JP2007098785A - Gravure printed article, and paper container using it - Google Patents

Gravure printed article, and paper container using it Download PDF

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JP2007098785A
JP2007098785A JP2005292191A JP2005292191A JP2007098785A JP 2007098785 A JP2007098785 A JP 2007098785A JP 2005292191 A JP2005292191 A JP 2005292191A JP 2005292191 A JP2005292191 A JP 2005292191A JP 2007098785 A JP2007098785 A JP 2007098785A
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varnish
gravure
printing
ultraviolet
gloss varnish
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JP4784246B2 (en
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Takehiko Tsuchiyama
土山　　武彦
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Toppan Inc
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Toppan Printing Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a gravure printed article having a good working efficiency, and in addition, having a high printing effect, and to which an embossing expression is applied at the same time with printing by using a cissing varnish, and to provide a paper container using the gravure printed article. <P>SOLUTION: A varnish layer (12) having liquid repellent property is provided on a printing base material (11) by using the gravure printing method. On the varnish layer (12) having the liquid repellent property, an ultraviolet-curing type high gloss varnish liquid is coated, and the embossing expression is afforded by partially providing an ultraviolet-curing type high gloss varnish layer (13) for this gravure printed article (10). In the gravure printed article (10), as the cissing varnish which constitutes the varnish layer (12) having the liquid repellent property, an acrylic-silicone copolymer resin is used. At the same time, as a diluting solvent for the ultraviolet-curing type high gloss varnish liquid which constitutes the ultraviolet-curing type high gloss varnish layer (13), a 6-10C aliphatic solvent is used. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、グラビア印刷物とそれを用いた紙容器に関するものであり、特には印刷と同時にエンボス表現を施したグラビア印刷物とそれを用いた紙容器に関する。   The present invention relates to a gravure printed material and a paper container using the same, and more particularly to a gravure printed material that is embossed at the same time as printing and a paper container using the same.

従来、高級紙容器などの外面に凹凸感を持たせる方法として、印刷用紙に直接、あるいは印刷用紙の印刷面に撥液性を有するニス層を設け、その上に紫外線硬化型ハイグロスニスを重ね塗りして、紫外線硬化型ハイグロスニスを弾かせ、ニスのある個所とない個所とを出現させてエンボス表現をする方法が、オフセット印刷、グラビア印刷共に実施されてきた（例えば、特許文献１参照）。   Conventionally, as a method of making the outer surface of a high-grade paper container or the like have a feeling of unevenness, a varnish layer having liquid repellency is provided directly on the printing paper or on the printing surface of the printing paper, and an ultraviolet curable high-gloss varnish is repeatedly applied thereon. Thus, a method of embossing by causing ultraviolet curable high-gloss varnish to appear and causing varnished and non-varnished parts to appear has been implemented for both offset printing and gravure printing (see, for example, Patent Document 1).

上記先行技術文献を示す。
特開２００４−１１４６５４号公報。 The said prior art document is shown.
JP 2004-114654 A.

しかし、グラビア印刷に限定して述べると、この方法においては、エンボス感を強く出すためには撥液性を有するニス（以下ハジキニスと称する）中に低分子量（重合度１０〜８０）のシリコンオイルをニス重量の２〜１０％添加する必要がある。   However, when limited to gravure printing, in this method, a silicone oil having a low molecular weight (degree of polymerization of 10 to 80) is contained in a liquid-repellent varnish (hereinafter referred to as “Hajikinis”) in order to give a strong embossed feeling. Needs to be added in an amount of 2 to 10% of the varnish weight.

印刷用紙（１０１）にハジキニス（１０２）を印刷すると、ハジキニスに添加されたシリコンオイルが乾燥までの後ラインのガイドロールやインプレッションロール（１０３）などに付着し、さらにこの付着したシリコンオイル（１０４）が用紙の印刷面に再転移（１０５）するという問題が発生する。   When the hajikinis (102) is printed on the printing paper (101), the silicon oil added to the hajikinis adheres to the guide roll, the impression roll (103), etc. in the back line until the drying, and further, the adhered silicon oil (104) Is re-transferred (105) to the printing surface of the paper.

この現象が紫外線硬化型ハイグロスニス（１０６）の印刷前に発生すると、不要な部分にニスのハジキが発生し、また、紫外線硬化型ハイグロスニスの印刷後に発生すると、ハイグロスニス面にハジキニスが付着してグロス面を曇らせるという現象につながる（図３参照）。   If this phenomenon occurs before UV curable high-gloss varnish (106) is printed, varnish repellency will occur in unnecessary areas, and if UV curable high-gloss varnish will occur after printing, it will adhere to the high-gloss varnish surface. This leads to a phenomenon of fogging the gloss surface (see FIG. 3).

また正しい位置に印刷されたハジキニスについても、紫外線硬化型ハイグロスニス版（１０７）を通過する際に、若干のシリコンオイルが紫外線硬化型ハイグロスニスの溶媒に溶かされて版側に転移する。
これが堆積（１０８）するとシリコンオイルのハジキによってグラビア版のセル（１０９）にニスが入らなくなり、エンボス部分に凹凸の全くない部分（１１０）が発生してしまうという現象が生じる（図４参照）。 In addition, as for Hajikinis printed at the correct position, when passing through the ultraviolet curable high gloss varnish plate (107), some silicon oil is dissolved in the solvent of the ultraviolet curable high gloss varnish and transferred to the plate side.
When this deposits (108), the varnish does not enter the gravure plate cell (109) due to the repelling of silicon oil, and a phenomenon occurs in which an embossed portion (110) is not formed at all (see FIG. 4).

本発明は、グラビア印刷法を用いて印刷基材に撥液性を有するニス層を設け、その上に紫外線硬化型ハイグロスニスを重ね塗りして、紫外線硬化型ハイグロスニスを弾かせてハイグロスニスの塗布してある部分と塗布してない部分を形成させることでエンボス表現をする印刷物に関する以上のような問題に鑑みてなされたもので、作業効率が良く、しかも、印刷効果の高い、ハジキニスを用いて印刷と同時にエンボス表現を施したグラビア印刷物とそれを用いた紙容器を提供することを課題とする。   In the present invention, a varnish layer having liquid repellency is provided on a printing substrate using a gravure printing method, and an ultraviolet curable high-gloss varnish is applied over the varnish layer, and the ultraviolet-curable high-gloss varnish is repelled. It was made in view of the above-mentioned problems related to the printed matter that expresses embossing by forming a coated part and a non-coated part, and has a high working efficiency and high printing effect. It is an object of the present invention to provide a gravure printed material embossed at the same time as printing and a paper container using the same.

本発明の請求項１の発明は、グラビア印刷法を用いて印刷基材に撥液性を有するニス層
を設け、該撥液性を有するニス層の上に、さらに紫外線硬化型ハイグロスニス液を重ね塗りして、紫外線硬化型ハイグロスニス層が部分的に設けられることによりエンボス表現をする印刷物において、前記撥液性を有するニス層を構成するハジキニスにアクリル−シリコン共重合体樹脂を使用すると共に、前記紫外線硬化型ハイグロスニス層を構成する紫外線硬化型ハイグロスニス液の希釈溶媒に炭素数６〜１０の脂肪族系溶媒を用いることを特徴とする、グラビア印刷物である。 According to the first aspect of the present invention, a varnish layer having liquid repellency is provided on a printing substrate using a gravure printing method, and an ultraviolet curable high gloss varnish liquid is further provided on the varnish layer having liquid repellency. In printed materials that are overcoated and partially embossed with UV-curable high-gloss varnish layer, and using acrylic-silicone copolymer resin for Hajikinis that constitutes the liquid-repellent varnish layer A gravure print is characterized in that an aliphatic solvent having 6 to 10 carbon atoms is used as a diluting solvent for the ultraviolet curable high gloss varnish liquid constituting the ultraviolet curable high gloss varnish layer.

このように請求項１記載の発明によれば、ハジキニスにアクリル−シリコン共重合体樹脂を使用しているので、ガイドロールやインプレッションロールなどへの付着および再転移によるグロス面の光沢不良や不要なハジキ部分発生などの不具合が抑制される、と同時に、紫外線硬化型ハイグロスニス液の希釈溶媒に炭素数６〜１０の脂肪族系溶媒を用いているので、これまで印刷によるエンボス表現の際に慢性的に発生していた紫外線硬化型ハイグロスニス用のグラビア版の版詰まりが防止できる。   Thus, according to the first aspect of the present invention, since the acrylic-silicone copolymer resin is used for hajikinis, glossiness on the gloss surface due to adhesion and re-transfer to a guide roll or an impression roll is unnecessary. Problems such as the occurrence of repellency are suppressed, and at the same time, an aliphatic solvent having 6 to 10 carbon atoms is used as a diluting solvent for the UV-curable high-gloss varnish solution. It is possible to prevent clogging of the gravure plate for UV curable high gloss varnish that has been generated.

ハジキニスにアクリル−シリコン共重合体樹脂を用いること。紫外線硬化型ハイグロスニス液の希釈溶媒に炭素数６〜１０の脂肪族系溶媒を用いること。この二つの方法を合わせて実施することで、量産時に短時間での停止を余儀なくされていたものを連続的に運転することができるようになった。   Use acrylic-silicone copolymer resin for Hajikinis. An aliphatic solvent having 6 to 10 carbon atoms is used as a dilution solvent for the ultraviolet curable high-gloss varnish solution. By carrying out these two methods together, it has become possible to continuously operate what had to be stopped in a short time during mass production.

また、請求項２の発明は、請求項１記載の印刷物を用いた紙容器である。   A second aspect of the present invention is a paper container using the printed matter according to the first aspect.

このように請求項２記載の発明によれば、請求項１に記載の印刷物を用いた紙容器であるので、印刷表現の優れた紙容器が得られる。   Thus, according to the invention described in claim 2, since it is a paper container using the printed matter described in claim 1, a paper container excellent in printed expression can be obtained.

これまで版詰まり、ニス面の曇り、不要な部分でのハジキなどにより、量産時に少なくとも３０分〜９０分に一回の割合でグラビア印刷機を停止させて、原因部分の清掃、研磨などの作業を実施する必要があったが、本発明によりその必要がなくなった。   The gravure printing machine is stopped at a rate of at least once every 30 to 90 minutes during mass production due to plate clogging, varnish surface fogging, repellency on unnecessary parts, etc., and work such as cleaning and polishing of the cause part However, this is no longer necessary according to the present invention.

また、従来用いられてきたハジキニスは、ほとんどが水性アクリル樹脂と水性シリコンオイルという組み合わせであるが、アクリル−シリコン共重合体樹脂は油性溶媒にしか溶解しないため、油性ニスとしての取扱いになる。そのため、乾燥時間が非常に短いので紙面への塗布量を増やしてハジキ力を増大させるなどという工夫が簡単に行えるというメリットもある。   Further, most of the conventionally used hajikinis is a combination of a water-based acrylic resin and a water-based silicone oil. However, since the acrylic-silicone copolymer resin is soluble only in an oil-based solvent, it is handled as an oil-based varnish. Therefore, since the drying time is very short, there is an advantage that it is possible to easily devise such as increasing the amount of application to the paper surface and increasing the repellency.

本発明を一実施形態に基づいて以下に詳細に説明する。
本発明のグラビア印刷物は、例えば、図１に示すように、印刷基材（１１）に撥液性を有するニス層（１２）を設け、その上に紫外線硬化型ハイグロスニス（１３）を重ね塗りして、紫外線硬化型ハイグロスニス層（１３）が部分的に設けられることによりエンボス表現をするグラビア印刷物（１０）である。 The present invention will be described in detail below based on one embodiment.
For example, as shown in FIG. 1, the gravure printed material of the present invention is provided with a varnish layer (12) having liquid repellency on a printing substrate (11), and an ultraviolet curable high-gloss varnish (13) is repeatedly applied thereon. And it is a gravure printed matter (10) which carries out emboss expression by providing the ultraviolet curable high gloss varnish layer (13) partially.

また、印刷基材（１１）に通常の印刷インキ層（１５）を設け、その上に撥液性を有するニス層（１２）を設ける構成としても良い（図２参照）。   Moreover, it is good also as a structure which provides a normal printing ink layer (15) in a printing base material (11), and provides the varnish layer (12) which has liquid repellency on it (refer FIG. 2).

そして、撥液性を有するニス層（１２）を構成するハジキニスには、アクリル−シリコン共重合体樹脂を用いている。   And acrylic-silicone copolymer resin is used for the hajikinis which comprises the varnish layer (12) which has liquid repellency.

従来のシリコンオイルを添加する方法であると、シリコンオイルがガイドロール等に付着し、さらに付着したシリコンオイルが用紙の印刷面に再転移するという現象を防止する
ために、ハジキニス中のシリコンオイルを無くすることを検討した。シリコンオイル以外でハジキ力を発生させるために、ニスの主成分樹脂にアクリル−シリコン共重合体樹脂を用いた。これは重合度１５０〜４００の中級アクリル樹脂の主鎖に重合度１００〜２００のシリコン樹脂をグラフト重合させたものである。 In the conventional method of adding silicone oil, in order to prevent the phenomenon that the silicone oil adheres to the guide roll and the like, and the adhered silicone oil re-transfers to the printing surface of the paper, the silicone oil in the hajikinis is added. We considered eliminating it. In order to generate repellency other than silicon oil, an acrylic-silicone copolymer resin was used as the main component resin of the varnish. This is obtained by graft-polymerizing a silicon resin having a polymerization degree of 100 to 200 to the main chain of a middle-grade acrylic resin having a polymerization degree of 150 to 400.

この樹脂はシリコン成分がアクリル樹脂に固定化されているため、単独で付着、溶解などしない。しかし、シリコン成分がある程度被膜の表面に出てくるので、ハジキ力を発生させることができる。   Since this resin has the silicon component fixed to the acrylic resin, it does not adhere or dissolve alone. However, since a silicon component appears to some extent on the surface of the film, a repellency can be generated.

さらに、紫外線硬化型ハイグロスニス層（１３）を構成する紫外線硬化型ハイグロスニス液の希釈溶媒に、炭素数が６〜１０の脂肪族溶媒を用いた。   Further, an aliphatic solvent having 6 to 10 carbon atoms was used as a diluting solvent for the ultraviolet curable high gloss varnish liquid constituting the ultraviolet curable high gloss varnish layer (13).

グラビア版の版詰まりの原因としては、印刷して乾燥したハジキニスが紫外線硬化型ハイグロスニス版（１４）を通過する際に、紫外線硬化型ハイグロスニス液の溶媒（例えば、酢酸エチル、イソプロピルアルコール、メチルアルコールなど）にシリコンオイルが溶解することが考えられる。   As a cause of clogging of the gravure plate, the solvent (for example, ethyl acetate, isopropyl alcohol, methyl) of the UV-curable high-gloss varnish solution is used when the printed and dried Hajikinis passes through the UV-curable high-gloss varnish plate (14). It is considered that silicon oil dissolves in alcohol or the like.

よって、このシリコンオイルを溶解させにくい溶媒として、炭素数が６〜１０の脂肪族系溶媒を使用する。具体的には、ヘキサンＣ6 Ｈ14、シクロヘキサンＣ6 Ｈ12、メチルシクロヘキサンＣ7 Ｈ14、ペンタンＣ5 Ｈ12、シクロペンタンＣ5 Ｈ10、オクタンＣ8 Ｈ18、ノナンＣ9 Ｈ20、デカンＣ10Ｈ22などが列記できる。 Therefore, an aliphatic solvent having 6 to 10 carbon atoms is used as a solvent that hardly dissolves the silicon oil. Specifically, hexane C 6 H 14 , cyclohexane C 6 H 12 , methylcyclohexane C 7 H 14 , pentane C 5 H 12 , cyclopentane C 5 H 10 , octane C 8 H 18 , nonane C 9 H 20 , decane C 10 H 22 and the like can be listed.

これらの溶媒を使用することで、紫外線硬化型ハイグロスニス版を通過する際でも、シリコンオイルの紫外線硬化型ハイグロスニス液の溶媒への溶け込みが防止できるため、グラビア版のセルが詰まることも大幅に改善できる。   By using these solvents, even when passing through the UV-curable high-gloss varnish plate, it is possible to prevent the silicon oil from dissolving into the solvent of the UV-curable high-gloss varnish solution, so the gravure plate cell is also clogged significantly. Can improve.

ハジキニスの主成分にアクリル−シリコン共重合体樹脂を使用することで、版詰まりにも効果があるが、若干の溶解は発生するため紫外線硬化型ハイグロスニス液の溶媒変更も同時に実施する必要がある。   Using an acrylic-silicone copolymer resin as the main component of Hajikinis is effective in clogging the plate, but some dissolution occurs, so it is necessary to simultaneously change the solvent of the UV-curable high-gloss varnish solution. .

また、印刷基材（１１）は、印刷物を提供できるものであれば任意の材料が使用できる。例えば、紙、プラスチックフィルムやシート、金属箔、金属板、木材などが列記できる。紙容器用の印刷基材としては、コートボール、ノーコートボール、マニラボール、クラフトボールなどの板紙が挙げられる。   The printing substrate (11) can be made of any material as long as it can provide a printed matter. For example, paper, plastic film or sheet, metal foil, metal plate, wood, etc. can be listed. Examples of the printing substrate for the paper container include paperboard such as a coated ball, an uncoated ball, a manila ball, and a craft ball.

本発明のグラビア印刷物の一実施例を模式的に示す説明図である。It is explanatory drawing which shows typically one Example of the gravure printed matter of this invention. 本発明のグラビア印刷物の別の実施例を模式的に示す説明図である。It is explanatory drawing which shows typically another Example of the gravure printed matter of this invention. 印刷されたハジキニスがガイドロール等を通って排出される工程を模式的に示す説明図で、（ａ）は印刷されたハジキニス中のシリコンオイルがガイドロール等に付着した状態を示し、（ｂ）はガイドロール等に付着したシリコンオイルが印刷用紙に再付着した状態を示し、（ｃ）は印刷用紙の出来具合を示す。It is explanatory drawing which shows typically the process by which the printed hajikinis is discharged | emitted through a guide roll etc., (a) shows the state which the silicon oil in printed hajikinis adhered to the guide roll etc., (b) Indicates a state in which the silicon oil adhering to the guide roll or the like is reattached to the printing paper, and (c) indicates the condition of the printing paper. ハイグロスニスが印刷用紙に印刷される状態を示す模式説明図で、（ａ）は ハイグロスニスがハイグロスニス版を使って印刷されている状態を示し、（ｂ）はハイグロスニス版の拡大説明図であり、（ｃ）は出来上がった印刷用紙の断面説明図である。It is a schematic explanatory view showing a state where the high gloss varnish is printed on the printing paper, (a) shows a state where the high gloss varnish is printed using the high gloss varnish plate, (b) is an enlarged explanatory view of the high gloss varnish plate. (C) is a cross-sectional explanatory view of the finished printing paper.

符号の説明Explanation of symbols

１０‥‥グラビア印刷物
１１‥‥印刷基材
１２‥‥撥液性を有するニス層、ハジキニス層
１３‥‥紫外線硬化型ハイグロスニス層
１４‥‥紫外線硬化型ハイグロスニス版、グラビア版
１５‥‥印刷インキ層
１０１‥‥印刷用紙
１０２‥‥ハジキニス
１０３‥‥ガイドロール
１０４‥‥ガイドロールに付着したハジキニス、シリコンオイル
１０５‥‥再転移したハジキニス、シリコンオイル
１０６‥‥紫外線硬化型ハイグロスニス
１０７‥‥紫外線硬化型ハイグロスニス版、グラビア版
１０８‥‥セルに堆積したハジキニス
１０９‥‥セル
１１０‥‥凹凸の全くない部分
１１１‥‥ハイグロスニス版に付着したハジキニス、シリコンオイル DESCRIPTION OF SYMBOLS 10 ... Gravure printed matter 11 ... Printing substrate 12 ... Liquid repellency varnish layer, Hajikinis layer 13 ... UV curable high gloss varnish layer 14 ... UV curable high gloss varnish plate, gravure plate 15 ... Printing ink Layer 101 ··· Printing paper 102 ··· Hajikinis 103 ··· Guide roll 104 · Hajikinis and silicon oil 105 adhering to the guide roll · · · Retransferred Hajikinis and silicon oil 106 · · · UV curable high gloss varnish 107 · · · UV curing Type high-gloss varnish plate, gravure plate 108 Hajikinis 109 deposited on the cell 110 cell 110 part with no irregularities 111 Hajikinis, silicon oil adhering to the high-gloss varnish plate

Claims (2)

グラビア印刷法を用いて印刷基材に撥液性を有するニス層を設け、該撥液性を有するニス層の上に、さらに紫外線硬化型ハイグロスニス液を重ね塗りして、紫外線硬化型ハイグロスニス層が部分的に設けられることによりエンボス表現をするグラビア印刷物において、
前記撥液性を有するニス層を構成するハジキニスにアクリル−シリコン共重合体樹脂を使用すると共に、前記紫外線硬化型ハイグロスニス層を構成する紫外線硬化型ハイグロスニス液の希釈溶媒に炭素数６〜１０の脂肪族系溶媒を用いることを特徴とする、グラビア印刷物。 A varnish layer having liquid repellency is provided on a printing substrate using a gravure printing method, and an ultraviolet curable high gloss varnish liquid is further coated on the varnish layer having liquid repellency to form an ultraviolet curable high gloss varnish. In the gravure printed material that is embossed by partially providing a layer,
An acrylic-silicone copolymer resin is used for hajikinis that constitutes the liquid-repellent varnish layer, and a dilution solvent of the ultraviolet-curable high-gloss varnish solution that constitutes the ultraviolet-curable high-gloss varnish layer has 6 to 10 carbon atoms. A gravure printed material, characterized by using an aliphatic solvent. 請求項１記載のグラビア印刷物を用いた紙容器。   A paper container using the gravure printed matter according to claim 1.
JP2005292191A 2005-10-05 2005-10-05 Gravure printed matter and paper container using it Expired - Fee Related JP4784246B2 (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007276326A (en) * 2006-04-10 2007-10-25 Dainippon Printing Co Ltd Printed matter and its manufacturing method
JP2015030513A (en) * 2013-08-02 2015-02-16 日本製紙クレシア株式会社 Tissue paper storage box and tissue paper storage box package
JP2015040068A (en) * 2013-08-23 2015-03-02 凸版印刷株式会社 Paper container
JP2015139927A (en) * 2014-01-28 2015-08-03 凸版印刷株式会社 Printed matter and packaging material using the same
JP2015180711A (en) * 2014-03-06 2015-10-15 Ｄｉｃグラフィックス株式会社 Ink composition and laminated coating film

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Publication number Priority date Publication date Assignee Title
JPS62290573A (en) * 1986-06-11 1987-12-17 Dainippon Printing Co Ltd Manufacture of polypropylene molded form applied with printing
JPH06278354A (en) * 1992-11-10 1994-10-04 Shinsuidou:Kk Surface processed print painted matter having uneven pattern
JP2003181370A (en) * 2001-12-20 2003-07-02 Dainippon Printing Co Ltd Matted print with rugged touch and its processing method
JP2004114654A (en) * 2002-09-30 2004-04-15 Toppan Printing Co Ltd Printed matter and packaging material using it

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62290573A (en) * 1986-06-11 1987-12-17 Dainippon Printing Co Ltd Manufacture of polypropylene molded form applied with printing
JPH06278354A (en) * 1992-11-10 1994-10-04 Shinsuidou:Kk Surface processed print painted matter having uneven pattern
JP2003181370A (en) * 2001-12-20 2003-07-02 Dainippon Printing Co Ltd Matted print with rugged touch and its processing method
JP2004114654A (en) * 2002-09-30 2004-04-15 Toppan Printing Co Ltd Printed matter and packaging material using it

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007276326A (en) * 2006-04-10 2007-10-25 Dainippon Printing Co Ltd Printed matter and its manufacturing method
JP2015030513A (en) * 2013-08-02 2015-02-16 日本製紙クレシア株式会社 Tissue paper storage box and tissue paper storage box package
JP2015040068A (en) * 2013-08-23 2015-03-02 凸版印刷株式会社 Paper container
JP2015139927A (en) * 2014-01-28 2015-08-03 凸版印刷株式会社 Printed matter and packaging material using the same
JP2015180711A (en) * 2014-03-06 2015-10-15 Ｄｉｃグラフィックス株式会社 Ink composition and laminated coating film

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