JP2007064709A - Deodorization testing machine - Google Patents

Deodorization testing machine Download PDF

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Publication number
JP2007064709A
JP2007064709A JP2005248736A JP2005248736A JP2007064709A JP 2007064709 A JP2007064709 A JP 2007064709A JP 2005248736 A JP2005248736 A JP 2005248736A JP 2005248736 A JP2005248736 A JP 2005248736A JP 2007064709 A JP2007064709 A JP 2007064709A
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carbon dioxide
sample chamber
deodorization
gas
color
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JP2005248736A
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Yasutaro Seto
保太郎 瀬戸
Shuichi Motonaka
修一 源中
Yoshinari Miyamura
佳成 宮村
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Suminoe Textile Co Ltd
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Suminoe Textile Co Ltd
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Priority to JP2005248736A priority Critical patent/JP2007064709A/en
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  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a deodorization testing machine (e.g., a presenting testing machine for performing a deodorizing capacity recognizing test of a deodorant before customers) capable of visually showing a process for finally decomposing a malodorous gas into water and carbon dioxide, to simply prove the effects of adsorption, deodorization, decomposition, etc. <P>SOLUTION: A deodorizing substance having the deodorant supported thereon is placed in a sample chamber, a definite amount of the malodorous gas is injected in the sample chamber and a malodor is decomposed by circulating air in the sample chamber to accumulate carbon dioxide in the gas. The increase situation of the concentration of carbon dioxide is visually recognized by inserting a color developing device reacting with carbon dioxide to develop a color in the circulating route. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、消臭分解能力を客観的に簡便に評価できるようにした消臭試験機に関するものである。   The present invention relates to a deodorization tester capable of objectively and simply evaluating the deodorizing ability.

近年、住宅の高気密化にともない、シックハウス症候群に代表されるように、例えば住宅建材等から発生する微量なホルムアルデヒト等の揮発性有機化合物(VOC)が、人間の目、鼻、喉等の粘膜に影響を及ぼし、様々な症状を引き起こす原因と考えられるようになっている。また一方、生活者の清潔嗜好がすすみ、ホルムアルデヒドだけでなく、体臭や、食品等の臭い、更にはペット臭や生ゴミ臭等の生活臭が混交され、悪臭として高気密化された室内空間にこもってしまい不快感をかもしだすことから、室内生活環境の汚染問題が急速に問題視されてきている。   In recent years, with the increase in airtightness of houses, as represented by sick house syndrome, for example, a small amount of volatile organic compounds (VOC) such as formaldehyde, which are generated from house building materials, are used in the mucous membranes of human eyes, nose, throat, etc. It is considered to be a cause of various symptoms. On the other hand, the consumer's preference for cleanliness has progressed, and not only formaldehyde but also body odors, food odors, and other odors such as pet odors and garbage odors are mixed, resulting in a highly airtight indoor space. The problem of contamination of the indoor living environment has rapidly been regarded as a problem because it has become awkward and uncomfortable.

これにともない、脱臭、吸着、消臭等の機能性を付与する技術は多く開示され実用化されているものの、その効果を実証しようとすると実験装置が大掛かりで高価なものとなってしまうことから、悪臭の発生する現場で簡易的に、吸着、消臭、分解等の効果を実証する試験機の開発がのぞまれている。   Along with this, many technologies that provide functionality such as deodorization, adsorption, and deodorization have been disclosed and put into practical use, but when trying to demonstrate the effect, the experimental apparatus becomes large and expensive. The development of testing machines that easily demonstrate the effects of adsorption, deodorization, decomposition, etc. is desired at sites where malodors occur.

特許文献1においては、試料の設置される試料室をはさんで、前室および後室を持つタテ型筒状の装置で、前室から試料室、後室へと気体を流し、この間試料室の試料に気体を定量的に暴露させ、時間や場所をかえても測定値にばらつきがなく、信頼性のあるデータを得ることができる臭気吸着濃度比較試験機の技術を開示している。   In Patent Document 1, a vertical cylindrical apparatus having a front chamber and a rear chamber across a sample chamber in which a sample is placed, and a gas is allowed to flow from the front chamber to the sample chamber and the rear chamber. The technology of an odor adsorption concentration comparison tester is disclosed in which a gas is quantitatively exposed to a sample and the measured value does not vary even when the time and place are changed, and reliable data can be obtained.

特開平5−18947号公報JP-A-5-18947

しかしながら、上記の方法では、室内空気における様々な臭気ガスの吸着性能を正確に測定するには有効な方法であるが、触媒等で悪臭ガスが分解され、最終的に水と二酸化炭素に分解されることを示すようなものではなかった。本発明は、悪臭ガスが分解され、最終的に水と二酸化炭素に分解される過程を視覚的に示し、吸着、消臭、分解等の効果を簡易的に実証することができる試験機(例えば消臭剤の消臭性能の確認試験としてお客様の前で試験するプレゼン用試験機)として開発をするものである。   However, the above method is an effective method for accurately measuring the adsorption performance of various odorous gases in indoor air, but the malodorous gas is decomposed by a catalyst or the like and finally decomposed into water and carbon dioxide. It was not something to show that. The present invention visually shows a process in which malodorous gas is decomposed and finally decomposed into water and carbon dioxide, and can easily demonstrate the effects of adsorption, deodorization, decomposition, etc. (for example, As a confirmation test of deodorant performance of deodorants, it will be developed as a test machine for presentations to be tested in front of customers.

本発明は、試料室内に、消臭剤や消臭剤を担持した繊維物を置き、悪臭ガスを一定量注入してから密閉し、試料室内の空気を循環させてやることにより、悪臭が分解され気体中の二酸化炭素が蓄積して、濃度が増加する様子を視覚的に確認できるようにしたものである。上記課題を達成するために、本発明は以下の手段を提供する。   In the present invention, a deodorant or a fiber carrying a deodorant is placed in a sample chamber, a certain amount of malodorous gas is injected and sealed, and air in the sample chamber is circulated to decompose bad odor. In this way, carbon dioxide in the gas accumulates and it is possible to visually confirm how the concentration increases. In order to achieve the above object, the present invention provides the following means.

[1]試料室と、試料室内の気体を循環させる循環装置とからなる消臭試験機において、前記気体の循環経路中に二酸化炭素に反応して発色する発色装置を挿入していることを特徴とする消臭試験機。   [1] In a deodorization tester comprising a sample chamber and a circulation device for circulating a gas in the sample chamber, a coloring device that reacts with carbon dioxide and inserts a coloring device in the gas circulation path. Deodorization testing machine.

[2]前記発色装置は、内部に酸化カリウムまたはヒドラジンと、指示薬が充填された発色装置である前項1に記載の消臭試験機。   [2] The deodorization tester according to [1], wherein the color development device is a color development device filled with potassium oxide or hydrazine and an indicator.

[3]前記二酸化炭素に反応して発色する発色装置は、二酸化炭素の濃度に応じて色の濃度を変化させる発色装置である前項1または2に記載の消臭試験機。   [3] The deodorization tester according to [1] or [2], wherein the color developing device that develops color in response to carbon dioxide is a color developing device that changes the color density according to the carbon dioxide concentration.

[1]の発明では、気体の循環経路中に二酸化炭素に反応して発色する発色装置を挿入しているので、悪臭が分解されて発生する二酸化炭素を視覚的に確認することができるので、専門的な知識を有しない人でも二酸化炭素の発生を確認することができる。   In the invention of [1], since the coloring device that reacts with carbon dioxide in the gas circulation path is inserted, it is possible to visually confirm carbon dioxide generated by the decomposition of malodor, Even people without specialized knowledge can confirm the generation of carbon dioxide.

[2]の発明では、発色装置中の酸化カリウムまたはヒドラジンが二酸化炭素に反応して、指示薬が紫色に発色するので、色の変化を目視して二酸化炭素の発生を確認することができる。   In the invention of [2], since potassium oxide or hydrazine in the color developing device reacts with carbon dioxide and the indicator develops a purple color, the color change can be visually observed to confirm the generation of carbon dioxide.

[3]の発明では、二酸化炭素の濃度に応じて色の濃度を変化させる発色装置であるので、発色装置の色から二酸化炭素の濃度を特定して悪臭ガスの濃度を大まかに推定することができる。   In the invention of [3], since the color developing device changes the color density according to the carbon dioxide concentration, the concentration of carbon dioxide can be specified from the color of the color developing device to roughly estimate the malodorous gas concentration. it can.

以下本発明をさらに図1により詳しく説明する。本発明は、試料室2と、試料室内の気体を循環させる循環装置3と、気体の循環経路4と発色装置5からなっている。試料室2に悪臭ガスを入れ、循環装置3を稼動して試料室内のガスを均一にし、発色装置5が発色していないことを確認する。その後、試料室2内に消臭材をいれ、徐々に発色装置5が発色していくのを観察し、二酸化炭素の増加が確認され、悪臭ガスが分解していることを客観的に確認することができる。   Hereinafter, the present invention will be described in more detail with reference to FIG. The present invention includes a sample chamber 2, a circulation device 3 that circulates gas in the sample chamber, a gas circulation path 4, and a coloring device 5. Odor gas is put into the sample chamber 2, the circulation device 3 is operated to make the gas in the sample chamber uniform, and it is confirmed that the color developing device 5 is not colored. Thereafter, a deodorizing material is placed in the sample chamber 2, and the color developing device 5 is observed to gradually develop color, and an increase in carbon dioxide is confirmed, and it is objectively confirmed that malodorous gas is decomposed. be able to.

試料室2は、密閉された空間が確保されれば特に限定しないが、内部の状況が確認できるよう透明な密閉容器が好ましい。容積としては、1〜20リットルあればよく、ガス注入口6と消臭材挿入口7を具備していることが好ましい。   The sample chamber 2 is not particularly limited as long as a sealed space is secured, but a transparent sealed container is preferable so that an internal situation can be confirmed. The volume may be 1 to 20 liters, and preferably includes the gas injection port 6 and the deodorant insertion port 7.

循環装置3は、密閉された試料室内のガスを一定速度で循環させるためのもので、ポンプや送風機等であればよい。   The circulation device 3 is for circulating the gas in the sealed sample chamber at a constant speed, and may be a pump, a blower or the like.

循環経路4は、試料室の壁面にガス入口と排出口を設けて、ガスの漏れのないようにパイプでつないであり、循環経路4の途中に循環装置3と発色装置5を入れる。   The circulation path 4 is provided with a gas inlet and a discharge port on the wall surface of the sample chamber, and is connected by a pipe so that no gas leaks. The circulation apparatus 3 and the color development apparatus 5 are inserted in the middle of the circulation path 4.

発色装置5は透明容器で試料室内のガスがポンプや送風機等で通過する密度に酸化カリウムまたはヒドラジンと、指示薬を詰めておけばよい。二酸化炭素のない時は白色であるが、二酸化炭素の量が増えるにつれて紫色となり濃度を増すようになっている。   The color developing device 5 is a transparent container, and potassium oxide or hydrazine and an indicator may be packed at a density at which gas in the sample chamber passes by a pump, a blower, or the like. When there is no carbon dioxide, it is white, but as the amount of carbon dioxide increases, it becomes purple and the concentration increases.

<実施例1>
図1のように25cm角の透明なアクリル樹脂製で、ガス注入口6と試料挿入口7を具備している試料室2に、純空気を入れ循環装置3(ポンプ)を5分間稼動し発色装置5が発色していないことを確認する。次にトルエンガスを500PPMとなるようにガス注入口6から注入し、循環装置3(ポンプ)を5分間稼動し、試料室2内のトルエンガスを均一に混ぜ合わせ、発色装置5が発色していないことを確認した。次に試料挿入口7から、光触媒消臭剤を塗布した消臭布帛(10×10cm)を試料室2内の底面に置いて光照射しそのまま循環装置3(ポンプ)を6時間稼動し続けたところ、試料室2内のトルエンガスは300PPMまで減少し、二酸化炭素の量が増え、発色装置5が徐々に紫色に変色していくのが確認された。これによってトルエンガスが分解されて発生する二酸化炭素を視覚的に確認することができた。なお、発色装置5としてガステック株式会社製二酸化炭素検知管を使用した。
<Example 1>
As shown in Fig. 1, pure air is introduced into a sample chamber 2 made of a transparent acrylic resin of 25 cm square and equipped with a gas injection port 6 and a sample insertion port 7. Confirm that the device 5 is not colored. Next, toluene gas is injected from the gas inlet 6 to 500 PPM, the circulation device 3 (pump) is operated for 5 minutes, the toluene gas in the sample chamber 2 is mixed uniformly, and the color developing device 5 develops color. Confirmed that there is no. Next, a deodorizing fabric (10 × 10 cm) coated with a photocatalytic deodorant was placed on the bottom of the sample chamber 2 from the sample insertion port 7 and irradiated with light, and the circulation device 3 (pump) continued to operate for 6 hours. However, it was confirmed that the toluene gas in the sample chamber 2 decreased to 300 PPM, the amount of carbon dioxide increased, and the color developing device 5 gradually changed to purple. As a result, carbon dioxide generated by the decomposition of toluene gas could be visually confirmed. A carbon dioxide detector tube manufactured by Gastec Corporation was used as the color developing device 5.

<実施例2>
発色装置5を新しいものと交換し、実施例1において試料室2内に純空気を入れ次にトルエンガスを100PPMとして用いた以外は、実施例1と同様にした。実施例1と同様に、発色装置5が徐々に紫色に変色していくのが確認されたが、紫色の濃さが実施例1よりもうすいこと目視し、二酸化炭素の発生量の少ないことを視覚的に確認することができた。
<Example 2>
The color developing device 5 was replaced with a new one, and the same procedure as in Example 1 was performed except that pure air was introduced into the sample chamber 2 in Example 1 and then toluene gas was used as 100 PPM. As in Example 1, it was confirmed that the color developing device 5 gradually changed to purple, but it was confirmed that the purple color was darker than Example 1, and that the amount of carbon dioxide generated was small. It was confirmed visually.

本発明の1実施例の消臭試験機1の説明図である。1 is an explanatory diagram of a deodorization testing machine 1 according to one embodiment of the present invention. FIG.

符号の説明Explanation of symbols

1 消臭試験機
2 試料室
3 循環装置
4 循環経路
5 発色装置
6 ガス注入口
7 試料挿入口
1 Deodorization testing machine
2 Sample chamber 3 Circulating device 4 Circulating path 5 Coloring device 6 Gas inlet 7 Sample inlet

Claims (3)

試料室と、試料室内の気体を循環させる循環装置とからなる消臭試験機において、前記気体の循環経路中に二酸化炭素に反応して発色する発色装置を挿入していることを特徴とする消臭試験機。   In the deodorization tester comprising a sample chamber and a circulation device for circulating gas in the sample chamber, a color developing device for coloring in response to carbon dioxide is inserted in the gas circulation path. Odor testing machine. 前記発色装置は、内部に酸化カリウムまたはヒドラジンと、指示薬が充填された発色装置である請求項1に記載の消臭試験機。   The deodorization tester according to claim 1, wherein the color developing device is a color developing device filled with potassium oxide or hydrazine and an indicator. 前記二酸化炭素に反応して発色する発色装置は、二酸化炭素の濃度に応じて色の濃度を変化させる発色装置である請求項1または2に記載の消臭試験機。   The deodorization tester according to claim 1 or 2, wherein the color development device that develops color in response to carbon dioxide is a color development device that changes a color density in accordance with the concentration of carbon dioxide.
JP2005248736A 2005-08-30 2005-08-30 Deodorization testing machine Pending JP2007064709A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101205032B1 (en) 2011-05-03 2012-11-26 한국섬유개발연구원 Deodorization rate measuring system for fabrics
JP2018169359A (en) * 2017-03-30 2018-11-01 日東紡績株式会社 Evaluation device for functional fiber
JP2020071121A (en) * 2018-10-31 2020-05-07 大陽日酸株式会社 Hydrogen isotope ratio measurement method and device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101205032B1 (en) 2011-05-03 2012-11-26 한국섬유개발연구원 Deodorization rate measuring system for fabrics
JP2018169359A (en) * 2017-03-30 2018-11-01 日東紡績株式会社 Evaluation device for functional fiber
JP2020071121A (en) * 2018-10-31 2020-05-07 大陽日酸株式会社 Hydrogen isotope ratio measurement method and device
JP7189730B2 (en) 2018-10-31 2022-12-14 大陽日酸株式会社 Hydrogen isotope ratio measurement method and apparatus

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