JP2007217848A - Press felt for papermaking - Google Patents

Press felt for papermaking Download PDF

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JP2007217848A
JP2007217848A JP2006066678A JP2006066678A JP2007217848A JP 2007217848 A JP2007217848 A JP 2007217848A JP 2006066678 A JP2006066678 A JP 2006066678A JP 2006066678 A JP2006066678 A JP 2006066678A JP 2007217848 A JP2007217848 A JP 2007217848A
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Prior art keywords
layer
wet paper
core
press
nylon
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JP4157136B2 (en
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Akira Onikubo
明 鬼久保
Shin Kawashima
伸 川島
Hiroyuki Oda
浩之 小田
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Ichikawa Co Ltd
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Ichikawa Co Ltd
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Priority to JP2006066678A priority Critical patent/JP4157136B2/en
Application filed by Ichikawa Co Ltd filed Critical Ichikawa Co Ltd
Priority to CA002642541A priority patent/CA2642541A1/en
Priority to US12/223,834 priority patent/US20100163202A1/en
Priority to AU2007216016A priority patent/AU2007216016A1/en
Priority to EP07708116A priority patent/EP1985752A4/en
Priority to CNA2007800050653A priority patent/CN101384770A/en
Priority to BRPI0707822-6A priority patent/BRPI0707822A2/en
Priority to PCT/JP2007/052067 priority patent/WO2007094207A1/en
Priority to KR1020087015589A priority patent/KR20080100418A/en
Priority to TW096105376A priority patent/TW200736462A/en
Publication of JP2007217848A publication Critical patent/JP2007217848A/en
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F7/00Other details of machines for making continuous webs of paper
    • D21F7/08Felts
    • D21F7/083Multi-layer felts
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F7/00Other details of machines for making continuous webs of paper
    • D21F7/08Felts
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F7/00Other details of machines for making continuous webs of paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21GCALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
    • D21G9/00Other accessories for paper-making machines
    • D21G9/0009Paper-making control systems

Abstract

<P>PROBLEM TO BE SOLVED: To provide a felt for papermaking having high compressibility and exhibiting excellent stain-proofing property. <P>SOLUTION: The felt for papermaking is equipped with a first bat layer formed on the surface of wet paper side of a base layer, a second bat layer formed on the surface of press side and a wet paper contact fiber layer formed on the surface of wet paper side of the first bad layer, and the wet paper contact fiber layer comprises a core-sheath conjugate fiber consisting of a core component having ≥80 mPa s absolute viscosity and composed of a high molecular weight nylon and a sheath component composed of a nylon having a melting point lower than that of the core component. Since the first bat layer is composed of a layer of nylon not containing the core-sheath conjugate fiber, the press felt has smoothness, resistance to hair loss/abrasion property, resistance to compressive fatigue and water-squeezing property in good balance. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、抄紙機械に使用される抄紙用プレスフェルト(以下、単に「プレスフェルト」という。)に関する。  The present invention relates to a papermaking press felt (hereinafter simply referred to as “press felt”) used in a papermaking machine.

従来から、製紙工程において、湿紙から搾水するため、プレス装置が使用されている。プレス装置において、紙層形成が行われた湿紙は、プレスニップでプレスフェルトを介して搾水される。なお、一般的に、プレス装置は、複数のプレスニップから構成される。  Conventionally, a press apparatus has been used in order to squeeze water from wet paper in a papermaking process. In the press apparatus, the wet paper on which the paper layer has been formed is squeezed through a press felt at the press nip. In general, a press apparatus is composed of a plurality of press nips.

図5は、プレス装置におけるプレスニップの概略図である。
このプレスニップは、一対のプレスロールP’,P’と、湿紙W’を挟持する一対のプレスフェルト11’,11’からなり、プレスロールP’,P’の加圧部において、プレスフェルト11’,11’と湿紙W’に圧力を加えて、湿紙W’から水分が搾り出されて、プレスフェルト11’,11’に吸収される。
FIG. 5 is a schematic view of a press nip in the press apparatus.
The press nip is composed of a pair of press rolls P ′ and P ′ and a pair of press felts 11 ′ and 11 ′ that sandwich the wet paper web W ′. A pressure is applied to 11 ′, 11 ′ and the wet paper W ′, and water is squeezed out of the wet paper W ′ and absorbed by the press felts 11 ′, 11 ′.

しかし、加圧部の中央(ニップ部)から出口にかけて、湿紙W’とプレスフェルト11’,11’に掛けられた圧力が急激に解放されるため、この部分において、プレスフェルト11’,11’の体積が急激に膨張する。その結果、プレスフェルト11’,11’に負圧が生じ、さらに、湿紙W’が細繊維からなるため毛細管現象も加わって、プレスフェルト11’,11’に吸収されていた水分が、再び湿紙側へ移行する現象、すなわち、再湿現象(re−wetting)が起きる。  However, since the pressure applied to the wet paper web W ′ and the press felts 11 ′ and 11 ′ is suddenly released from the center (nip part) of the pressurizing part to the outlet, the press felts 11 ′ and 11 are in this part. The volume of 'expands rapidly. As a result, a negative pressure is generated in the press felts 11 ′ and 11 ′, and further, since the wet paper W ′ is made of fine fibers, a capillary phenomenon is also added, so that the moisture absorbed in the press felts 11 ′ and 11 ′ is again obtained. A phenomenon of shifting to the wet paper side, that is, a re-wetting phenomenon occurs.

この再湿現象を防止するためのフェルトとして、例えば、特許文献1に開示されているプレスフェルトがある。これは、基層、湿紙側バット層、プレス側バット層からなるフェルトにおいて、湿紙側バット層中に親水性不織布が配置されたもので、この親水性不織布の親水作用によって、親水性不織布への水分移行作用、移行された水分の保持作用が発揮されるため、再湿現象を効果的に抑制することができるとされている。  As a felt for preventing this rewetting phenomenon, for example, there is a press felt disclosed in Patent Document 1. This is a felt composed of a base layer, a wet web side batt layer, and a press side batt layer, in which a hydrophilic nonwoven fabric is arranged in the wet paper side batt layer, and the hydrophilic action of this hydrophilic nonwoven fabric results in a hydrophilic nonwoven fabric. It is said that the re-wetting phenomenon can be effectively suppressed because the water transfer action and the retention action of the transferred water are exhibited.

また、抄紙用プレスフェルトでは、湿紙から水を搾る機能(搾水性)を維持するために、加圧により圧縮されたフェルトを除圧時に偏平化することなく回復させる機能(耐圧縮疲労性)や、フェルトが平滑になることにより湿紙平滑性を高める機能(平滑性)及び耐脱毛・摩耗性等も重要視されている。
このような機能を具えたフェルトとして、例えば、2成分材料よりなる芯鞘構造を有する繊維を含むプレスフェルトが特許文献2に開示されている。
このプレスフェルトでは、バット層の繊維として、低融点の鞘材料と高融点の芯材料からなる2成分材料が用いられ、プレスフェルトの加熱硬化処理により低融点の鞘材料が軟化してバット層内にマトリックスが形成されることにより、プレスフェルトの脱排水性能を向上させ、しかも、圧縮抵抗力を増強させることができるとされている。
さらに、最近の高速抄紙機械に対応するため、搾水性と平滑性に優れた織布が使用されたプレスフェルトが使われている。この織布は整経糸(フェルトのCMD方向糸)と打ち込み糸(同じくMD方向糸)とが、共にモノフィラメント単糸で織成されている(特許文献3を参照)。
In addition, in press felt for papermaking, to maintain the function of squeezing water from wet paper (water squeezing), the function of recovering felt compressed without pressure flattening during compression (compression fatigue resistance) In addition, the function (smoothness) of improving wet paper smoothness by smoothing the felt, hair removal resistance, wear resistance, and the like are also regarded as important.
As a felt having such a function, for example, a press felt including a fiber having a core-sheath structure made of a two-component material is disclosed in Patent Document 2.
In this press felt, a two-component material comprising a sheath material having a low melting point and a core material having a high melting point is used as a fiber for the bat layer, and the sheath material having a low melting point is softened by heat curing treatment of the press felt. It is said that by forming a matrix, it is possible to improve the dewatering performance of the press felt and to enhance the compression resistance.
Furthermore, press felt using a woven fabric excellent in water squeezing and smoothness is used to support recent high-speed paper machines. In this woven fabric, warp yarn (felt CMD direction yarn) and driving yarn (also MD direction yarn) are both woven with a monofilament single yarn (see Patent Document 3).

特開2004−143627号公報JP 2004-143627 A 特開平8−302584号公報Japanese Patent Laid-Open No. 8-302584 特開2000−170086号公報Japanese Patent Laid-Open No. 2000-170086

しかしながら、特許文献1及び2のプレスフェルトは、プレス装置による繰返しの圧縮疲労を受け易いという問題がある。
また、特許文献2のプレスフェルトのように2成分材料をバット層に用いる場合、フェルト製造時の熱プレスの影響により、芯材料の機械的強度の低下や化学的劣化が起こり、その結果、プレスフェルトの使用中に繊維が切断されたり、脱毛・摩耗が進み、早期に交換を必要とすることが多かった。
また特許文献3のプレスフェルトでは、従来の撚糸を使用したフェルトに比べてニードルパンチングによるバット繊維と織布との固着性が悪くなるため、フェルトの脱毛・摩耗性が著しく悪いことが知られている。
従って、再湿現象を抑制すると同時に、耐圧縮疲労性、平滑性、耐脱毛・摩耗性及び搾水性等の機能をバランス良く具備したプレスフェルトが望まれる。
However, the press felts of Patent Documents 1 and 2 have a problem that they are easily subjected to repeated compression fatigue by a press device.
In addition, when a two-component material is used for the batt layer as in the press felt of Patent Document 2, the mechanical strength of the core material is reduced or chemically deteriorated due to the influence of the hot press during the manufacture of the felt. During the use of the felt, the fiber was cut, hair removal and wear progressed, and replacement was often required at an early stage.
Further, in the press felt of Patent Document 3, it is known that the felt hair removal / wearing property is remarkably poor because the sticking property between the bat fiber and the woven fabric by needle punching is worse than the felt using the conventional twisted yarn. Yes.
Accordingly, a press felt that suppresses the rewetting phenomenon and at the same time has a good balance of functions such as compression fatigue resistance, smoothness, hair removal / wear resistance, and water squeezability.

本発明は、上記問題に鑑み、再湿現象を抑制するとともに、平滑性・耐摩耗性・耐圧縮疲労性、及び搾水性に優れた抄紙用プレスフェルトを提供することを目的とする。  In view of the above problems, an object of the present invention is to provide a press felt for papermaking that suppresses the rewetting phenomenon and is excellent in smoothness, wear resistance, compression fatigue resistance, and water squeezability.

本発明は、基層と、基層の湿紙側の表面に形成された第1バット層と、プレス側の表面に形成された第2バット層と、前記第1バット層の湿紙側の表面に形成された湿紙接触繊維層とを備え、前記湿紙接触繊維層が絶対粘度が80mPa・s以上である高分子量ナイロンからなる芯成分と、該芯成分よりも低融点のナイロンからなる鞘成分とから構成される芯鞘複合繊維を含み、前記第1バット層が、前記芯鞘複合繊維を含まないナイロンの層からなることを特徴とする抄紙用プレスフェルトにより、前記課題を解決した。
ここで、絶対粘度が80mPa・s以上とは、ナイロンを0.5g/95%硫酸100mlで溶解し、25℃の温度で測定した絶対粘度であって、振動式粘度計で測定することができる。
前記湿紙接触繊維層における前記芯鞘複合繊維の含有率は、25%〜75%であることが好ましい。
また、前記湿紙接触繊維層を多層構造にし、前記湿紙接触繊維層のプレス側から湿紙側に向かって、前記芯鞘複合繊維の含有量を段階的に増加させてもよい。そして、前記基層は、整経糸(フェルトのCMD方向糸)と打ち込み糸(同じくMD方向糸)とが、共にモノフィラメント単糸で織成されている織布であることが好ましい。
The present invention provides a base layer, a first butt layer formed on the surface of the base layer on the wet paper side, a second butt layer formed on the surface on the press side, and a surface of the first butt layer on the wet paper side. A core component made of high molecular weight nylon having an absolute viscosity of 80 mPa · s or more, and a sheath component made of nylon having a melting point lower than that of the core component. The above-mentioned problems have been solved by a press felt for papermaking, wherein the first batt layer is made of a layer of nylon that does not contain the core-sheath composite fiber.
Here, the absolute viscosity of 80 mPa · s or more is an absolute viscosity measured at a temperature of 25 ° C. by dissolving nylon with 100 ml of 0.5 g / 95% sulfuric acid, and can be measured with a vibration viscometer. .
The content of the core-sheath composite fiber in the wet paper contact fiber layer is preferably 25% to 75%.
The wet paper web contact fiber layer may have a multilayer structure, and the content of the core-sheath composite fiber may be increased stepwise from the press side of the wet paper web contact fiber layer toward the wet paper web. The base layer is preferably a woven fabric in which warp yarn (felt CMD direction yarn) and driving yarn (also MD direction yarn) are both woven with a monofilament single yarn.

本発明によれば、芯鞘複合繊維の鞘成分が溶融して湿紙接触繊維層が緻密になる。その結果、プレス側層の水分は、前記湿紙接触繊維層がバリアとなって湿紙側に移動しにくくなるため、再湿現象を抑制することができる。
また、前記芯鞘複合繊維の芯成分を高粘度にすること、すなわち高分子量ナイロンを使用することで、フェルトの耐脱毛・摩耗性及び耐圧縮疲労性が向上し、その結果、フェルトの寿命(ライフ)が延びてフェルト交換回数が減る、脱毛・摩耗による抜け毛が湿紙に付着することが少なくなり製紙品質が改善する、湿紙接触面の平滑性が維持される等の効果を奏する。
さらに、湿紙接触繊維層を芯鞘複合繊維で構成し、基層の湿紙側の表面に形成された第1バット層を芯鞘複合繊維を含まないナイロンの層で構成したことにより、平滑性、耐脱毛・摩耗性、耐圧縮疲労性、および搾水性がバランスよく具備される。
さらに、モノフィラメント単糸で織成された織布を基層に使用することにより、織布の通水性が改善されるため、搾水性に優れたフェルトを構成できる。
According to the present invention, the sheath component of the core-sheath composite fiber melts, and the wet paper web contact fiber layer becomes dense. As a result, the moisture in the press side layer becomes difficult to move to the wet paper web side because the wet paper web contact fiber layer serves as a barrier, so that the rewetting phenomenon can be suppressed.
Further, by making the core component of the core-sheath composite fiber highly viscous, that is, by using high molecular weight nylon, the hair removal / wear resistance and compression fatigue resistance of the felt are improved. As a result, the life of the felt ( Life) is extended, the number of felt exchanges is reduced, hair loss due to hair removal and wear is less likely to adhere to the wet paper, improving the papermaking quality, and maintaining the smoothness of the wet paper contact surface.
Further, the wet paper web contact fiber layer is composed of a core-sheath composite fiber, and the first bat layer formed on the surface of the base layer on the wet paper web side is composed of a nylon layer that does not contain the core-sheath composite fiber. The hair removal / wear resistance, compression fatigue resistance, and water squeezing resistance are well-balanced.
Furthermore, since the water permeability of the woven fabric is improved by using a woven fabric woven with monofilament single yarn as the base layer, a felt excellent in water squeezing can be configured.

以下、本発明の抄紙用プレスフェルトについて詳しく説明する。
図1は本発明によるプレスフェルト10のCMD方向の断面図である。
なお、「機械方向(MD)」は、抄紙機がプレスフェルトを移動させる経方向であり、「機械横断方向(CMD)」は、抄紙機がプレスフェルトを移動させる方向を横切る緯方向である。
図1に示すように、プレスフェルト10は、基層30と、基層の湿紙側の表面に形成された第1バット層22と、プレス側の表面に形成された第2バット層23とを具え、前記第1バット層の湿紙側の表面に配された湿紙接触側バット層21とからなる。
基層の湿紙側の表面に形成された第1バット層22と、プレス側の表面に形成された第2バット層23は、ステープルファイバーから構成され、ニードルパンチングによりそれぞれ基層30の湿紙側及びプレス側に絡合一体化され、更に湿紙接触側バット層21は、第1バット層22にニードルパンチングにより絡合一体化されている。
The papermaking press felt of the present invention will be described in detail below.
FIG. 1 is a sectional view in the CMD direction of a press felt 10 according to the present invention.
The “machine direction (MD)” is the warp direction in which the paper machine moves the press felt, and the “machine crossing direction (CMD)” is the weft direction across the direction in which the paper machine moves the press felt.
As shown in FIG. 1, the press felt 10 includes a base layer 30, a first butt layer 22 formed on the surface of the base layer on the wet paper web, and a second butt layer 23 formed on the surface on the press side. The wet paper web side batt layer 21 disposed on the wet paper side surface of the first batt layer.
The first butt layer 22 formed on the surface of the base layer on the wet paper side and the second bat layer 23 formed on the surface of the press side are composed of staple fibers, and are respectively formed on the wet paper side of the base layer 30 by needle punching. The wet web contact side batt layer 21 is intertwined and integrated with the first batt layer 22 by needle punching.

本発明のプレスフェルト10は、湿紙接触側バット層21が、温度25℃での絶対粘度が80mPa・s以上である高分子量ナイロンからなる芯成分と、この芯成分よりも低融点のナイロンからなる鞘成分とから構成される芯鞘複合繊維41のステープルファイバーを含み、基層の湿紙側の表面に形成された第1バット層22は、芯鞘複合繊維41を含まない従来のナイロン繊維42のステープルファイバーで構成される。
ここで、温度25℃での絶対粘度が80mPa・s以上とは、ナイロンを0.5g/95%硫酸100mlで溶解し、25℃の温度で測定した絶対粘度であり、これは振動式粘度計で測定することができる。
なお、図1では、便宜上、芯鞘複合繊維41が誇張して示されている。
In the press felt 10 of the present invention, the wet paper web side batt layer 21 is made of a core component made of high molecular weight nylon having an absolute viscosity of 80 mPa · s or more at a temperature of 25 ° C., and nylon having a melting point lower than that of the core component. The first batt layer 22 formed on the surface of the base layer on the wet paper web side includes the staple fiber of the core-sheath composite fiber 41 composed of the sheath component, and the conventional nylon fiber 42 not including the core-sheath composite fiber 41. Composed of staple fiber.
Here, the absolute viscosity at a temperature of 25 ° C. of 80 mPa · s or more is an absolute viscosity measured at a temperature of 25 ° C. by dissolving nylon with 100 ml of 0.5 g / 95% sulfuric acid. Can be measured.
In FIG. 1, the core-sheath composite fiber 41 is exaggerated for convenience.

従来、2成分材料よりなる芯鞘構造を有する繊維をプレスフェルトのバット層に用いる場合、芯成分の粘度、すなわち、分子量については考慮されていなかった。本発明では、芯成分を従来よりも高粘度、すなわち、高分子量ナイロンを使用し、且つ、この芯鞘複合繊維からなる層を、基層の湿紙側の表面に形成された第1バット層の表面上に配置することにより、平滑性、耐脱毛・摩耗性、耐圧縮疲労性がバランスよく具備される。  Conventionally, when a fiber having a core-sheath structure made of a two-component material is used for a butt layer of a press felt, the viscosity of the core component, that is, the molecular weight has not been considered. In the present invention, the core component has a higher viscosity than before, that is, high molecular weight nylon is used, and the layer made of the core-sheath composite fiber is formed on the surface of the base layer on the wet paper side of the first bat layer. By arranging on the surface, smoothness, hair removal / wear resistance, and compression fatigue resistance are provided in a well-balanced manner.

芯鞘複合繊維41の芯成分に用いられるナイロンは、温度25℃での絶対粘度が80mPa・s以上の高分子量ナイロンであり、且つ、鞘成分よりも融点の高いものが用いられる。芯成分のナイロンを高粘度(80mPa・s以上)にすることにより、フェルトの耐脱毛・摩耗性及び耐圧縮疲労性が向上する。これは高分子量ナイロンでは分子鎖が長くなるから、分子鎖同士の絡み合い効果による機械的特性(強度や摩擦・摩耗などの耐久性)が向上するためであると考えられる。絶対粘度が80mPa・s未満(中粘度)のナイロンを用いた場合、耐脱毛・摩耗性及び耐圧縮疲労性の効果が十分に得られない。  The nylon used for the core component of the core-sheath composite fiber 41 is a high molecular weight nylon having an absolute viscosity of 80 mPa · s or higher at a temperature of 25 ° C., and has a higher melting point than the sheath component. By making the core component nylon have a high viscosity (80 mPa · s or more), the hair removal / wear resistance and compression fatigue resistance of the felt are improved. This is presumably because the molecular weight of the high molecular weight nylon becomes longer, so that mechanical properties (strength, durability such as friction and wear) due to the entanglement effect between the molecular chains are improved. When nylon having an absolute viscosity of less than 80 mPa · s (medium viscosity) is used, the effect of hair removal / wear resistance and compression fatigue resistance cannot be sufficiently obtained.

芯成分に好ましく用いられるナイロンとしては、高分子量ナイロン6、高分子量ナイロン66、高分子量ナイロン46、高分子量ナイロン610、高分子量ナイロン612等であることが好ましい。詳しくはεカプロラクタムの重合(ナイロン6)や、ヘキサメチレンジアミン・アジピン酸塩の重縮合(ナイロン66)、1,4−ジアミノブタン・アジピン酸塩の重縮合(ナイロン46)、ヘキサメチレンジアミン・セバシン酸塩の重縮合(ナイロン610)、ヘキサメチレンジアミン・ドデカン二酸塩の重縮合(ナイロン612)等、ナイロン塩の重縮合により得られたナイロンが好ましく、しかもDSC(示差走査熱分析計)による融点が200℃以上である脂肪族ナイロンを挙げることができる。これらの高分子ナイロンの0.5g/95%硫酸100mlでの絶対粘度は、80mPa・s以上であることが好ましい。なお、これらの高分子量ナイロンは公知の重合方法、或いは一旦重合したナイロンフレークを、酸素を含まない120〜200℃の不活性ガス雰囲気内に置いて、固相重合する方法(例えば、特表2002−529604号)により製造されたものが用いられる。  Nylon preferably used for the core component is preferably high molecular weight nylon 6, high molecular weight nylon 66, high molecular weight nylon 46, high molecular weight nylon 610, high molecular weight nylon 612, or the like. Specifically, polymerization of ε-caprolactam (nylon 6), polycondensation of hexamethylenediamine and adipate (nylon 66), polycondensation of 1,4-diaminobutane and adipate (nylon 46), hexamethylenediamine and sebacine Nylon obtained by polycondensation of a nylon salt, such as polycondensation of an acid salt (nylon 610) or polycondensation of hexamethylenediamine / dodecanedioate (nylon 612), is preferred, and by DSC (differential scanning calorimetry) Mention may be made of aliphatic nylons having a melting point of 200 ° C. or higher. The absolute viscosity of these polymer nylons at 100 ml of 0.5 g / 95% sulfuric acid is preferably 80 mPa · s or more. These high molecular weight nylons are known polymerization methods, or a method of solid-phase polymerization in which nylon flakes once polymerized are placed in an inert gas atmosphere containing no oxygen and at 120 to 200 ° C. (for example, Special Table 2002). No. -529604) is used.

芯鞘複合繊維41の鞘成分に用いられるナイロンは、芯成分よりも低融点のナイロンが用いられる。鞘成分に好ましく用いられるナイロンとしては、ナイロン6/12、ナイロン6/610、ナイロン66/6、ナイロン66/12、ナイロン66/610等の二元共重合ナイロン、ナイロン6/66/12、ナイロン6/66/610等の三元共重合ナイロンを挙げることができる。なお、これらの共重合ナイロンは組成(共重合成分の重量%)により融点が変動することは良く知られる処であるが、本発明で使用できる共重合ナイロンは、その融点が180℃以下のものに限られる。  The nylon used for the sheath component of the core-sheath composite fiber 41 is nylon having a lower melting point than that of the core component. As nylons preferably used for the sheath component, binary copolymer nylons such as nylon 6/12, nylon 6/610, nylon 66/6, nylon 66/12, nylon 66/610, nylon 6/66/12, nylon Mention may be made of terpolymer nylons such as 6/66/610. It is well known that the melting point of these copolymer nylons varies depending on the composition (% by weight of the copolymer component), but the copolymer nylon that can be used in the present invention has a melting point of 180 ° C. or less. Limited to.

プレスフェルトの製造工程の熱プレスの際に鞘成分が溶融することにより、芯鞘複合繊維41の繊維収縮が起こり、それに伴って湿紙接触側バット層21が緻密になり、フェルト表面の平滑性が向上する。
湿紙接触側バット層21が緻密になると、プレスフェルト10がニップ加圧下を脱してゆく際に、基層と、基層の湿紙側の表面に形成された第1バット層と、プレス側の表面に形成された第2バット層にある水分が、緻密層がバリアとなって移動しにくくなり、再湿現象が効果的に抑制される。
When the sheath component melts during the hot pressing in the press felt manufacturing process, fiber shrinkage of the core-sheath composite fiber 41 occurs, and accordingly, the wet paper web side batt layer 21 becomes dense, and the felt surface is smooth. Will improve.
When the wet paper web side batt layer 21 becomes dense, when the press felt 10 is removed from the nip under pressure, the base layer, the first batt layer formed on the wet paper side surface of the base layer, and the press side surface Moisture in the second bat layer formed in this manner becomes difficult to move due to the dense layer as a barrier, and the rewetting phenomenon is effectively suppressed.

本発明では、基層の湿紙側の表面に形成された第1バット層22には芯鞘複合繊維41が含まれず、通常のナイロン繊維42で構成され、湿紙接触側バット層21のみに芯鞘複合繊維41が含まれる構成とした。これにより平滑性、耐脱毛・摩耗性、耐圧縮疲労性及び搾水性がバランスよく具備される。第1バット層22に芯鞘複合繊維41が含まれる場合、鞘成分が溶融して、基層の湿紙側の表面に形成されたバット層全体が非圧縮性となるため、耐脱毛・摩耗性には優れるが、プレスでの搾水性に劣るものとなる。  In the present invention, the first bat layer 22 formed on the surface of the base layer on the wet paper side does not include the core-sheath composite fiber 41, is composed of normal nylon fibers 42, and the core is formed only on the wet paper web-side butt layer 21. The sheath composite fiber 41 was included. Thereby, smoothness, depilation / wear resistance, compression fatigue resistance, and water squeezability are provided in a well-balanced manner. When the first bat layer 22 includes the core-sheath composite fiber 41, the sheath component melts, and the entire bat layer formed on the surface of the base layer on the wet paper web becomes incompressible. However, it is inferior to the water squeezing ability in a press.

湿紙接触側バット層21は、芯鞘複合繊維41と通常のナイロン繊維42とが一定の割合で混綿された繊維で構成されるのが好ましく、これにより平滑性・耐摩耗性・耐圧縮疲労性をよりバランスよく具えることができる。この場合、混綿の割合は、芯鞘複合繊維41の含有率75%〜25%、ナイロン繊維42の含有率25%〜75%とするのが好ましい。
芯鞘複合繊維41の含有率が25%未満の場合、湿紙接触側バット層21の緻密性が低くなるためフェルト表面の平滑性が悪くなり、再湿現象を抑制する効果が十分に得られない。
一方、芯鞘複合繊維41の含有率が75%を超えた場合は、フェルトの平滑性・耐摩耗性に優れ、再湿現象を効果的に抑制することができる反面、湿紙接触側バット層21が圧縮疲労しやすく、偏平化しやすい傾向になる。
The wet paper web-side batt layer 21 is preferably made of a fiber in which a core-sheath composite fiber 41 and a normal nylon fiber 42 are mixed at a certain ratio, thereby smoothness, wear resistance, and compression fatigue resistance. Can have a more balanced sex. In this case, the blended cotton ratio is preferably 75% to 25% of the core-sheath composite fiber 41 and 25% to 75% of the nylon fiber 42.
When the content ratio of the core-sheath composite fiber 41 is less than 25%, the denseness of the wet paper web side batt layer 21 is lowered, so that the smoothness of the felt surface is deteriorated and the effect of suppressing the rewetting phenomenon is sufficiently obtained. Absent.
On the other hand, when the content of the core-sheath composite fiber 41 exceeds 75%, the felt is excellent in smoothness and wear resistance, and the rewetting phenomenon can be effectively suppressed. No. 21 tends to fatigue compression and tends to flatten.

また、湿紙接触側バット層21を多層構造にし、該湿紙接触側バット層21のプレス側から湿紙側に向かって、芯鞘複合繊維41の含有量を段階的に増加させてもよく、これにより、平滑性と耐摩耗性を一層向上させることができる。
図2は、湿紙接触側バット層21を、第1層21a、第2層21bの2層構造とした場合の実施形態を示したものであり、第1層21aは、第2層21bよりも芯鞘複合繊維41の含有量が多くなっている。
このような構造とすることにより、湿紙接触側バット層21は再湿性と搾水性をバランスのよい構造にすることができる。つまり、芯鞘複合繊維41の含有量が多い第1層21aは緻密になるから再湿性と平滑性が維持でき、また芯鞘複合繊維41の含有量の少ない第1層21bは緻密性は低いが圧縮性が寄与されるため搾水性が向上し、湿紙接触側バット層21としては再湿性と搾水性を同時に付与することができる。このことから、湿紙接触側バット層21が単層の場合と比べて、平滑性と脱毛・摩耗性が維持されつつ、緻密層が2層に構成されるために再湿性が一層改善され、しかも搾水性も改善されるといった相乗効果を有することとなる。
逆に、湿紙接触側バット層21のプレス側から湿紙側に向かって、芯鞘複合繊維41の含有量を段階的に減少させた場合には、上記の構造とは逆の構造となるから、湿紙接触側バット層21が単層の場合と比べて、平滑性と脱毛・摩耗性、および再湿性が悪化する。
なお、図2では湿紙接触側バット層21を2層にしたが、3層以上で構成してもよい。
Alternatively, the wet paper web side batt layer 21 may have a multilayer structure, and the content of the core-sheath composite fiber 41 may be increased stepwise from the press side of the wet paper web side batt layer 21 toward the wet paper web side. Thereby, smoothness and wear resistance can be further improved.
FIG. 2 shows an embodiment in which the wet paper web side batt layer 21 has a two-layer structure of a first layer 21a and a second layer 21b. The first layer 21a is formed by the second layer 21b. However, the content of the core-sheath composite fiber 41 is increased.
By setting it as such a structure, the wet paper web side batt layer 21 can be made into a structure with a good balance between rewetting and water squeezing. That is, since the first layer 21a having a high content of the core-sheath composite fiber 41 becomes dense, the rewetting and smoothness can be maintained, and the first layer 21b having a low content of the core-sheath composite fiber 41 has a low density. However, since compressibility is contributed, water squeezing improves and the wet paper web side batt layer 21 can provide re-wetability and water squeezing simultaneously. From this, compared with the case where the wet paper web side batt layer 21 is a single layer, the wettability is further improved because the dense layer is composed of two layers while maintaining smoothness and hair removal and wear. In addition, it has a synergistic effect that water squeezing is also improved.
On the contrary, when the content of the core-sheath composite fiber 41 is decreased stepwise from the press side of the wet paper contact side batt layer 21 toward the wet paper side, the structure is opposite to the above structure. Therefore, compared with the case where the wet paper web side batt layer 21 is a single layer, the smoothness, hair removal / wear properties, and rewetting properties are deteriorated.
In FIG. 2, the wet paper web side batt layer 21 is formed in two layers, but it may be formed of three or more layers.

なお、芯鞘複合繊維41の芯部と鞘部の容積比率は特に限定されないが、5:1〜1:5の範囲、好ましくは1:1である。  The volume ratio of the core portion to the sheath portion of the core-sheath composite fiber 41 is not particularly limited, but is in the range of 5: 1 to 1: 5, preferably 1: 1.

また、湿紙接触側バット層21、プレス側バット層23を構成するナイロン繊維42、及び、芯鞘複合繊維41と混綿されるナイロン繊維42としては、ナイロン6、ナイロン66、ナイロン46、ナイロン610、ナイロン612等が好適である。  Further, nylon 6, nylon 66, nylon 46, nylon 610, which is mixed with the wet paper web side batt layer 21, the nylon fiber 42 constituting the press side batt layer 23, and the core-sheath composite fiber 41, are used. Nylon 612 or the like is preferable.

基層30は、図1及び図2に示すように、整経糸31(フェルトのCMD方向糸)と打ち込み糸32(同じくMD方向糸)をモノフィラメント単糸で織成することにより得られた織布が好ましく用いられるが、織組織としては(2/1,1/2)、(3/1,1/3)、(5/1,1/5)等の二重組織や三重組織、或いは(一重組織+二重組織)、(二重組織+二重組織)等の積層組織が使用できる。モノフィラメント単糸の太さは直径0.1mm〜0.6mmで、組織の糸密度は10〜100本/25mmが使用できる。
なお、本発明はこれに限定されず、MD方向糸材とCMD方向糸材を織成せずに重ねた構成、フィルム、編物、細い帯状体をスパイラルに巻回して幅広の帯状体を得た構成等、種々の構成を適宜採用することができる。また、基層30の素材としては、羊毛等の天然繊維や、耐摩耗性、耐疲労性、伸張特性、防汚性等に優れたポリエステルやナイロン6、ナイロン66等の合成繊維が用いられる。
As shown in FIGS. 1 and 2, the base layer 30 is made of a woven fabric obtained by weaving a warp yarn 31 (felt CMD direction yarn) and a driving yarn 32 (also MD direction yarn) with a monofilament single yarn. Although preferably used, as a woven structure, a double structure or a triple structure such as (2/1, 1/2), (3/1, 1/3), (5/1, 1/5), or (single Laminated structures such as (tissue + double structure) and (double structure + double structure) can be used. The thickness of the monofilament single yarn is 0.1 mm to 0.6 mm in diameter, and the yarn density of the structure can be 10 to 100/25 mm.
In addition, this invention is not limited to this, The structure which piled up the MD direction thread material and the CMD direction thread material without weaving, the film, the knitted fabric, and the thin strip | belt body wound spirally, and obtained the wide strip | belt body For example, various configurations can be adopted as appropriate. Further, as the material of the base layer 30, natural fibers such as wool, synthetic fibers such as polyester, nylon 6, nylon 66, etc. excellent in abrasion resistance, fatigue resistance, stretch characteristics, antifouling properties, etc. are used.

また、芯鞘複合繊維41の繊度は、抄紙機のプレスパートの前段で使用するピックアップ用フェルトでは、15〜25デシテックス(dtex)程度、また、抄紙機のプレスパートの中段で使用する2番プレスや3番プレス用のフェルトでは、10〜20デシテックス(dtex)程度のものを用いるとよい。
また、抄紙機のプレスパートの後段で使用する4番プレスやシュープレス用のフェルトでは、5〜20デシテックス(dtex)程度のものを用いるとよい。
In addition, the fineness of the core-sheath composite fiber 41 is about 15 to 25 dtex for a pickup felt used in the front stage of the paper machine press part, and the second press used in the middle stage of the paper machine press part. In the felt for No. 3 press or the like, it is preferable to use a felt of about 10 to 20 dtex.
Moreover, it is good to use about 5-20 dtex (dtex) about the felt for No. 4 press and shoe press used in the back | latter stage of the press part of a paper machine.

また、ナイロン繊維42の繊度は、抄紙機のプレスパートの前段で使用するピックアップ用フェルトの湿紙側バット層20には10〜25デシテックス(dtex)程度、プレス側バット層23には15〜25デシテックス(dtex)程度のものを用いるとよい。
また、抄紙機のプレスパートの中段で使用する2番プレスや3番プレス用のフェルトの湿紙側バット層20には10〜15デシテックス(dtex)程度、プレス側バット層層23には10〜20デシテックス(dtex)程度の繊度のものを用いるとよい。
また、抄紙機のプレスパートの後段で使用する4番プレスやシュープレス用のフェルトの湿紙側バット層32には5〜15デシテックス(dtex)程度、プレス側バット層23には5〜20デシテックス(dtex)程度の繊度のものを用いるとよい。
Further, the fineness of the nylon fiber 42 is about 10 to 25 dtex for the wet paper side batt layer 20 of the pick-up felt used in the front stage of the press part of the paper machine, and 15 to 25 for the press side batt layer 23. What is about decitex (dtex) may be used.
Further, the wet paper side butt layer 20 of the felt for No. 2 press or No. 3 press used in the middle part of the press part of the paper machine has about 10 to 15 dtex, and 10 to the press side butt layer layer 23. A fineness of about 20 dtex may be used.
Further, the wet paper side butt layer 32 of the No. 4 press or shoe press felt used in the subsequent stage of the press part of the paper machine has about 5 to 15 decitex (dtex), and the press side butt layer 23 has 5 to 20 decitex. It is good to use a fineness of about (dtex).

本発明の抄紙用プレスフェルトを、以下の実施例によって具体的に説明する。但し、本発明はこれらの実施例に限定されるものではない。  The press felt for papermaking of the present invention will be specifically described by the following examples. However, the present invention is not limited to these examples.

(芯鞘複合繊維の製造)
精錬されたナイロン6(カプロラクタム:融点220℃)と共重合ナイロン6/12(カプロラクタム/ラウロラクタム:融点140℃)を準備し、各々を脱揮口付きの押出機に個別に投入した後、押出機中で揮発物を除去し、溶融した芯材のナイロン6及び鞘材の共重合ナイロン6/12を、溶融状態にて定量ギアポンプにより定量して、各芯鞘複合紡糸ノズルに供給した。芯鞘複合紡糸ノズルを経て紡糸された芯鞘複合繊維をチムニーで冷却しつつオイリングして一旦自然延伸比で巻取り、その後延伸し捲縮加工後に定長でカットし、芯鞘複合繊維のステープルファイバーを製造した。
なお、芯鞘複合繊維の製造には「東洋精密工業製のMODEL−EMF」紡糸装置を使用することができる。この装置では、押出機とネルソン式多段延伸機及び巻取機が使用できる。
(Manufacture of core-sheath composite fiber)
Refined nylon 6 (caprolactam: melting point 220 ° C.) and copolymer nylon 6/12 (caprolactam / laurolactam: melting point 140 ° C.) were prepared, and each was individually fed into an extruder with a devolatilization port, followed by extrusion. Volatiles were removed in the machine, and melted core material nylon 6 and sheathed copolymer nylon 6/12 were quantified in a molten state with a quantitative gear pump and supplied to each core-sheath composite spinning nozzle. The core-sheath composite fiber spun through the core-sheath composite spinning nozzle is oiled while being cooled by a chimney, wound up at a natural stretch ratio, then stretched, then crimped, cut at a fixed length, and stapled with a core-sheath composite fiber. Fiber was manufactured.
For production of the core-sheath conjugate fiber, a “MODEL-EMF manufactured by Toyo Seimitsu Kogyo” spinning device can be used. In this apparatus, an extruder, a Nelson type multistage stretching machine, and a winder can be used.

本実施例では、芯材として高分子量ナイロン6(25℃での絶対粘度85mPa・s,融点220℃)と、中分子量ナイロン6(25℃での絶対粘度70mPa・s,融点220℃)の2種類、鞘材料として共重合ナイロン6/12(融点140℃)を使用し、芯部と鞘部の容積比率が1:1である芯鞘複合繊維のステープルファイバーを2種類製造した。芯材として高分子量ナイロン6を使用したものを複合繊維A、中分子量ナイロン6を使用したものを複合繊維Bとする。
なお、本実施例の絶対粘度85mPa・sと絶対粘度70mPa・sの数値を、汎用的な測定手段(ウベローデ粘度法)での相対粘度(ηrイーターアール)で表すとηr=4.5及び3.0となる。因みに絶対粘度80mPa・sはηr=4.0に相当する。
In this example, high molecular weight nylon 6 (absolute viscosity 85 mPa · s at 25 ° C., melting point 220 ° C.) and medium molecular weight nylon 6 (absolute viscosity 70 mPa · s at 25 ° C., melting point 220 ° C.) are used as core materials. Copolymer nylon 6/12 (melting point: 140 ° C.) was used as the type and sheath material, and two types of staple fiber of core-sheath composite fiber having a volume ratio of the core part to the sheath part of 1: 1 were produced. The one using high molecular weight nylon 6 as the core material is referred to as composite fiber A, and the one using medium molecular weight nylon 6 as composite fiber B.
In addition, when the numerical values of the absolute viscosity of 85 mPa · s and the absolute viscosity of 70 mPa · s in this example are expressed by the relative viscosity (ηr eater) in a general-purpose measuring means (Ubbelohde viscosity method), ηr = 4.5 and 3 .0. Incidentally, the absolute viscosity of 80 mPa · s corresponds to ηr = 4.0.

(抄紙用プレスフェルトの製造)
実施例、比較例ともに諸条件を共通とするため、全てのフェルトの基本構成を次の通りとした。
・基層:織布A[240dtexのナイロンモノフィラメントを2本撚り(下撚り)し、該下撚り糸を2本束ねて撚った(上撚り)撚糸を、MD方向糸材とCMD方向糸材にして織成した、(3/1,1/3)の二重組織]:坪量300g/m
:織布B[1100dtexのナイロンモノフィラメント単糸を、MD方向糸材とCMD方向糸材にして織成した、(3/1,1/3)の二重組織]:坪量300g/m
・バット層:湿紙接触側バット層(第1層)には(17dtexのナイロン6繊維、及び17dtexの複合繊維A又はBのステープルファイバー)で総坪量120g/m
:湿紙接触側バット層(第2層)には(17dtexのナイロン6繊維、及び17dtexの複合繊維Aのステープルファイバー)で総坪量120g/m
:第1バット層には(17dtexのナイロン6繊維、及び17dtexの複合繊維Aのステープルファイバー)で総坪量120g/m
:第2バット層には(17dtexのナイロン6繊維のステープルファイバー)で総坪量100g/m
・針打ち密度:700回/cm
・熱プレス:針打ち後のフェルトを、1対の熱カレンダーロール(ロール温度160℃、プレス圧30kg/cm)に、5m/minの速度で5回繰返して通過させ、0.5g/cm以上の密度を持つフェルトを得た。
実施例1〜8及び比較例1〜6のフェルトの構成を表1及び表2に示す。
(Manufacture of press felt for papermaking)
In order to make the conditions common to the examples and comparative examples, the basic configuration of all felts was as follows.
-Base layer: Woven Cloth A [twisted (primary twisted) two nylon monofilaments of 240 dtex, and twisted (supertwisted) two strands of the lower twisted yarn into MD direction yarn material and CMD direction yarn material Woven (3/1, 1/3) double structure]: basis weight 300 g / m 2
: Woven Cloth B [Double structure of (3/1, 1/3) of 1100 dtex nylon monofilament single yarn woven with MD direction yarn material and CMD direction yarn material]: Basis weight 300 g / m 2
・ Batt layer: Wet paper contact side batt layer (first layer) (17 dtex nylon 6 fiber and 17 dtex composite fiber A or B staple fiber) with a total basis weight of 120 g / m 2
: Wet paper contact side batt layer (second layer) (17 dtex nylon 6 fiber and 17 dtex composite fiber A staple fiber) with a total basis weight of 120 g / m 2
: The first batting layer (17 dtex nylon 6 fiber and 17 dtex composite fiber A staple fiber) has a total basis weight of 120 g / m 2
: The second batting layer (17 dtex nylon 6 fiber staple fiber) with a total basis weight of 100 g / m 2
・ Needle density: 700 times / cm 2
Hot press: The felt after needle punching is repeatedly passed through a pair of heat calender rolls (roll temperature: 160 ° C., press pressure: 30 kg / cm) at a speed of 5 m / min 5 times, 0.5 g / cm 3 A felt with the above density was obtained.
Tables 1 and 2 show the configurations of the felts of Examples 1 to 8 and Comparative Examples 1 to 6.

Figure 2007217848
Figure 2007217848

Figure 2007217848
Figure 2007217848

上記の実施例及び比較例の抄紙用プレスフェルトを使用して、以下の条件、方法により再湿現象と搾水性の評価及び耐圧縮疲労性、耐脱毛・摩耗性、平滑性の評価を行なった。  Using the paper felt press felts of the above examples and comparative examples, the following conditions and methods were used to evaluate the rewetting phenomenon and squeezing resistance, and the compression fatigue resistance, hair loss / wear resistance, and smoothness. .

(再湿現象と搾水性の評価)
図3及び図4に示される装置により再湿現象と搾水性の評価を行った。
まず、図3、図4に示される装置において、図中、Pはプレスロール、110はトップ側フェルト、10はボトム側フェルト、SCはサクションチューブ、SNはシャワーノズルである。
なお、上記実施例及び比較例は、いずれの装置においてもボトム側フェルト10として使用されている。この場合、トップ側フェルトとしては、比較例2に示したものと同様のプレスフェルトを使用した。
また、図3、図4に示される装置は、ともに、フェルトの走行速度が800m/minであり、プレス圧力が80kg/cmである。
(Evaluation of rewetting phenomenon and water squeezing)
The rewetting phenomenon and water squeezing were evaluated by the apparatus shown in FIGS.
First, in the apparatus shown in FIG. 3 and FIG. 4, P is a press roll, 110 is a top felt, 10 is a bottom felt, SC is a suction tube, and SN is a shower nozzle.
In addition, the said Example and comparative example are used as the bottom side felt 10 also in any apparatus. In this case, a press felt similar to that shown in Comparative Example 2 was used as the top felt.
3 and 4 both have a felt travel speed of 800 m / min and a press pressure of 80 kg / cm.

図3に示される装置は、ニップ圧下を脱した湿紙が、ボトム側フェルト10に載置され搬送される構造となっている。従って、ニップ圧下を脱した後、ボトム側フェルト10に載置され搬送された位置(プレス出口1)における湿紙の湿潤度合いを計測すると、再湿現象が発生した湿紙の水分含有量データを得ることができる。
これに対し、図4に示される装置は、ボトム側フェルト10がプレスロールに接触する面積が大きく、ニップ圧下を脱した湿紙が、フェルト10,110に接触する時間が非常に短いものである。ここで、このニップ圧下を脱した直後の位置(プレス出口2)における湿紙の湿潤度合いを計測すると、再湿現象のあまり生じていない湿紙の水分含有量データが得られる。
The apparatus shown in FIG. 3 has a structure in which wet paper that has been released from the nip pressure is placed on the bottom felt 10 and conveyed. Accordingly, when the wet paper wetness at the position (press outlet 1) placed and transported on the bottom felt 10 is measured after the nip pressure is removed, the moisture content data of the wet paper in which the rewetting phenomenon occurs is obtained. Obtainable.
On the other hand, the apparatus shown in FIG. 4 has a large area where the bottom-side felt 10 comes into contact with the press roll, and the time when the wet paper released from the nip pressure comes into contact with the felt 10, 110 is very short. . Here, when the wetness of the wet paper at the position immediately after the release of the nip pressure (press outlet 2) is measured, the moisture content data of the wet paper that does not cause much rewetting is obtained.

ここで、図3の装置による水分含有量データと、図4の装置による同データを求め、再湿現象と搾水性の評価を行った。搾水性の評価については、図3の装置によるプレス出口1での水分含有量データにおいて、水分48%以上49%未満のものは(搾水性評価「良」)とした。そして水分49%以上のものは(搾水性評価「不良」)とした。再湿現象の評価については、図3の装置による水分含有量データと、図4の装置による同データの差において、両者の差が0.5%未満のものは再湿現象を生じないものとした(評価「良」)。一方、この両者の差が0.5%以上1.0%未満のものは、やや再湿現象が生じているとし(評価「可」)、1.0%以上のものは再湿現象が生じているとした(評価「不良」)。  Here, the moisture content data by the apparatus of FIG. 3 and the same data by the apparatus of FIG. For the evaluation of water squeezing, in the water content data at the press outlet 1 by the apparatus of FIG. And the thing of 49% or more of water | moisture content was set to (water extraction evaluation "poor"). Regarding the evaluation of the rewetting phenomenon, the difference between the water content data by the apparatus of FIG. 3 and the same data by the apparatus of FIG. (Evaluation “good”). On the other hand, when the difference between the two is 0.5% or more and less than 1.0%, a re-wetting phenomenon occurs (evaluation is “OK”), and when the difference is 1.0% or more, a re-wetting phenomenon occurs. (Evaluation “bad”).

(繰返し圧縮疲労試験)
120kg/cmで5Hzパルス荷重を繰返し30万回与え、圧縮疲労試験を行なった。圧縮疲労性を(試験後の密度/仕上がり密度)比で表し、1.30未満を「優」、1.30以上1.39以下のものを「良」、1.40以上のもの「不良」とした。
(Repeated compression fatigue test)
A compression fatigue test was conducted by repeatedly applying a 5 Hz pulse load at 120 kg / cm 2 and 300,000 times. Compressive fatigue is expressed as a ratio (density after test / finished density), where “less than” 1.30 is “excellent”, 1.30 or more and 1.39 or less is “good”, and 1.40 or more “bad”. It was.

(テーパー脱毛・摩耗試験)
JIS1023−1992に基づくテーパー研磨試験機により、抄紙用フェルトから脱落した繊維量を測ることにより、耐脱毛・摩耗性の評価を行なった。回転するターンテーブル上に円盤状の試験片を載置し、さらに試験片上に抵抗の大きい回転ロールを当接させて、繊維の脱落量(脱毛・摩耗量)を測った。(荷重:0.5kg、ホイール:CS−17、回転数:3000回、単位:mg)
脱毛・摩耗量が40mg以下のものを「良」、40mgを超えたものを「不良」とした。
(Taper hair removal and wear test)
Hair removal resistance and abrasion resistance were evaluated by measuring the amount of fibers dropped from the papermaking felt using a taper polishing tester based on JIS1023-1992. A disk-shaped test piece was placed on a rotating turntable, and a rotating roll with high resistance was brought into contact with the test piece to measure the amount of fiber falling off (hair removal / wear amount). (Load: 0.5 kg, Wheel: CS-17, Number of revolutions: 3000 times, Unit: mg)
A hair removal / wear amount of 40 mg or less was evaluated as “good”, and a hair loss / wear amount exceeding 40 mg was determined as “bad”.

(表面粗さの測定)
テーパー脱毛・摩耗試験前の、仕上がりフェルトの十点平均粗さRz(μm)(JIS−B0601)を測定し、フェルト表面の平滑性の評価を行なった。
表面粗さ60μm未満のものを「優」、60μm以上99μm以下のものを「良」、100μm以上のものを「不良」とした。
各試験の測定結果及び評価を表3に示す。
(Measurement of surface roughness)
The smoothness of the felt surface was evaluated by measuring the ten-point average roughness Rz (μm) (JIS-B0601) of the finished felt before the taper hair removal / wear test.
A sample having a surface roughness of less than 60 μm was defined as “excellent”, a sample having a surface roughness of 60 μm to 99 μm was defined as “good”, and a sample having a surface roughness of 100 μm or greater was defined as “bad”.
Table 3 shows the measurement results and evaluation of each test.

Figure 2007217848
Figure 2007217848

表3の実施例1〜8に示されるように、本発明の抄紙用プレスフェルトは、再湿現象を抑制すると同時に、耐圧縮疲労性、耐脱毛・摩耗性、平滑性及び搾水性の機能をバランス良く具備することが確認された。  As shown in Examples 1 to 8 in Table 3, the press felt for papermaking of the present invention suppresses the rewetting phenomenon, and at the same time has the functions of compression fatigue resistance, hair removal / wear resistance, smoothness and water squeezing function. It was confirmed that it was well-balanced.

第1バット層を芯鞘複合繊維で構成した比較例1は、耐圧縮疲労性と耐脱毛・摩耗性は良いが、フェルト表面の平滑性には劣ることが分かる。
また、湿紙接触側バット層の芯鞘複合繊維の含有量が25%未満である実施例3や比較例3及び芯鞘繊維を含まない比較例2では、耐圧縮疲労性の機能は果たしているが、再湿現象が抑制されないことが分かる。
また、湿紙接触側バット層のプレス側から湿紙側に向かって、芯鞘複合繊維の含有量を段階的に減少させた比較例4は、耐圧縮疲労性・再湿性の機能を果たしているが、平滑性が悪い。これは芯鞘複合繊維をより少なく含む芯鞘複合繊維層(第2層)がフェルト表面を構成するためと考えられる。
また、芯鞘複合繊維の芯成分に中分子量ナイロンを用いた比較例5は、高分子量ナイロンを用いた実施例1と比較して、耐圧縮疲労性・耐脱毛・摩耗性が悪くなることが分かる。さらに、実施例8は、基層にモノフィラメント単糸で織成された織布を基層Bとして使用しているので、基層Aのモノフィラメント撚糸で織成された織布を使用した実施例1よりもプレス出口での水分(1及び2)が何れも低く、搾水性が優れることが確認された。
It can be seen that Comparative Example 1 in which the first batt layer is composed of the core-sheath composite fiber has good compression fatigue resistance and anti-hair removal / wear resistance, but is inferior in the felt surface smoothness.
Further, in Example 3 and Comparative Example 3 in which the content of the core-sheath composite fiber in the wet paper web side batt layer is less than 25% and Comparative Example 2 not including the core-sheath fiber, the function of compression fatigue resistance is achieved. However, it can be seen that the rewetting phenomenon is not suppressed.
Further, Comparative Example 4 in which the content of the core-sheath composite fiber was decreased stepwise from the press side of the wet paper contact side batt layer toward the wet paper side has a function of resistance to compression fatigue and rewetting. However, the smoothness is poor. This is considered because the core-sheath composite fiber layer (second layer) containing less core-sheath composite fiber constitutes the felt surface.
In addition, Comparative Example 5 using medium molecular weight nylon as the core component of the core-sheath composite fiber has worse compression fatigue resistance, hair removal resistance, and wear resistance than Example 1 using high molecular weight nylon. I understand. Furthermore, since Example 8 uses a woven fabric woven with a monofilament monofilament as the base layer B as the base layer B, it is more pressed than Example 1 using a woven fabric woven with the monofilament twisted yarn of the base layer A. It was confirmed that the water content at the outlet (1 and 2) was both low and water squeezed was excellent.

本発明のプレスフェルトの実施形態の断面図。Sectional drawing of embodiment of the press felt of this invention. 本発明のプレスフェルトの別の実施形態の断面図。Sectional drawing of another embodiment of the press felt of this invention. 本発明のプレスフェルトの効果を確認するための装置の概要図。The schematic diagram of the apparatus for confirming the effect of the press felt of this invention. 本発明のプレスフェルトの効果を確認するための装置の概要図。The schematic diagram of the apparatus for confirming the effect of the press felt of this invention. 製紙機械のプレス装置の概略説明図。Schematic explanatory drawing of the press apparatus of a papermaking machine.

符号の説明Explanation of symbols

10:抄紙用プレスフェルト
21:湿紙接触側バット層(芯鞘複合繊維層)
21a,21b:湿紙接触側バット層(芯鞘複合繊維層)
22:第1バット層
23:第2バット層
30:基層
31:整経糸
32:打ち込み糸
41:芯鞘複合繊維
42:ナイロン繊維
10: Press felt for papermaking 21: Wet paper contact side butt layer (core-sheath composite fiber layer)
21a, 21b: wet paper web side batt layer (core-sheath composite fiber layer)
22: 1st butt layer 23: 2nd butt layer 30: Base layer 31: Warp yarn 32: Driving yarn 41: Core-sheath composite fiber 42: Nylon fiber

Claims (4)

基層と、基層の湿紙側の表面に形成された第1バット層と、プレス側の表面に形成された第2バット層と、前記第1バット層の湿紙側の表面に形成された湿紙接触繊維層とを備え、
前記湿紙接触繊維層が絶対粘度が80mPa・s以上である高分子量ナイロンからなる芯成分と、該芯成分よりも低融点のナイロンからなる鞘成分とから構成される芯鞘複合繊維を含み、
前記第1バット層が、前記芯鞘複合繊維を含まないナイロンの層からなることを特徴とする、
抄紙用プレスフェルト。
A base layer, a first butt layer formed on the wet paper web surface of the base layer, a second bat layer formed on the press paper surface, and a wet paper web surface formed on the wet paper web surface of the first bat layer. A paper contact fiber layer,
The wet paper contact fiber layer includes a core / sheath composite fiber composed of a core component made of high molecular weight nylon having an absolute viscosity of 80 mPa · s or more, and a sheath component made of nylon having a lower melting point than the core component,
The first batt layer is made of a layer of nylon that does not contain the core-sheath conjugate fiber,
Press felt for papermaking.
前記湿紙接触繊維層における前記芯鞘複合繊維の含有率が25%〜75%である、請求項1の抄紙用プレスフェルト。  The press felt for papermaking of Claim 1 whose content rate of the said core-sheath composite fiber in the said wet paper contact fiber layer is 25%-75%. 前記湿紙接触繊維層を多層構造とし、前記第1バット層のプレス側から湿紙側に向かって、前記芯鞘複合繊維の含有量を段階的に増加させた、請求項1又は2の抄紙用プレスフェルト。  The papermaking according to claim 1 or 2, wherein the wet paper contact fiber layer has a multilayer structure, and the content of the core-sheath composite fiber is increased stepwise from the press side of the first batt layer toward the wet paper side. Press felt. 前記基層が、モノフィラメント単糸の整経糸と打ち込み糸とから織成された織布である、請求項1〜3のいずれかの抄紙用プレスフェルト。  The press felt for papermaking according to any one of claims 1 to 3, wherein the base layer is a woven fabric woven from a warp yarn and a driving yarn of a monofilament single yarn.
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JP3440442B2 (en) 1998-01-06 2003-08-25 市川毛織株式会社 Felt for papermaking and method for producing the same
US6235390B1 (en) 1998-11-03 2001-05-22 E. I. Du Pont De Nemours And Company High RV filaments, and apparatus and processes for making high RV flake and the filaments
DE19854732C1 (en) 1998-11-26 2000-09-14 Inventa Ag Core-jacket bicomponent fiber and its use
JP2000170087A (en) * 1998-12-08 2000-06-20 Ichikawa Woolen Textile Co Ltd Press felt for paper making
JP2000170086A (en) 1998-12-08 2000-06-20 Ichikawa Woolen Textile Co Ltd Press felt for paper making
JP4102644B2 (en) 2002-10-24 2008-06-18 イチカワ株式会社 Press felt for paper making and press machine for paper machine
WO2005098128A1 (en) 2004-04-08 2005-10-20 Ems Chemie Ag Press felt for paper machine and method and device for producing said felt
JP4454408B2 (en) * 2004-06-25 2010-04-21 イチカワ株式会社 Felt for papermaking
JP4875895B2 (en) * 2006-01-06 2012-02-15 イチカワ株式会社 Press felt for papermaking

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010031394A (en) * 2008-07-25 2010-02-12 Nippon Felt Co Ltd Felt for making paper and method for producing the same
JP2011162910A (en) * 2010-02-09 2011-08-25 Nippon Felt Co Ltd Papermaking felt and method for producing the same
JP2011162911A (en) * 2010-02-09 2011-08-25 Nippon Felt Co Ltd Papermaking felt and method for producing the same, as well as papermaking belt and method for producing the same

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EP1985752A4 (en) 2009-03-25
EP1985752A1 (en) 2008-10-29
JP4157136B2 (en) 2008-09-24
AU2007216016A1 (en) 2007-08-23
BRPI0707822A2 (en) 2011-05-10
CA2642541A1 (en) 2007-08-23
WO2007094207A1 (en) 2007-08-23
KR20080100418A (en) 2008-11-18
CN101384770A (en) 2009-03-11
TW200736462A (en) 2007-10-01
US20100163202A1 (en) 2010-07-01

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