JP2007075061A - Browning restraining agent, and food and drink - Google Patents
Browning restraining agent, and food and drink Download PDFInfo
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- JP2007075061A JP2007075061A JP2005270466A JP2005270466A JP2007075061A JP 2007075061 A JP2007075061 A JP 2007075061A JP 2005270466 A JP2005270466 A JP 2005270466A JP 2005270466 A JP2005270466 A JP 2005270466A JP 2007075061 A JP2007075061 A JP 2007075061A
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Abstract
Description
本発明は、飲食品を保存する際の褐変を抑制するために該飲食品に添加される褐変抑制剤、及び該褐変抑制剤を含有する飲食品に関する。 The present invention relates to a browning inhibitor added to the food or drink in order to suppress browning when the food or drink is stored, and a food or drink containing the browning inhibitor.
飲食品を保存する際の品質低下を抑える技術としては、例えば特許文献1に開示されているような、色と風味に優れた容器入り緑茶飲料の製造方法が知られている。この製造方法は、過熱水蒸気を用いて緑茶の茶葉を無菌化した後、無菌雰囲気下で無菌水により抽出し、抽出液を無菌雰囲気下で容器に充填密封することを特徴とする。また、特許文献2には、製茶後の茶葉を過熱水蒸気にて蒸気抽出することにより得られる揮発性成分について開示されている。
本発明者らは、茶葉の過熱蒸気抽出物の特徴、性質、作用、用途などについて、様々な面から鋭意研究を行った。その結果、驚くべきことに、茶葉の過熱蒸気抽出物には、それ自体の褐変を抑える作用があるとともに、該過熱蒸気抽出物を添加した飲料品の褐変をも抑える作用があることを見出した。そして、これらの知見に基づいて、本発明を完成するに至った。 The present inventors have intensively studied from various aspects about the characteristics, properties, actions, uses, etc. of tea leaves superheated steam extract. As a result, it was surprisingly found that the superheated steam extract of tea leaves has the effect of suppressing browning of itself and also has the effect of suppressing the browning of beverages to which the superheated steam extract is added. . And based on these knowledge, it came to complete this invention.
本発明の目的とするところは、飲食品の褐変を効果的に抑えることができる褐変抑制剤を提供することにある。本発明の別の目的とするところは、褐変しにくい飲食品を提供することにある。 The object of the present invention is to provide a browning inhibitor capable of effectively suppressing browning of food and drink. Another object of the present invention is to provide a food or drink that is not easily browned.
上記の目的を達成するために、請求項1に記載の発明は、飲食品の褐変を抑制するために該飲食品に添加される褐変抑制剤であって、該褐変抑制剤は、茶葉の過熱蒸気抽出物よりなることを要旨とする。 In order to achieve the above object, the invention described in claim 1 is a browning inhibitor added to the food or drink to suppress browning of the food or drink, and the browning inhibitor is a tea leaf overheating. The main point is that it consists of a steam extract.
請求項2に記載の褐変抑制剤は、請求項1に記載の発明において、前記茶葉は、緑茶、ウーロン茶又は紅茶の茶葉であることを要旨とする。
請求項3に記載の褐変抑制剤は、請求項1又は請求項2に記載の発明において、ビタミンCの分解、メイラード反応及び酸化劣化から選ばれる少なくとも一種に起因する前記飲食品の褐変を抑制する作用を有することを要旨とする。
The browning inhibitor according to claim 2 is characterized in that, in the invention according to claim 1, the tea leaves are green tea, oolong tea or tea tea leaves.
The browning inhibitor according to claim 3 suppresses browning of the food or drink resulting from at least one selected from the decomposition of vitamin C, Maillard reaction, and oxidative deterioration in the invention according to claim 1 or claim 2. The gist is to have an action.
請求項4に記載の飲食品は、請求項1から請求項3のいずれか一項に記載の褐変抑制剤を含有することを要旨とする。
請求項5に記載の飲食品は、請求項4に記載の発明において、当該飲食品は、茶類飲料であることを要旨とする。
The gist of the food and drink according to claim 4 is that it contains the browning inhibitor according to any one of claims 1 to 3.
The food and drink according to claim 5 is the gist of the invention according to claim 4, wherein the food and drink is a tea beverage.
本発明によれば、飲食品の褐変を効果的に抑えることができる褐変抑制剤、及び褐変しにくい飲食品を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the browning inhibitor which can suppress the browning of food / beverage products effectively, and the food / beverage products which cannot be easily browned can be provided.
以下、本発明を褐変抑制剤及び飲食品に具体化した一実施形態について説明する。
本実施形態の褐変抑制剤は、茶葉の過熱蒸気抽出物よりなる。この褐変抑制剤は、飲食品に添加するための添加物として主に利用され、ビタミンCの分解、メイラード反応、酸化劣化などに起因する飲食品の褐変の進行を抑える効果を発揮する。よって、本実施形態の褐変抑制剤は、ビタミンC、蛋白質、糖質などの褐変の進行を促進しやすい成分を高い割合で含有する飲食品に添加される場合に特に有効である。
Hereinafter, an embodiment in which the present invention is embodied in a browning inhibitor and a food or drink will be described.
The browning inhibitor of this embodiment consists of a superheated steam extract of tea leaves. This browning inhibitor is mainly used as an additive to be added to foods and drinks, and exhibits the effect of suppressing the progress of browning of foods and drinks due to vitamin C degradation, Maillard reaction, oxidative degradation, and the like. Therefore, the browning inhibitor of this embodiment is particularly effective when it is added to a food or drink containing a high proportion of ingredients that facilitate the progress of browning such as vitamin C, protein, and carbohydrate.
茶葉の過熱蒸気抽出物は、過熱水蒸気を用いて茶葉を蒸気抽出することによって得られるものである。前記茶葉としては、通常、摘み取った生茶葉を、蒸し、揉み、乾燥のような公知の製茶工程を経て製造された製茶後の茶葉が使用される。また、製茶工程を経ていない生茶葉や、生茶葉を醗酵させた茶葉を使用することも可能である。このような茶葉は、通常、ドライな状態で蒸気抽出に供される。ドライな状態の茶葉とは、水に浸漬する処理や水で蒸らす処理を行っていないものを指す。茶葉の種類としては、緑茶、ウーロン茶、紅茶、麦茶、ハト麦茶、ジャスミン茶、プアール茶、ルイボス茶、ハーブのような飲料品に使用可能なものが挙げられる。これらの茶葉は、単独で用いてもよく、複数種類の茶葉をブレンドして用いてもよい。 The superheated steam extract of tea leaves is obtained by steam-extracting tea leaves using superheated steam. As the tea leaf, a tea leaf after tea production produced through a known tea making process such as steaming, tasting, and drying is usually used. It is also possible to use fresh tea leaves that have not undergone the tea-making process or tea leaves obtained by fermenting fresh tea leaves. Such tea leaves are usually subjected to steam extraction in a dry state. The dry tea leaves are those that have not been soaked in water or steamed with water. Examples of the tea leaves include those that can be used for beverages such as green tea, oolong tea, black tea, barley tea, pigeon tea, jasmine tea, puar tea, rooibos tea, and herbs. These tea leaves may be used alone or in combination with a plurality of types of tea leaves.
蒸気抽出は、過熱水蒸気を茶葉に直接接触させた後、その接触後の蒸気を回収する処理である。過熱水蒸気は、飽和水蒸気に対して圧力を上げることなくさらに熱を加えることによって生成される蒸気である。ちなみに、飽和水蒸気は、水の沸点(常圧では100℃)で沸騰中の液体の水が蒸発することによって生成される蒸気である。よって、過熱水蒸気は、液体の水をボイラー又は電磁誘導加熱により沸騰させることによって生成した飽和水蒸気を、バーナー、電気ヒーター又は電磁誘導加熱装置で加熱することにより得られる。飽和水蒸気を加熱する際には、飽和水蒸気を加圧しながら加熱することが可能であるが、加圧後の減圧によって(加圧された状態から常圧の状態に戻すときに)過熱水蒸気の温度を制御しにくいことから、加圧せずに加熱することが好ましい。電磁誘導加熱装置は、通常、周波数100Hz〜100kHzの電磁誘導加熱によりセラミック又は金属製の発熱体を加熱し、その発熱体の表面に飽和水蒸気を接触させることによって過熱水蒸気を生成させる。 Steam extraction is a process in which superheated steam is brought into direct contact with tea leaves and the steam after the contact is recovered. Superheated steam is steam generated by applying more heat to saturated steam without increasing the pressure. Incidentally, saturated water vapor is a vapor generated by the evaporation of boiling liquid water at the boiling point of water (100 ° C. at normal pressure). Therefore, superheated steam is obtained by heating saturated steam generated by boiling liquid water by boiler or electromagnetic induction heating with a burner, an electric heater or an electromagnetic induction heating device. When heating the saturated steam, it is possible to heat the saturated steam while pressurizing, but the temperature of the superheated steam by the reduced pressure after pressurization (when returning from the pressurized state to the normal pressure state) Since it is difficult to control, it is preferable to heat without applying pressure. The electromagnetic induction heating device normally heats a ceramic or metal heating element by electromagnetic induction heating with a frequency of 100 Hz to 100 kHz, and generates superheated steam by bringing saturated steam into contact with the surface of the heating element.
蒸気抽出する際の過熱水蒸気の温度は、常圧で100℃より高く、好ましくは常圧で105℃以上200℃未満、より好ましくは常圧で107℃を超え200℃未満である。過熱水蒸気の温度が200℃以上の場合には、過熱蒸気抽出物にほうじ茶様の加熱臭(焙じ臭)が付与されるために好ましくない。ちなみに、過熱水蒸気は、常圧(1.01325×105Pa、即ち1気圧)で107℃に転移点を有しており、その転移点より高い温度にあるときに熱力学的に極めて安定な状態となる。 The temperature of superheated steam at the time of steam extraction is higher than 100 ° C. at normal pressure, preferably 105 ° C. or higher and lower than 200 ° C. at normal pressure, more preferably higher than 107 ° C. and lower than 200 ° C. at normal pressure. When the temperature of the superheated steam is 200 ° C. or higher, it is not preferable because a roasted tea-like heated odor (roast odor) is imparted to the superheated steam extract. Incidentally, superheated steam has a transition point at 107 ° C. at normal pressure (1.01325 × 10 5 Pa, ie, 1 atm), and is extremely thermodynamically stable at a temperature higher than the transition point. It becomes a state.
蒸気抽出に用いられる過熱水蒸気の蒸気量は、茶葉1Kgあたり好ましくは1〜100Kg/h、より好ましくは3〜30Kg/hである。蒸気量が1Kg/h未満の場合には、過熱蒸気抽出物の回収に多くの時間を要する。逆に100Kg/hを超える場合には、過熱水蒸気を発生させる装置内の内圧が高くなることから、圧力制御を実施するための装置コストが高くなったり、大きな装置スペースが必要となったりする。 The amount of steam of superheated steam used for steam extraction is preferably 1 to 100 kg / h, more preferably 3 to 30 kg / h per 1 kg of tea leaves. When the amount of steam is less than 1 kg / h, it takes a long time to recover the superheated steam extract. On the other hand, when it exceeds 100 Kg / h, the internal pressure in the apparatus for generating superheated steam becomes high, so that the apparatus cost for performing pressure control becomes high and a large apparatus space is required.
この好ましい蒸気量で蒸気抽出を行う場合の抽出時間は、好ましくは10秒〜30分間、より好ましくは30秒〜10分間である。前記抽出時間が10秒未満の場合には、茶葉から褐変抑制作用を有する過熱蒸気抽出物を効率的に抽出することができない。逆に30分を超えると、過熱蒸気抽出物を飲食品に添加したときに該飲食品の風香味を変化させやすくなる。特に、過熱水蒸気を用いて30分を越えて蒸気抽出する場合には、茶葉が焙焼されやすくなって、ほうじ茶様の加熱臭(焙じ臭)が増加するおそれがある。 The extraction time when performing steam extraction with this preferable amount of steam is preferably 10 seconds to 30 minutes, more preferably 30 seconds to 10 minutes. When the extraction time is less than 10 seconds, the superheated steam extract having a browning inhibitory effect cannot be efficiently extracted from tea leaves. On the contrary, when it exceeds 30 minutes, when the superheated steam extract is added to the food or drink, the flavor of the food or drink is easily changed. In particular, when steam extraction is performed using superheated steam for more than 30 minutes, the tea leaves are likely to be roasted, and there is a risk of increasing the roasted tea-like odor (roast odor).
蒸気抽出は、過熱蒸気抽出物の飛散及び拡散による回収ロスを低減させるために、密閉容器内で実施することが最も好ましい。また、蒸気抽出は、通常は常圧で行われるが、加圧状態で行われても構わない。さらに、蒸気抽出は、窒素ガスや希ガスのような不活性ガス雰囲気下(いわゆる脱酸素状態)で行われることが最も好ましい。この場合、過熱蒸気抽出物自体の酸化劣化が抑えられるため、酸化劣化に起因する褐変抑制作用に優れた過熱蒸気抽出物を得ることが容易になる。ちなみに、溶存酸素を除去した水(いわゆる脱酸素水)を用いて作製した水蒸気には、酸素がほとんど溶存していない。このため、茶葉を仕込んだ密閉容器内を不活性ガスで置換した後、前記脱酸素水より作製した過熱水蒸気を用いて蒸気抽出すると、その密閉容器内の不活性ガス雰囲気が容易かつ継続的に維持される。 Steam extraction is most preferably carried out in a closed container in order to reduce recovery loss due to scattering and diffusion of the superheated steam extract. Moreover, although steam extraction is normally performed at a normal pressure, it may be performed in a pressurized state. Furthermore, the steam extraction is most preferably performed in an inert gas atmosphere (so-called deoxygenated state) such as nitrogen gas or rare gas. In this case, since the oxidative degradation of the superheated steam extract itself can be suppressed, it becomes easy to obtain a superheated steam extract excellent in the action of suppressing browning caused by the oxidative degradation. Incidentally, oxygen is hardly dissolved in water vapor produced using water from which dissolved oxygen is removed (so-called deoxygenated water). For this reason, after replacing the inside of the sealed container filled with tea leaves with an inert gas, when steam extraction is performed using superheated steam produced from the deoxygenated water, the inert gas atmosphere in the sealed container is easily and continuously. Maintained.
蒸気抽出による過熱蒸気抽出物の回収率は、茶葉の種類により大きく異なるが、全般に茶葉に対して固形分として0.01〜10重量%(Brix0.01〜10)であることが適当である。しかしながら、品質面を考慮すると固形分として0.05〜5重量%(Brix0.05〜5)であることが好ましい。前記回収率が0.01重量%未満の場合には、十分な量の過熱蒸気抽出物が回収されないため、褐変抑制作用を十分に発揮させることができない。逆に10重量%を超える場合には、茶葉由来の風香味の強い過熱蒸気抽出物が得られやすくなるため、飲食品に添加した場合に該飲食品本来の風香味を妨げてしまうおそれが高まる。 The recovery rate of the superheated steam extract by steam extraction varies greatly depending on the type of tea leaf, but it is generally appropriate that the solid content is 0.01 to 10% by weight (Brix 0.01 to 10) with respect to the tea leaf. . However, in view of quality, the solid content is preferably 0.05 to 5% by weight (Brix 0.05 to 5). When the recovery rate is less than 0.01% by weight, a sufficient amount of the superheated steam extract is not recovered, so that the browning suppressing effect cannot be sufficiently exhibited. Conversely, when it exceeds 10% by weight, it becomes easy to obtain a superheated steam extract with a flavor derived from tea leaves, and therefore, when added to a food or drink, the risk of hindering the original flavor of the food or drink increases. .
この過熱蒸気抽出物は、液状、粒状、粉状、固形状、半固形状のような形態で回収された後、密閉容器のような容器内で保存されるか、或いは飲食品中に添加される。液状の過熱蒸気抽出物は、前記蒸気抽出において茶葉に接触した後の蒸気を集めて冷却することにより得られる。粒状又は粉状の過熱蒸気抽出物は、前記液状の過熱蒸気抽出物又は前記茶葉に接触した後の蒸気を、フリーズドライ法又はスプレードライ法で乾燥させることにより得られる。固形状又は半固形状の過熱蒸気抽出物は、前記液状の過熱蒸気抽出物を常法により加熱乾燥又は濃縮することにより得られる。なおこのとき、過熱蒸気抽出物の化学的特性を利用して、蒸留、減圧蒸留又は分留により褐変抑制作用の高い画分を分画したり、樹脂カラムを使用して褐変抑制作用の高い成分を精製したりすることも可能である。 This superheated steam extract is collected in the form of liquid, granular, powder, solid, semi-solid, and then stored in a container such as a sealed container, or added to food or drink. The The liquid superheated steam extract is obtained by collecting and cooling the steam after contacting the tea leaves in the steam extraction. The granular or powdery superheated steam extract can be obtained by drying the liquid superheated steam extract or the steam after contacting the tea leaves by freeze drying or spray drying. The solid or semi-solid superheated steam extract can be obtained by drying or concentrating the liquid superheated steam extract by a conventional method. At this time, by utilizing the chemical characteristics of the superheated steam extract, fractions having a high browning inhibitory effect are obtained by distillation, distillation under reduced pressure or fractional distillation, or components having a high browning inhibitory effect are obtained using a resin column Can also be purified.
本実施形態の飲食品は、上記褐変抑制剤を含有する飲料品又は食品である。飲料品としては、緑茶、ウーロン茶、紅茶、麦茶、ハト麦茶、ジャスミン茶、プアール茶、ルイボス茶、ハーブ茶、ブレンド茶のような茶類飲料が挙げられる。また、レモン、オレンジ、グレープフルーツ、ライム、ゆずのような柑橘類の果汁、ピーチ、グレープ、パインアップル、アップル、イチゴのような果実の果汁、キャロット、ほうれん草、トマトのような野菜の汁、コーンスープのような穀物汁、生乳、殺菌乳、加工乳、粉乳(脱脂粉乳、全脂粉乳)、乳脂肪、クリームのような乳成分などを含む飲食品も挙げられる。 The food / beverage products of this embodiment are the drinks or foodstuffs containing the said browning inhibitor. Examples of the beverage include tea beverages such as green tea, oolong tea, black tea, barley tea, pigeon tea, jasmine tea, puar tea, rooibos tea, herbal tea, and blended tea. Also, citrus juice like lemon, orange, grapefruit, lime, yuzu, peach, grape, pineapple, apple, fruit juice like strawberry, carrot, spinach, vegetable juice like tomato, corn soup Food / beverage products containing dairy ingredients such as cereal juice, raw milk, pasteurized milk, processed milk, powdered milk (skim powdered milk, whole milk powder), milk fat, and cream are also included.
このような飲食品は、メイラード反応を引き起こし得る蛋白質及び糖質を始めとして、ビタミンCなどを含有しているが、本実施形態の褐変抑制剤の褐変抑制作用により褐変しにくくなっている。その結果、これらの飲食品では、長期保存時における色の変化が抑えられるため、品質の安定性が高まっている。特に、酸化防止剤としてのビタミンCが人為的に添加されてなる茶類飲料、栄養ドリンク、スポーツドリンクのような飲食品では、保存時の褐変が効果的に抑制されるとともに、ビタミンCや他の褐変抑制作用を有する添加物の含有量を低減させることも可能となる。なお、本実施形態の褐変抑制剤には、茶葉に由来する揮発性の高い芳香成分も含まれているため、そのような芳香成分によって飲食品の風香味が大幅に損なわれないように、飲食品の素材選択、褐変抑制剤の蒸気抽出条件、褐変抑制剤の添加量などが適宜調整されていることが好ましい。 Such foods and drinks contain proteins and sugars that can cause a Maillard reaction, but also vitamin C and the like, but are less likely to brown due to the browning inhibitory action of the browning inhibitor of this embodiment. As a result, in these foods and drinks, since the color change at the time of long-term storage is suppressed, the stability of quality is increased. Especially in foods and beverages such as tea beverages, nutritional drinks, and sports drinks, to which vitamin C as an antioxidant is artificially added, browning during storage is effectively suppressed, vitamin C and other It is also possible to reduce the content of an additive having a browning inhibiting action. In addition, since the browning inhibitor of this embodiment also contains a highly volatile aroma component derived from tea leaves, the flavor of food and drink is not significantly impaired by such an aroma component. It is preferable that the material selection of the product, the steam extraction condition of the browning inhibitor, the addition amount of the browning inhibitor, and the like are appropriately adjusted.
飲食品としての茶類飲料を製造する際には、褐変抑制剤を蒸気抽出した後の茶葉を水抽出した後、前記褐変抑制剤を添加することにより製造することが、特にコスト面で有利である。この場合、茶葉(第1の茶葉)に過熱水蒸気を接触させて褐変抑制剤を蒸気抽出した後、該褐変抑制剤を抽出した後の残渣(第1の茶葉)に60℃程度の水を浸漬させて水抽出し、得られた第1の茶葉の水抽出物に前記褐変抑制剤が添加される。 When producing a tea beverage as a food or drink, it is particularly advantageous in terms of cost to produce a tea leaf after steam extraction of the browning inhibitor and then adding the browning inhibitor. is there. In this case, the tea leaves (first tea leaves) are brought into contact with superheated steam to steam extract the browning inhibitor, and then water at about 60 ° C. is immersed in the residue (first tea leaves) after the browning inhibitor is extracted. The browning inhibitor is added to the water extract of the first tea leaves obtained by water extraction.
また、褐変抑制剤を抽出した茶葉とは別の茶葉を水抽出した後、褐変抑制剤を添加することにより製造することも可能である。この場合、茶葉(第1の茶葉)に過熱水蒸気を接触させて褐変抑制剤を蒸気抽出した後、該褐変抑制剤を抽出した茶葉(第1の茶葉)とは別の茶葉(第2の茶葉)に60℃程度の水を浸漬させて水抽出し、得られた第2の茶葉の水抽出物に前記褐変抑制剤が添加される。このような茶類飲料の製造方法においては、第1の茶葉と第2の茶葉とを同じ種類の茶葉により構成すること、及び第1の茶葉と第2の茶葉とを別の種類の茶葉により構成すること、のいずれの方法を選択してもよい。 Moreover, it is also possible to produce by adding a browning inhibitor after water-extracting a tea leaf different from the tea leaf from which the browning inhibitor has been extracted. In this case, after the tea leaf (first tea leaf) is contacted with superheated steam and the browning inhibitor is steam-extracted, the tea leaf (second tea leaf) different from the tea leaf (first tea leaf) from which the browning inhibitor is extracted is extracted. ) Is immersed in water at about 60 ° C. and extracted with water, and the browning inhibitor is added to the obtained water extract of the second tea leaf. In such a tea beverage production method, the first tea leaf and the second tea leaf are composed of the same type of tea leaf, and the first tea leaf and the second tea leaf are composed of another type of tea leaf. Any method of configuring may be selected.
なお、茶葉を水抽出する場合には、ニーダー式、ドリップ式、ボックス式、多塔式などの一般的に茶類の水抽出に使用される全ての抽出機が利用可能である。また、水抽出する際の温度も特に限定されない。茶類飲料には、必要に応じて、重曹のようなpH調整剤、ビタミンCのような酸化防止剤、ショ糖脂肪酸エステルやグリセリン脂肪酸エステルのような乳化剤、カラギーナンのような安定剤、砂糖、果糖、ブドウ糖、糖アルコールのような甘味料、各種酸味料、香料のような添加物が添加されていてもよい。これらの添加物は、単独で添加されてもよく、複数種類を組合わせて添加されてもよい。また、牛乳、粉乳、脱脂粉乳、クリーム、植物油脂などが配合されていてもよい。 In addition, when extracting tea leaves with water, all extractors generally used for water extraction of teas such as a kneader type, a drip type, a box type, and a multi-tower type can be used. Moreover, the temperature at the time of water extraction is not specifically limited. For tea beverages, pH adjusters such as baking soda, antioxidants such as vitamin C, emulsifiers such as sucrose fatty acid esters and glycerin fatty acid esters, stabilizers such as carrageenan, sugar, Additives such as sweeteners such as fructose, glucose, and sugar alcohol, various acidulants, and fragrances may be added. These additives may be added alone or in combination of a plurality of types. In addition, milk, powdered milk, skim milk powder, cream, vegetable oils and the like may be blended.
このようにして製造された茶類飲料は、缶、ビン、PETボトル、紙容器、プラスチック容器のような保存性を高めるための容器内に封入されることが好ましい。さらに、これらの容器内に封入される茶類飲料には、保存性を高めるための殺菌処理(UHT殺菌後にホットパック充填、無菌充填による容器詰め、容器詰め後のレトルト殺菌など)が施されていることが好ましい。 The tea beverage produced in this manner is preferably enclosed in a container for enhancing the storage stability such as a can, a bottle, a PET bottle, a paper container, or a plastic container. In addition, tea beverages sealed in these containers are subjected to sterilization treatment (such as hot pack filling after UHT sterilization, container filling by aseptic filling, retort sterilization after container filling, etc.) to enhance storage stability. Preferably it is.
前記実施形態によって発揮される効果について、以下に記載する。
・ 本実施形態の褐変抑制剤は、茶葉の過熱蒸気抽出物よりなる。過熱蒸気抽出物には、それ自体の褐変を抑える作用があるとともに、該過熱蒸気抽出物を添加した飲食品の褐変をも抑える作用がある。このため、過熱蒸気抽出物よりなる褐変抑制剤は、飲食品に添加するための添加物として利用することができる。この場合、褐変抑制剤は、飲食品の長期保存時における色の変化を効果的に抑えることができるため、飲食品の品質低下を抑えつつ、長期間の保存を容易にする。また、この褐変抑制剤は、ビタミンCの分解、メイラード反応、酸化劣化などに起因する飲食品の褐変を抑制することから、ビタミンCや他の褐変抑制作用を有する添加物の含有量を低減させた飲食品を提供する際にも有用である。
The effects exhibited by the embodiment will be described below.
-The browning inhibitor of this embodiment consists of a superheated steam extract of tea leaves. The superheated steam extract has an effect of suppressing browning of itself, and also has an effect of suppressing browning of food and drink to which the superheated steam extract is added. For this reason, the browning inhibitor which consists of a superheated steam extract can be utilized as an additive for adding to food-drinks. In this case, since the browning inhibitor can effectively suppress the color change during long-term storage of the food and drink, it facilitates long-term storage while suppressing deterioration in the quality of the food and drink. Moreover, since this browning inhibitor suppresses browning of food and drink caused by decomposition of vitamin C, Maillard reaction, oxidative degradation, etc., it reduces the content of vitamin C and other additives having a browning inhibitory effect. It is also useful when providing food and drink.
・ 本実施形態の飲食品は、前記褐変抑制剤を含有しているため、長期保存に際して褐変しにくく、長期間保存しても品質の低下を少なくすることが可能である。特に、褐変抑制剤の製造に用いた茶葉(第1の茶葉)の水抽出物、又は第1の茶葉と同じ種類の茶葉(第2の茶葉)の水抽出物を含有する茶類飲料は、良好な風香味と素材本来の色とを保持しつつ、長期保存時における褐変を抑制することができるため、極めて好ましい飲食品となり得る点で優れている。 -Since the food / beverage products of this embodiment contain the said browning inhibitor, it is hard to brown at the time of long-term storage, and even if it preserve | saves for a long period of time, it is possible to reduce deterioration of quality. In particular, the tea beverage containing the water extract of the tea leaves (first tea leaves) used for the production of the browning inhibitor, or the same type of tea leaves (second tea leaves) as the first tea leaves, Since it can suppress browning during long-term storage while maintaining a good flavor and the original color of the material, it is excellent in that it can be an extremely preferable food and drink.
<緑茶飲料の製造1>
(試験例1)
緑茶葉3Kgを密閉可能な抽出容器内に仕込んだ。続いて、抽出容器内の茶葉の下方から120℃の過熱水蒸気を1時間あたりに30Kgの蒸気量で3分間注入することにより、過熱水蒸気を茶葉に直接接触させた。そして、抽出容器の上端部から流出する蒸気を直ちに冷却することにより、液状の過熱蒸気抽出物1.2Kgを得た。次に、過熱蒸気抽出物を抽出した後の茶葉を、60℃の温水を用いてニーダーにて12分間水抽出した。得られた茶葉の水抽出物をタンニン量61mg/100mLとなるように調整した後、pH調整剤としての重曹を0.3g/L、酸化防止剤としてのビタミンCを0.4g/Lとなるように添加し、さらに前記過熱蒸気抽出物を全量添加することにより、緑茶飲料を製造した。この緑茶飲料を138℃で30秒間のUHT殺菌を行った後、500mLのPETボトルにホットパック充填した。
<Manufacture of green tea beverage 1>
(Test Example 1)
3 kg of green tea leaves were charged into a sealable extraction container. Subsequently, the superheated steam was brought into direct contact with the tea leaves by injecting 120 ° C superheated steam at a steam volume of 30 kg per hour for 3 minutes from below the tea leaves in the extraction container. And the steam which flows out from the upper end part of an extraction container was cooled immediately, and liquid superheated steam extract 1.2Kg was obtained. Next, the tea leaves after extracting the superheated steam extract were subjected to water extraction with a kneader for 12 minutes using 60 ° C. warm water. After adjusting the obtained tea leaf water extract to a tannin amount of 61 mg / 100 mL, sodium bicarbonate as a pH adjuster is 0.3 g / L, and vitamin C as an antioxidant is 0.4 g / L. Then, a green tea beverage was produced by adding the whole amount of the superheated steam extract. The green tea beverage was UHT sterilized at 138 ° C. for 30 seconds and then hot-packed into a 500 mL PET bottle.
(試験例2)
緑茶葉3Kgを密閉可能な抽出容器内に仕込んだ。続いて、抽出容器内の茶葉の下方から120℃の過熱水蒸気を1時間あたりに30Kgの蒸気量で9分間注入することにより、過熱水蒸気を茶葉に直接接触させた。そして、抽出容器の上端部から流出する蒸気を直ちに冷却することにより、液状の過熱蒸気抽出物3.8Kgを得た。次に、過熱蒸気抽出物を抽出した後の茶葉を、60℃の温水を用いてニーダーにて12分間水抽出した。得られた茶葉の水抽出物をタンニン量61mg/100mLとなるように調整した後、重曹を0.3g/L、ビタミンCを0.4g/Lとなるように添加し、さらに前記過熱蒸気抽出物を全量添加することにより、緑茶飲料を製造した。この緑茶飲料を138℃で30秒間のUHT殺菌を行った後、500mLのPETボトルにホットパック充填した。
(Test Example 2)
3 kg of green tea leaves were charged into a sealable extraction container. Subsequently, superheated steam was directly brought into contact with the tea leaves by injecting 120 ° C superheated steam at a steam volume of 30 kg per hour for 9 minutes from below the tea leaves in the extraction container. And the vapor | steam which flows out from the upper end part of an extraction container was cooled immediately, and liquid superheated steam extract 3.8Kg was obtained. Next, the tea leaves after extracting the superheated steam extract were subjected to water extraction with a kneader for 12 minutes using 60 ° C. warm water. After adjusting the obtained tea leaf water extract to a tannin amount of 61 mg / 100 mL, sodium bicarbonate was added to 0.3 g / L, vitamin C was added to 0.4 g / L, and the superheated steam extraction was further performed. A green tea beverage was produced by adding all of the product. The green tea beverage was UHT sterilized at 138 ° C. for 30 seconds and then hot-packed into a 500 mL PET bottle.
(比較例1)
緑茶葉3Kgを60℃の温水を用いてニーダーにて12分間水抽出した。得られた茶葉の水抽出物をタンニン量61mg/100mLとなるように調整した後、重曹を0.3g/L、ビタミンCを0.4g/Lとなるように添加することにより、緑茶飲料を製造した。この緑茶飲料を138℃で30秒間のUHT殺菌を行った後、500mLのPETボトルにホットパック充填した。
(Comparative Example 1)
3 kg of green tea leaves were extracted with water at 60 ° C. using a kneader for 12 minutes. After adjusting the water extract of the obtained tea leaves to a tannin amount of 61 mg / 100 mL, a green tea beverage was prepared by adding sodium bicarbonate 0.3 g / L and vitamin C 0.4 g / L. Manufactured. The green tea beverage was UHT sterilized at 138 ° C. for 30 seconds and then hot-packed into a 500 mL PET bottle.
<褐変抑制効果の確認1>
試験例1,2及び比較例1の各緑茶飲料を60℃で保存した。4日間、7日間及び14日間保存した後の緑茶飲料の色調を測定した。色調の測定は、日本電色工業社製の測色色差計ZE2000を用いて、黄色度YI値を測定した。結果を表1に示す。なお、表1に示す数値は、未経時品のYI値を基準(100%)として、所定期間保存後の緑茶飲料の褐変の度合い(YI値増加率)を算出した結果を示す。
<Confirmation 1 of browning suppression effect>
The green tea beverages of Test Examples 1 and 2 and Comparative Example 1 were stored at 60 ° C. The color tone of the green tea beverage after storage for 4 days, 7 days and 14 days was measured. The color tone was measured by measuring the yellowness YI value using a colorimetric color difference meter ZE2000 manufactured by Nippon Denshoku Industries Co., Ltd. The results are shown in Table 1. In addition, the numerical value shown in Table 1 shows the result of having calculated the browning degree (YI value increase rate) of the green tea drink after preservation | save for a predetermined period on the basis (100%) of YI value of an unaged product.
表1より、比較例1の緑茶飲料では、時間経過とともに褐変の度合い(黄色度YI値)が増加した。これに対し、試験例1,2の緑茶飲料では、いずれも、比較例1よりも明らかに褐変の度合いの変化が低く抑えられていた。 From Table 1, the degree of browning (yellowness YI value) increased with time in the green tea beverage of Comparative Example 1. On the other hand, in the green tea beverages of Test Examples 1 and 2, the change in the degree of browning was clearly suppressed to be lower than that in Comparative Example 1.
<緑茶飲料の製造2>
(試験例3)
緑茶葉3Kgを密閉可能な抽出容器内に仕込んだ。続いて、抽出容器内の茶葉の下方から170℃の過熱水蒸気を1時間あたりに25Kgの蒸気量で6分間注入することにより、過熱水蒸気を茶葉に直接接触させた。そして、抽出容器の上端部から流出する蒸気を直ちに冷却することにより、液状の過熱蒸気抽出物1.75Kgを得た。次に、過熱蒸気抽出物を抽出した後の茶葉を、60℃の温水120Lを用いてニーダーにて12分間水抽出した。得られた茶葉の水抽出物をタンニン量61mg/100mLとなるように調整した後、重曹を0.3g/L、ビタミンCを0.4g/Lとなるように添加し、さらに前記過熱蒸気抽出物を全量添加することにより、緑茶飲料を製造した。この緑茶飲料を138℃で30秒間のUHT殺菌を行った後、500mLのPETボトルにホットパック充填した。
<Manufacture of green tea beverage 2>
(Test Example 3)
3 kg of green tea leaves were charged into a sealable extraction container. Subsequently, the superheated steam was directly brought into contact with the tea leaves by injecting 170 ° C superheated steam at a steam amount of 25 kg per hour for 6 minutes from below the tea leaves in the extraction container. And the steam which flows out from the upper end part of an extraction container was cooled immediately, and liquid superheated steam extract 1.75Kg was obtained. Next, the tea leaves after extracting the superheated steam extract were subjected to water extraction with a kneader for 12 minutes using 120 L of hot water at 60 ° C. After adjusting the obtained tea leaf water extract to a tannin amount of 61 mg / 100 mL, sodium bicarbonate was added to 0.3 g / L, vitamin C was added to 0.4 g / L, and the superheated steam extraction was further performed. A green tea beverage was produced by adding all of the product. The green tea beverage was UHT sterilized at 138 ° C. for 30 seconds and then hot-packed into a 500 mL PET bottle.
(試験例4)
緑茶葉3Kgを密閉可能な抽出容器内に仕込んだ。続いて、抽出容器内の茶葉の下方から170℃の過熱水蒸気を1時間あたりに25Kgの蒸気量で6分間注入することにより、過熱水蒸気を茶葉に直接接触させた。そして、抽出容器の上端部から流出する蒸気を直ちに冷却することにより、液状の過熱蒸気抽出物1.75Kgを得た。次に、過熱水蒸気処理していない別の茶葉3Kgを、60℃の温水120Lを用いてニーダーにて12分間水抽出した。得られた茶葉の水抽出物をタンニン量61mg/100mLとなるように調整した後、重曹を0.3g/L、ビタミンCを0.4g/Lとなるように添加し、さらに前記過熱蒸気抽出物を全量添加することにより、緑茶飲料を製造した。この緑茶飲料を138℃で30秒間のUHT殺菌を行った後、500mLのPETボトルにホットパック充填した。
(Test Example 4)
3 kg of green tea leaves were charged into a sealable extraction container. Subsequently, the superheated steam was directly brought into contact with the tea leaves by injecting 170 ° C superheated steam at a steam amount of 25 kg per hour for 6 minutes from below the tea leaves in the extraction container. And the steam which flows out from the upper end part of an extraction container was cooled immediately, and liquid superheated steam extract 1.75Kg was obtained. Next, 3 kg of another tea leaf not subjected to superheated steam treatment was subjected to water extraction with a kneader for 12 minutes using 120 L of hot water at 60 ° C. After adjusting the obtained tea leaf water extract to a tannin amount of 61 mg / 100 mL, sodium bicarbonate was added to 0.3 g / L, vitamin C was added to 0.4 g / L, and the superheated steam extraction was further performed. A green tea beverage was produced by adding all of the product. The green tea beverage was UHT sterilized at 138 ° C. for 30 seconds and then hot-packed into a 500 mL PET bottle.
(試験例5)
緑茶葉3Kgを密閉可能な抽出容器内に仕込んだ。続いて、抽出容器内の茶葉の下方から170℃の過熱水蒸気を1時間あたりに25Kgの蒸気量で6分間注入することにより、過熱水蒸気を茶葉に直接接触させた。そして、抽出容器の上端部から流出する蒸気を直ちに冷却することにより、液状の過熱蒸気抽出物1.75Kgを得た。次に、過熱蒸気抽出物を抽出した後の茶葉を、60℃の温水120Lを用いてニーダーにて12分間水抽出した。得られた茶葉の水抽出物をタンニン量61mg/100mLとなるように調整した後、重曹を0.3g/L、ビタミンCを0.2g/Lとなるように添加し、さらに前記過熱蒸気抽出物を全量添加することにより、緑茶飲料を製造した。この緑茶飲料を138℃で30秒間のUHT殺菌を行った後、500mLのPETボトルにホットパック充填した。
(Test Example 5)
3 kg of green tea leaves were charged into a sealable extraction container. Subsequently, the superheated steam was directly brought into contact with the tea leaves by injecting 170 ° C superheated steam at a steam amount of 25 kg per hour for 6 minutes from below the tea leaves in the extraction container. And the steam which flows out from the upper end part of an extraction container was cooled immediately, and liquid superheated steam extract 1.75Kg was obtained. Next, the tea leaves after extracting the superheated steam extract were subjected to water extraction with a kneader for 12 minutes using 120 L of hot water at 60 ° C. After adjusting the obtained tea leaf water extract to a tannin amount of 61 mg / 100 mL, sodium bicarbonate was added to 0.3 g / L and vitamin C was added to 0.2 g / L, and the superheated steam extraction was further performed. A green tea beverage was produced by adding all of the product. The green tea beverage was UHT sterilized at 138 ° C. for 30 seconds and then hot-packed into a 500 mL PET bottle.
(比較例2)
緑茶葉3Kgを、60℃の温水120Lを用いてニーダーにて12分間水抽出した。得られた茶葉の水抽出物をタンニン量61mg/100mLとなるように調整した後、重曹を0.3g/L、ビタミンCを0.4g/Lとなるように添加することにより、緑茶飲料を製造した。この緑茶飲料を138℃で30秒間のUHT殺菌を行った後、500mLのPETボトルにホットパック充填した。
(Comparative Example 2)
3 kg of green tea leaves were extracted with water using 120 L of hot water at 60 ° C. for 12 minutes. After adjusting the water extract of the obtained tea leaves to a tannin amount of 61 mg / 100 mL, a green tea beverage was prepared by adding sodium bicarbonate 0.3 g / L and vitamin C 0.4 g / L. Manufactured. The green tea beverage was UHT sterilized at 138 ° C. for 30 seconds and then hot-packed into a 500 mL PET bottle.
(比較例3)
緑茶葉3Kgを、60℃の温水120Lを用いてニーダーにて12分間水抽出した。得られた茶葉の水抽出物をタンニン量61mg/100mLとなるように調整した後、重曹を0.3g/L、ビタミンCを0.2g/Lとなるように添加することにより、緑茶飲料を製造した。この緑茶飲料を138℃で30秒間のUHT殺菌を行った後、500mLのPETボトルにホットパック充填した。
(Comparative Example 3)
3 kg of green tea leaves were extracted with water using 120 L of hot water at 60 ° C. for 12 minutes. After adjusting the water extract of the obtained tea leaves to a tannin amount of 61 mg / 100 mL, by adding sodium bicarbonate 0.3 g / L and vitamin C 0.2 g / L, a green tea beverage was obtained. Manufactured. The green tea beverage was UHT sterilized at 138 ° C. for 30 seconds and then hot-packed into a 500 mL PET bottle.
<褐変抑制効果の確認2>
試験例3〜5及び比較例2,3の各緑茶飲料を60℃で保存した。3日間、10日間、15日間及び21日間保存した後の緑茶飲料の色調(黄色度YI値)を実施例1と同様に求めた。結果を表2に示す。
<Confirmation 2 of browning suppression effect>
Each green tea beverage of Test Examples 3 to 5 and Comparative Examples 2 and 3 was stored at 60 ° C. The color tone (yellowness YI value) of the green tea beverage after storage for 3 days, 10 days, 15 days and 21 days was determined in the same manner as in Example 1. The results are shown in Table 2.
表2より、試験例3,4と比較例2とを比較すると、茶葉の過熱蒸気抽出物を茶葉の水抽出物に添加することによって、密閉容器(PETボトル)に充填した後の緑茶飲料の褐変が効果的に抑制されることが示された。さらに、試験例3と試験例4とを比較すると、蒸気抽出した後の茶葉を用いて水抽出した茶葉の水抽出物に、茶葉の過熱蒸気抽出物を添加することによって、緑茶飲料の褐変がより一層効果的に防止されることも明らかになった。 From Table 2, when the test examples 3 and 4 and the comparative example 2 are compared, the green tea beverage after filling the hermetic container (PET bottle) by adding the tea leaf superheated steam extract to the tea leaf water extract. It was shown that browning is effectively suppressed. Furthermore, comparing Test Example 3 and Test Example 4, the browning of the green tea beverage is improved by adding the tea leaf superheated steam extract to the water extract of the tea leaf extracted with water after steam extraction. It has also become clear that it can be prevented more effectively.
また、試験例5と比較例2,3とを比較すると、茶葉の過熱蒸気抽出物を緑茶飲料に添加することにより、酸化防止剤であるビタミンCの添加量を2分の1に低減しても、褐変を抑制する効果を十分に高めることができた。また、試験例1及び試験例3の結果より、過熱水蒸気の温度は、120〜170℃の範囲で効果があり、また、蒸気抽出における抽出時間も3〜6分間で効果があることが分かった。 Moreover, when the test example 5 and the comparative examples 2 and 3 are compared, the addition amount of the vitamin C which is antioxidant is reduced to 1/2 by adding the superheated steam extract of a tea leaf to a green tea drink. Moreover, the effect which suppresses browning was fully able to be improved. Moreover, from the results of Test Example 1 and Test Example 3, it was found that the temperature of superheated steam is effective in the range of 120 to 170 ° C., and the extraction time in steam extraction is also effective in 3 to 6 minutes. .
さらに、各試験例の茶葉の過熱蒸気抽出物について、ヨウ素法にて還元型ビタミンCを分析するとともに、酒石酸鉄法にてタンニン(カテキン類)を分析したところ、これらの成分がいずれも検出されなかった。また、各試験例の茶葉の過熱蒸気抽出物はいずれも、中性のpHを示していた。従って、茶葉の過熱蒸気抽出物による褐変防止効果は、通常酸化防止剤として利用されるアスコルビン酸やカテキン類による褐変防止効果ではないことが明らかとなった。 Furthermore, for the superheated steam extract of tea leaves of each test example, when reduced vitamin C was analyzed by the iodine method and tannin (catechins) was analyzed by the iron tartrate method, all of these components were detected. There wasn't. Moreover, all the superheated steam extracts of the tea leaves of each test example showed neutral pH. Therefore, it became clear that the browning prevention effect by the superheated steam extract of tea leaves is not the browning prevention effect by ascorbic acid or catechins which are usually used as an antioxidant.
<褐変抑制剤を含むレモンジュースの製造>
(試験例6)
緑茶葉3Kgを密閉可能な抽出容器内に仕込んだ。続いて、抽出容器内の茶葉の下方から120℃の過熱水蒸気を1時間あたりに36Kgの蒸気量で14分間注入することにより、過熱水蒸気を茶葉に直接接触させた。そして、抽出容器の上端部から流出する蒸気を直ちに冷却することにより、液状の過熱蒸気抽出物8.4Kgを得た。この過熱蒸気抽出物を濃縮レモン果汁(Brix37)の還元水として用いて、該濃縮レモン果汁を4倍(W/W)希釈することにより、Brix9.3のレモンジュースを製造した。このレモンジュースを93℃で3秒間の瞬間殺菌を行った後、PETボトルにホットパック充填した。
<Manufacture of lemon juice containing browning inhibitor>
(Test Example 6)
3 kg of green tea leaves were charged into a sealable extraction container. Subsequently, superheated steam was brought into direct contact with the tea leaves by injecting superheated steam at 120 ° C. for 14 minutes at a steam volume of 36 kg per hour from below the tea leaves in the extraction container. And the liquid which flows out from the upper end part of an extraction container was cooled immediately, and liquid superheated steam extract 8.4Kg was obtained. Using this superheated steam extract as the reduced water of concentrated lemon juice (Brix37), the concentrated lemon juice was diluted 4-fold (W / W) to produce Brix9.3 lemon juice. This lemon juice was instantly sterilized at 93 ° C. for 3 seconds and then filled into a PET bottle in a hot pack.
(比較例4)
イオン交換水にて濃縮レモン果汁(Brix37)を4倍(W/W)希釈することにより、Brix9.3のレモンジュースを製造した。このレモンジュースを93℃で3秒間の瞬間殺菌を行った後、PETボトルにホットパック充填した。
(Comparative Example 4)
A lemon juice of Brix 9.3 was produced by diluting concentrated lemon juice (Brix37) four times (W / W) with ion-exchanged water. This lemon juice was instantly sterilized at 93 ° C. for 3 seconds and then filled into a PET bottle in a hot pack.
<褐変抑制効果の確認>
試験例6及び比較例4の各レモンジュースを45℃で保存した。1週間及び2週間保存した後の各レモンジュースの色調を測定した。色調の測定は、測色色差計ZE2000を用いて、黄色味b値を測定した。結果を表3に示す。なお、表3に示す数値は、未経時品のb値を基準(100%)として、所定期間保存後のレモンジュースの褐変の度合い(b値増加率)を算出した結果を示す。また、ヨウ素法を用いて、未経時品に含まれるビタミンCの量を基準(100%)として、所定期間保存後の各レモンジュースのビタミンCの残存率を算出した。結果を表3に示す。
<Confirmation of browning suppression effect>
Each lemon juice of Test Example 6 and Comparative Example 4 was stored at 45 ° C. The color tone of each lemon juice after storage for 1 week and 2 weeks was measured. The color tone was measured by measuring the yellowness b value using a colorimetric color difference meter ZE2000. The results are shown in Table 3. In addition, the numerical value shown in Table 3 shows the result of calculating the degree of browning of lemon juice (b value increasing rate) after storage for a predetermined period using the b value of the untimed product as a reference (100%). Further, using the iodine method, the residual ratio of vitamin C in each lemon juice after storage for a predetermined period was calculated using the amount of vitamin C contained in the untimed product as a reference (100%). The results are shown in Table 3.
表3より、茶葉の過熱蒸気抽出物を濃縮レモン果汁の還元水として用いること、即ち、茶葉の過熱蒸気抽出物を飲食品に添加することにより、経時的に進行する褐変を効果的に抑制できるとともに、経時的に進行する還元型ビタミンCの分解を抑制できることが示された。なお、試験例6で経時的な褐変が抑制されたことは、酸化劣化が抑えられたことにも起因していると考えられる。 From Table 3, it is possible to effectively suppress browning that progresses over time by using the superheated steam extract of tea leaves as the reduced water of concentrated lemon juice, that is, by adding the superheated steam extract of tea leaves to food and drink. In addition, it was shown that the degradation of reduced vitamin C that progresses with time can be suppressed. In addition, it is considered that the browning over time was suppressed in Test Example 6 because the oxidative deterioration was suppressed.
<褐変抑制剤を含むオレンジジュースの製造>
(試験例7)
試験例6で得られた茶葉の過熱蒸気抽出物を混濁濃縮オレンジ果汁(Brix66)の還元水として用いて、該濃縮オレンジ果汁を6倍(W/W)希釈することにより、Brix7.6のオレンジジュースを製造した。このオレンジジュースを93℃で3秒間の瞬間殺菌を行った後、PETボトルにホットパック充填した。
<Manufacture of orange juice containing browning inhibitor>
(Test Example 7)
By using the superheated steam extract of the tea leaves obtained in Test Example 6 as reducing water for turbid concentrated orange juice (Brix66), the concentrated orange juice was diluted 6 times (W / W) to obtain an orange of Brix7.6. Juice was produced. This orange juice was instantly sterilized at 93 ° C. for 3 seconds and then filled in a PET bottle in a hot pack.
(比較例5)
イオン交換水にて混濁濃縮オレンジ果汁(Brix66)を6倍(W/W)希釈することにより、Brix7.6のオレンジジュースを製造した。このオレンジジュースを93℃で3秒間の瞬間殺菌を行った後、PETボトルにホットパック充填した。
(Comparative Example 5)
Brix 7.6 orange juice was prepared by diluting turbid concentrated orange juice (Brix 66) 6 times (W / W) with ion-exchanged water. This orange juice was instantly sterilized at 93 ° C. for 3 seconds and then filled in a PET bottle in a hot pack.
<褐変抑制効果の確認>
試験例7及び比較例5の各オレンジジュースを45℃で2週間保存した。保存前及び保存後の各オレンジジュースに100%エタノールを等量加えた後、遠心分離により不溶性パルプを除去後、得られた各上清についてそれぞれ420nmにおける吸光度を測定することにより、褐変の度合いを調べた。結果を表4に示す。
<Confirmation of browning suppression effect>
Each orange juice of Test Example 7 and Comparative Example 5 was stored at 45 ° C. for 2 weeks. After adding an equal amount of 100% ethanol to each orange juice before and after storage, removing the insoluble pulp by centrifugation, and measuring the absorbance at 420 nm for each of the obtained supernatants, the degree of browning can be determined. Examined. The results are shown in Table 4.
表4より、茶葉の過熱蒸気抽出物を飲食品に添加することにより、製造直後の飲食品の色調(水色)を良好にすることができるうえ、経時的な褐変を抑制できることが示された。なお、試験例7では、オレンジジュースに高い濃度で含まれる糖類のメイラード反応が抑えられたこと、及び、酸化劣化が抑えられたことにより、経時的な褐変が抑制されたものと考えられる。 From Table 4, it was shown that the color tone (light blue) of the food and drink immediately after production can be improved by adding the superheated steam extract of tea leaves to the food and drink, and that browning with time can be suppressed. In Test Example 7, it is considered that the browning over time was suppressed because the Maillard reaction of sugars contained in orange juice at a high concentration was suppressed and the oxidative deterioration was suppressed.
さらに、前記実施形態より把握できる技術的思想について以下に記載する。
・ 前記過熱蒸気抽出物は、前記茶葉に過熱水蒸気を接触させた後、その接触後の蒸気を回収することにより得られたものである請求項1から請求項3のいずれか一項に記載の褐変抑制剤。
Further, the technical idea that can be grasped from the embodiment will be described below.
The superheated steam extract is obtained by bringing the tea leaves into contact with superheated steam and then collecting the steam after the contact. Browning inhibitor.
・ 前記茶類飲料は、緑茶、ウーロン茶、紅茶、麦茶、ハト麦茶、ジャスミン茶、プアール茶、ルイボス茶、ハーブ茶又はそれらのブレンド茶である請求項5に記載の飲食品。
・ 前記過熱蒸気抽出物は、前記茶葉に過熱水蒸気を接触させた後、その接触後の蒸気を回収する蒸気抽出により得られたものであり、当該飲食品はさらに、前記蒸気抽出後の茶葉を水抽出することにより得られた茶葉の水抽出物を含有する請求項5に記載の飲食品。
The food and drink according to claim 5, wherein the tea beverage is green tea, oolong tea, black tea, barley tea, pigeon tea, jasmine tea, puar tea, rooibos tea, herbal tea, or a blended tea thereof.
The superheated steam extract is obtained by steam extraction in which superheated steam is brought into contact with the tea leaves, and then the steam after the contact is recovered, and the food or drink further contains the tea leaves after the steam extraction. The food / beverage product of Claim 5 containing the water extract of the tea leaf obtained by water-extracting.
・ 前記過熱蒸気抽出物は、前記茶葉に過熱水蒸気を接触させた後、その接触後の蒸気を回収する蒸気抽出により得られたものであり、当該飲食品はさらに、前記蒸気抽出の対象とされていない茶葉を水抽出することにより得られた茶葉の水抽出物を含有する請求項5に記載の飲食品。 The superheated steam extract is obtained by steam extraction in which the tea leaves are brought into contact with superheated steam, and the steam after the contact is recovered, and the food or drink is further subject to steam extraction. The food / beverage product of Claim 5 containing the water extract of the tea leaf obtained by carrying out the water extraction of the tea leaf which is not.
・ 前記過熱蒸気抽出物は、前記茶葉に過熱水蒸気を接触させた後、その接触後の蒸気を回収する蒸気抽出により得られたものであり、当該飲食品はさらに、前記蒸気抽出の対象とされた茶葉と同じ種類の別の茶葉を水抽出することにより得られた茶葉の水抽出物を含有する請求項5に記載の飲食品。 The superheated steam extract is obtained by steam extraction in which the tea leaves are brought into contact with superheated steam, and the steam after the contact is recovered, and the food or drink is further subject to steam extraction. The food / beverage products of Claim 5 containing the water extract of the tea leaf obtained by carrying out the water extraction of another tea leaf of the same kind as the tea leaf.
Claims (5)
該褐変抑制剤は、茶葉の過熱蒸気抽出物よりなることを特徴とする褐変抑制剤。 A browning inhibitor added to the food or drink to suppress browning of the food or drink,
The browning inhibitor comprises a superheated steam extract of tea leaves.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2012097042A (en) * | 2010-11-02 | 2012-05-24 | Shizuokaken Koritsu Daigaku Hojin | Method for producing tea leaf for beverage |
JP2020039311A (en) * | 2018-09-12 | 2020-03-19 | ポッカサッポロフード&ビバレッジ株式会社 | Fruit juice and beverage containing flavorful acid citrus syrup |
KR102622345B1 (en) * | 2022-10-31 | 2024-01-09 | 이재준 | Preparing Method of Apple Juice With Minimal Browning Reaction |
KR102622346B1 (en) * | 2022-10-31 | 2024-01-09 | 이재준 | Preparing Method of Apple Juice With Minimal Destruction of Vitamins and Nutrients |
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JP2003159038A (en) * | 2001-11-29 | 2003-06-03 | Taiyo Kagaku Co Ltd | Photo deterioration-preventing agent |
JP2005137269A (en) * | 2003-11-06 | 2005-06-02 | Pokka Corp | Volatile component, method for producing the same, and food and drink |
JP2007038115A (en) * | 2005-08-02 | 2007-02-15 | Dainippon Kasei Kk | Method of extracting biological origin component |
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JPS63135483A (en) * | 1986-11-26 | 1988-06-07 | Sankyo Co Ltd | Antioxidant |
JP2003159038A (en) * | 2001-11-29 | 2003-06-03 | Taiyo Kagaku Co Ltd | Photo deterioration-preventing agent |
JP2005137269A (en) * | 2003-11-06 | 2005-06-02 | Pokka Corp | Volatile component, method for producing the same, and food and drink |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2012097042A (en) * | 2010-11-02 | 2012-05-24 | Shizuokaken Koritsu Daigaku Hojin | Method for producing tea leaf for beverage |
JP2020039311A (en) * | 2018-09-12 | 2020-03-19 | ポッカサッポロフード&ビバレッジ株式会社 | Fruit juice and beverage containing flavorful acid citrus syrup |
JP7228354B2 (en) | 2018-09-12 | 2023-02-24 | ポッカサッポロフード&ビバレッジ株式会社 | Citrus molasses-containing fruit juices and beverages |
KR102622345B1 (en) * | 2022-10-31 | 2024-01-09 | 이재준 | Preparing Method of Apple Juice With Minimal Browning Reaction |
KR102622346B1 (en) * | 2022-10-31 | 2024-01-09 | 이재준 | Preparing Method of Apple Juice With Minimal Destruction of Vitamins and Nutrients |
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