JP2007191379A - Hydrogen generator and vessel for hydrogen generator - Google Patents

Hydrogen generator and vessel for hydrogen generator Download PDF

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JP2007191379A
JP2007191379A JP2006039977A JP2006039977A JP2007191379A JP 2007191379 A JP2007191379 A JP 2007191379A JP 2006039977 A JP2006039977 A JP 2006039977A JP 2006039977 A JP2006039977 A JP 2006039977A JP 2007191379 A JP2007191379 A JP 2007191379A
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hydrogen generator
water
hydrogen
solid
cover
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JP5115779B2 (en
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Kenichi Sunamoto
健市 砂本
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AKANE KK
Akane Co Ltd
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AKANE KK
Akane Co Ltd
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a hydrogen generator by which hydrogen is inexpensively produced and is efficiently incorporated in water. <P>SOLUTION: The hydrogen generator is formed by providing a Ca solid obtained by compacting Ca powder in the case main body and a mesh like cover on the upper surface of the Ca solid. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、主に風呂の中にいれ、水素を発生させ、水素水を製造する水素発生器及び水素発生器用容器に関するものである。  The present invention relates to a hydrogen generator and a hydrogen generator container for producing hydrogen water by mainly entering a bath to generate hydrogen.

従来の技術としては、水をマグネシウムに接触させ、水との反応で水素ガスが発生する際に活性水素を水に混入させ、酸化還元電位の低い活性水素水を製造するものがある。（特許文献１参照）  As a conventional technique, there is a technique in which water is brought into contact with magnesium, and active hydrogen is mixed into water when hydrogen gas is generated by reaction with water to produce active hydrogen water having a low oxidation-reduction potential. (See Patent Document 1)

また、別の従来技術として、マグネシュウム金属容器を設け、内容物の大きさ以下の窓を設け、内容物としてマグネシュウム金属と、トルマリン鉱石を封じ込めた構造のものがある。（特許文献２参照）
特開２００４−３３００２８号公報 特開２００２−３３６８７７号公報 As another conventional technique, there is a structure in which a magnesium metal container is provided, a window having a size smaller than the size of the contents is provided, and the contents of magnesium metal and tourmaline ore are contained as contents. (See Patent Document 2)
JP 2004-330028 A JP 2002-336877 A

上記の各従来技術は、マグネシウムを主体として作られている。
周知のとおり、マグネシウムは発火し易い物質であり、特に加工時においては、安全な設備等を必要とする。
また、高価な物質であり、コスト的にも高くつくものである。Each of the above prior arts is made mainly of magnesium.
As is well known, magnesium is a substance that easily ignites, and requires safe equipment, especially during processing.
Moreover, it is an expensive substance and expensive.

本発明は、上記の問題点に鑑みなされたもので、その目的は、安価に製造できると共に、効率よく水素を水（湯）の中に混入することのできる水素発生器を提供するものである。  The present invention has been made in view of the above-described problems, and an object of the present invention is to provide a hydrogen generator that can be manufactured at low cost and can efficiently mix hydrogen into water (hot water). .

本発明は、上記目的を達成するために、水素発生器においては、ケース本体に、Ｃａの粉末を圧縮したＣａ固形を設け、該Ｃａ固体の上面にメッシュ状のカバーを設けてなる。
また、ケース本体の内部をポーラス状にしてなる。
さらに、ケース本体の内部に水を引き込むための布を設けてなる。
そして、カバーをステンレス製とし、使用時に浮上しない重さとする。
さらにまた、ケース本体の中心部にＣａ固体を設け、該Ｃａ固体の周囲全体をポーラス状に形成してなる。
水素発生器用容器においては、開閉自在な容器の蓋の一部に通孔を設け、該通孔に水が流通するカバーを設けると共に、内部に弾性体を設けてなることを特徴とする。In order to achieve the above object, according to the present invention, in a hydrogen generator, a case solid is provided with a Ca solid obtained by compressing Ca powder, and a mesh-like cover is provided on the upper surface of the Ca solid.
Moreover, the inside of the case body is made porous.
Further, a cloth for drawing water into the case body is provided.
The cover is made of stainless steel and does not lift when used.
Furthermore, a Ca solid is provided at the center of the case body, and the entire periphery of the Ca solid is formed in a porous shape.
The hydrogen generator container is characterized in that a through hole is provided in a part of the lid of the openable / closable container, a cover through which water flows is provided, and an elastic body is provided inside.

１）、水素発生器においては、ケース本体に、Ｃａの粉末を圧縮したＣａ固形を設け、該Ｃａ固体の上面にメッシュ状のカバーを設けることにより、水（湯）の中でＣａが徐々に反応し、水素ガスを発生し、水（湯）の中に水素ガスを混入（溶解）することができ、水素水として美肌等に効果を有するものである。
２）、ケース本体の内部をポーラス状にすることにより、水（湯）が徐々に入り込みより効率よくＣａと反応し、水素水を作ることができる。
３）、布を設けることにより、水をケース本体の内部（ポーラス状）に引き込むことができ、反応をより効率よく行うことができる。
４）、カバーをメッシュ状にすることにより、泡を小さくでき、より効率よく水素水を作ることができる。
５）、カバーをステンレス製とし、適度な重さとすることにより、浮上することなく使用でき、風呂（容器）の底で、最後まで反応するものである。
６）、Ｃａ固体の周囲全体をポーラス状に形成することにより、水（湯）が徐々に入っていくため、時間をある程度掛けて反応させるのに有効である。
７）、水素発生器用容器においては、弾性体により、水素発生器の上面をカバーに密着して使用できるため、反応をより遅くすることができ、長時間使用する場合に有効である。1) In the hydrogen generator, the case main body is provided with a Ca solid obtained by compressing Ca powder, and a mesh-like cover is provided on the upper surface of the Ca solid so that the Ca is gradually contained in water (hot water). It reacts, generates hydrogen gas, can mix (dissolve) hydrogen gas in water (hot water), and has an effect on skin and the like as hydrogen water.
2) By making the inside of the case body porous, water (hot water) gradually enters and reacts with Ca more efficiently, and hydrogen water can be produced.
3) By providing a cloth, water can be drawn into the inside of the case body (porous), and the reaction can be performed more efficiently.
4) By making the cover mesh-shaped, bubbles can be made smaller and hydrogen water can be made more efficiently.
5) Since the cover is made of stainless steel and has an appropriate weight, it can be used without rising and reacts at the bottom of the bath (container) to the end.
6) Since the entire periphery of the Ca solid is formed in a porous shape, water (hot water) gradually enters, so that it is effective for taking a certain amount of time for reaction.
7) In the hydrogen generator container, the elastic body can be used with the upper surface of the hydrogen generator in close contact with the cover, so that the reaction can be made slower, which is effective when used for a long time.

水素発生器１は、樹脂等によるケース本体２の外側をやや硬く形成し、内部をポーラス状２ａにしてなる樹脂等によるケース本体２に、Ｃａ（カルシウム）の粉末を圧縮したＣａ固形３を設け、該Ｃａ固形３の上面に、ステンレス製等によるメッシュ状のカバー４をケース本体２と一体に連結してある。  The hydrogen generator 1 is provided with a Ca solid 3 obtained by compressing Ca (calcium) powder in a case body 2 made of a resin or the like that is made of a resin 2 or the like and has a porous shape 2a. A mesh-shaped cover 4 made of stainless steel or the like is integrally connected to the case main body 2 on the upper surface of the Ca solid 3.

上記水素発生器１の使用例について下記に述べる。
湯Ｙを入れた風呂Ｆに水素発生器１を投入することにより、底面ＴにてＣａ固形３がカバー４を通過した水（湯Ｙ）と反応し、水素Ｓを発生すると共に、ポーラス状２ａに水（湯Ｙ）が浸入し、Ｃａ固形３の側面及び裏面とも反応し、水素Ｓ１を発生させることができるものである。An example of use of the hydrogen generator 1 will be described below.
By introducing the hydrogen generator 1 into the bath F containing the hot water Y, the Ca solid 3 reacts with the water (hot water Y) that has passed through the cover 4 at the bottom T to generate hydrogen S and the porous 2a. Water (hot water Y) enters and reacts with the side surface and back surface of the Ca solid 3 to generate hydrogen S1.

この時、カバー４を通過して水素Ｓ・Ｓ１が発生するため、小さな気泡となり、より効率よく水（湯Ｙ）と混合し、溶解できるもので、純度の高い水素水を得ることができる。  At this time, since hydrogen S · S1 is generated through the cover 4, it becomes a small bubble, can be mixed and dissolved more efficiently with water (hot water Y), and high-purity hydrogen water can be obtained.

つぎに、Ｃａ固形３と水（湯Ｙ）が反応して水素Ｓ・Ｓ１を発生させるメカニズムについて述べる。
カルシウムＣａと水Ｈ２Ｏは加水分解してカルシウムイオンと水素イオンと水酸イオンになる。カルシウムと水酸イオンは化合して水酸化カルシウムＣａ（ＯＨ）２という中和塩を作る。
水酸化カルシウムは水に溶解しにくい。２０℃における水１Ｌへの溶解度は１６００ｍｇ／Ｌである。残りの水酸化カルシウムはスラリになって沈殿する。溶解した水酸化カルシウムは加水分解するのでＣａ（ＯＨ）２⇔Ｃａ２＋２ＯＨ−カルシウムイオンと水酸イオンになる。
水酸イオン２ＯＨ−と水素陽イオン２Ｈ＋は化合して水を生成すると共に水を水酸イオン水（すなわちアルカリ水）化し、水素（ガス）Ｈ２を発生する。Next, a mechanism by which Ca solid 3 and water (hot water Y) react to generate hydrogen S · S1 will be described.
Calcium Ca and water H 2 O are hydrolyzed to calcium ions, hydrogen ions, and hydroxide ions. Calcium and hydroxide ions combine to form a neutralized salt called calcium hydroxide Ca (OH) 2 .
Calcium hydroxide is difficult to dissolve in water. The solubility in 1 L of water at 20 ° C. is 1600 mg / L. The remaining calcium hydroxide becomes a slurry and precipitates. Comprising calcium ions and hydroxide ions - dissolution of calcium hydroxide was the Ca (OH) 2 ⇔Ca 2+ 2OH Because hydrolysis.
Hydroxide ion 2OH − and hydrogen cation 2H + combine to generate water, and water is converted to hydroxide ion water (ie, alkaline water) to generate hydrogen (gas) H 2 .

次に、第２実施例の水素発生器について述べる。
水素発生器２１は、上記と同様な形態に加え、ケース本体２への内部（ポーラス状２２ａ）に水（湯）を引き込むための布５を設けてなるものである。Next, the hydrogen generator of the second embodiment will be described.
In addition to the same form as described above, the hydrogen generator 21 is provided with a cloth 5 for drawing water (hot water) into the case body 2 (porous shape 22a).

つづいて、第３実施例の水素発生器について述べる。
水素発生器３１は、樹脂製等によるケース本体３２の中心部にＣａ固体３３を設け、該Ｃａ固体３３の周囲全体を樹脂製等によりポーラス状３２ａに形成してなるものである。Next, the hydrogen generator of the third embodiment will be described.
The hydrogen generator 31 is formed by providing a Ca solid 33 in the center of a case body 32 made of resin or the like, and forming the entire periphery of the Ca solid 33 into a porous shape 32a by resin or the like.

最後に、水素発生器用容器について述べる。
水素発生器用容器１０は、合成樹脂製等による開閉自在な容器１０ａの蓋１０ａ１の中央部に通孔１０ａ２を設け、該通孔１０ａ２に水（湯）が流通すべく金網、布、スポンジ等によるカバー１０ａ３を設けると共に、容器１０ａの底部にスポンジあるいはバネ等による弾性体１０ｂを設けてなるものである。Finally, the hydrogen generator container will be described.
The container 10 for hydrogen generator is provided with a through hole 10a2 at the center of a lid 10a1 of a container 10a that can be opened and closed made of synthetic resin or the like. A cover 10a3 is provided, and an elastic body 10b made of a sponge or a spring is provided at the bottom of the container 10a.

上記水素発生器用容器１０の使用例を下記に述べる。
まず、水素発生器用容器１０の蓋１０ａ１を開き、中に例えば上記水素発生器３１を入れる。
つづいて、蓋１０ａ１を締めることにより、弾性体１０ｂにより水素発生器３１は上方に押され、上面がカバー１０ａ３に当接して保持される。
この状態で、水中に投入することにより、カバー１０ａ３から水（湯）が流入し、反応するものである。
なお、使用後は再度蓋１０ａ１を開き、水素発生器３１を取り出し、再度新品を入れ、何度でも使用できるものである。Examples of use of the hydrogen generator container 10 will be described below.
First, the lid 10a1 of the hydrogen generator container 10 is opened, and, for example, the hydrogen generator 31 is placed therein.
Subsequently, by tightening the lid 10a1, the hydrogen generator 31 is pushed upward by the elastic body 10b, and the upper surface is held in contact with the cover 10a3.
In this state, by pouring into water, water (hot water) flows from the cover 10a3 and reacts.
After use, the lid 10a1 is opened again, the hydrogen generator 31 is taken out, a new one is inserted again, and it can be used any number of times.

上記実施例において、ケース本体の材質、大きさやＣａ固形の量（大きさ）等は必要に応じて決めればよい。
また、カバーのメッシュも、例えば＃２００とするが、特に限定するものではない。In the above embodiment, the material and size of the case main body and the amount (size) of Ca solid may be determined as necessary.
Also, the mesh of the cover is, for example, # 200, but is not particularly limited.

本発明の第１実施例の水素発生器を示す縦断正面図。1 is a longitudinal front view showing a hydrogen generator according to a first embodiment of the present invention. 本発明の第１実施例の水素発生器を示す平面図。The top view which shows the hydrogen generator of 1st Example of this invention. 本発明の第１実施例の水素発生器を示す使用状態の縦断正面図。BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a longitudinal front view of a use state showing a hydrogen generator of a first embodiment of the present invention. 本発明の第２実施例の水素発生器を示す縦断正面図。The longitudinal section front view showing the hydrogen generator of the 2nd example of the present invention. 本発明の第３実施例の水素発生器を示す縦断正面図。The longitudinal cross-sectional front view which shows the hydrogen generator of 3rd Example of this invention. 本発明の一実施例を示す水素発生器用容器を示す一部縦断正面図。1 is a partially longitudinal front view showing a hydrogen generator container according to an embodiment of the present invention. 本発明の一実施例を示す水素発生器用容器の使用状態を示す一部縦断面図。The partial longitudinal cross-sectional view which shows the use condition of the container for hydrogen generators which shows one Example of this invention.

符号の説明Explanation of symbols

１−−−−水素発生器
２−−−−ケース本体
２ａ−−−ポーラス状
３−−−−Ｃａ固形
４−−−−カバー
５−−−−布
１０−−−水素発生器用容器
１０ａ−−容器
１０ａ１−蓋
１０ａ２−通孔
１０ａ３−カバー
１０ｂ−−弾性体
Ｙ−−−−湯
Ｆ−−−−風呂
Ｔ−−−−底面
Ｓ−−−−水素1 ---- Hydrogen generator 2 ---- Case body 2a --- Porous shape 3 ---- Ca solid 4 ---- Cover 5 ---- Cloth 10 --- Hydrogen generator container 10a- -Container 10a1- Lid 10a2- Through-hole 10a3- Cover 10b- Elastic body Y ---- Hot water F ---- Bath T ---- Bottom S ---- Hydrogen

Claims (6)

ケース本体に、Ｃａの粉末を圧縮したＣａ固形を設け、該Ｃａ固体の上面にメッシュ状のカバーを設けてなることを特徴とする水素発生器。  A hydrogen generator comprising: a case main body provided with a Ca solid obtained by compressing Ca powder; and a mesh-like cover provided on an upper surface of the Ca solid. ケース本体の内部をポーラス状にしてなることを特徴とする請求項１記載の水素発生器。  2. The hydrogen generator according to claim 1, wherein the inside of the case body is made porous. ケース本体の内部に水を引き込むための布を設けてなることを特徴とする請求項１又は２記載の水素発生器。  The hydrogen generator according to claim 1 or 2, wherein a cloth for drawing water is provided inside the case body. カバーをステンレス製とし、使用時に浮上しない重さとすることを特徴とする請求項１、２又は３記載の水素発生器。  The hydrogen generator according to claim 1, 2, or 3, wherein the cover is made of stainless steel and has a weight that does not float during use. ケース本体の中心部にＣａ固体を設け、該Ｃａ固体の周囲全体をポーラス状に形成してなることを特徴とする水素発生器。  A hydrogen generator, characterized in that a Ca solid is provided at the center of a case body, and the entire periphery of the Ca solid is formed in a porous shape. 開閉自在な容器の蓋の一部に通孔を設け、該通孔に水が流通するカバーを設けると共に、内部に弾性体を設けてなることを特徴とする水素発生器用容器。  A container for a hydrogen generator, wherein a through hole is provided in a part of a lid of an openable / closable container, a cover through which water flows is provided, and an elastic body is provided therein.
JP2006039977A 2006-01-20 2006-01-20 Hydrogen generator and hydrogen generator container Expired - Fee Related JP5115779B2 (en)

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JP2011032148A (en) * 2009-08-05 2011-02-17 Aquafairy Kk Hydrogen-generating agent, method for producing the same, and method for generating hydrogen
ITMI20130305A1 (en) * 2013-02-28 2014-08-29 Eliodoro Pomar SYSTEM FOR SEPARATING THE HYDROGEN FROM OXYGEN CONTAINED IN WATER
JP2017078009A (en) * 2015-10-19 2017-04-27 株式会社アカネ Hydrogen generator
JP2019193703A (en) * 2018-05-01 2019-11-07 浩章 皆川 In-bath hydrogen generation device and in-bath hydrogen generation method with hydrogen generation agent storage device

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JP2011032148A (en) * 2009-08-05 2011-02-17 Aquafairy Kk Hydrogen-generating agent, method for producing the same, and method for generating hydrogen
ITMI20130305A1 (en) * 2013-02-28 2014-08-29 Eliodoro Pomar SYSTEM FOR SEPARATING THE HYDROGEN FROM OXYGEN CONTAINED IN WATER
JP2017078009A (en) * 2015-10-19 2017-04-27 株式会社アカネ Hydrogen generator
JP2019193703A (en) * 2018-05-01 2019-11-07 浩章 皆川 In-bath hydrogen generation device and in-bath hydrogen generation method with hydrogen generation agent storage device

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