JP2007064469A5 - - Google Patents
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- JP2007064469A5 JP2007064469A5 JP2005280758A JP2005280758A JP2007064469A5 JP 2007064469 A5 JP2007064469 A5 JP 2007064469A5 JP 2005280758 A JP2005280758 A JP 2005280758A JP 2005280758 A JP2005280758 A JP 2005280758A JP 2007064469 A5 JP2007064469 A5 JP 2007064469A5
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- heat insulating
- base material
- silicate
- natoryuumu
- insulating material
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- 239000000463 material Substances 0.000 claims description 61
- 239000000835 fiber Substances 0.000 claims description 44
- 239000003365 glass fiber Substances 0.000 claims description 33
- 239000011810 insulating material Substances 0.000 claims description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 23
- 239000000126 substance Substances 0.000 claims description 22
- 239000004745 nonwoven fabric Substances 0.000 claims description 20
- 239000002759 woven fabric Substances 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 11
- 229920000742 Cotton Polymers 0.000 claims description 10
- 239000003610 charcoal Substances 0.000 claims description 10
- 239000004115 Sodium Silicate Substances 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 8
- 235000013311 vegetables Nutrition 0.000 claims description 7
- 239000002699 waste material Substances 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 58
- 239000011248 coating agent Substances 0.000 description 17
- 238000000576 coating method Methods 0.000 description 17
- 239000010425 asbestos Substances 0.000 description 13
- 229910052895 riebeckite Inorganic materials 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- 238000005470 impregnation Methods 0.000 description 12
- 229910000831 Steel Inorganic materials 0.000 description 11
- 238000009413 insulation Methods 0.000 description 11
- 239000010959 steel Substances 0.000 description 11
- 241000196324 Embryophyta Species 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 239000004744 fabric Substances 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 239000003063 flame retardant Substances 0.000 description 5
- 239000003779 heat-resistant material Substances 0.000 description 5
- 239000004566 building material Substances 0.000 description 4
- 238000004079 fireproofing Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 240000007170 Cocos nucifera Species 0.000 description 3
- 241000255925 Diptera Species 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000004587 chromatography analysis Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000011152 fibreglass Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 210000001736 Capillaries Anatomy 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011490 mineral wool Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000002990 reinforced plastic Substances 0.000 description 2
- 230000003014 reinforcing Effects 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 101710042463 ANAPC1 Proteins 0.000 description 1
- OHORFAFFMDIQRR-UHFFFAOYSA-P Hexafluorosilicic acid Chemical compound [H+].[H+].F[Si-2](F)(F)(F)(F)F OHORFAFFMDIQRR-UHFFFAOYSA-P 0.000 description 1
- 210000003666 Nerve Fibers, Myelinated Anatomy 0.000 description 1
- 241000253999 Phasmatodea Species 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 206010063562 Radiation skin injury Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001464 adherent Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 230000029578 entry into host Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000011068 load Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 230000001717 pathogenic Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000009715 pressure infiltration Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000979 retarding Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 210000001519 tissues Anatomy 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Description
全産業分野にわたって使用可能な断熱材である。 In all industries is an insulation material that can be used I cotton.
従来の断熱材、特にアスベスト断熱材は全国的に健康被害をもたらしており、現状では、これに代わる物が無い。 Conventional insulation material, and especially asbestos insulation resulted in a nationwide health damage, at present, there is no an alternative to Re this.
アスベストの微細繊維の気中浮遊とアスベストが持つ発病特性が、人類の健康に大きな被害をもたらした。 Airborne asbestos fine fibers and the pathogenic characteristics of asbestos have caused great damage to human health.
又、アスベストに限らず、従来から使用されているガラス繊維においては、ガラス自体が持つ溶解温度が600℃前後でも、一旦繊維化すれば、300℃から400℃が最大であり、建材に使用のアルミ泊付きのガラス繊維に至っては、接着材によって200℃強で着火燃焼する欠点を持っている。 Further, not limited to asbestos, in the glass fiber which has been used conventionally, even melting temperature 600 ° C. before and after with the glass itself, once fiberizing, a maximum 400 ° C. from 300 ° C., the used building materials Glass fibers with aluminum stays have the disadvantage that they are ignited and burned at 200 ° C. or more with adhesives.
又、断熱材、特に火災における金属の熱性強度劣化防御として、アスベストに代わる最短距離は、周知の事実で生産されているガラス繊維の強度昂進化であるが、従来の400℃で高温化する火災には全く意味が無く、ガラス繊維を、より高温に耐え得る加工が望まれていた。 Also, insulation, as thermal deterioration of strength defense metals particularly in fire, the shortest distance in place of asbestos, but Ru Oh intensity Ngong evolution of the glass fibers are produced in a known fact, high Yutakaka a conventional 400 ° C. There is no meaning in the fire, and the processing which can endure glass fiber to higher temperature was desired.
特に、断熱材では無い物性は使用に値しないが、それを加工する事によって900℃前後の耐熱材に変化させる技術が望まれている。
以上に述べた通り、単なる日常生活に必要な省エネルギ的断熱効果目的なら従来のガラス繊維でも十分であるが、一旦火災発生の場合、或はそれに匹敵する環境での耐熱材の使用ではガラス繊維では全く意味が無く、その使用に値しない環境で、しかもアスベストに代わるものとして利用出来るガラス繊維とするには次の課題が存在する。 As mentioned above, it is also sufficient conventional glass fiber if Shoeneru formic adiabatic effect purposes required just daily, once the glass in the use of heat-resistant material in an environment when the fire, or comparable to that There is the following problem to make glass fiber that can be used as an alternative to asbestos in an environment that is completely meaningless and not worth using.
ガラス繊維の特徴である、同じ直径のピアノ線よりも高い抗張力、但し屈曲に弱い欠点は直径の微細口径化で対応できるが、耐熱性は300℃を越えれば急速に劣化現象を起こす。 Is characteristic of fiberglass, higher tensile strength than the piano wire of the same diameter, although weak drawbacks flexion may correspond with a fine diameter of a diameter, heat resistance causes rapid deterioration if exceeds the 300 ° C..
無アルカリ性の特殊ガラス繊維も400℃耐熱性ではあるが、火災等、或はそれに匹敵する温度環境下では使用に値しない。 Alkali-free special glass fibers are also heat resistant at 400 ° C., but are not suitable for use in a fire or the like or in a temperature environment comparable to that.
特に、数多い各種素材の中で、可燃物を不燃にする技術の確立が出来れば、幾何級数的に用途が拡大される。 In particular, among the many various materials, as long established technique for flammable materials nonflammable, exponentially application is enlarged.
前記する課題を解決するために、本願発明に係る断熱材は、基材に、珪酸ナトリュウムが含浸塗布されてなることを特徴とする。In order to solve the above-described problems, the heat insulating material according to the present invention is characterized in that a base material is impregnated with sodium silicate.
また、前記基材は、ガラス繊維であることを特徴とする。The base material is glass fiber.
また、前記基材は、ガラス繊維不織布であることを特徴とする。The base material is a glass fiber nonwoven fabric.
また、前記基材は、ガラス繊維織布であることを特徴とする。The base material is a glass fiber woven fabric.
また、前記基材は、ガラス繊維綿であることを特徴とする。The base material is glass fiber cotton.
また、前記基材は、パルプ紙であることを特徴とする。The base material is pulp paper.
また、前記基材は、綿状パルプであることを特徴とする。The base material is cotton-like pulp.
また、前記基材は、植物繊維であることを特徴とする。The base material is a plant fiber.
また、前記基材は、植物繊維不織布であることを特徴とする。The base material is a vegetable fiber nonwoven fabric.
また、前記基材は、植物繊維織布であることを特徴とする。The substrate is a vegetable fiber woven fabric.
また、前記基材は、樹木の破砕粉であることを特徴とする。The base material is a crushed powder of a tree.
また、前記基材は、化学繊維であることを特徴とする。The base material is a chemical fiber.
また、前記基材は、化学繊維不織布であることを特徴とする。The base material is a chemical fiber nonwoven fabric.
また、前記基材は、化学繊維織布であることを特徴とする。The base material is a chemical fiber woven fabric.
また、前記基材は、木炭であることを特徴とする。The base material is charcoal.
また、前記基材は、塊状炭素であることを特徴とする。Further, the base material is a block carbon.
また、前記基材は、粒状炭素であることを特徴とする。The base material is granular carbon.
また、前記基材は、各種廃棄物であることを特徴とする。The base material is various wastes.
また、前記基材の断熱材の少なくとも二つからなることを特徴とする。Moreover, it consists of at least two of the heat insulating materials of the base material.
基材に、珪酸ナトリュウムが含浸塗布されてなる断熱材は、アーク溶接棒の1600℃以上の温度環境に使用される被覆材にも使用される物で、耐熱性能保持は言う間でもない。 The substrate, insulation silicate Natoryuumu is being impregnated coated, be construed as being also used for coating materials used in the 1600 ° C. or higher temperature environment of arc welding rod, nor between heat resistance holding said .
この珪酸ナトリュウムを、300℃から400℃迄の耐熱材に塗布含浸させる事によって、耐熱性能を昂進して断熱性能を向上させる。 By applying and impregnating sodium silicate with a heat-resistant material at 300 ° C. to 400 ° C. , the heat-resistant performance is improved and the heat insulating performance is improved .
もう一つは、植物素材の活性炭素の板、或は、粒状物は、不燃材とはいっても、高温では灰化して消滅すれば断熱材の意味が無くなる事から、これらに珪酸ナトリュウムを塗布含浸させる事によって、灰化消滅する事を防止し、断熱維持性能の付加となる。 Second, activated carbon plates of plant material, or granules, coating also entered a non-combustible, from the fact that the meaning of the heat insulating material is eliminated if disappear incinerated at high temperatures, these silicate Natoryuumu Impregnation prevents the ash from disappearing and adds heat insulation performance.
もう一つは、不燃材には程遠い物質、植物綿や樹脂腐食布等に含浸させる事によって、可燃物が不燃物に変化するものである。 The other is that a combustible material is changed into a non-combustible material by impregnating it with a material far from the incombustible material, such as vegetable cotton or resin corroded cloth.
例えば、珪酸ナトリュウムを樹脂繊維不織布に含浸させるだけで、樹脂繊維自体に浸潤するまでもなく、繊維が細ければ細い程、不織布の毛細管現象によって繊維周囲に付着し、火炎接触部位が1mmから1.5mmの深さで黒変炭化するだけで、完全に近い耐熱素材へと変化する。 For example, the resin fiber nonwoven fabric is simply impregnated with sodium silicate silicate so that it does not infiltrate the resin fiber itself. The thinner the fiber, the more it adheres to the periphery of the fiber due to the capillary phenomenon of the nonwoven fabric. only blackening carbonized at a depth of .5mm, changes to nearly complete thermally resistant material.
但し、大きな可燃性物体で、芯まで含浸せずに表面部位だけ塗布含浸可能な場合は残念ながら、芯部位が可燃性維持である事はやむを得ない。 However, a large flammable objects, unfortunately only when applying impregnation available-for surface sites without impregnation to the core, it core sites are flammable maintained unavoidable.
アスベストの健康被害が数十年経過後に頻発している現状では、一刻も早く、その代替物質の開発が急がれている中で、アスベスト以外の不燃物の選択寄りも幾何級数的種類が有る可燃物を、珪酸ナトリュウム含浸塗布によって断熱材とする事が、経済性とも相まって、大きなメリットを発揮する。 At present health hazards of asbestos have been frequent after the lapse of a few tens of years, as soon as possible, in the development of its generation Kawabutsu quality are urgently needed, select closer geometric kind of non-combustible substances other than asbestos the there combustibles, that a heat insulating material by silica Natoryuumu impregnation coating, combined also with economy, exerts significant benefits.
同時に、環境保全のリサイクル、省エネルギの面からは、間伐材を破砕粉化して、珪酸ナトリュウムを含浸塗布すれば、岩綿以上の耐熱材も可能であり、同時に、古紙パルプに珪酸ナトリュウムを含浸塗布すれば、吹きつけ岩綿材と同様の効果が発揮され、鉄骨吹き付けが素材は紙である事の、夢の話しが現実に実証された。 At the same time, the environmental recycling, from the viewpoint of saving energy formic, turned into 砕粉 broken thinned wood, if impregnated coated silicate Natoryuumu, are also possible over the heat-resistant material rock wool, simultaneously, silicate waste paper pulp Natoryuumu When impregnated, the same effect as sprayed rock wool material was demonstrated, and the story of the dream that the steel spray was made of paper was actually demonstrated.
以下、実施例を説明するが、その前に、珪酸ナトリュウムの性状を記す。 The following will explain the actual施例, prior to, referred to properties of silicate Natoryuumu.
珪酸ナトリュウムの製法には乾式と湿式が有るが、両者共、珪砂または珪酸白土とソーダ灰又は苛性ソーダが原料で、健康に害を及ぼすものではない。 Although dry and wet is present in preparation of silicate Natoryuumu, both of silica sand or the raw material silicate clay and soda ash or caustic soda, do not harm health.
この珪砂とソーダ灰の比率によって種々効力に差が生じるが、不燃処理対応物によって選択が出来る。 Although differences in various efficacy by the ratio of the silica sand and soda ash is produced, it is selected by the noncombustible treatment counterparts.
珪酸ナトリュウム液を目的物に塗布含浸して火炎放射での耐熱効果は、一例として、処理物がティッシュペーパーで、超可燃物で有るにもかかわらず、珪酸ナトリュウム液浸潤で2mm板状乾燥では、被火炎部位が1mm乃至1.5mmの深さまでの炭化で、炭化部位が断熱層になり、ブタンガスバーナーで一点集中バーニングしても1.5mm以下の深部迄の炭化が進行せず、2mm厚みの裏側は全くバーニング前と色も変化無く、断熱と耐火性能を表した。 Heat effect of the flame radiation by coating impregnated silicate Natoryuumu liquid to an object is to an example, the processing object is a tissue Bae over path over, despite there ultra combustibles, 2 mm silicate Natoryuumu solution dipping the plate-like drying, carbonization of depth of the flame sites 1mm to 1.5mm, carbide site becomes heat insulating layer, even if one point focused bar training in Butangasuba over Na over until the following deep 1.5mm carbonization does not proceed, the back is quite bar training before 2mm thickness and color without any change, represents the thermal insulation and fire resistance.
(糸状)ガラス繊維の集合体、例えばガラス繊維ロープ或はガラス繊維断熱材の繊維間に、珪酸ナトリュウム溶液を、ガラス繊維表面への密着剤にて密着、含浸付着する事によって耐熱性を保持し、仮に火災時の様な高温になって密着剤が高温化しても珪酸ナトリュウムによって密着剤も難燃化或は不燃化して耐熱効果を表す。 (Filamentous) aggregate of glass fibers, for example, between the fibers of the glass fiber B-loop or fiberglass insulation, silicate Natoryuumu solution, adhesion at the adhesion agent to the glass fiber surface, the heat resistance by impregnating adhesion holding, if represents the heat effect adhesion agent is hot, such as may be flame retardant of or fireproofing also adhesion agent by silica Natoryuumu be heated to a high temperature of a fire.
ガラス繊維不織布に、珪酸ナトリュウム溶液を含浸塗布することによって、不織布だけに毛細管現象同様に非常に多くの珪酸ナトリュウム溶液を抱き込み、耐熱効果は上がるがコストの問題も有り、加工方法としては、ガラス繊維不織布を珪酸ナトリュウム溶液槽を通過させて、両面ローラーで絞り、乾燥させたが、上下、或は左右ローラーを思いっきり加圧して絞っても、機能性に変化はなかった。 The glass fiber nonwoven fabric, by impregnation coating a silicate Natoryuumu solution, capillary action only nonwoven likewise very embrace many silicate Natoryuumu solution, heat effect increases but there is also cost issues, as a processing method, the glass fiber nonwoven fabric by passing the silicate Natoryuumu solution bath, squeezed with a double-sided b over La chromatography, was dried, vertically, or horizontally Russia be squeezed by applying over La chromatography fullest pressure and no change in functional It was.
ガラス繊維織布に、珪酸ナトリュウム溶液を含浸塗布することは、FRP強化プラスティック等に使用されるガラスクロスの耐熱性向上と、難燃性樹脂成型用の強化材に使用する目的で加工したが、本発明のFRP強化プラスチック板の燃焼試験では、500℃バーニング試験では樹脂が燃焼消滅した後も、最後迄残ったのは珪酸ナトリュウム溶液含浸塗布のガラス繊維織布であった。 The glass fiber woven fabric impregnated with sodium silicate solution was processed for the purpose of improving the heat resistance of glass cloth used for FRP reinforced plastics and the like, and for reinforcing materials for flame retardant resin molding. the combustion test of FRP reinforced plastic plate of the present invention, even after the resin has been extinguished combustion at 500 ° C. bar training trials, the last until the remaining is given and a glass fiber woven fabric silicate Natoryuumu solution impregnated coating.
ガラス繊維綿に、珪酸ナトリュウム溶液を含浸塗布させれば、全くの高温不燃性綿が誕生し、アスベスト吹きつけ工程と同様の作業工程で、不燃材の建築物吹きつけ作業が可能であった。
又、可燃性液体、或は可燃性ガス等の移送管継手の断熱材コーティングにも、全くアスベストに勝る効果を表した。
この場合には、一例として、温度管理のレベルで選択されたガラスクロス又はカーボンクロスで、珪酸ナトリュウム溶液を含浸塗布乾燥させたガラス繊維綿を座布団様式で包み、管継手を覆う事によって目的を果たした。
The glass fibers of cotton, if impregnated coated silicate Natoryuumu solution, born at all hot incombustible cotton, asbestos spraying process similar working process, it was possible to work blown building nonflammable .
Further, combustible liquid, or even heat-insulating material co computing the transfer pipe fittings such as combustible gas, represents the effect that at all over asbestos.
In this case, as an example, a glass cloth or mosquitoes over Bonkurosu selected at the level of temperature control, a glass fiber cotton impregnated coated dried silicate Natoryuumu solution wrapped in cushion manner, the object by covering the pipe joint Played.
パルプ紙に、珪酸ナトリュウムを含浸塗布したもので、最もユニークであったものは、古紙再生過程の綿状古紙に含浸させて、鋼製建材に吹きつけ、アスベスト同様の目的が達成された事である。 A pulp paper, which was impregnated coated silicate Natoryuumu, most uni over those were click is impregnated into cotton-like paper of used paper recycling process, blown into the steel construction materials, asbestos similar purposes have been achieved It is a thing.
又、古紙再生段階で珪酸ナトリュウム溶液を含浸塗布し、圧密乾燥させれば、完全な耐熱ボードが形成された。 Further, silicate Natoryuumu solution impregnated coated with paper recycling stage, if compacted dry, full heat board is formed.
もう一つは、製鋼所高炉の溶解鉄サンプリングで、紙管に珪酸ナトリュウム溶液を含浸塗布し、千数百度の溶解鉄のサンプリングに、一定時間とは言え使用可能であった事も特筆すべきである。 Notably other is in a dissolved iron sampling steel mill blast furnace, silicate Natoryuumu solution was impregnated applied to the paper tube, the sampling of the thousand several hundred degrees of dissolution of iron, it could be used although the predetermined time even It is.
同時に、車社会でのトンネル内火災時の最も危険なエンジンルームで、外部からの引火危険性防止で、キャブレター濾過紙の400℃発火不能試験でも、濾過機能の低下もなく、含浸塗布濃度の調整だけで効果を上げた。 At the same time, the most dangerous engine Le chromatography beam during tunnel fires with motorization, a flash hazard prevention from outside, even at 400 ° C. firing untestable the carburetor filter paper, no reduction in the filtration function, impregnation coating The effect was improved only by adjusting the concentration.
忘れてはならない含浸塗布加工物は、和風建築に欠かせない障子紙で、珪酸ナトリュウム溶液を希釈して障子紙に吹きつけるだけで、ライターの炎を直に付けても、黒く炭化するだけで、煙も出ない現象であった。 Forget impregnated coated workpiece must is a shoji paper indispensable to Japanese building, only diluted silicate Natoryuumu solution sprayed on shoji paper, only be directly attached to the flame of the writer over, black carbonized It was a phenomenon with no smoke.
植物性綿状パルプに、珪酸ナトリュウム溶液を含浸塗布することで、型押し乾燥によって種々形状成型が出来、自動車マフラー内に使用されているアスベスト型成型品の代替にもなり、この種の製品はこれに限らず、各種素材でも可能である。 The plant properties flocculent pulp, by impregnating coating a silicate Natoryuumu solution, can be variously shaped molded by embossing drying, becomes a replacement cash asbestos type moldings that are used in the automobile muffler, this type the product is not limited to being this, it is also possible in a variety of materials.
植物繊維に、珪酸ナトリュウム溶液を含浸塗布する場合、もともとの素材が可燃物であってもその不燃化、又は難燃化は、全ての素材において適用される用途目的毎の珪酸ナトリュウム溶液の希釈で対応が可能であり、自動車関連では多くの不燃化さえ可能である。 The plant fibers, when impregnated coated silicate Natoryuumu solution, even original material combustibles its fireproofing or fire retardant is diluted silicate Natoryuumu solution for each application purpose to be applied in all materials in a possible correspondence, in the automotive may even many non-flammable.
植物繊維不織布に、珪酸ナトリュウム溶液を含浸塗布することによって、その用途は巾広く、内装用加圧ボード不燃建材から、列車、自動車、船舶にいたる迄、その用途は無限である。 The plant fiber nonwoven fabric, by impregnation coating a silicate Natoryuumu solution, the application width wide, from interior pressurized圧Bo over de noncombustible building materials, trains, automobiles, until reaching the ship, its use is infinite.
植物繊維織布に、珪酸ナトリュウム溶液を含浸塗布することによって、可燃物を不燃化、難燃化する事になり、用途の増大化も図った。 The plant fiber woven fabric, by impregnation coating a silicate Natoryuumu solution, fireproofing flammable materials, Ri Do to be flame retardant, it was also attempted increase in the application.
樹木の破砕粉(樹木破砕粉)に、珪酸ナトリュウム溶液を含浸塗布することによって、樹木破砕粉、例えば製材鋸屑、或は他の用途での破砕微粉屑等、又目的を持った樹木微細粉利用のパーチクルボード等は、完全な難燃ボード、或は不燃ボードに変化し、付加価値は勿論、粉塵飛散で健康障害をもたらしたフレキボードや石膏ボードの代替にも有効であった。 The crushed powder of the trees (wood crushed powder), by impregnating coating a silicate Natoryuumu solution, trees crushed powder, for example lumber sawdust or crushed fine dust, etc. In other applications, also trees fine powder having the desired Pa over Chikurubo over de etc. available, complete Nan燃Bo over de, or changes in the incombustible board, value added, of course, the Furekibo over de and gypsum board brought health problems in dusting also alternative was effective.
全ての物質で共通な事であるが、珪酸ナトリュウム溶液を吸液させる事は、その粒度の大きさによって、単なる浸潤から加圧浸潤迄さまざまな吸液方法があり、特に樹木破砕粉では2mm乃至3mm以上の粒度では浸潤時間を調整するか、或は加圧浸潤で深部迄吸液させる事が望ましいが、これは、目的物の難燃度合いによる。 Although common thing in all things quality, that is liquid-absorbing silicate Natoryuumu solution, depending on the size of the particle size, there is pressure leaching Junmade various liquid absorption method from a mere invasion, trees especially In the case of crushed powder, it is desirable to adjust the infiltration time when the particle size is 2 mm to 3 mm or more, or to absorb the liquid deeply by pressure infiltration, depending on the flame retardance of the target product.
化学繊維に、珪酸ナトリュウム溶液を含浸塗布する場合、化学繊維には吸水性を有するものがあり、この種の樹脂繊維が望ましく、繊維自体のデニール細さが細ければ細い程、珪酸ナトリュウム溶液の付着どあいが多くなり、完全不燃に近い効果が有った。 The chemical fibers, when impregnated coated silicate Natoryuumu solution, the chemical fiber has shall be possessed water-absorbing, rather then desirable this kind of resin fibers, if Hosokere the denier Lumpur fineness of the fiber itself The thinner, the more adherent sodium silicate solution was, and the effect was almost incombustible.
化学繊維不織布に、珪酸ナトリュウム溶液を含浸塗布させれば、繊維間隙に浸潤した珪酸ナトリュウム溶液により、樹脂繊維の種類を問わず、不燃断熱効果は絶大であった。 The chemical fiber non-woven fabric, if impregnated coated silicate Natoryuumu solution, by infiltrating silicate Natoryuumu solution fiber interstices, regardless of the type of resin fibers, noncombustible insulation effect was enormous.
可燃性物質移送管継手フランジのパッキン保護目的の実施例である、25mm厚みの二つ割り嵌合成型品では、900℃局部火炎放射で内部管継手の温度上昇はアスベスト座布団巻きよりも効果が有り、珪酸ナトリュウム溶液を含浸塗布した化学繊維不織布自体の焼損は全く無かった。 In the case of a 25 mm thick split fitting molded product, which is an example for the purpose of protecting the flammable substance transfer pipe joint flange, the temperature rise of the internal pipe joint is more effective than the asbestos cushion winding by 900 ° C local flame radiation. The chemical fiber nonwoven fabric impregnated with the sodium solution was not burned at all.
ちなみに、本実施例に使用した化学繊維不織布は、ポリエステル100%のニードルパンチ不織布で、繊維は150デニール、不織布厚みは10mm,25mm,50mmで実施した。 Incidentally, chemical fiber non-woven fabric used in this example is a 100% polyester double over Dorupanchi nonwoven fibers 150 deniers Lumpur, the nonwoven thickness was performed 10 mm, 25 mm, with 50 mm.
化学繊維織布に、珪酸ナトリュウム溶液を含浸塗布する場合、不織布の様な厚みを必要とせず、断熱効果よりも化学繊維織布自体の不燃化或は難燃化を目的としたことにより効果が有る事は言うまでも無い。 The chemical fiber woven fabric, to impregnate coated silicate Natoryuumu solution, without requiring a thickness such as nonwoven fabric, more it has the purpose of fireproofing or fire retarding chemical fiber fabric itself than insulating effect Needless to say, there is an effect.
種々ある炭素に、珪酸ナトリュウム溶液を含浸塗布することで、炭素がもつ着火性を防止し、同時に炭素特有の不燃性を維持して断熱効果を表すものであり、例えば一般的木炭そのままでの800℃火炎放射では無焔燃焼して暖炉、火鉢の着火炭同様となるが、珪酸ナトリュウム溶液を含浸塗布した物は、全く着火せずに800℃火炎放射に耐え得た。 Seed s to a carbon, by impregnation coating a silicate Natoryuumu solution to prevent the ignitability with carbon, which represent the heat insulating effect to maintain the carbon inherent incombustible simultaneously, for example as in a general charcoal The 800.degree. C. flame radiation burns without burning and is similar to the ignition charcoal in the fireplace and brazier, but the product impregnated with the sodium silicate solution can withstand 800.degree. C. flame radiation without ignition.
塊状炭素に、珪酸ナトリュウム溶液を含浸塗布する場合、椰子殻活性炭を使用したが、全く木炭の場合と同様の着火不能の機能を果たし、目的によっては有効である事は間違いない。 Lump-like carbon, to impregnate coated silicate Natoryuumu solution, was used a coconut shell activated carbon, exactly fulfilling the same ignition disabling function in the case of charcoal, it is no doubt is effective depending on the purpose.
粒状炭素に、珪酸ナトリュウム溶液を含浸塗布することによって、この用途は無限であろうと思われる。 The grain carbon, by impregnation coating a silicate Natoryuumu solution, this application is believed that it would be infinite.
粒状炭素に、珪酸ナトリュウム溶液を含浸塗布した物に僅かなバインダを混合して成型すれば軽量の不燃成型品が出来、不燃の織布又は不織布で座布団の様に包み込めばこれまた有効な断熱構造ともなり、鋼製防火扉や金庫等の充填材にも使用出来、その用途は無限である。 The grain-like carbon, silicate Natoryuumu solution can impregnated coated lightweight nonflammable molded product when molding by mixing a slight Vine Da to those, which also effectively if Tsutsumikome like a cushion non-combustible woven or nonwoven It can be used for fillers such as steel fire doors and safes, and its uses are endless.
上述の各種素材の混合又は組み合わせによって高度な断熱構成も可能であり、本願発明の一例として斜視図を示すが、これ以外にも多くの実施例が有り、全産業分野での用途におけるより良い構成での断熱構造商品の開発が可能である。 Advanced thermal insulation structure by mixing or combination of the above various materials are possible, shows a perspective view as an example of the present invention, which many embodiments other than that there may configure than in applications in all industries It is possible to develop heat insulation structure products in Japan.
1 ガラス繊維マット
2 珪酸ナトリュウム含浸
3 ガラス繊維不織布
4 ガラス繊維織布
5 ガラス繊維綿
6 パルプ紙
7 綿状パルプ
8 樹木柱
9 植物繊維不織布
10 植物繊維織布
11 樹木破砕粉
12 化学繊維
13 化学繊維不織布
14 化学繊維織布
15 木炭
16 塊状炭素
17 粒状活性炭
1 glass fiber mat 2 silicate Natoryuumu impregnated 3 Glass fiber nonwoven fabric 4 woven fiber glass 5 glass fiber 維綿 6 pulp 7 flocculent pulp 8 trees pillars 9 vegetable fiber nonwoven 10 plant fiber woven fabric 11 trees crushed powder 12 chemical fiber 13 Chemical fiber nonwoven fabric 14 Chemical fiber woven fabric 15 Charcoal 16 Bulk carbon 17 Granular activated carbon
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