JP2006340682A - Heat-resistant chocolate and method for producing the same - Google Patents

Heat-resistant chocolate and method for producing the same Download PDF

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JP2006340682A
JP2006340682A JP2005170611A JP2005170611A JP2006340682A JP 2006340682 A JP2006340682 A JP 2006340682A JP 2005170611 A JP2005170611 A JP 2005170611A JP 2005170611 A JP2005170611 A JP 2005170611A JP 2006340682 A JP2006340682 A JP 2006340682A
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Prior art keywords
chocolate
producing
heat resistance
high humidity
kestose
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JP2005170611A
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Japanese (ja)
Inventor
Daisuke Watabe
大介 渡部
Hiroyuki Utsunomiya
洋之 宇都宮
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Meiji Seika Kaisha Ltd
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Meiji Seika Kaisha Ltd
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Priority to JP2005170611A priority Critical patent/JP2006340682A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To provide chocolate strengthened in heat resistance, and to provide a method for producing the same. <P>SOLUTION: This method for producing the chocolate comprises molding chocolate dough containing kestose followed by exposing in high humidity environment. The kestose content is preferably 50-100 wt.% of glucide in the chocolate dough, the relative humidity of the high humidity environment is preferably 68-85%, and time to expose in the high humidity environment is preferably 5-72 h. The chocolate produced by the method is also provided. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、耐熱性の向上したチョコレート及びその製造方法に関する。   The present invention relates to chocolate having improved heat resistance and a method for producing the chocolate.

フラクトオリゴ糖はショ糖のフラクトース残基に1〜3分子のフラクトースが結合した糖の混合物であり、整腸作用、ミネラル吸収促進作用、難う蝕性等の優れた生理活性を有し、且つ低カロリー、低甘味であることが知られている。この中でケストースはショ糖に1分子のフラクトースが結合した3糖類であり、いわゆる1−ケストースのことをいう。ショ糖に2分子のフラクトースが結合したニストース、3分子のフラクトースが結合した1F−フラクトフラノシルニストースと共に、ケストースはフラクトオリゴ糖としての生理活性を有する。本出願人は、既にこのケストースを利用した菓子類の特許出願を行っており、ケストースを含有したチョコレートも公知となっている。(特許文献1参照)
チョコレートは30℃前後で軟化し、その形状を保てなくなる。夏期の室内では30℃前後の温度となることもあり、この温度帯での耐熱性を少しでも向上させることができれば、チョコレートの品質向上に大きく役立つ。
特許文献2には、特定のトリグリセリドからなる、チョコレートの耐熱性付与剤及びそれを含有するチョコレートが開示されている。この耐熱性付与剤は、トランス酸系ハードバターを用いたチョコレートに限定されるものである。
特許文献3には、チョコレート等の油脂性菓子生地を吸湿させてから焼成する、耐熱性の優れた菓子の製造法が開示されている。これは、焼成することを必須としているため、焦げやボソツキ感が発生しやすく、またファットブルームが発生してしまうので実用に耐えるものではない。
特開平9−65829号公報 特開平10−165100号公報 特開2001−245594号公報
Fructooligosaccharide is a mixture of sucrose fructose residues with 1 to 3 fructose-bound sugars, and has excellent physiological activities such as intestinal regulation, mineral absorption promotion and caries resistance, and low calories. It is known to have low sweetness. Among them, kestose is a trisaccharide in which one molecule of fructose is bonded to sucrose, which is a so-called 1-kestose. Kistose has physiological activity as a fructooligosaccharide together with nystose in which two molecules of fructose are bound to sucrose and 1F-fructofuranosylnystose in which three molecules of fructose are bound. The present applicant has already filed a patent application for confectionery using this kestose, and chocolate containing kestose is also known. (See Patent Document 1)
Chocolate softens around 30 ° C and cannot keep its shape. In summer, the temperature may be around 30 ° C., and if the heat resistance in this temperature range can be improved as much as possible, it will greatly help improve the quality of chocolate.
Patent Document 2 discloses a chocolate heat resistance imparting agent comprising a specific triglyceride and a chocolate containing the same. This heat resistance imparting agent is limited to chocolate using trans acid hard butter.
Patent Document 3 discloses a method for producing a confectionery excellent in heat resistance, in which an oily confectionery dough such as chocolate is moisture-absorbed and then baked. Since it is essential to fire, this is likely to cause scorching and vomit, and a fat bloom is generated, which is not practical.
JP-A-9-65829 JP 10-165100 A JP 2001-245594 A

耐熱性の増強されたチョコレート及びその製造方法を提供することを課題とした。   An object is to provide a chocolate having enhanced heat resistance and a method for producing the chocolate.

本発明は、ケストースを含有したチョコレートを成型した後、高湿度環境に曝すと耐熱性が向上するという知見に基づくものであり、以下に示すものである。
(1) ケストースを含有したチョコレート生地を成型した後、高湿度環境に曝すことを
特徴とするチョコレートの製造方法。
(2) ケストース含有量が、チョコレート生地中の糖質の50〜100重量%である
(1)に記載のチョコレートの製造方法。
(3) 高湿度環境の相対湿度が68〜85%である(1)又は(2)に記載のチョコ
レートの製造方法。
(4) 高湿度環境に曝す時間が5〜72時間である(1)〜(3)の何れかに記載の
チョコレートの製造方法。
(5) (1)〜(4)の何れかに記載の方法により製造され、耐熱性が向上したことを
特徴とするチョコレート。
The present invention is based on the knowledge that heat resistance is improved when a chocolate containing kestose is molded and then exposed to a high humidity environment, and is shown below.
(1) A method for producing chocolate characterized by exposing a high-humidity environment to a chocolate dough containing kestose.
(2) The method for producing chocolate according to (1), wherein the kestose content is 50 to 100% by weight of the sugar in the chocolate dough.
(3) The manufacturing method of the chocolate rate as described in (1) or (2) whose relative humidity of a high humidity environment is 68 to 85%.
(4) The method for producing chocolate according to any one of (1) to (3), wherein the time of exposure to a high humidity environment is 5 to 72 hours.
(5) A chocolate produced by the method according to any one of (1) to (4) and having improved heat resistance.

本発明によれば、低カロリーであり、整腸作用、ミネラル吸収促進作用等の優れた生理活性を有するのみならず、耐熱性の向上という、物性面でも機能の向上したチョコレートを得ることができる。優れた生理活性を有するケストースの、チョコレートにおける新たな物性改善方法を見いだし、それによって耐熱性が向上したケストース入りチョコレートを提供できることとなった。   According to the present invention, it is possible to obtain a chocolate that is low in calories and has not only excellent physiological activities such as intestinal regulation and mineral absorption promotion, but also improved physical properties such as improved heat resistance. . A new method for improving physical properties of kestose having excellent physiological activity has been found, and thereby it has become possible to provide kestose-containing chocolate with improved heat resistance.

本発明でいうチョコレートとは規約ないし法規上の規定に限定されるものではなく、カカオ脂及びカカオ代用脂を使用したチョコレート、油脂加工食品、及びそれを他の可食物と組み合わせたものを含む。そして本発明のチョコレートは、板チョコレートの他、粒チョコレート、ナッツチョコレート、センタークリーム入りチョコレート、糖衣掛けチョコレート、チョコレートバー、焼き菓子等と組み合わせたチョコスナック等として利用することができる。   The chocolate referred to in the present invention is not limited to the provisions of regulations or regulations, but includes chocolates using cocoa butter and cocoa substitutes, processed oils and fats, and combinations thereof with other edible foods. And the chocolate of this invention can be utilized as chocolate snacks combined with grain chocolate, nut chocolate, chocolate with center cream, sugar-coated chocolate, chocolate bar, baked confectionery, etc. in addition to plate chocolate.

本発明のチョコレート生地は、原料混合、微粒化、コンチング等により常法通りに製造できるが、チョコレート生地中に含まれる糖質の50〜100重量%がケストースであると、本発明の方法に従う場合において耐熱性の向上に有利であり好ましい。本発明の方法においては、ケストースを含有するチョコレート生地を、モールド成型、エンロービング、エリクセン成型、パンコーティング等、チョコレートの一般的な成型方法により成型した後、高湿度環境に曝す。   The chocolate dough of the present invention can be produced in the usual way by mixing raw materials, atomization, conching, etc., but according to the method of the present invention when 50 to 100% by weight of the sugar contained in the chocolate dough is kestose Is advantageous and preferable for improving heat resistance. In the method of the present invention, a chocolate dough containing kestose is molded by a general chocolate molding method such as molding, enrobing, Erichsen molding, pan coating, etc., and then exposed to a high humidity environment.

なお本発明において湿度とは、特記しない限り相対湿度を示す。そして高湿度環境の相対湿度は68〜85%が好ましい。湿度68%未満では充分な耐熱性が得られず、逆に85%を越えるとチョコレートの表面が結露してくるので好ましくない。また、高湿度環境に曝す場合の温度は、チョコレート表面の結露や軟化を避けるために15〜28℃が好ましい。さらに曝す時間は5〜72時間が好ましい。5時間以上曝せば耐熱性が得られ、また72時間を超えて曝しても効果は変わらず、これ以上は製品完成までに要する時間が長くなるだけなので生産性が落ちることになり好ましくない。   In the present invention, humidity refers to relative humidity unless otherwise specified. The relative humidity in the high humidity environment is preferably 68 to 85%. If the humidity is less than 68%, sufficient heat resistance cannot be obtained. On the other hand, if it exceeds 85%, the chocolate surface is condensed, which is not preferable. Further, the temperature when exposed to a high humidity environment is preferably 15 to 28 ° C. in order to avoid condensation or softening on the chocolate surface. Further, the exposure time is preferably 5 to 72 hours. Heat resistance is obtained when exposed for 5 hours or more, and the effect does not change even when exposed for more than 72 hours, and more than this is not preferable because it only increases the time required to complete the product, resulting in decreased productivity.

次に高湿度環境に曝されたチョコレートはそのまま、もしくは必要に応じてさらに糖衣掛け等の二次加工を行った後、包装工程に供され最終製品となる。   Next, the chocolate exposed to the high humidity environment is used as it is or after further secondary processing such as sugar coating as required, and then subjected to a packaging process to become a final product.

本発明のチョコレートによれば、30℃前後の温度において、約1℃耐熱性が向上する。なお、本発明において耐熱性は、レオメーターにて、3mm径の円形プランジャーを用いて進入速度2cm/分で、対象チョコレートに3mm進入した時の負荷重量を測定することで評価し、該負荷重量が300g荷重となった温度を耐熱限界温度としている。
以下に実施例を示して本発明をさらに詳細に説明するが、これらは例示であって本発明はこれに限定されるものではない。
According to the chocolate of this invention, about 1 degreeC heat resistance improves in the temperature around 30 degreeC. In the present invention, the heat resistance is evaluated by measuring the load weight when entering 3 mm into the target chocolate with a rheometer using a 3 mm diameter circular plunger at an entry speed of 2 cm / min. The temperature at which the weight becomes 300 g load is defined as the heat resistant limit temperature.
The present invention will be described in more detail with reference to the following examples, but these are illustrative and the present invention is not limited thereto.

試験例1
表1の配合にて、常法により厚さ6mm、1粒5gの四角錐台状のチョコレートを作成した。
Test example 1
With the formulation shown in Table 1, a square pyramid shaped chocolate with a thickness of 6 mm and a grain size of 5 g was prepared by a conventional method.

Figure 2006340682
これらのチョコレートを27℃、湿度80%に24時間静置した。静置する前後に、30℃前後の温度帯でレオメーターNRM−2010J−CW(フドー社製)を用いて、これらのチョコレートの耐熱限界温度をもとめた。静置前後の各サンプルからもとめた耐熱限界温度を表2に示す。
Figure 2006340682
These chocolates were allowed to stand at 27 ° C. and 80% humidity for 24 hours. Before and after standing, the heat resistant limit temperature of these chocolates was determined using a rheometer NRM-2010J-CW (manufactured by Fudo) in a temperature range of about 30 ° C. Table 2 shows the heat-resistant limit temperatures obtained from the samples before and after standing.

Figure 2006340682
ケストースを含有するサンプル1〜3は、高湿度条件に静置したことで耐熱性の向上が見られた。
Figure 2006340682
Samples 1 to 3 containing kestose showed an improvement in heat resistance when left in high humidity conditions.

試験例2
試験例1のサンプル1のチョコレートを20℃にて湿度60〜90%で24時間静置した。試験例1の方法により該チョコレートの耐熱限界温度をもとめた。結果を表3に示す。
Test example 2
The chocolate of Sample 1 of Test Example 1 was allowed to stand at 20 ° C. and a humidity of 60 to 90% for 24 hours. The heat resistant limit temperature of the chocolate was determined by the method of Test Example 1. The results are shown in Table 3.

Figure 2006340682
湿度68〜85%において品質に問題なく、耐熱性の向上が見られた。
試験例3
試験例1のサンプル1のチョコレートを20℃、湿度80%下で5〜72時間静置した。試験例1の方法により該チョコレートの耐熱限界温度をもとめた。結果を表4に示す。
Figure 2006340682
There was no problem in quality at a humidity of 68 to 85%, and an improvement in heat resistance was observed.
Test example 3
The chocolate of Sample 1 of Test Example 1 was allowed to stand for 5 to 72 hours at 20 ° C. and 80% humidity. The heat resistant limit temperature of the chocolate was determined by the method of Test Example 1. The results are shown in Table 4.

Figure 2006340682
5時間以上の静置で耐熱性の向上が見られた。
Figure 2006340682
Improvement in heat resistance was observed after standing for 5 hours or more.

本発明は、チョコレートの耐熱性向上に利用でき、耐熱保形性と生理活性機能面ともに優れたチョコレートを提供できるので、チョコレート市場の活性化に大いに役立つものである。   INDUSTRIAL APPLICABILITY The present invention can be used for improving the heat resistance of chocolate and can provide a chocolate excellent in both heat-resisting shape retention and physiological activity function, and is thus very useful for the activation of the chocolate market.

Claims (5)

ケストースを含有したチョコレート生地を成型した後、高湿度環境に曝すことを特徴とするチョコレートの製造方法。   A method for producing chocolate, characterized in that a chocolate dough containing kestose is molded and then exposed to a high humidity environment. ケストース含有量が、チョコレート生地中の糖質の50〜100重量%である請求項1に記載のチョコレートの製造方法。   The method for producing chocolate according to claim 1, wherein the kestose content is 50 to 100% by weight of the sugar in the chocolate dough. 高湿度環境の相対湿度が68〜85%である請求項1又は2に記載のチョコレートの製造方法。   The method for producing chocolate according to claim 1 or 2, wherein the relative humidity of the high humidity environment is 68 to 85%. 高湿度環境に曝す時間が5〜72時間である請求項1〜3の何れか一項に記載のチョコレートの製造方法。   The method for producing chocolate according to any one of claims 1 to 3, wherein the time of exposure to a high humidity environment is 5 to 72 hours. 請求項1〜4の何れか一項に記載の方法により製造され、耐熱性が向上したことを特徴とするチョコレート。  Chocolate manufactured by the method as described in any one of Claims 1-4, and heat resistance improved.
JP2005170611A 2005-06-10 2005-06-10 Heat-resistant chocolate and method for producing the same Pending JP2006340682A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011087485A (en) * 2009-10-21 2011-05-06 Meiji Seika Kaisha Ltd Composite oily confectionery prevented from fat bloom
JP2018153148A (en) * 2017-03-21 2018-10-04 株式会社明治 Oil and fat sweets having improved sweetness
JP2019076012A (en) * 2017-10-24 2019-05-23 株式会社明治 Fat confectionery having improved flavor

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011087485A (en) * 2009-10-21 2011-05-06 Meiji Seika Kaisha Ltd Composite oily confectionery prevented from fat bloom
JP2018153148A (en) * 2017-03-21 2018-10-04 株式会社明治 Oil and fat sweets having improved sweetness
JP2019076012A (en) * 2017-10-24 2019-05-23 株式会社明治 Fat confectionery having improved flavor
JP7042055B2 (en) 2017-10-24 2022-03-25 株式会社明治 Oily confectionery with improved flavor

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