JP2007244218A - Oil-and-fat composition for whipped cream - Google Patents

Oil-and-fat composition for whipped cream Download PDF

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JP2007244218A
JP2007244218A JP2006068311A JP2006068311A JP2007244218A JP 2007244218 A JP2007244218 A JP 2007244218A JP 2006068311 A JP2006068311 A JP 2006068311A JP 2006068311 A JP2006068311 A JP 2006068311A JP 2007244218 A JP2007244218 A JP 2007244218A
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oil
fatty acid
whipped cream
mass
fat
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Yosuke Miyazaki
洋祐 宮崎
Shuichi Abe
秀一 阿部
Motoharu Arai
基晴 新井
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NOF Corp
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NOF Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an oil-and-fat composition for whipped cream substantially containing no trans acid and developing the same physical property as that developed when using a conventional oil-and-fat composition for whipped cream containing hardened oil. <P>SOLUTION: The oil-and-fat composition for whipped cream comprises 5-50 pts.mass of extremely hardened oil and fat whose constituent fatty acid has 5-60 mass% of 20-24C saturated fatty acid as a component (A), and 50-95 pts.mass of liquid oil and fat as a component B. The oil and fat composition has a melting point of the 35-50°C, and the constituent fatty acid of the oil and fat composition contains 10-60 mass% of saturated fatty acid. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、トランス型脂肪酸を実質的に含有しないホイップクリーム用油脂組成物及びこれを原料とするホイップクリームに関する。   The present invention relates to a whipped cream oil composition substantially free of trans fatty acids and whipped cream using the same as a raw material.

ホイップクリームはケーキ類やパフェ等洋菓子に大量に使用されている。その種類は牛乳を遠心分離して得られる生クリーム、動植物性脂肪を加工して得られる合成クリーム、さらに前記二者を混合したコンパウンドクリームの3種類に大別される。ホイップクリームは油脂組成物を水に乳化し、これに空気を抱き込ませるようにホイップして製造される。これらクリーム類の大部分は、水中油型乳化液として流通・販売されており、最終使用者である製菓工場や洋菓子店、家庭で必要に応じてその都度ホイップして使用されている。   Whipped cream is used in large quantities in pastries such as cakes and parfaits. The types are roughly classified into three types: fresh cream obtained by centrifuging milk, synthetic cream obtained by processing animal and vegetable fats, and compound cream obtained by mixing the two. The whipped cream is manufactured by emulsifying an oil / fat composition in water and whipping it so that air is embraced therein. Most of these creams are distributed and sold as oil-in-water emulsions, and are used by whipping each time as needed in confectionery factories, pastry shops, and homes that are end users.

ホイップクリーム用水中油型乳化液は、流通・保管時の振動や温度変化などに対して、増粘・固化等の性質の変化を起こさない振動耐性や温度安定性などの乳化安定性の良いものが求められる。さらに、ホイップ時には短時間で解乳化し、適度のオーバーランが得られるホイップ性も求められる。また、ホイップ後のクリームの性能として、洋菓子等のトッピング、フィリングとして使用した場合の造花性や保形性などの形状の安定性、及び良好な食感が求められる。   Oil-in-water emulsions for whipped cream have good emulsion stability such as vibration resistance and temperature stability that do not cause changes in properties such as thickening and solidification against vibration and temperature changes during distribution and storage. Desired. Furthermore, whipability is also required in which demulsification is achieved in a short time during whipping and an appropriate overrun is obtained. Moreover, as the performance of the cream after whipping, the topping of Western confectionery or the like, the stability of the shape such as flower-forming property and shape retention when used as a filling, and a good texture are required.

生クリームを用いたホイップクリームは、口あたり、口溶け等の食感が良く、また比較的さっぱりとした乳味感を有しており、風味も非常に良好である。しかし、生クリームは高価で、品質の一定したものが供給されにくいという問題がある。またホイップさせるのに技術を要し、さらにホイップしたものは、不安定で、造花性が悪く、温度や振動によってその造形物が変形する等、使用しにくい欠点を持っている。   The whipped cream using the fresh cream has a good texture such as mouthfeel and melted mouth, a relatively refreshing milky taste, and a very good flavor. However, fresh cream is expensive and has a problem that it is difficult to supply a constant quality. In addition, it requires a technique for whipping, and the whipped product is unstable, has poor artificial nature, and has a drawback that it is difficult to use such as deformation of the modeled object due to temperature and vibration.

一方、合成クリームは今日では多くの改良研究が進み乳化安定性、ホイップ性等の物性も向上しており、生クリームに比べて安価なことから、今日では大量に使用されている。それら合成クリームの原料油脂としては、菜種油、ヤシ油、パーム油、パーム核油等の植物油やその分別油、またはこれらの部分硬化油(部分水素添加油)が多く使用されている。これらは部分水素添加時に生成したトランス酸により、水中油型乳化液の乳化安定性、ホイップ性を付与したものである(例えば、特許文献1等)。   On the other hand, synthetic creams are being used in large quantities today because many improvements have been made and physical properties such as emulsification stability and whipping properties have been improved and are cheaper than fresh creams. As raw oils and fats for these synthetic creams, vegetable oils such as rapeseed oil, coconut oil, palm oil and palm kernel oil, and fractionated oils thereof, or these partially hardened oils (partially hydrogenated oils) are often used. These are those obtained by imparting emulsification stability and whipping properties of an oil-in-water emulsion by transacid generated during partial hydrogenation (for example, Patent Document 1).

しかしながら、近年の研究では、トランス酸が血漿中のLDL/HDLコレステロール比を増大させ、循環器疾患の原因となるとの報告がある。このように、トランス酸を過剰摂取することによる健康への影響に対する懸念があるので、油脂中のトランス酸含量を少なくした方が好ましい。
特開2002−17256号公報
However, recent studies have reported that trans acid increases the LDL / HDL cholesterol ratio in plasma and causes cardiovascular disease. Thus, since there is a concern about the health effects caused by excessive intake of trans acid, it is preferable to reduce the trans acid content in the fats and oils.
JP 2002-17256 A

以上のように、振動耐性及び乳化安定性やホイップ性能に係わるトランス酸の含有量を少なくし、ホイップクリームに用いることのできる性能を持つ油脂組成物の開発が望まれていた。本研究はトランス酸を実質的に含まず、かつ従来の硬化油を用いたホイップクリーム用油脂組成物を使用する際の物性を発現できるホイップクリーム用油脂組成物を提供するものである。   As described above, it has been desired to develop an oil / fat composition having a performance that can be used for whipping cream by reducing the content of transacid related to vibration resistance, emulsion stability and whipping performance. This study provides an oil / fat composition for whipped cream that is substantially free of trans acid and can exhibit physical properties when using a conventional oil / fat composition for whipped cream using a hardened oil.

本発明は下記の発明である。
本発明における第1の発明は、A成分として構成脂肪酸中に炭素数20〜24の飽和脂肪酸を5〜60質量%含む極度硬化油脂5〜50質量部、及びB成分として液状油脂50〜95質量部からなるホイップクリーム用油脂組成物であって、油脂組成物の融点が35〜50℃であり、油脂組成物の構成脂肪酸中に飽和脂肪酸を10〜60質量%含むホイップクリーム用油脂組成物である。
The present invention is the following invention.
1st invention in this invention is 5-50 mass parts of extremely hardened fats and oils which contain 5-60 mass% of C20-24 saturated fatty acids in a constituent fatty acid as A component, and liquid fats 50-95 mass as B component. An oil / fat composition for whipped cream comprising a part, wherein the oil / fat composition has a melting point of 35 to 50 ° C., and comprises 10 to 60% by mass of a saturated fatty acid in a constituent fatty acid of the oil / fat composition. is there.

本発明における第2の発明は、A成分が構成脂肪酸中に炭素数12の飽和脂肪酸を2〜50質量%含む極度硬化油である第1の発明のホイップクリーム用油脂組成物である。   2nd invention in this invention is an oil-fat composition for whipped creams of 1st invention whose A component is an extremely hardened oil which contains 2-50 mass% of C12 saturated fatty acids in a constituent fatty acid.

本発明における第3の発明は、第1又は第2の発明のホイップクリーム用油脂組成物を原料とするホイップクリームである。   3rd invention in this invention is a whipped cream which uses the oil-fat composition for whipped cream of 1st or 2nd invention as a raw material.

本発明における第1の発明によれば、実質的にトランス酸を含有しない油脂組成物にも関わらず、水中油型乳化液の乳化安定性(振動耐性、温度安定性)、ホイップ性が優れ、ホイップクリームの造花性に優れたホイップクリーム用油脂組成物が提供される。   According to the first invention of the present invention, the oil-in-water emulsion has excellent emulsification stability (vibration resistance, temperature stability) and whip property despite the fact that the oil composition is substantially free of trans acid. An oil and fat composition for whipped cream having excellent whipped cream artificial flower properties is provided.

本発明における第2の発明によれば、第1の発明において、さらにホイップ後のクリームの口あたりや口溶け等の食感の良いホイップクリーム用油脂組成物が提供される。   According to the 2nd invention in this invention, in 1st invention, the oil-fat composition for whipped creams with a sufficient food texture, such as the mouth feel of a cream after whipping, and a mouth melt | dissolution, is further provided.

本発明における第3の発明によれば、生クリームを用いたホイップクリームと同等の性能を持つホイップクリームが提供される。   According to the 3rd invention in this invention, the whipped cream which has a performance equivalent to the whipped cream using a fresh cream is provided.

本発明に使用するホイップクリーム用油脂組成物は、A成分として構成脂肪酸中に炭素数20〜24の飽和脂肪酸を5〜60質量%含む極度硬化油脂及びB成分として液状油脂からなる油脂組成物である。   The fat and oil composition for whipped cream used in the present invention is an oil and fat composition comprising an extremely hardened fat and oil containing 5 to 60% by mass of a saturated fatty acid having 20 to 24 carbon atoms in the constituent fatty acid as the A component and a liquid fat and oil as the B component. is there.

(A成分)
本発明にA成分として使用する極度硬化油は、構成脂肪酸中に炭素数20〜24の飽和脂肪酸を5〜60質量%含む極度硬化油脂である。このような脂肪酸組成の油脂は天然界には知られておらず、本発明のA成分の極度硬化油は、脂肪酸とグリセリンとの合成や、天然油脂を極度硬化することにより得られる。また、それら極度硬化油同士をエステル交換、或いはエステル交換した天然油脂を極度硬化しても得ることができる。炭素数20〜24の飽和脂肪酸を構成成分に多く含む油脂としては、例えば、ハイエルシン菜種油や魚油等の極度硬化油が知られている。本発明のA成分として、これらの極度硬化油を用いることができる。また、これらの油脂と例えば菜種油、コーン油、大豆油、パーム油、パーム核油、ヤシ油等の油脂の極度硬化油とをエステル交換した油脂も用いることができる。
(A component)
The extremely hardened oil used as the component A in the present invention is an extremely hardened oil and fat containing 5 to 60% by mass of a saturated fatty acid having 20 to 24 carbon atoms in the constituent fatty acid. Oils and fats having such a fatty acid composition are not known in nature, and the extremely hardened oil of component A of the present invention can be obtained by synthesizing fatty acids and glycerin or by hardening natural oils and fats. Moreover, it can obtain even if extremely hardened natural fats and oils which transesterified these extremely hardened oils or transesterified. As fats and oils that contain a large amount of saturated fatty acids having 20 to 24 carbon atoms in their constituent components, for example, extremely hardened oils such as Hyelsin rapeseed oil and fish oil are known. These extremely hardened oils can be used as the component A of the present invention. In addition, fats and oils obtained by transesterifying these fats and oils with extremely hardened oils such as rapeseed oil, corn oil, soybean oil, palm oil, palm kernel oil, and palm oil can also be used.

本発明のA成分は極度硬化油である。極度硬化油は、油脂構成脂肪酸に含まれる脂肪酸の二重結合が水素添加により飽和された油脂であり、そのヨウ素価は1以下である。
水素添加は、原料油脂に、主にニッケル触媒を用いて、水添開始温度を120〜160℃、最高温度が180〜230℃となるようにコントロールしながら、水素を注入することによって行うことができる。
エステル交換油脂を用いる場合、エステル交換は水素添加する前の油脂に行ってもよく、また、水素添加後の油脂をエステル交換してもよい。
エステル交換はナトリウムメチラート等のアルカリ触媒を用いた方法或いは、リパーゼ等の酵素触媒を用いた方法等が挙げられるが、特に限定はされない。
The component A of the present invention is an extremely hardened oil. Extremely hardened oil is fat and oil in which the double bond of fatty acid contained in fat and oil constituting fatty acid is saturated by hydrogenation, and the iodine value thereof is 1 or less.
Hydrogenation is performed by injecting hydrogen into the raw oil and fat, mainly using a nickel catalyst while controlling the hydrogenation start temperature to be 120 to 160 ° C. and the maximum temperature to be 180 to 230 ° C. it can.
When using transesterified fats and oils, transesterification may be performed on the fats and oils before hydrogenation, and the fats and oils after hydrogenation may be transesterified.
The transesterification includes a method using an alkali catalyst such as sodium methylate or a method using an enzyme catalyst such as lipase, but is not particularly limited.

本発明は、A成分として使用する構成脂肪酸中に炭素数20〜24の飽和脂肪酸を5〜60質量%含む極度硬化油脂を使用することを特徴とする。炭素数20〜24の飽和脂肪酸量が5質量%に満たない場合、これを用いて製造させる水中油型乳化液をホイップする際の時間がかかりすぎるといった問題やホイップクリームの造花性が悪くなり、60質量%を超えるとホイップクリームの口溶けが悪く、食感が悪化しやすくなる。また、極度硬化油脂を使用しないで、部分硬化油を使用する場合、トランス酸含有量が増加してしまう。   The present invention is characterized by using an extremely hardened oil and fat containing 5 to 60% by mass of a saturated fatty acid having 20 to 24 carbon atoms in the constituent fatty acid used as the component A. If the amount of saturated fatty acid having 20 to 24 carbon atoms is less than 5% by mass, the problem that it takes too much time to whip an oil-in-water emulsion to be produced using this, and the artificial nature of whipped cream, When it exceeds 60% by mass, the whipped cream is poorly melted and the texture is liable to deteriorate. Moreover, when using partially hardened oil, without using extremely hardened oil and fat, trans acid content will increase.

本発明に使用するA成分は、さらに構成脂肪酸中に炭素数12の飽和脂肪酸を2〜50質量%含む極度硬化油脂であることが好ましい。
炭素数12の飽和脂肪酸を構成成分に多く含む油脂としては、パーム核油、ヤシ油等のようにヤシ科の種子から得られる油脂、及びそれらを分別、水素添加、エステル交換した油脂が挙げられる。A成分としては、上述の炭素数20〜24の脂肪酸を構成成分に多く含む油脂と炭素数8〜12の飽和脂肪酸を構成成分に多く含む油脂とのエステル交換油脂であることが好ましい。例えば、好ましいA成分として、ハイエルシン菜種極度硬化油とパーム核極度硬化油及び/又はヤシ極度硬化油とのエステル交換油を例示できる。
A成分の構成脂肪酸中に炭素数12の飽和脂肪酸が含まれると、ホイップクリームの口溶けがより良くなるので好ましい。炭素数12の飽和脂肪酸の含有量が2質量%未満であれば、ホイップクリームの口あたり、口溶け等の食感が悪くなり、50質量%を超えるとホイップクリームの粘稠性や造花性が悪くなるおそれがある。
The component A used in the present invention is preferably an extremely hardened fat and oil containing 2 to 50% by mass of a saturated fatty acid having 12 carbon atoms in the constituent fatty acid.
Examples of fats and oils that contain a large amount of saturated fatty acids having 12 carbon atoms as constituents include fats and oils obtained from palm seeds such as palm kernel oil and palm oil, and oils and fats obtained by fractionating, hydrogenating, and transesterifying them. . The component A is preferably a transesterified oil / fat of an oil / fat containing a large amount of the fatty acid having 20 to 24 carbon atoms as a component and an oil / fat containing a saturated fatty acid having a carbon number of 8 to 12 as a component. For example, as a preferable A component, a transesterified oil of Hyelsin rapeseed extremely hardened oil and palm kernel extremely hardened oil and / or palm extremely hardened oil can be exemplified.
It is preferable that a saturated fatty acid having 12 carbon atoms is contained in the constituent fatty acid of the component A, since the melting of the whipped cream becomes better. If the content of saturated fatty acids having 12 carbon atoms is less than 2% by mass, the mouthfeel of the whipped cream will be poor in mouthfeel, and if it exceeds 50% by mass, the whipped cream will have poor consistency and artificial nature. There is a risk.

(B成分)
本発明にB成分として使用する液状油脂は、25℃で液状の油脂であり、特に限定されないが、例えば、菜種油、コーン油、大豆油、米油、米糠油、ヒマワリ油、ハイオレイックヒマワリ油、サフラワー油、ハイオレイックサフラワー油、オリーブ油、綿実油、あるいはそれらの分別油等が挙げられ、それらを1種又は2種以上使用することができる。さらに液状油脂の融点が10℃以下であることが好ましい。
(B component)
The liquid fat used as component B in the present invention is a liquid fat at 25 ° C. and is not particularly limited. For example, rapeseed oil, corn oil, soybean oil, rice oil, rice bran oil, sunflower oil, high oleic sunflower oil , Safflower oil, high oleic safflower oil, olive oil, cottonseed oil, or fractionated oils thereof, and one or more of them can be used. Furthermore, it is preferable that melting | fusing point of liquid fats is 10 degrees C or less.

(ホイップクリーム用油脂組成物)
本発明のホイップクリーム用油脂組成物は、A成分の極度硬化油脂5〜50質量部とB成分の液状油脂50〜95質量部からなる油脂組成物であり、油脂組成物の融点が35〜50℃であり、油脂組成物の構成脂肪酸中に飽和脂肪酸を10〜60質量%含む油脂組成物である。
A成分の極度硬化油脂の含有量が5質量部未満の場合、すなわちB成分の液状油脂の含有量が95質量部を超える場合、これを用いて製造される水中油型乳化液のホイップ性能に劣ることになる。また、ホイップクリームを製造した際、粘稠性が弱いホイップクリームとなってしまい、造花したクリームの型が崩れやすい。A成分の極度硬化油脂の含有量が50質量部を超える場合、すなわちB成分の液状油脂の含有量が50質量部未満の場合、水中油型乳化液の振動耐性・温度安定性がなく、乳化安定性が悪くなってしまう場合がある。また、ホイップクリームを製造した際、造花性が悪化し、口溶けが悪くなりやすい。
(Oil composition for whipped cream)
The oil / fat composition for whipped cream of the present invention is an oil / fat composition comprising 5 to 50 parts by mass of the A component extremely hardened oil and fat and 50 to 95 parts by mass of the B component liquid oil / fat, and the melting point of the oil / fat composition is 35 to 50. It is an oil-and-fat composition which is 10 to 60 mass% of saturated fatty acid in the constituent fatty acid of oil-and-fat composition.
When the content of the extremely hardened fat of component A is less than 5 parts by mass, that is, when the content of the liquid fat of component B exceeds 95 parts by mass, the whipping performance of the oil-in-water emulsion produced using this It will be inferior. Moreover, when manufacturing whipped cream, it becomes a whipped cream having a low viscosity, and the shape of the artificial cream tends to collapse. When the content of the extremely hardened fat of component A exceeds 50 parts by mass, that is, when the content of the liquid fat of component B is less than 50 parts by mass, the oil-in-water emulsion does not have vibration resistance and temperature stability and is emulsified. Stability may deteriorate. Moreover, when producing whipped cream, the artificial nature deteriorates and the mouth melt tends to deteriorate.

油脂組成物の融点が35℃未満の場合、これを用いて製造される水中油型乳化液のホイップ性能に劣ることになる。また、ホイップクリームを製造した際、粘稠性が弱いホイップクリームとなってしまい、造花したクリームの型が崩れやすい。また、融点が50℃を超える場合、ホイップクリームの口溶けが悪くなってしまう。
油脂組成物の構成脂肪酸中に飽和脂肪酸を10質量%未満含む場合、ホイップクリームの粘稠性が下がり、クリームの型が崩れる等、造花性が悪くなる。飽和脂肪酸が60質量%を超えて含まれる場合、水中油型乳化液での乳化安定性が悪くなりやすい。また、ホイップクリームの口溶けが悪くなりやすい。
また、油脂組成物の構成脂肪酸中に炭素数20〜24の飽和脂肪酸は2.5〜30質量%、炭素数12の飽和脂肪酸は1〜30質量%であることが好ましい。
When melting | fusing point of an oil-fat composition is less than 35 degreeC, it will be inferior to the whipping performance of the oil-in-water type emulsion manufactured using this. Moreover, when manufacturing whipped cream, it becomes a whipped cream having a low viscosity, and the shape of the artificial cream tends to collapse. Moreover, when melting | fusing point exceeds 50 degreeC, the mouth melting of whipped cream will worsen.
When the fatty acid component of the oil / fat composition contains less than 10% by mass of saturated fatty acid, the whipped cream viscosity is lowered and the shape of the cream is broken, resulting in poor flowering properties. When saturated fatty acid is contained exceeding 60 mass%, the emulsion stability in an oil-in-water emulsion tends to deteriorate. In addition, the melting of the whipped cream tends to worsen.
Moreover, it is preferable that the saturated fatty acid of carbon number 20-24 is 2.5-30 mass%, and the saturated fatty acid of carbon number 12 is 1-30 mass% in the constituent fatty acid of the oil and fat composition.

本発明のホイップクリーム用油脂組成物は、上記の条件を満たすように、A成分とB成分を混合して製造することができる。   The oil and fat composition for whipped cream of the present invention can be produced by mixing the A component and the B component so as to satisfy the above conditions.

(ホイップクリーム)
本発明のホイップクリーム用油脂組成物は、これに水、乳化剤、酸化防止剤、着香料、着色料、保存料等を加えて水中油型乳化液を形成し、これを手だて、電動泡立て機、縦型ケーキミキサー、プレッシャーミキサー等で空気を抱き込ませるように撹拌し、ホイップさせる。
(Whipped cream)
The oil and fat composition for whipped cream of the present invention is added with water, an emulsifier, an antioxidant, a flavoring agent, a coloring agent, a preservative and the like to form an oil-in-water emulsion, Stir in a vertical cake mixer, pressure mixer, etc. so that air is entrapped, and whipped.

水中油型乳化液は、例えば、ホイップクリーム用油脂組成物100質量部に水100〜150質量部加え、乳化剤を加えて乳化して製造することができる。添加する乳化剤としては、例えばレシチン、グリセリン脂肪酸エステル、グリセリン酢酸脂肪酸エステル、グリセリン乳酸脂肪酸エステル、グリセリンコハク酸脂肪酸エステル、グリセリンジアセチル酒石酸脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ショ糖酢酸イソ酪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ポリオキシエチレンソルビタンモノステアレート、ポリオキシエチレンソルビタンモノグリセリド等が挙げられる。これらの乳化剤は単独で用いることもでき、又は2種類以上を組み合わせて用いることもできる。乳化する方法としては、撹拌機、高速乳化機等を用いる方法や、必要に応じ、バルブ式ホモジナイザー、ホモミキサー、コロイドミル等の均質化装置を用いる方法等が挙げられる。
製造される水中油型乳化液は、この形態で流通し、最終使用者である製菓工場や洋菓子店、家庭等で必要に応じてその都度ホイップしてホイップクリームが製造されることから、保存時の安定性が要求される。水中油型乳化液の安定性は、冷蔵(3℃〜10℃)保存時で60日間安定であることが好ましい。
The oil-in-water emulsion can be produced by, for example, adding 100 to 150 parts by mass of water to 100 parts by mass of the oil / fat composition for whipped cream and adding an emulsifier to emulsify. Examples of the emulsifier to be added include lecithin, glycerin fatty acid ester, glycerin acetic acid fatty acid ester, glycerin lactic acid fatty acid ester, glycerin succinic acid fatty acid ester, glycerin diacetyl tartaric acid fatty acid ester, sorbitan fatty acid ester, sucrose fatty acid ester, and sucrose acetate isobutyric acid ester. , Polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester, stearoyl calcium lactate, sodium stearoyl lactate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monoglyceride and the like. These emulsifiers can be used alone or in combination of two or more. Examples of the emulsification method include a method using a stirrer, a high-speed emulsifier, and the like, and a method using a homogenizer such as a valve homogenizer, a homomixer, or a colloid mill, if necessary.
The oil-in-water emulsions produced are distributed in this form, and whipped cream is produced by whipping each time as necessary at the confectionery factory, pastry shop, home, etc., which is the end user. Stability is required. The stability of the oil-in-water emulsion is preferably stable for 60 days when stored in a refrigerator (3 ° C. to 10 ° C.).

本発明のホイップクリームは、本発明のホイップクリーム用油脂組成物を原料とし、これを乳化した水中油型乳化液の油層部及び水層部に、必要に応じ、安定剤、蛋白質、糖類、果汁、ジャム、カカオ及びカカオ製品、コーヒー及びコーヒー製品等の呈味成分、調味料、着香料、着色料、保存料、酸化防止剤、pH調整剤等を加えて製造される。
上記安定剤としては、特に限定されないが、リン酸塩(ヘキサメタリン酸、第2リン酸、第1リン酸)、クエン酸のアルカリ金属塩(カリウム、ナトリウム等)、グアーガム、キサンタンガム、タマリンドガム、カラギーナン、アルギン酸塩、ファーセルラン、ローカストビーンガム、ペクチン、カードラン、澱粉、化工澱粉、結晶セルロース、ゼラチン、デキストリン、寒天、デキストラン等の安定剤が挙げられる。これらの安定剤は、単独で用いることもでき、又は2種以上を組み合わせて用いることもできる。
The whipped cream of the present invention is made from the oil-and-fat composition for whipped cream of the present invention as a raw material, and if necessary, a stabilizer, protein, saccharide, fruit juice , Jam, cacao and cacao products, coffee and coffee products, and other flavoring ingredients, seasonings, flavorings, colorants, preservatives, antioxidants, pH adjusters and the like.
The stabilizer is not particularly limited, but phosphates (hexametaphosphoric acid, diphosphoric acid, primary phosphoric acid), alkali metal salts of citric acid (potassium, sodium, etc.), guar gum, xanthan gum, tamarind gum, carrageenan , Stabilizers such as alginate, fercellan, locust bean gum, pectin, curdlan, starch, modified starch, crystalline cellulose, gelatin, dextrin, agar, dextran. These stabilizers can be used alone or in combination of two or more.

上記蛋白質としては、特に限定されないが、例えばα−ラクトアルブミンやβ−ラクトグロブリン、血清アルブミン等のホエイ蛋白質、カゼイン、その他の乳蛋白質、低密度リポ蛋白質、ホスビチン、リベチン、リン糖蛋白質、オボアルブミン、コンアルブミン、オボムコイド等の卵蛋白質、グリアジン、グルテニン、プロラミン、グルテリン等の小麦蛋白質、その他動物性及び植物性蛋白質等の蛋白質が挙げられる。これらの蛋白質は、目的に応じて1種ないし2種以上の蛋白質として、あるいは1種ないし2種以上の蛋白質を含有する食品素材の形で添加しても良い。   The protein is not particularly limited. For example, whey protein such as α-lactalbumin, β-lactoglobulin, serum albumin, casein, other milk proteins, low density lipoprotein, phosvitin, ribetin, phosphoglycoprotein, ovalbumin And egg proteins such as conalbumin and ovomucoid, wheat proteins such as gliadin, glutenin, prolamin and glutelin, and other proteins such as animal and plant proteins. Depending on the purpose, these proteins may be added as one or more proteins or in the form of a food material containing one or more proteins.

上記糖類としては、特に限定されないが、例えばブドウ糖、果糖、ショ糖、麦芽糖、酵素糖化水飴、乳糖、還元澱粉糖化物、異性化液糖、ショ糖結合水飴、オリゴ糖、還元糖ポリデキストロース、ソルビトール、還元乳糖、トレハロース、キシロース、キシリトール、マルチトール、エリスリトール、マンニトール、フラクトオリゴ糖、大豆オリゴ糖、ガラクトオリゴ糖、乳果オリゴ糖、ラフィノース、ラクチュロース、パラチノースオリゴ糖、ステビア、アスパルテーム等の糖類が挙げられる。これらの糖類は、単独で用いることもでき、又は2種以上で用いることもできる。   The saccharide is not particularly limited. For example, glucose, fructose, sucrose, maltose, enzymatic saccharified starch syrup, lactose, reduced starch saccharified product, isomerized liquid sugar, sucrose-conjugated starch syrup, oligosaccharide, reducing sugar polydextrose, sorbitol And sugars such as reduced lactose, trehalose, xylose, xylitol, maltitol, erythritol, mannitol, fructooligosaccharide, soybean oligosaccharide, galactooligosaccharide, dairy oligosaccharide, raffinose, lactulose, palatinose oligosaccharide, stevia and aspartame. These saccharides can be used alone or in combination of two or more.

以下に、実施例を挙げ、本発明をさらに詳しく説明する。
実施例において、油脂の融点は基準油脂分析試験法2.2.4.2−1996にて測定した上昇融点である。
表1に実施例に使用する油脂成分の構成脂肪酸組成の分析例を示す。脂肪酸含有量は基準油脂分析法2.4.2.1−1996にて分析を行った。
Hereinafter, the present invention will be described in more detail with reference to examples.
In Examples, the melting point of fats and oils is the rising melting point measured by the standard fat and oil analysis test method 2.2.4.2-1996.
Table 1 shows an analysis example of the constituent fatty acid composition of the fat and oil component used in the examples. The fatty acid content was analyzed by the standard fat analysis method 2.4.2.1-1996.

Figure 2007244218
Figure 2007244218

製造例1及び4
製造例1及び4は、それぞれハイエルシン菜種油及び菜種油の極度硬化油である。反応器中に原料油を仕込み、水素を1.0kg/cm3の圧力で吹き込みながら、撹拌しつつ150℃まで加熱した。その後、ニッケル触媒0.1〜0.2質量部を反応器内に投入し、190℃で水素を3.0kg/cmの圧力で吹き込みながら、撹拌し水素を添加した。ヨウ素価を基準油脂分析法2.3.4.1−1996にて分析し、その値が1以下になった時点で水素の吹き込み及び撹拌を止め、反応を停止した。その後、油温を100〜120℃に冷却し白土を3質量部加えて濾過した。
Production Examples 1 and 4
Production Examples 1 and 4 are extremely hardened oils of Hyelsin rapeseed oil and rapeseed oil, respectively. Raw material oil was charged into the reactor and heated to 150 ° C. with stirring while blowing hydrogen at a pressure of 1.0 kg / cm 3 . Thereafter, 0.1 to 0.2 parts by mass of a nickel catalyst was charged into the reactor, and hydrogen was added while stirring at 190 ° C. while blowing hydrogen at a pressure of 3.0 kg / cm 3 . The iodine value was analyzed by the standard fat analysis method 2.3.4.1-1996, and when the value became 1 or less, hydrogen blowing and stirring were stopped, and the reaction was stopped. Thereafter, the oil temperature was cooled to 100 to 120 ° C., 3 parts by mass of white clay was added, and the mixture was filtered.

製造例2及び3
製造例2及び3は製造例1及び4と同様にして製造されたハイエルシン菜種油とパーム核油の極度硬化油をエステル交換した油脂である。エステル交換油の反応方法及び条件を以下に示す。反応容器に原料混合油を仕込み、窒素気流中において撹拌しつつ加熱した。100℃〜120℃の状態で3時間以上この状態を保ち、油脂中の水分が100ppm以下になるまで脱水した。その後、油脂を80℃まで冷却し、ナトリウムメチラートを0.1〜0.2質量部加え、撹拌下窒素気流中で30分間反応させた。反応液に70℃の温水を加え撹拌した後、静置して油層と水層を分離する温水洗浄を行った。分離した水層のpHが8以下になるまで温水洗浄を繰り返した後、窒素気流中、撹拌しつつ加熱し、100℃〜120℃で水分が蒸発しなくなるまで脱水した。次いで、活性白土を3質量部加え15分間脱色した後、濾過した。原料混合油及び反応油のトリグリセライド・トータルカーボン組成に基づき、反応率を求め、本製造例では、反応率が95%以上であった。
Production Examples 2 and 3
Production Examples 2 and 3 are fats and oils obtained by transesterifying highly hardened oil of rapeseed rapeseed oil and palm kernel oil produced in the same manner as Production Examples 1 and 4. The reaction method and conditions of the transesterified oil are shown below. The raw material mixed oil was charged into the reaction vessel and heated with stirring in a nitrogen stream. This state was maintained for 3 hours or more in a state of 100 ° C. to 120 ° C., and dehydration was performed until the water content in the fats and oils became 100 ppm or less. Thereafter, the oil and fat was cooled to 80 ° C., 0.1 to 0.2 parts by mass of sodium methylate was added, and the mixture was reacted for 30 minutes in a nitrogen stream with stirring. To the reaction solution, 70 ° C. warm water was added and stirred, and then allowed to stand to perform warm water washing for separating the oil layer and the aqueous layer. Washing with hot water was repeated until the pH of the separated aqueous layer was 8 or less, and then heating was performed in a nitrogen stream while stirring, and dehydration was performed until water no longer evaporated at 100 ° C to 120 ° C. Next, 3 parts by mass of activated clay was added and decolorized for 15 minutes, followed by filtration. The reaction rate was determined based on the triglyceride / total carbon composition of the raw material mixed oil and the reaction oil. In this production example, the reaction rate was 95% or more.

製造例5
製造例5は製造例1及び4と同様にして製造された菜種油の極度硬化油とパーム核油の極度硬化油を製造例2及び3と同様にしてエステル交換した油脂である。
Production Example 5
Production Example 5 is an oil and fat obtained by transesterifying an extremely hardened oil of rapeseed oil and an extremely hardened oil of palm kernel oil produced in the same manner as in Production Examples 1 and 4, as in Production Examples 2 and 3.

製造例6
製造例6は菜種油を製造例1にじて準じて水素添加し、ヨウ素価:73.4となるまで反応を行った。
Production Example 6
In Production Example 6, rapeseed oil was hydrogenated according to Production Example 1, and the reaction was continued until the iodine value was 73.4.

製造例1〜6の油脂の配合及び炭素数8〜12と炭素数20〜24の飽和脂肪酸の含有量を表2に示した。   Table 2 shows the composition of fats and oils of Production Examples 1 to 6 and the content of saturated fatty acids having 8 to 12 carbon atoms and 20 to 24 carbon atoms.

実施例1〜5
上記の製造例1〜3で得られた油脂を用いて、表2の配合に従い、それぞれ混合し、実施例1〜5のホイップクリーム用油脂組成物を製造した。また、実施例1〜5のホイップクリーム用油脂組成物の融点及び炭素数8〜12と炭素数20〜24の飽和脂肪酸の含有量、飽和脂肪酸及びトランス酸の含有量を示した。融点は基準油脂分析法2.2.4.2−1996にて、脂肪酸含有量は上記方法にて、トランス酸含有量はAOCSCe1f−96にて分析を行った。また、実施例1〜5のホイップクリーム用油脂組成物を用いて水中油型乳化液及びホイップクリームを製造し、水中油型乳化液の乳化安定性(振動耐性、温度安定性)及びホイップ性(ホイップ時間、オーバーラン)、ホイップクリームの性能(粘稠性、造花状態、食感)について評価を行い、その結果も表3に示した。
Examples 1-5
Using the fats and oils obtained in the above Production Examples 1 to 3, the oils and fat compositions for whipped cream of Examples 1 to 5 were produced by mixing in accordance with the formulation of Table 2. Moreover, melting | fusing point of the fats and oils composition for whipped cream of Examples 1-5, content of a C8-C12 and C20-C24 saturated fatty acid, content of a saturated fatty acid, and a trans acid were shown. The melting point was analyzed by the standard fat analysis method 2.2.4.2-1996, the fatty acid content was analyzed by the above method, and the trans acid content was analyzed by AOCSCe1f-96. Moreover, the oil-in-water emulsion and the whipped cream were produced using the whipped cream fat composition of Examples 1 to 5, and the emulsion stability (vibration resistance, temperature stability) and whipping property of the oil-in-water emulsion ( Whipping time, overrun) and performance (viscosity, artificial flower state, texture) of whipped cream were evaluated, and the results are also shown in Table 3.

(水中油型乳化液の製造方法)
まず、水49.48質量部を70℃に昇温し、撹拌しながら脱脂粉乳4質量部、ヘキサメタリン酸ナトリウム0.12質量部を溶解させた水相部を調整した。これとは別に、上記の実施例1〜5で得られたホイップクリーム用油脂45質量部に、予めレシチン0.64質量部、ショ糖脂肪酸エステル0.22質量部、モノグリセリン脂肪酸エステル0.18質量部、ポリグリセリン脂肪酸エステル0.11質量部、ソルビタン脂肪酸エステル0.25質量部を溶解させた油相部を調整し、上記の水相部に加え混合撹拌し予備乳化液を調整した。予備乳化後、高圧均質機(三和機械(株)製)を用いて圧力110kg/cmで均質化し、それを冷却した。その後、冷蔵庫で24時間エージングを行った。
(Method for producing oil-in-water emulsion)
First, 49.48 parts by mass of water was heated to 70 ° C., and 4 parts by mass of skim milk powder and 0.12 parts by mass of sodium hexametaphosphate were dissolved while stirring. Separately from this, 45 parts by mass of the fats and oils for whipped cream obtained in the above Examples 1 to 5, 0.66 parts by mass of lecithin, 0.22 parts by mass of sucrose fatty acid ester, 0.18 of monoglycerin fatty acid ester in advance. The oil phase part in which the mass part, 0.11 part by mass of the polyglycerin fatty acid ester and 0.25 part by mass of the sorbitan fatty acid ester were dissolved was prepared, added to the aqueous phase part and mixed and stirred to prepare a preliminary emulsion. After preliminary emulsification, the mixture was homogenized at a pressure of 110 kg / cm 3 using a high-pressure homogenizer (manufactured by Sanwa Kikai Co., Ltd.) and cooled. Thereafter, aging was performed in the refrigerator for 24 hours.

得られた水中油型乳化液の乳化安定性(振動耐性、温度安定性)及びホイップ性(ホイップ時間、オーバーラン)、また、ホイップクリームの性能(粘稠性、造花状態、食感)の評価は下記の方法で行った。   Evaluation of emulsification stability (vibration resistance, temperature stability) and whipping properties (whipping time, overrun) of the obtained oil-in-water emulsion, and whipped cream performance (viscosity, artificial state, texture) Was carried out by the following method.

(評価方法)
(1)振動耐性
振動機を用い、容器に入れた水中油型乳化液を7℃の状態で180回/分の速さで水平方向に3時間振動させ、粘度計(BROOKFIELD社製)を用いて水中油型乳化液の粘度を測定し評価した。
◎:振動後の水中油型乳化液の粘度が500cp未満、
○:振動後の水中油型乳化液の粘度が500cp以上1000cp未満、
△:振動後の水中油型乳化液の粘度が1000cp以上、
×:振動後の水中油型乳化液が固化。
(2)温度安定性(ヒートショック試験):
冷蔵庫で24時間エージングを行った水中油型乳化液を30℃の恒温槽に7時間静置し、粘度計(BROOKFIELD社製)を用いて水中油型乳化液の粘度を測定し評価した。
◎:ヒートショック後の水中油型乳化液の粘度が500cp未満
○:ヒートショック後の水中油型乳化液の粘度が500cp以上1000cp未満
△:ヒートショック後の水中油型乳化液の粘度が1000cp以上
×:ヒートショック後の水中油型乳化液が固化
(3)ホイップ時間:水中油型乳化液600g及び砂糖60gを容器に仕込み、ホイッパーを装着したホバートミキサー(関東混合機社製)を用いて2速でホイップした。そして、下記で測定されるオーバーランが最大の値を示すのに要した時間を求め評価した。
◎:開始〜12分未満、○:12分以上、
△:最大オーバーラン状態が認められないが、ホイップは可能、
×:ホイップ不可能
(3)オーバーラン
ホイップ開始時より6分までは2分毎に、6分以降は1分毎にホイップクリームをサンプリングし、下記の式により増加体積割合を算出した。そして、その最大値を下記の4段階で評価した。
〔(一定容積の水中油型乳化液の重量−同容積のホイップ後のクリーム重量)/(同容積のホイップ後のクリーム重量)〕×100(%)
◎:150以上、○:100以上150未満、
△:100未満、×:ホイップ不可能。
(4)粘稠性:レオメーター(サン科学社製CR−200D、圧縮弾性アダプター使用、25℃において直径2cmのプランジャーで1cm押した時の応力値(g)を測定)により、オーバーランが最大値を示した時点のホイップクリームの粘稠度合を測定し評価した。
◎:30g以上 ○:20g以上30以下 △:10g以上20g未満 ×:10g未満
(5)造花状態:ホイップ後のクリームについて絞り袋を使用して造花したときの絞り易い、造花物の形状、キメの状態等を総合評価した。
◎:最良・・・絞り易い。造花物がきれい。キメが良好
○:良好・・・絞り易い。造花物がややダレている。気泡少し壊れている。
△:不良・・・絞りにくい。造花物がダレている。気泡が壊れている。
×:不良・・・絞りにくい。造花物がアレている。
(6)食感:口に含んだときに感じる油っぽさ、口溶け、爽快さ等の口当たりを評価した。
◎:最良、○:良好、△:やや良好、×:不良
(Evaluation methods)
(1) Vibration resistance Using a vibrator, the oil-in-water emulsion in a container is vibrated in the horizontal direction at a speed of 180 times / minute for 3 hours at 7 ° C., and a viscometer (manufactured by BROOKFIELD) is used. The viscosity of the oil-in-water emulsion was measured and evaluated.
A: The viscosity of the oil-in-water emulsion after vibration is less than 500 cp,
○: The viscosity of the oil-in-water emulsion after vibration is 500 cp or more and less than 1000 cp,
(Triangle | delta): The viscosity of the oil-in-water emulsion after vibration is 1000 cp or more,
X: Oil-in-water emulsion after vibration solidifies.
(2) Temperature stability (heat shock test):
The oil-in-water emulsion that was aged for 24 hours in a refrigerator was allowed to stand in a thermostatic bath at 30 ° C. for 7 hours, and the viscosity of the oil-in-water emulsion was measured and evaluated using a viscometer (manufactured by BROOKFIELD).
A: Viscosity of oil-in-water emulsion after heat shock is less than 500 cp B: Viscosity of oil-in-water emulsion after heat shock is 500 cp or more and less than 1000 cp Δ: Viscosity of oil-in-water emulsion after heat shock is 1000 cp or more X: Oil-in-water emulsion after heat shock solidifies (3) Whip time: 2 using a Hobart mixer (manufactured by Kanto Mixer Co., Ltd.) equipped with 600 g of oil-in-water emulsion and 60 g of sugar in a container and equipped with a whipper Whip at speed. Then, the time required for the overrun measured below to show the maximum value was obtained and evaluated.
◎: Start ~ less than 12 minutes, ○: 12 minutes or more,
△: Maximum overrun condition is not recognized, but whip is possible,
X: Whipping impossible (3) Overrun The whipped cream was sampled every 2 minutes up to 6 minutes from the start of whipping, and every minute after 6 minutes, and the increased volume ratio was calculated by the following formula. And the maximum value was evaluated in the following four steps.
[(Weight of a fixed volume of oil-in-water emulsion−weight of cream after whipping of the same volume) / (weight of cream after whipping of the same volume)] × 100 (%)
A: 150 or more, B: 100 or more and less than 150,
(Triangle | delta): Less than 100, x: Whip impossible.
(4) Viscosity: Rheometer (CR-200D manufactured by Sun Scientific Co., Ltd., using a compression elastic adapter, measuring the stress value (g) when pressed with a plunger with a diameter of 2 cm at 25 ° C.) The consistency of the whipped cream at the time when the maximum value was shown was measured and evaluated.
◎: 30 g or more ○: 20 g or more and 30 or less △: 10 g or more and less than 20 g ×: Less than 10 g (5) Artificial state: The shape and texture of an artificial flower that is easy to squeeze when whipped cream is made using a squeezed bag. A comprehensive evaluation of the state of
A: Best ... Easy to squeeze. Artificial flowers are beautiful. Good texture: Good: Easy to squeeze. Artificial flowers are slightly sagging. Bubbles are a bit broken.
Δ: Defect: difficult to squeeze. Artificial flowers are dripping. Bubbles are broken.
X: Defect ... It is difficult to squeeze. There are artificial flowers.
(6) Texture: The mouthfeel, such as oiliness, melting in the mouth, refreshingness, etc. felt when put in the mouth was evaluated.
A: Best, B: Good, B: Slightly good, X: Bad

比較例1〜7
上記の製造例1〜6で得られた各油脂を用いて、表4の配合に従い、それぞれを混合し、比較例1〜7のホイップクリーム用油脂組成物を製造した。また、それらの融点及び炭素数8〜12と炭素数20〜24の飽和脂肪酸の含有量、飽和脂肪酸、トランス酸の含有量を上記の方法により測定し、その結果を示した。また、比較例1〜7のホイップクリーム用油脂組成物を用いて水中油型乳化液及びホイップクリームを上記の方法により製造し、水中油型乳化液の乳化安定性(振動耐性、温度安定性)及びホイップ性(ホイップ時間、オーバーラン)、ホイップクリームの性能(粘稠性、造花状態、食感)について上記の方法により評価を行い、その結果も表3に示した。
Comparative Examples 1-7
Using each of the oils and fats obtained in Production Examples 1 to 6, the oils and fat compositions for whipped cream of Comparative Examples 1 to 7 were produced in accordance with the formulations shown in Table 4 and mixed. Moreover, those melting | fusing point and the content of C8-C12 and C20-C24 saturated fatty acid, saturated fatty acid, and trans acid were measured by said method, and the result was shown. Moreover, the oil-in-water emulsion and the whipped cream were produced by the above-described method using the whipped cream fat composition of Comparative Examples 1 to 7, and the emulsion stability (vibration resistance, temperature stability) of the oil-in-water emulsion was prepared. The whipping properties (whipping time, overrun) and the performance of the whipped cream (viscosity, artificial flower state, texture) were evaluated by the above methods. The results are also shown in Table 3.

Figure 2007244218
Figure 2007244218

Figure 2007244218
Figure 2007244218

Figure 2007244218
Figure 2007244218

比較例1はA成分の構成脂肪酸中の炭素数20〜24の飽和脂肪酸の含有量が少なく、融点が低い例、比較例2はA成分の構成脂肪酸中の炭素数20〜24の飽和脂肪酸の含有量が少ない例、比較例3は油脂組成物の構成脂肪酸中の飽和脂肪酸の含有量が多い例、比較例4はA成分が少ない例、比較例5は融点が高い例、及び比較例6は融点が低い例であるが、いずれも実施例と同等のホイップクリーム用油脂としての性能は得られなかった。なお、比較例7はトランス酸を大量に含む場合の例である。   Comparative Example 1 is an example in which the content of saturated fatty acids having 20 to 24 carbon atoms in the constituent fatty acids of the A component is low and the melting point is low, and Comparative Example 2 is that of saturated fatty acids having 20 to 24 carbon atoms in the constituent fatty acids of the A component. An example with a low content, Comparative Example 3 is an example with a high content of saturated fatty acids in the constituent fatty acids of the oil and fat composition, Comparative Example 4 is an example with a low A component, Comparative Example 5 is an example with a high melting point, and Comparative Example 6 Is an example with a low melting point, but none of the performances as fats and oils for whipped cream equivalent to those in Examples were obtained. Comparative Example 7 is an example in the case of containing a large amount of trans acid.

Claims (3)

A成分として構成脂肪酸に炭素数20〜24の飽和脂肪酸を5〜60質量%含む極度硬化油脂5〜50質量部、及びB成分として液状油脂50〜95質量部からなるホイップクリーム用油脂組成物であって、油脂組成物の融点が35〜50℃であり、油脂組成物の構成脂肪酸に飽和脂肪酸を10〜60質量%含むホイップクリーム用油脂組成物。   An oil / fat composition for whipped cream comprising 5 to 50 parts by mass of an extremely hardened fat and oil containing 5 to 60% by mass of a saturated fatty acid having 20 to 24 carbon atoms as a constituent fatty acid, and 50 to 95 parts by mass of a liquid fat and oil as a B component. And the melting | fusing point of an oil-fat composition is 35-50 degreeC, The oil-fat composition for whipped cream which contains 10-60 mass% of saturated fatty acids in the constituent fatty acid of an oil-fat composition. A成分が構成脂肪酸中に炭素数12の飽和脂肪酸を2〜50質量%含む極度硬化油である第1の発明のホイップクリーム用油脂組成物。   The fat and oil composition for whipped cream according to the first invention, wherein the component A is an extremely hardened oil containing 2 to 50% by mass of a saturated fatty acid having 12 carbon atoms in the constituent fatty acid. 請求項1又は2に記載のホイップクリーム用油脂組成物を原料とするホイップクリーム。   The whipped cream which uses as a raw material the oil-fat composition for whipped creams of Claim 1 or 2.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009219391A (en) * 2008-03-14 2009-10-01 Ueda Oils & Fats Mfg Co Ltd Oil and fat composition for whipped cream
JP2009284869A (en) * 2008-05-30 2009-12-10 Taiyo Yushi Kk Oil-in-water emulsified oil-and-fat composition for whipped-cream
JP2010081930A (en) * 2008-09-05 2010-04-15 Taiyo Yushi Kk Oil and fat composition for whipped cream
JP2010115161A (en) * 2008-11-13 2010-05-27 Taiyo Yushi Kk Oil-and-fat composition for cream

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009219391A (en) * 2008-03-14 2009-10-01 Ueda Oils & Fats Mfg Co Ltd Oil and fat composition for whipped cream
JP4612702B2 (en) * 2008-03-14 2011-01-12 植田製油株式会社 Oil composition for foaming cream
JP2009284869A (en) * 2008-05-30 2009-12-10 Taiyo Yushi Kk Oil-in-water emulsified oil-and-fat composition for whipped-cream
JP2010081930A (en) * 2008-09-05 2010-04-15 Taiyo Yushi Kk Oil and fat composition for whipped cream
JP2010115161A (en) * 2008-11-13 2010-05-27 Taiyo Yushi Kk Oil-and-fat composition for cream

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