steam supplied into the steam chamber, gradually cool the sulfur-containing material in the cavity, and the sulfur-containing material in the cavity is cooled and solidified to form sulfur A sulfur solidified body is manufactured by taking out the solidified body from the mold.

また、上記底板部及び側板部の両方を二重構造として蒸気室を設け、この蒸気室内に蒸気入口から蒸気を供給すると共に蒸気出口から蒸気を排出させることで、上記底板部及び側板部の両方の内側部材を予備加熱してもよい。これにより、硫黄固化体を成形する型枠の底板部及び側板部の両方を二重構造として蒸気室を設け、上記底板部及び側板部の両方の内側部材を予備加熱する。   Moreover, both the bottom plate part and the side plate part are provided with a steam chamber having a double structure, and both the bottom plate part and the side plate part are supplied to the steam chamber from the steam inlet and discharged from the steam outlet. The inner member may be preheated. Thus, both the bottom plate portion and the side plate portion of the mold for forming the sulfur solidified body are provided with a dual structure, and a steam chamber is provided, and the inner members of both the bottom plate portion and the side plate portion are preheated.

さらに、上記蒸気室が設けられた底板部及び側板部の外側部材の背面には、断熱材層を設け設けてもよい。これにより、蒸気室が設けられた底板部及び側板部の外側部材の背面に設けられた断熱材層によって、硫黄固化体を成形する型枠の底板部及び側板部の温度低下を抑える。   Furthermore, you may provide and provide a heat insulating material layer in the back surface of the outer member of the baseplate part and side plate part in which the said steam chamber was provided. Thereby, the temperature reduction of the bottom plate part and the side plate part of the mold for molding the sulfur solidified body is suppressed by the heat insulating material layer provided on the back surface of the outer member of the bottom plate part and the side plate part provided with the steam chamber.

請求項1に係る発明によれば、硫黄固化体を成形する型枠の底板部及び側板部のうち少なくとも底板部を二重構造として蒸気室を設け、この蒸気室内に蒸気入口から蒸気を供給すると共に蒸気出口から蒸気を排出させることで、上記底板部及び側板部のうち少なくとも底板部の内側部材を加熱し、キャビティー内に流し込まれた硫黄含有資材の急冷を防止することができる。また、常に蒸気室内の蒸気を入れ替えることで、少なくとも底板部の内側部材を高温に加熱することができる。これにより、底板部及び側板部により囲まれたキャビティー内に流し込まれた溶融状態の硫黄含有資材の急冷を防止して、硫黄固化体の表面の荒れを低減することができる。なお、本発明による型枠は、電気ヒータを用いないので、製油所などにおける防爆仕様に合致するものである。   According to the first aspect of the present invention, the steam chamber is provided with at least the bottom plate portion of the bottom plate portion and the side plate portion of the mold for forming the solidified sulfur body as a double structure, and steam is supplied into the steam chamber from the steam inlet. At the same time, by discharging the steam from the steam outlet, at least the inner member of the bottom plate portion of the bottom plate portion and the side plate portion is heated, and the rapid quenching of the sulfur-containing material poured into the cavity can be prevented. Moreover, at least the inner member of the bottom plate portion can be heated to a high temperature by always replacing the steam in the steam chamber. Thereby, rapid cooling of the molten sulfur-containing material poured into the cavity surrounded by the bottom plate portion and the side plate portion can be prevented, and the surface roughness of the sulfur solidified body can be reduced. In addition, since the formwork by this invention does not use an electric heater, it corresponds to the explosion-proof specification in refineries etc.

また、請求項4に係る発明によれば、底板部及びこの底板部の周縁に立設された側板部のうち少なくとも底板部を二重構造として蒸気室を設けた型枠の該蒸気室内に蒸気入口から蒸気を供給すると共に蒸気出口から蒸気を排出させ、上記底板部及び側板部のうち少なくとも底板部の内側部材を予備加熱し、上記型枠の底板部及び側板部により囲まれたキャビティー内に溶融状態の硫黄含有資材を流し込み、上記蒸気室内に供給する蒸気を徐々に少なくし、又は止めて上記キャビティー内の硫黄含有資材を徐冷し、上記キャビティー内の硫黄含有資材が冷却固化して成形された硫黄固化体を上記型枠から取り出すことで、硫黄固化体を製造することができる。これにより、底板部及び側板部により囲まれたキャビティー内に流し込まれた溶融状態の硫黄含有資材の急冷を防止して、硫黄固化体の表面の荒れを低減することができる。また、溶融状態の硫黄含有資材を流し込んだ後、蒸気室に供給する蒸気を減らし、又は停止することで型枠内の硫黄含有資材を徐冷し、均質な高品質の硫黄固化体を製造できる。徐冷速度は、蒸気室内の蒸気圧をコントロールすることで調整できる。   According to the fourth aspect of the present invention, the steam is contained in the steam chamber of the formwork in which at least the bottom plate portion of the bottom plate portion and the side plate portions erected on the periphery of the bottom plate portion has a double structure and the steam chamber is provided. Steam is supplied from the inlet and discharged from the steam outlet to preheat at least the inner member of the bottom plate portion of the bottom plate portion and the side plate portion, and in the cavity surrounded by the bottom plate portion and the side plate portion of the mold Pour molten sulfur-containing material into the steam chamber, gradually reduce or stop the steam supplied to the steam chamber, gradually cool the sulfur-containing material in the cavity, and cool and solidify the sulfur-containing material in the cavity Then, the sulfur solidified body can be produced by taking out the sulfur solidified body molded in this manner from the mold. Thereby, rapid cooling of the molten sulfur-containing material poured into the cavity surrounded by the bottom plate portion and the side plate portion can be prevented, and the surface roughness of the sulfur solidified body can be reduced. In addition, after pouring molten sulfur-containing material, the steam supplied to the steam chamber is reduced or stopped to gradually cool the sulfur-containing material in the mold to produce a homogeneous high-quality sulfur solidified body. . The slow cooling rate can be adjusted by controlling the vapor pressure in the vapor chamber.

そして、請求項2又は5に係る発明によれば、硫黄固化体を成形する型枠の底板部及び側板部の両方を二重構造として蒸気室を設け、上記底板部及び側板部の両方の内側部材を加熱することができる。また、常に蒸気室内の蒸気を入れ替えることで、上記底板部及び側板部の両方の内側部材を高温に加熱することができる。これにより、底板部及び側板部により囲まれたキャビティー内に流し込まれた溶融状態の硫黄含有資材の急冷を防止して、硫黄固化体の表面の荒れを低減することができる。   And according to the invention which concerns on Claim 2 or 5, a steam chamber is provided by making both the baseplate part and side plate part of a mold which shape | mold a sulfur solidified body into a double structure, and the inside of both the said baseplate part and side plate part The member can be heated. Moreover, the inner members of both the bottom plate part and the side plate part can be heated to a high temperature by always replacing the steam in the steam chamber. Thereby, rapid cooling of the molten sulfur-containing material poured into the cavity surrounded by the bottom plate portion and the side plate portion can be prevented, and the surface roughness of the sulfur solidified body can be reduced.

さらに、請求項3又は6に係る発明によれば、蒸気室が設けられた底板部及び側板部の外側部材の背面に設けられた断熱材層によって、硫黄固化体を成形する型枠の底板部及び側板部の温度低下を抑えることができる。この場合、熱効率が向上して底板部及び側板部の内側部材をより高温に加熱することが可能となる。   Furthermore, according to the invention which concerns on Claim 3 or 6, the baseplate part of the formwork which shape | molds a sulfur solidified body by the heat insulating material layer provided in the back surface of the outer side member of the baseplate part in which the steam chamber was provided, and the side plate part. And the temperature fall of a side-plate part can be suppressed. In this case, the thermal efficiency is improved and the inner members of the bottom plate portion and the side plate portion can be heated to a higher temperature.

以下、本発明の実施形態を添付図面に基づいて詳細に説明する。図1は本発明による硫黄成形体用型枠の実施形態を示す平面断面図であり、図2は上記硫黄成形体用型枠の実施形態を示す正面断面図である。この型枠1は、底板部及び側板部により囲まれたキャビティー内に流し込まれた溶融状態の硫黄含有資材を冷却固化させて例えば直方体形状の硫黄固化体を成形するもので、図1及び図2に示すように、側板部2,3,4と、底板部5とを備えて成る。ここで、上記底板部5及びこの底板部5の周縁に立設された側板部2,3,4により囲まれた直方体空間がキャビティーCとなる。また、上記側板部2,3,4及び底板部5は、基台6に載せられている。   Embodiments of the present invention will be described below in detail with reference to the accompanying drawings. FIG. 1 is a plan sectional view showing an embodiment of a mold for sulfur molding according to the present invention, and FIG. 2 is a front sectional view showing an embodiment of the mold for sulfur molding. The mold 1 is formed by cooling and solidifying a molten sulfur-containing material poured into a cavity surrounded by a bottom plate portion and side plate portions to form, for example, a rectangular solid-shaped sulfur solidified body. As shown in FIG. 2, side plate portions 2, 3, and 4 and a bottom plate portion 5 are provided. Here, a rectangular parallelepiped space surrounded by the bottom plate portion 5 and the side plate portions 2, 3, 4 erected on the periphery of the bottom plate portion 5 is a cavity C. The side plate portions 2, 3, 4 and the bottom plate portion 5 are mounted on a base 6.

上記底板部5及び側板部2,3,4は二重構造とされてそれぞれ蒸気室7が設けられ、この蒸気室7内に蒸気入口8から蒸気を供給すると共に蒸気出口9から蒸気を排出させることで、上記底板部5の内側部材5a及び側板部2,3,4の内側部材2a,3a,4aを加熱するようになっている。上記底板部5及び側板部2,3,4は、鋼板を主体として、必要に応じて鋼板、L形鋼、コ字形鋼などの鋼材で補強される。   The bottom plate portion 5 and the side plate portions 2, 3, 4 have a double structure and are each provided with a steam chamber 7. Steam is supplied into the steam chamber 7 from the steam inlet 8 and discharged from the steam outlet 9. Thus, the inner member 5a of the bottom plate portion 5 and the inner members 2a, 3a, 4a of the side plate portions 2, 3, 4 are heated. The bottom plate portion 5 and the side plate portions 2, 3, 4 are mainly reinforced by a steel material such as a steel plate, an L-shaped steel, and a U-shaped steel as needed.

上記側板部2,3,4の内側部材2a,3a,4a及び底板部5の内側部材5aの背面側には、所定の空間をあけて鋼板から成る外側部材2b,3b,4b,5bを溶接することで蒸気室7が形成されている。各蒸気室7の両端部の位置には、蒸気入口8及び蒸気出口9が設けられている。各蒸気入口8及び蒸気出口9には蒸気の開閉及び流量調整を行うバルブ(図示せず)が設けられている。蒸気入口8には高圧蒸気を供給する蒸気供給手段(ボイラーなど、図示せず)から蒸気が送られるパイプが接続される。また、蒸気出口9には安全な場所に蒸気を排出するためのパイプが接続される。   Outer members 2b, 3b, 4b, 5b made of steel plates are welded to the back side of the inner members 2a, 3a, 4a of the side plate portions 2, 3, 4 and the inner member 5a of the bottom plate portion 5 with a predetermined space therebetween. As a result, the steam chamber 7 is formed. A steam inlet 8 and a steam outlet 9 are provided at both ends of each steam chamber 7. Each steam inlet 8 and steam outlet 9 is provided with a valve (not shown) for opening and closing the steam and adjusting the flow rate. Connected to the steam inlet 8 is a pipe through which steam is sent from a steam supply means (not shown) such as a boiler for supplying high-pressure steam. The steam outlet 9 is connected to a pipe for discharging the steam to a safe place.

基台6は、上記側板部2,3,4及び底板部5を載せる台で、H形鋼、鋼板など適宜の鋼材を組み合わせて製造されるが、実施形態では鋼板で製造された例を示している。側板部2は、硫黄固化体の隣接する2辺を成形するもので、底板部5及び基台6に平面視でL字形に形成されて溶接固定されている。側板部3、4は、それぞれ硫黄固化体の他の1辺を成形するもので、図2に示すように、上記側板部3、4の下端に溶接固定されたL字形の脚部11の水平部分が、基台6に溶接固定されたガイド12(例えば角形パイプ)の中を摺動することで水平方向に移動可能となっている。なお、図2では、側板部3に設けられた脚部11だけが図示されているが、他の側板部4にも同様の脚部11が設けられている。底板部5は、硫黄固化体の底面を成形するもので、基台6の上面に溶接固定されている。   The base 6 is a stage on which the side plate portions 2, 3, 4 and the bottom plate portion 5 are placed, and is manufactured by combining appropriate steel materials such as H-shaped steel and steel plate. In the embodiment, an example of the steel plate is shown. ing. The side plate part 2 forms two adjacent sides of the sulfur solidified body, is formed in an L shape in plan view on the bottom plate part 5 and the base 6 and is fixed by welding. The side plate portions 3 and 4 respectively form the other side of the sulfur solidified body, and as shown in FIG. 2, the horizontal side of the L-shaped leg portion 11 welded and fixed to the lower ends of the side plate portions 3 and 4. The portion can move in the horizontal direction by sliding in a guide 12 (for example, a square pipe) fixed to the base 6 by welding. In FIG. 2, only the leg portion 11 provided on the side plate portion 3 is illustrated, but the other side plate portion 4 is provided with the same leg portion 11. The bottom plate portion 5 forms the bottom surface of the sulfur solidified body, and is fixed to the upper surface of the base 6 by welding.

また、上記蒸気室7が設けられた底板部5及び側板部2,3,4の外側部材2b,3b,4b,5bの背面には、断熱材層10が設けられている。この断熱材層10は、発泡プラスチック、グラスウールなどの適宜の断熱材を使用可能で、接着剤での接着、フラットバーで押さえるなどの公知手段によって取り付けることができる。   Further, a heat insulating material layer 10 is provided on the back surface of the outer member 2b, 3b, 4b, 5b of the bottom plate part 5 and the side plate parts 2, 3, 4 provided with the steam chamber 7. This heat insulating material layer 10 can use appropriate heat insulating materials such as foamed plastic and glass wool, and can be attached by known means such as bonding with an adhesive or pressing with a flat bar.

なお、図1及び図2に示すのは型枠1の側板部3,4を閉じた状態であり、側板部2,3,4の隣り合うもの同士を締付クランプ(図示せず)で締め付けて固定する。図3に示すのは型枠1の側板部3,4を開いた状態であり、該側板部3,4を外側に向かって水平方向に移動した状態である。この状態で成形の完了した硫黄固化体を取り出すことができる。   1 and 2 show the state in which the side plate portions 3 and 4 of the mold 1 are closed, and the adjacent ones of the side plate portions 2, 3 and 4 are clamped with a clamping clamp (not shown). And fix. FIG. 3 shows a state in which the side plate portions 3 and 4 of the mold 1 are opened, and the side plate portions 3 and 4 are moved in the horizontal direction toward the outside. In this state, the solidified sulfur molded body can be taken out.

ここで、前記硫黄固化体について説明する。この硫黄固化体は、常温では固体でありおよそ119℃を超えると溶融するという硫黄の性質を利用して、119℃以上に加熱して溶融させた硫黄に砂や砂利、石炭灰等を混合して、およそ119℃〜159℃を保持しながら練り混ぜ、これを冷却固化させて製造するものである。なお、ここでは、同様に加熱して溶融させた硫黄と、この溶融硫黄を変性する硫黄改質剤とを混合して改質硫黄を製造し、この改質硫黄に砂や砂利、石炭灰等を混合して、上記と同様に加熱しながら練り混ぜ、これを冷却固化させて製造する改質硫黄固化体を含むものとする。   Here, the said sulfur solidified body is demonstrated. This sulfur solidified material is solid at normal temperature and melts when it exceeds approximately 119 ° C. By mixing the sulfur that has been heated and melted above 119 ° C, sand, gravel, coal ash, etc. are mixed. The mixture is kneaded while maintaining a temperature of about 119 ° C. to 159 ° C., and is cooled and solidified. In addition, here, sulfur that has been heated and melted in the same manner and a sulfur modifier that modifies the molten sulfur are mixed to produce modified sulfur, and sand, gravel, coal ash, etc. And a modified sulfur solidified body produced by cooling and solidifying the mixture while heating and mixing in the same manner as described above.

上記改質硫黄固化体について更に詳細に説明する。改質硫黄固化体は、硫黄と、硫黄改質剤と、微細粉と、骨材とを原料として製造される。まず、溶融した硫黄と硫黄改質剤とを混合して改質硫黄を製造する。硫黄は、通常の単体硫黄であり、例えば天然産、又は石油や天然ガスの脱硫によって生成した硫黄等が挙げられる。硫黄改質剤は、溶融硫黄を変性、例えば硫黄を重合することによって改質する。この硫黄改質剤としては、硫黄を重合し得る化合物であればよく、例えば炭素数4〜20のオレフィン系炭化水素又はジオレフィン系炭化水素、具体的には、リモネン、ピネン等の環状オレフィン系炭化水素、スチレン、ビニルトルエン、メチルスチレン等の芳香族炭化水素、ジシクロペンタジエン(DCPD)及びそのオリゴマ−、シクロペンタジエン、テトラハイドロインデン(THI)、ビニルシクロヘキセン、ビニルノルボルネン、エチリデンノルボルネン、シクロオクタジエン等のジエン系炭化水素等の1種又は2種以上との混合物が挙げられる。上記硫黄と硫黄改質剤との混合は、硫黄が溶融した状態、すなわち119〜159℃、好ましくは130〜155℃の温度で行われる。   The modified sulfur solidified body will be described in more detail. The modified sulfur solidified body is produced using sulfur, sulfur modifier, fine powder, and aggregate as raw materials. First, molten sulfur and a sulfur modifier are mixed to produce modified sulfur. Sulfur is normal elemental sulfur, for example, sulfur produced naturally or by desulfurization of petroleum or natural gas. Sulfur modifiers modify molten sulfur by modifying, for example, polymerizing sulfur. The sulfur modifier may be any compound that can polymerize sulfur, for example, an olefinic hydrocarbon or diolefinic hydrocarbon having 4 to 20 carbon atoms, specifically, cyclic olefins such as limonene and pinene. Hydrocarbons, aromatic hydrocarbons such as styrene, vinyltoluene, methylstyrene, dicyclopentadiene (DCPD) and its oligomers, cyclopentadiene, tetrahydroindene (THI), vinylcyclohexene, vinylnorbornene, ethylidenenorbornene, cyclooctadiene And a mixture with one or more of diene-based hydrocarbons and the like. The mixing of the sulfur and the sulfur modifier is performed in a state where sulfur is melted, that is, at a temperature of 119 to 159 ° C, preferably 130 to 155 ° C.

前記改質硫黄は、硫黄と硫黄改質剤とを溶融混合することで得ることができるが、このときの硫黄改質剤の使用割合は、硫黄と硫黄改質剤との合計量に対して、通常0.1〜30質量%、特に1.0〜20質量%の割合が好ましい。得られた改質硫黄は、所定の温度(例えば150℃)に加温された微細粉と混合されて改質硫黄中間資材とされる。微細粉としては、石炭灰、珪砂、シリカヒューム、ガラス粉末、燃料焼却灰、電気集塵灰及び貝殻粉砕物のうち1種又は2種以上を選択すればよい。   The modified sulfur can be obtained by melting and mixing sulfur and a sulfur modifier. At this time, the use ratio of the sulfur modifier is based on the total amount of sulfur and the sulfur modifier. Usually, a ratio of 0.1 to 30% by mass, particularly 1.0 to 20% by mass is preferable. The obtained modified sulfur is mixed with fine powder heated to a predetermined temperature (for example, 150 ° C.) to obtain a modified sulfur intermediate material. As the fine powder, one or more of coal ash, silica sand, silica fume, glass powder, fuel incineration ash, electrostatic dust collection ash, and shell pulverized material may be selected.

上記得られた改質硫黄中間資材は、溶融状態を保つことのできる温度(例えば130〜140℃)に保持された状態で、例えば130〜140℃程度に加温された骨材と混合される。この骨材は、骨材として使用可能であれば特に限定されず、一般にコンクリートで用いられる骨材を使用できる。このような骨材としては、例えば、天然石、砂、れき、硅砂、鉄鋼スラグ、フェロニッケルスラグ、銅スラグ、金属の製造時に生成される副生物、溶融スラグ類、貝殻及びこれらの混合物等からなる群より選択される1種又は2種以上が挙げられる。   The obtained modified sulfur intermediate material is mixed with an aggregate heated to, for example, about 130 to 140 ° C. while being maintained at a temperature capable of maintaining a molten state (for example, 130 to 140 ° C.). . The aggregate is not particularly limited as long as it can be used as an aggregate, and an aggregate generally used in concrete can be used. Examples of such aggregates include natural stone, sand, rubble, dredged sand, steel slag, ferronickel slag, copper slag, by-products generated during metal production, molten slag, shells, and mixtures thereof. 1 type (s) or 2 or more types selected from a group are mentioned.

上記の改質硫黄中間資材と骨材とを、例えば混練装置を用いて混合することによって改質硫黄資材が製造され、これを冷却して固化させることで改質硫黄固化体が製造される。   The modified sulfur intermediate material and the aggregate are mixed by using, for example, a kneading apparatus to produce a modified sulfur material, and this is cooled and solidified to produce a modified sulfur solidified body.

次に、上記のように構成された型枠1を用いて硫黄固化体を成形する製造方法について、その手順を説明する。図1、図2に示すように、型枠1を閉じた状態で、蒸気入口8及び蒸気出口9のバルブを開き、蒸気室7内に蒸気を導いて底板部5の内側部材5a及び側板部2,3,4の内側部材2a,3a,4aを予備加熱する。各内側部材2a,3a,4a,5aの表面温度は、硫黄含有資材の固化温度と同程度か、それよりもやや高い温度となるようにするのが好ましく、通常は119〜130℃程度が好適である。そのためには、蒸気室7内の蒸気圧を2気圧程度あるいはそれよりもやや高い程度の圧力となるようにバルブ調整をする。   Next, the procedure of a manufacturing method for forming a sulfur solidified body using the mold 1 configured as described above will be described. As shown in FIGS. 1 and 2, with the mold 1 closed, the valves of the steam inlet 8 and the steam outlet 9 are opened, and the steam is guided into the steam chamber 7, so that the inner member 5 a and the side plate portion of the bottom plate portion 5. The inner members 2a, 3a, 4a of 2, 3, 4 are preheated. It is preferable that the surface temperature of each inner member 2a, 3a, 4a, 5a is the same as or slightly higher than the solidification temperature of the sulfur-containing material, and usually about 119 to 130 ° C is preferable. It is. For this purpose, the valve is adjusted so that the vapor pressure in the vapor chamber 7 is about 2 atm or slightly higher.

次に、型枠1のキャビティーC内に硫黄含有資材を流し込む。このとき、底板部5の内側部材5a及び側板部2,3,4の内側部材2a,3a,4aが予備加熱されているので、硫黄含有資材は底板部5及び側板部2,3,4に触れても急激に固化することがない。通常は、この状態で型枠1に振動を与えて硫黄含有資材をキャビティーCの隅々に行き渡らせる。次に、蒸気入口8又は蒸気出口の9のバルブを調整して蒸気の供給量を徐々に減らすか、蒸気入口8のバルブを閉めて蒸気を止めることで、型枠1内の硫黄含有資材を徐冷する。これにより、型枠1内の硫黄含有資材は外側部分から内側部分に向かって徐々に固化していき、表面の荒れのない硫黄固化体が成形される。その後、図3に示すように型枠1の側板部3,4を開き、成形の完了した硫黄固化体をその型枠1から取り出す。   Next, a sulfur-containing material is poured into the cavity C of the mold 1. At this time, since the inner member 5a of the bottom plate part 5 and the inner members 2a, 3a, 4a of the side plate parts 2, 3, 4 are preheated, the sulfur-containing material is transferred to the bottom plate part 5 and the side plate parts 2, 3, 4 Even if touched, it does not solidify rapidly. Usually, in this state, the mold 1 is vibrated to spread the sulfur-containing material to every corner of the cavity C. Next, by adjusting the valve of the steam inlet 8 or the steam outlet 9 to gradually reduce the amount of steam supplied or by closing the steam inlet 8 valve to stop the steam, the sulfur-containing material in the mold 1 is removed. Slowly cool. Thereby, the sulfur-containing material in the mold 1 is gradually solidified from the outer portion toward the inner portion, and a sulfur solidified body having no rough surface is formed. Thereafter, as shown in FIG. 3, the side plate portions 3 and 4 of the mold 1 are opened, and the molded sulfur solidified body is taken out from the mold 1.

図4は他の実施形態の型枠20を示す平面図であり、図5は図4におけるA−A線断面図である。この型枠20は、厚さが薄いパネル状の硫黄固化体を成形するもので、側板部21、22、23、24、底板部25及び基台26などからなる。側板部21〜24及び底板部25で囲まれた空間がキャビティーCとなる。側板部21〜24及び底板部25は、鋼板を主体として、必要に応じて鋼板、L形鋼、コ字形鋼などの鋼材で補強される(補強鋼材は図示せず)。基台6は、側板部21〜24及び底板部25を載せる台となるもので、H形鋼、鋼板など適宜の鋼材を組み合わせて製造されるが、実施形態は鋼板で製造された例を示している。   FIG. 4 is a plan view showing a mold 20 according to another embodiment, and FIG. 5 is a cross-sectional view taken along line AA in FIG. The mold 20 is for molding a panel-shaped sulfur solidified body having a small thickness, and includes side plate portions 21, 22, 23, 24, a bottom plate portion 25, a base 26, and the like. A space surrounded by the side plate portions 21 to 24 and the bottom plate portion 25 is a cavity C. The side plate portions 21 to 24 and the bottom plate portion 25 are mainly reinforced with steel plates such as steel plates, L-shaped steels, and U-shaped steels as necessary (reinforcing steel materials are not shown). The base 6 serves as a base on which the side plate portions 21 to 24 and the bottom plate portion 25 are placed, and is manufactured by combining appropriate steel materials such as H-shaped steel and steel plate, but the embodiment shows an example manufactured by a steel plate. ing.

上記側板部21〜24は、硫黄固化体の各辺を成形するもので、基台26に蝶番31により回動可能に取り付けられている。図4及び図5の実線で示すのは型枠20を閉じた状態で、側板部21〜24の隣り合うもの同士を締付クランプ(図示せず)で締め付け固定する。図5に鎖線で示すのは型枠20を開いた状態で、側板部21〜24を外方に倒した状態である。この状態で成形の完了した硫黄固化体を取り出すことができる。底板部25は、硫黄固化体の底面を成形するもので、基台6に溶接固定されている。なお、図5において、符号25aは底板部25の内側部材を示し、符号25bは底板部25の外側部材を示している。   The said side-plate parts 21-24 shape | mold each side of a sulfur solidified body, and are attached to the base 26 so that rotation is possible by the hinge 31. FIG. 4 and FIG. 5 shows a state in which the mold 20 is closed, and the adjacent ones of the side plate portions 21 to 24 are clamped and fixed with a clamping clamp (not shown). In FIG. 5, a chain line indicates a state where the side plate portions 21 to 24 are tilted outward while the mold 20 is opened. In this state, the solidified sulfur molded body can be taken out. The bottom plate portion 25 forms the bottom surface of the sulfur solidified body and is fixed to the base 6 by welding. In FIG. 5, reference numeral 25 a indicates an inner member of the bottom plate portion 25, and reference numeral 25 b indicates an outer member of the bottom plate portion 25.

上記底板部25の内側部材25aの背面側には、所定の空間をあけて鋼板から成る外側部材25bを溶接することで蒸気室27が形成されている。蒸気室27には、蒸気入口28及び蒸気出口29が設けられている。蒸気入口28及び蒸気出口29には蒸気の開閉及び流量調整を行うバルブ(図示せず)が設けられている。蒸気入口28には高圧蒸気を供給する蒸気供給手段(ボイラーなど、図示せず)から蒸気が送られるパイプが接続される。蒸気出口29には安全な場所に蒸気を排出するためのパイプが接続される。また、蒸気室27の背面(下面)には、断熱材層30を設けている。この断熱材層30は、発泡プラスチック、グラスウールなどの適宜の断熱材を使用可能で、接着剤での接着、フラットバーで押さえるなどの公知手段によって取り付けることができる。   A steam chamber 27 is formed on the back surface side of the inner member 25a of the bottom plate portion 25 by welding an outer member 25b made of a steel plate with a predetermined space therebetween. The steam chamber 27 is provided with a steam inlet 28 and a steam outlet 29. The steam inlet 28 and the steam outlet 29 are provided with valves (not shown) for opening and closing the steam and adjusting the flow rate. The steam inlet 28 is connected to a pipe through which steam is sent from a steam supply means (not shown) such as a boiler for supplying high-pressure steam. A pipe for discharging steam to a safe place is connected to the steam outlet 29. In addition, a heat insulating material layer 30 is provided on the back surface (lower surface) of the vapor chamber 27. This heat insulating material layer 30 can use an appropriate heat insulating material such as foamed plastic or glass wool, and can be attached by known means such as adhesion with an adhesive or pressing with a flat bar.

この実施形態では、蒸気室27は、底板部25にのみ設けられ、側板部21〜24には設けられていない。これは、成形する硫黄固化体の形状が薄いパネル状で、側板部21〜24の面積が小さいので、硫黄含有資材の固化に与える影響が少ないためである。また、底板部25を予備加熱すると、底板部25の内側部材25aの熱が側板部21〜24にも伝達され、側板部21〜24もある程度予備加熱されることとなる。このように、型枠20のうちで面積の小さい部分には蒸気室を設けないことも可能である。型枠20で硫黄固化体を成形する手順は、前述の型枠1で硫黄固化体を成形する手順に準じて行えばよい。   In this embodiment, the steam chamber 27 is provided only in the bottom plate portion 25 and is not provided in the side plate portions 21 to 24. This is because the shape of the sulfur solidified body to be molded is a thin panel shape and the area of the side plate portions 21 to 24 is small, so that the influence on the solidification of the sulfur-containing material is small. Moreover, when the baseplate part 25 is preheated, the heat of the inner member 25a of the baseplate part 25 will be transmitted also to the side plate parts 21-24, and the side plate parts 21-24 will also be preheated to some extent. Thus, it is also possible not to provide a steam chamber in a portion having a small area in the mold 20. What is necessary is just to perform the procedure which shape | molds a sulfur solidified body with the mold 20 according to the procedure which shape | molds a sulfur solidified body with the above-mentioned mold 1. FIG.

本発明による硫黄成形体用型枠の実施形態を示す平面断面図である。It is a plane sectional view showing an embodiment of a formwork for sulfur fabrication objects by the present invention. 上記型枠の実施形態を示す正面断面図である。It is front sectional drawing which shows embodiment of the said formwork. 上記型枠の側板部を開いた状態を示す平面図である。It is a top view which shows the state which opened the side-plate part of the said formwork. 他の実施形態による型枠を示す平面図である。It is a top view which shows the formwork by other embodiment. 図4におけるA−A線断面図である。It is the sectional view on the AA line in FIG.

符号の説明Explanation of symbols

1 型枠
2〜4 側板部
2a〜4a 内側部材
2b〜4b 外側部材
5 底板部
5a 内側部材
5b 外側部材
6 基台
7 蒸気室
8 蒸気入口
9 蒸気出口
10 断熱材層
11 脚部
12 ガイド
20 型枠
21〜24 側板部
25 底板部
25a 内側部材
25b 外側部材
26 基台
27 蒸気室
28 蒸気入口
29 蒸気出口
30 断熱材層
31 蝶番
DESCRIPTION OF SYMBOLS 1 Formwork 2-4 Side board part 2a-4a Inner member 2b-4b Outer member 5 Bottom board part 5a Inner member 5b Outer member 6 Base 7 Steam chamber 8 Steam inlet 9 Steam outlet 10 Heat insulating material layer 11 Leg part 12 Guide 20 type | mold Frames 21 to 24 Side plate portion 25 Bottom plate portion 25a Inner member 25b Outer member 26 Base 27 Steam chamber 28 Steam inlet 29 Steam outlet 30 Heat insulation material layer 31 Hinge

Claims (6)

底板部及びこの底板部の周縁に立設された側板部により囲まれたキャビティー内に流し込まれた溶融状態の硫黄含有資材を冷却固化させて硫黄固化体を成形する型枠であって、
上記底板部及び側板部のうち少なくとも底板部を二重構造として蒸気室を設け、この蒸気室内に蒸気入口から蒸気を供給すると共に蒸気出口から蒸気を排出させることで、上記底板部及び側板部のうち少なくとも底板部の内側部材を加熱し、上記キャビティー内に流し込まれた硫黄含有資材の急冷を防止することを特徴とする硫黄成形体用型枠。
A mold for forming a solidified sulfur by cooling and solidifying a molten sulfur-containing material poured into a cavity surrounded by a bottom plate and a side plate standing on the periphery of the bottom plate,
A steam chamber is provided with at least a bottom plate portion of the bottom plate portion and the side plate portion as a double structure, and steam is supplied into the steam chamber from the steam inlet and discharged from the steam outlet, so that the bottom plate portion and the side plate portion Among them, a formwork for a sulfur molded body characterized in that at least an inner member of a bottom plate portion is heated to prevent quenching of a sulfur-containing material poured into the cavity.
上記底板部及び側板部の両方を二重構造として蒸気室を設け、この蒸気室内に蒸気入口から蒸気を供給すると共に蒸気出口から蒸気を排出させることで、上記底板部及び側板部の両方の内側部材を加熱することを特徴とする請求項1記載の硫黄成形体用型枠。   Both the bottom plate part and the side plate part are provided with a steam chamber, and a steam chamber is provided, and steam is supplied into the steam chamber from the steam inlet and discharged from the steam outlet, so that the inside of both the bottom plate part and the side plate part is provided. The formwork for a sulfur molded body according to claim 1, wherein the member is heated. 上記蒸気室が設けられた底板部及び側板部の外側部材の背面には、断熱材層を設けたことを特徴とする請求項1又は2記載の硫黄成形体用型枠。   The formwork for a sulfur molded body according to claim 1 or 2, wherein a heat insulating material layer is provided on the back surface of the outer member of the bottom plate portion and the side plate portion provided with the steam chamber. 底板部及びこの底板部の周縁に立設された側板部のうち少なくとも底板部を二重構造として蒸気室を設けた型枠の該蒸気室内に蒸気入口から蒸気を供給すると共に蒸気出口から蒸気を排出させ、上記底板部及び側板部のうち少なくとも底板部の内側部材を予備加熱するステップと、
上記型枠の底板部及び側板部により囲まれたキャビティー内に溶融状態の硫黄含有資材を流し込むステップと、
上記蒸気室内に供給する蒸気を徐々に少なくし、又は止めて上記キャビティー内の硫黄含有資材を徐冷するステップと、
上記キャビティー内の硫黄含有資材が冷却固化して成形された硫黄固化体を上記型枠から取り出すステップと、
を行うことを特徴とする硫黄成形体の製造方法。
Steam is supplied from the steam inlet to the steam chamber of the mold provided with a steam chamber with at least the bottom plate portion of the bottom plate portion and the side plate portion erected on the periphery of the bottom plate portion, and steam is supplied from the steam outlet. Discharging and preheating at least the inner member of the bottom plate portion of the bottom plate portion and the side plate portion; and
Pouring a molten sulfur-containing material into a cavity surrounded by a bottom plate portion and a side plate portion of the mold, and
Gradually reducing or stopping the steam supplied into the steam chamber and gradually cooling the sulfur-containing material in the cavity;
Removing the sulfur solidified material formed by cooling and solidifying the sulfur-containing material in the cavity from the mold, and
A method for producing a sulfur molded body characterized in that
上記底板部及び側板部の両方を二重構造として蒸気室を設け、この蒸気室内に蒸気入口から蒸気を供給すると共に蒸気出口から蒸気を排出させることで、上記底板部及び側板部の両方の内側部材を予備加熱することを特徴とする請求項4記載の硫黄成形体の製造方法。   Both the bottom plate part and the side plate part are provided with a steam chamber, and a steam chamber is provided, and steam is supplied into the steam chamber from the steam inlet and discharged from the steam outlet, so that the inside of both the bottom plate part and the side plate part is provided. The method for producing a sulfur molded body according to claim 4, wherein the member is preheated. 上記蒸気室が設けられた底板部及び側板部の外側部材の背面には、断熱材層を設けたことを特徴とする請求項4又は5記載の硫黄成形体の製造方法。   The method for producing a sulfur molded body according to claim 4 or 5, wherein a heat insulating material layer is provided on the back surface of the outer member of the bottom plate portion and the side plate portion provided with the steam chamber.
JP2006088312A 2006-03-28 2006-03-28 Form for sulfur molded body and method for producing sulfur molded body Expired - Fee Related JP4820970B2 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010029787A1 (en) * 2008-09-12 2010-03-18 新日本石油株式会社 Formwork apparatus for solidified sulfur product
JP2010228445A (en) * 2009-03-02 2010-10-14 Jx Nippon Oil & Energy Corp Method for manufacturing solidified sulfur panel, sulfur solidified sulfur panel, and method for mounting solidified sulfur panel

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4825696A (en) * 1971-08-05 1973-04-03
JPH04504101A (en) * 1989-03-10 1992-07-23 カーカーカーカー アクティー ゼルスカブ Acid-resistant concrete products, especially sulfur concrete pipes and their manufacturing method
JP2005082475A (en) * 2003-09-11 2005-03-31 Nippon Oil Corp Intermediate sulfur material, sulfur material and its producing method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4825696A (en) * 1971-08-05 1973-04-03
JPH04504101A (en) * 1989-03-10 1992-07-23 カーカーカーカー アクティー ゼルスカブ Acid-resistant concrete products, especially sulfur concrete pipes and their manufacturing method
JP2005082475A (en) * 2003-09-11 2005-03-31 Nippon Oil Corp Intermediate sulfur material, sulfur material and its producing method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010029787A1 (en) * 2008-09-12 2010-03-18 新日本石油株式会社 Formwork apparatus for solidified sulfur product
JP2010064409A (en) * 2008-09-12 2010-03-25 Nippon Oil Corp Mold device for sulfur solidified product
JP2010228445A (en) * 2009-03-02 2010-10-14 Jx Nippon Oil & Energy Corp Method for manufacturing solidified sulfur panel, sulfur solidified sulfur panel, and method for mounting solidified sulfur panel

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