JP2006336164A - Method for dyeing fabric by using seaweeds and leaves of chestnut tree - Google Patents

Method for dyeing fabric by using seaweeds and leaves of chestnut tree Download PDF

Info

Publication number
JP2006336164A
JP2006336164A JP2005163698A JP2005163698A JP2006336164A JP 2006336164 A JP2006336164 A JP 2006336164A JP 2005163698 A JP2005163698 A JP 2005163698A JP 2005163698 A JP2005163698 A JP 2005163698A JP 2006336164 A JP2006336164 A JP 2006336164A
Authority
JP
Japan
Prior art keywords
dye
seaweeds
fabric
dyeing
leaves
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2005163698A
Other languages
Japanese (ja)
Inventor
Hisao Kimura
木村久雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KIMURA SHOJI KK
Original Assignee
KIMURA SHOJI KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KIMURA SHOJI KK filed Critical KIMURA SHOJI KK
Priority to JP2005163698A priority Critical patent/JP2006336164A/en
Publication of JP2006336164A publication Critical patent/JP2006336164A/en
Pending legal-status Critical Current

Links

Images

Landscapes

  • Coloring (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To dye fabric by extracting natural pigments that are friendly to human bodies from seaweeds and leaves of chestnut trees since adverse effect to human body are caused such as surface roughness, when the cloth dyed with chemically synthetic dye is used for underwear or the like. <P>SOLUTION: The seaweeds in nature, friendly to human body, particularly sargasso seaweed and leaves of chestnut tree are dried and crushed. Then, the crushed product is heated in soft water at 90 to 100°C for many hours and the pigment is extracted until the concentration of pigments attaining to a prescribed level. The concentrated pigment is used as a natural dye for dying fabric. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は自然界に在る海藻類および栗の葉の色素を抽出し、布地ヘ染色する事に関する。   The present invention relates to the extraction of the pigments of seaweeds and chestnut leaves that exist in nature and dyeing them on fabrics.

従来の木綿を始めセルロース繊維ヘ染色する場合は、合成染料を使用し多量の中性塩もしくは中性塩と共にアルカリを使用している。また羊毛を始め動物性蛋白繊維用染料の染色物の一部には重金属であるクロームが含まれている場合がある。特に木綿の場合、アルカリが染色物へ残留した場合は、人体の肌あれとなり、またある種の反応性染色による染色物の場合、未反応の合成染料が残留し、染料による塩酸が繊維上に生成され、人体および繊維製品へ悪影響を及ぼすことになる。そこで現在行われている反応染料による染色方法について図1を参照しながら説明する。まず精練・漂白は、木綿の原糸にたんぱく質・ペクチン質・脂肪酸・ろう質などの不純物が含まれているので、これらを取り除き、白く晒す。
工程は、精練釜に軟水・木綿・精練安定剤・苛性ソーダ・過酸化水素を入れて常圧処方の場合は90℃、高温処方の場合は120℃で30分かけて精練漂白す る。次に、染色には、反応染料が多く使用されている。反応染料は、色相が鮮明で洗濯、日光には強い染料であるが塩素に弱い欠点がある。工程は、染色釜に軟水、精練漂白した木綿をいれて40℃まで昇温して、反応染料を入れて10分後に芒硝1/10・4/10・5/10と5分おきに入れる。その後60℃まで昇温して10分後にアルカリ剤を1/10・4/10・5/10と5分おきに入れて、淡色の場合は30分、濃色の場合は50分間染色する。その後、排水して水洗する。洗浄は、染色後に未反応染料、分解染料を除去し染料堅牢度を高めるため、洗浄を行う。工程は、水洗後に一旦排水して、軟水を設定された量入れた後、洗浄剤を入れて、90℃まで昇温して15分間洗浄する。その後、排水して水洗するがこの洗浄工程が不充分の場合に布地へアルカリ等が残り人体の肌荒れが起こる。(例えば、特許文献1、2参照)
特開平7-188574 特開平1-22970
In the case of dyeing cellulose fibers such as conventional cotton, a synthetic dye is used and an alkali is used together with a large amount of neutral salt or neutral salt. Some dyeings of animal protein fiber dyes such as wool may contain heavy metal chrome. In particular, in the case of cotton, if alkali remains in the dyed product, the skin of the human body will become rough, and in the case of dyed product obtained by some kind of reactive dyeing, unreacted synthetic dye will remain and hydrochloric acid by the dye will remain on the fiber Produced and will adversely affect the human body and textiles. Therefore, a method for dyeing with reactive dyes currently used will be described with reference to FIG. First of all, in scouring and bleaching, impurities such as protein, pectin, fatty acid and wax are contained in the cotton yarn, so these are removed and exposed to white.
In the process, soft water, cotton, scouring stabilizer, caustic soda, and hydrogen peroxide are placed in a scouring pot, and scouring bleaching is performed at 90 ° C for normal pressure formulation and 120 ° C for high temperature formulation over 30 minutes. Next, reactive dyes are often used for dyeing. Reactive dyes have a clear hue and are resistant to washing and sunlight, but are weak against chlorine. In the process, put soft water and scoured and bleached cotton in a dyeing pot, raise the temperature to 40 ° C, add the reactive dye, and after 10 minutes, add it every 5 minutes, 1/10, 4/10, 5/10. Then, raise the temperature to 60 ° C, and after 10 minutes, add the alkaline agent every 5 minutes, 1/10, 4/10, 5/10, and dye for 30 minutes for light colors and 50 minutes for dark colors. Then drain and wash. Washing is performed after dyeing in order to remove unreacted dyes and decomposing dyes to increase dye fastness. In the process, the water is once drained after washing with water, and after adding a set amount of soft water, a cleaning agent is added, the temperature is raised to 90 ° C., and washing is performed for 15 minutes. After that, drain and wash with water, but when this washing process is insufficient, alkali or the like remains on the fabric, causing rough skin. (For example, see Patent Documents 1 and 2)
JP-A-7-188574 JP-A-1-22970

本発明は、合成染料で染色した布地を肌着として使用した場合、人の体質により肌あれ現象が起こり、人体へ悪影響を及ぼす。そこで人体にやさしい自然界に在る海藻や栗の葉の色素を抽出し、布地へ染色を行う。   In the present invention, when a fabric dyed with a synthetic dye is used as an undergarment, a rough skin phenomenon occurs depending on the human constitution, which adversely affects the human body. Therefore, we extract the pigments of seaweed and chestnut leaves that are natural to the human body and dye them on the fabric.

人体にやさしい自然界に在る海藻類特にホンダワラ類や栗の葉を乾燥後、粉砕加工を行ったものを軟水中に投入し90〜100℃で長時間加熱し色素を所定の濃度まで抽出したものを染料とし布地ヘ染色を行う。   Natural algae that are kind to the human body, especially hondawalas and chestnut leaves, dried and then pulverized into soft water and heated at 90-100 ° C for a long time to extract the pigment to the specified concentration Dye the fabric with the dye.

海藻類、特にホンダワラ類を抽出した染料はカルシウム、鉄、マグネシウム、が多く含有されているため人体の肌にはやさしく、汗疹、かぶれ等の肌荒れ防止効果がある。また栗の葉のせんじた液の薬効は古くから、漆かぶれ、ぎんなんかぶれ、汗疹等の肌荒れ防止に使用されている。この栗の葉を抽出した染料を布地へ染色したものを肌着として使用すれば肌荒れ防止効果がある。   Dye extracted from seaweeds, especially Honda Walla, is rich in calcium, iron, and magnesium, so it is gentle on human skin and has the effect of preventing rough skin such as sweats and rashes. In addition, the medicinal effects of chestnut leaves are used to prevent rough skin such as lacquer rashes, rashes, and rashes. If the chestnut leaf-extracted dye is used as an underwear, there is an effect of preventing rough skin.

人体にやさしい自然界に在る海藻類特にホンダワラ類や栗の葉を乾燥後、粉砕加工を行ったものを軟水中に投入し90〜100℃で長時間加熱し色素を所定の濃度まで抽出したものを染料とし布地ヘ染色を行う。   Natural algae that are kind to the human body, especially hondawalas and chestnut leaves, dried and then pulverized into soft water and heated at 90-100 ° C for a long time to extract the pigment to the specified concentration Dye the fabric with the dye.

以下、本発明の実施例を用いて説明する。まず染料の製造方法について説明する。染料の原料は、海藻類のホンダワラ又は栗の葉を使用し、採取後、表面へ付着しているゴミや不燃物を水洗にて取り除き、その後100℃の乾燥機内へ入れ完全に乾くまで乾燥する。乾燥されたホンダワラ又は栗の葉は色素の抽出を容易にする目的で、粉砕機で2mmアンダーまで粉末化を行う。次に色素の抽出方法は、粉末化された粉末100gと軟水1Lを染色機へ投入し、95℃で60分間加熱を行い色素の抽出を行い、ガーゼ等で濾し、染料液を取り出し染料とする。   The present invention will be described below with reference to examples. First, a method for producing a dye will be described. The raw material for the dye is the seaweed Honda Walla or chestnut leaves. After collection, remove dust and incombustible material adhering to the surface by washing with water, and then put it in a dryer at 100 ° C to dry it completely. . For the purpose of facilitating the extraction of the pigment, dried Honda Walla or chestnut leaves are pulverized to 2 mm or less with a pulverizer. Next, the pigment is extracted by adding 100 g of powdered powder and 1 L of soft water to a dyeing machine, heating at 95 ° C. for 60 minutes, extracting the pigment, filtering with gauze, etc., taking out the dye solution and using it as a dye .

次に染料前の前処理方法について説明する。染色物の木綿などの植物繊維はセルロースでできている為シルクやウールなどの動物繊維に比べて染色があまり良くない。本特許の特徴である前処理へ使用する大豆タンパク質を加工して繊維につけることにより、染色が大幅に改善される。大豆タンパク質の前処理工程は、大豆100gに対して水を10倍量の1000gを入れ半日ぐらい漬けておく。その後大豆を水ごとミキサーにかけて潰す。ミキサーから取り出し、ガーゼで濾して、豆乳を作る。次に、被染物が木綿10gの場合、豆乳200gを染色機に豆乳、木綿の順に投入し、30℃で30分間処理し、大豆タンパク質を木綿へ付着させる。次に染色機から取り出した木綿を脱水機で30秒間して乾燥機の温度30℃で120分間乾燥して前処理工程を終える。本前処理工程は図2を参照下さい。また、豆乳に代えカチオン化剤で綿繊維へ付けることも出来る。被染物が木綿10gの場合、カチオン化剤2g(第4級アンモニウム塩を含むポリカチオン性物質)、アルカリ4g、軟水200gを染色機へ、カチオン化剤、アルカリ、軟水、木綿、の順に投入し、80℃で30分間加熱し、カチオン化剤を木綿へ付着させた後処理液を染色機より排出する。次に被染物を中和させる為、酢酸0.2gと軟水200gを染色機へ入れ、40℃で10分間中和処理を行い、その後水洗し、前処理工程を終える。   Next, a pretreatment method before dye will be described. Plant fibers such as dyed cotton are made of cellulose and are not dyed much better than animal fibers such as silk and wool. Dyeing is greatly improved by processing soy protein used in the pretreatment characteristic of this patent and attaching it to the fiber. In the soy protein pretreatment process, 1000 grams of water is added to 100 grams of soybeans and soaked for about half a day. Then mash the soybeans with water in a mixer. Remove from the mixer and filter with gauze to make soy milk. Next, when the material to be dyed is 10 g of cotton, 200 g of soy milk is put into the dyeing machine in the order of soy milk and cotton, and treated at 30 ° C. for 30 minutes to attach the soy protein to the cotton. Next, the cotton taken out from the dyeing machine is dried with a dehydrator for 30 seconds and at a dryer temperature of 30 ° C. for 120 minutes to complete the pretreatment process. See Fig. 2 for the pretreatment process. Moreover, it can replace with soybean milk and can attach to cotton fiber with a cationizing agent. If the material to be dyed is 10 g of cotton, add 2 g of cationizing agent (polycationic substance containing a quaternary ammonium salt), 4 g of alkali and 200 g of soft water to the dyeing machine in the order of cationizing agent, alkali, soft water and cotton. After heating at 80 ° C. for 30 minutes to attach the cationizing agent to cotton, the treatment solution is discharged from the dyeing machine. Next, in order to neutralize the object to be dyed, 0.2 g of acetic acid and 200 g of soft water are put into the dyeing machine, neutralized at 40 ° C. for 10 minutes, then washed with water, and the pretreatment process is completed.

前処理を終えた木綿へ染色を行う方法について説明する。例えばらくだ色の中色程度の色へ染色する場合、木綿10gに対して染料を50ccと軟水150ccを染色機へ投入し、よく攪拌してから木綿を投入し染料機で攪拌を行う。その後徐々に昇温を行い80℃で30分間染色処理を行う。染色後染色機より木綿を取り出し、水槽で水洗を3回程度行い、脱水機で脱水し、乾燥機で100℃で20分間乾燥を行うと、人体にやさしい自然界の染料で染色された布地を提供することができる。また羊毛および絹等動物性蛋白繊維の場合は、大豆蛋白処理は必要とせず、木綿と同様の染色処理により自然界の染料で染色されて、肌にやさしい布地ができる。染色の濃度は染料の量により自由に調整できる。
A method for dyeing cotton after pretreatment will be described. For example, when dyeing to a neutral color of camel, add 50cc of dye and 150cc of soft water to 10g of cotton, stir well, add cotton and stir in the dye machine. Thereafter, the temperature is gradually raised and dyeing is performed at 80 ° C. for 30 minutes. After dyeing, the cotton is taken out from the dyeing machine, washed in the water tank about 3 times, dehydrated with a dehydrator, and dried at 100 ° C for 20 minutes with a dryer to provide a fabric dyed with natural dyes that are gentle to the human body. can do. In the case of animal protein fibers such as wool and silk, soy protein treatment is not required, and the fabric is gentle to the skin by being dyed with natural dyes by the same dyeing treatment as cotton. The concentration of dyeing can be freely adjusted by the amount of dye.

反応染料染色工程を示した説明図である。It is explanatory drawing which showed the reactive dye dyeing | staining process. 大豆(タンパク)での前処理工程を示した説明図である。It is explanatory drawing which showed the pre-processing process with soybean (protein).

Claims (3)

海藻類のホンダワラ類を乾燥し、粉砕加工したものを軟水中に投入し90〜100℃で長時間加熱し、色素を所定の濃度まで抽出した染料を布地へ染色する方法で染色前の前処理工程に大豆タンパク質を加工し繊維へ付ける方法。   Pretreatment before dyeing by drying the seaweed hondawala, pulverizing it into soft water, heating it at 90-100 ° C for a long time, and dyeing the dye extracted to the specified concentration on the fabric A method of processing soy protein and attaching it to fibers in the process. 海藻類のホンダワラ類を乾燥し、粉砕加工したものを軟水中に投入し、90〜100℃で長時間加熱し、色素を所定の濃度まで抽出した染料を布地へ染色する方法。   A method in which dried seaweeds such as seaweeds are pulverized and put into soft water, heated at 90 to 100 ° C. for a long time, and dyed with a dye extracted to a predetermined concentration on a fabric. 栗の葉を乾燥し、粉砕加工したものを軟水中に投入し、90〜100℃で長時間加熱し、色素を所定の濃度まで抽出した染料を布地へ染色する方法。




A method in which chestnut leaves are dried and pulverized, put into soft water, heated at 90 to 100 ° C. for a long time, and dyed to extract a dye having a predetermined concentration to fabric.




JP2005163698A 2005-06-03 2005-06-03 Method for dyeing fabric by using seaweeds and leaves of chestnut tree Pending JP2006336164A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005163698A JP2006336164A (en) 2005-06-03 2005-06-03 Method for dyeing fabric by using seaweeds and leaves of chestnut tree

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005163698A JP2006336164A (en) 2005-06-03 2005-06-03 Method for dyeing fabric by using seaweeds and leaves of chestnut tree

Publications (1)

Publication Number Publication Date
JP2006336164A true JP2006336164A (en) 2006-12-14

Family

ID=37556963

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005163698A Pending JP2006336164A (en) 2005-06-03 2005-06-03 Method for dyeing fabric by using seaweeds and leaves of chestnut tree

Country Status (1)

Country Link
JP (1) JP2006336164A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101183958B1 (en) 2012-06-21 2012-09-19 한밭대학교 산학협력단 Dyeing method using algae extract and textile products and algae dyed textile products
KR101239350B1 (en) 2010-12-14 2013-03-05 전라남도 Dyeing method using enteromorpha extracts
JP2018009163A (en) * 2011-06-30 2018-01-18 イー アンド ジェイ ガロ ワイネリイE. & J. Gallo Winery Natural crystalline coloring agent and production method
KR101895730B1 (en) * 2017-09-06 2018-09-05 남옥선 Manufacturing method of natural dye having excellent light-fastness using chestnut bur and dyeing method using thereof
JP2021105114A (en) * 2019-12-26 2021-07-26 和文 金子 Fabric printing ink

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101239350B1 (en) 2010-12-14 2013-03-05 전라남도 Dyeing method using enteromorpha extracts
JP2018009163A (en) * 2011-06-30 2018-01-18 イー アンド ジェイ ガロ ワイネリイE. & J. Gallo Winery Natural crystalline coloring agent and production method
KR101183958B1 (en) 2012-06-21 2012-09-19 한밭대학교 산학협력단 Dyeing method using algae extract and textile products and algae dyed textile products
KR101895730B1 (en) * 2017-09-06 2018-09-05 남옥선 Manufacturing method of natural dye having excellent light-fastness using chestnut bur and dyeing method using thereof
JP2021105114A (en) * 2019-12-26 2021-07-26 和文 金子 Fabric printing ink
JP7373844B2 (en) 2019-12-26 2023-11-06 和文 金子 ink for fabric printing

Similar Documents

Publication Publication Date Title
US8697429B2 (en) Method for dyeing a textile product using Neem and Holy basil extract
JP2008514824A (en) How to remove rubber from jute
KR100267169B1 (en) Production and dyeing method of natural dyes from the acorn and the chestnut shell, and texttile products with these dyestuffs
JP2006336164A (en) Method for dyeing fabric by using seaweeds and leaves of chestnut tree
CN107177992A (en) A kind of dyeing and finishing technology of people&#39;s cotton fabrics
Bahtiyari et al. Ozone bleaching of cotton fabrics with the aid of ultrasonic humidifier
WO2019011288A1 (en) Natural fruit-dyed colored paper tissue production method
Chattopadhyay et al. Printing of jute fabric with natural dyes extracted from manjistha, annatto and ratanjot
El-AAty et al. Investigation of the discharge printing of cotton and silk fabrics dyed with reactive and natural dyes
KR101720170B1 (en) Method for natural dyeing by using dyeing machine and the natural dyeing fabric
CN108948781A (en) The preparation method of spun gold emperor&#39;s chrysanthemum natural dye and the natural dye and colouring method prepared by this method
CN112252056A (en) Wax printing color fixing method for vegetable natural dye
CN101100795B (en) Tea dyeing technique for face towel
CN105780530A (en) Rose flower cloth dyeing technology
JP2010222722A (en) Method for dyeing cellulose fiber with natural dye
KR100321991B1 (en) A manufacturing method of loess dyes and natural textiles dyeing method by loess dyes
KR100405653B1 (en) A process of natural dyeing of a priests robe
CN105780529A (en) Cardamine hirsute cloth dyeing technology
CN105780532A (en) Process for dyeing cloth with Chinese gall
CN105780531A (en) Cymbaria dahurica cloth dyeing technology
JP3268553B2 (en) Processing method of cellulosic fiber
CN104341793A (en) Cotton cloth vegetable blue dye
JP2002371480A (en) Method for dyeing and dyed material dyed by the same
KR102477862B1 (en) Decoloration method of blue jean with eco-friendly
JP2015083729A (en) Method of scouring cotton fiber