JP2007039392A - Contact-controlling screen having antibacterial layer, and method for producing the same - Google Patents

Contact-controlling screen having antibacterial layer, and method for producing the same Download PDF

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JP2007039392A
JP2007039392A JP2005226653A JP2005226653A JP2007039392A JP 2007039392 A JP2007039392 A JP 2007039392A JP 2005226653 A JP2005226653 A JP 2005226653A JP 2005226653 A JP2005226653 A JP 2005226653A JP 2007039392 A JP2007039392 A JP 2007039392A
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control screen
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JP4766945B2 (en
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Shunmin Ko
俊民 胡
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TrendON Touch Tech Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To produce a contact-controlling screen also having an antibacterial function to improve the antibacterial characteristics and application region of the contact-controlling screen. <P>SOLUTION: The contact-controlling screen having the antibacterial function is produced by homogeneously dispersing particles of a metallic material with nano meter sizes in a chemical for surface treatment, keeping the concentration within 20-500 ppm, coating the resultant dispersion on the surface of the contact-controlling screen, subjecting the chemical uniformly applied on the surface of the contact-controlling screen to heat treatment to form the antibacterial layer on the surface of the contact-controlling screen when the solvent in the chemicals is completely evaporated, and the particles of the metallic material with the nanometer sizes are intimately attached to the surface of the contact-controlling screen. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は抗菌層のある接触制御スクリーン及びその製造法に関するもので、特にナノメータ級金属材料を接触制御スクリーンの表面に均一かつ緊密に付着させ、抗菌機能のある接触制御スクリーンの製作及びその方法を指したものである。   The present invention relates to a contact control screen having an antibacterial layer and a method for manufacturing the same, and in particular, a nanometer-class metallic material is uniformly and tightly attached to the surface of the contact control screen, and a method and a method for manufacturing a contact control screen having an antibacterial function are provided. It is what I pointed to.

ここ数年来、ネットワークの勢い盛んな発展によって電子情報産業の革命をもたらし、電子情報製品の設計及び製造業者は消費者の差し迫ったニーズを満足するため、すでに多くの軽薄短小かつ携帯しやすい製品を開発しており、他に使用者の親和性のニーズに符合するため、更にその各種電子情報製品の入出力介面、または装置に消費者の使用慣習を徹底的に変える設計が行われ、その中の一つの重要な設計がすなわち「接触制御スクリーン」である。電子情報製品の接触制御スクリーンはその電子情報製品から出力された文字または図形の画面を表すことに用いられるほか、使用者が入力した文字または指令をその電子情報製品に伝送することにも使われ、それと同時にその電子情報製品の出力及び入力装置でもあるので、使用者はその各電子情報製品上でその接触制御スクリーンに現れる文字または図形を見て更に画面の指示によって直接その接触制御スクリーンに現れる仮想のボタンまたは図標(アイコン)を押せば、順調にその電子情報製品を操作制御することができる。使用者に対して言えば、その電子情報製品は使用上極めて便利であり、かつ操作上極めて親和力がある。ソフトウェア設計者に対して言えば、その電子情報製品は極めてフレキシブルに設計された互動式作業プラットフォームを提供し、それによって更に親和力のある互動プログラムを設計することができる。また購買者に対して言えば、その電子情報製品は定額外の入力装置を必要としないので、ほかに入力装置の購入に必要な費用及び予め残す設置空間を節約することができる。   Over the past few years, the vigorous development of the network has revolutionized the electronic information industry, and the design and manufacturers of electronic information products have already created many small, light, small, and portable products to satisfy the immediate needs of consumers. In order to meet the needs of other users' compatibility, the design for changing the usage customs of consumers to the input / output interface of various electronic information products or devices has been made. One important design is the “touch control screen”. The contact control screen of an electronic information product is used to display a screen of characters or figures output from the electronic information product, and is also used to transmit characters or commands input by the user to the electronic information product. At the same time, since it is also an output and input device for the electronic information product, the user sees the characters or figures appearing on the touch control screen on each electronic information product and appears directly on the touch control screen according to the instructions on the screen If a virtual button or icon (icon) is pressed, the electronic information product can be smoothly controlled. For the user, the electronic information product is very convenient in use and very compatible in operation. For software designers, the electronic information product provides an interactive work platform that is designed to be very flexible, thereby allowing more interactive programs to be designed. In addition, to the purchaser, the electronic information product does not require an input device that is not a fixed amount, so that it is possible to save the cost necessary for purchasing the input device and the installation space left in advance.

そのために、ここ数年来、接触制御スクリーンが設けられる各種電子情報製品はすでに多くの公共場所に幅広く使用され、例えば学校、デパート、病院、空港、汽車駅等で多くの不特定使用者に情報の問い合わせ及びガイダンスを行うことに供され、使用者のために操作が簡単便利でかつ親和力のある入出力装置を提供し、このほか、それに取り付けられるソフトウェアの設計が適切である場合、それにより更に効果的に多くの使用者が公共場所で遭遇する多くの問題及び困りごとを迅速に解決することができる。ところが、玉に瑕というか、この種の接触制御スクリーンが設けられる電子情報製品は公共場所に設置され、多くの使用者の操作に供されるので、発生可能な唯一の欠点は細菌が伝播する媒介物に極めてなりやすく、公共衛生及び人々の健康の大きな脅威になる。そのために、如何にして公共場所中の各種電子情報製品の接触制御スクリーンの清潔衛生を確保するかが、各公共場所の主管機関の特に注意するべき、かつ軽易に見落とせない重要な課題になっている。   For this reason, various electronic information products equipped with contact control screens have been widely used in many public places for the past several years. For example, information is provided to many unspecified users in schools, department stores, hospitals, airports, train stations, etc. Provide an input / output device that is easy to use, convenient and compatible for the user, and is more effective if the design of the software attached to it is appropriate. Therefore, many problems and troubles that many users encounter in public places can be solved quickly. However, because the electronic information product, which is called a ball or a contact control screen of this kind, is installed in public places and is used for many users' operation, the only possible defect is propagation of bacteria. It is extremely easy to become an intermediary and is a major threat to public health and people's health. Therefore, how to ensure the cleanliness and hygiene of the contact control screens of various electronic information products in public places is an important issue that should be paid special attention to the main authority in each public place and cannot be easily overlooked. ing.

接触制御スクリーンがすでに公共場所での細菌を伝播する媒介物になることに鑑み、多くの電子情報製品の設計及び製造業者はこの潜在的危機を解決するため、尽力して細菌抑制能力のある接触制御スクリーンを研究開発し、その方法は接触制御スクリーンの上に細菌抑制能力のある組成物を塗布するが、一般に、現在の各電子情報製品の業者が使用する細菌抑制組成物の多くは有機物から構成され、それら有機物が接触制御スクリーンの表面に塗布されると細菌の生長を抑制することができるが、それらの融点または沸点が低いので極めて容易に蒸発または分解してしまい、そのために長期間の細菌抑制効果がなく、更にその材料には一般に毒性があるので、人間が直接接触する製品に応用または塗布することに適しない。他の業者は近年来かなり流行っている酸化チタン触媒を利用して抑菌または抗菌処理を行っているが、それはUV光源の下で行わなければ光催化及び殺菌作用がなく、一般の室内の光源でのUV光線はかなり微弱であるので、それに発生する抗菌効果はあまり理想でない。   In view of the fact that contact control screens are already an intermediary for the transmission of bacteria in public places, many electronic information product designs and manufacturers are working hard to resolve this potential crisis and make contact with bacteria-controlling capabilities. Research and development of control screens, the method of applying a bacterial control ability composition on the touch control screen, in general, many of the current bacterial information product manufacturers use organic control products from organic matter When the organic substances are applied to the surface of the contact control screen, the growth of bacteria can be suppressed. However, since their melting point or boiling point is low, they evaporate or decompose very easily, and for this reason, It is not suitable for application or application to products that are in direct contact with humans because it has no bacteria-inhibiting effect and the material is generally toxic. Other vendors have been using antibacterial or antibacterial treatments using titanium oxide catalysts that have been quite popular in recent years, but they have no photo-acceleration and bactericidal action unless performed under a UV light source. Since the UV light at is very weak, the antibacterial effect that occurs in it is not very ideal.

そのために、いかにして適切な抑菌材料を選択し、並びに新しい製造過程を設計して抗菌機能を兼ねた接触制御スクリーンを製造し、その接触制御スクリーンの抗菌特性及び応用領域を向上するのが本発明のここで検討する重要な課題である。
前述周知の接触制御スクリーンがそれぞれ長くから存在する問題に鑑み、発明人は長年の実務経験及び研究心得によって、本発明の抗菌層のある接触制御スクリーン及びその製造法を開発した。
Therefore, how to select an appropriate antibacterial material and design a new manufacturing process to produce a contact control screen that also has antibacterial functions, and improve the antibacterial properties and application area of the contact control screen. This is an important issue to be examined here.
In view of the problems that the above-mentioned known touch control screens have existed for a long time, the inventor has developed a touch control screen having an antibacterial layer of the present invention and a manufacturing method thereof based on many years of practical experience and research knowledge.

上記目的を達成するため、本発明による抗菌層のある接触制御スクリーン及びその製造法は、ナノメータ級金属材料の粒子を均一に表面処理の薬液中に分散させ、その濃度を20〜500ppmの間に保持し、その後更にそれを接触制御スクリーンの表面に塗布し、並びにその接触制御スクリーンの表面に均一に塗布した薬液に対して熱処理を行い、その薬液中の溶剤が完全に蒸発し、かつそのナノメータ級金属材料の粒子が緊密に接触制御スクリーンの表面に付着すれば、その接触制御スクリーンの表面に抗菌層が形成され、抗菌機能のある接触制御スクリーンが製作される。   In order to achieve the above object, a contact control screen having an antibacterial layer according to the present invention and a method for manufacturing the same, uniformly disperse particles of a nanometer-grade metal material in a chemical solution for surface treatment, and a concentration of 20 to 500 ppm. Hold, and then apply it further to the surface of the contact control screen, and heat-treat the chemical uniformly applied to the surface of the contact control screen, the solvent in the chemical is completely evaporated, and the nanometer If the particles of the class metal material adhere closely to the surface of the contact control screen, an antibacterial layer is formed on the surface of the contact control screen, and a contact control screen having an antibacterial function is manufactured.

また、本発明による抗菌層のある接触制御スクリーン及びその製造法は、伝統的赤外線式、抵抗式、キャパシタンス式、音波式等の各種接触制御スクリーンの使用者と接触する表面に対して伝統的硬化、耐磨耗、抗目くらみ、抗反射等の適切な表面処理を行うときに、ナノメータ級金属の粒子を均一に表面処理の薬液中に分散させ、その濃度を20〜500ppmの間に保持し、更にそれを接触制御スクリーンの表面に塗布し、並びに熱処理を行えば、そのナノメータ級金属の粒子は緊密に接触制御スクリーンの表面に付着して抗菌層が形成される。   In addition, the contact control screen having an antibacterial layer according to the present invention and a method of manufacturing the same may be applied to a surface that comes into contact with a user of various contact control screens such as a traditional infrared type, a resistance type, a capacitance type, and a sonic type. When performing appropriate surface treatments such as wear resistance, anti-glare, anti-reflection, etc., nanometer-class metal particles are uniformly dispersed in the surface treatment chemical solution, and the concentration is kept between 20 and 500 ppm. Further, when it is applied to the surface of the contact control screen and subjected to a heat treatment, the nanometer-grade metal particles closely adhere to the surface of the contact control screen to form an antibacterial layer.

さらに、本発明による抗菌層のある接触制御スクリーン及びその製造法は、研磨または超音波振動法を利用し、ナノメータ級金属を均一に表面処理の薬液中に分散する。
さらに、本発明による抗菌層のある接触制御スクリーン及びその製造法は、回転塗布、浸漬塗布、スプレー塗布、ローラ塗布等の塗布法を利用し、その薬液を接触制御スクリーンの表面に塗布することである。
Furthermore, the contact control screen having an antibacterial layer according to the present invention and the method for manufacturing the same use a polishing or ultrasonic vibration method to uniformly disperse a nanometer class metal in a chemical solution for surface treatment.
Furthermore, the contact control screen with an antibacterial layer according to the present invention and the method for manufacturing the contact control screen use a coating method such as spin coating, dip coating, spray coating, roller coating, etc. is there.

さらに、本発明による抗菌層のある接触制御スクリーン及びその製造法は、その接触制御スクリーンの表面基材がPET膜のような有機化合物である場合、その表面処理液の組成を紫外線型または熱固化型の樹脂及び適宜な溶剤にし、その処理液が均一にPET膜の表面に塗布された後、使用された樹脂の種類によってUVランプで照射または熱処理し、その熱処理の温度はやや低く、約50〜100℃の間である。   Furthermore, the contact control screen having an antibacterial layer according to the present invention and the method for manufacturing the contact control screen, when the surface base material of the contact control screen is an organic compound such as a PET film, the composition of the surface treatment liquid is ultraviolet type or heat solidified. After making the resin of the mold and an appropriate solvent and applying the treatment liquid uniformly on the surface of the PET film, it is irradiated or heat-treated with a UV lamp depending on the type of the resin used, and the temperature of the heat treatment is somewhat low, about 50 Between -100 ° C.

さらに、本発明による抗菌層のある接触制御スクリーン及びその製造法は、その接触制御スクリーンの表面基材がガラスの構造のような無機化合物である場合、その表面処理液の組成をケイ酸塩(エステル)、水、酸及び適宜な溶剤にし、その処理液が均一にガラスの表面に塗布された後は熱処理する必要があり、その熱処理の温度はやや高く、約160〜200℃の間である。   Furthermore, in the contact control screen having an antibacterial layer according to the present invention and the manufacturing method thereof, when the surface substrate of the contact control screen is an inorganic compound such as a glass structure, the composition of the surface treatment liquid is changed to silicate ( Ester), water, acid, and a suitable solvent, and after the treatment liquid is uniformly applied to the surface of the glass, it is necessary to perform heat treatment, and the temperature of the heat treatment is slightly high, and is between about 160-200 ° C. .

本発明の目的、発明理念及び技術原理がより詳しく認識されるよう、ここに実施形態を採り上げ、図面と合わせて以下に詳細説明する。
本発明による抗菌層のある接触制御スクリーン及びその製造法は、図1に示す如く、粒子径が約1nm〜100nmであるナノメータ級金属材料を均一に表面処理の薬液中に分散させ、それの濃度を20〜500ppmの間に保持し、その後は更にそれを接触制御スクリーンの表面に塗布し、並びにその接触制御スクリーンの表面に均一に塗布した薬液に対して熱処理を行い、その薬液中の溶剤が完全に蒸発し、かつそのナノメータ級金属材料の粒子が緊密に接触制御スクリーンの表面に付着すれば、その接触制御スクリーンの表面に抗菌層が形成され、抗菌効果のある接触制御スクリーンを作ることができる。本発明で言う「ナノメータ級金属材料」は特に長らく生物化学活性のあることが証明され、細菌の細胞壁を貫き通り、細胞内の酵素蛋白を変質させて自然死亡させる効果があり、かつ粒子径が1nm〜100nmであるナノメータ級金属材料を指したもので、例えば、ナノメータ金(Au)、ナノメータ銀(Ag)、ナノメータ銅(Cu)、ナノメータ亜鉛(Zn)、ナノメータ白金(Pt)等のナノメータ級金属材料またはその組成物、またはその化合物、例えばナノメータ酸化銀、ナノメータ酸化銅、ナノメータ酸化亜鉛、ナノメータ硝酸銀、ナノメータ硝酸銅、ナノメータ硝酸亜鉛等である。
In order that the purpose, inventive concept, and technical principle of the present invention will be recognized in more detail, embodiments will be taken here and described in detail below in conjunction with the drawings.
As shown in FIG. 1, the contact control screen having an antibacterial layer according to the present invention and the manufacturing method thereof uniformly disperse a nanometer-class metal material having a particle size of about 1 nm to 100 nm in a surface treatment chemical solution, and the concentration thereof. Is then applied to the surface of the contact control screen, and the chemical solution uniformly applied to the surface of the contact control screen is subjected to a heat treatment, and the solvent in the chemical solution is removed. If it completely evaporates and the nanometer-grade metallic material particles adhere tightly to the surface of the contact control screen, an antibacterial layer is formed on the surface of the contact control screen, making an antibacterial contact control screen. it can. The “nanometer-class metallic material” referred to in the present invention has long been proved to have biochemical activity, has an effect of passing through the bacterial cell wall, altering the enzyme protein in the cell and causing natural death, and has a particle size of This refers to nanometer-class metallic materials having a thickness of 1 to 100 nm, such as nanometer gold (Au), nanometer silver (Ag), nanometer copper (Cu), nanometer zinc (Zn), nanometer platinum (Pt), etc. Metallic materials or compositions thereof, or compounds thereof, such as nanometer silver oxide, nanometer copper oxide, nanometer zinc oxide, nanometer silver nitrate, nanometer copper nitrate, nanometer zinc nitrate and the like.

本発明に於いて、その接触制御スクリーンはそれの製造方法及び構造の違いによって赤外線式、抵抗式、キャパシタンス式、音波式等の各種接触制御スクリーン中のいかなる一種でもよく、その各接触制御スクリーンの使用者の接触に供される表面は、一般に実際のニーズによって適切な表面処理が行われ、例えば硬化処理、耐磨耗処理、抗目くらみ処理、抗反射処理等の表面処理で、本発明に於いてその各表面処理に必要な薬液を製造する場合、そのナノメータ級金属の粒子を均一に表面処理の薬液中に分散させ、並びにその濃度を20〜500ppmの間に保持し、更に伝統的塗布方法、例えば回転塗布、浸漬塗布、スプレー塗布、ローラ塗布等の塗布法を利用してそれを接触制御スクリーンの表面に塗布し、並びにその接触制御スクリーンの表面に塗布された薬液に対して熱処理を行い、その薬液中の溶剤が完全に蒸発すると、その中に含まれるナノメータ級金属の粒子は緊密に接触制御スクリーンの表面に付着し、抗菌機能のある接触制御スクリーンを作り出すことができる。本発明に於いて、それら薬液を作成する場合、それは研磨または超音波振動法等分散法を利用し、そのナノメータ級金属の粒子を均一に表面処理の薬液中に分散することができる。   In the present invention, the touch control screen may be any one of various touch control screens such as an infrared type, a resistance type, a capacitance type, and a sonic type depending on the manufacturing method and structure thereof. The surface to be contacted by the user is generally subjected to an appropriate surface treatment according to actual needs. For example, the surface treatment such as curing treatment, anti-wear treatment, anti-glare treatment, anti-reflection treatment, etc. In manufacturing the chemicals required for each surface treatment, the nanometer-grade metal particles are uniformly dispersed in the surface treatment chemicals, and the concentration is kept between 20 and 500 ppm. Apply it to the surface of the contact control screen using methods such as spin coating, dip coating, spray coating, roller coating, etc. When the chemical solution applied to the surface of the liquid is heat-treated and the solvent in the chemical solution is completely evaporated, the nanometer-class metal particles contained in the chemical solution adhere closely to the surface of the contact control screen and have an antibacterial function. Can produce some touch control screens. In the present invention, when preparing these chemical solutions, it is possible to uniformly disperse the nanometer class metal particles in the surface treatment chemical solution using a dispersion method such as polishing or ultrasonic vibration method.

伝統的に、その接触制御スクリーンの製作に用いられる基材はそれの材料特性の違いによって有機化合物と無機化合物の両種に分けられ、そのうち前者は常にPET膜であり、後者はガラスの構造である。したがって、本発明に於いて、前述の両種違う基材に対し、その必要とする表面処理液及び後続の製造過程も完全に違い、その接触制御スクリーンの基材がPET膜である場合、表面処理に必要とする薬液の組成は一般に紫外線型または熱固化型の樹脂及び適宜な溶剤であり、その表面処理薬液が均一にPET膜の表面に塗布された後、使用された樹脂の種類によってUVランプで照射または熱処理し、その熱処理の温度はやや低く、約50〜100℃の間である。その接触制御スクリーンの表面基材がガラスである場合、その表面処理液の組成はケイ酸塩(エステル)、水、酸及び適宜な溶剤であり、薬液が均一にガラスの表面に塗布された後は熱処理を行うだけで、その熱処理の温度はやや高く、約160〜200℃の間である。
発明人は本発明の設計理念及び工作原理を充分に表すため、特に若干の実施例を取り上げて次の如く詳細説明し、並びに製作した接触制御スクリーンに対して実測を行い、具体的に本発明が実現しようとする抗菌または抑菌効果を表すことにした。
Traditionally, the substrates used to make the contact control screens are divided into organic and inorganic compounds depending on their material properties, of which the former is always a PET film and the latter is a glass structure. is there. Therefore, in the present invention, for the above-mentioned different types of substrates, the necessary surface treatment liquid and the subsequent manufacturing process are completely different, and when the substrate of the contact control screen is a PET film, The composition of the chemical solution required for the treatment is generally an ultraviolet-type or heat-solidified resin and an appropriate solvent. After the surface treatment chemical solution is uniformly applied to the surface of the PET film, the UV is changed depending on the type of resin used. Irradiated or heat-treated with a lamp, the temperature of the heat treatment is somewhat low, between about 50-100 ° C. When the surface base material of the contact control screen is glass, the composition of the surface treatment liquid is silicate (ester), water, acid and an appropriate solvent, and after the chemical liquid is uniformly applied to the glass surface Only performs a heat treatment, and the temperature of the heat treatment is slightly high, and is between about 160-200 ° C.
In order to fully express the design philosophy and working principle of the present invention, the inventor takes a few examples and explains in detail as follows, and performs actual measurements on the manufactured contact control screen to specifically describe the present invention. Decided to represent the antibacterial or antibacterial effect to be realized

本発明の最適実施例に於いて、それはガラス材料をスクリーン基材とした接触制御スクリーンに対して抗目くらみ処理を行った場合、先ず粒子径が約1nm〜100nmのナノメータ銀の粒子を10〜50KHzの超音波振動方式をもって次粒子の状態で均一にアルコール類溶剤の中に分散させて必要とする分散液を形成し、その後更にケイ酸塩(エステル)化合物とアルコールまたはその他溶剤から構成された抗目くらみ表面処理液をその分散液の中に加入し、攪拌法によってそれに約10分間またはより長い時間の攪拌を行って二者を均一に混合させ、並びにその混合液のpHを酸性に調整し、かつそのナノメータ銀の粒子の濃度を約20〜500ppmに維持する。そしてその混合液をスプレー方式をもってその接触制御スクリーンの表面に均一に塗布し、その後は更にその接触制御スクリーンの表面に対して熱処理を行い、その熱処理の温度は約160〜200℃で、熱処理時間は約30〜60分であり、その接触制御スクリーンに塗布された組成物中の溶剤が完全に蒸発し、並びにゲル化反応が完成したらその接触制御スクリーン上に抗菌効果のある抗目くらみ層が形成され、その抗目くらみ層の主要組成は二酸化シリコン及びナノメータ銀であり、それの理想な厚さは約50〜5000オングストロームである。   In an optimum embodiment of the present invention, when anti-glare treatment is performed on a contact control screen using a glass material as a screen base, first, nanometer silver particles having a particle size of about 1 nm to 100 nm are 10 to 10 nm. The required dispersion was formed by uniformly dispersing in the alcohol solvent in the form of the next particles with an ultrasonic vibration method of 50 KHz, and then further comprising a silicate (ester) compound and alcohol or other solvent. Add anti-glare surface treatment liquid into the dispersion, stir it for about 10 minutes or longer by stirring method to mix the two uniformly, and adjust the pH of the liquid mixture to acidic And maintaining the nanometer silver particle concentration at about 20-500 ppm. Then, the mixed solution is uniformly applied to the surface of the contact control screen by a spray method, and thereafter, the surface of the contact control screen is further subjected to heat treatment, and the heat treatment temperature is about 160 to 200 ° C. Is about 30-60 minutes, the solvent in the composition applied to the contact control screen is completely evaporated, and when the gelation reaction is completed, an anti-glare layer having an antibacterial effect is formed on the contact control screen. The major composition of the anti-blaze layer that is formed is silicon dioxide and nanometer silver, and its ideal thickness is about 50-5000 Angstroms.

前述の実施例に於いて、もしその接触制御スクリーンが赤外線接触制御スクリーンであれば、0.1グラムの粒子径が約10nmであるナノメータ銀の粒子を選択し、均一に100グラムのアルコール中に分散させて必要な分散液が得られ、その後は更にその分散液中に900グラムのケイ酸エステル抗目くらみ表面処理液を加入し、並びにその二者を均一に混合させ、かつその混合液のpH値を4に調整する。そしてその混合液をその赤外線接触制御スクリーンの表面ガラスに均一にスプレーし、並びに熱処理を行い、その熱処理の温度は約180℃、熱処理時間は約1時間で、厚さ約1000オングストロームの抗菌効果のある抗目くらみ層が形成される。発明人は製作されたその赤外線接触制御スクリーンと一般伝統的抗菌処理を行っていない赤外線接触制御スクリーンに対して実験比較を行い、大腸菌をそれぞれ各スクリーンの表面に(百万/平方センチメートル)接種し、並びに24時間後、その上に生き残った大腸菌数を計数したところ、結果は本実施例によって製作したその赤外線接触制御スクリーン上の大腸菌数はもともと接種した数より大幅に90%減少し、抗菌処理を行っていない伝統的赤外線接触制御スクリーン上の大腸菌の数は減少しておらず、これからわかるように、本実施例は確かに接触制御スクリーンの表面の菌類の成長を抑制する効果を持たせることができる。   In the embodiment described above, if the contact control screen is an infrared contact control screen, nanometer silver particles of 0.1 gram particle size of about 10 nm are selected and uniformly in 100 grams of alcohol. Dispersion gives the required dispersion, after which 900 grams of silicate ester anti-stigma surface treatment liquid is added to the dispersion, and the two are uniformly mixed, and the mixture Adjust the pH value to 4. The mixed solution is uniformly sprayed on the surface glass of the infrared contact control screen, and heat treatment is performed. The heat treatment temperature is about 180 ° C., the heat treatment time is about 1 hour, and the antibacterial effect is about 1000 angstroms thick. An anti-glare layer is formed. The inventor made an experimental comparison between the manufactured infrared contact control screen and a non-traditional infrared contact control screen, and inoculated E. coli on the surface of each screen (million per square centimeter), 24 hours later, the number of Escherichia coli surviving was counted. As a result, the number of Escherichia coli on the infrared contact control screen produced according to the present example was greatly reduced by 90% from the number originally inoculated. The number of E. coli on traditional infrared contact control screens that have not been performed has not decreased, and as can be seen, this example certainly has the effect of inhibiting the growth of fungi on the surface of the contact control screen. it can.

本発明のもう一つの最適実施例に於いて、それはPET膜をスクリーンの基材とした抵抗式接触制御スクリーンの表面に硬化処理を行う場合、先ず0.1グラムの粒子径が約10nmであるナノメータ銀の粒子を均一に100グラムのメチルエチルケトン中に分散させて必要とする分散液を形成し、その後は更にその分散液中に900グラムのポリウレタンアクリレートモノマーを主とするUV硬化剤を加入し、並びにその二者を均一に混合させる。更にその混合液を均一に抵抗式接触制御スクリーンの表面にスプレーした後、その表面に遠赤外線(IR)で約5分間加熱し、混合液中の溶剤が完全に蒸発した後、更にUVランプ(40〜60W)で照射して硬化処理を完成すれば、厚さ約数ミクロンの抗菌硬化膜が形成される。発明人は製作されたその抵抗式接触制御スクリーンと一般伝統的抗菌処理を行っていない抵抗式接触制御スクリーンに対して実験比較を行い、大腸菌をそれぞれ各スクリーンの表面に(百万/平方センチメートル)接種し、並びに24時間後、その上に生き残った大腸菌数を計数し、結果は本実施例により製作したその抵抗式接触制御スクリーン上の大腸菌数はもともと接種した数より大幅に90%減少し、抗菌処理を行っていない伝統的抵抗式接触制御スクリーン上の大腸菌の数は減少しておらず、これによって、本実施例は確かに接触制御スクリーンの表面に菌類の成長を抑制する効果があることが実験証明された。
以上に述べたのは本発明の最適実施例だけであり、本発明が主張する権利範囲はこれに局限しなく、およそこの技術を熟知するものが本発明が開示した技術内容によって軽易に考え付ける効果の変化等は、すべて本発明の保護範囲を離脱しないものとするべきである。
In another optimal embodiment of the present invention, when a curing process is performed on the surface of a resistive contact control screen using a PET film as the base material of the screen, the particle size of 0.1 gram is first about 10 nm. Nanometer silver particles are uniformly dispersed in 100 grams of methyl ethyl ketone to form the required dispersion, and then 900 grams of polyurethane acrylate monomer-based UV curing agent is added to the dispersion, And the two are mixed uniformly. Furthermore, after spraying the mixed solution uniformly on the surface of the resistance contact control screen, the surface is heated with far infrared rays (IR) for about 5 minutes, and after the solvent in the mixed solution is completely evaporated, a UV lamp ( When the curing process is completed by irradiation at 40 to 60 W), an antibacterial cured film having a thickness of about several microns is formed. The inventor made an experimental comparison between the manufactured resistive contact control screen and a general non-traditional resistance contact control screen, and inoculated E. coli on the surface of each screen (million / square centimeter). And after 24 hours, the number of E. coli surviving was counted, and the result was that the number of E. coli on the resistive contact control screen produced according to this example was significantly reduced by 90% from the number originally inoculated. The number of E. coli on the traditional resistance-type contact control screen that has not been treated has not been reduced, so that this example certainly has the effect of suppressing fungal growth on the surface of the touch-control screen. Proven experiment.
What has been described above is only the optimal embodiment of the present invention, and the scope of rights claimed by the present invention is not limited to this, and those who are familiar with this technology can easily conceive according to the technical contents disclosed by the present invention. All changes in effect should not depart from the protection scope of the present invention.

本発明に係る製造過程の模式図である。It is a schematic diagram of the manufacturing process which concerns on this invention.

Claims (12)

ナノメータ級金属材料の粒子を均一に表面処理の薬液中に分散させた薬液を生成し、前記薬液の濃度を20〜500ppmの間に保持し、
前記薬液を均一に接触制御スクリーンの表面に塗布し、
均一に接触制御スクリーンの表面に塗布された前記薬液に対して熱処理を行い、前記薬液中の溶剤が完全に蒸発し、かつ前記ナノメータ級金属材料の粒子が緊密に接触制御スクリーンの表面に付着して、前記接触制御スクリーンの表面に抗菌層が形成される抗菌層のある接触制御スクリーンの製造法。
Producing a chemical solution in which particles of a nanometer-class metal material are uniformly dispersed in a chemical solution for surface treatment, and maintaining the concentration of the chemical solution between 20 and 500 ppm;
Apply the chemical solution uniformly to the surface of the contact control screen,
The chemical solution uniformly applied to the surface of the contact control screen is subjected to a heat treatment, the solvent in the chemical solution is completely evaporated, and the particles of the nanometer-class metal material are closely adhered to the surface of the contact control screen. A method for manufacturing a contact control screen having an antibacterial layer on which an antibacterial layer is formed on the surface of the contact control screen.
前記ナノメータ級金属材料は、生物化学活性があって、細菌の細胞壁を貫通可能であり、細胞内の酵素蛋白を変質させて自然死亡させる効果があり、かつ粒子径が1nm〜100nmである請求項1に記載の抗菌層のある接触制御スクリーンの製造法。   The nanometer-class metallic material has biochemical activity, can penetrate bacterial cell walls, has an effect of causing spontaneous death by altering intracellular enzyme protein, and has a particle size of 1 nm to 100 nm. 2. A method for producing a contact control screen having an antibacterial layer according to 1. 前記ナノメータ級金属材料は、少なくともナノメータ金(Au)、ナノメータ銀(Ag)、ナノメータ銅(Cu)、ナノメータ亜鉛(Zn)、またはナノメータ白金(Pt)のいずれかである請求項2に記載の抗菌層のある接触制御スクリーンの製造法。   The antibacterial according to claim 2, wherein the nanometer-grade metal material is at least one of nanometer gold (Au), nanometer silver (Ag), nanometer copper (Cu), nanometer zinc (Zn), or nanometer platinum (Pt). A method of manufacturing a contact control screen with layers. 前記ナノメータ級金属材料は、少なくともナノメータ金(Au)、ナノメータ銀(Ag)、ナノメータ銅(Cu)、ナノメータ亜鉛(Zn)、またはナノメータ白金(Pt)のいずれかを含む組成物または化合物である請求項2に記載の抗菌層のある接触制御スクリーンの製造法。   The nanometer-grade metallic material is a composition or compound containing at least one of nanometer gold (Au), nanometer silver (Ag), nanometer copper (Cu), nanometer zinc (Zn), or nanometer platinum (Pt). Item 3. A method for producing a contact control screen having an antibacterial layer according to Item 2. 前記表面処理の薬液は硬化処理、耐磨耗処理、抗目くらみ処理、または抗反射処理の表面処理を行うことに必要な薬液である請求項2に記載の抗菌層のある接触制御スクリーンの製造法。   The touch-control screen having an antibacterial layer according to claim 2, wherein the chemical liquid for the surface treatment is a chemical liquid necessary for performing a surface treatment such as curing treatment, anti-wear treatment, anti-glare treatment, or anti-reflection treatment. Law. 前記接触制御スクリーンの基材がPET膜である場合、前記薬液の組成は紫外線型または熱固化型樹脂及び溶剤であり、前記薬液が均一にPET膜の表面に塗布された後、使用された樹脂の種類によってUVランプで照射または熱処理され、前記熱処理の温度が50〜100℃の間である請求項5に記載の抗菌層のある接触制御スクリーンの製造法。   When the base material of the contact control screen is a PET film, the composition of the chemical solution is an ultraviolet type or heat-setting resin and a solvent, and the resin used after the chemical solution is uniformly applied to the surface of the PET film 6. The method of manufacturing a contact control screen having an antibacterial layer according to claim 5, wherein irradiation with a UV lamp or heat treatment is performed depending on the kind of the heat treatment, and the temperature of the heat treatment is between 50 and 100C. 前記接触制御スクリーンの表面基材がガラスである場合、前記薬液の組成はケイ酸塩(エステル)、水、酸及び溶剤であり、前記薬液が均一にガラスの表面に塗布された後は熱処理する必要があり、前記熱処理の温度が160〜200℃の間である請求項5に記載の抗菌層のある接触制御スクリーンの製造法。   When the surface substrate of the contact control screen is glass, the chemical solution is composed of silicate (ester), water, acid and solvent, and heat treatment is performed after the chemical solution is uniformly applied to the glass surface. The method for producing a contact control screen having an antibacterial layer according to claim 5, wherein the temperature of the heat treatment is between 160 and 200 ° C. 接触制御スクリーンと、
接触制御スクリーンの常に使用者に接触される一側の表面に塗布され、ナノメータ級金属材料の粒子及び溶剤が完全に蒸発した表面処理の薬液材料を含み、前記ナノメータ級金属材料の粒子は、その薬液中の溶剤が蒸発する前は均一に表面処理の薬液中に分散され、濃度は20〜500ppmの間に保持される抗菌層と、
を備える抗菌層のある接触制御スクリーン。
With touch control screen,
The surface of the contact control screen is applied to the surface that is always in contact with the user, and includes a nanometer-grade metallic material particle and a surface-treated chemical liquid material in which the solvent is completely evaporated. Before the solvent in the chemical solution evaporates, it is uniformly dispersed in the chemical solution for surface treatment, and the antibacterial layer is maintained at a concentration of 20 to 500 ppm;
Touch control screen with antibacterial layer.
前記ナノメータ級金属材料は、生物化学活性があり、細菌の細胞壁を貫通可能であり、細胞内の酵素蛋白を変質させて自然死亡させる効果があり、かつ粒子径が1nm〜100nmであるナノメータ級金属材料である請求項8に記載の抗菌層のある接触制御スクリーン。   The nanometer-class metal material has biochemical activity, can penetrate bacterial cell walls, has the effect of spontaneously dying by altering intracellular enzyme protein, and has a particle diameter of 1 nm to 100 nm. The contact control screen having an antibacterial layer according to claim 8, which is a material. 前記ナノメータ級金属材料は、少なくともナノメータ金(Au)、ナノメータ銀(Ag)、ナノメータ銅(Cu)、ナノメータ亜鉛(Zn)またはナノメータ白金(Pt)のいずれかである請求項9に記載の接触制御スクリーン。   The contact control according to claim 9, wherein the nanometer-grade metal material is at least one of nanometer gold (Au), nanometer silver (Ag), nanometer copper (Cu), nanometer zinc (Zn), or nanometer platinum (Pt). screen. 前記ナノメータ級金属材料は、少なくともナノメータ金(Au)、ナノメータ銀(Ag)、ナノメータ銅(Cu)、ナノメータ亜鉛(Zn)またはナノメータ白金(Pt)のいずれかを含む組成物または化合物である請求項9に記載の接触制御スクリーン。   The nanometer-grade metal material is a composition or compound containing at least one of nanometer gold (Au), nanometer silver (Ag), nanometer copper (Cu), nanometer zinc (Zn), or nanometer platinum (Pt). 10. The touch control screen according to 9. 前記表面処理の薬液は硬化処理、耐磨耗処理、抗目くらみ処理または抗反射処理の表面処理を行うことに必要な薬液である請求項9に記載の接触制御スクリーン。   The contact control screen according to claim 9, wherein the chemical liquid for the surface treatment is a chemical liquid necessary for performing a surface treatment such as a curing treatment, an anti-abrasion treatment, an anti-glare treatment, or an anti-reflection treatment.
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WO2008150867A2 (en) 2007-05-29 2008-12-11 Innova Materials, Llc Surfaces having particles and related methods
US8748749B2 (en) 2011-08-24 2014-06-10 Innova Dynamics, Inc. Patterned transparent conductors and related manufacturing methods
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US10787386B2 (en) 2015-09-02 2020-09-29 Corning Incorporated Antimicrobial-antireflective articles and methods for making the same
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Publication number Priority date Publication date Assignee Title
WO2008150867A2 (en) 2007-05-29 2008-12-11 Innova Materials, Llc Surfaces having particles and related methods
WO2008150867A3 (en) * 2007-05-29 2009-02-05 Innova Materials Llc Surfaces having particles and related methods
JP2010529231A (en) * 2007-05-29 2010-08-26 イノーバ マテリアルズ、エルエルシー Particle-containing surfaces and related methods
US8852689B2 (en) 2007-05-29 2014-10-07 Innova Dynamics, Inc. Surfaces having particles and related methods
US10024840B2 (en) 2007-05-29 2018-07-17 Tpk Holding Co., Ltd. Surfaces having particles and related methods
US8749009B2 (en) 2010-08-07 2014-06-10 Innova Dynamics, Inc. Device components with surface-embedded additives and related manufacturing methods
US9185798B2 (en) 2010-08-07 2015-11-10 Innova Dynamics, Inc. Device components with surface-embedded additives and related manufacturing methods
US9713254B2 (en) 2010-08-07 2017-07-18 Tpk Holding Co., Ltd Device components with surface-embedded additives and related manufacturing methods
US8748749B2 (en) 2011-08-24 2014-06-10 Innova Dynamics, Inc. Patterned transparent conductors and related manufacturing methods
US8969731B2 (en) 2011-08-24 2015-03-03 Innova Dynamics, Inc. Patterned transparent conductors and related manufacturing methods
US10787386B2 (en) 2015-09-02 2020-09-29 Corning Incorporated Antimicrobial-antireflective articles and methods for making the same
CN113845877A (en) * 2021-09-23 2021-12-28 谢文富 Preparation method and use method of adhesive with far infrared, antibacterial and antioxidant functions

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