JP2007033394A - Sensor property calibration device - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To calibrate the output of an exhaust gas sensor when oxidization gas in exhaust gas detected by the exhaust gas sensor is mainly NO. <P>SOLUTION: In this sensor property calibration device which calibrates sensor property of the exhaust gas sensor making output according to the oxygen concentration of evaluation gas, the evaluation gas consists of reducing gas of a predetermined concentration and oxidizing gas of a predetermined concentration. The oxidizing gas is mainly composed of NO. The sensor output of the exhaust gas sensor for the concentration of the reducing gas and the concentration of the oxidizing gas in the evaluation gas is detected, and the output of the exhaust gas sensor is calibrated based on the sensor output. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to a sensor characteristic calibration apparatus. More specifically, the present invention relates to a sensor characteristic calibration device that calibrates the output characteristic of a sensor that generates an output corresponding to the oxygen concentration of exhaust gas.

  Conventionally, JP-A-5-312092 discloses a control device for controlling the air-fuel ratio of an internal combustion engine based on the output of an oxygen concentration sensor. In this control device, the oxygen concentration sensor is disposed in the exhaust pipe of the internal combustion engine, and generates an output corresponding to the oxygen concentration of the exhaust gas flowing in the exhaust pipe. The control device performs air-fuel ratio control by controlling the output of the oxygen concentration sensor to be a control target value.

  Further, the control device of the above prior art stores in advance the output of the oxygen concentration sensor with respect to the oxygen concentration in the atmosphere as a reference output value. On the other hand, when the driving of the internal combustion engine is stopped, this control device detects the sensor output when all the exhaust gas is discharged from the exhaust pipe. The sensor output detected here is an output corresponding to the oxygen concentration in the atmosphere. The control device obtains a value of the detected sensor output with respect to a reference output value stored in advance, and stores this value as a calibration value. While the internal combustion engine is being driven in this control device, the sensor output is calibrated by multiplying the stored calibration value by the sensor output. According to such a method, the calibration value is obtained each time the internal combustion engine is stopped, and the output of the oxygen concentration sensor is calibrated based on the calibration value. Therefore, according to the above-described prior art, variations among individual oxygen concentration sensors and changes in sensor output characteristics due to deterioration over time are appropriately calibrated, and accurate air-fuel ratio control can be performed.

JP-A-5-312092

  In order to execute the air-fuel ratio control more accurately, there is a system in which an air-fuel ratio sensor is arranged upstream of the three-way catalyst and an oxygen sensor is arranged downstream of the three-way catalyst. In such a system, air-fuel ratio control is performed based on the output of the downstream oxygen sensor and the output of the upstream air-fuel ratio sensor. The oxygen sensor has an electrode and a diffusion prevention layer covering the electrode. The exhaust gas in the exhaust passage reaches the electrode through the diffusion prevention layer. The electrode is provided with a catalyst layer, and a slight remaining fuel component is subjected to the final combustion in this catalyst layer. Then, the oxygen sensor emits an output corresponding to the oxygen concentration based on the components finally remaining around the electrode through such a process.

The oxygen gas sensor disposed on the downstream side of the three-way catalyst in such a system uses the exhaust gas after being purified by the three-way catalyst as its detection target. The exhaust gas after purification by the three-way catalyst is an extremely low concentration gas, but the ratio of CH ₄ is large in the reducing gas component in the gas, and the ratio of NO is large in the oxidizing gas component. Here, CH ₄ has a faster diffusion rate than other gases in the exhaust gas. For this reason, the ratio of each component gas in the exhaust gas reaching the electrode of the oxygen sensor may be slightly different from the actual exhaust gas, that is, the ratio in the exhaust gas flowing through the exhaust passage. In addition, CH ₄ may not be completely combusted in the catalyst of the exhaust gas sensor. For this reason, the component remaining around the electrode does not necessarily match the component remaining as a result of the complete reaction of each component in the exhaust gas. In extremely low concentration gases such as the gas downstream of the three-way catalyst, the influence of such a shift is large, and therefore the sensor output of the oxygen sensor downstream of the three-way catalyst tends to vary.

  On the other hand, NO shows a milder oxidation reaction than oxygen. For this reason, a sensor whose detection target is a gas containing NO as the main oxidizing gas has a sensor output characteristic different from the output characteristic of the exhaust gas sensor when oxygen is contained in a large proportion as an oxidizing gas component. Can be considered. Therefore, in the case of an exhaust gas sensor that detects a gas having a large proportion of gas components that easily affect its output characteristics, such as an oxygen sensor used on the downstream side of the three-way catalyst, a sensor for the atmosphere as in the above prior art Even if the output is detected and the sensor output is calibrated with the calibration value calculated based on the output, accurate calibration may not always be performed.

  The present invention has been made to solve the above-described problems, and an object of the present invention is to provide a sensor characteristic calibrating apparatus which is improved so that a calibration value of an exhaust gas sensor can be obtained under an environment corresponding to a use environment. And

In order to achieve the above object, a first invention is a sensor characteristic calibration device for calibrating a sensor characteristic of an exhaust gas sensor that emits an output corresponding to an oxygen concentration of an evaluation gas,
The evaluation gas includes a reducing gas having a predetermined concentration and an oxidizing gas having a predetermined concentration,
The oxidizing gas is mainly composed of NO,
Sensor output detection means for detecting sensor output of the exhaust gas sensor with respect to the concentration of the reducing gas and the concentration of the oxidizing gas;
Calibration means for calibrating the output of the exhaust gas sensor based on the sensor output;
It is characterized by providing.

The second invention is the first invention, wherein
NO supply means for changing the concentration of the oxidizing gas by changing the supply amount of NO,
The sensor output detection means detects the sensor output of the exhaust gas sensor as a value corresponding to the concentration of the oxidizing gas.

  According to a third aspect, in the second aspect, the NO supply means supplies the NO by changing the supply amount of the NO from the rich side to the lean side.

According to a fourth invention, in any one of the first to third inventions, the reducing gas is a gas containing at least CH ₄ .

Further, a fifth invention is the invention according to any one of the first to fourth inventions,
Reference sensor output storage means for storing a reference sensor output at an arbitrary excess air ratio;
An excess air ratio calculating means for calculating an excess air ratio of the evaluation gas according to the concentration of the reducing gas and the NO concentration,
The sensor output detection means detects the sensor output as a value corresponding to the excess air ratio calculated by the excess air ratio calculation means,
The calibration means calibrates the sensor output based on the sensor output at the arbitrary excess air ratio and the reference sensor output.

Further, a sixth invention is the sub-O ₂ sensor according to any one of the first to fifth inventions, wherein the exhaust gas sensor is disposed downstream of the three-way catalyst of the internal combustion engine,
The reference sensor output storage means stores a reference sensor output when the excess air ratio is 1,
The calibration means calibrates the sensor output based on the sensor output when the excess air ratio calculated by the excess air ratio calculation means is 1 and the reference sensor output.

The seventh invention achieves the above object,
A sensor characteristic calibration device that calibrates sensor characteristics of an exhaust gas sensor that emits an output corresponding to an oxygen concentration of exhaust gas of an internal combustion engine,
Output target value setting means for setting an output target value of the exhaust gas sensor;
Output determination means for determining whether the sensor output of the exhaust gas sensor has reached the output target value;
A concentration detection means for detecting the concentration of the reducing gas and the concentration of NO in the exhaust gas when it is determined that the sensor output has reached the output target value;
Calibration means for calibrating the sensor output of the exhaust gas sensor based on the concentration of the reducing gas and the concentration of NO and the output target value;
It is characterized by providing.

The eighth invention is characterized in that, in the seventh invention, the concentration detecting means detects the concentration of CH ₄ as the concentration of the reducing gas.

  The ninth invention is characterized in that, in the seventh or eighth invention, the concentration detecting means detects the concentration of CO as the concentration of the reducing gas.

The tenth aspect of the invention is any one of the seventh to ninth aspects of the invention,
The output target value setting means changes and sets the output target value,
The concentration detecting means detects the concentrations of the reducing gas and the NO, respectively, according to the output target value.

The eleventh aspect of the invention is the tenth aspect of the invention,
Reference sensor output storage means for storing a reference sensor output at an arbitrary excess air ratio;
An excess air ratio calculating means for calculating an excess air ratio of the exhaust gas according to the concentration of the reducing gas and the NO concentration,
The calibration means calibrates the sensor output based on the output target value at the arbitrary excess air ratio and the reference sensor output.

In a twelfth aspect of the invention according to any one of the seventh to eleventh aspects, the exhaust gas sensor is a sub O ₂ sensor disposed downstream of the three-way catalyst of the internal combustion engine,
The reference sensor output storage means stores a reference sensor output when the excess air ratio is 1,
The calibration means calibrates the sensor output based on the sensor output when the excess air ratio calculated by the excess air ratio calculation means is 1 and the reference sensor output.

  According to the first aspect of the invention, the sensor output of the exhaust gas sensor with respect to the concentration of the reducing gas and the NO concentration in the evaluation gas is obtained, and the output of the exhaust gas sensor is calibrated based on this sensor output. Therefore, the calibration value of the sensor output can be obtained based on the environment in which the exhaust gas sensor is used, and a more accurate sensor output can be obtained.

  According to the second invention, the supply amount of NO in the evaluation gas is changed and supplied, and the sensor output detection means detects the sensor output of the exhaust gas sensor as a value corresponding to the supply amount of NO. Therefore, it is possible to detect the output characteristics of the exhaust gas sensor with respect to the evaluation gas when the oxidizing gas contains a large amount of NO.

  According to the third aspect of the invention, NO is supplied by changing the supply amount from the rich side to the lean side. Therefore, the sensor output can be accurately calibrated based on the sensor output characteristics when the air-fuel ratio of the internal combustion engine changes from rich to lean.

According to the fourth invention, the reducing gas in the evaluation gas is a gas containing at least CH ₄ . Therefore, the output can be calibrated more accurately for an exhaust gas sensor whose detection target is a gas containing CH ₄ that has a higher diffusion rate than other gas components and affects the sensor output characteristics.

  According to the fifth aspect, the excess air ratio can be calculated, and the sensor output corresponding to the excess air ratio can be detected. Therefore, the sensor output can be calibrated according to the excess air ratio, and accurate air-fuel ratio control can be performed.

According to the sixth aspect of the invention, it is possible to calibrate the output more accurately in accordance with the usage environment, particularly for the sub O ₂ sensor used on the downstream side of the three-way catalyst where the gas to be detected becomes lean. it can.

  According to the seventh to ninth aspects, the exhaust gas output target value is set, and the reducing gas concentration and the NO concentration with respect to the output target value are detected. Thereby, the sensor output can be calibrated based on the output target value for the reducing gas concentration and the NO concentration in the exhaust gas. Therefore, the exhaust gas sensor can be calibrated in accordance with the actual use environment, and more accurate air-fuel ratio control can be performed.

  According to the tenth and eleventh inventions, the output target value is set by changing, and the reducing gas concentration and the NO gas concentration in the exhaust gas are detected according to each output characteristic. Therefore, the output characteristic of the air-fuel ratio sensor can be obtained over a wider range.

According to the twelfth aspect of the invention, in particular, the sub O ₂ sensor used on the downstream side of the three-way catalyst where the gas to be detected becomes lean can be calibrated more accurately according to the usage environment. it can.

Embodiments of the present invention will be described below with reference to the drawings. In the drawings, the same or corresponding parts are denoted by the same reference numerals, and the description thereof is simplified or omitted.
Embodiment 1 FIG.

FIG. 1 is a schematic diagram for explaining an oxygen sensor used in the system of the first embodiment. The oxygen sensor 10 shown in FIG. The cover 12 is provided with a plurality of vent holes 14 for introducing exhaust gas therein. A sensor element 16 is disposed in the cover 12. The sensor element 16 has a tubular structure with one end closed. A catalyst layer 18 is provided on the outer surface of the tubular structure. A coating layer 20 is provided inside the catalyst layer 18. The coating layer 20 is made of a heat-resistant porous ceramic, for example, a spinel type compound (MgO.Al ₂ O ₃ ) using alumina, and has a function of controlling the exhaust gas diffusion rate on the surface of the sensor element 16. is doing.

  An exhaust side electrode 22 is disposed inside the coating layer 20. The exhaust side electrode 22 is exposed to the exhaust gas that has passed through the coating layer 20. A solid electrolyte layer 24 is disposed on the surface of the exhaust side electrode 22 opposite to the surface in contact with the coating layer 20. An atmosphere side electrode 26 is disposed on the surface of the solid electrolyte layer 24 opposite to the exhaust side electrode 22. The exhaust side electrode 22 and the atmosphere side electrode 26 are electrodes made of a metal having high catalytic action such as Pt.

  An air chamber 28 is formed inside the sensor element 16. In the atmosphere chamber 28, the atmosphere is guided and the atmosphere side electrode 26 is exposed to the atmosphere. A heater 30 is disposed in the atmospheric chamber 28. The heater 30 is electrically connected to a heater control circuit (not shown), and heats the sensor element 16 to an appropriate temperature by being controlled by the control circuit. The sensor element 16 exhibits stable output characteristics when heated to an activation temperature of about 700 ° C.

The oxygen sensor 10 configured as described above is disposed on the downstream side of the three-way catalyst of the internal combustion engine, and is used as a sub O ₂ sensor. In the air-fuel ratio control of the internal combustion engine in the system including the sub O ₂ sensor downstream of the three-way catalyst, first, the correction value for the output of the air-fuel ratio sensor arranged on the upstream side of the three-way catalyst is determined by the output of the sub O ₂ sensor. Calculated. Next, the output of the upstream air-fuel ratio sensor is corrected based on this correction value, and the air-fuel ratio is controlled by this corrected sensor output.

When the oxygen sensor 10 is used as a sub O ₂ sensor, the oxygen sensor 10 is assembled in a pipe on the downstream side of the three-way catalyst so that the cover 12 is exposed to the exhaust gas. Exhaust gas flows into the cover 12 of the oxygen sensor 10 from the vent hole 14, and the exhaust side electrode 22 is exposed to the exhaust gas downstream of the three-way catalyst. As a result, oxygen ions move in the solid electrolyte layer 24 due to the difference in oxygen concentration between the atmosphere near the atmosphere-side electrode 24 and the exhaust gas introduced near the exhaust-side electrode 22, and the exhaust-side electrode 22 and the atmosphere-side electrode 26 generates an electromotive force. By detecting this electromotive force, the air-fuel ratio of the exhaust gas can be detected.

  The output of the oxygen sensor 10 outputs a high voltage when the oxygen concentration difference in the exhaust gas is large and rich, and outputs a substantially constant low voltage when the oxygen concentration difference is small and lean. Also, the change from a high voltage output to a low voltage output is abrupt. Usually, the exhaust gas at the output sudden change point at which the output changes rapidly is the excess air ratio λ = 1, that is, the gas near the stoichiometric ratio. However, the sensor output characteristics of the oxygen sensor include variations that are recognized as tolerances for individual oxygen sensors. Further, the oxygen sensor 10 may deteriorate due to use, and the output characteristics may vary. For this reason, it is necessary to calibrate the output deviation of the oxygen sensor 10 due to fluctuations in the output characteristics of the oxygen sensor 10.

  As a method for calibrating the output of the exhaust gas sensor, for example, there is a method of calibrating the sensor output by obtaining a calibration value by measuring the oxygen concentration in the atmosphere after the internal combustion engine is stopped. More specifically, first, the sensor output with respect to the atmospheric oxygen concentration is detected. Thereafter, a calibration value is obtained as a ratio of the detected output to the reference output at the atmospheric oxygen concentration stored in advance. While the internal combustion engine is being driven, the sensor output is calibrated by multiplying the sensor output by this calibration value.

However, the exhaust gas to be detected by the oxygen sensor 10 may become exhaust gas purified by the three-way catalyst 16. The exhaust gas downstream of the three-way catalyst is an extremely low concentration gas, but the proportion of CH ₄ (methane) and CO (carbon monoxide) is large in the reducing gas in the exhaust gas, that is, the rich gas component. Here, in particular, CH ₄ has the fastest diffusion rate except for H ₂ among the component gases in the exhaust gas. Further, even with a sensor having the catalyst layer 18 such as the oxygen sensor 10, it is difficult to completely burn CH ₄ in the catalyst layer 18. Therefore, the proportion of CH _{4 in} the exhaust gas that reaches the vicinity of the exhaust-side electrode 22 of the oxygen sensor 10 due to the fact that CH ₄ has a diffusion rate different from that of other gases and is not burned is the proportion in the actual exhaust gas. It can be different from that. In addition, it is considered that this change in the ratio tends to be large particularly in a rare gas such as an exhaust gas downstream of the three-way catalyst.

By the way, the oxygen sensor 10 has a characteristic in which the output changes suddenly within the range of a slight change of each component gas of the exhaust gas near the stoichiometric range. For this reason, if the ratio of each component gas in the exhaust gas reaching the exhaust side electrode 22 changes, even if the change is slight, the sensor output will be greatly affected. For this reason, it is considered that the influence of CH ₄ on the output of the oxygen sensor 10 on the downstream side of the three-way catalyst is large. Therefore, it is preferable to calibrate the output of the oxygen sensor 10 used on the downstream side of the three-way catalyst in consideration of the influence of CH ₄ .

On the downstream side of the three-way catalyst, when the exhaust gas is near the stoichiometric ratio, the ratio of O ₂ is very small and the ratio of NO is large in the oxidizing gas in the exhaust gas, that is, the component of the lean gas. Therefore, the lean gas that strongly affects the output of the oxygen sensor 10 is considered to be NO. NO reacts as an oxidizing substance much more slowly than oxygen. For this reason, it is conceivable that an output characteristic different from the sensor output characteristic when oxygen is considered as lean gas is generated. In addition, a sensor with high sensitivity to NO is required from the viewpoint of emission regulation in air-fuel ratio control. Therefore, it is preferable to calibrate the output of the oxygen sensor 10 used on the downstream side of the three-way catalyst in consideration of the influence of NO.

As described above, when calculating the calibration value for the output of the oxygen sensor 10 used downstream of the three-way catalyst, in the first embodiment, a unique exhaust gas atmosphere is prepared on the downstream side of the three-way catalyst. In other words, considering that the exhaust gas detected by the oxygen sensor 10 on the downstream side of the three-way catalyst is very lean, the rich gas component in the exhaust gas is mostly CH ₄ , and the lean gas component is rich in NO. Thus, the output calibration value of the oxygen sensor 10 is obtained in the following environment.

FIG. 2 shows a calibration device used for sensor characteristic calibration of an oxygen sensor. As shown in FIG. 2, the calibration apparatus includes a gas chamber 32. A supply pipe 34 through which an evaluation gas flows is connected to the gas chamber 32. A supply source 36 for supplying an evaluation gas is connected to the supply pipe 34. The supply source 36 can supply CH ₄ , CO, and NO in required supply amounts. On the other hand, an exhaust pipe 38 for exhausting the internal gas is connected to the gas chamber 32.

  When obtaining the output calibration value of the oxygen sensor 10, the sensor element 16 is incorporated into the gas chamber 32 so that the cover 12 of the oxygen sensor 10 is incorporated, and the evaluation gas in the gas chamber flowing in from the vent hole 14. The oxygen sensor 10 is arranged so as to be exposed. Further, the calibration device includes a control device 40. A supply source 36 and the oxygen sensor 10 are connected to the control device 40. The control device 40 can control the supply amount of each gas from the supply source 36, and can detect the air-fuel ratio corresponding to the evaluation gas by receiving the output of the oxygen sensor 10.

When obtaining the output calibration value of the oxygen sensor 10, the evaluation gas is supplied from the supply source 36 into the gas chamber 32. In the evaluation gas, CH ₄ and CO are mixed as rich gas. The concentration of the rich gas is set so as to have the same concentration and flow velocity as the rich gas in the exhaust gas downstream of the three-way catalyst, for example, during idling after warming up the catalyst. Specifically, the CH ₄ concentration in the evaluation gas is 200 ppm or less, and the CO concentration is about 500 ppm or less. During idling, it is considered that the exhaust gas flow rate is the slowest and the concentration of each component of the exhaust gas is the lowest. Thus, in the region of low concentration and low flow rate, the influence of CH ₄ and NO tends to be prominent, so that an accurate calibration value in this region can be obtained.

Further, while supplying CH ₄ and CO as the rich gas at a predetermined flow rate and a predetermined concentration, NO is simultaneously supplied from the supply source 36 as the lean gas. Similarly to the above, the flow rate at the time of NO supply is set to the flow rate at the time of idling, that is, the lowest flow rate assumed in the operation of the internal combustion engine. Further, the supply amount of NO is set so as to be gradually changed. In the case of an evaluation gas for calibration of the downstream oxygen sensor 30, the supply concentration of NO in the evaluation gas is about 500 ppm at the maximum.

FIG. 3 is a graph showing the relationship between the excess air ratio λ, the sensor output, and the concentration of each gas obtained when the supply amount of NO is gradually changed under the conditions set as described above. In FIG. 3, the horizontal axis represents the excess air ratio λ, and the vertical axis represents the sensor output and the concentration of each gas. As shown in FIG. 3, NO is gradually supplied from the supply amount Q _min by ΔQ and increased to Q _max . That is, NO is supplied by SWEEPing from rich to lean. However, N ₂ is mixed in accordance with the _NO supply amount QNO to achieve a balance so that the entire supply amount of lean gas becomes constant. In this state, the output of the oxygen sensor 10 is detected every time the concentration of NO increases by ΔQ. Further, the excess air ratio λ is calculated from the supplied NO concentration, CH ₄ concentration, and CO concentration. As a result, a graph of the output characteristics of the oxygen sensor 10 with respect to the excess air ratio λ as shown in FIG. 3 can be obtained.

The control device 40 detects the sensor output when the excess air ratio λ = 1, that is, the air-fuel ratio becomes the stoichiometric air-fuel ratio, and stores this value as the calibration control target value. Further, the ratio of the calibration control target value to the control target value which is the reference value of the sensor output with respect to λ = 1 stored in advance is calculated and stored as a calibration value. When the air-fuel ratio control of the internal combustion engine is actually performed using the oxygen sensor 10 as the sub O ₂ sensor, the calibration value calculated as described above is stored in advance in the air-fuel ratio control device of the internal combustion engine. Then, by multiplying the obtained sensor output by, for example, the calibration value, the sensor output is corrected, and air-fuel ratio control is performed using the corrected sensor output.

FIG. 4 is a control routine executed by control device 40 in the first embodiment of the present invention. In the routine of FIG. 4, first, the oxygen sensor 10 that is the target for calculating the output calibration value is set at a predetermined position in the gas chamber 32 (step S102). Next, among the evaluation gases, rich gas is first supplied into the gas chamber 32 (step S104). The control device 40 supplies the rich gas from the supply source 36 at a flow rate and CH ₄ and CO concentrations set in advance based on the flow rate and concentration of the exhaust gas near the stoichiometric exhaust exhausted during idling after the catalyst warms up. Control to do.

Then, the supply amount _{Q NO} of NO in the lean gas _is set to _{Q min} (step S106). The NO supply amount Q _min is an amount corresponding to the NO concentration in the evaluation gas in the richest state among the evaluation gases whose output should be detected for the output calibration of the oxygen sensor 10. The supply amount Q _min is stored in the control device 40 in advance. Then, the lean gas is supplied at a feed rate _{Q NO} of the set NO (step S108). The control device 40 controls the NO supply amount from the supply source 36 so that a set amount of NO is supplied into the gas chamber 32.

  Next, the sensor element 16 of the oxygen sensor 10 is heated (step S110). The control device 40 heats the sensor element 16 by applying a voltage having a predetermined magnitude by sending a control signal to the control circuit of the heater 30 of the oxygen sensor 10. Next, it is determined whether or not the sensor element 16 has reached a predetermined activation temperature (step S112). Specifically, the element impedance of the sensor element 16 is detected, and the activity determination is performed based on whether or not the element impedance has decreased to the activity determination value. The control device 40 stores in advance the element impedance when the sensor element 16 reaches the activation temperature as the activation determination value. In step S112, when the activity of the sensor element 16 is not recognized, an accurate sensor output cannot be obtained, and therefore the heating of the sensor element 16 is continued (step S110).

  On the other hand, if the activation of the sensor element 16 is recognized in step S112, it is next determined whether or not five minutes or more have passed after the start of the lean gas supply (step S114). It is determined that the concentration of each gas in the gas chamber 32 is stably in an equilibrium state after 5 minutes or more have passed since the lean gas was supplied. When the elapse of 5 minutes or more is not recognized in step S114, the supply of lean gas is continued.

On the other hand, when the passage of 5 minutes or more has been recognized after the start of the lean gas supply, the output of the oxygen sensor 10 is detected (step S116). This sensor output is an output corresponding to the current evaluation gas in the gas chamber 32, that is, when rich gas containing CH ₄ and CO is supplied at a predetermined flow rate and concentration, and lean gas containing _{NO is} supplied QNO. The output corresponds to the evaluation gas.

Then, the excess air ratio corresponding to the current supply amount _{Q NO} lambda is calculated (step S118). The excess air ratio λ is calculated based on the concentration of NO, the concentration of CH _{4 and} the concentration of CO. Next, the sensor output detected in step S116 is stored as the sensor output at the excess air ratio λ calculated in step S118 (step S120).

Next, it is determined whether or not the detection of the sensor output has been completed for all the regions that need to be rich to lean (step S122). The control device 40 stores the NO supply amount in the leanest state where the sensor output should be detected for calculating the output calibration value as _Qmax . Here, it is determined whether or not the currently set NO supply amount _QNO is equal to or greater than _Qmax .

In step _S122, if the establishment of _{Q NO} ≧ _{Q max} is not recognized, the value obtained by adding ΔQ to the current supply amount _{Q NO} is set as the next NO supply amount _{Q NO} (step S124). The control device 40 stores in advance an increment ΔQ of one NO supply amount. Here, in order to accurately detect the sensor output characteristic in the vicinity of the stoichiometry, the change amount ΔQ of the NO supply amount Q _NO is set to a very small value. In step S124, the the supply amount _{Q NO} is reset, after being confirmed activity again the sensor element (step S112), by performing the steps S114~S116 Similarly, the sensor in the current supply amount _{Q NO} Output is detected. Thereafter, the excess air ratio λ is calculated (step S118), and the detected sensor output is stored as a sensor output for the excess air ratio λ (step S120).

On the other hand, if establishment of Q _NO ≧ Q _max is recognized in step S122, it is determined that the detection of the entire region from rich to lean is completed, and the sensor output at the excess air ratio λ = 1 is the calibration of the oxygen sensor 10. It is read as a control target value (step S126). Next, a calibration value is calculated based on the read calibration control target value and a reference control target value stored in advance as a reference output at the excess air ratio λ (step S128). Specifically, the calibration value is calculated as a ratio of the calibration control target value to the reference control target value. Next, the obtained calibration value is stored as the calibration value of the oxygen sensor 10 (step S130).

  The calibration value stored as described above corrects the sensor output by, for example, multiplying the sensor output during driving of the internal combustion engine. On the other hand, based on the sensor output stored in step S120, a graph of sensor output characteristics with respect to the excess air ratio λ as shown in FIG. 3 can be obtained. Thereby, the output characteristic of the oxygen sensor 10 in the actual use environment of the oxygen sensor 10 can be predicted, which is used for more reliable air-fuel ratio control.

As described above, in the first embodiment, the sensor output is detected using the evaluation gas in which NO is introduced into the gas containing CH ₄ and CO, and the sensor at the theoretical air-fuel ratio (excess air ratio λ = 1) is further detected. A sensor output calibration value is set based on the output. Thereby, when the oxygen sensor 10 is used as a sub O ₂ sensor, the output of the oxygen sensor 10 can be calibrated in consideration of the components contained in the gas to be detected. Therefore, the output can be calibrated according to the usage environment of the sub O ₂ sensor, and the output of the air-fuel ratio sensor can be corrected more accurately.

Further, in the first embodiment, NO is SWEEPed from rich to lean, and the sensor output at each stage is detected. From this result, a graph of sensor output characteristics with respect to the excess air ratio λ as shown in FIG. 3 can be obtained. Therefore, the output characteristics of the sensor can be obtained in accordance with the usage environment of the oxygen sensor 10, and can be used for evaluating the output characteristics of the sensor. However, the present invention is not limited to this, and if NO is used as the oxygen gas component in the evaluation gas, conversely, the amount of NO is constant and CH ₄ is changed from rich to lean. SWEEP may be performed so that the supply amount of CH ₄ is decreased by a predetermined ratio, and the sensor output at each supply amount may be detected.

  In the first embodiment, the case where NO is gradually swept from rich to lean is supplied. There is hysteresis in the sensor output, and it is considered that there is a slight deviation in the sensor output depending on whether the evaluation gas changes from rich to lean or from lean to rich. Therefore, in consideration of the actual usage environment of the oxygen sensor 10, it is considered that there are many usage situations in which the engine becomes rich once and then leans, for example, during acceleration of the internal combustion engine. For this reason, in the first embodiment, the calibration value is calculated based on the sensor output when SWEEPing from the rich state to the lean state according to the actual use environment. However, the present invention is not limited to this, and SWEEP may be performed from lean to rich. In this way, even when changing from lean to rich, it is possible to set a calibration value that is accurate to some extent.

In the first embodiment, the case where the supply amount of NO is swept from Q _min to Q _max and supplied, and the calibration control target value is calculated and the graph of the output characteristic of the sensor output has been described. By calculating this graph, the output characteristics of the sensor can be grasped more reliably. However, the present invention is not limited to this. For example, the sensor output of the oxygen sensor 10 is detected only at one point by fixing the concentration of CH ₄ , CO, and NO in a state where the excess air ratio λ = 1. The calibration value may be calculated based on this output.

  In the first embodiment, the case where only NO is used as the oxidizing gas in the evaluation gas has been described. However, in this invention, the oxidizing gas only needs to be able to calibrate the output deviation of the sensor caused by NO. Therefore, if the gas is mainly NO, the gas contains some oxygen or the like in addition to NO. It may be.

In the first embodiment, it has been described a case of using the one containing the CH ₄ and CO at a predetermined ratio as the reducing gas. However, the present invention is not limited to this, and for example, C ₃ H ₈ or the like may be used as the reducing gas.

Further, the sensor output detected for calculating the calibration value in the first embodiment is not limited to the case of λ = 1, but is calculated based on the value corresponding to other excess air ratio. Also good. Moreover, it is not restricted to what calculates a calibration value based on an excess air ratio. For example, if a reference sensor output at a certain CH ₄ , CO, NO concentration is obtained as a known value, a calibration value can be obtained based on the sensor output detected at this concentration.

  In the first embodiment, the calibration value is calculated by obtaining the ratio of the calibration control target value to the reference control target value. However, in the present invention, such a calculation method of the calibration value is an example of calibration of the sensor output, and the present invention is not limited to this. The calibration value may be calculated by an appropriate calculation method from the sensor output result for the evaluation gas as described above.

  For example, in the first embodiment, the “sensor output detection unit” of the present invention is realized by executing step S116, and the “calibration unit” is realized by executing steps S128 to S130. Further, the “NO supply means” of the present invention is realized by executing step S124. Further, by executing step S128, the “reference sensor output storage means” and the “calibration means” of the present invention are realized, and by executing step S118, the “excess air ratio calculating means” is realized.

Embodiment 2. FIG.
In the second embodiment, the calibration value is calculated using the actual exhaust gas as a model. FIG. 5 shows a control device for an internal combustion engine using the oxygen sensor 10 in the second embodiment. As shown in FIG. 5, the system according to the second embodiment includes an internal combustion engine 50. Although the internal combustion engine 50 has a plurality of cylinders, only the cross section of one cylinder is shown in FIG. An intake branch pipe 54 is connected to the intake port 52 of each cylinder of the internal combustion engine 50. A fuel injection valve 56 is provided in the intake branch pipe 54. On the other hand, the exhaust port 58 of each cylinder of the internal combustion engine 50 is connected to a common exhaust manifold 60. The exhaust manifold 60 is connected to a catalytic converter 64 containing a three-way catalyst 62. The catalytic converter 64 is connected to the exhaust pipe 66.

An upstream air-fuel ratio sensor 68 is disposed upstream of the exhaust manifold 60, that is, the three-way catalyst 62. The upstream air-fuel ratio sensor 68 is a so-called global air-fuel ratio sensor that generates an output voltage corresponding to the air-fuel ratio over a wide air-fuel ratio region. Further, a sub O ₂ sensor 70 is assembled downstream of the exhaust pipe 66, that is, the three-way catalyst 62. The sub O ₂ sensor 70 is the same as the oxygen sensor 10 as shown in FIG. 1 and has a characteristic that its output value changes stepwise in the vicinity of the theoretical air-fuel ratio. Further, a CH ₄ concentration sensor 72, a CO concentration sensor 74, and an NO concentration sensor 76 are assembled in the exhaust pipe 66, respectively. The CH ₄ concentration sensor 72, the CO concentration sensor 74, and the NO concentration sensor 76 are sensors that emit outputs corresponding to the concentrations of CH ₄ , CO, and NO, respectively.

This system also has a control device 78. The control device 78 is connected to the fuel injection valve 56, the air-fuel ratio sensor 68, the sub O ₂ sensor 70, the CH ₄ concentration sensor 72, the CO concentration sensor 74, and the NO concentration sensor 76, respectively. The control device 78 can control the fuel injection amount from the fuel injection valve 56 in order to cause the outputs of the air-fuel ratio sensor 68 and the sub O ₂ sensor 70 to SWEEP to the output target value. Further, the control device 78 can detect the concentrations of CH ₄ , CO, and NO in the gas discharged at this time based on the outputs from the concentration sensors 72 to 76.

When calculating the calibration value of the sub O ₂ sensor 70, the environment is set as follows. First, the internal combustion engine 50 is set in an idle state. This is because the calibration value of the sensor output is obtained in an environment where the exhaust gas concentration is very thin and CH ₄ or NO gas greatly affects the sensor output, such as during idling. In this state, the output target value V _tgt of the air-fuel ratio sensor 68 and the sub O ₂ sensor 70 is gradually changed from the rich side (0.8 V) to the lean side (0.2 V). That is, feedback control is performed each time so that the sensor output of the output target value V _tgt is obtained, and the fuel injection amount is controlled. While the outputs of the air-fuel ratio sensor 68 and the sub O2 sensor 70 are stable at the set output target value V _tgt , the CH ₄ , CO, and NO gas concentrations at that time are detected.

FIG. 6 is a graph showing the relationship between the concentration of CH ₄ , CO and NO detected in the above environment and the sensor output target value. In FIG. 6, the horizontal axis represents the elapsed time, and the vertical axis represents the sensor output target value and the CH ₄ , CO, and NO concentrations. In the graph shown in FIG. 6, the sensor output target value is changed so that the air-fuel ratio changes from rich to lean as time passes. As shown in FIG. 6, the concentrations of CH4 and CO decrease from the rich state until the excess air ratio λ = 1 is reached, reach an almost equilibrium state at λ = 1, and remain substantially constant thereafter. . On the other hand, the concentration of NO starts to increase around λ = 1 and increases as the lean state is reached. From such a relationship, the point at which the excess air ratio λ = 1 can be predicted theoretically based on the balance of the CH ₄ , CO, and NO concentrations detected according to the output target value of the sensor output. it can. The output target value V _tgt of the sub O ₂ sensor 70 at the predicted excess air ratio λ = 1 is set as the calibration control target value. Further, the reference output of the sensor at the excess air ratio λ = 1 is stored in advance as a reference calibration control target value. Accordingly, the calibration value is calculated as a ratio of the calibration control target value to the reference control target value. This calibration value is stored and used as the output calibration value of the sub O ₂ sensor 70 during driving of the internal combustion engine.

  FIG. 7 is a flowchart for illustrating a control routine executed by control device 78 in the second embodiment. In the routine shown in FIG. 7, first, it is determined whether or not the operating state of the internal combustion engine 50 is idling in order to calculate a calibration value (step S202). If it is determined that the vehicle is not operating in an idle state, this process is once terminated.

On the other hand, when it is determined that the engine is idling, the output target value V _{tgt of} the air-fuel ratio sensor 68 and the sub O ₂ sensor 70 is set to V _max (step S204). V _max is an output target value in the richest state in each gas concentration detection range for the current calibration value calculation, and is stored in the control device 78 in advance.

  Next, the sensor element 16 is heated (step S206). The sensor element 16 is heated by sending a control signal from the control device 78 to the control circuit of the heater 30 and applying a predetermined voltage. Next, it is determined whether or not the sensor element has reached the activation temperature (step S208). Whether the sensor element is active is determined based on whether or not the element impedance has decreased to a pre-stored activity determination value. In step S208, if the activation of the sensor element is not recognized, the heating of the sensor is continued until the element impedance decreases to the activation determination value.

On the other hand, if the sensor activity is recognized in step S208, it is next determined whether or not the feedback control is completed (step S210). That is, it is determined whether the outputs of the air-fuel ratio sensor 68 and the sub O ₂ sensor 70 are the same as the set output target value V _tgt . In step S210, when the completion of the feedback control is not recognized, the feedback control is continued so that the outputs of the air-fuel ratio sensor 68 and the sub O2 sensor 70 become the output target value V _tgt .

On the other hand, if the completion of the feedback control is recognized in step S210, the concentrations of CO, CH ₄ and NO at that time are detected (step S212). The concentration of each gas is detected based on outputs from the CH ₄ concentration sensor 72, the CO concentration sensor 74, and the NO concentration sensor 76. Next, the concentration of each gas detected in step S212 is stored in the RAM as the concentration with respect to the output target value V _tgt at this time (step S214).

Next, it is determined whether or not the detection of the concentration of each gas for all measurement regions from rich to lean has been completed (step S216). Here, it is determined whether or not the output target value V _tgt is equal to or less than V _min . Note that the control device 78 stores in advance, as V _min , the smallest value among the output target values of all the areas necessary for detecting the sensor output characteristics.

In step _S216, if the establishment of the _{V tgt} ≦ _{V min} is not _recognized, the value obtained by subtracting ΔV from _{V tgt} is set as a new target output value _{V tgt} (step S218). The control device 78 stores ΔV in advance as a rate of changing the output target value. In step S218, after the new output target value V _tgt is set, it is determined again that the sensor element is active (step S208). When the feedback control is completed in step S210, the CH at the output target value V _tgt is determined. _4. Each concentration of CO, NO is detected and stored together with the output target value V _tgt (steps S212, S214). In the flow of FIG. 7, in step S216, the output target value V _tgt is decreased by ΔV until V _tgt ≦ V _min is established, and each gas concentration is stepwise within the range of V _max to V _min. Will be measured.

On the other hand, if the establishment of V _tgt ≦ V _min is recognized in step S216, the excess air ratio λ is the point closest to the atmosphere on the downstream side of the three-way catalyst at the time of stoichiometry based on the measurement result of each gas concentration. = 1 (step S220). Next, the output target value V _tgt at λ = 1 is read as the calibration control target value at λ = 1 of this sensor (step S222). Thereafter, the calibration value of the sub O ₂ sensor 70 is calculated from the calibration control target value (step S224). The calibration value is calculated as the value of the calibration control target value with respect to the control target value stored in advance. Thereafter, the calculated calibration value is stored (step S226).

As described above, the output calibration value of the sub O ₂ sensor 70 can be obtained even under an actual exhaust gas environment. Thus, the calibration value close to the usage environment of the sub O ₂ sensor 70 can be obtained by setting the internal combustion engine to the actual operating state and obtaining the calibration value from the output corresponding to the exhaust gas in this case. it can. Therefore, it is possible to more reliably calibrate the output deviation that is likely to occur in the usage environment, and to perform accurate air-fuel ratio control.

In the second embodiment, the concentration closest to the atmosphere downstream of the three-way catalyst at the time of stoichiometry is predicted from the concentrations of CH ₄ , CO, and NO, and this time is referred to as excess air ratio λ = 1. As described above, the case where the output target value V _tgt at this time is used for the calibration value calculation has been described. However, the prediction method of the excess air ratio λ = 1 in the present invention is not limited to this, and any method can be used as long as the excess air ratio λ = 1 can be specified. For example, as shown in FIG. 6, the concentration of CO, which is a rich gas, and the concentration of CH ₄ decrease from the rich state as it approaches the vicinity of stoichiometry. Value. In particular, this tendency is remarkable for CO, and the CO concentration after passing through the stoichiometry is almost in an equilibrium state and does not change. Therefore, for example, it is possible to obtain a point at which the concentration of CO is minimized, assume that λ = 1, and set the sensor output at this time as the calibration control target value. Further, at the time of stoichiometry, it is conceivable that both the rich gas and the lean gas have low concentrations. Therefore, even if the excess air ratio λ = 1 is assumed to be the lowest average point from the concentration of each gas, the output target value V _tgt at this time is set as the calibration control target value. Good. As described above, it is difficult to accurately identify the stoichiometric point of the exhaust gas from the gas concentration. However, according to any of the above methods, the excess air ratio λ = 1 within the range of the slight deviation near the stoichiometric range. It is thought that the place that becomes can be specified. Therefore, by setting the sensor output at these times as the calibration control target value, it is possible to perform accurate output calibration suitable for the use environment of the sub O ₂ sensor 70. Alternatively, the excess air ratio may be calculated by obtaining the air-fuel ratio not from the detected gas concentrations but from the fuel injection amount from the fuel injection valve and the intake air amount.

  In the above embodiment, when referring to the number of each element, quantity, quantity, range, etc., unless otherwise specified or clearly specified in principle, the number referred to It is not limited. Further, the structures described in the embodiments, steps in the method, and the like are not necessarily essential to the present invention unless otherwise specified or clearly specified in principle.

  For example, in the second embodiment, the “output target value setting unit” of the present invention is realized by executing step S218, and the “output determination unit” of the present invention is realized by executing step S210. Then, by executing step S212, the “concentration detection means” is realized, and by executing steps S224 to S226, “calibration means” and “reference sensor output storage means” are realized, and step S220 is executed. Thus, the “excess air ratio calculating means” of the present invention is realized.

It is a schematic diagram for demonstrating the oxygen sensor in Embodiment 1 of this invention. It is a schematic diagram for demonstrating the calibration apparatus in Embodiment 1 of this invention. It is a graph for demonstrating the relationship between the excess air ratio in Embodiment 1 of this invention, and the output of an oxygen sensor. It is a flowchart for demonstrating the routine of control which a control apparatus performs in Embodiment 1 of this invention. It is a schematic diagram for demonstrating the system in Embodiment 2 of this invention. It is a graph for demonstrating the relationship between the density | concentration of each gas in Embodiment 2 of this invention, and the output of an oxygen sensor. It is a flowchart for demonstrating the control routine which a control apparatus performs in Embodiment 2 of this invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 10 Oxygen sensor 12 Cover 14 Ventilation hole 16 Sensor element 18 Catalyst layer 20 Coating layer 22 Exhaust side electrode 24 Solid electrolyte layer 26 Atmosphere side electrode 28 Atmosphere chamber 30 Heater 32 Gas chamber 34 Supply pipe 36 Supply source 38 Exhaust pipe 40 Controller 50 Internal combustion engine 52 Intake port 54 Intake branch pipe 56 Fuel intake valve 58 Exhaust port 60 Exhaust manifold 62 Three-way catalyst 64 Catalytic converter 66 Exhaust pipe 68 Air-fuel ratio sensor 70 Sub O ₂ sensor 72 CH ₄ concentration sensor 74 CO concentration sensor 76 NO concentration Sensor 78 Control device

Claims (12)

A sensor characteristic calibration device that calibrates sensor characteristics of an exhaust gas sensor that emits an output corresponding to the oxygen concentration of an evaluation gas,
The evaluation gas includes a reducing gas having a predetermined concentration and an oxidizing gas having a predetermined concentration,
The oxidizing gas is mainly composed of NO,
Sensor output detection means for detecting sensor output of the exhaust gas sensor with respect to the concentration of the reducing gas and the concentration of the oxidizing gas;
Calibration means for calibrating the output of the exhaust gas sensor based on the sensor output;
A sensor characteristic calibration device comprising: NO supply means for changing the concentration of the oxidizing gas by changing the supply amount of NO,
2. The sensor characteristic calibration apparatus according to claim 1, wherein the sensor output detection means detects a sensor output of the exhaust gas sensor as a value corresponding to the concentration of the oxidizing gas.   The sensor characteristic calibration apparatus according to claim 2, wherein the NO supply unit supplies the NO by changing the supply amount of the NO from the rich side to the lean side. The sensor characteristic calibration apparatus according to claim 1, wherein the reducing gas is a gas containing at least CH ₄ . Reference sensor output storage means for storing a reference sensor output at an arbitrary excess air ratio;
An excess air ratio calculating means for calculating an excess air ratio of the evaluation gas according to the concentration of the reducing gas and the NO concentration,
The sensor output detection means detects the sensor output as a value corresponding to the excess air ratio calculated by the excess air ratio calculation means,
The sensor characteristic calibration according to claim 1, wherein the calibration unit calibrates the sensor output based on a sensor output at the arbitrary excess air ratio and the reference sensor output. apparatus. The exhaust gas sensor is a sub O ₂ sensor disposed downstream of the three-way catalyst of the internal combustion engine,
The reference sensor output storage means stores a reference sensor output when the excess air ratio is 1,
The calibration means calibrates the sensor output based on a sensor output when the excess air ratio calculated by the excess air ratio calculation means is 1 and the reference sensor output. The sensor characteristic calibration apparatus according to 1. A sensor characteristic calibration device that calibrates sensor characteristics of an exhaust gas sensor that emits an output corresponding to an oxygen concentration of exhaust gas of an internal combustion engine,
Output target value setting means for setting an output target value of the exhaust gas sensor;
Output determination means for determining whether the sensor output of the exhaust gas sensor has reached the output target value;
A concentration detection means for detecting the concentration of the reducing gas and the concentration of NO in the exhaust gas when it is determined that the sensor output has reached the output target value;
Calibration means for calibrating the sensor output of the exhaust gas sensor based on the concentration of the reducing gas and the concentration of NO and the output target value;
A sensor characteristic calibration device comprising: The sensor characteristic calibration apparatus according to claim 7, wherein the concentration detection unit detects a concentration of CH ₄ as the concentration of the reducing gas.   9. The sensor characteristic calibration apparatus according to claim 7, wherein the concentration detection unit detects a CO concentration as the concentration of the reducing gas. The output target value setting means changes and sets the output target value,
The sensor characteristic calibration apparatus according to claim 7, wherein the concentration detection unit detects the concentration of the reducing gas and the NO in accordance with the output target value. Reference sensor output storage means for storing a reference sensor output at an arbitrary excess air ratio;
An excess air ratio calculating means for calculating an excess air ratio of the exhaust gas according to the concentration of the reducing gas and the NO concentration,
The sensor specific calibration apparatus according to claim 10, wherein the calibration unit calibrates the sensor output based on the output target value at the arbitrary excess air ratio and the reference sensor output. The exhaust gas sensor is a sub O ₂ sensor disposed downstream of the three-way catalyst of the internal combustion engine,
The reference sensor output storage means stores a reference sensor output when the excess air ratio is 1,
12. The calibration means calibrates the sensor output based on a sensor output when the excess air ratio calculated by the excess air ratio calculating means is 1 and the reference sensor output. The sensor characteristic calibration apparatus according to 1.

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