JP2007021943A - Manufacturing method of sealing material - Google Patents

Manufacturing method of sealing material Download PDF

Info

Publication number
JP2007021943A
JP2007021943A JP2005208789A JP2005208789A JP2007021943A JP 2007021943 A JP2007021943 A JP 2007021943A JP 2005208789 A JP2005208789 A JP 2005208789A JP 2005208789 A JP2005208789 A JP 2005208789A JP 2007021943 A JP2007021943 A JP 2007021943A
Authority
JP
Japan
Prior art keywords
rubber
fluororesin
molded body
sealing material
unvulcanized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2005208789A
Other languages
Japanese (ja)
Inventor
Mitsuyasu Uchida
光泰 内田
Ryozo Iwata
良三 岩田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KAWAGUCHI SANGYO KK
Nakanishi Metal Works Co Ltd
Original Assignee
KAWAGUCHI SANGYO KK
Nakanishi Metal Works Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KAWAGUCHI SANGYO KK, Nakanishi Metal Works Co Ltd filed Critical KAWAGUCHI SANGYO KK
Priority to JP2005208789A priority Critical patent/JP2007021943A/en
Publication of JP2007021943A publication Critical patent/JP2007021943A/en
Pending legal-status Critical Current

Links

Images

Landscapes

  • Specific Sealing Or Ventilating Devices For Doors And Windows (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a manufacturing method of a sealing material capable of manufacturing a sealing material of a high quality while achieving an improved production efficiency and a reduced cost. <P>SOLUTION: The manufacturing method of the sealing material includes a process of obtaining an unvulcanized rubber shaped body by shaping an unvulcanized synthetic rubber material, a process of applying fluororesin-based coating on at least a part of the surface of the unvulcanized rubber shaped body, and a process of obtaining an elastic rubber shaped body by vulcanizing the unvulcanized rubber by heating the unvulcanized rubber shaped body on which the fluororesin-based coating is applied and forming a coating layer on the surface of the elastic rubber shaped body by heating and fixing the fluororesin-based coating. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

この発明は、弾性ゴム成形体の表面にフッ素樹脂系のコーティング層が形成された密封材の製造方法に関する。   The present invention relates to a method for manufacturing a sealing material in which a fluororesin-based coating layer is formed on the surface of an elastic rubber molded body.

建築物、車両、各種装置などの開口部を、窓、ドア、引き戸、障子などの開閉部材によって開閉するようにしたものにおいては、開閉部材と開口枠との間の隙間部分に、水密性、気密性、断熱性、防音性などを確保できるように、弾性密封材が設けられるのが通例である。この密封材は、開閉部材と開口枠とのいずれか一方の部材に設けられ、その密封材を他方の部材に摺接させることにより、両者間を密封状態に閉塞するものである。   In the case where the opening of a building, vehicle, various devices, etc. is opened and closed by an opening / closing member such as a window, door, sliding door, shoji, etc., the watertightness in the gap between the opening / closing member and the opening frame, Usually, an elastic sealing material is provided so as to ensure airtightness, heat insulation, soundproofing and the like. This sealing material is provided on any one of the opening / closing member and the opening frame, and the sealing material is slidably brought into contact with the other member, whereby the space between them is sealed.

たとえば建築物のサッシなどにおいては、開口枠の所定位置に弾性密封材を取り付けて、その密封材の一部(リップ部)を障子やドアなどの開閉部材に摺接させて、両者間を密封するようにしている。   For example, in a building sash, an elastic sealing material is attached to a predetermined position of the opening frame, and a part of the sealing material (lip part) is slidably contacted with an opening / closing member such as a shoji or a door to seal between the two. Like to do.

この種の密封材として従来より、合成ゴムなどの弾性材料をもって構成されるものが周知である。この合成ゴム製の密封材は、リップ部(摺接部)が開閉部材に摺接するものであるため、接触圧を強くすれば、密封性を向上させることができる反面、摩擦抵抗が大きくなり、開閉をスムーズに行うことができず、開閉時の操作性をスムーズに行うことが困難になる。特に密封材のリップ部を強い圧力で開閉部材に接触させたままの状態で長期にわたって放置したような場合には、密封材のリップ部が開閉部材に密着してしまい、開閉部材の操作がより一層困難になる恐れがある。   Conventionally, this type of sealing material is made of an elastic material such as synthetic rubber. Since this synthetic rubber sealing material is one in which the lip portion (sliding contact portion) is in sliding contact with the opening and closing member, if the contact pressure is increased, the sealing performance can be improved, but the frictional resistance increases. Opening and closing cannot be performed smoothly, and it becomes difficult to perform operability during opening and closing smoothly. In particular, when the lip portion of the sealing material is left in contact with the opening / closing member with a strong pressure for a long period of time, the lip portion of the sealing material adheres to the opening / closing member, and the operation of the opening / closing member is further improved. May be even more difficult.

逆に密封材の開閉部材に対する接触圧を弱くすると、開閉時の摩擦抵抗が小さくなり、開閉をスムーズに行うことができるものの、密封材と開閉部材との間に隙間が生じて、密封性が損なわれる恐れがある。   Conversely, if the contact pressure of the sealing material on the opening / closing member is weakened, the frictional resistance at the time of opening / closing is reduced, and the opening / closing can be performed smoothly. There is a risk of damage.

そこで、下記特許文献1,2に示すように、密封材のリップ部にフッ素樹脂を被覆するようにした技術が提案されている。このフッ素コートの密封材においては、リップ部を障子やドアなどの開閉部材に強く接触させようとも、摩擦抵抗が小さいため、開閉を容易に行うことができる上さらに、良好な密封性も確保することができる。
実開昭52−126642号(請求の範囲第1−3項) 特開平10−231668号(請求項5)
Therefore, as shown in Patent Documents 1 and 2 below, a technique has been proposed in which a lip portion of a sealing material is covered with a fluororesin. In this fluorine-coated sealant, the frictional resistance is small even when the lip portion is brought into strong contact with an opening / closing member such as a shoji or a door, so that it can be easily opened and closed, and a good sealing property is secured. be able to.
Japanese Utility Model Publication No. 52-126642 (claims 1-3) JP-A-10-231668 (Claim 5)

従来、上記のようにフッ素コートタイプの密封材を製造する場合、未加硫の合成ゴム材料を押出成形して、未加硫ゴム成形体を製造し、その未加硫ゴム成形体に対し、熱加硫を行って弾性ゴム製品を製造する。続いてその弾性ゴム製品にフッ素樹脂系の塗料を塗布した後、加熱によってフッ素樹脂系塗料を乾燥固化して、弾性ゴム製品の表面にフッ素樹脂系のコーティング層を形成するようにしている。   Conventionally, when producing a fluorine-coated type sealing material as described above, an unvulcanized synthetic rubber material is extruded to produce an unvulcanized rubber molded body. Elastic rubber products are manufactured by heat vulcanization. Subsequently, after applying a fluororesin-based paint to the elastic rubber product, the fluororesin-based paint is dried and solidified by heating to form a fluororesin-based coating layer on the surface of the elastic rubber product.

しかしながら、上記従来の密封材の製造方法においては、弾性ゴム製品を製造する工程と、コーティング層を形成する工程とを別々に独立して行うようにしているため、工程間での製品の移行をスムーズに行えず、生産効率が低下するとともに、コストも増大するという問題があった。さらに2つの工程を個別に行うものであるため、両工程間での共有化を全く行うことができず、一段と生産効率の低下およびコストの増大を来すという問題が発生する。   However, in the above conventional sealing material manufacturing method, the process of manufacturing the elastic rubber product and the process of forming the coating layer are performed separately and independently, so that the product is transferred between the processes. There was a problem that it could not be performed smoothly, the production efficiency was lowered, and the cost was increased. Furthermore, since the two steps are performed separately, sharing between the two steps cannot be performed at all, and there arises a problem that the production efficiency is further reduced and the cost is further increased.

また従来の密封材の製造方法では、弾性ゴム製品を製造する際の加硫時と、コーティング層を形成する際の塗料硬化時とで2回も熱を加えるものであるため、受熱量が多くなり、熱劣化(熱老化)によりゴム製品の物性が低下してしまうという問題もあった。   In addition, the conventional sealing material manufacturing method applies heat twice during vulcanization when manufacturing an elastic rubber product and during paint curing when forming a coating layer. Thus, there has been a problem that the physical properties of the rubber product are lowered due to thermal deterioration (heat aging).

さらに従来の密封材の製造方法では、熱加硫によって得られた弾性ゴム製品の表面に、ブルーミングにより配合成分が析出付着するため、その析出成分が、ゴム製品表面とコーティング層との間に介在されて、コーティング層の密着性が不十分となる。従ってコーティング層に剥離などが生じ易く、この点においても、密封材製品の品質を低下させるという問題を抱えている。   Furthermore, in the conventional method for producing a sealing material, since the compounding component is deposited by blooming on the surface of the elastic rubber product obtained by heat vulcanization, the deposited component is interposed between the rubber product surface and the coating layer. As a result, the adhesion of the coating layer becomes insufficient. Accordingly, the coating layer is likely to be peeled off, which also has a problem of reducing the quality of the sealing material product.

この発明は、上記従来技術の問題を解消し、生産効率の向上およびコストの削減を図りつつ、高品質の密封材を得ることができる密封材の製造方法を提供することを目的とする。   An object of the present invention is to provide a manufacturing method of a sealing material that can solve the above-described problems of the prior art and obtain a high-quality sealing material while improving production efficiency and reducing costs.

上記目的を達成するため、本発明は以下の構成を要旨としている。   In order to achieve the above object, the present invention is summarized as follows.

[1] 未加硫の合成ゴム材料を成形加工して未加硫ゴム成形体を得る工程と、
未加硫ゴム成形体の表面における少なくとも一部に、フッ素樹脂系塗料を塗布する工程と、
フッ素樹脂系塗料が塗布された未加硫ゴム成形体を加熱することにより、未加硫ゴムを加硫して弾性ゴム成形体を得るとともに、フッ素樹脂系塗料を加熱定着させて弾性ゴム成形体の表面にコーティング層を形成する工程と、を含むことを特徴とした密封材の製造方法。
[1] A step of molding an unvulcanized synthetic rubber material to obtain an unvulcanized rubber molded body;
Applying a fluororesin-based paint to at least a part of the surface of the unvulcanized rubber molded body;
By heating an unvulcanized rubber molded body coated with a fluororesin-based paint, an unvulcanized rubber is vulcanized to obtain an elastic rubber molded body, and the fluororesin-based paint is heated and fixed to form an elastic rubber molded body. And a step of forming a coating layer on the surface of the sealing material.

[2] フッ素樹脂系塗料として、ポリテトラフルオロエチレン(PTFE)粉末と、樹脂系バインダーと、溶剤とを含有した組成物を用いるようにした前項1に記載の密封材の製造方法。   [2] The method for producing a sealing material according to item 1 above, wherein a composition containing polytetrafluoroethylene (PTFE) powder, a resin binder and a solvent is used as the fluororesin paint.

[3] 合成ゴム材料として、エチレンプロピレンゴム(EPDM)またはクロロプレンゴム(CR)を用いるようにした前項1または2に記載の密封材の製造方法。   [3] The method for producing a sealing material according to item 1 or 2, wherein ethylene propylene rubber (EPDM) or chloroprene rubber (CR) is used as the synthetic rubber material.

発明[1]の密封材の製造方法によれば、合成ゴム加硫時の加熱工程と、フッ素樹脂系塗料硬化時の加熱工程とを1度の加熱工程で共有させるものであるため、工程数を削減できて、生産効率を向上させることができるとともに、コストを削減することができる。   According to the manufacturing method of the sealing material of the invention [1], the heating process at the time of vulcanizing the synthetic rubber and the heating process at the time of curing the fluororesin-based paint are shared by one heating process. As a result, the production efficiency can be improved and the cost can be reduced.

さらに本発明の製造方法を構成している成形工程、塗料塗布工程、および加熱工程を一連の工程で連続して行うことができるため、工程間で製品が滞ることなく、工程間の製品移行をスムーズに行うことができ、より一層、生産効率の向上およびコストの削減を図ることができる。   Furthermore, since the molding process, paint coating process, and heating process that constitute the manufacturing method of the present invention can be performed continuously in a series of processes, the product can be transferred between the processes without stagnation between the processes. This can be performed smoothly, and the production efficiency can be further improved and the cost can be reduced.

また加熱工程は1回だけで良いため、受熱量が少なくなり熱劣化が抑制され、ゴム製品として高い品質を得ることができる。   In addition, since the heating process only needs to be performed once, the amount of heat received is reduced, thermal degradation is suppressed, and high quality as a rubber product can be obtained.

さらに合成ゴムの加硫と、樹脂塗料の硬化とを並行して行うものであるため、加硫時のブルーミングによりゴム表面に配合成分が析出する前に、樹脂塗料がゴム表面に定着する。従ってゴム表面とコーティング層との間に析出成分が介在するのを防止でき、コーティング層の密着性を向上させることができ、より一層高い品質を得ることができる。   Further, since the vulcanization of the synthetic rubber and the curing of the resin coating are performed in parallel, the resin coating is fixed on the rubber surface before the compounding components are precipitated on the rubber surface by blooming during vulcanization. Accordingly, it is possible to prevent the precipitation component from interposing between the rubber surface and the coating layer, to improve the adhesion of the coating layer, and to obtain a higher quality.

発明[2][3]の密封材の製造方法によれば、上記の効果をより一層確実に得ることができる。   According to the manufacturing method of the sealing material of the invention [2] and [3], the above effect can be obtained more reliably.

図1はこの発明の実施形態である密封材の製造方法における製造工程を示すブロック図である。同図に示すように本実施形態の製造方法は、未加硫の合成ゴム材料を押出成形して未加硫ゴム成形体を得る工程(押出成形工程)と、未加硫ゴム成形体にフッ素樹脂系塗料を塗布する工程(塗料塗布工程)と、フッ素樹脂系塗料付きの未加硫ゴム成形体を、マイクロ波加熱および熱風加熱により加熱して、合成ゴムを加硫させると同時にフッ素樹脂系塗料を硬化させる工程(加熱工程)と、を含むものである。   FIG. 1 is a block diagram showing a manufacturing process in a method for manufacturing a sealing material according to an embodiment of the present invention. As shown in the figure, the manufacturing method of the present embodiment includes a process of extruding an unvulcanized synthetic rubber material to obtain an unvulcanized rubber molded body (extrusion molding process), and a fluorine in the unvulcanized rubber molded body. Applying resin-based paint (paint application process) and unvulcanized rubber molding with fluororesin-based paint heated by microwave heating and hot air heating to vulcanize synthetic rubber and at the same time fluororesin-based A step of curing the coating material (heating step).

本実施形態において、合成ゴム材料としては、エチレンプロピレンゴム(EPDM)、クロロプレンゴム(CR)、ブタジエンゴム(BR)、アクリロニトリルブタジエンゴム(NBR)、スチレンブタジエンゴム(SBR)、アクリルゴム(ACR)、ウレタンゴム(U)などを使用でき、中でも、EPDM、CR、NBR、Uを好適に用いることができる。   In the present embodiment, the synthetic rubber material includes ethylene propylene rubber (EPDM), chloroprene rubber (CR), butadiene rubber (BR), acrylonitrile butadiene rubber (NBR), styrene butadiene rubber (SBR), acrylic rubber (ACR), Urethane rubber (U) or the like can be used, and among them, EPDM, CR, NBR, and U can be preferably used.

特に住宅などの建造物における開口部と、その開口部を開閉する窓、ドア、引き戸などの開閉部材との隙間部分の密封材として用いる場合には、EPDM、CRをゴム材料として好適に用いることができる。すなわちこれらのゴム材料は、耐候性、耐オゾン性などの耐劣化性能に優れ、枠部材の密封材として、良好な物性を維持しつつ、長期間使用することができる。   EPDM and CR are preferably used as rubber materials especially when used as a sealing material for gaps between openings in buildings such as houses and opening and closing members such as windows, doors, and sliding doors that open and close the openings. Can do. That is, these rubber materials are excellent in deterioration resistance such as weather resistance and ozone resistance, and can be used for a long period of time as a sealing material for a frame member while maintaining good physical properties.

本実施形態においては、上記の合成ゴム材料に、通常用いられる添加剤、たとえば加硫剤、加硫促進剤、老化防止剤、補強剤、充填剤、可塑剤などを適宜加えて、成形用のゴム材料とする。   In the present embodiment, additives usually used such as a vulcanizing agent, a vulcanization accelerator, an anti-aging agent, a reinforcing agent, a filler, a plasticizer, and the like are appropriately added to the above-described synthetic rubber material for molding. Rubber material.

こうして得られたゴム材料を、押出成形して、所定の断面形状を有する未加硫ゴム成形体を製作する。   The rubber material thus obtained is extruded to produce an unvulcanized rubber molded body having a predetermined cross-sectional shape.

続いて、この未加硫ゴム成形体の表面における少なくとも一部、つまり開閉枠や開閉部材と摺接する部分(摺接部、リップ部など)にフッ素樹脂系の塗料を塗布する。   Subsequently, a fluororesin-based paint is applied to at least a part of the surface of the unvulcanized rubber molded body, that is, a portion (sliding contact portion, lip portion, etc.) in sliding contact with the opening / closing frame or the opening / closing member.

本実施形態において、フッ素樹脂系塗料としては、フッ素樹脂粉末と、樹脂バインダーとが溶剤中に分散状態に配合された組成物を好適に使用することができる。   In the present embodiment, as the fluororesin-based paint, a composition in which a fluororesin powder and a resin binder are blended in a solvent in a dispersed state can be suitably used.

フッ素樹脂としては、ポリテトラフルオロエチレン(PTFE)樹脂などを好適に用いることができる。   As the fluororesin, polytetrafluoroethylene (PTFE) resin or the like can be suitably used.

本実施形態においてフッ素樹脂として用いられるPTFE樹脂粉末の分子量は特に限定されるものではないが、1,000〜10,000,000のものを使用でき、好ましくは10,000〜5,000,000のものを使用するのが良い。   The molecular weight of the PTFE resin powder used as the fluororesin in this embodiment is not particularly limited, but 1,000 to 10,000,000 can be used, and preferably 10,000 to 5,000,000. Good to use.

またPTFE樹脂粉末は、溶媒に分散させた状態で塗布するものであるが、分散方法としては、界面活性剤を用いて溶媒中に分散させたり、乳化重合によって得られる分散体を使用することができる。   The PTFE resin powder is applied in a state of being dispersed in a solvent. As a dispersion method, it is possible to disperse in a solvent using a surfactant or use a dispersion obtained by emulsion polymerization. it can.

PTFE樹脂粉末は、塗料用組成物中における配合量が、固形成分で1〜50重量%、好ましくは1〜40重量%、より好ましくは1〜20重量%に設定される。すなわちPTFE樹脂粉末の配合量が少な過ぎる場合(1重量%未満の場合)には、製造した密封材に良好な摩擦低減効果を得ることが困難になる。逆にPTFE樹脂粉末の配合量が多過ぎる場合(40重量%超の場合)には、造膜性が悪く、例えばコーティング層が硬くなり過ぎて、剥離や割れが生じ易くなり、またコストも増大するので、好ましくない。   The amount of the PTFE resin powder in the coating composition is set to 1 to 50% by weight, preferably 1 to 40% by weight, more preferably 1 to 20% by weight as a solid component. That is, when the blending amount of the PTFE resin powder is too small (less than 1% by weight), it is difficult to obtain a good friction reducing effect on the produced sealing material. Conversely, when the amount of PTFE resin powder is too large (over 40% by weight), the film-forming property is poor, for example, the coating layer becomes too hard, and peeling and cracking are likely to occur, and the cost is increased. Therefore, it is not preferable.

また樹脂バインダーとしては、アクリル樹脂系、エポキシ樹脂系、ポリウレタン系、酢酸ビニル系、フタル酸系、ポリエステル系、メラミン系、アクリルウレタン系のものを用いることができる。中でもエラストマー系のもの、特にフッ素樹脂(母材)と馴染み性に優れたものを好適に用いることができる。   As the resin binder, acrylic resin, epoxy resin, polyurethane, vinyl acetate, phthalic acid, polyester, melamine, and acrylic urethane can be used. Among them, an elastomeric material, particularly a material excellent in compatibility with a fluororesin (base material) can be preferably used.

樹脂バインダーは、塗料用組成物中における配合量が、固形成分で1〜60重量%、好ましくは3〜50重量%、より好ましくは5〜45重量%に設定される。樹脂バインダー量が多過ぎたり、少な過ぎたりすると、PTFE樹脂粉末量が相対的に増減して、上記の不具合が生じる恐れがある。   The blending amount of the resin binder in the coating composition is set to 1 to 60% by weight, preferably 3 to 50% by weight, more preferably 5 to 45% by weight as a solid component. If the amount of the resin binder is too large or too small, the amount of PTFE resin powder is relatively increased or decreased, and the above-described problem may occur.

また溶剤としては、有機溶剤や水などが通常用いられる。   As the solvent, an organic solvent or water is usually used.

なお塗料用組成物には、必要に応じて、乾燥調整剤、増粘剤、防錆剤、顔料、帯電防止剤などの添加剤を配合しても良い。   In addition, you may mix | blend additives, such as a drying regulator, a thickener, a rust preventive agent, a pigment, and an antistatic agent, with a coating composition as needed.

塗料用組成物の調製方法としては、PTFE樹脂粉末および樹脂バインダーを溶剤と同時に撹拌混合して調製するようにしても良いし、樹脂バインダーにPTFE樹脂粉末を練り込んだ後、溶剤で希釈して調製するようにしても良い。   The coating composition may be prepared by stirring and mixing the PTFE resin powder and the resin binder simultaneously with the solvent, or after kneading the PTFE resin powder into the resin binder and diluting with the solvent. It may be prepared.

塗料用組成物の未加硫ゴム成形体への塗布方法は、スプレー塗り方法、刷毛塗り方法、ローラ塗り方法、浸漬方法などの従来より一般的に用いられる方法が採用されるが、中でも、スプレー塗り方法を用いる場合には、塗布領域に均一に塗布できて、均一な厚さの良好な塗膜(コーティング層)を形成することができる。   Conventionally used methods such as spray coating, brush coating, roller coating, and dipping are used as the method for applying the coating composition to the unvulcanized rubber molded body. When the coating method is used, it can be uniformly applied to the application region, and a good coating film (coating layer) having a uniform thickness can be formed.

本実施形態において、塗料が塗布された未加硫ゴム成形体に対し加熱することによって、未加硫ゴムを加硫すると同時に、塗料を加熱定着させてフッ素樹脂系のコーティング層を形成するものである。   In this embodiment, by heating the unvulcanized rubber molded body to which the paint is applied, the unvulcanized rubber is vulcanized, and at the same time, the paint is heated and fixed to form a fluororesin-based coating layer. is there.

本実施形態においては、図1に示すように加熱工程では、塗料付き未加硫ゴム成形体をUHF槽でのマイクロ波加熱と、HAV槽での熱風加熱とを順次連続して行うものである。   In this embodiment, as shown in FIG. 1, in the heating step, the unvulcanized rubber molded body with paint is successively subjected to microwave heating in the UHF tank and hot air heating in the HAV tank in sequence. .

ここで本実施形態において、加熱条件は、合成ゴム材料の加硫温度と、フッ素樹脂系塗料の硬化温度とを考慮して設定するものである。   Here, in the present embodiment, the heating conditions are set in consideration of the vulcanization temperature of the synthetic rubber material and the curing temperature of the fluororesin-based paint.

たとえば本実施形態においては、加熱温度は、合成ゴム材料の加硫温度と、フッ素樹脂系塗料の硬化温度とが共に含まれる温度範囲に設定するものである。換言すれば本実施形態においては、合成ゴム材料の加硫温度と、フッ素樹脂系塗料の硬化温度とが近似するように、合成ゴム材料およびフッ素樹脂系塗料を構成するのが良い。   For example, in this embodiment, the heating temperature is set to a temperature range in which both the vulcanization temperature of the synthetic rubber material and the curing temperature of the fluororesin-based paint are included. In other words, in the present embodiment, the synthetic rubber material and the fluororesin-based paint are preferably configured so that the vulcanization temperature of the synthetic rubber material and the curing temperature of the fluororesin-based paint are approximated.

ここで本実施形態においては、合成ゴム材料として、クロロプレンゴムを用いる場合、その加硫温度は140〜180℃であるため、その加硫温度に近似した温度で硬化するフッ素樹脂系塗料を使用するのが好ましい。具体的には、硬化温度(乾燥固化温度)が200℃以下、好ましくは140〜160℃のフッ素樹脂系塗料を用いるのが良い。なおフッ素樹脂系塗料は通常、200〜350℃で硬化するタイプのものが多いが、上記したPTFE樹脂と樹脂バインダーとからなるフッ素樹脂系塗料などは、200℃以下で上記好適な温度範囲で硬化するものであるため、この塗料の使用が望まれる。   Here, in this embodiment, when chloroprene rubber is used as the synthetic rubber material, since the vulcanization temperature is 140 to 180 ° C., a fluororesin-based paint that cures at a temperature close to the vulcanization temperature is used. Is preferred. Specifically, a fluororesin-based paint having a curing temperature (drying and solidification temperature) of 200 ° C. or lower, preferably 140 to 160 ° C. may be used. In general, fluororesin-based paints are usually of a type that cures at 200 to 350 ° C. However, the above-mentioned fluororesin-based paints composed of PTFE resin and resin binder cure at 200 ° C. or less in the above-mentioned suitable temperature range. Therefore, the use of this paint is desired.

本実施形態においては、上記塗料付きの未加硫ゴム成形体を加熱することよって、未加硫ゴムが加硫されて弾性ゴム成形体として形成され、その加硫と同時に、塗料が乾燥固化されて、弾性ゴム成形体の表面にフッ素樹脂系のコーティング層が形成される。   In this embodiment, by heating the unvulcanized rubber molded body with the paint, the unvulcanized rubber is vulcanized to form an elastic rubber molded body. At the same time as the vulcanization, the paint is dried and solidified. Thus, a fluororesin-based coating layer is formed on the surface of the elastic rubber molded body.

ここで、硬化後のコーティング層の厚さは、3〜30μmに調整するのが良く、好ましくは5〜20μm、より好ましくは7〜15μmに調整するのが良い。すなわちこの膜厚が薄過ぎる場合には、膜厚のコントロールが困難になり、広範囲にわたって均等に被膜を形成できず、十分な摩擦低減効果を得ることができない恐れがある。逆に膜厚が厚過ぎる場合には、被膜が剥がれるなどの不具合が発生する場合があり、好ましくない。   Here, the thickness of the coating layer after curing is preferably adjusted to 3 to 30 μm, preferably 5 to 20 μm, more preferably 7 to 15 μm. That is, when this film thickness is too thin, it becomes difficult to control the film thickness, and a film cannot be formed uniformly over a wide range, and there is a possibility that a sufficient friction reducing effect cannot be obtained. On the other hand, when the film thickness is too thick, problems such as peeling of the film may occur, which is not preferable.

また加硫後の弾性ゴム成形体(弾性ゴム製品)のゴム硬度は、50〜70°(JIS A硬度)に調整するのが好ましい。すなわちゴム硬度が50°未満の場合には、柔らか過ぎて、弾性変形が大きくなり、密封材として良好な密封性(シール性)を得ることが困難になる恐れがある。逆に70°超の場合には、硬くなり過ぎて、弾性変形が極端に乏しくなり、密封材として良好な密封性(シール性)を得ることが困難になることがあり、好ましくない。   Further, the rubber hardness of the elastic rubber molded body (elastic rubber product) after vulcanization is preferably adjusted to 50 to 70 ° (JIS A hardness). That is, when the rubber hardness is less than 50 °, the rubber is too soft and elastic deformation is increased, which may make it difficult to obtain a good sealing property (sealing property) as a sealing material. On the other hand, if it exceeds 70 °, it becomes too hard and the elastic deformation becomes extremely poor, and it may be difficult to obtain a good sealing property (sealing property) as a sealing material, which is not preferable.

以上説明した本実施形態における密封材の製造方法においては、合成ゴム加硫時の加熱工程と、フッ素樹脂系塗料硬化時の加熱工程とを1度の加熱工程で共有させるものであるため、これらの加熱工程を別々に行う場合と比較して、工程数を削減でき、その分、生産効率を向上させることができるとともに、コストを削減することができる。   In the manufacturing method of the sealing material in the present embodiment described above, the heating process at the time of vulcanizing the synthetic rubber and the heating process at the time of curing the fluororesin-based paint are shared by one heating process. Compared with the case where the heating process is performed separately, the number of processes can be reduced, and the production efficiency can be improved correspondingly, and the cost can be reduced.

さらに本実施形態においては、押出成形工程、塗料塗布工程、および加熱工程を一連の工程で連続して行うことができ、たとえば弾性ゴム成形体の製造工程と、フッ素樹脂系コーティング層の形成工程とをそれぞれ別々に独立させて行うものと比較して、工程間で製品が滞ることなく、工程間の製品移行をスムーズに行うことができ、より一層、生産効率の向上およびコストの削減を図ることができる。   Furthermore, in the present embodiment, the extrusion molding process, the paint application process, and the heating process can be continuously performed in a series of processes. For example, an elastic rubber molded body manufacturing process, a fluororesin-based coating layer forming process, Compared to those that are performed independently of each other, products can be smoothly transferred between processes without delaying products between processes, and production efficiency and costs can be further reduced. Can do.

また本実施形態においては、合成ゴムの加硫と、フッ素樹脂の硬化とを同時に行うものであるため、加熱は1回だけで済み、受熱量が少なくなり熱老化が抑制され、ゴム製品として良好な物性を得ることができる。   Further, in this embodiment, since the vulcanization of the synthetic rubber and the curing of the fluororesin are performed at the same time, only one heating is required, the amount of heat received is reduced, the heat aging is suppressed, and the rubber product is good. Physical properties can be obtained.

また本実施形態においては、合成ゴムを加硫させる前に、ゴム表面にコーティング層用の樹脂塗料を塗布し、合成ゴムの加硫と、樹脂塗料の硬化とを同時に行うものであるため、コーティング層に高い密着性を得ることができる。すなわち加硫時のブルーミングによりゴム表面に配合成分が析出する前に、樹脂塗料がゴム表面に定着することにより、ゴム表面に配合成分が析出するのを防止することができる。従ってコーティング層を基材に、不純物(析出成分)を介さずに直接、取り付けることができ、高い密着性を得ることができ、コーティング層の剥離などの不具合を有効に防止することができる。   In this embodiment, before the synthetic rubber is vulcanized, the resin coating for the coating layer is applied to the rubber surface, and the vulcanization of the synthetic rubber and the curing of the resin coating are performed simultaneously. High adhesion to the layer can be obtained. That is, before the compounding components are deposited on the rubber surface by blooming during vulcanization, the resin coating is fixed on the rubber surface, thereby preventing the compounding components from precipitating on the rubber surface. Therefore, the coating layer can be directly attached to the substrate without any impurities (deposited components), high adhesion can be obtained, and defects such as peeling of the coating layer can be effectively prevented.

以下、この発明に関連した実施例と、その実施例と比較対比される比較例とについて詳細に説明する。   Hereinafter, the Example relevant to this invention and the comparative example compared with the Example are described in detail.

Figure 2007021943
Figure 2007021943

<実施例1>
表1に示すように、合成ゴム材料として、クロロプレンゴム(CR)のポリマー(50重量%)に、加硫剤などの所定の添加剤(50重量%)を配合して混練し、その配合ゴム材料を押出機を用いて押出成形して、厚さ1.2mm、幅10mmの帯状(テープ状)の未加硫ゴム成形体を得た。
<Example 1>
As shown in Table 1, as a synthetic rubber material, a chloroprene rubber (CR) polymer (50% by weight) is blended with a predetermined additive (50% by weight) such as a vulcanizing agent and kneaded. The material was extruded using an extruder to obtain a band-shaped (tape-shaped) unvulcanized rubber molded body having a thickness of 1.2 mm and a width of 10 mm.

次に、この未加硫ゴム成形体の一面に、フッ素樹脂としてのPTFE樹脂粉末(固形成分で3.0重量%)と、樹脂バインダーとしてのウレタンバインダー(固形成分で10重量%)と、溶剤とが含まれるフッ素樹脂系塗料をスプレー塗りにより塗布した。なお塗布量としては、乾燥後の膜厚が10μmとなるように調整した。   Next, on one surface of this unvulcanized rubber molded body, PTFE resin powder (3.0 wt% in solid component) as a fluororesin, urethane binder (10 wt% in solid component) as a resin binder, solvent A fluorine resin paint containing and was applied by spray coating. The coating amount was adjusted so that the film thickness after drying was 10 μm.

こうして得られた塗料付きの未加硫ゴム成形体を、UHF槽でのマイクロ波加熱と、HAV槽での熱風加熱とを連続して行った。このとき、マイクロ波加熱により200℃で1分間加熱し、熱風加熱により160℃で20分間加熱した。これにより未加硫ゴムを熱加硫して弾性ゴム成形体を得ると同時に、フッ素樹脂系塗料を乾燥固化(加熱安定)させて弾性ゴム成形体の一面(表面)にフッ素樹脂系のコーティング層(被膜)を形成し、密封材サンプルを製造した。   The unvulcanized rubber molded body with paint thus obtained was subjected to continuous microwave heating in the UHF tank and hot air heating in the HAV tank. At this time, it heated at 200 degreeC by microwave heating for 1 minute, and heated at 160 degreeC for 20 minutes by hot air heating. As a result, an unvulcanized rubber is thermally vulcanized to obtain an elastic rubber molded body, and at the same time, the fluororesin-based paint is dried and solidified (heated and stabilized) to form a fluorine resin-based coating layer on one surface (surface) of the elastic rubber molded body (Coating) was formed, and a sealant sample was manufactured.

<実施例2>
表1に示すように、合成ゴム材料として、エチレンプロピレンゴム(EPDM)のポリマー(55重量%)に、添加剤(45重量%)を配合して混練し、その配合ゴム材料を押出機を用いて押出成形して、上記と同じ形状の未加硫ゴム成形体を得た。
<Example 2>
As shown in Table 1, as a synthetic rubber material, an ethylene propylene rubber (EPDM) polymer (55% by weight) is blended with an additive (45% by weight) and the compounded rubber material is used with an extruder. And extruded to obtain an unvulcanized rubber molded body having the same shape as described above.

次に、この未加硫ゴム成形体の一面に、フッ素樹脂としてのPTFE樹脂粉末(固形成分で3.0重量%)と、樹脂バインダーとしてのウレタンバインダー(固形成分で10重量%)と、溶剤とが含まれるフッ素樹脂系塗料をスプレー塗りにより塗布した。なお塗布量としては、乾燥後の膜厚が18μmとなるように調整した。   Next, on one surface of this unvulcanized rubber molded body, PTFE resin powder (3.0 wt% in solid component) as a fluororesin, urethane binder (10 wt% in solid component) as a resin binder, solvent A fluorine resin paint containing and was applied by spray coating. The coating amount was adjusted so that the film thickness after drying was 18 μm.

こうして得られた塗料付きの未加硫ゴム成形体を、マイクロ波加熱により200℃で2分間加熱し、続けて熱風加熱により160℃で25分間加熱した。これにより未加硫ゴムを熱加硫すると同時に、フッ素樹脂系塗料を硬化させて、密封材サンプルを製造した。   The thus obtained unvulcanized rubber molded body with paint was heated at 200 ° C. for 2 minutes by microwave heating, and subsequently heated at 160 ° C. for 25 minutes by hot air heating. As a result, the unvulcanized rubber was thermally vulcanized, and at the same time, the fluororesin-based paint was cured to produce a sealing material sample.

<実施例3>
表1に示すように、合成ゴム材料として、アクリロニトリルブタジエンゴム(NBR)のポリマー(45重量%)に、添加剤(55重量%)を配合して混練し、その配合ゴム材料を押出機を用いて押出成形して、上記と同じ形状の未加硫ゴム成形体を得た。
<Example 3>
As shown in Table 1, as a synthetic rubber material, an acrylonitrile butadiene rubber (NBR) polymer (45% by weight) is blended with an additive (55% by weight), and the compounded rubber material is used with an extruder. And extruded to obtain an unvulcanized rubber molded body having the same shape as described above.

次に、この未加硫ゴム成形体の一面に、フッ素樹脂としてのPTFE樹脂粉末(固形成分で3.0重量%)と、樹脂バインダーとしてのウレタンバインダー(固形成分で10重量%)と、溶剤とが含まれるフッ素樹脂系塗料をスプレー塗りにより塗布した。なお塗布量としては、乾燥後の膜厚が25μmとなるように調整した。   Next, on one surface of this unvulcanized rubber molded body, PTFE resin powder (3.0 wt% in solid component) as a fluororesin, urethane binder (10 wt% in solid component) as a resin binder, solvent A fluorine resin paint containing and was applied by spray coating. The coating amount was adjusted so that the film thickness after drying was 25 μm.

こうして得られた塗料付きの未加硫ゴム成形体を、マイクロ波加熱により200℃で1分間加熱し、続けて熱風加熱により150℃で20分間加熱した。これにより未加硫ゴムを熱加硫すると同時に、フッ素樹脂系塗料を硬化させて、密封材サンプルを製造した。   The thus obtained unvulcanized rubber molded body with paint was heated at 200 ° C. for 1 minute by microwave heating, and then heated at 150 ° C. for 20 minutes by hot air heating. As a result, the unvulcanized rubber was thermally vulcanized, and at the same time, the fluororesin-based paint was cured to produce a sealing material sample.

<実施例4>
表1に示すように、合成ゴム材料として、ウレタンゴム(U)のポリマー(65重量%)に、添加剤(35重量%)を配合して混練し、その配合ゴム材料を押出機を用いて押出成形して、上記と同じ形状の未加硫ゴム成形体を得た。
<Example 4>
As shown in Table 1, as a synthetic rubber material, an additive (35% by weight) is blended with a polymer (65% by weight) of urethane rubber (U) and kneaded. Extrusion molding was performed to obtain an unvulcanized rubber molded body having the same shape as described above.

次に、この未加硫ゴム成形体の一面に、フッ素樹脂としてのPTFE樹脂粉末(固形成分で3.0重量%)と、樹脂バインダーとしてのウレタンバインダー(固形成分で10重量%)と、溶剤とが含まれるフッ素樹脂系塗料をスプレー塗りにより塗布した。なお塗布量としては、乾燥後の膜厚が5μmとなるように調整した。   Next, on one surface of this unvulcanized rubber molded body, PTFE resin powder (3.0 wt% in solid component) as a fluororesin, urethane binder (10 wt% in solid component) as a resin binder, solvent A fluorine resin paint containing and was applied by spray coating. The coating amount was adjusted so that the film thickness after drying was 5 μm.

こうして得られた塗料付きの未加硫ゴム成形体を、マイクロ波加熱により200℃で2分間加熱し、続けて熱風加熱により160℃で30分間加熱した。これにより未加硫ゴムを熱加硫すると同時に、フッ素樹脂系塗料を硬化させて、密封材サンプルを製造した。   The thus obtained unvulcanized rubber molded body with paint was heated at 200 ° C. for 2 minutes by microwave heating, and subsequently heated at 160 ° C. for 30 minutes by hot air heating. As a result, the unvulcanized rubber was thermally vulcanized, and at the same time, the fluororesin-based paint was cured to produce a sealing material sample.

<比較例1>
実施例1と同じ組成の合成ゴム材料を用いて、同様に未加硫ゴム成形体を得た後、その未加硫ゴム成形体を、UHF槽でのマイクロ波加熱と、HAV槽での熱風加熱とを連続して行った。このとき、マイクロ波加熱により200℃で1分間加熱し、熱風加熱により160℃で20分間加熱した。これにより未加硫ゴムを熱加硫して弾性ゴム成形体を得た。
<Comparative Example 1>
Using the synthetic rubber material having the same composition as in Example 1, an unvulcanized rubber molded body was obtained in the same manner, and then the unvulcanized rubber molded body was subjected to microwave heating in the UHF tank and hot air in the HAV tank. Heating was performed continuously. At this time, it heated at 200 degreeC by microwave heating for 1 minute, and heated at 160 degreeC for 20 minutes by hot air heating. Thereby, the unvulcanized rubber was heat vulcanized to obtain an elastic rubber molded body.

続いて、上記弾性ゴム成形体の一面に、実施例1と同じ組成のフッ素樹脂系塗料をスプレー塗りによって同じ厚さに塗布した。   Subsequently, a fluororesin-based paint having the same composition as that of Example 1 was applied to one surface of the elastic rubber molded body to the same thickness by spray coating.

その後、整列し、塗料付き弾性ゴム成形体を160℃で30分間加熱して、塗料を硬化させることにより、弾性ゴム成形体の表面にフッ素樹脂系のコーティング層を形成し、密封材サンプルを製造した。   Then, the elastic rubber molding with paint is heated at 160 ° C. for 30 minutes to cure the paint, thereby forming a fluororesin-based coating layer on the surface of the elastic rubber molding and producing a sealing material sample. did.

<比較例2>
実施例2と同じ組成の合成ゴム材料を用いて、同様に未加硫ゴム成形体を得た後、その未加硫ゴム成形体を、マイクロ波加熱により200℃で2分間加熱し、続けて熱風加熱により160℃で25分間加熱した。これにより未加硫ゴムを熱加硫して弾性ゴム成形体を得た。
<Comparative example 2>
Using a synthetic rubber material having the same composition as in Example 2, an unvulcanized rubber molded body was obtained in the same manner, and then the unvulcanized rubber molded body was heated at 200 ° C. for 2 minutes by microwave heating. It heated at 160 degreeC by hot-air heating for 25 minutes. Thereby, the unvulcanized rubber was heat vulcanized to obtain an elastic rubber molded body.

続いて、上記弾性ゴム成形体の一面に、実施例2と同じ組成のフッ素樹脂系塗料をスプレー塗りによって同じ厚さに塗布した。   Subsequently, a fluororesin-based paint having the same composition as that of Example 2 was applied to one surface of the elastic rubber molded body to the same thickness by spray coating.

その後、整列し、塗料付き弾性ゴム成形体を160℃で30分間加熱して、塗料を硬化させることにより、弾性ゴム成形体の表面にフッ素樹脂系のコーティング層を形成し、密封材サンプルを製造した。   Then, the elastic rubber molding with paint is heated at 160 ° C. for 30 minutes to cure the paint, thereby forming a fluororesin-based coating layer on the surface of the elastic rubber molding and producing a sealing material sample. did.

<比較例3>
実施例3と同じ組成の合成ゴム材料を用いて、同様に未加硫ゴム成形体を得た後、その未加硫ゴム成形体を、マイクロ波加熱により200℃で1分間加熱し、続けて熱風加熱により150℃で20分間加熱した。これにより未加硫ゴムを熱加硫して弾性ゴム成形体を得た。
<Comparative Example 3>
Using the synthetic rubber material having the same composition as in Example 3, an unvulcanized rubber molded body was obtained in the same manner, and then the unvulcanized rubber molded body was heated at 200 ° C. for 1 minute by microwave heating. It heated at 150 degreeC by hot-air heating for 20 minutes. Thereby, the unvulcanized rubber was heat vulcanized to obtain an elastic rubber molded body.

続いて、上記弾性ゴム成形体の一面に、実施例3と同じ組成のフッ素樹脂系塗料をスプレー塗りによって同じ厚さに塗布した。   Subsequently, a fluororesin-based paint having the same composition as in Example 3 was applied to one surface of the elastic rubber molded body to the same thickness by spray coating.

その後、整列し、塗料付き弾性ゴム成形体を160℃で30分間加熱して、塗料を硬化させることにより、弾性ゴム成形体の表面にフッ素樹脂系のコーティング層を形成し、密封材サンプルを製造した。   Then, the elastic rubber molding with paint is heated at 160 ° C. for 30 minutes to cure the paint, thereby forming a fluororesin-based coating layer on the surface of the elastic rubber molding and producing a sealing material sample. did.

<比較例4>
実施例4と同じ組成の合成ゴム材料を用いて、同様に未加硫ゴム成形体を得た後、その未加硫ゴム成形体を、マイクロ波加熱により200℃で2分間加熱し、続けて熱風加熱により160℃で30分間加熱した。これにより未加硫ゴムを熱加硫して弾性ゴム成形体を得た。
<Comparative example 4>
Using a synthetic rubber material having the same composition as in Example 4, an unvulcanized rubber molded body was obtained in the same manner, and then the unvulcanized rubber molded body was heated at 200 ° C. for 2 minutes by microwave heating, and then Heating was performed at 160 ° C. for 30 minutes by hot air heating. Thereby, the unvulcanized rubber was heat vulcanized to obtain an elastic rubber molded body.

続いて、上記弾性ゴム成形体の一面に、実施例4と同じ組成のフッ素樹脂系塗料をスプレー塗りによって同じ厚さに塗布した。   Subsequently, a fluororesin-based paint having the same composition as that of Example 4 was applied to one surface of the elastic rubber molded body to the same thickness by spray coating.

その後、整列し、塗料付き弾性ゴム成形体を160℃で30分間加熱して、塗料を硬化させることにより、弾性ゴム成形体の表面にフッ素樹脂系のコーティング層を形成し、密封材サンプルを製造した。   Then, the elastic rubber molding with paint is heated at 160 ° C. for 30 minutes to cure the paint, thereby forming a fluororesin-based coating layer on the surface of the elastic rubber molding and producing a sealing material sample. did.

<評価>
以上のように製造された各密封材サンプルを、同じ条件で数十回折り曲げて、テープ剥離を行いコーティング層の剥離具合を観察した。そして剥離が認められなかったものを「○」、僅かに剥離が認められたものを「△」、大きい剥離が認められたものを「×」として評価した。各サンプルの評価結果を表2に示す。
<Evaluation>
Each sealing material sample manufactured as described above was bent several tens of times under the same conditions, and the tape was peeled off to observe the peeling state of the coating layer. Then, “◯” indicates that no peeling was observed, “Δ” indicates that peeling was slightly observed, and “×” indicates that large peeling was observed. The evaluation results for each sample are shown in Table 2.

Figure 2007021943
Figure 2007021943

表2から明らかなように、本発明に関連した実施例1〜4のサンプルでは、コーティング層が安定状態で確実に密着していた。特に実施例1,2のサンプルでは、コーティング層に剥離が認められず、より高い品質の密封材を得ることができた。   As is apparent from Table 2, in the samples of Examples 1 to 4 related to the present invention, the coating layer was firmly adhered in a stable state. In particular, in the samples of Examples 1 and 2, no peeling was observed in the coating layer, and a higher quality sealing material could be obtained.

また本発明の要旨を逸脱する比較例1〜4のサンプルでは、コーティング層に剥離が認められた。ここで比較例の密封材において、コーティング層の密着性が低いのは、コーティング層を形成する前に、合成ゴムを熱加硫することが要因であると考えられる。すなわち未加硫ゴムを加硫すると、ブルーミングによってゴム表面に配合成分が析出して付着する。この析出成分は、ゴム成形体の表面から確実に除去することは困難であるため、比較例においては、ゴム成形体の表面に析出成分が付着したままの状態で、フッ素樹脂系塗料を塗布硬化させてコーティング層を形成することになる。つまり基材(合成ゴム)とコーティング層との間に、不純物(析出成分)が介在されるため、コーティング層の密着性が低下してしまうと考えられる。   In the samples of Comparative Examples 1 to 4 that depart from the gist of the present invention, peeling was observed in the coating layer. Here, in the sealing material of the comparative example, the low adhesion of the coating layer is considered to be caused by heat vulcanization of the synthetic rubber before forming the coating layer. That is, when the unvulcanized rubber is vulcanized, the blended components are deposited and adhered to the rubber surface by blooming. Since this deposited component is difficult to remove reliably from the surface of the rubber molded body, in the comparative example, the fluororesin-based paint is applied and cured with the deposited component still attached to the surface of the rubber molded body. Thus, a coating layer is formed. That is, it is considered that the adhesion of the coating layer is reduced because impurities (deposited components) are interposed between the base material (synthetic rubber) and the coating layer.

これに対し、本発明に関連した実施例1〜4の密封材においては、合成ゴムを加硫させる前に、ゴム表面にコーティング層用の樹脂塗料を塗布し、合成ゴムの加硫と、樹脂塗料の硬化とを同時に行うものである。このため加硫時のブルーミングによりゴム表面に配合成分が析出する前に、樹脂塗料がゴム表面に定着することにより、基材(合成ゴム)の表面に配合成分が析出するのを防止することができる。従ってコーティング層が基材に、不純物(析出成分)を介さずに直接、取り付けられるため、高い密着性を得ることができる。   On the other hand, in the sealing materials of Examples 1 to 4 related to the present invention, before the synthetic rubber is vulcanized, a resin coating for the coating layer is applied to the rubber surface, and the synthetic rubber is vulcanized and the resin is vulcanized. The coating is cured simultaneously. For this reason, it is possible to prevent the compounding component from being deposited on the surface of the base material (synthetic rubber) by fixing the resin coating on the rubber surface before the compounding component is deposited on the rubber surface by blooming during vulcanization. it can. Accordingly, since the coating layer is directly attached to the base material without any impurities (deposited components), high adhesion can be obtained.

一方、比較例1〜4の密封材は、実施例1〜4の密封材と比較して、弾力性や柔軟性などの物性が低下しており、耐久性に問題があると考えられる。これは、比較例1〜4の密封材は、加硫時と、フッ素樹脂硬化時との2回も熱を加えるものであるため、被熱量が多くなり、熱劣化によってゴム製品の物性が低下するものと考えられる。   On the other hand, the sealing materials of Comparative Examples 1 to 4 have lower physical properties such as elasticity and flexibility than the sealing materials of Examples 1 to 4, and it is considered that there is a problem in durability. This is because the sealing materials of Comparative Examples 1 to 4 apply heat twice during vulcanization and when the fluororesin is cured, so the amount of heat increases, and the physical properties of the rubber product decrease due to thermal degradation. It is thought to do.

これに対し、実施例1〜4の密封材は、合成ゴムの加硫と、フッ素樹脂の硬化とを同時に行うものであるため、加熱工程を1回だけ行えば良く、受熱量が少なく熱劣化が抑制され、ゴム製品に良好な物性を長期間にわたって維持させることができる。   On the other hand, since the sealing materials of Examples 1 to 4 perform vulcanization of the synthetic rubber and curing of the fluororesin at the same time, the heating process only needs to be performed once, and the amount of heat received is small, resulting in thermal deterioration. Is suppressed, and good physical properties of the rubber product can be maintained over a long period of time.

この発明の実施形態である密封材の製造方法における製造工程を示すブロック図である。It is a block diagram which shows the manufacturing process in the manufacturing method of the sealing material which is embodiment of this invention.

Claims (3)

未加硫の合成ゴム材料を成形加工して未加硫ゴム成形体を得る工程と、
未加硫ゴム成形体の表面における少なくとも一部に、フッ素樹脂系塗料を塗布する工程と、
フッ素樹脂系塗料が塗布された未加硫ゴム成形体を加熱することにより、未加硫ゴムを加硫して弾性ゴム成形体を得るとともに、フッ素樹脂系塗料を加熱定着させて弾性ゴム成形体の表面にコーティング層を形成する工程と、を含むことを特徴とした密封材の製造方法。
A step of molding an unvulcanized synthetic rubber material to obtain an unvulcanized rubber molded body;
Applying a fluororesin-based paint to at least a part of the surface of the unvulcanized rubber molded body;
By heating an unvulcanized rubber molded body coated with a fluororesin-based paint, an unvulcanized rubber is vulcanized to obtain an elastic rubber molded body, and the fluororesin-based paint is heated and fixed to form an elastic rubber molded body. And a step of forming a coating layer on the surface of the sealing material.
フッ素樹脂系塗料として、ポリテトラフルオロエチレン(PTFE)粉末と、樹脂系バインダーと、溶剤とを含有した組成物を用いるようにした請求項1に記載の密封材の製造方法。   The method for producing a sealing material according to claim 1, wherein a composition containing polytetrafluoroethylene (PTFE) powder, a resin binder, and a solvent is used as the fluororesin paint. 合成ゴム材料として、エチレンプロピレンゴム(EPDM)またはクロロプレンゴム(CR)を用いるようにした請求項1または2に記載の密封材の製造方法。   The method for producing a sealing material according to claim 1 or 2, wherein ethylene-propylene rubber (EPDM) or chloroprene rubber (CR) is used as the synthetic rubber material.
JP2005208789A 2005-07-19 2005-07-19 Manufacturing method of sealing material Pending JP2007021943A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005208789A JP2007021943A (en) 2005-07-19 2005-07-19 Manufacturing method of sealing material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005208789A JP2007021943A (en) 2005-07-19 2005-07-19 Manufacturing method of sealing material

Publications (1)

Publication Number Publication Date
JP2007021943A true JP2007021943A (en) 2007-02-01

Family

ID=37783325

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005208789A Pending JP2007021943A (en) 2005-07-19 2005-07-19 Manufacturing method of sealing material

Country Status (1)

Country Link
JP (1) JP2007021943A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115042358A (en) * 2022-06-15 2022-09-13 赛博特密封科技(浙江)有限公司 Method for coating polytetrafluoroethylene sealing ring

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61225222A (en) * 1985-03-30 1986-10-07 Kinugawa Rubber Ind Co Ltd Surface treatment of polymer elastomer
JPH02198807A (en) * 1989-01-27 1990-08-07 Toyoda Gosei Co Ltd Preparation of weather strip
JPH02211278A (en) * 1989-02-13 1990-08-22 Toshiba Silicone Co Ltd Surface treatment method of high-molecular elastic substrate and surface-treated high-molecular elastic substrate
JPH02235719A (en) * 1989-03-10 1990-09-18 Toyoda Gosei Co Ltd Manufacture of foamed rubber molding
JPH04502025A (en) * 1988-11-26 1992-04-09 ヘルケル・コマンディットゲゼルシャフト・アウフ・アクチェン Anti-friction paint for elastomer parts
JPH0616044A (en) * 1992-06-30 1994-01-25 Toyoda Gosei Co Ltd Rubber laminated body
JPH079562A (en) * 1993-06-24 1995-01-13 Nok Corp Molding method for outer layer of rubber
JPH09109703A (en) * 1995-10-13 1997-04-28 Akurosu Kk Paint composition and fuel cap packing
JPH10166868A (en) * 1996-12-09 1998-06-23 Toyoda Gosei Co Ltd Weather strip for glass
JPH10231668A (en) * 1997-02-19 1998-09-02 Howa Mach Ltd Sound-roof sash
JP2002067050A (en) * 2000-08-25 2002-03-05 Mitsuboshi Belting Ltd Method for manufacturing composite layer of rubber material and fluorine-containing coating
JP2003047911A (en) * 2001-08-08 2003-02-18 Daikin Ind Ltd Fluororesin-coated product production method and fluororesin-coated product
JP2003149948A (en) * 2001-11-09 2003-05-21 Toyo Tire & Rubber Co Ltd Semiconductive seamless rubber belt, transfer drum and method for manufacturing the same
JP2004276491A (en) * 2003-03-18 2004-10-07 Mitsubishi Cable Ind Ltd Marking method of rubber product

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61225222A (en) * 1985-03-30 1986-10-07 Kinugawa Rubber Ind Co Ltd Surface treatment of polymer elastomer
JPH04502025A (en) * 1988-11-26 1992-04-09 ヘルケル・コマンディットゲゼルシャフト・アウフ・アクチェン Anti-friction paint for elastomer parts
JPH02198807A (en) * 1989-01-27 1990-08-07 Toyoda Gosei Co Ltd Preparation of weather strip
JPH02211278A (en) * 1989-02-13 1990-08-22 Toshiba Silicone Co Ltd Surface treatment method of high-molecular elastic substrate and surface-treated high-molecular elastic substrate
JPH02235719A (en) * 1989-03-10 1990-09-18 Toyoda Gosei Co Ltd Manufacture of foamed rubber molding
JPH0616044A (en) * 1992-06-30 1994-01-25 Toyoda Gosei Co Ltd Rubber laminated body
JPH079562A (en) * 1993-06-24 1995-01-13 Nok Corp Molding method for outer layer of rubber
JPH09109703A (en) * 1995-10-13 1997-04-28 Akurosu Kk Paint composition and fuel cap packing
JPH10166868A (en) * 1996-12-09 1998-06-23 Toyoda Gosei Co Ltd Weather strip for glass
JPH10231668A (en) * 1997-02-19 1998-09-02 Howa Mach Ltd Sound-roof sash
JP2002067050A (en) * 2000-08-25 2002-03-05 Mitsuboshi Belting Ltd Method for manufacturing composite layer of rubber material and fluorine-containing coating
JP2003047911A (en) * 2001-08-08 2003-02-18 Daikin Ind Ltd Fluororesin-coated product production method and fluororesin-coated product
JP2003149948A (en) * 2001-11-09 2003-05-21 Toyo Tire & Rubber Co Ltd Semiconductive seamless rubber belt, transfer drum and method for manufacturing the same
JP2004276491A (en) * 2003-03-18 2004-10-07 Mitsubishi Cable Ind Ltd Marking method of rubber product

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115042358A (en) * 2022-06-15 2022-09-13 赛博特密封科技(浙江)有限公司 Method for coating polytetrafluoroethylene sealing ring

Similar Documents

Publication Publication Date Title
CA2037953C (en) Production method for glass runs
US20060046047A1 (en) Wiper blade for windscreen wiper and method for producing the same
JP2007021943A (en) Manufacturing method of sealing material
CN112795197A (en) Methyl vinyl silicone rubber and preparation method thereof
EP2025707B1 (en) Cable extrudate and method for its manufacture and application
US20140377475A1 (en) Crosslinkable ultraviolet (uv) cured coating over flock fibers for improved performance
EP1172403A1 (en) Paint composition and its use
EP1467884B1 (en) Coating system for flexible extrusions
JP2019206634A (en) Coating composition, and automobile sealant
JP2000178439A (en) Thermoplastic elastomer composition and weather strip
JP2007137357A (en) Seal member and its molding method
DE102009000072B4 (en) Wiper blade
MX2012010924A (en) Method for producing a wiper blade.
JPS6241140B2 (en)
JP2006027431A (en) Method for manufacturing weather strip having coating film
KR20160128200A (en) automobiles weather strip manufacturing method
KR20020067195A (en) Solid coating method of weather strip sponge part by extrusion process
WO2007007187A1 (en) Moulded member and coating
JP3300577B2 (en) Rubber compound, rubber molded article and method for producing the rubber molded article
Wefringhaus Flocking of rubber profiles for the automotive industry
JPH03161329A (en) Preparation of glass run
JPH04169348A (en) Weatherstrip
JPH03240530A (en) Rubber laminate with finished film layer
US20090111941A1 (en) Extrudable and cross-linkable slip coats
EP2440606A1 (en) Method for coating an extruded section

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20070305

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20091207

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20091215

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20100210

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20100817

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20101214