JP2007205011A - Construction method and coating method for soil-based pavement - Google Patents

Construction method and coating method for soil-based pavement Download PDF

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JP2007205011A
JP2007205011A JP2006024282A JP2006024282A JP2007205011A JP 2007205011 A JP2007205011 A JP 2007205011A JP 2006024282 A JP2006024282 A JP 2006024282A JP 2006024282 A JP2006024282 A JP 2006024282A JP 2007205011 A JP2007205011 A JP 2007205011A
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soil
pavement
coating
earth
paving
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Hiroteru Maenami
洋輝 前浪
Yuuji Kuriaki
裕次 栗秋
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Inax Corp
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/49Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
    • C04B41/4905Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
    • C04B41/495Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as oligomers or polymers
    • C04B41/4961Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • C04B2111/343Crack resistant materials

Abstract

<P>PROBLEM TO BE SOLVED: To realize both the prevention of the appearance of a crack, and that of a deterioration in designability, caused by efflorescence, and the production of dust etc., in a soil-based pavement. <P>SOLUTION: In this construction method for the soil-based pavement, after the preparation of a mixture for the soil-based pavement, in which soil, and cement and/or hydrated lime are mixed together, water is mixed into the mixture for the soil-based pavement, so that a pavement material can be prepared; and the pavement material is placed and spread in a paving place, subjected to surface compaction, and cured for the soil-based pavement. When the soil for use contains 2-30 mass% particles with a particle diameter of 75 μm or less and the mixture for the soil-based pavement contains a surfactant-based shrinkage reducing agent 1a, the construction method comprises a coating step of forming a surface layer 2, which is composed of an acrylic silicon-based, urethane-based or epoxy silicon-based coating agent, on the soil-based pavement 1. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、土系舗装の施工方法及び土系舗装へのコーティング方法に関する。   The present invention relates to a method for constructing an earth-based pavement and a method for coating the earth-based pavement.

従来、出願人は特許文献1〜10の常温固化無機材料調合物等を提案した。また、特許文献11〜13に他の調合物が開示されている。これらの調合物は、土及びセメント、消石灰等のカルシウム分を含むものである。   Conventionally, the applicant has proposed the room temperature solidified inorganic material preparations of Patent Documents 1-10. Patent Documents 11 to 13 disclose other preparations. These formulations contain calcium, such as soil and cement, slaked lime.

これらの調合物は、水が混合された後、舗装場所に敷きならされ、転圧及び養生されれば、土系舗装となり得る。この土系舗装は自然の土の雰囲気がそのまま残り、優れた意匠を呈する。   These formulations can be ground pavement after being mixed with water and then laid down on the pavement, rolled and cured. This earth-based pavement retains the natural soil atmosphere and exhibits an excellent design.

特開2000−1347号公報JP 2000-1347 A 特開2000−1358号公報JP 2000-1358 A 特開2001−31462号公報JP 2001-31462 A 特開2000−290058号公報JP 2000-290058 A 特開2000−203922号公報JP 2000-203922 A 特開2001−114579号公報JP 2001-114579 A 特開2001−271306号公報JP 2001-271306 A 特開2002−87872号公報JP 2002-87872 A 特開2001−192256号公報JP 2001-192256 A 特開2004−52536号公報JP 2004-52536 A 特開平11−302643号公報Japanese Patent Laid-Open No. 11-302643 特開平10−1908号公報Japanese Patent Laid-Open No. 10-1908 特開平11−71582号公報JP-A-11-71582

しかし、上記従来の土系舗装は、土に細かい粒子を含む場合が多いことから、収縮によってクラックが発生し易い。一般的に、このようなクラックの発生防止のためには、調合物、ひいては土系舗装中に界面活性剤系の収縮低減剤を含ませることが有効である。   However, since the conventional earth-based pavement often contains fine particles in the soil, cracks are likely to occur due to shrinkage. Generally, in order to prevent the occurrence of such cracks, it is effective to include a surfactant-based shrinkage reducing agent in the preparation, and thus in the soil-based pavement.

また、この土系舗装は、屋外に施工された場合には雨水により、また屋内に施工された場合には清掃等で使用する水により、未反応のカルシウム分が表面に溶出して白華を生じ、意匠性が低下してしまうこともある。また、この土系舗装は、表面硬度の不足により摩耗し易く、粉塵等の発生も懸念される。一般的に、これらの防止のためには、土系舗装上に樹脂系のコーティング剤からなる表面層を形成することが有効である。   In addition, when this soil-based pavement is constructed outdoors, unreacted calcium is eluted on the surface by rainwater and when it is constructed indoors by water used for cleaning, etc. It may occur and the designability may deteriorate. In addition, this earth-based pavement is likely to be worn due to insufficient surface hardness, and there is a concern about generation of dust and the like. Generally, in order to prevent these problems, it is effective to form a surface layer made of a resin-based coating agent on earth-based pavement.

しかしながら、上記両不具合を解決すべく、調合物中に界面活性剤系の収縮低減剤を含ませつつ、土系舗装上に樹脂系のコーティング剤からなる表面層を形成すると、その表面層が硬化不良を生じてしまうことが明らかとなった。   However, in order to solve both of the above problems, if a surface layer made of a resin-based coating agent is formed on a soil-based pavement while a surfactant-based shrinkage reducing agent is included in the preparation, the surface layer is cured. It became clear that it would cause defects.

本発明は、上記従来の実情に鑑みてなされたものであって、土系舗装において、クラックの発生防止と、白華による意匠性の低減及び粉塵等の発生の防止との両者を実現することを解決すべき課題としている。   The present invention has been made in view of the above-described conventional situation, and realizes both prevention of generation of cracks, reduction of designability by white flower and prevention of generation of dust and the like in earth-based pavement. Is a problem to be solved.

発明者らは、上記課題解決のための鋭意研究を行い、界面活性剤系の収縮低減剤による上記表面層の硬化不良が土系舗装に用いる土の粒径、その通水性及び表面層の樹脂の種類に基づくことを発見し、本発明を完成させるに至った。   The inventors have intensively studied to solve the above-mentioned problems, and the surface layer is poorly cured by a surfactant-based shrinkage reducing agent. The particle size of the soil used for soil-based paving, its water permeability, and the resin of the surface layer. The present invention has been completed by discovering that it is based on the kind of the above.

この発見に基づく第1発明の土系舗装の施工方法は、土と、セメント及び/又は消石灰とが混合されてなる土系舗装用調合物を調製する調製工程と、   The construction method of the earth-based pavement of the first invention based on this discovery is a preparation step of preparing a composition for earth-based pavement in which soil and cement and / or slaked lime are mixed,

該土系舗装用調合物に水を混合して舗装材とし、該舗装材を舗装場所に敷きならし、転圧及び養生して土系舗装とする舗装工程とを備えた土系舗装の施工方法において、   Construction of earth-based pavement comprising a pavement process in which water is mixed with the composition for earth-based pavement to form a pavement material, and the pavement material is laid on a pavement place and rolled and cured to form a soil-type pavement. In the method

前記土は粒径75μm以下の粒子が2〜30質量%であり、前記土系舗装用調合物が界面活性剤系の収縮低減剤を含む場合、前記土系舗装上にアクリルシリコン系、ウレタン系又はエポキシシリコン系のコーティング剤からなる表面層を形成するコーティング工程を行なうことを特徴とする。   When the soil has a particle size of 2 to 30% by mass with a particle size of 75 μm or less, and the soil-based paving preparation contains a surfactant-based shrinkage reducing agent, an acrylic silicon-based or urethane-based material is formed on the soil-based paving. Alternatively, a coating process for forming a surface layer made of an epoxy silicon-based coating agent is performed.

土は、一般に礫分と砂分とシルト分と粘土分とからなる。礫分は粒径が2000μmを超えるものである。細砂、中砂及び粗砂からなる砂分は粒径が74μmを超え、2000μm以下のものである。シルト分は粒径が5μmを超え、75μm以下のものである。粘土分(コロイドを含む。)は粒径が5μm以下のものである。コンクリートには砂分は用いられるが、シルト分及び粘土分は用いられない。本発明に係る土は、シルト分以下、つまり粒径75μm以下の粒子が2〜30質量%である。このため、土系舗装は、自然の土の雰囲気がそのまま残り、優れた意匠を呈する一方、クラックを生じやすく、かつ通水性を有する。   Soil generally consists of gravel, sand, silt and clay. The gravel has a particle size exceeding 2000 μm. The sand composed of fine sand, medium sand and coarse sand has a particle size of more than 74 μm and not more than 2000 μm. The silt component has a particle size of more than 5 μm and 75 μm or less. The clay (including colloid) has a particle size of 5 μm or less. Sand is used for concrete, but silt and clay are not used. The soil according to the present invention contains 2 to 30% by mass of silt or less, that is, particles having a particle size of 75 μm or less. For this reason, the soil-based pavement retains the natural soil atmosphere as it is and exhibits an excellent design, while being prone to cracking and having water permeability.

そして、その土系舗装中にクラックの発生防止のために界面活性剤系の収縮低減剤を含ませると、土系舗装の通水性によって水が表面側にも移動し、この水の表面側への移動とともに収縮低減剤も表面に移動して濃縮される。このため、コーティング工程として、土系舗装上に樹脂系のコーティング剤からなる表面層を形成すれば、濃縮した収縮低減剤がその表面層と接触し、樹脂が特定のものである場合には、その表面層は硬化が妨げられてしまう。   If a surfactant-based shrinkage reducing agent is included in the soil-based pavement to prevent cracks, the water moves to the surface side due to the water permeability of the soil-based pavement, and the surface of this water is moved to the surface side. The shrinkage reducing agent also moves to the surface as it moves, and is concentrated. For this reason, if a surface layer made of a resin-based coating agent is formed on the soil-based pavement as a coating step, the concentrated shrinkage reducing agent comes into contact with the surface layer, and when the resin is a specific one, The surface layer is prevented from curing.

この点、第1発明の施工方法では、土系舗装上にコーティング工程によって形成する表面層の樹脂をアクリルシリコン系、ウレタン系又はエポキシシリコン系としている。発明者らの試験結果によれば、これらの樹脂からなる表面層であれば、たとえ濃縮した収縮低減剤がその表面層と接触しても、表面層は好適に硬度を維持する。   In this regard, in the construction method of the first invention, the resin of the surface layer formed by the coating process on the earth-based pavement is an acrylic silicon type, a urethane type or an epoxy silicon type. According to the test results of the inventors, if the surface layer is made of these resins, the surface layer suitably maintains the hardness even if the concentrated shrinkage reducing agent comes into contact with the surface layer.

また、同発見に基づく第2発明の土系舗装へのコーティング方法は、土と、セメント及び/又は消石灰とが混合されてなる土系舗装用調合物に水が混合されて舗装材とされ、該舗装材が舗装場所に敷きならされ、転圧及び養生されて形成された土系舗装へのコーティング方法であって、   In addition, the method for coating a soil-based pavement of the second invention based on the same discovery is a pavement material in which water is mixed with a soil-based pavement composition in which soil and cement and / or slaked lime are mixed. A method for coating an earth-based pavement in which the pavement material is laid on a pavement, formed by rolling and curing,

前記土は粒径75μm以下の粒子が2〜30質量%であり、前記土系舗装用調合物が界面活性剤系の収縮低減剤を含む場合、前記土系舗装上にアクリルシリコン系、ウレタン系又はエポキシシリコン系のコーティング剤からなる表面層を形成するコーティング工程を行なうことを特徴とする。   When the soil has a particle size of 2 to 30% by mass with a particle size of 75 μm or less, and the soil-based paving preparation contains a surfactant-based shrinkage reducing agent, an acrylic silicon-based or urethane-based material is formed on the soil-based paving. Alternatively, a coating process for forming a surface layer made of an epoxy silicon-based coating agent is performed.

第2発明のコーティング方法においても、土系舗装上にコーティング工程によって形成する表面層の樹脂をアクリルシリコン系、ウレタン系又はエポキシシリコン系としているため、たとえ濃縮した収縮低減剤がその表面層と接触しても、表面層は好適に硬度を維持する。   Also in the coating method of the second invention, since the resin of the surface layer formed by the coating process on the earth-based pavement is an acrylic silicon type, a urethane type or an epoxy silicon type, the concentrated shrinkage reducing agent is in contact with the surface layer. Even so, the surface layer preferably maintains hardness.

したがって、第1発明の施工方法又は第2発明のコーティング方法であれば、土系舗装におけるクラックの発生防止と、白華による意匠性の低減及び粉塵等の発生の防止との両者を実現することができる。   Therefore, if it is the construction method of the first invention or the coating method of the second invention, it is possible to realize both prevention of generation of cracks in earth-based pavement, reduction of design by white flower and prevention of generation of dust and the like. Can do.

なお、特許第2816854号公報には、粒状弾性材よりなる空隙率の大きい下地層上にポリウレタン樹脂のコーティング剤からなる表面層を形成することが開示されている。しかし、この技術は、土系舗装特有の課題を解決したものではない。   Japanese Patent No. 2816854 discloses that a surface layer made of a polyurethane resin coating agent is formed on a base layer made of a granular elastic material and having a high porosity. However, this technology does not solve the problems peculiar to earth paving.

第1発明の施工方法又は第2発明のコーティング方法において、コーティング剤は水系のアクリルシリコン系のものであることが好ましい。発明者らの試験結果によれば、アクリルシリコン系のコーティング剤が最も優れた効果を発揮する。そして、それが水系のものであれば、作業性にも優れる。   In the construction method of the first invention or the coating method of the second invention, the coating agent is preferably a water-based acrylic silicon-based one. According to the test results of the inventors, the acrylic silicon-based coating agent exhibits the most excellent effect. And if it is an aqueous thing, it is excellent also in workability | operativity.

また、第1発明の施工方法又は第2発明のコーティング方法において、コーティング剤は有機溶剤系のものであることも好ましい。有機溶剤系のコーティング剤であれば、アクリルシリコン系、ウレタン系又はエポキシシリコン系において、優れた効果を発揮する。   In the construction method of the first invention or the coating method of the second invention, the coating agent is preferably an organic solvent-based one. In the case of an organic solvent-based coating agent, an excellent effect is exhibited in an acrylic silicon system, a urethane system, or an epoxy silicon system.

なお、土系舗装用調合物は顔料や骨材を含むこともできる。骨材としては、砂利、砕石の他、コンクリートがら、陶磁器がら、カレット等の無機廃棄物も採用することができる。   The soil-based paving preparation can also contain pigments and aggregates. As the aggregate, in addition to gravel and crushed stone, inorganic waste such as concrete, ceramics, cullet and the like can also be used.

以下、第1発明を具体化した実施例1〜3及び第2発明を具体化した実施例4を図面を参照しつつ説明する。   Examples 1 to 3 that embody the first invention and Example 4 that embody the second invention will be described below with reference to the drawings.

表1に示す配合で各材料を用意し、水を除く他の材料をミキサーで混合して土系舗装用調合物とした。   Each material was prepared with the composition shown in Table 1, and other materials except water were mixed with a mixer to obtain a soil-based paving formulation.

Figure 2007205011
Figure 2007205011

土は、59.74質量部の砂と、40.26質量部の砕石廃土とからなる。土の粒度分布を図1に示すとおり、砂は粒径75μm以下の粒子を全体に対して1.32質量%含み、砕石廃土は粒径75μm以下の粒子を全体に対して7.23質量%含んでいる。表1に示す配合で砂と砕石廃土とを混合させた土は、最大粒径が10mm以下であり、粒径75μm以下の粒子が3.7質量%(内訳;砂が0.8質量%、砕石廃土が2.9質量%)である。また、セメントは普通ポルトランドセメントである。骨材は、粒径5〜13mmの6号砕石4.05質量部と、粒径2.5〜5mmの7号砕石15.44質量部とからなる。収縮低減剤はポリエーテル系界面活性剤(竹本油脂(株)製「ヒビダンB」)である。なお、混和剤はAE剤及び消泡剤である。   The soil consists of 59.74 parts by mass of sand and 40.26 parts by mass of crushed stone waste. As shown in FIG. 1, the particle size distribution of the soil includes 1.32% by mass of particles having a particle size of 75 μm or less, and the crushed stone waste soil has 7.23% by mass of particles having a particle size of 75 μm or less. % Is included. The soil obtained by mixing sand and crushed stone waste with the composition shown in Table 1 has a maximum particle size of 10 mm or less, and 3.7% by mass of particles having a particle size of 75 μm or less (breakdown: 0.8% by mass of sand) The crushed stone waste soil is 2.9% by mass). The cement is usually Portland cement. The aggregate consists of 4.05 parts by mass of No. 6 crushed stone having a particle size of 5 to 13 mm and 15.44 parts by mass of No. 7 crushed stone having a particle size of 2.5 to 5 mm. The shrinkage reducing agent is a polyether surfactant (“Hibidan B” manufactured by Takemoto Yushi Co., Ltd.). The admixture is an AE agent and an antifoaming agent.

この土系舗装用調合物に表1に示す配合の水を添加し、これらをミキサーにより混合して舗装材とした。型枠を設置した舗装場所にこの舗装材を7.5〜8cmの厚さで敷きならし、ハンドガイドローラ等により厚さが5cmになるように転圧を行った後、ブルーのビニールシートを被せて7日間養生した。なお、必要に応じて手作業による転圧も行った。こうして、図2に示す土系舗装1を得た。土系舗装1中には、界面活性剤系の収縮低減剤1aが含まれている。   Water of the composition shown in Table 1 was added to this soil-based paving preparation, and these were mixed by a mixer to obtain a paving material. Spread this pavement material at a thickness of 7.5 to 8 cm on the pavement where the formwork is installed, roll it with a hand guide roller to a thickness of 5 cm, and then cover it with a blue vinyl sheet. For 7 days. In addition, the rolling by manual work was also performed as needed. Thus, the earth-based pavement 1 shown in FIG. 2 was obtained. The earth-based pavement 1 contains a surfactant-based shrinkage reducing agent 1a.

次いで、コーティング剤を用意した。コーティング剤は、表2に示すNo.4の原液(アクリルシリコン系)を用いたものである。   Next, a coating agent was prepared. The coating agent is No. 2 shown in Table 2. No. 4 stock solution (acrylic silicon type) is used.

Figure 2007205011
Figure 2007205011

このコーティング剤を塗布量100〜200g/m2で土系舗装1上に塗布し、乾燥させることによって表面層2を形成した。 This coating agent was applied onto the earth-based pavement 1 at a coating amount of 100 to 200 g / m 2 and dried to form the surface layer 2.

表3に示すコーティング剤により、実施例1と同様に土系舗装1上に表面層2を形成した。他の条件は実施例1と同様である。   A surface layer 2 was formed on the earth-based pavement 1 in the same manner as in Example 1 by using the coating agent shown in Table 3. Other conditions are the same as in the first embodiment.

Figure 2007205011
Figure 2007205011

表4に示すコーティング剤により、実施例1と同様に土系舗装1上に表面層2を形成した。他の条件は実施例1と同様である。   A surface layer 2 was formed on the earth-based pavement 1 in the same manner as in Example 1 by using the coating agent shown in Table 4. Other conditions are the same as in the first embodiment.

Figure 2007205011
Figure 2007205011

実施例4では、既に施工してあった土系舗装1上に実施例1のコーティング剤を塗布し、土系舗装1上に表面層2を形成した。他の条件は実施例1と同様である。なお、実施例2、3のコーティング剤を用いて表面層2を形成することも可能である。   In Example 4, the coating agent of Example 1 was applied on the soil-based pavement 1 that had already been constructed, and the surface layer 2 was formed on the soil-based pavement 1. Other conditions are the same as in the first embodiment. It is also possible to form the surface layer 2 using the coating agents of Examples 2 and 3.

(評価1)
種々のコーティング剤の原液について、収縮低減剤による影響を評価した。評価に用いたコーティング剤の成分及び溶剤を表2に示す。収縮低減剤はポリエーテル系界面活性剤(竹本油脂(株)製「ヒビダンB」)である。
(Evaluation 1)
The effects of shrinkage reducing agents were evaluated on stock solutions of various coating agents. Table 2 shows the components and solvents of the coating agent used in the evaluation. The shrinkage reducing agent is a polyether surfactant (“Hibidan B” manufactured by Takemoto Yushi Co., Ltd.).

造膜試験Aは、コーティング剤の原液のみでガラス板上に造膜し、その性状を観察したものである。No.2、3のコーティング剤の原液で評価が△であったのは、得られた膜の強度が不十分であったからである。また、No.7のコーティング剤の原液で評価が△であったのは、得られた膜がややべたついたからである。   Film formation test A is a film formed on a glass plate only with a stock solution of a coating agent, and its properties are observed. No. The reason for the evaluation of the two or three coating agent stock solutions was Δ was that the strength of the obtained film was insufficient. No. The reason why the coating solution of No. 7 was evaluated as Δ was that the obtained film was slightly sticky.

造膜試験Bは、コーティング剤の原液と収縮低減剤とを質量比10:1で混合し、この混合物でガラス板上に造膜し、その性状を観察したものである。No.1〜4、7の混合物で評価が△であったのは、得られた膜がべたついたからである。   In the film-forming test B, an undiluted coating agent solution and a shrinkage reducing agent were mixed at a mass ratio of 10: 1, a film was formed on a glass plate with this mixture, and the properties thereof were observed. No. The reason why the evaluation of the mixture of 1 to 4 and 7 was Δ was that the obtained film was sticky.

造膜試験Cは、コーティング剤の原液と収縮低減剤とを質量比10:8で混合し、この混合物でガラス板上に造膜し、その性状を観察したものである。評価×は硬化しなかったことを示す。No.9〜11、15、16、17、19、21〜23の混合物で評価が△であったのは、得られた膜がべたついたからである。No.14、18の混合物で評価が△であったのは、膜は固まるが、柔らかかったからである。   In the film-forming test C, a stock solution of a coating agent and a shrinkage reducing agent were mixed at a mass ratio of 10: 8, a film was formed on the glass plate with this mixture, and the properties thereof were observed. Evaluation x shows that it did not harden | cure. No. The reason why the evaluation was Δ in the mixture of 9 to 11, 15, 16, 17, 19, 21 to 23 was that the obtained film was sticky. No. The reason why the evaluation was Δ in the mixture of 14 and 18 was that the film was hardened but soft.

表2に示すように、各コーティング剤を用いて造膜後、1日経過後に収縮低減剤を表面から垂らし、その耐性試験も行った。評価×は膜が軟化し、液状化したことを示す。No.4、6、8、9、11〜14、18、20、21で評価が○であったのは、膜は爪で傷がつくだけで、十分な硬度だったからである。No.16で評価が△であったのは、膜が軟化したからである。   As shown in Table 2, the shrinkage reducing agent was hung from the surface after 1 day after film formation using each coating agent, and the resistance test was also performed. Evaluation x indicates that the film was softened and liquefied. No. The reason why the evaluation was “good” in 4, 6, 8, 9, 11-14, 18, 20, and 21 was that the film was scratched with a nail and had sufficient hardness. No. The evaluation at 16 was Δ because the film was softened.

以上の結果、No.4、6、9、11〜14、16、17、18〜21のコーティング剤、つまりアクリルシリコン系、ウレタン系又はエポキシシリコン系のコーティング剤を用いることが好ましいことがわかる。このため、図2に示すように、これらのコーティング剤により表面層2を形成すれば、土系舗装の通水性により、濃縮した収縮低減剤1aがその表面層2と接触しても、表面層2は好適に硬度を維持する。   As a result, no. It turns out that it is preferable to use the coating agent of 4, 6, 9, 11-14, 16, 17, 18-21, ie, an acrylic silicon type, urethane type, or an epoxy silicon type coating agent. For this reason, as shown in FIG. 2, if the surface layer 2 is formed with these coating agents, even if the concentrated shrinkage reducing agent 1a comes into contact with the surface layer 2 due to the water permeability of the earth-based pavement, the surface layer 2 suitably maintains the hardness.

特に、No.4、6のコーティング剤は、水系のアクリルシリコン系のものであることから、優れた作業性を呈し、好ましい。これは実施例1、2で得られる土系舗装が優れた作業性の下で施工され、かつクラックを発生し難く、白華による意匠性の低減及び粉塵等の発生の防止の効果も発揮できることの証である。   In particular, no. Since the coating agents 4 and 6 are water-based acrylic silicon-based, they exhibit excellent workability and are preferable. This is because the earth-based pavement obtained in Examples 1 and 2 is constructed under excellent workability, is less likely to generate cracks, and can also exhibit the effect of reducing design by white flower and preventing the generation of dust, etc. It is a proof of.

また、No.9、11〜14、16、17、18〜21のコーティング剤は有機溶剤系のものであることから、アクリルシリコン系、ウレタン系又はエポキシシリコン系において、優れた効果を発揮することもわかる。   No. Since the coating agents of Nos. 9, 11 to 14, 16, 17, and 18 to 21 are based on an organic solvent, it can be seen that an excellent effect is exhibited in an acrylic silicon type, a urethane type, or an epoxy silicon type.

以上において、本発明を実施例1〜4に即して説明したが、本発明は上記実施例1〜4に制限されるものではなく、その趣旨を逸脱しない範囲で適宜変更して適用できることはいうまでもない。   In the above, the present invention has been described with reference to the first to fourth embodiments. However, the present invention is not limited to the first to fourth embodiments, and can be appropriately modified and applied without departing from the spirit of the present invention. Needless to say.

第1、2発明は舗装、床等に利用可能である。   The first and second inventions can be used for pavements, floors and the like.

実施例1、2で用いた砂及び砕石廃土の粒度分布を示すグラフである。It is a graph which shows the particle size distribution of the sand used in Example 1, 2 and crushed stone waste soil. 実施例1、2の土系舗装及び表面層の模式断面図である。It is a schematic cross section of the earth-based pavement and the surface layer of Examples 1 and 2. 実施例1、2の土系舗装及び表面層の模式断面図である。It is a schematic cross section of the earth-based pavement and the surface layer of Examples 1 and 2.

Claims (6)

土と、セメント及び/又は消石灰とが混合されてなる土系舗装用調合物を調製する調製工程と、
該土系舗装用調合物に水を混合して舗装材とし、該舗装材を舗装場所に敷きならし、転圧及び養生して土系舗装とする舗装工程とを備えた土系舗装の施工方法において、
前記土は粒径75μm以下の粒子が2〜30質量%であり、前記土系舗装用調合物が界面活性剤系の収縮低減剤を含む場合、前記土系舗装上にアクリルシリコン系、ウレタン系又はエポキシシリコン系のコーティング剤からなる表面層を形成するコーティング工程を行なうことを特徴とする土系舗装の施工方法。
A preparation step for preparing a soil-based pavement composition in which soil and cement and / or slaked lime are mixed;
Construction of earth-based pavement comprising mixing the water for the earth-based pavement composition into a pavement material, laying the pavement material on the pavement site, and rolling and curing to make the earth-based pavement. In the method
In the case where the soil has a particle size of 2 to 30% by mass with a particle size of 75 μm or less, and the soil-based paving preparation contains a surfactant-based shrinkage reducing agent, an acrylic silicon-based or urethane-based material is formed on the soil-based paving. Or the construction method of the earth-based pavement characterized by performing the coating process which forms the surface layer which consists of an epoxy silicon type coating agent.
前記コーティング剤は水系のアクリルシリコン系のものである請求項1記載の土系舗装の施工方法。   The method for constructing a soil-based pavement according to claim 1, wherein the coating agent is a water-based acrylic silicon-based one. 前記コーティング剤は有機溶剤系のものである請求項1記載の土系舗装の施工方法。   The method for constructing an earth-based pavement according to claim 1, wherein the coating agent is an organic solvent-based one. 土と、セメント及び/又は消石灰とが混合されてなる土系舗装用調合物に水が混合されて舗装材とされ、該舗装材が舗装場所に敷きならされ、転圧及び養生されて形成された土系舗装へのコーティング方法であって、
前記土は粒径75μm以下の粒子が2〜30質量%であり、前記土系舗装用調合物が界面活性剤系の収縮低減剤を含む場合、前記土系舗装上にアクリルシリコン系、ウレタン系又はエポキシシリコン系のコーティング剤からなる表面層を形成するコーティング工程を行なうことを特徴とする土系舗装へのコーティング方法。
Water is mixed with an earth-based paving composition in which soil and cement and / or slaked lime are mixed to form a paving material, and the paving material is laid on the paving site, and is formed by rolling and curing. A method for coating a soil-based pavement,
In the case where the soil has a particle size of 2 to 30% by mass with a particle size of 75 μm or less, and the soil-based paving preparation contains a surfactant-based shrinkage reducing agent, an acrylic silicon-based or urethane-based material is formed on the soil-based paving. Or the coating method to the earth-type pavement characterized by performing the coating process which forms the surface layer which consists of an epoxy silicon type coating agent.
前記コーティング剤は水系のアクリルシリコン系のものである請求項4記載の土系舗装へのコーティング方法。   The method for coating a soil-based pavement according to claim 4, wherein the coating agent is a water-based acrylic silicon-based one. 前記コーティング剤は有機溶剤系のものである請求項1記載の土系舗装へのコーティング方法。   The method for coating a soil-based pavement according to claim 1, wherein the coating agent is based on an organic solvent.
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