JP2007016095A - Water-erasable ink composition - Google Patents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
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Abstract
Description
本発明は、筆跡が鮮明に発色し、かつ発色した筆跡を水で消去することができる水消去性インキ組成物に関する。 The present invention relates to a water erasable ink composition capable of clearly coloring handwriting and erasing the colored handwriting with water.
従来、ロイコ染料及び顕色剤を用いて、水により筆跡を消去することができる水消去性インキ組成物が種々提供されている（特許文献１〜特許文献１５）。すなわち、ロイコ染料を顕色剤で着色し、これを含むインキを用いて筆記乃至塗布した後、その筆跡に水を付着させることにより、顕色剤が水に溶解し、水に溶けない染料から顕色剤が離脱し、ロイコ染料が元の無色の構造に戻ることにより消去するインキ組成物である。 Conventionally, various water-erasable ink compositions that can erase handwriting with water using a leuco dye and a developer have been provided (Patent Documents 1 to 15). That is, after coloring or coating leuco dye with a developer and writing or coating with ink containing the leuco dye, the developer is dissolved in water by attaching water to the handwriting, and from a dye that does not dissolve in water The ink composition is erased when the developer is released and the leuco dye returns to its original colorless structure.
上記顕色剤として、各種の水溶性顕色剤が例示されており、亜鉛塩、コバルト塩、ニッケル塩等の水溶性チオシアン酸金属塩、サリチル酸亜鉛、没食子酸、ポリオキシアルキレンモノアリルモノメチルエーテル／無水マレイン酸／スチレン共重合体、ポリオキシエチレンアルキルエーテル化カルボン酸、ポリオキシエチレンアリールエーテル燐酸エステル、ポリオキシエチレンアルキルエーテル燐酸エステル、ｐ−スルホサリチル酸、Ｐ−トルエンスルホン酸、ナフタリンスルホン酸、乳酸、酒石酸、クエン酸などが挙げられる。またこのほか、水不溶性顕色剤としてビスフェノールＡ、ビスフェノールＳを例示することができる。 Examples of the color developer include various water-soluble color developers, such as water-soluble thiocyanate such as zinc salt, cobalt salt, nickel salt, zinc salicylate, gallic acid, polyoxyalkylene monoallyl monomethyl ether / Maleic anhydride / styrene copolymer, polyoxyethylene alkyl etherified carboxylic acid, polyoxyethylene aryl ether phosphate, polyoxyethylene alkyl ether phosphate, p-sulfosalicylic acid, P-toluenesulfonic acid, naphthalenesulfonic acid, lactic acid , Tartaric acid, citric acid and the like. In addition, bisphenol A and bisphenol S can be exemplified as the water-insoluble developer.
しかし、従来のこれらの水消去性インキ組成物では、筆跡を水で消去しても、多少の発色した跡が残る場合があった。 However, in these conventional water-erasable ink compositions, even when the handwriting is erased with water, some colored marks may remain.
本発明の課題は、筆跡の発色が鮮明であるとともに、この筆跡を水で消去すると、従来の様な多少の発色した跡も残らない水消去性インキ組成物を提供するところにある。 An object of the present invention is to provide a water-erasable ink composition that has clear coloration of the handwriting and that does not leave a slight coloration mark as in the prior art when the handwriting is erased with water.
上記課題を解決するため水消去後の上記発色の残跡の原因について鋭意検討した結果、水を筆跡に付着させるだけでは染料から離脱し難い一部の顕色剤がある知見を得た。かかる知見に基づき、本発明は、ロイコ染料、水溶性顕色剤、減感剤、水溶性樹脂及び有機溶剤を含む水消去性インキ組成物を採用した。そして、好ましい減感剤として、４級アンモニウム塩、ピリジニウム塩、イミダゾリウム塩、アルキルアミン・エチレンオキサイド付加物の群から選ばれる１種以上の化合物を採用した。
本請求項１の発明は、ロイコ染料、水溶性顕色剤、減感剤、水溶性樹脂及び有機溶剤を含む水消去性インキ組成物である。本請求項２の発明は、前記減感剤が、４級アンモニウム塩、ピリジニウム塩、イミダゾリウム塩、アルキルアミン・エチレンオキサイド付加物の群から選ばれる１種以上の化合物である請求項１記載の水消去性インキ組成物である。
As a result of intensive studies on the cause of the coloration residue after water erasing in order to solve the above-mentioned problems, the inventors have found that there is a part of the developer that is difficult to remove from the dye by simply attaching water to the handwriting. Based on this knowledge, the present invention employs a water-erasable ink composition containing a leuco dye, a water-soluble developer, a desensitizer, a water-soluble resin and an organic solvent. As a preferred desensitizer, one or more compounds selected from the group of quaternary ammonium salts, pyridinium salts, imidazolium salts, and alkylamine / ethylene oxide adducts were employed.
The invention of claim 1 is a water erasable ink composition comprising a leuco dye, a water-soluble developer, a desensitizer, a water-soluble resin and an organic solvent. The invention according to claim 2 is characterized in that the desensitizer is one or more compounds selected from the group of quaternary ammonium salts, pyridinium salts, imidazolium salts, and alkylamine / ethylene oxide adducts. It is a water erasable ink composition.
なお、ロイコ染料及び水溶性顕色剤に対し、前記減感剤はインキ組成物全量に対して０．２〜２０重量％、好ましくは０．５〜１０重量％、より好ましくは顕色剤０．２〜２０重量％に対して０．２〜２０重量％、さらに好適には０．５〜１０重量％含ませることが好ましい。上記減感剤を０．２〜２０重量％、好ましくは０．５〜１０重量％の量的範囲内で含有量を調節することにより、水消去性に対する補完的な消去性能が向上する。 The desensitizer is 0.2 to 20% by weight, preferably 0.5 to 10% by weight, and more preferably 0 to the leuco dye and the water-soluble developer. It is preferable to include 0.2 to 20% by weight, more preferably 0.5 to 10% by weight with respect to 2 to 20% by weight. By adjusting the content of the desensitizer within a quantitative range of 0.2 to 20% by weight, preferably 0.5 to 10% by weight, complementary erasing performance with respect to water erasability is improved.
なお、初期発色濃度を大きくするために、顕色剤としてスルホン系顕色剤、特にｐ−トルエンスルホン酸、スルホサリチル酸及びナフタレンスルホン酸の群から選ばれる１又は２以上の有機酸を用いることが好ましい。 In order to increase the initial color density, it is possible to use a sulfone developer, particularly one or more organic acids selected from the group of p-toluenesulfonic acid, sulfosalicylic acid and naphthalenesulfonic acid, as the developer. preferable.
また、本発明のインキは水溶性樹脂を含有する組成物であるため、水消去性が良好である。 Moreover, since the ink of the present invention is a composition containing a water-soluble resin, it has good water erasability.
これにより、本発明のインキ組成物を用いて筆記すると、減感剤が含まれているインキ組成物であるため、減感剤が含まれていないインキ組成物と比較して、水を筆跡に付着させたときの消去性が向上した。また、本発明の組成物は、減感剤を含んでいるが、発色している時は減感作用がなく、水を付着させた場合に減感作用を示した。
これにより、上記の原料を含むインキを筆記した後、水を含むスポンジで拭くと、従来のごとき発色の残跡も残らず、水でより消去しやすくなり、優れた水消去性を発揮することができる。
Thereby, when writing using the ink composition of the present invention, since it is an ink composition containing a desensitizer, compared to an ink composition containing no desensitizer, water is used as a handwriting. Improved erasability when adhered. Further, the composition of the present invention contains a desensitizer, but has no desensitizing action when colored, and showed a desensitizing action when water was attached.
After writing the ink containing the above raw materials and then wiping with a sponge containing water, it will be easier to erase with water without leaving a color residue like conventional, and exhibit excellent water erasability Can do.
本発明で用いられるロイコ染料としては、トリフェニルメタン系、フルオラン系、スピロピラン系、インドリルフタリド系、ローダミンラクタム系、ロイコオーラミン系などを例示することができ、特に限定されるものではない。
上記ロイコ染料は、インキ組成物全量に対して０．１〜５重量％含ませることができ、好ましい含有量は０．５〜３重量％である。上記ロイコ染料がインキ組成物全量に対して５重量％を超えるとインキ組成物に溶解することが困難であり、０．１重量％未満では発色濃度が薄く、筆記直後の筆跡の初期発色性が乏しい。
The leuco dye used in the present invention, triphenylmethane, fluoran, sp e b pin run system, indolyl phthalide, rhodamine lactam-based, can be exemplified a leuco auramine, limited It is not something.
The leuco dye can be contained in an amount of 0.1 to 5% by weight with respect to the total amount of the ink composition, and the preferred content is 0.5 to 3% by weight. If the leuco dye exceeds 5% by weight with respect to the total amount of the ink composition, it is difficult to dissolve in the ink composition. If it is less than 0.1% by weight, the color density is low, and the initial color developability of the handwriting immediately after writing is low. poor.
本発明で用いられる顕色剤は、限定されるものではなく、サリチル酸亜鉛、没食子酸、ポリオキシアルキレンモノアリルモノメチルエーテル／無水マレイン酸／スチレン共重合体、ポリオキシエチレンアルキルエーテル化カルボン酸、ポリオキシエチレンアリールエーテル燐酸エステル、ポリオキシエチレンアルキルエーテル燐酸エステル、ｐ−スルホサリチル酸、Ｐ−トルエンスルホン酸、ナフタリンスルホン酸、乳酸、酒石酸、クエン酸などの水溶性顕色剤を用いることができる。これらは１種又は２種以上を混合して用いることも可能である。 The color developer used in the present invention is not limited. Zinc salicylate, gallic acid, polyoxyalkylene monoallyl monomethyl ether / maleic anhydride / styrene copolymer, polyoxyethylene alkyl etherified carboxylic acid, polyoxyethylene Water-soluble color developers such as oxyethylene aryl ether phosphate, polyoxyethylene alkyl ether phosphate, p-sulfosalicylic acid, P-toluenesulfonic acid, naphthalenesulfonic acid, lactic acid, tartaric acid, and citric acid can be used. These may be used alone or in combination of two or more.
なお、初期発色性の点では、スルホン基を有する有機酸、中でもスルホン基を有する水溶性の有機酸が好ましい。具体的には、ｐ−トルエンスルホン酸、スルホサリチル酸、ナフタレンスルホン酸などが挙げられ、本発明では、前記水溶性顕色剤として、ｐ−トルエンスルホン酸、スルホサリチル酸及びナフタレンスルホン酸の群から選ばれる１又は２以上の有機酸を用いることが好ましい。 In terms of initial color developability, an organic acid having a sulfone group, particularly a water-soluble organic acid having a sulfone group is preferable. Specifically, p-toluenesulfonic acid, sulfosalicylic acid, naphthalenesulfonic acid and the like can be mentioned. In the present invention, the water-soluble developer is selected from the group of p-toluenesulfonic acid, sulfosalicylic acid and naphthalenesulfonic acid. It is preferable to use one or more organic acids.
上記顕色剤は、インキ組成物全量に対して、０．２〜２０重量％含ませることができ、好ましい含有量は０．５〜１０重量％である。上記顕色剤がインキ組成物全量に対して２０重量％を超えると、経時消去性が低下し、０．２重量％未満では発色濃度が薄く、筆記直後の筆跡の初期発色性が乏しい。 The developer can be contained in an amount of 0.2 to 20% by weight with respect to the total amount of the ink composition, and the preferred content is 0.5 to 10% by weight. When the developer exceeds 20% by weight with respect to the total amount of the ink composition, the erasability is deteriorated with time. When the developer is less than 0.2% by weight, the color density is low, and the initial color developability of the handwriting immediately after writing is poor.
上記顕色剤は、インキ組成物全量中、ロイコ染料０．１〜５重量％に対してそれぞれ０．２〜２０重量％含ませることが好ましい。 The developer is preferably contained in an amount of 0.2 to 20% by weight based on 0.1 to 5% by weight of the leuco dye in the total amount of the ink composition.
本発明で用いる減感剤としては、例えば脂肪族アミン塩、４級アンモニウム塩、バンザルコニウム塩、ビリジニウム塩及びイミダゾリウム塩を例示することができ、これらの群から選ばれる減感剤を含むインキ組成物が好ましい。また、ポリオキシエチレンアルキルアミンなどのアルキルアミン・エチレンオキサイド付加物が好ましい。
具体的には、塩化ラウリルトリメチルアンモニウム、ポリオキシエチレンステアリルアミン、２−クロロ−１，３−ジメチルイミダゾリニウムクロライド、塩化セチルピリジニウムが好ましい。
Examples of the desensitizer used in the present invention include aliphatic amine salts, quaternary ammonium salts, vanzarconium salts, biridinium salts and imidazolium salts, and ink compositions containing a desensitizer selected from these groups Things are preferred. Further, an alkylamine / ethylene oxide adduct such as polyoxyethylene alkylamine is preferable.
Specifically, lauryltrimethylammonium chloride, polyoxyethylene stearylamine, 2-chloro-1,3-dimethylimidazolinium chloride, and cetylpyridinium chloride are preferable.
上記減感剤は、インキ組成物全量に対して０．２〜２０重量％、好ましくは０．５〜１０重量％、より好ましくは顕色剤０．２〜２０重量％に対して０．２〜２０重量％、さらに好適には０．５〜１０重量％含ませることが好ましい。 The desensitizer is 0.2 to 20% by weight, preferably 0.5 to 10% by weight, more preferably 0.2 to 20% by weight of the developer based on the total amount of the ink composition. -20% by weight, more preferably 0.5-10% by weight.
本発明は水溶性樹脂を用いることができる。例えばポリビニルピロリドン、セルロース系樹脂などを用いることができ、具体的にはポリビニルピロリドン、ヒドロキシプロピルセルロースを好ましく用いることができる。本発明のインキ組成物にこれらの水溶性樹脂を用いて造膜することにより、筆跡中に有機溶剤が残ったときのノビを防止し、さらに樹脂そのものが水溶性であるため、水に対する消去性が向上する。 In the present invention, a water-soluble resin can be used. Such as polyvinylpyrrolidone, it can be used as the cellulose-based resin, specifically can be used preferably polyvinylpyrrolidone, a hydroxy profile pills cellulose. By forming a film using these water-soluble resins in the ink composition of the present invention, nodding when an organic solvent remains in the handwriting is prevented, and furthermore, since the resin itself is water-soluble, it is erasable to water. Will improve.
上記水溶性樹脂は、インキ組成物全量に対して１〜２０重量％含ませることができ、好ましい含有量は２〜１０重量％である。１重量％以上含有することにより、水による消去性が向上する。上記水溶性樹脂がインキ組成物全量に対して２０重量％を超えると、水により消去し難くなる。 The water-soluble resin can be contained in an amount of 1 to 20% by weight based on the total amount of the ink composition, and the preferred content is 2 to 10% by weight. By containing 1% by weight or more, erasability with water is improved. When the water-soluble resin exceeds 20% by weight based on the total amount of the ink composition, it becomes difficult to erase with water.
本発明で用いる有機溶剤としては、任意に選定できるが、ロイコ染料その他成分の溶解性や筆跡の乾燥速度を考慮して選定することが好ましい。揮発性有機溶剤が好ましい。アルコール系、セロソルブ系、グリコールエーテル系、エステル系等を例示することができる。具体的には、イソプロピルアルコール、ブタノール、プロピレングリコールモノメチルエーテルなどを用いることができる。なお、上記有機溶剤は、インキ組成物中、残りの成分（残部）含有量として配合することができる。 The organic solvent used in the present invention can be arbitrarily selected, but is preferably selected in consideration of the solubility of the leuco dye and other components and the drying speed of the handwriting. Volatile organic solvents are preferred. Examples include alcohols, cellosolves , glycol ethers, and esters. Specifically, isopropyl alcohol, butanol, propylene glycol monomethyl ether, or the like can be used. In addition, the said organic solvent can be mix | blended as remaining component (remainder) content in an ink composition.
また、湿潤剤として、ポリエチレングリコール、グリセリン、プロピレングリコールなどを配合することができる。 Moreover, polyethylene glycol, glycerin, propylene glycol, etc. can be mix | blended as a wetting agent.
下記表１に示す組成にて、ロイコ染料、顕色剤、水溶性樹脂及び減感剤を有機溶剤に添加し、攪拌溶解させて、実施例及び比較例に係るインキ組成物を得た。
In the composition shown in Table 1 below, a leuco dye, a developer, a water-soluble resin, and a desensitizer were added to an organic solvent and dissolved by stirring to obtain ink compositions according to Examples and Comparative Examples.
次に、上記実施例、比較例の各インキ組成物をポリエステル繊維束からなる中芯に充填し、マーキングペンを作成し、筆記直後の初期発色性、筆記１ヶ月後の経時発色性、筆記直後の水消去性、筆記１日後の水消去性についてそれぞれ評価した。 Next, each ink composition of the above examples and comparative examples is filled into a core made of a polyester fiber bundle to prepare a marking pen, initial color development immediately after writing, color development with time after one month of writing, immediately after writing The water erasability and the water erasability one day after writing were evaluated.
＜評価＞
（筆記直後の初期発色性）
発色の状態を目視にて確認した。
○：筆記後すぐに鮮明に発色
×：筆記後、溶剤が揮発後発色
<Evaluation>
(Initial color development immediately after writing)
The state of color development was confirmed visually.
○: Color develops immediately after writing ×: Color develops after writing and solvent volatilization
（筆記直後の水消去性）
ホーロー製のホワイトボードに筆記する。
筆記後、水を含ませた布で筆跡を消去する。
○：綺麗に消去出来る
△：筆跡の一部が残る
×：消去されない
（筆記１日後の水消去性）
筆記1日後の筆跡を、水を含ませた布で筆跡を消去する。
○：綺麗に消去出来る
△：筆跡の一部が残る
×：消去されない
(Water erasability immediately after writing)
Write on an enamel whiteboard.
After writing, erase the handwriting with a cloth soaked in water.
○: Clearly erased
Δ: Part of the handwriting remains ×: Not erased (water erasability after 1 day of writing)
Erase the handwriting one day after writing with a cloth soaked in water.
○: Clearly erased
Δ: Part of the handwriting remains ×: Not erased
表１より、減感剤を含まない比較例に対して、減感剤を含む実施例のインキはいずれも筆記後の水消去性が良好である。 From Table 1, the ink of the Example which contains a desensitizer is good in the water erasability after writing with respect to the comparative example which does not contain a desensitizer.
本発明は、水又は水を含んだスポンジや布等で筆跡を消去することができる白板用または描画シート用のインキ組成物や、マーキングペン用インキなどに用いることができる。
INDUSTRIAL APPLICABILITY The present invention can be used for a white plate or drawing sheet ink composition that can erase handwriting with water or a water-containing sponge or cloth, a marking pen ink, and the like.
Claims (6)
ｉ） ロイコ染料 ０．１〜５重量％
ｉｉ） 顕色剤 ０．２〜２０重量％
ｉｉｉ）減感剤 ０．２〜２０重量％
ｉｖ） 水溶性樹脂 １〜２０重量％
ｖ） 有機溶剤 残部 A time-erasable ink composition containing the following components based on the total amount of the ink composition.
i) 0.1 to 5% by weight of leuco dye
ii) Developer 0.2 to 20% by weight
iii) Desensitizer 0.2-20% by weight
iv) Water-soluble resin 1-20% by weight
v) Organic solvent balance
A writing instrument using the ink composition according to any one of claims 1 to 5.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005197341A JP4909536B2 (en) | 2005-07-06 | 2005-07-06 | Water erasable ink composition |
| PCT/JP2006/313269 WO2007004629A1 (en) | 2005-07-06 | 2006-07-04 | Water-erasable ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005197341A JP4909536B2 (en) | 2005-07-06 | 2005-07-06 | Water erasable ink composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007016095A true JP2007016095A (en) | 2007-01-25 |
| JP4909536B2 JP4909536B2 (en) | 2012-04-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005197341A Expired - Fee Related JP4909536B2 (en) | 2005-07-06 | 2005-07-06 | Water erasable ink composition |
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| Country | Link |
|---|---|
| JP (1) | JP4909536B2 (en) |
| WO (1) | WO2007004629A1 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007169319A (en) * | 2005-12-19 | 2007-07-05 | Shachihata Inc | Water-erasable oily ink |
| JP2011502191A (en) * | 2007-10-25 | 2011-01-20 | ジョン−ス ハン | Erasable ink composition and erasing method |
| WO2014033587A2 (en) | 2012-08-28 | 2014-03-06 | Kimberly-Clark Worldwide, Inc. | A color-changing composition and material |
| KR101879600B1 (en) * | 2016-02-18 | 2018-07-18 | 이병선 | Eco-friendly water-removable aqueous ink composition and marking pen using the same |
| KR102044165B1 (en) * | 2018-08-31 | 2019-11-13 | 이영욱 | Pesticide-preventing mask |
| CN110806387A (en) * | 2019-11-12 | 2020-02-18 | 中国刑事警察学院 | Method for judging formation time of iron tannate ink handwriting |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8697003B2 (en) | 2009-12-14 | 2014-04-15 | Kimberly-Clark Worldwide, Inc. | Aqueous-triggered color-appearing inks |
| CN102898895B (en) * | 2012-11-09 | 2014-10-29 | 天津环球磁卡股份有限公司 | Ink Capable of Developing Color in Presence of Water and Preparation Method Thereof |
| CN102964926B (en) * | 2012-11-29 | 2014-10-08 | 山西大学 | Environment-friendly degradable child colored oiled crayon and preparation method thereof |
| CN104250474A (en) * | 2014-09-17 | 2014-12-31 | 句容市给力包装制品厂 | Erasable ink and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04239069A (en) * | 1991-01-11 | 1992-08-26 | Brother Ind Ltd | Ink composition |
| JPH1017814A (en) * | 1996-07-05 | 1998-01-20 | Sanai Sekiyu Kk | Water-erasable ink and method for regenerating image holding support by erasing image containing the ink |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0485374A (en) * | 1990-07-27 | 1992-03-18 | Brother Ind Ltd | Ink composition |
| JPH10287081A (en) * | 1997-04-11 | 1998-10-27 | Mitsubishi Pencil Co Ltd | Liquid writing instrument and method for erasing its drawn line |
| JP2001311024A (en) * | 2000-02-25 | 2001-11-09 | Zebra Pen Corp | Water-based ink composition decolorable with solvent or by heating and solvent composition for decoloring and solvent applicator for decoloring |
| JP3971939B2 (en) * | 2002-02-25 | 2007-09-05 | ゼブラ株式会社 | Decolorizable water-based ink composition |
| JP4097634B2 (en) * | 2004-07-08 | 2008-06-11 | 株式会社サクラクレパス | Time-erasable ink composition |
-
2005
- 2005-07-06 JP JP2005197341A patent/JP4909536B2/en not_active Expired - Fee Related
-
2006
- 2006-07-04 WO PCT/JP2006/313269 patent/WO2007004629A1/en active Application Filing
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04239069A (en) * | 1991-01-11 | 1992-08-26 | Brother Ind Ltd | Ink composition |
| JPH1017814A (en) * | 1996-07-05 | 1998-01-20 | Sanai Sekiyu Kk | Water-erasable ink and method for regenerating image holding support by erasing image containing the ink |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007169319A (en) * | 2005-12-19 | 2007-07-05 | Shachihata Inc | Water-erasable oily ink |
| JP2011502191A (en) * | 2007-10-25 | 2011-01-20 | ジョン−ス ハン | Erasable ink composition and erasing method |
| WO2014033587A2 (en) | 2012-08-28 | 2014-03-06 | Kimberly-Clark Worldwide, Inc. | A color-changing composition and material |
| WO2014033587A3 (en) * | 2012-08-28 | 2014-04-24 | Kimberly-Clark Worldwide, Inc. | A color-changing composition and material |
| CN104780951A (en) * | 2012-08-28 | 2015-07-15 | 金伯利-克拉克环球有限公司 | A color-changing composition and material |
| EP2890413A4 (en) * | 2012-08-28 | 2016-06-08 | Kimberly Clark Co | A color-changing composition and material |
| KR101879600B1 (en) * | 2016-02-18 | 2018-07-18 | 이병선 | Eco-friendly water-removable aqueous ink composition and marking pen using the same |
| KR102044165B1 (en) * | 2018-08-31 | 2019-11-13 | 이영욱 | Pesticide-preventing mask |
| CN110806387A (en) * | 2019-11-12 | 2020-02-18 | 中国刑事警察学院 | Method for judging formation time of iron tannate ink handwriting |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007004629A1 (en) | 2007-01-11 |
| JP4909536B2 (en) | 2012-04-04 |
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