JP2007111042A - Method and apparatus for preserving green tea beverage packed in transparent container - Google Patents

Method and apparatus for preserving green tea beverage packed in transparent container Download PDF

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JP2007111042A
JP2007111042A JP2006255732A JP2006255732A JP2007111042A JP 2007111042 A JP2007111042 A JP 2007111042A JP 2006255732 A JP2006255732 A JP 2006255732A JP 2006255732 A JP2006255732 A JP 2006255732A JP 2007111042 A JP2007111042 A JP 2007111042A
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green tea
light
tea beverage
green
storage
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JP4655014B2 (en
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Toshihiro Tanabe
利裕 田辺
Kaori Higuchi
香織 樋口
Yoshio Aoyama
好男 青山
Takako Goto
隆子 後藤
Fumi Okiura
文 沖浦
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Toyo Seikan Group Holdings Ltd
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Toyo Seikan Kaisha Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for preserving green tea beverage packed in a transparent container, capable of showing sufficient browning decreasing effect by an easy and low-cost method; and to provide an apparatus for preserving the green tea beverage. <P>SOLUTION: This method for preserving the green tea beverage packed in a transparent container comprises irradiating green tea beverage colored light or white light which contains wavelength component of 495-505 nm at an irradiance of ≥2 μW/mL in cold preservation and ≥15 μW/mL in a heating condition of ≥50°C at an integrated value of radiant flux of 495-505 nm. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、PETボトル等透明容器詰緑茶飲料を販売するためショーケース、ウオーマ等において透明容器詰緑茶飲料を保存中に発生する褐変を低減することができる透明容器詰緑茶飲料の保存方法および保存装置に関する。   The present invention relates to a storage method and storage of a transparent container-packed green tea beverage capable of reducing browning that occurs during storage of the transparent container-packed green tea beverage in a showcase, a wamer, etc. for selling transparent container-packed green tea beverages such as PET bottles. Relates to the device.

従来PETボトル等透明容器詰め緑茶飲料を保存する場合は、保存中の褐変が進行するのを低減するために、低温で保存したり、酸素バリヤー性や酸素吸収性を賦与した容器を使用する等の方法が採られている。また、特許文献1には茶飲料にトレハロースを添加することにより茶飲料の褐変を防止する方法が開示されている。   Conventionally, when storing green tea beverages packed in transparent containers such as PET bottles, in order to reduce the progress of browning during storage, it is stored at a low temperature, or a container with an oxygen barrier property or oxygen absorption property is used. The method is adopted. Patent Document 1 discloses a method for preventing browning of a tea beverage by adding trehalose to the tea beverage.

しかしながら、これらの方法は褐変低減効果がなお充分でないか、あるいは飲料の製造等にコストが嵩むなどの問題点がある。
特開2001−112414号公報
However, these methods have a problem that the effect of reducing browning is not yet sufficient, or the production of beverages is expensive.
JP 2001-112414 A

本発明は、従来技術の問題点にかんがみなされたものであって、簡単で低コストな方法で充分な褐変低減効果を奏することができる透明容器詰緑茶飲料の保存方法および保存装置を提供しようとするものである。   The present invention has been considered in view of the problems of the prior art, and is intended to provide a storage method and storage device for a transparent container-packed green tea beverage that can exhibit a sufficient browning reduction effect by a simple and low-cost method. To do.

本発明者等は、上記発明の目的を達成するための実験と研究を重ねる過程において、保存中の透明容器詰緑茶飲料に緑色光を照射すると、従来のように低温保存でなく、常温または加温下での保存であっても、褐変の進行を見かけ上有効に低減できることを見出し、またこの現象は緑色光に限らず青色光等赤色光以外の着色光でも観察され、さらに白色光でも通常の蛍光灯の照度を超える1000Lux以上の高い照度で照射すれば同様に褐変低減効果が奏されることを見出した。そしてさらに実験と研究を重ねた結果、495〜505nmの放射束の積算値で常温保存の場合2μW/mL以上、50℃以上の加温下での保存の場合15μW/mL以上の放射照度で495〜505nmの波長成分を含む有色光または白色光を緑茶飲料に照射すると、有効かつ確実に褐変低減効果が奏されることを見出し、本発明に到達した。従来緑茶を保存するための技術においては、たとえば茶葉を日光に当てると日光臭を生じる等、一般に緑茶に光を当てると劣化が生じるという考えが常識であり、緑茶飲料に着色光や強い白色光を照射することにより劣化を生じることなく褐変の進行を低減できるということは、まったく意外な発見であった。   In the process of repeating experiments and research to achieve the object of the present invention, the present inventors, when irradiated with green light to a transparent container-packed green tea beverage being stored, are not stored at low temperature as in the prior art, but at room temperature or It has been found that even when stored at a low temperature, the progress of browning can be effectively reduced, and this phenomenon is observed not only with green light but also with colored light other than red light such as blue light, and even with white light. It was found that the effect of reducing browning can be achieved by irradiating at a high illuminance of 1000 Lux or more exceeding the illuminance of the fluorescent lamp. As a result of further experimentation and research, the accumulated value of the radiant flux of 495 to 505 nm is 495 at an irradiance of 2 μW / mL or more when stored at room temperature and 15 μW / mL or more when stored at 50 ° C. or higher. It has been found that when a green tea beverage is irradiated with colored light or white light containing a wavelength component of ˜505 nm, the browning reduction effect is effectively and reliably achieved, and the present invention has been achieved. Conventionally, in the technology for preserving green tea, it is common sense that when tea leaves are exposed to sunlight, a odor of sunlight is generally generated, which causes deterioration when exposed to green tea. It was a surprising discovery that the progress of browning can be reduced without causing deterioration by irradiation.

本発明の目的を達成する第1の構成は、透明容器詰緑茶飲料の常温での保存中495〜505nmの放射束の積算値で2μW/mL以上の放射照度で495〜505nmの波長成分を含む有色光または白色光を該緑茶飲料に照射することを特徴とする透明容器詰緑茶飲料の保存方法である。   A first configuration for achieving the object of the present invention includes a wavelength component of 495 to 505 nm at an irradiance of 2 μW / mL or more as an integrated value of radiant flux of 495 to 505 nm during storage at room temperature of a green tea beverage packed in a transparent container. A method for preserving a green tea beverage in a transparent container, characterized in that the green tea beverage is irradiated with colored light or white light.

本発明の第2の構成は、該有色光の放射照度4μW/mL以上であることを特徴とする第1の構成の保存方法である。   A second configuration of the present invention is the storage method according to the first configuration, wherein the colored light has an irradiance of 4 μW / mL or more.

本発明の第3の構成は、該有色光は、480〜540nmの波長成分を有する青ー緑色光であることを特徴とする構成1または2の保存方法である。   The third configuration of the present invention is the storage method according to the first or second configuration, wherein the colored light is blue-green light having a wavelength component of 480 to 540 nm.

本発明の第4の構成は、該白色光の照度は1000Lux以上であることを特徴とする第1の構成の保存方法である。   A fourth configuration of the present invention is the storage method according to the first configuration, wherein the illuminance of the white light is 1000 Lux or more.

本発明の第5の構成は、透明容器詰緑茶飲料の50℃以上の加温下での保存中495〜505nmの放射束の積算値で15μW/mL以上の放射照度で495〜505nmの波長成分を含む有色光または白色光を該緑茶飲料に照射することを特徴とする透明容器詰緑茶飲料の保存方法である。   The fifth configuration of the present invention is a wavelength component of 495 to 505 nm with an irradiance of 15 μW / mL or more with an integrated value of radiant flux of 495 to 505 nm during storage of a transparent container-packed green tea beverage under heating at 50 ° C. or more. A method for preserving a transparent container-packed green tea beverage, wherein the green tea beverage is irradiated with colored light or white light containing

本発明の第6の構成は、該有色光の放射照度は30μW/mL以上であることを特徴とする第5の構成の保存方法である。   A sixth configuration of the present invention is the storage method according to the fifth configuration, wherein the irradiance of the colored light is 30 μW / mL or more.

本発明の第7の構成は、該有色光は、480〜540nmの波長成分を有する青ー緑色光であることを特徴とする第5または6の構成の保存方法である。   A seventh configuration of the present invention is the storage method according to the fifth or sixth configuration, wherein the colored light is blue-green light having a wavelength component of 480 to 540 nm.

本発明の第8の構成は、該白色光の照度は5000Lux以上であることを特徴とする第5の構成の透明容器詰緑茶飲料の保存方法。   According to an eighth configuration of the present invention, the illuminance of the white light is 5000 Lux or more, and the method for preserving a transparent container-packed green tea beverage according to the fifth configuration.

本発明の第9の構成は、透明容器詰緑茶飲料を常温保存する保存室と、該保存室内に設けられ、該緑茶飲料の保存中495〜505nmの放射束の積算値で2μW/mL以上の放射照度で495〜505nmの波長成分を含む有色光または白色光を該緑茶飲料に照射する手段とを備えることを特徴とする透明容器詰緑茶飲料保存装置である。   The ninth configuration of the present invention is a storage room for storing a transparent container-packed green tea beverage at room temperature, and is provided in the storage chamber, and the accumulated value of radiant flux of 495 to 505 nm during storage of the green tea beverage is 2 μW / mL or more. And a means for irradiating the green tea beverage with colored light or white light containing a wavelength component of 495 to 505 nm in irradiance.

本発明の第10の構成は、該有色光の放射照度は4μW/mL以上であることを特徴とする第9の構成の保存装置である。   A tenth configuration of the present invention is the storage device according to the ninth configuration, wherein the irradiance of the colored light is 4 μW / mL or more.

本発明の第11の構成は、該有色光は、480〜540nmの波長成分を有する青―緑色光であることを特徴とする第9または10の構成の保存装置である。   An eleventh aspect of the present invention is the storage device according to the ninth or tenth aspect, wherein the colored light is blue-green light having a wavelength component of 480 to 540 nm.

本発明の第12の構成は、該白色光の照度は1000Lux以上であることを特徴とする第9の構成の保存装置である。   A twelfth configuration of the present invention is the storage device according to the ninth configuration, wherein the illuminance of the white light is 1000 Lux or more.

本発明の第13の構成は、透明容器詰緑茶飲料を50℃以上の加温下で保存する保存室と、該保存室内に設けられ、該緑茶飲料の保存中495〜505nmの放射束の積算値で15μW/mL以上の放射照度で495〜505nmの波長成分を含む有色光または白色光を該緑茶飲料に照射する手段とを備えることを特徴とする透明容器詰緑茶飲料保存装置である。   The thirteenth configuration of the present invention is a storage room for storing a transparent container-packed green tea beverage under heating at 50 ° C. or higher, and an accumulation of 495 to 505 nm radiant flux during storage of the green tea beverage. And a means for irradiating the green tea beverage with colored light or white light containing a wavelength component of 495 to 505 nm with an irradiance of 15 μW / mL or more in value.

本発明の第14の構成は、該有色光の放射照度は30μW/mL以上であることを特徴とする第13の構成の保存装置である。   A fourteenth configuration of the present invention is the storage device according to the thirteenth configuration, wherein the irradiance of the colored light is 30 μW / mL or more.

本発明の第15の構成は、該有色光は、480〜540nmの波長成分を有する青―緑色光であることを特徴とする第13または14の構成の保存装置である。   A fifteenth configuration of the present invention is the storage device according to the thirteenth or fourteenth configuration, wherein the colored light is blue-green light having a wavelength component of 480 to 540 nm.

本発明の第16の構成は、該白色光の照度は5000Luxであることを特徴とする第13の構成の保存装置である。   A sixteenth configuration of the present invention is the storage device according to the thirteenth configuration, wherein the illuminance of the white light is 5000 Lux.

上記各構成に係る発明によれば、簡単で低コストな方法および装置により、緑茶飲料の風味に悪影響を与えることなく透明容器詰緑茶飲料の保存中の褐変の進行を有意に低減することができる。   According to the invention according to each of the above-described configurations, the progress of browning during storage of the transparent container-packed green tea beverage can be significantly reduced without adversely affecting the flavor of the green tea beverage by a simple and low-cost method and apparatus. .

また、着色光が495〜505nmの波長成分を常温保存中で2μW/mL以上、50℃以上の加温下で保存中で5μW/mL以上含む緑色である構成においては、褐変低減効果に加えて、緑茶飲料製品がショーケース等により店頭に陳列されている場合における製品の見栄えを良くする効果があり、特に好ましい。   In addition, in the configuration in which the colored light is a green component containing a wavelength component of 495 to 505 nm at 2 μW / mL or more during storage at normal temperature and 5 μW / mL or more during storage under heating at 50 ° C. or more, in addition to the browning reduction effect The green tea beverage product is particularly preferable because it has the effect of improving the appearance of the product when it is displayed at a storefront by a showcase or the like.

以下添付図面を参照して本発明の実施の形態について説明する。
本発明の保存方法の対象はPETボトルやガラスびん等の透明容器に充填されショーケース、ウオーマ、自動販売機等に収容され保存される容器詰緑茶飲料である。容器の内容物である緑茶飲料は、緑茶の茶葉を熱水等により抽出して得られた抽出液またはその希釈液である。
Embodiments of the present invention will be described below with reference to the accompanying drawings.
The object of the preservation method of the present invention is a packaged green tea beverage that is filled in a transparent container such as a PET bottle or a glass bottle and stored and stored in a showcase, a warmer, a vending machine, or the like. The green tea beverage as the contents of the container is an extract obtained by extracting green tea leaves with hot water or the like, or a diluted solution thereof.

本発明は、透明容器詰緑茶飲料に光を照射することにより褐変の進行を低減することを特徴とするものであるが、照射すべき光としては、495〜505nmの放射束の積算値で常温保存の場合2μW/mL以上の放射照度が得られない光たとえば赤色光や紫外線は不適当である。本発明においては、495〜505nmの放射束の積算値で常温保存の場合2μW/mL以上、好ましくは4μW/mL以上、50℃以上の加温下での保存の場合15μW/mL以上、好ましくは30μW/mL以上の波長成分を含む光を照射すれば、褐変低減効果を奏することが実験の結果判明したので、このような着色光が本発明において照射する光として適当である。特に緑色光は、PETボトル等の透明容器詰緑茶飲料がショーケース等店頭に陳列されている場合に製品の見栄えを良くする効果があるので、もっとも好ましい着色光である。   The present invention is characterized in that the progress of browning is reduced by irradiating light to a transparent container-packed green tea beverage, and the light to be irradiated is normal temperature with an integrated value of 495 to 505 nm radiant flux. In the case of storage, light that cannot provide irradiance of 2 μW / mL or more, such as red light or ultraviolet light, is inappropriate. In the present invention, the integrated value of radiant flux of 495 to 505 nm is 2 μW / mL or more when stored at room temperature, preferably 4 μW / mL or more, preferably 15 μW / mL or more when stored at a temperature of 50 ° C. or more, preferably As a result of experiments, it has been found that if a light containing a wavelength component of 30 μW / mL or more is irradiated, the effect of reducing browning is found. As a result, such colored light is suitable as light to be irradiated in the present invention. In particular, green light is the most preferred colored light because it has an effect of improving the appearance of the product when a transparent container-packed green tea beverage such as a PET bottle is displayed in a store such as a showcase.

透明容器詰緑茶飲料のショーケース等における保存期間を12週間とした場合に保存中の容器詰緑茶飲料に照射する着色光の放射照度は、充分な褐変低減効果を奏するためにボトル肩部において常温での保存中は0.2mW/cm以上必要であり、50℃以上の加温下での保存中は1.0mW/cm2以上必要である。これらの放射照度未満では上記保存期間中に褐変が生じ進行する。 The irradiance of the colored light irradiating the stored green tea beverage during storage in a showcase of a transparent container packed green tea beverage is 12 weeks at room temperature at the bottle shoulder to achieve a sufficient browning reduction effect. During storage at a temperature of 0.2 mW / cm 2 or more is required, and during storage at a temperature of 50 ° C. or higher, 1.0 mW / cm 2 or more is required. Below these irradiances, browning occurs and proceeds during the storage period.

白色光でも、透明容器詰緑茶飲料を12週間常温で保存した場合に、通常ショーケース等で使用されている蛍光灯による照明の照度を超える1000Lux以上の照度で透明容器詰緑茶飲料に対し白色光を照射すると、着色光と同様の褐変低減効果があることが判った。また50℃以上の加温下での保存中は5000Lux以上の照度で白色光を照射すれば着色光と同様の褐変低減効果があることが判った。   Even when white light is stored in a transparent container-packed green tea beverage at room temperature for 12 weeks, white light is emitted against the transparent container-packed green tea beverage at an illuminance of 1000 Lux or more, which exceeds the illuminance of the fluorescent light normally used in showcases, etc. It was found that the effect of reducing browning was the same as that of colored light. In addition, it was found that during storage under heating at 50 ° C. or higher, if white light is irradiated at an illuminance of 5000 Lux or higher, there is an effect of reducing browning similar to colored light.

本発明の1実施態様においては、透明容器詰緑茶飲料を保存する保存室と、該保存室内に設けられ、常温保存の場合2μW/mL以上、50℃以上の加温下での保存の場合15μW/mL以上の放射照度で赤色光を除く着色光を該透明容器詰緑茶飲料に照射する手段を備える容器詰緑茶飲料保存装置が提供される。   In one embodiment of the present invention, a storage room for storing a transparent container-packed green tea beverage, and a storage room provided at the room temperature, 2 μW / mL or more when stored at room temperature, and 15 μW when stored at a temperature of 50 ° C. or more. A container-packed green tea beverage storage device comprising means for irradiating the transparent container-packed green tea beverage with colored light excluding red light with an irradiance of / mL or more is provided.

また、本発明の他の実施態様においては、透明容器詰緑茶飲料を保存する保存室と、該保存室内に設けられ、1000Lux以上の照度で白色光を該透明容器詰緑茶飲料に照射する手段とを備える容器詰緑茶飲料保存装置が提供される。   In another embodiment of the present invention, a storage room for storing the transparent container-packed green tea beverage, and means for irradiating the transparent container-packed green tea drink with white light at an illuminance of 1000 Lux or more provided in the storage chamber; A container-packed green tea beverage storage device is provided.

これらの容器詰緑茶飲料保存装置において、透明容器詰緑茶飲料を保存する保存室は、透明容器詰緑茶飲料販売店に設置されたショーケース、ウオーマ、自動販売機等を含むが、これに限定されるものではない。   In these container-packed green tea beverage storage devices, the storage room for storing transparent container-packed green tea beverages includes, but is not limited to, showcases, womas, vending machines, etc. installed in transparent container-packed green tea beverage stores. It is not something.

また、これらの保存装置において、該保存室内には、2μW/mL以上の放射照度で赤色光を除く着色光を透明容器詰緑茶飲料に照射する手段または1000Lux以上の照度で白色光を透明容器詰緑茶飲料に照射する手段として蛍光管またはLEDランプ等が設けられている。これらの照射手段は、保存室内の透明容器詰緑茶飲料の配置された位置に応じて容器全体または容器表面積の中なるべく広い面積に着色光または白色光が当るように適当な位置に設置される。緑茶飲料を50℃以上で加温販売のため保存する場合は、これら蛍光管またはLEDランプ等は15μW/mL以上の放射照度の着色光または5000Lux以上の照度の白色光を照射する能力を有することが必要である。   Further, in these storage devices, the storage chamber is filled with a means for irradiating colored green tea beverages with a irradiance of 2 μW / mL or more except for red light to a transparent container or white containers with an illuminance of 1000 Lux or more. As means for irradiating the green tea beverage, a fluorescent tube or an LED lamp is provided. These irradiating means are installed at appropriate positions so that colored light or white light hits the entire container or the surface area of the container as much as possible depending on the position of the transparent container-packed green tea beverage in the storage room. When storing green tea drinks at 50 ° C. or higher for warm sales, these fluorescent tubes or LED lamps, etc. have the ability to irradiate colored light with an irradiance of 15 μW / mL or more or white light with an illuminance of 5000 Lux or more. is required.

図10は、このような保存装置の1例を模式的に示すもので、1はPETボトル詰緑茶飲料を加温販売するショーケース、2はPETボトル詰緑茶飲料である。この装置は上下3段に分かれており、各段の床板上には緑茶飲料を50℃以上の所定の温度たとえば55℃〜60℃に加温する板状のヒーター3が配置されており、このヒーター3上に緑茶飲料2が所定数置かれている。各段の緑茶飲料の上方には緑茶飲料の天面と所定の間隔を置いて放射照度1.0mW/cm以上の緑色光または照度5000Lux以上の白色光を照射する蛍光管、LED等の照射手段4が設置され、各緑茶飲料を照射するように構成されている。各照射手段はそれぞれショーケース外に設けられた発光源に接続されている。 FIG. 10 schematically shows an example of such a storage device, where 1 is a showcase for heating and selling a PET bottled green tea beverage, and 2 is a PET bottled green tea beverage. This apparatus is divided into upper and lower three stages, and a plate-like heater 3 for heating the green tea beverage to a predetermined temperature of 50 ° C. or higher, for example, 55 ° C. to 60 ° C. is disposed on the floor plate of each stage. A predetermined number of green tea beverages 2 are placed on the heater 3. Irradiation of fluorescent tubes, LEDs, etc. that irradiate green light with an irradiance of 1.0 mW / cm 2 or more or white light with an illuminance of 5000 Lux or more at a predetermined interval above the top of the green tea drink at each stage. Means 4 are installed and configured to irradiate each green tea beverage. Each irradiation means is connected to a light source provided outside the showcase.

容器詰緑茶飲料として、市販の350mLPETボトル入りの緑茶飲料(伊藤園「お〜いお茶」)を使用し、22℃、60%RHの環境下で、光を遮断できる保管箱に保存した群(暗所群)、天面に透明セロハンを貼った箱に保存した群(白色群)、同様に赤色セロハンを貼った箱に保存した群(赤色群)、緑色セロハンを貼った箱に保存した群(緑色群)および青色セロハンを貼った箱に保存した群(青色群)を用意し、暗所群以外のそれぞれの照射群の光の放射照度を約0.23mW/cm(白色光で約1000Lux相当)に合わせ、常温で12週間保存し、途中任意の時点でサンプリングを行い、色調測定(Hunter L、a、b)により色差(ΔE)を求めるとともに風味の評価を行った。 As a packaged green tea beverage, a commercially available 350 mL PET bottled green tea beverage (Itoen “Oi Ocha”) was used and stored in a storage box that can block light in an environment of 22 ° C. and 60% RH (dark) Group), a group stored in a box with a transparent cellophane on the top (white group), a group stored in a box with a red cellophane similarly (red group), a group stored in a box with a green cellophane ( Green group) and a group stored in a box with blue cellophane (blue group) are prepared, and the irradiance of light of each irradiation group other than the dark place group is about 0.23 mW / cm 2 (about 1000 Lux with white light) The color difference (ΔE) was obtained by color tone measurement (Hunter L, a, b) and the flavor was evaluated.

使用した照射光の分光分布を図1に示す。図1において、Aは白色光、Bは青色光、Cは緑色光、Dは赤色光を示す。また、色調測定結果を図2〜5に示す。図中、色調のL値は明度を示し、100に近いほど透明であることを示している。また、a値はマイナス値が大きいほど緑色が強く、マイナス値が小さいほど赤色が強いことを示している。また、b値はプラス値が大きいほど黄色が強く、プラス値が小さいほど青色が強いことを示している。緑茶の褐変が進行するとL値が低下し、a値が上昇する。   The spectral distribution of the used irradiation light is shown in FIG. In FIG. 1, A indicates white light, B indicates blue light, C indicates green light, and D indicates red light. Moreover, the color tone measurement results are shown in FIGS. In the figure, the L value of the color tone indicates the lightness, and the closer to 100, the more transparent it is. The a value indicates that the larger the negative value, the stronger the green color, and the smaller the negative value, the stronger the red color. The b value indicates that yellow is stronger as the positive value is larger, and blue is stronger as the positive value is smaller. As the browning of green tea proceeds, the L value decreases and the a value increases.

図2〜5から、暗所群や赤色群では褐変の進行(L値の低下かつa値の上昇)が明瞭で、白色群、青色群、緑色群では色調変化が少ない、すなわち褐変の進行が低減されていることが明瞭に示された。   From FIG. 2 to FIG. 5, the browning progress (decrease in the L value and increase in the a value) is clear in the dark group and the red group, and the color change is small in the white group, the blue group, and the green group, that is, the browning progresses. It was clearly shown that it was reduced.

照射光の各波長ごとの放射照度において、495〜505nmの積算値を計算すると、白色光が8.036μW/cm、青色光が10.7715μW/cm、緑色光が17.8559μW/cm、赤色光が0.6375μW/cmである。これらの値がΔEの大きさと完全には一致しているわけではないが、ΔEの最も小さかった緑色光のデータを採用すると、容器への照射面積を80cmとして、照射された放射束は、17.8559μW/cm×80cm=1428.472μWである。茶液量が350mLであったため、22℃条件において色調変化がほとんど起こらない茶液量当りの必要放射束は、1428.472μW÷350mL≒4.1μW/mLであったことになる。 When the integrated value of 495 to 505 nm is calculated at the irradiance for each wavelength of the irradiation light, the white light is 8.036 μW / cm 2 , the blue light is 10.7715 μW / cm 2 , and the green light is 17.8559 μW / cm 2. , Red light is 0.6375 μW / cm 2 . Although these values do not completely coincide with the magnitude of ΔE, when the green light data with the smallest ΔE is adopted, the irradiation area to the container is set to 80 cm 2 , and the irradiated radiant flux is 17.85559 μW / cm 2 × 80 cm 2 = 1428.472 μW. Since the amount of tea liquid was 350 mL, the necessary radiant flux per tea liquid amount that hardly caused a change in color tone at 22 ° C. was 1428.272 μW ÷ 350 mL≈4.1 μW / mL.

また、風味の評価では、白色、青色、緑色の各群で特に風味に悪影響がないことが確認できた。   Further, in the evaluation of the flavor, it was confirmed that the flavor was not particularly adversely affected in the white, blue and green groups.

55℃加温下条件における色つき蛍光灯による褐変低減効果の実験を行った。   The experiment of the browning reduction effect by the colored fluorescent lamp under 55 degreeC heating conditions was conducted.

試料として伊藤園社製「お〜いお茶」350mL PETボトル詰(コールド用)を使用した。照明は、三菱オスラム社製の色蛍光ランプFL20SP(赤)、FL20SG(緑)、FL20SB(青)を使用した。各照射光の分光分布を図6に示す。図6において、Aは青蛍光灯、Bは緑蛍光灯、Cは赤蛍光灯を示す。放射照度は、すべて4.3mW/cmに統一した。照射光は容器の前面に当たるようにした。保存は、55℃、10%RHの恒温室内において実施した。
茶液の変色は、495nmの吸光度(OD495nm)測定結果を指標とできることが実験的に確認できている。
As a sample, 350 ml PET bottled bottle (for cold) made by ITO EN Co., Ltd. was used. For illumination, color fluorescent lamps FL20SP (red), FL20SG (green), and FL20SB (blue) manufactured by Mitsubishi OSRAM were used. The spectral distribution of each irradiation light is shown in FIG. In FIG. 6, A indicates a blue fluorescent lamp, B indicates a green fluorescent lamp, and C indicates a red fluorescent lamp. The irradiance was all unified to 4.3 mW / cm 2 . Irradiation light hit the front of the container. Storage was carried out in a constant temperature room at 55 ° C. and 10% RH.
It has been experimentally confirmed that the discoloration of the tea liquid can be based on the measurement result of absorbance at 495 nm (OD495 nm).

茶液の各色蛍光灯照射時におけるOD495nmの変化を図7に示す。暗所保存と赤色蛍光灯照射において、OD495nmの変化速度に差が認められず、赤色蛍光当照射の効果はないことが判った。緑色蛍光灯と青色蛍光灯の照射により、暗所保存と比較してOD495nmの変化が少なくなる効果が観察され、特に青色蛍光灯照射では褪色が認められた。   FIG. 7 shows the change in OD495 nm when the tea liquid is irradiated with each color fluorescent lamp. No difference was observed in the change rate of OD 495 nm between dark storage and red fluorescent lamp irradiation, indicating that there was no effect of red fluorescent irradiation. The effect of reducing the change in OD 495 nm by the irradiation of the green fluorescent lamp and the blue fluorescent lamp was observed as compared with the preservation in the dark place.

照射光の各波長ごとの放射照度において、495〜505nm積算値は、青色光が163.1706μW/cm、緑色光が159.4403μW/cm、赤色光が2.3894μW/cmである。これらの値はOD495nmの変化量とほぼ一致している。OD495nmの変化の最も小さかった緑色光のデータを採用すると、容器への照射面積を80cmとして、照射された放射束は、159.4403μW/cm×80cm=12755.224μWであある。茶液量が350mLであったため、55℃において色調変化がほとんど起こらない茶液量当りの必要放射束は、12755.224μW÷350mL≒36.4μW/mLであったことになる。 In irradiance for each wavelength of the irradiated light, 495~505Nm integrated value, blue light 163.1706μW / cm 2, green light 159.4403μW / cm 2, red light is 2.3894μW / cm 2. These values almost coincide with the amount of change at OD495 nm. When the data of green light with the smallest change in OD 495 nm is adopted, the irradiation area to the container is 80 cm 2 , and the irradiated radiant flux is 159.4403 μW / cm 2 × 80 cm 2 = 12755.224 μW. Since the amount of tea liquid was 350 mL, the necessary radiant flux per tea liquid amount at which color change hardly occurred at 55 ° C. was 12755.224 μW ÷ 350 mL≈36.4 μW / mL.

一方、赤色光照射で効果がなかったことに関し、赤色蛍光灯光には430〜440nmの間に約166μW/cmという495〜505nmの緑色光のものに匹敵する強さの放射照度を含む。これは、430〜440nmの光は効果がないことを示している。同様に、赤色蛍光灯光には540〜550nmの間に約198μW/cmという放射照度を含み、540〜550nmの光も効果がないことを示している。 On the other hand, the red fluorescent lamp light has an irradiance of about 166 μW / cm 2 between 430 and 440 nm, which is comparable to that of green light of 495 to 505 nm, with respect to the ineffectiveness of red light irradiation. This indicates that light of 430 to 440 nm has no effect. Similarly, red fluorescent lamp light has an irradiance of about 198 μW / cm 2 between 540 and 550 nm, indicating that light at 540 to 550 nm is also ineffective.

風味に関して、55℃―2週間暗所保存品と55℃―2週間緑色蛍光灯光照射品について、冷蔵保存品を基準として、味認識装置を使用して評価した結果を図8に示す。   FIG. 8 shows the results of evaluation using the taste recognition device with respect to the flavor of the 55 ° C.-2 weeks stored product in the dark and the 55 ° C./2 weeks irradiated product with the green fluorescent lamp on the basis of the refrigerated product.

味認識装置としては、株式会社インテリジェントセンサーテクノロジー製SA402B味認識装置を使用した。ウエーバーの法則によれば、人間はウエーバー比(濃度差)約20%で誰でも識別可能といわれていることから、味認識装置SA402Bでは、味強度の違いを測定値を換算式を用いて推定数値化している。推定数値を用いたマッピング中では、1目盛りの濃度差で味の量を識別できるように表示している。上記図8の場合、第一主成分は主に苦味・雑味を示し、第二主成分は主に酸味を示している。味評価の結果は、冷蔵品と55℃2週間暗所保存品、冷蔵品と55℃2週間緑色光照射品とでは味が識別できるが、55℃2週間暗所保存品と55℃2週間緑色光照射品とでは味が明確に識別できず、光の照射の有無の影響は認められなかった。   As a taste recognition device, SA402B taste recognition device manufactured by Intelligent Sensor Technology Co., Ltd. was used. According to Weber's law, it is said that anyone can be identified with a Weber ratio (concentration difference) of about 20%, so the taste recognition device SA402B estimates the difference in taste intensity using a conversion formula. It is digitized. In the mapping using the estimated numerical value, it is displayed so that the amount of taste can be identified by the density difference of one scale. In the case of FIG. 8 described above, the first main component mainly shows bitterness and miscellaneous taste, and the second main component mainly shows sourness. The results of the taste evaluation show that the taste can be discriminated between the refrigerated product and 55 ° C for 2 weeks in the dark, the refrigerated product and 55 ° C for 2 weeks in the green light irradiation product, but the 55 ° C for 2 weeks in the dark and 55 ° C for 2 weeks. The taste could not be clearly distinguished from the green light-irradiated product, and no effect of light irradiation was observed.

60℃加温下条件(缶ウオーマ)におけるLEDランプによる褐変低減効果の実験を行った。   The experiment of the browning reduction effect by the LED lamp in 60 degreeC heating conditions (can womar) was conducted.

試料として伊藤園社製「お〜いお茶」350mL PETボトル詰(コールド用)を使用した。LEDランプは、490nmにピークを有するもの(青緑)、530nmにピークを有するもの(緑)および590nmにピークを有するもの(黄)を使用した。   As a sample, 350 ml PET bottled bottle (for cold) made by ITO EN Co., Ltd. was used. As the LED lamp, one having a peak at 490 nm (blue green), one having a peak at 530 nm (green), and one having a peak at 590 nm (yellow) were used.

放射照度は約2.0mW/cmとした。保存は缶ウオーマ内(温度は約60℃となる)で2週間とした。 The irradiance was about 2.0 mW / cm 2 . Storage was carried out for 2 weeks in the canister (temperature was about 60 ° C.).

透過スペクトルの測定結果および照射光源の分光分布を図9に示す。図9において、Aは490nmLEDランプを、Bは530nmLEDランプを、Cは590nmLEDランプを示す。また、Dは保存前の茶液の透過スペクトルを、Eは490nmLED照射茶液の透過スペクトルを、Fは530nmLED照射茶液の透過スペクトルを、Gは590nmLED照射茶液の透過スペクトルを、Hは暗所保存茶液の透過スペクトルをそれぞれ示す。   The measurement result of the transmission spectrum and the spectral distribution of the irradiation light source are shown in FIG. In FIG. 9, A indicates a 490 nm LED lamp, B indicates a 530 nm LED lamp, and C indicates a 590 nm LED lamp. D is the transmission spectrum of the tea liquid before storage, E is the transmission spectrum of the 490 nm LED irradiated tea liquid, F is the transmission spectrum of the 530 nm LED irradiated tea liquid, G is the transmission spectrum of the 590 nm LED irradiated tea liquid, and H is dark. The transmission spectra of the preserved tea liquid are shown.

495〜505nmをほとんど含まない590nm(黄)ランプの光に色調変化低減作用は認められず、暗所保存品とほぼ同様の透過スペクトルとなった。   The light of a 590 nm (yellow) lamp that hardly contains 495 to 505 nm was not observed to have a color tone change reducing effect, and the transmission spectrum was almost the same as that stored in the dark place.

490nm(青緑)ランプの光による照射では効果が明瞭で、保存前とほぼ同等の透過スペクトルを示し、色調がほとんど変化していないことが認められた。530nm(緑)ランプの光による照射では、490nm(青緑)ランプのほぼ半分程度の効果であった。   Irradiation with light from a 490 nm (blue-green) lamp showed a clear effect, showed almost the same transmission spectrum as before storage, and it was recognized that the color tone hardly changed. Irradiation with light from a 530 nm (green) lamp was about half the effect of a 490 nm (blue green) lamp.

青緑ランプと緑ランプによる色調変化低減効果が倍程度であったことから、放射照度の差が2倍程度の範囲を探すと、495〜505nmの範囲の積算値で、青緑が約370μW/cm、緑が約180μW/cmと約2倍差であった。 Since the effect of reducing the change in color tone between the blue-green lamp and the green lamp was about double, when looking for a range where the difference in irradiance was about double, blue-green was about 370 μW / in the integrated value in the range of 495 to 505 nm. cm 2 and green were about 180 μW / cm 2 , which was about twice the difference.

適正な照射量を求めるため、変色がほとんどなかった方の青緑の方のデータを採用すると、容器への照射面積を80cmとして、照射された495〜505nmの範囲の放射束は、372.5911μW/cm×80cm=29807.288μWである。茶液量が350mLであったため、60℃条件において色調変化がほとんど起こらない茶液量当りの必要放射束は、29807.288μW÷350mL≒85.2μW/mLであったことになる。 In order to obtain an appropriate irradiation amount, when the data of the blue-green side having almost no discoloration is adopted, the irradiation area to the container is set to 80 cm 2 , and the irradiated radiant flux in the range of 495 to 505 nm is 372. It is 5911 μW / cm 2 × 80 cm 2 = 29807.288 μW. Since the amount of tea liquid was 350 mL, the required radiant flux per tea liquid amount that hardly caused a change in color tone at 60 ° C. was 29807.288 μW ÷ 350 mL≈85.2 μW / mL.

容器詰緑茶飲料として市販の酸素吸収性を有する350mLPETボトル入り飲料を使用し、室内においてヨシキン製の缶ウオーマを置き、上下2段の保存室中上段は約1000Luxの白色光で照明し、下段には緑色LEDランプを取り付け、ボトルのキャップ天面より7cmの距離に上方から照射した(約6000Lux相当)。   Use a commercially available 350 mL PET bottled beverage with oxygen-absorbing ability as a container-packed green tea beverage. Place a can-wine made of Yoshikin in the room, and illuminate the upper part of the upper and lower two-stage storage rooms with white light of about 1000 Lux. A green LED lamp was attached and irradiated from above at a distance of 7 cm from the top of the bottle cap (equivalent to about 6000 Lux).

55℃〜60℃の加温下で2週間保存試験の結果、これらの保存品の透過スペクトルを、冷蔵庫で同一期間冷蔵保存した同一飲料を対照として比較した。その結果、図11のグラフおよび図12の部分拡大グラフに示されるように、450〜500nmのあたりで上段の缶ウオーマ保存品の透過度が対照である冷蔵保存品に比べて明確に低下し、褐変が進行していることが観察された。一方緑色LEDランプを照射した下段の缶ウオーマ保存品は透過度の低下が低減されていることが認められた。   As a result of the storage test at 55 ° C. to 60 ° C. for 2 weeks, the transmission spectra of these stored products were compared with the same beverage stored in the refrigerator for the same period as the control. As a result, as shown in the graph of FIG. 11 and the partially enlarged graph of FIG. 12, the permeability of the upper canned stored product is clearly lower than that of the refrigerated stored product as a control, around 450 to 500 nm. It was observed that browning was progressing. On the other hand, it was observed that the lower canned product preserved by irradiating the green LED lamp had reduced decrease in transmittance.

色調の変化としてΔEで表わすと、図13に示すように、対照である冷蔵保存品が約1.0、上段の缶ウオーマ保存品が約6.5、下段の缶ウオーマ保存品が約2.7であり、緑色光照射により、明確に褐変低減効果が認められた。   When the change in color tone is represented by ΔE, as shown in FIG. 13, the control refrigerated product is about 1.0, the upper canned product stored is about 6.5, and the lower canned product stored is about 2. 7 and the browning reduction effect was clearly recognized by green light irradiation.

また、下段の缶ウオーマ保存品については、照射による不快な風味の変化は官能的にはまったく認められなかった。   Moreover, about the canned-can preserved product of the lower stage, the unpleasant flavor change by irradiation was not sensuously recognized.

比較例1Comparative Example 1

容器詰飲料として市販の酸素吸収性を有する350mLPETボトル入り飲料を使用し、55℃、10%RHの環境下で、光を遮断できる保管箱に保存した群(暗所群)、天面に白色トレーシングペーパーを貼った箱に保存した群(白色群)、同様に赤色セロハンを貼った箱に保存した群(赤色群)、緑色セロハンを貼った箱に保存した群(緑色群)および青色セロハンを貼った箱に保存した群(青色群)を用意し、暗所群以外のそれぞれの照射群の光の放射照度を約0.21mW/cm(白色光で約900Lux相当)に合わせ、試料の横方向から照射した(縦方向からの場合の2倍強の面積で照射を受ける)。2週間保存し、途中任意の時点でサンプリングを行い、色調測定(Hunter L、a、b)より色差(ΔE)を求めるとともに、風味の評価を行った。 Using a commercially available 350 mL PET bottled beverage with oxygen absorption as a packaged beverage, stored in a storage box that can block light in an environment of 55 ° C. and 10% RH (dark place group), white on top Group stored in a box with tracing paper (white group), similarly group stored in a box with red cellophane (red group), group stored in a box with green cellophane (green group), and blue cellophane Prepare a group (blue group) stored in a box with sapphire, adjust the irradiance of light of each irradiation group other than the dark place group to about 0.21 mW / cm 2 (equivalent to about 900 Lux with white light), and sample Irradiated from the lateral direction of (received in an area slightly more than twice that from the longitudinal direction). The sample was stored for 2 weeks, sampled at an arbitrary point in the middle, color difference (ΔE) was determined from color tone measurement (Hunter L, a, b), and flavor was evaluated.

色差測定結果を図14に示す。青色、緑色で色調変化がやや少なめのようにも見えるが、全体として差が不明瞭であった。また図15に示すように、各色で風味に有意な差は認められなかった。   The color difference measurement results are shown in FIG. Although the color change in blue and green looks slightly less, the overall difference was unclear. In addition, as shown in FIG. 15, no significant difference in flavor was recognized between the colors.

以上の結果から、光の照射量が充分でないと明確な褐変低減効果が得られないことが判る。   From the above results, it can be seen that a clear browning reduction effect cannot be obtained unless the amount of light irradiation is sufficient.

実施例1における照射光の分光分布を示すグラフである。3 is a graph showing a spectral distribution of irradiation light in Example 1. 実施例1のPETボトル詰緑茶飲料の保存中におけるL値の経時変化に及ぼす光の影響を示すグラフである。It is a graph which shows the influence of the light which acts on the time-dependent change of L value during the preservation | save of the PET bottled green tea drink of Example 1. 実施例1のPETボトル詰緑茶飲料の保存中におけるa値の経時変化に及ぼす光の影響を示すグラフである。It is a graph which shows the influence of the light which acts on the time-dependent change of a value during the preservation | save of the PET bottled green tea drink of Example 1. 実施例1のPETボトル詰緑茶飲料の保存中におけるb値の経時変化に及ぼす光の影響を示すグラフである。It is a graph which shows the influence of the light which has on the time-dependent change of b value during preservation | save of the PET bottled green tea drink of Example 1. FIG. 実施例1のPETボトル詰緑茶飲料の保存中におけるΔE値の経時変化に及ぼす光の影響を示すグラフである。It is a graph which shows the influence of the light which has on the time-dependent change of (DELTA) E value during preservation | save of the PET bottled green tea drink of Example 1. FIG. 実施例2における照射光の分光分布を示すグラフである。6 is a graph showing a spectral distribution of irradiation light in Example 2. 実施例2における各色蛍光灯照射時の吸光度変化を示すグラフである。It is a graph which shows the light absorbency change at the time of each color fluorescent lamp irradiation in Example 2. FIG. 実施例2における味認識装置による風味評価の結果を示すグラフである。It is a graph which shows the result of the flavor evaluation by the taste recognition apparatus in Example 2. 実施例3における茶液の透過スペクトルおよび照射光源の分光分布を示すグラフである。It is a graph which shows the transmission spectrum of the tea liquid in Example 3, and the spectral distribution of an irradiation light source. 実施例4における透明容器詰緑茶飲料保存装置の1例を模式的に示す正面図である。It is a front view which shows typically one example of the transparent container filling green tea drink preservation | save apparatus in Example 4. FIG. 実施例4のPETボトル詰緑茶飲料の保存中における透過度の経時変化に及ぼす光の影響を示すグラフである。It is a graph which shows the influence of the light which acts on the time-dependent change of the transmittance | permeability in the preservation | save of the PET bottled green tea drink of Example 4. 図11における波長450〜500nmにおける透過度を拡大して示すグラフである。12 is an enlarged graph showing the transmittance at a wavelength of 450 to 500 nm in FIG. 11. 実施例4のPETボトル詰緑茶飲料の保存中における色差の経時変化に及ぼす光の影響を示すグラフである。It is a graph which shows the influence of the light which acts on the time-dependent change of the color difference in the preservation | save of the PET bottled green tea drink of Example 4. 比較例1のPETボトル詰緑茶飲料の保存中における色差の経時変化に及ぼす光の影響を示すグラフである。It is a graph which shows the influence of the light which acts on the time-dependent change of the color difference in the preservation | save of the PET bottled green tea drink of the comparative example 1. 比較例1のPETボトル詰緑茶飲料の保存中における風味の経時変化を示すグラフである。It is a graph which shows the time-dependent change of the flavor during preservation | save of the PET bottled green tea drink of the comparative example 1.

Claims (16)

透明容器詰緑茶飲料の常温での保存中495〜505nmの放射束の積算値で2μW/mL以上の放射照度で495〜505nmの波長成分を含む有色光または白色光を該緑茶飲料に照射することを特徴とする透明容器詰緑茶飲料の保存方法。   Irradiating the green tea beverage with colored light or white light containing a wavelength component of 495 to 505 nm with an irradiance of 2 μW / mL or more as an integrated value of radiant flux of 495 to 505 nm during storage at room temperature of the transparent container-packed green tea beverage A method for preserving a green tea beverage in a transparent container. 該有色光の放射照度は4μW/mL以上であることを特徴とする請求項1記載の保存方法。   2. The storage method according to claim 1, wherein the irradiance of the colored light is 4 [mu] W / mL or more. 該有色光は、480〜540nmの波長成分を有する青ー緑色光であることを特徴とする請求項1または2記載の保存方法。   The storage method according to claim 1 or 2, wherein the colored light is blue-green light having a wavelength component of 480 to 540 nm. 該白色光の照度は1000Lux以上であることを特徴とする請求項1記載の保存方法。   2. The storage method according to claim 1, wherein the illuminance of the white light is 1000 Lux or more. 透明容器詰緑茶飲料の50℃以上の加温下での保存中495〜505nmの放射束の積算値で15μW/mL以上の放射照度で495〜505nmの波長成分を含む有色光または白色光を該緑茶飲料に照射することを特徴とする透明容器詰緑茶飲料の保存方法。   During storage of a green tea beverage in a transparent container at a temperature of 50 ° C. or higher, a colored or white light containing a wavelength component of 495 to 505 nm with an irradiance of 15 μW / mL or more with an integrated value of 495 to 505 nm radiant flux A method for preserving a green tea beverage in a transparent container, characterized by irradiating the green tea beverage. 該有色光の放射照度は30μW/mL以上であることを特徴とする請求項5記載の保存方法。   6. The storage method according to claim 5, wherein the irradiance of the colored light is 30 [mu] W / mL or more. 該有色光は、480〜540nmの波長成分を有する青ー緑色光であることを特徴とする請求項5または6記載の保存方法。   The storage method according to claim 5 or 6, wherein the colored light is blue-green light having a wavelength component of 480 to 540 nm. 該白色光の照度は5000Lux以上であることを特徴とする請求項5記載の透明容器詰緑茶飲料の保存方法。   The method for preserving a transparent container-packed green tea beverage according to claim 5, wherein the illuminance of the white light is 5000 Lux or more. 透明容器詰緑茶飲料を常温保存する保存室と、該保存室内に設けられ、該緑茶飲料の保存中495〜505nmの放射束の積算値で2μW/mL以上の放射照度で495〜505nmの波長成分を含む有色光または白色光を該緑茶飲料に照射する手段とを備えることを特徴とする透明容器詰緑茶飲料保存装置。   A storage room for storing the green tea beverage in a transparent container at room temperature, and a wavelength component of 495 to 505 nm with an irradiance of 2 μW / mL or more as an integrated value of the 495 to 505 nm radiant flux during storage of the green tea beverage. And a means for irradiating the green tea beverage with colored light or white light containing a transparent container-packed green tea beverage storage device. 該有色光の放射照度は4μW/mL以上であることを特徴とする請求項9記載の保存装置。   10. The storage device according to claim 9, wherein the irradiance of the colored light is 4 [mu] W / mL or more. 該有色光は、480〜540nmの波長成分を有する青―緑色光であることを特徴とする請求項9または10記載の保存装置。   The storage device according to claim 9 or 10, wherein the colored light is blue-green light having a wavelength component of 480 to 540 nm. 該白色光の照度は1000Lux以上であることを特徴とする請求項9記載の保存装置。   The storage device according to claim 9, wherein the illuminance of the white light is 1000 Lux or more. 透明容器詰緑茶飲料を50℃以上の加温下で保存する保存室と、該保存室内に設けられ、該緑茶飲料の保存中495〜505nmの放射束の積算値で15μW/mL以上の放射照度で495〜505nmの波長成分を含む有色光または白色光を該緑茶飲料に照射する手段とを備えることを特徴とする透明容器詰緑茶飲料保存装置。   A storage room for storing the green tea beverage in a transparent container under a temperature of 50 ° C. or higher, and an irradiance of 15 μW / mL or more provided in the storage room and an accumulated value of 495 to 505 nm radiant flux during storage of the green tea beverage And a means for irradiating the green tea beverage with colored light or white light containing a wavelength component of 495 to 505 nm. 該有色光の放射照度は30μW/mL以上であることを特徴とする請求項13記載の保存装置。   14. The storage device according to claim 13, wherein the irradiance of the colored light is 30 [mu] W / mL or more. 該有色光は、480〜540nmの波長成分を有する青―緑色光であることを特徴とする請求項13または14記載の保存装置。   15. The storage device according to claim 13, wherein the colored light is blue-green light having a wavelength component of 480 to 540 nm. 該白色光の照度は5000Luxであることを特徴とする請求項13記載の保存装置。   14. The storage device according to claim 13, wherein the illuminance of the white light is 5000 Lux.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01296561A (en) * 1988-05-25 1989-11-29 Toshiba Lighting & Technol Corp Lamp and lighting device and beverage vending machine using them
JP2001112414A (en) * 1999-08-10 2001-04-24 Mitsui Norin Co Ltd Method for producing tea drink prevented from browning
JP2004057844A (en) * 2002-07-24 2004-02-26 Ishikawajima Harima Heavy Ind Co Ltd Beverage sterilizer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01296561A (en) * 1988-05-25 1989-11-29 Toshiba Lighting & Technol Corp Lamp and lighting device and beverage vending machine using them
JP2001112414A (en) * 1999-08-10 2001-04-24 Mitsui Norin Co Ltd Method for producing tea drink prevented from browning
JP2004057844A (en) * 2002-07-24 2004-02-26 Ishikawajima Harima Heavy Ind Co Ltd Beverage sterilizer

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