JP2007082463A - Edible foaming agent and method for producing the same - Google Patents

Edible foaming agent and method for producing the same Download PDF

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JP2007082463A
JP2007082463A JP2005275083A JP2005275083A JP2007082463A JP 2007082463 A JP2007082463 A JP 2007082463A JP 2005275083 A JP2005275083 A JP 2005275083A JP 2005275083 A JP2005275083 A JP 2005275083A JP 2007082463 A JP2007082463 A JP 2007082463A
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fatty acid
foaming agent
acid ester
oil
particle size
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JP4535977B2 (en
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Yoshihisa Hatano
善久 幡野
Hisae Aomori
久恵 青森
Akira Ota
晶 太田
Kazuhiko Kuwata
和彦 桑田
Akiteru Matsumoto
晁暎 松本
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Miyoshi Yushi KK
Miyoshi Oil and Fat Co Ltd
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Miyoshi Yushi KK
Miyoshi Oil and Fat Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an edible foaming agent having a good dispersing property even when the temperature of a dough is low, making stable formation of air bubbles each having a moderate size in the dough, and excellent in palate feeling, flavor, melting feeling in the mouth and the like so as to produce air bubble-containing food such as cakes. <P>SOLUTION: The edible foaming agent comprises O/W-type emulsified substance, contains sugar alcohol, lecithin as an emulsifying agent, sucrose fatty acid ester and glycerine fatty acid monoester, wherein the emulsified oil and fat grains have two granular-diameter distributions comprising a granular-diameter distribution having its peak at <5 μm, and that having its peak at 5-20 μm. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、スポンジケーキ等の気泡含有食品を製造する際に用いる食用起泡剤に関し、生地中の気泡を安定化させて適度な大きさの気泡を形成することができ、食感、風味、口溶けの良い気泡含有食品を得ることのできる食用起泡剤に関する。   The present invention relates to an edible foaming agent used when producing a bubble-containing food such as sponge cake, and can stabilize bubbles in a dough to form bubbles of an appropriate size, texture, flavor, The present invention relates to an edible foaming agent capable of obtaining a bubble-containing food that melts well in the mouth.

スポンジケーキ、パウンドケーキ等のケーキ類の気泡構造は卵の起泡力を利用して形成されているが、起泡構造はケーキ類の食感、ボリューム感の良否を左右するため、起泡力を高めたり気泡を安定化させるため、生地中に起泡剤を添加使用している。この種の起泡剤としては、グリセリン脂肪酸エステルと、HLB7以上の蔗糖脂肪酸エステルとを特定の比率で含む水中油型乳化物よりなる起泡剤(特許文献1)、蔗糖脂肪酸エステルと、HLB9以上のポリグリセリン脂肪酸エステルとを特定の割合で含み、平均乳化粒子径が3〜15μmの水中油型乳化物よりなる起泡剤(特許文献2)、グリセリン脂肪酸モノエステル、HLB7以上の蔗糖脂肪酸エステル、有機モノグリセライド及び/又はポリグリセリン脂肪酸エステルを特定の割合で含む水中油型乳化物よりなる起泡剤(特許文献3)等が提案されている。   The foam structure of cakes such as sponge cakes and pound cakes is formed by using the foaming power of eggs, but the foaming structure influences the quality of the cake's texture and volume. A foaming agent is added to the dough to increase the air flow and stabilize the bubbles. As this type of foaming agent, a foaming agent (Patent Document 1) consisting of an oil-in-water emulsion containing glycerin fatty acid ester and sucrose fatty acid ester of HLB7 or higher in a specific ratio, sucrose fatty acid ester, and HLB9 or higher A polyglycerin fatty acid ester in a specific ratio and a foaming agent (Patent Document 2) comprising an oil-in-water emulsion having an average emulsion particle size of 3 to 15 μm, a glycerin fatty acid monoester, a sucrose fatty acid ester of HLB7 or higher, The foaming agent (patent document 3) etc. which consist of an oil-in-water type emulsion which contains organic monoglyceride and / or polyglycerol fatty acid ester in a specific ratio are proposed.

特開平6−339340号公報JP-A-6-339340 特開平9−201160号公報JP-A-9-201160 特開平7−327597号公報Japanese Patent Laid-Open No. 7-327597

しかしながら、特許文献1に記載されている起泡剤は、気泡を微細化し過ぎるためにケーキのキメが細かくなり過ぎて、食感が損なわれる虞があった。また特許文献2に記載されている起泡剤は、ホイップ時間が一定とならないため作業性が悪いという問題があり、特許文献3に記載の起泡剤もホイップ時間が一定にならないという問題と共に、低温において生地中への分散が悪いという問題があった。また上記した起泡剤を用いる場合でも、ケーキ類の風味を高めるためにケーキ生地に卵を添加することが多い。しかしながら、冷蔵庫で保存されていた低温の卵を生地に添加すると生地温度が低くなりこの結果、生地の粘度が低くなって起泡剤の分散が悪くなり、ミキシング時間が長くなると小麦粉中のグルテンが溶出してケーキに曳きがでたり、ケーキの目が細かくなって色が悪いケーキとなる等の問題がある。このため生地温度が低下しないように温度調節する等の煩雑な作業が必要となるといった問題があった。   However, the foaming agent described in Patent Document 1 has a risk that the texture of the cake is impaired because the texture of the cake becomes too fine because the bubbles are too fine. In addition, the foaming agent described in Patent Document 2 has a problem that workability is poor because the whipping time is not constant, and the foaming agent described in Patent Document 3 also has a problem that the whipping time is not constant, There was a problem of poor dispersion in the dough at low temperatures. Even when the above-mentioned foaming agent is used, eggs are often added to the cake dough in order to enhance the flavor of the cakes. However, adding low-temperature eggs stored in the refrigerator to the dough will lower the dough temperature, resulting in lower dough viscosity and poor foaming dispersion, and longer mixing time will result in gluten in the flour. There are problems such as elution and whispering on the cake, and the cake has a fine color and becomes a cake with a poor color. For this reason, there has been a problem that complicated work such as temperature adjustment is required so that the dough temperature does not decrease.

本発明者等は上記課題を解決すべく鋭意研究した結果、油脂粒子が2つの粒子径分布を有するように乳化分散されている水中油型乳化物が、上記従来技術の欠点を解決できることを見出し、本発明を完成するに至った。   As a result of diligent research to solve the above-mentioned problems, the present inventors have found that an oil-in-water emulsion in which oil and fat particles are emulsified and dispersed so as to have two particle size distributions can solve the above-mentioned disadvantages of the prior art. The present invention has been completed.

即ち本発明は、
(1)O/W型乳化物であって、糖アルコールと、乳化剤としてレシチン、蔗糖脂肪酸エステル及びグリセリン脂肪酸モノエステルとを含み、乳化されている油脂粒子が、5μm未満に頂点を有する粒径分布と、5μm以上、20μm以下に頂点を有する粒径分布の2つの粒径分布を有することを特徴とする食用起泡剤、
(2)乳化剤として、更にプロピレングリコール脂肪酸エステル及び/又はポリグリセリン脂肪酸エステルを含有する上記(1)の食用起泡剤、
(3)糖アルコール及び、乳化剤としてレシチン、グリセリン脂肪酸モノエステル、蔗糖脂肪酸エステルを含む糖濃度60以上の水相を60〜80℃にし、この水相に60〜80℃の油相を添加し、乳化して保持し、次いで昇温して80〜100℃に保持した後、冷却することを特徴とする食用起泡剤の製造方法、
を要旨とする。
That is, the present invention
(1) O / W type emulsion, comprising sugar alcohol, lecithin, sucrose fatty acid ester and glycerin fatty acid monoester as emulsifiers, and the emulsified fat particles have an apex of less than 5 μm And an edible foaming agent characterized by having two particle size distributions having a particle size distribution having an apex at 5 μm or more and 20 μm or less,
(2) The edible foaming agent according to (1), which further contains propylene glycol fatty acid ester and / or polyglycerin fatty acid ester as an emulsifier,
(3) Sugar alcohol and lecithin, glycerin fatty acid monoester, sucrose fatty acid ester as an emulsifier, a sugar phase of 60 or more water phase containing 60 to 80 ° C., an oil phase of 60 to 80 ° C. is added to this water phase, Emulsified and held, then heated and held at 80 to 100 ° C., and then cooled, a method for producing an edible foaming agent,
Is the gist.

本発明の食用起泡剤は、ケーキ生地への添加量が少なくても優れた起泡性を発揮し、低温で粘度が低い生地への分散性が良いため、ケーキ類を製造する際の作業性を向上できるとともに、ミキシング時間を一定にすることができるため生産性を向上できる。本発明の食用起泡剤を用いて得た生地はエア抜けや生地の分離などが起こりにくいなど安定性が良く、香料、着色料を添加しなくても共立て法ような色合い、粗いキメ、卵風味を有し、食感、口溶け感に優れたケーキ類を得ることができる。   The edible foaming agent of the present invention exhibits excellent foaming properties even when the amount added to the cake dough is small, and has good dispersibility in the dough having a low viscosity at a low temperature. The productivity can be improved because the mixing time can be made constant. The dough obtained using the edible foaming agent of the present invention has good stability such that air bleed or dough separation is unlikely to occur. Cakes having an egg flavor and excellent texture and melting feeling can be obtained.

本発明の食用起泡剤に用いる食用油脂としては、例えば大豆油、ナタネ油、綿実油、コーン油、サフラワー油、ひまわり油、ピーナッツ油、オリーブ油、米糠油等の植物油脂、魚油、牛脂、豚脂等の動物油脂、植物油脂や動物油脂のエステル交換油、上記動植物油脂、エステル交換油に水素添加した硬化油等が挙げられる。上記食用油脂は1種又は2種以上を混合して用いることができる。食用油脂としては常温で液状である大豆油、ナタネ油、綿実油、コーン油、サフラワー油、ひまわり油、ピーナッツ油、オリーブ油、米糠油等の植物油脂が好ましい。   Examples of edible fats and oils used in the edible foaming agent of the present invention include vegetable oils such as soybean oil, rapeseed oil, cottonseed oil, corn oil, safflower oil, sunflower oil, peanut oil, olive oil, rice bran oil, fish oil, beef tallow, pork Examples thereof include animal oils and fats such as fats, transesterified oils of vegetable oils and animal fats and oils, animal and vegetable oils and fats, hydrogenated hydrogenated oils, and the like. The said edible fats and oils can be used 1 type or in mixture of 2 or more types. As edible oils and fats, vegetable oils such as soybean oil, rapeseed oil, cottonseed oil, corn oil, safflower oil, sunflower oil, peanut oil, olive oil, rice bran oil and the like which are liquid at normal temperature are preferable.

本発明の起泡剤は、水中油型に乳化されている油脂粒子が、5μm未満に頂点を有する粒径分布と、5μm以上、20μm以下に頂点を有する粒径分布の、2つの粒径分布を有する粒度で分散されていることが必要であるが、1〜3μm未満に頂点を有する粒径分布と、8μm〜15μmに頂点を有する粒径分布を有する粒度で分散されていることが好ましい。乳化されている油脂粒子が1つの粒径分布しか有さない場合や、2つの粒径分布を有していても一方、又は両方の頂点が上記した範囲から外れる場合には、ミキシング時間が一定とならない、ケーキのキメが細かくなりすぎたり、粗くなりすぎて場合によっては芯の発生を伴うことがある。起泡剤の粒度分布測定は、SHIMADZU SALD2100(レーザー回折式粒度分布測定装置)を使用し、起泡剤をイオン交換水に分散し、屈折率:1.50−0.10iの条件にて測定を行うのが良い。   The foaming agent of the present invention has two particle size distributions, ie, a particle size distribution in which oil and fat particles emulsified in an oil-in-water type have an apex at less than 5 μm and a particle size distribution with an apex at 5 μm or more and 20 μm or less. It is necessary to be dispersed with a particle size distribution having a particle size distribution having an apex at less than 1 to 3 μm and a particle size distribution having an apex at 8 μm to 15 μm. When the emulsified fat and oil particles have only one particle size distribution, or when one or both vertices are out of the above range even if they have two particle size distributions, the mixing time is constant. The texture of the cake is not too fine or too coarse, and in some cases it may be accompanied by the formation of wicks. The particle size distribution of the foaming agent is measured using SHIMADZU SALD2100 (laser diffraction particle size distribution measuring device), the foaming agent is dispersed in ion-exchanged water, and the refractive index is 1.50 to 0.10i. Good to do.

本発明の起泡剤に用いられる糖アルコールとしては、ソルビトール、エリスリトール、マンニット、キシリトール、マルチトール、ラクチトール、パラニット、還元水飴等が挙げられる。これらの糖アルコールのうち、ソルビトールが好ましい。   Examples of the sugar alcohol used in the foaming agent of the present invention include sorbitol, erythritol, mannitol, xylitol, maltitol, lactitol, paranit, reduced starch syrup and the like. Of these sugar alcohols, sorbitol is preferred.

本発明の起泡剤は、上記糖アルコールを10〜50重量%、レシチンを0.1〜2.0重量%、蔗糖脂肪酸エステルを3.0〜4.0重量%、グリセリン脂肪酸モノエステルを2〜9重量%含有することが好ましい。糖アルコールや乳化剤の量が上記範囲から外れると、乳化サイズが小さくなりすぎたり、分散性が悪くなり、乳化物がケーキ生地に分散しにくくなり、そのため、ミキシング時間が長くなりケーキの目が細かくなり、ケーキの食感に曳きが出たり、ねちゃついたりする虞がある。また本発明の起泡剤は糖濃度が60以上であることが好ましく、糖濃度60未満の場合、2つの粒度分布が維持され難くなる。尚、上記糖濃度は糖濃度計によって測定した値である。乳化剤として用いられるレシチンとしては、酵素処理レシチン、酵素分解レシチン、大豆レシチン、卵黄レシチン等が挙げられるこれらのレシチンの内、特に大豆レシチン、卵黄レシチンが好ましい。蔗糖脂肪酸エステルとしては、構成脂肪酸の主体がミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸が挙げられる。これらのうち、ステアリン酸が気泡を安定させる上で好ましい。グリセリン脂肪酸モノエステルとしては、例えば、構成脂肪酸の主体がミリスチン酸、パルミチン酸、ステアリン酸等の脂肪酸とグリセリンとのモノエステルが挙げられるが、パルミチン酸、ステアリン酸のモノエステルが気泡を安定させる上で好ましい。   The foaming agent of the present invention comprises 10-50% by weight of the above sugar alcohol, 0.1-2.0% by weight of lecithin, 3.0-4.0% by weight of sucrose fatty acid ester, and 2 of glycerin fatty acid monoester. It is preferable to contain -9 weight%. If the amount of sugar alcohol or emulsifier is out of the above range, the emulsified size becomes too small, the dispersibility becomes worse, and the emulsified product becomes difficult to disperse in the cake dough, so the mixing time becomes longer and the cake eyes become finer There is a risk that the texture of the cake will be whispered or sticky. Further, the foaming agent of the present invention preferably has a sugar concentration of 60 or more. When the sugar concentration is less than 60, it is difficult to maintain two particle size distributions. The sugar concentration is a value measured with a sugar concentration meter. As lecithin used as an emulsifier, among these lecithins including enzyme-treated lecithin, enzyme-decomposed lecithin, soybean lecithin, egg yolk lecithin and the like, soybean lecithin and egg yolk lecithin are particularly preferable. Examples of the sucrose fatty acid ester include myristic acid, palmitic acid, stearic acid, and oleic acid as the main constituent fatty acids. Of these, stearic acid is preferred for stabilizing the bubbles. Examples of glycerin fatty acid monoesters include monoesters of fatty acids such as myristic acid, palmitic acid, and stearic acid, and glycerin, which are the main constituent fatty acids, but the monoester of palmitic acid and stearic acid stabilizes bubbles. Is preferable.

本発明の起泡剤には、上記乳化剤の他に更にプロピレングリコール脂肪酸エステル及び/又はポリグリセリン脂肪酸エステルを乳化剤として含んでいると、乳化物の乳化性や物性、食感の改良の点で好ましい。プロピレングリコール脂肪酸エステルとしては、構成脂肪酸の主体がベヘン酸、ステアリン酸、オレイン酸、ミリスチン酸などが挙げられる。これらのうちベヘン酸が好ましい。またポリグリセリン脂肪酸エステルとしては、エステル化度が1〜10が好ましく、構成脂肪酸の主体としては、例えばラウリン酸、ミリスチン酸、オレイン酸、ステアリン酸等が挙げられる。またグリセリンの重合度としては2〜10の範囲が挙げられる。これらのうち、モノステアリン酸のデカグリセリンが好ましい。プロピレングリコール脂肪酸エステル、ポリグリセリン脂肪酸エステルは2種以上を併用することができる。プロピレングリコール脂肪酸エステル及び/又はポリグリセリン脂肪酸エステルを用いる場合、これらの割合はプロピレングリコール脂肪酸エステルは、2.4〜4.0重量%、ポリグリセリン脂肪酸エステル0.5〜2.0重量%が好ましい。   The foaming agent of the present invention preferably contains propylene glycol fatty acid ester and / or polyglycerin fatty acid ester as an emulsifier in addition to the above emulsifiers, from the viewpoint of improving emulsifying properties, physical properties and texture of the emulsion. . As propylene glycol fatty acid esters, constituent fatty acids mainly include behenic acid, stearic acid, oleic acid, myristic acid and the like. Of these, behenic acid is preferred. The polyglycerin fatty acid ester preferably has an esterification degree of 1 to 10, and examples of constituent fatty acids include lauric acid, myristic acid, oleic acid, stearic acid, and the like. Moreover, the range of 2-10 is mentioned as a polymerization degree of glycerol. Of these, monostearic acid decaglycerin is preferred. Two or more of propylene glycol fatty acid esters and polyglycerin fatty acid esters can be used in combination. When using propylene glycol fatty acid ester and / or polyglycerin fatty acid ester, the proportion of propylene glycol fatty acid ester is preferably 2.4 to 4.0% by weight, and polyglycerin fatty acid ester 0.5 to 2.0% by weight. .

本発明の起泡剤は、上記成分の他に必要に応じて更に増粘多糖類、着色料、香料等を含有していても良い。起泡剤中におけるこれら成分の割合は起泡性、食感を損なわない程度が好ましい。   The foaming agent of the present invention may further contain a thickening polysaccharide, a coloring agent, a fragrance, and the like as necessary in addition to the above components. The ratio of these components in the foaming agent is preferably such that foamability and texture are not impaired.

本発明の起泡剤は、糖アルコール及び、レシチン、グリセリン脂肪酸モノエステル、蔗糖脂肪酸エステルを含む糖濃度60以上の水相を60〜80℃にし、これに60〜80℃の油相を添加して水中油型に乳化し保持し、その後昇温して80〜100℃に保持した後、冷却することにより得ることができる。好ましくは水相の保持としては60〜80℃で10分〜30分保持することが好ましい。また、水中油型に乳化した後は80〜100℃で10分〜30分保持することが好ましい。起泡剤製造に際して乳化剤として更にプロピレングリコール脂肪酸エステル、ポリグリセリン脂肪酸エステルを用いる場合、プロピレングリコール脂肪酸エステルは油相中に、ポリグリセリン脂肪酸エステルは水相中に添加することが好ましい。レシチンを乳化剤として用いた水中油型乳化物を製造する場合、従来はレシチンを油相に添加して乳化を行っているが、本発明ではレシチンを添加する水相として、糖アルコールを含む糖濃度60以上の水相を用いることにより、安定した2つの粒径分布を有する乳化物が得られる。水相に油相を乳化するに際し、プロペラ攪拌式の乳化機等が用いられる。また乳化物を昇温保持後、冷却するためにボテーター、コンビネーター、パーフェクター等が用いられる。   In the foaming agent of the present invention, an aqueous phase having a sugar concentration of 60 or more containing sugar alcohol, lecithin, glycerin fatty acid monoester and sucrose fatty acid ester is brought to 60 to 80 ° C., and an oil phase of 60 to 80 ° C. is added thereto. And then emulsified and held in an oil-in-water type, and then heated to 80 to 100 ° C. and then cooled. The aqueous phase is preferably maintained at 60 to 80 ° C. for 10 to 30 minutes. Moreover, after emulsifying in an oil-in-water type, it is preferable to hold | maintain at 80-100 degreeC for 10 minutes-30 minutes. When a propylene glycol fatty acid ester or a polyglycerin fatty acid ester is further used as an emulsifier in the production of the foaming agent, it is preferable to add the propylene glycol fatty acid ester into the oil phase and the polyglycerin fatty acid ester into the aqueous phase. When producing an oil-in-water emulsion using lecithin as an emulsifier, conventionally, lecithin is added to the oil phase for emulsification, but in the present invention, the sugar concentration containing sugar alcohol is used as the aqueous phase to which lecithin is added. By using 60 or more aqueous phases, an emulsion having two stable particle size distributions can be obtained. When emulsifying the oil phase in the aqueous phase, a propeller stirring type emulsifier or the like is used. In addition, a botator, a combinator, a perfector, or the like is used to cool the emulsion after raising the temperature.

以下、実施例を挙げて本発明を更に詳細に説明する。
実施例1〜6
表1に示す配合に基づき、室温において水相部の糖アルコール水溶液を調製した後、水相部の乳化剤を添加した。その後、昇温し62℃〜67℃の温度領域で、油相を添加して水中油型に乳化し10分間保持し、プロペラ攪拌を使用し乳化を行った。次いで昇温速度を1℃〜3℃/minで90〜95℃まで昇温して10分〜20分間保持し乳化サイズを整えた後、室温放置後調温庫に保管し15℃まで冷却した。得られた乳化物における油脂粒子の粒径分布を、SHIMADZU SALD2100(レーザー回折式粒度分布測定装置)を使用し、起泡剤をイオン交換水に分散して屈折率:1.50−0.10iの条件にて測定を測定したところ、2つの粒径分布を有していた。各粒径分布のピークに相当する粒径を表3に示した。
Hereinafter, the present invention will be described in more detail with reference to examples.
Examples 1-6
Based on the formulation shown in Table 1, an aqueous sugar alcohol aqueous solution was prepared at room temperature, and then an aqueous emulsifier was added. Thereafter, the temperature was raised, and in the temperature range of 62 ° C. to 67 ° C., an oil phase was added to emulsify in an oil-in-water type and held for 10 minutes, and emulsification was performed using propeller stirring. Next, the temperature was increased from 90 ° C. to 95 ° C. at a rate of 1 ° C. to 3 ° C./min and held for 10 minutes to 20 minutes to adjust the emulsified size. . The particle size distribution of the fat and oil particles in the obtained emulsion was measured using a SHIMADZU SALD2100 (laser diffraction particle size distribution measuring device), and the foaming agent was dispersed in ion-exchanged water to have a refractive index of 1.50-0.10i. When the measurement was performed under the above conditions, it had two particle size distributions. Table 3 shows the particle size corresponding to the peak of each particle size distribution.

Figure 2007082463
Figure 2007082463

表1において使用した各乳化剤は以下の通りである。
グリセリン脂肪酸モノエステル:理研ビタミン社製エマルジーMS
蔗糖脂肪酸エステル:三菱化学フーズ社製リョートーシュガーエステルS1170
ポリグリセリン脂肪酸エステル:太陽化学社製サンソフトQ18S
レシチン:エーディーエムファーイースト社製ウルトラレックP
プロピレングリコール脂肪酸エステル:理研ビタミン社製リケマールPB−100
Each emulsifier used in Table 1 is as follows.
Glycerin fatty acid monoester: Emergy MS made by Riken Vitamin
Sucrose fatty acid ester: Ryoto Sugar Ester S1170 manufactured by Mitsubishi Chemical Foods
Polyglycerin fatty acid ester: Sunsoft Q18S manufactured by Taiyo Kagaku
Lecithin: Ultrameck P manufactured by ADM Far East
Propylene glycol fatty acid ester: Rikenmar PB-100 manufactured by Riken Vitamin

比較例1〜4
表2に示す配合に基づき、比較例1〜3は室温において糖アルコール水溶液を調製した後、乳化剤を添加して水相部を調製した。また比較例4は室温において還元でん粉糖化物水溶液を調製した後、乳化剤を添加して水相部を調製した。但し、比較例1は蔗糖脂肪酸エステルを添加せず、比較例2は、グリセリン脂肪酸モノエステルを添加せず、比較例3はレシチンを添加せずにそれぞれ水相部を調製した。ついで水相部を昇温し62℃〜67℃の温度領域で、プロペラ攪拌しながら油相を添加して10分間保持し水中油型に乳化した。次いで昇温速度1℃〜3℃/minで90〜95℃まで乳化物を昇温して10分〜20分間保持し乳化サイズを整えた後、室温放置後調温庫に保管し15℃まで冷却した。比較例1は乳化物が得られず、乳化物が得られた比較例2〜4について油脂粒子の粒径分布を、SHIMADZU SALD2100(レーザー回折式粒度分布測定装置)を使用し、起泡剤をイオン交換水に分散して屈折率:1.50−0.10iの条件にて測定を測定したところ、2つの粒径分布を有していた。各粒径分布のピークに相当する粒径を表3に示した。
Comparative Examples 1-4
Based on the formulation shown in Table 2, Comparative Examples 1 to 3 prepared an aqueous sugar alcohol solution at room temperature, and then added an emulsifier to prepare an aqueous phase part. In Comparative Example 4, a reduced starch saccharified aqueous solution was prepared at room temperature, and then an emulsifier was added to prepare an aqueous phase part. However, Comparative Example 1 did not add sucrose fatty acid ester, Comparative Example 2 did not add glycerin fatty acid monoester, and Comparative Example 3 prepared an aqueous phase part without adding lecithin. Next, the temperature of the aqueous phase was raised, and in the temperature range of 62 ° C. to 67 ° C., the oil phase was added with propeller stirring and held for 10 minutes to emulsify into an oil-in-water type. Next, the emulsion is heated to 90 to 95 ° C. at a temperature rising rate of 1 ° C. to 3 ° C./min and held for 10 to 20 minutes to adjust the emulsified size. Cooled down. In Comparative Example 1, an emulsion was not obtained, and for Comparative Examples 2 to 4 in which an emulsion was obtained, the particle size distribution of the fat and oil particles was measured using a SHIMADZU SALD2100 (laser diffraction particle size distribution measuring device), and a foaming agent was used. When dispersed in ion-exchanged water and measured under the conditions of refractive index: 1.50-0.10i, it had two particle size distributions. Table 3 shows the particle size corresponding to the peak of each particle size distribution.

(表2)

Figure 2007082463
(Table 2)
Figure 2007082463

表2において使用した乳化剤は以下の通りである。
グリセリン脂肪酸モノエステル:理研ビタミン社製エマルジーMS
蔗糖脂肪酸エステル:三菱化学フーズ社製リョートーシュガーエステルS1170
ポリグリセリン脂肪酸エステル:太陽化学社製サンソフトQ18S
レシチン:エーディーエムファーイースト社製ウルトラレックP
プロピレングリコール脂肪酸エステル:理研ビタミン社製リケマールPB−100
The emulsifiers used in Table 2 are as follows.
Glycerin fatty acid monoester: Emergy MS made by Riken Vitamin
Sucrose fatty acid ester: Ryoto Sugar Ester S1170 manufactured by Mitsubishi Chemical Foods
Polyglycerin fatty acid ester: Sunsoft Q18S manufactured by Taiyo Kagaku
Lecithin: Ultrameck P manufactured by ADM Far East
Propylene glycol fatty acid ester: Rikenmar PB-100 manufactured by Riken Vitamin

(表3)

Figure 2007082463
(Table 3)
Figure 2007082463

上記実施例1〜6、比較例2〜4の各乳化物を起泡剤として用い、以下の配合・条件にてスポンジケーキを焼成した。
スポンジケーキ配合
薄力粉 100重量部
砂糖 110重量部
全卵 160重量部
水 25重量部
ベーキングパウダー 1重量部
起泡剤 12重量部
生地は関東ミキサーに20クォートミキサーボールと攪拌羽を用い、オールイン法で低速で15秒間ミキシングした後、中高速で生地比重が0.45に達するまでホイップして調製した。得られた生地を7号のデコ型に500g充填し、160℃のオーブンで40分間焼成した。実施例1〜6の起泡剤の生地への分散性、ホイップ時間、得られたスポンジケーキの評価を表4に、比較例2〜4の起泡剤の生地への分散性、ホイップ時間、得られたスポンジケーキの評価を表5に示す。
Sponge cakes were fired under the following formulation and conditions using the emulsions of Examples 1 to 6 and Comparative Examples 2 to 4 as foaming agents.
Sponge cake formulation Soft flour 100 parts by weight Sugar 110 parts by weight Whole egg 160 parts by weight Water 25 parts by weight Baking powder 1 part by weight Foaming agent 12 parts by weight Using a 20-quarter mixer ball and stirring blades in a Kanto mixer, all-in After mixing at low speed for 15 seconds, it was prepared by whipping at medium to high speed until the dough specific gravity reached 0.45. The obtained dough was filled in 500 g in a No. 7 deco mold and baked in an oven at 160 ° C. for 40 minutes. Dispersibility of the foaming agents of Examples 1 to 6 into the dough, whipping time, evaluation of the obtained sponge cake in Table 4, dispersibility of the foaming agents of Comparative Examples 2 to 4 into the dough, whipping time, The evaluation of the obtained sponge cake is shown in Table 5.

(表4)

Figure 2007082463
(Table 4)
Figure 2007082463

(表5)

Figure 2007082463
(Table 5)
Figure 2007082463

生地への分散性
起泡剤以外の原料の仕込み品温を5℃にし、オールインミックス法で生地を作成した際に、
○・・1分以内に生地中に分散する。
×・・分散に1分以上を要する。
として評価した。
Dispersibility in the dough When the temperature of the raw materials other than the foaming agent is 5 ° C and the dough is made by the all-in-mix method,
○ ・ ・ Disperses in the dough within 1 minute.
× ·· Dispersion takes 1 minute or more.
As evaluated.

ホイップ時間
ホイップ時間は、生地をすべてミキサーボールに仕込み始め低速で15秒攪拌後、中高速にてホイップして0.45になる時間までに要した合計時間とした。
Whipping time The whipping time was defined as the total time required to start the preparation of all the dough into the mixer ball, stir at low speed for 15 seconds, and then whip at medium to high speed to reach 0.45.

スポンジケーキの風味、口溶けは、パネラー10名が以下の基準で評価した。
評価は、各人個別に他人の評価に影響されないように評価した。評価は、各項目について4段階(3点、2点、1点、0点)でそれぞれ評価をした。
スポンジケーキの風味
3点・・卵の味が非常に良く出ており、乳化剤の味がしない。
2点・・卵の味が出ており、乳化剤の味がしない。
1点・・卵の味が出ていないが、乳化剤の味はしない。
0点・・卵の味が出ておらず、乳化剤の味もする。
スポンジケーキの口溶け
3点・・生地がさっと口から溶けてなくなる
2点・・生地にネチャツキが無く口から溶けてなくなる。
1点・・生地がネチャツクが口から溶けてなくなる。
0点・・生地がネチャツキ、いつまでも口の中に存在する。
評価の基準として総合点が、25点以上が◎、20点〜24点が○、15点〜19点が△、14点以下=×とした。
The taste of sponge cake and melting in the mouth were evaluated by 10 panelists according to the following criteria.
The evaluation was made so that each person was not influenced by the evaluation of others. Each item was evaluated in four stages (3 points, 2 points, 1 point, 0 points).
Sponge cake flavor 3 points ・ ・ The taste of egg is very good and there is no emulsifier.
2 points ... The taste of the egg is coming out and there is no taste of the emulsifier.
1 point ・ ・ No egg taste, but no emulsifier taste.
0 points. ・ No egg taste and emulsifier taste.
Sponge cake melts in the mouth 3 points ... The dough melts quickly from the mouth 2 points ... The dough has no stickiness and melts out of the mouth.
1 point ... The dough melts away from the mouth.
0 points ... The dough is sticky and will always exist in the mouth.
As the evaluation standard, 25 or more points were evaluated as ◎, 20 to 24 points as ◯, 15 to 19 points as Δ, and 14 points or less = ×.

内相の状態
スポンジケーキを縦方向と横方向に切りそれぞれ切断面を目視し内相状態を確認し、以下の基準で評価した。
◎・・キメが均一に開き、黄色
○・・キメが比較的細かく、黄色み薄い
△・・キメが非常に細かく白色
×・・キメが壊れていて商品価値なし
State of inner phase The sponge cake was cut in the longitudinal direction and the transverse direction, the cut surfaces were visually observed to confirm the inner phase state, and the evaluation was performed according to the following criteria.
◎ ・ ・ Texture opens uniformly, yellow ○ ・ ・ Texture is relatively fine, yellowish pale △ ・ ・ Texture is very fine and white × ・ ・ Texture is broken and there is no commercial value

Claims (3)

O/W型乳化物であって、糖アルコールと、乳化剤としてレシチン、蔗糖脂肪酸エステル及びグリセリン脂肪酸モノエステルとを含み、乳化されている油脂粒子が、5μm未満に頂点を有する粒径分布と、5μm以上、20μm以下に頂点を有する粒径分布の2つの粒径分布を有することを特徴とする食用起泡剤。 O / W type emulsion, comprising sugar alcohol and lecithin, sucrose fatty acid ester and glycerin fatty acid monoester as emulsifiers, and the emulsified fat particles have a particle size distribution having a peak at less than 5 μm and 5 μm As described above, an edible foaming agent having two particle size distributions having a particle size distribution having an apex of 20 μm or less. 乳化剤として、更にプロピレングリコール脂肪酸エステル及び/又はポリグリセリン脂肪酸エステルを含有する請求項1記載の食用起泡剤。 The edible foaming agent according to claim 1, further comprising propylene glycol fatty acid ester and / or polyglycerin fatty acid ester as an emulsifier. 糖アルコール及び、乳化剤としてレシチン、グリセリン脂肪酸モノエステル、蔗糖脂肪酸エステルを含む糖濃度60以上の水相を60〜80℃にし、この水相に60〜80℃の油相を添加し、乳化して保持し、次いで昇温して80〜100℃に保持した後、冷却することを特徴とする食用起泡剤の製造方法。
The aqueous phase containing sugar alcohol and lecithin, glycerin fatty acid monoester, sucrose fatty acid ester as an emulsifier and having a sugar concentration of 60 or more is adjusted to 60 to 80 ° C., and an oil phase of 60 to 80 ° C. is added to the aqueous phase and emulsified. A method for producing an edible foaming agent, comprising: holding, then raising the temperature and holding at 80 to 100 ° C., followed by cooling.
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JP2009095246A (en) * 2007-10-12 2009-05-07 Adeka Corp Foamable emulsifier composition for cake
JP2009165369A (en) * 2008-01-11 2009-07-30 Kaneka Corp Foaming emulsified oil-and-fat composition and method for producing the same
JP2010110250A (en) * 2008-11-05 2010-05-20 Kaneka Corp Foaming emulsified oil-and-fat composition, and cake using this composition
JP2014036630A (en) * 2012-08-20 2014-02-27 Kao Corp Oil-in-water type emulsion composition
CN109527125A (en) * 2018-12-05 2019-03-29 天津南侨食品有限公司 A kind of liquid milk carburetion and its preparation method and application

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JPH11187836A (en) * 1997-12-26 1999-07-13 Kao Corp Oil-in-water type emulsion composition
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JPH01289465A (en) * 1988-05-14 1989-11-21 Q P Corp Oil-in-water type emulsified food
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Publication number Priority date Publication date Assignee Title
JP2009095246A (en) * 2007-10-12 2009-05-07 Adeka Corp Foamable emulsifier composition for cake
JP2009165369A (en) * 2008-01-11 2009-07-30 Kaneka Corp Foaming emulsified oil-and-fat composition and method for producing the same
JP2010110250A (en) * 2008-11-05 2010-05-20 Kaneka Corp Foaming emulsified oil-and-fat composition, and cake using this composition
JP2014036630A (en) * 2012-08-20 2014-02-27 Kao Corp Oil-in-water type emulsion composition
CN109527125A (en) * 2018-12-05 2019-03-29 天津南侨食品有限公司 A kind of liquid milk carburetion and its preparation method and application
CN109527125B (en) * 2018-12-05 2022-10-11 天津南侨食品有限公司 Liquid emulsified oil and preparation method and application thereof

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