JP2007032092A - Electrification preventive painting floor structure - Google Patents

Electrification preventive painting floor structure Download PDF

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JP2007032092A
JP2007032092A JP2005216855A JP2005216855A JP2007032092A JP 2007032092 A JP2007032092 A JP 2007032092A JP 2005216855 A JP2005216855 A JP 2005216855A JP 2005216855 A JP2005216855 A JP 2005216855A JP 2007032092 A JP2007032092 A JP 2007032092A
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antistatic coating
epoxy resin
floor material
antistatic
coating floor
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Isao Miura
勇雄 三浦
Toshiro Itaya
俊郎 板谷
Hideyuki Hakamadani
秀幸 袴谷
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Toda Corp
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Toda Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an electrification preventive painting floor structure for reducing damage of a surface, easy in repairing when electrification preventive performance reduces, shortening a repairing period, and reducing cost, while maintaining the electrification preventive effect. <P>SOLUTION: This electrification preventive painting floor structure is formed by applying an electrification preventive painting floor material of upper-lower two layers on a floor base 20. A solventless epoxy resin-based electrification preventive painting floor material 10 is used as a lower layer side electrification preventive painting floor material, and an aqueous epoxy resin-based electrification preventive painting floor material 12 is used as an upper layer side electrification preventive painting floor material. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、生産施設などの床基盤上に帯電防止塗り床材を塗布して形成する帯電防止塗り床構造に関する。   The present invention relates to an antistatic coating floor structure formed by applying an antistatic coating floor material on a floor base such as a production facility.

半導体製造工場や精密機器工場等の生産施設においては、高度の安定した帯電防止性能を有する床材が要求されている。   In production facilities such as semiconductor manufacturing factories and precision instrument factories, floor materials having high and stable antistatic performance are required.

このような帯電防止用床材として帯電防止塗り床材が知られている。   Antistatic coating floor materials are known as such antistatic floor materials.

この帯電防止塗り床材は、ウレタン樹脂やエポキシ樹脂などの塗り床材用のバインダーに、カーボンブラックや金属粉末などの導電性粉体を混入したり、あるいは、カーボン繊維やステンレス繊維を混入したものなどが用いられている(特許文献1、従来の技術参照)。
特開平6−2417号公報
This antistatic coating material is made by mixing conductive powders such as carbon black and metal powder with carbon fiber or stainless steel fibers in binders for coating materials such as urethane resin and epoxy resin. Etc. are used (see Patent Document 1, conventional technology).
JP-A-6-2417

このような生産施設などの帯電防止塗り床材は、施設内をフォークリフトや台車などが走行することにより、摩耗や損傷を受けて、表面に傷が付き、帯電防止性能が低下しやすいものであった。   Such antistatic coated flooring materials in production facilities are subject to wear and damage due to running of forklifts and carts in the facility, and the surface is easily scratched, and the antistatic performance is likely to deteriorate. It was.

例えば、防爆仕様であることから帯電防止性能を有する床材が要求される精密機器工場において、調合工程時に焼成セラミックパウダーが床にこぼれ落ち、その上をキャスターが走行したために床表面を損傷して。帯電防止性能が損なわれてしまうようなことがあった。   For example, in precision equipment factories where floor materials with antistatic performance are required due to the explosion-proof specifications, the fired ceramic powder spills onto the floor during the blending process, and the caster travels on the floor to damage the floor surface. In some cases, the antistatic performance is impaired.

そのため、帯電防止塗り床材を補修しなければならず、その補修のためには損傷した帯電防止塗り床材をはつって除去した後、再度塗り直す必要があり、補修のために多くの時間とコストを費やしている。   Therefore, it is necessary to repair the antistatic coating floor material. To repair the antistatic coating floor material, it is necessary to remove the damaged antistatic coating floor material and then apply it again. And spend the cost.

本発明の目的は、帯電防止効果を維持しつつ、表面の損傷を減少させると共に、帯電防止性能が低下した際には容易に補修を行え、補修期間の短縮及びコストの削減をなし得る帯電防止塗り床構造を提供することにある。   The object of the present invention is to reduce the damage to the surface while maintaining the antistatic effect, and to easily perform repair when the antistatic performance is reduced, thereby reducing the repair period and reducing the cost. It is to provide a painted floor structure.

前記目的を達成するため、本発明の帯電防止塗り床構造は、床基盤上に少なくとも下層側及び上層側帯電防止塗り床材を塗布して複数層に形成する帯電防止塗り床構造であって、
前記下層側帯電防止塗り床材として、無溶剤形エポキシ樹脂系帯電防止塗り床材を用い、
前記上層側帯電防止塗り床材として、水性形エポキシ樹脂系帯電防止塗り床材を用いることを特徴とする。
In order to achieve the above object, the antistatic coating floor structure of the present invention is an antistatic coating floor structure in which at least a lower layer side and an upper layer side antistatic coating floor material are applied on a floor base to form a plurality of layers.
As the lower layer side antistatic coating flooring, a solventless epoxy resin-based antistatic coating flooring is used,
A water-based epoxy resin-based antistatic coating floor material is used as the upper layer side antistatic coating floor material.

本発明によれば、無溶剤形エポキシ樹脂系帯電防止塗り床材は、帯電防止効果はあるが、耐磨耗性はそれほど高くなく、水性形エポキシ樹脂系帯電防止塗り床材は、耐磨耗性及び帯電防止効果は高い。   According to the present invention, the solvent-free epoxy resin-based antistatic coating flooring has an antistatic effect, but the wear resistance is not so high. Property and antistatic effect are high.

そこで、水性形エポキシ樹脂系帯電防止塗り床材を上層側、無溶剤形エポキシ樹脂系帯電防止塗り床材を下層側に配置することで、水性形エポキシ樹脂系帯電防止塗り床材によって耐磨耗性を持たせて表面の損傷を減少させると共に、水性形エポキシ樹脂系帯電防止塗り床材の帯電防止性能が低下した際には、無溶剤形エポキシ樹脂系帯電防止塗り床材が水性形エポキシ樹脂系帯電防止塗り床材をバックアップして帯電防止効果を維持することができ、その結果、帯電防止効果と耐磨耗性を確保することができる。   Therefore, by placing the water-based epoxy resin-based antistatic coating flooring on the upper layer side and the solvent-free epoxy resin-based antistatic coating flooring on the lower layer side, the water-based epoxy resin-based antistatic coating flooring wears away. When the antistatic performance of the water-based epoxy resin-based antistatic coating flooring is reduced, the solvent-free epoxy resin-based antistatic coating flooring becomes a water-based epoxy resin. The antistatic coating flooring can be backed up to maintain the antistatic effect, and as a result, the antistatic effect and wear resistance can be ensured.

また、水性形エポキシ樹脂系帯電防止塗り床材は損傷した水性形エポキシ樹脂系帯電防止塗り床材上に重ね塗りすることで容易に補修ができ、補修期間の短縮及びコストの削減をなし得ることができる。   In addition, water-based epoxy resin-based antistatic coating floor materials can be easily repaired by recoating them on a damaged water-based epoxy resin-based antistatic coating floor material, and the repair period and cost can be reduced. Can do.

さらに、無溶剤形エポキシ樹脂系帯電防止塗り床材及び水性形エポキシ樹脂系帯電防止塗り床材は、ホルムアルデヒドやVOC(有機揮発化合物)などを含まないので、環境や人体の健康に悪影響を及ぼすことがない。   In addition, solvent-free epoxy resin-based antistatic coating materials and water-based epoxy resin-based antistatic coating materials do not contain formaldehyde, VOC (organic volatile compounds), etc., which may adversely affect the environment and human health. There is no.

本発明においては、前記下層側帯電防止塗り床材と前記上層側帯電防止塗り床材との間に、水性形導電性プライマーを用いた中間層を有するものとすることができる。   In the present invention, an intermediate layer using an aqueous conductive primer can be provided between the lower layer side antistatic coating floor material and the upper layer side antistatic coating floor material.

このような構成とすることにより、帯電防止効果の高い水性形導電性プライマーを中間層に用いることで、より帯電防止効果を高めることができる。   By setting it as such a structure, an antistatic effect can be heightened more by using an aqueous | water-based conductive primer with a high antistatic effect for an intermediate | middle layer.

この場合も、ホルムアルデヒドやVOC(有機揮発化合物)などを含まないので、環境や人体の健康に悪影響を及ぼすことがない。   Also in this case, since it does not contain formaldehyde or VOC (organic volatile compound), it does not adversely affect the environment and human health.

以下、本発明の実施の形態について図面を参照して説明する。   Hereinafter, embodiments of the present invention will be described with reference to the drawings.

図1は、本発明の一実施の形態にかかる帯電防止塗り床構造を示す断面図である。   FIG. 1 is a sectional view showing an antistatic coating floor structure according to an embodiment of the present invention.

この帯電防止塗り床構造は、床基盤20上に上下層の帯電防止塗り床材を塗布して2層に形成したもので、下層側帯電防止塗り床材として、無溶剤形エポキシ樹脂系帯電防止塗り床材10を用い、上層側帯電防止塗り床材として、水性形エポキシ樹脂系帯電防止塗り床材12を用いている。   This antistatic coating floor structure is formed by applying upper and lower antistatic coating floor materials on the floor base 20 to form two layers. As a lower layer antistatic coating floor material, a solventless epoxy resin-based antistatic agent is used. The coating floor material 10 is used, and the water-based epoxy resin-based antistatic coating floor material 12 is used as the upper layer side antistatic coating floor material.

この無溶剤形エポキシ樹脂系帯電防止塗り床材10は、帯電防止効果はあるが、耐磨耗性はそれほど高くない。   This solventless epoxy resin-based antistatic coating flooring 10 has an antistatic effect, but is not so high in wear resistance.

また、水性形エポキシ樹脂系帯電防止塗り床材12は、耐磨耗性及び帯電防止効果が高い。   Further, the water-based epoxy resin-based antistatic coating flooring 12 has high wear resistance and antistatic effect.

そして、上層側の水性形エポキシ樹脂系帯電防止塗り床材12によって耐磨耗性を持たせて表面の損傷を減少させると共に、下層側の無溶剤形エポキシ樹脂系帯電防止塗り床材10によって、水性形エポキシ樹脂系帯電防止塗り床材12の帯電防止効果が低下した際に、水性形エポキシ樹脂系帯電防止塗り床材12の帯電防止効果をバックアップして帯電防止効果を維持させるようにしている。   Then, the upper layer side water-based epoxy resin-based antistatic coating flooring 12 has wear resistance to reduce surface damage, and the lower layer side solvent-free epoxy resin-based antistatic coating flooring 10 When the antistatic effect of the water-based epoxy resin-based antistatic coating flooring 12 is lowered, the antistatic effect of the water-based epoxy resin-based antistatic coating flooring 12 is backed up to maintain the antistatic effect. .

これによって、帯電防止効果と耐磨耗性を確保した帯電防止塗り床構造を形成するようにしている。   As a result, an antistatic coated floor structure that ensures an antistatic effect and wear resistance is formed.

この無溶剤形エポキシ樹脂系帯電防止塗り床材10及び水性形エポキシ樹脂系帯電防止塗り床材12の塗布厚は、それぞれ0.8〜4mmとしている。   The coating thicknesses of the solventless epoxy resin-based antistatic coating floor material 10 and the water-based epoxy resin-based antistatic coating floor material 12 are set to 0.8 to 4 mm, respectively.

無溶剤形エポキシ樹脂系帯電防止塗り床材10及び水性形エポキシ樹脂系帯電防止塗り床材12の施工は、床基盤20に無溶剤形エポキシ樹脂系帯電防止塗り床材10を塗布して硬化した後、水性形エポキシ樹脂系帯電防止塗り床材12を塗布してもよく、あるいは、無溶剤形エポキシ樹脂系帯電防止塗り床材10及び水性形エポキシ樹脂系帯電防止塗り床材12をラミネート状にして同時に塗布するようにしてもよい。   The construction of the solventless epoxy resin-based antistatic coating flooring 10 and the water-based epoxy resin-based antistatic coating flooring 12 was performed by applying the solventless epoxy resin-based antistatic coating flooring 10 to the floor base 20 and curing it. Thereafter, the water-based epoxy resin-based antistatic coating floor 12 may be applied, or the solventless epoxy resin-based antistatic coating floor 10 and the water-based epoxy resin-based antistatic coating floor 12 are laminated. May be applied simultaneously.

また、水性形エポキシ樹脂系帯電防止塗り床材12は、損傷した水性形エポキシ樹脂系帯電防止塗り床材の表面上に重ね塗りすることで容易に補修ができ、補修期間の短縮及びコストの削減をなし得ることができる。   In addition, the water-based epoxy resin-based antistatic coating flooring 12 can be easily repaired by recoating it on the surface of the damaged water-based epoxy resin-based antistatic coating flooring, thereby shortening the repair period and reducing the cost. Can be obtained.

この補修時の塗布厚は、0.8〜4mmである。   The coating thickness at the time of repair is 0.8 to 4 mm.

さらに、無溶剤形エポキシ樹脂系帯電防止塗り床材10及び水性形エポキシ樹脂系帯電防止塗り床材12は、ホルムアルデヒドやVOC(有機揮発化合物)などを含まないので、環境や人体の健康に悪影響を及ぼすことがなく、良好な帯電防止塗り床構造が得られる。   Furthermore, since the solventless epoxy resin-based antistatic coating floor material 10 and the water-based epoxy resin-based antistatic coating floor material 12 do not contain formaldehyde, VOC (organic volatile compounds), etc., they have an adverse effect on the environment and human health. And a good antistatic coating floor structure is obtained.

図2は、本発明の他の実施の形態にかかる帯電防止塗り床構造を示す断面図である。   FIG. 2 is a sectional view showing an antistatic coating floor structure according to another embodiment of the present invention.

この実施の形態では、図1の実施の形態における下層側帯電防止塗り床材である無溶剤形エポキシ樹脂系帯電防止塗り床材10と、上層側帯電防止塗り床材である水性形エポキシ樹脂系帯電防止塗り床材12との間に、中間層として水性形導電性プライマー14を配設して3層のものとしている。   In this embodiment, a solventless epoxy resin-based antistatic coating floor material 10 which is the lower layer side antistatic coating floor material in the embodiment of FIG. 1 and an aqueous epoxy resin system which is the upper layer side antistatic coating floor material. A water-based conductive primer 14 is disposed as an intermediate layer between the antistatic coating floor material 12 and has three layers.

この水性形導電性プライマー14は帯電防止効果が高く、このような帯電防止効果の高い水性形導電性プライマー14を中間層に用いることで、無溶剤形エポキシ樹脂系帯電防止塗り床材10のみを水性形エポキシ樹脂系帯電防止塗り床材12のバックアップとして用いる場合よりも帯電防止効果を高めることができる。   This water-based conductive primer 14 has a high antistatic effect. By using the water-based conductive primer 14 having such a high antistatic effect as an intermediate layer, only the solventless epoxy resin-based antistatic coating flooring 10 is used. The antistatic effect can be enhanced as compared with the case where the water-based epoxy resin-based antistatic coating floor 12 is used as a backup.

また、この場合も、水性形導電性プライマー14は、ホルムアルデヒドやVOC(有機揮発化合物)などを含まないので、環境や人体の健康に悪影響を及ぼすことがない。   Also in this case, since the aqueous conductive primer 14 does not contain formaldehyde, VOC (organic volatile compound) or the like, it does not adversely affect the environment and human health.

他の構成及び作用は前記実施の形態と同様である。   Other configurations and operations are the same as those in the above embodiment.

次に、帯電防止塗り床材の帯電防止性能実験の結果について説明する。   Next, the result of the antistatic performance experiment of the antistatic coating floor material will be described.

[実験対象]
図3に示すように、下層(下塗り)が無溶剤形エポキシ樹脂系で上層(上塗り)が水性形エポキシ樹脂系の2層の帯電防止塗り床材(図1の実施の形態に相当)、下層(下塗り)が水性形エポキシ樹脂系で上層(上塗り)が無溶剤形エポキシ樹脂系の2層の帯電防止塗り床材、下層(下塗り)が無溶剤形エポキシ樹脂系で上層(上塗り)が溶剤形エポキシ樹脂系の2層の帯電防止塗り床材、水性形エポキシ樹脂系1層の帯電防止塗り床材、無溶剤形エポキシ樹脂系1層の帯電防止塗り床材、溶剤形エポキシ樹脂系1層の帯電防止塗り床材、ビニルエステル樹脂系1層の帯電防止塗り床材の7種類の帯電防止塗り床材について実験を行った。
[Target of experiment]
As shown in FIG. 3, the lower layer (undercoat) is a solvent-free epoxy resin-based and the upper layer (overcoat) is an aqueous epoxy resin-based two-layer antistatic coating floor material (corresponding to the embodiment of FIG. 1), the lower layer (Undercoat) is a water-based epoxy resin base and the upper layer (overcoat) is a solventless epoxy resin-based two-layer antistatic coating floor material, the lower layer (undercoat) is a solventless epoxy resin base and the upper layer (overcoat) is solvent-based Epoxy resin-based two-layer antistatic coating flooring, water-based epoxy resin-based one-layer antistatic coating flooring, solvent-free epoxy resin-based one-layer antistatic coating flooring, solvent-type epoxy resin-based one-layer coating Experiments were conducted on seven types of antistatic coating floor materials, an antistatic coating floor material and a vinyl ester resin-based single layer antistatic coating floor material.

試験体は、寸法が300mm×300mmで、フレキシブル板表面に前記7種類の帯電防止塗り床材を所定の厚さで塗布したものを用いた。   The test body used had a dimension of 300 mm × 300 mm, and the above-mentioned seven types of antistatic coating floor materials were applied to the surface of the flexible plate with a predetermined thickness.

[実験方法]
促進キャスター試験
キャスターの走行動作は、DIN54324(床材疲労試験)に準じてキャスター試験機で模擬した。
[experimental method]
Accelerated caster test The running operation of the caster was simulated by a caster tester according to DIN 54324 (floor material fatigue test).

具体的には、ターンテーブルに固定された試験体の上にセラミックパウダー40gを一様に塗布し、キャスターが着いた円盤を試験体の上にセットした。   Specifically, 40 g of ceramic powder was uniformly applied on the test body fixed to the turntable, and the disk on which the caster was attached was set on the test body.

さらに、円盤におもりを載せ、総荷重を120kgにして固定し、ターンテーブルを14サイクル/分の速度で回転させて、5000サイクルまで試験した。   Further, a weight was placed on the disk, the total load was fixed at 120 kg, and the turntable was rotated at a speed of 14 cycles / min.

なお、試験は、20℃、65%RHの室内で行った。   Note that the test was performed in a room at 20 ° C. and 65% RH.

帯電防止性能の評価は、所定のサイクル後にセラミックパウダーを除去してから電気表面抵抗値を測定して行った。   The antistatic performance was evaluated by measuring the electric surface resistance after removing the ceramic powder after a predetermined cycle.

[実験結果]
キャスター試験後の電気表面抵抗の変化を図4に示す。
[Experimental result]
The change in electrical surface resistance after the caster test is shown in FIG.

帯電防止塗り床材の種類は、図3の各帯電防止塗り床材の左側に示した記号により表示している。   The type of the antistatic coating floor material is indicated by the symbol shown on the left side of each antistatic coating floor material in FIG.

精密機器工場の帯電防止床では、通常、図4の太線で示すように、105Ω以上で109Ω未満の抵抗が要求されている。 In an antistatic floor of a precision equipment factory, a resistance of 10 5 Ω or more and less than 10 9 Ω is usually required as shown by a thick line in FIG.

実験の結果、下層が水性形エポキシ樹脂系、上層が無溶剤形エポキシ樹脂系の帯電防止塗り床材及びビニルエステル樹脂系の帯電防止塗り床材は、試験開始直後から109Ωを超える高い抵抗値を示した。 As a result of the experiment, the antistatic coating floor material in which the lower layer is a water-based epoxy resin system and the upper layer is a solventless epoxy resin system and the vinyl ester resin type antistatic coating floor material has a high resistance exceeding 10 9 Ω immediately after the start of the test. The value is shown.

下層が無溶剤形エポキシ樹脂系、上層が溶剤形エポキシ樹脂系の帯電防止塗り床材、無溶剤形エポキシ樹脂系の帯電防止塗り床材及び溶剤形エポキシ樹脂系の帯電防止塗り床材は、1000サイクル前後で109Ωを超えるまでに抵抗値が上がった。 The lower layer is a solventless epoxy resin-based, the upper layer is a solvent-based epoxy resin-based antistatic coating floor material, the solventless epoxy resin-based antistatic coating floor material and the solvent-type epoxy resin-based antistatic coating floor material are 1000 The resistance value increased up to 10 9 Ω before and after the cycle.

水性形エポキシ樹脂系の帯電防止塗り床材は、1500サイクル前後で109Ωを超えるまでに抵抗値が上がった。 The resistance value of the water-based epoxy resin-based antistatic coating floor material increased to about 10 9 Ω before and after 1500 cycles.

下層が無溶剤形エポキシ樹脂系、上層が水性形エポキシ樹脂系の帯電防止塗り床材(図1の実施の形態に相当)は、2000サイクルまで管理基準値を維持し、5000サイクルでも1010程度の抵抗値を示していた。 The antistatic coating floor material (corresponding to the embodiment shown in FIG. 1) whose lower layer is a solvent-free epoxy resin system and whose upper layer is a water-based epoxy resin system maintains the control standard value up to 2000 cycles, and is about 10 10 even at 5000 cycles. The resistance value was shown.

このように、下層が無溶剤形エポキシ樹脂系で、上層が水性形エポキシ樹脂系の帯電防止塗り床材(図1の実施の形態に相当)が、良好な帯電防止性能を発揮することが判明した。   Thus, it was found that the antistatic coating floor material (corresponding to the embodiment shown in FIG. 1) having a solvent-free epoxy resin system in the lower layer and an aqueous epoxy resin system in the upper layer exhibits good antistatic performance. did.

本発明は、前記実施の形態に限定されるものではなく、本発明の要旨の範囲内において種々の形態に変形可能である。   The present invention is not limited to the above-described embodiment, and can be modified into various forms within the scope of the gist of the present invention.

例えば、前記実施の形態では、2層及び3層の帯電防止塗り床構造について説明したが、これらの実施の形態に限らず、下層が無溶剤形エポキシ樹脂系で、上層が水性形エポキシ樹脂系の帯電防止塗り床材であれば、4層以上にすることも可能である。   For example, in the above-described embodiment, the antistatic coating floor structure having two layers and three layers has been described. However, the present invention is not limited to these embodiments, and the lower layer is a solvent-free epoxy resin system and the upper layer is an aqueous epoxy resin system. If it is an antistatic coating floor material, it is possible to have four or more layers.

本発明の一実施の形態にかかる帯電防止塗り床構造を示す断面図である。It is sectional drawing which shows the antistatic coating floor structure concerning one embodiment of this invention. 本発明の他の実施の形態にかかる帯電防止塗り床構造を示す断面図である。It is sectional drawing which shows the antistatic coating floor structure concerning other embodiment of this invention. 実験対象を示す図である。It is a figure which shows a test object. キャスター試験後の電気表面抵抗の変化を示す図である。It is a figure which shows the change of the electrical surface resistance after a caster test.

符号の説明Explanation of symbols

10 無溶剤形エポキシ樹脂系帯電防止塗り床材
12 水性形エポキシ樹脂系帯電防止塗り床材
14 水性形導電性プライマー
20 床基盤
DESCRIPTION OF SYMBOLS 10 Solvent-free epoxy resin type antistatic coating floor material 12 Aqueous type epoxy resin type antistatic coating floor material 14 Aqueous type conductive primer 20 Floor base

Claims (2)

床基盤上に少なくとも下層側及び上層側帯電防止塗り床材を塗布して複数層に形成する帯電防止塗り床構造であって、
前記下層側帯電防止塗り床材として、無溶剤形エポキシ樹脂系帯電防止塗り床材を用い、
前記上層側帯電防止塗り床材として、水性形エポキシ樹脂系帯電防止塗り床材を用いることを特徴とする帯電防止塗り床構造。
An antistatic coating floor structure in which at least a lower layer side and an upper layer side antistatic coating floor material are applied on a floor base to form a plurality of layers,
As the lower layer side antistatic coating flooring, a solventless epoxy resin-based antistatic coating flooring is used,
A water-based epoxy resin-based antistatic coating floor material is used as the upper layer side antistatic coating floor material.
請求項1において、
前記下層側帯電防止塗り床材と前記上層側帯電防止塗り床材との間に、水性形導電性プライマーを用いた中間層を有することを特徴とする帯電防止塗り床構造。
In claim 1,
An antistatic coating floor structure comprising an intermediate layer using an aqueous conductive primer between the lower layer side antistatic coating floor material and the upper layer side antistatic coating floor material.
JP2005216855A 2005-07-27 2005-07-27 Electrification preventive painting floor structure Withdrawn JP2007032092A (en)

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JP2005216855A JP2007032092A (en) 2005-07-27 2005-07-27 Electrification preventive painting floor structure

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JP2007032092A true JP2007032092A (en) 2007-02-08

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011195839A (en) * 2010-03-19 2011-10-06 Merck Patent Gmbh Electrically conductive floor care composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011195839A (en) * 2010-03-19 2011-10-06 Merck Patent Gmbh Electrically conductive floor care composition

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