JP2006326886A - Quick-drying wood surface treatment agent - Google Patents

Quick-drying wood surface treatment agent Download PDF

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JP2006326886A
JP2006326886A JP2005150348A JP2005150348A JP2006326886A JP 2006326886 A JP2006326886 A JP 2006326886A JP 2005150348 A JP2005150348 A JP 2005150348A JP 2005150348 A JP2005150348 A JP 2005150348A JP 2006326886 A JP2006326886 A JP 2006326886A
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wax
wood
drying
quick
surface treatment
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Kazuhiro Senda
和弘 千田
Ryuta Osada
竜太 長田
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REVANCHE KK
RICE CREATE KK
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REVANCHE KK
RICE CREATE KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a quick-drying wood surface treatment agent constituted of 100% of a natural component harmless to the human body, having a drying time faster than that of quick-drying oil such as sesame oil, linseed oil, tung oil, etc. and having a function for enhancing the aesthetic feeling of wood such as a function for making the woodgrain of wood conspicuous, a function for making the surface of wood lusterous. <P>SOLUTION: The quick-drying wood surface treatment agent to be used is compounded with 5.0 wt.% or above of animal and plant oils and fats, which are characterized in that the total amount of oleic acid and linoleic acid in fatty acids constituting the animal and plant oils and fats having a saponification number is 170-200 is 65.0% or above and the ratio of both acids is 1.0:0.6-1.1, and 40.0 wt.% or below of at least one of carnauba wax, candelilla wax, rice wax, jojoba wax, vegetable wax, shellac wax, Chinese wax, beeswax, spermaceti wax, lanoline, montan wax, ozocerite, paraffin wax and microcrystalline wax all of which are natural wax. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、建造物の木製内装又は木製家具等に使用され、乾燥性に優れる事から作業性が大幅に向上し、且つ天然成分100%の木材表面処理剤に関するものであり、更に詳しくは、木材の木目を際立たせ、更には表面の艶を出す等、木材の美感を向上させる機能を有する、天然成分100%の速乾性木材表面処理剤に関するものである。 The present invention is used for a wooden interior or wooden furniture of a building, and is related to a wood surface treatment agent having 100% natural ingredients, which is greatly improved in workability because of its excellent drying property. The present invention relates to a quick-drying wood surface treatment agent having a natural component of 100%, which has a function of improving the aesthetics of wood, such as making the wood grain stand out and further giving the surface gloss.

建造物の木製内装又は木製家具等に使用される木材には、種々の表面処理剤が使用され、木目を際立たせたり、艶を出す等の美感向上の処理が施されている。その表面処理剤には、必須成分としてアセトン、メチルエチルケトン、酢酸メチル、ジオキサン、セロソルブ等の有機溶剤が配合されている。しかし、これらの有機溶剤は、人体に対して有害であり、また揮発性が高い為、その使用に際しては作業空間に充満しない様に作業場の換気を十分に行う必要があった。また、作業時間が長い場合には、作業者の健康を損なう恐れもあった。その上、有機溶剤は木材内部に浸透し易い為、たとえ表面が乾燥していても、木材内部から長期に渡って有機溶剤が徐々に揮発していき、居住者が鼻や目、喉の刺激、頭痛を訴える等、人体に悪影響を及ぼす場合が多かった。近年、環境汚染物質に対する規制等の動向を受け、地球環境に優しい木材表面処理剤等の塗料が求められている。また、住宅・家具業界では、ホルマリンを始めとする環境ホルモンによるアレルギーや、化学物質過敏症等の所謂シックハウス症候群が社会問題になっており、この様な背景から、植物から採取した天然原料を主体とする「エコ塗料」が使用されつつある。 Various surface treatment agents are used for wood used in wooden interiors or wooden furniture of buildings, and are subjected to treatments for improving aesthetics such as making the grain stand out or glossing. In the surface treatment agent, an organic solvent such as acetone, methyl ethyl ketone, methyl acetate, dioxane, cellosolve or the like is blended as an essential component. However, these organic solvents are harmful to the human body and have high volatility. Therefore, when they are used, it is necessary to sufficiently ventilate the workplace so as not to fill the work space. In addition, when the working time is long, there is a risk of damaging the health of the worker. In addition, organic solvents easily penetrate into wood, so even if the surface is dry, organic solvents will gradually evaporate from inside the wood over a long period of time, causing residents to irritate the nose, eyes, and throat. There were many cases where the human body was adversely affected, such as complaining of headaches. In recent years, paints such as wood surface treatment agents that are friendly to the global environment have been demanded in response to regulations on environmental pollutants. In the housing and furniture industry, allergens such as formalin and other environmental hormones and so-called sick house syndrome such as chemical hypersensitivity have become social problems. Against this background, natural ingredients collected from plants are mainly used. “Eco paint” is being used.

これら「エコ塗料」として、亜麻仁油、荏胡麻油、桐油等の植物性の乾性油を主成分とするものや、これら乾性油を加工したスタンド油やボイル油、更にはオレンジから得たオレンジシトラール等の精油成分を主成分とする木材表面処理剤が開発され、使用されつつある。しかし、これらのものは、乾燥するまでの時間が2日程度と長く、作業効率的に問題があった。その上、特有の好ましくない臭気が強く、その臭気により作業者に不快感を与え、乾燥後もその臭気が残り、居住者にとっても不快感を与えるものであった。この乾燥時間の長さを解決する技術として特許文献1が報告されている。このものは、天然原料であるリグノフェノール誘導体を使用したものであるが、それを溶解させる為、アセトンや酢酸メチル等の人体に有害な有機溶剤が必須成分として配合されている。この様に現行の「エコ塗料」においても問題が山積しており、これら問題点を解消した、即ち、人体に無害な天然成分100%で、且つ乾燥性に優れる木材表面処理剤の開発が望まれていた。
特開2003−226841
These “eco-paints” include vegetable dry oils such as linseed oil, sesame oil, and tung oil, stand oil and boil oil processed from these dry oils, and orange citral obtained from orange. A wood surface treatment agent mainly composed of essential oil components is being developed and used. However, these products have a long work time of about 2 days and have a problem in work efficiency. In addition, the characteristic unpleasant odor is strong, and the odor gives an unpleasant feeling to the worker, and the odor remains even after drying, giving the resident an unpleasant feeling. Patent Document 1 has been reported as a technique for solving this length of drying time. This uses a lignophenol derivative which is a natural raw material, but in order to dissolve it, an organic solvent harmful to the human body such as acetone or methyl acetate is blended as an essential component. As described above, there are a lot of problems in the current “eco-paints”, and it is hoped to develop a wood surface treatment agent that has solved these problems, that is, 100% natural ingredients that are harmless to the human body and excellent in drying properties. It was rare.
JP 2003-226841 A

本発明が解決しようとする課題は、人体に無害な天然成分100%で構成され、且つ荏胡麻油や亜麻仁油、桐油等の乾性油より乾燥時間が短く、更には、木材の木目を際立たせたり、表面の艶を出す等、木材の美感を向上させる機能を有する速乾性木材表面処理剤を提供することである。 The problem to be solved by the present invention is composed of 100% natural ingredients that are harmless to the human body, and has a shorter drying time than dry oils such as sesame oil, linseed oil, and paulownia oil, and further makes wood grain stand out. An object of the present invention is to provide a quick-drying wood surface treatment agent having a function of improving the aesthetics of wood, such as giving the surface gloss.

本発明者らは、上記課題を解決するため鋭意検討した結果、選ばれた特定の動植物油脂を配合した速乾性木材表面処理剤が、上記課題を解決し得ることを見出し、本発明を完成するに至った。即ち本発明は、油脂の鹸化価が170〜200の範囲である動植物油脂において、その油脂を構成する脂肪酸の内、オレイン酸とリノール酸との総量が65.0%以上で、且つそのオレイン酸とリノール酸との比が1.0:0.6〜1.1である動植物油脂を5.0重量%以上、天然ワックスであるカルナバワックス、キャンデリラワックス、ライスワックス、ホホバワックス、木蝋、セラック蝋、イボタ蝋、蜜蝋、鯨蝋、ラノリン、モンタンロウ、オゾケライト、パラフィンワックス、マイクロクリスタリンワックスの1種又は2種以上を40.0重量%以下配合する速乾性木材表面処理剤に関するものである。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that a quick-drying wood surface treatment agent blended with selected specific animal and vegetable oils and fats can solve the above-mentioned problems and complete the present invention. It came to. That is, the present invention relates to animal and vegetable fats and oils having a saponification value of fats and oils in the range of 170 to 200, the total amount of oleic acid and linoleic acid among the fatty acids constituting the fats and oils is 65.0% or more More than 5.0% by weight of animal and vegetable oils and fats in which the ratio of linoleic acid is 1.0: 0.6 to 1.1, carnauba wax, candelilla wax, rice wax, jojoba wax, wood wax, shellac, which are natural waxes The present invention relates to a quick-drying wood surface treating agent containing 40.0% by weight or less of one or more of wax, ibota wax, beeswax, spermaceti, lanolin, montan wax, ozokerite, paraffin wax and microcrystalline wax.

本発明の速乾性木材表面処理剤は、人体に無害な天然成分100%で構成され、荏胡麻油や亜麻仁油、桐油等の乾性油より乾燥時間が早く、乾燥性に優れており、且つ木材の木目を際立たせたり、表面の艶を出す等、木材の美感を向上させる機能を有する速乾性木材表面処理剤である。 The quick-drying wood surface treatment agent of the present invention is composed of 100% natural ingredients that are harmless to the human body, has a faster drying time than drying oils such as sesame sesame oil, linseed oil, and paulownia oil, and has excellent drying properties. It is a quick-drying wood surface treatment agent that has the function of improving the aesthetics of wood, such as making the wood stand out and giving the surface gloss.

以下、本発明を詳細に説明する。   Hereinafter, the present invention will be described in detail.

本発明では、油脂の鹸化価が170〜200の範囲である動植物油脂において、その油脂を構成する脂肪酸の内、オレイン酸とリノール酸との総量が65.0%以上で、且つそのオレイン酸とリノール酸との比が1.0:0.6〜1.1である動植物油脂を使用する。前記条件に合致していれば特に限定はなく、その油脂の1種又は2種以上を混合して用いる。また、この条件を満たすものとしては、例えば、ごま油、ツンブ核油、マツナッツ油、ゆず種子油、落花生油等が挙げられる。これら動植物油脂の内、米油(米糠油)は、木材へ塗布した場合の乾燥性や、木目を際立たせたり、表面の艶を出す等、木材の美感を向上する機能に優れており特に好ましい。 In the present invention, in the animal and vegetable fats and oils whose fats and oils have a saponification value of 170 to 200, the total amount of oleic acid and linoleic acid among the fatty acids constituting the fats and oils is 65.0% or more, and the oleic acid and Animal and vegetable fats and oils having a ratio to linoleic acid of 1.0: 0.6 to 1.1 are used. If it matches the said conditions, there will be no limitation in particular, 1 type, or 2 or more types of the fats and oils are mixed and used. Moreover, as what satisfy | fills this condition, sesame oil, a tunbu kernel oil, a pine nut oil, a citron seed oil, peanut oil etc. are mentioned, for example. Among these animal and vegetable fats and oils, rice oil (rice bran oil) is particularly preferred because it has excellent functions to improve the aesthetics of wood, such as drying when applied to wood, and making the grain stand out and gloss on the surface. .

前記動植物油脂を、本発明の速乾性木材表面処理剤に対し、5.0重量%以上、好ましくは10.0重量%以上配合する。5.0重量%未満では、本発明が目的とする木材へ塗布した場合の乾燥性や、木目を際立たせたり、表面の艶を出す等、木材の美感を向上する機能が不十分となり好ましくない。 The said animal and vegetable fats and oils are mix | blended 5.0 weight% or more with respect to the quick-drying wood surface treating agent of this invention, Preferably 10.0 weight% or more is mix | blended. If it is less than 5.0% by weight, the drying property when applied to the target wood of the present invention, and the function of improving the aesthetics of the wood, such as making the grain stand out or giving the surface gloss, are not preferable. .

本発明の速乾性木材表面処理剤には、木材表面の保護や艶の更なる向上を図る目的で、天然ワックスであるカルナバワックス、キャンデリラワックス、ライスワックス、ホホバワックス、木蝋、セラック蝋、イボタ蝋、蜜蝋、鯨蝋、ラノリン、モンタンロウ、オゾケライト、パラフィンワックス、マイクロクリスタリンワックスの1種又は2種以上を使用する。これらの天然ワックスは特に限定はないが、カルナバワックス、キャンデリラワックス、ライスワックス、ホホバワックス等の植物性ワックスを使用した場合には、100%
植物原料で構成された速乾性木材表面処理剤を得ることが出来る。
The quick-drying wood surface treatment agent of the present invention includes natural waxes such as carnauba wax, candelilla wax, rice wax, jojoba wax, wood wax, shellac wax, and ibota for the purpose of protecting the wood surface and further improving luster. One or more of wax, beeswax, spermaceti, lanolin, montan wax, ozokerite, paraffin wax and microcrystalline wax are used. These natural waxes are not particularly limited, but when using vegetable wax such as carnauba wax, candelilla wax, rice wax, jojoba wax, etc., 100%
A quick-drying wood surface treatment agent composed of plant materials can be obtained.

前記天然ワックスを本発明の速乾性木材表面処理剤に対し、40.0重量%以下、好ましくは5〜30重量%の範囲で配合する。40重量%を超えて配合した場合、製剤が硬くなり過ぎ塗布が困難となり、作業性の面で好ましくない。 The natural wax is blended in an amount of 40.0% by weight or less, preferably 5 to 30% by weight, with respect to the quick-drying wood surface treatment agent of the present invention. If it exceeds 40% by weight, the preparation becomes too hard and application becomes difficult, which is not preferable in terms of workability.

また、乳化剤及び水等を配合し、O/W又はW/Oエマルジョンタイプの木材表面処理剤を調製し、使用した場合も、速乾性や木材表面の美感向上等、本発明が目的とする機能を十分に発揮することが出来る。 Also, when the emulsifier and water are blended to prepare and use an O / W or W / O emulsion type wood surface treatment agent, the functions intended by the present invention, such as quick-drying and improving the aesthetics of the wood surface, etc. Can be fully demonstrated.

本発明の速乾性木材表面処理剤には、本発明の機能を損なわない範囲で通常木材表面処理剤に配合される成分、例えば荏胡麻油、亜麻仁油、桐油等の乾性油や、これら乾性油を加工したスタンド油やボイル油、精油等の天然成分を配合することが出来る。 The quick-drying wood surface treatment agent of the present invention contains components usually blended in the wood surface treatment agent within a range not impairing the functions of the present invention, for example, dry oils such as sesame oil, linseed oil, and paulownia oil, and these drying oils. Natural ingredients such as processed stand oil, boil oil, and essential oil can be blended.

本発明の速乾性木材表面処理剤は、建造物の床板、壁板、柱、敷居、框、幅木、廻り縁、欄間、木製ドア、内部建具、箪笥、ベッド、机、イス等の家具、木製工芸等に使用出来、ウエス等の布に含浸させて、木材表面に塗布し擦り込み使用する。 The quick-drying wood surface treatment agent of the present invention is a building floor board, wall board, pillar, sill, fence, skirting board, surrounding edge, bam, wooden door, interior fittings, fence, bed, desk, furniture such as a chair, It can be used for wooden crafts, etc. It is impregnated with cloth such as waste cloth, applied to the surface of wood and rubbed.

以下、本発明を実施例により詳細に説明するが、本発明はこれらに限定されるものではない。 EXAMPLES Hereinafter, although an Example demonstrates this invention in detail, this invention is not limited to these.

実施例1
米糠及び米胚芽を圧搾(冷圧)採油し、油脂に通常行われる方法での脱色、脱臭等の精製を行い、鹸化価が187.0、油脂を構成する脂肪酸の内、オレイン酸とリノール酸との総量が79.0%、オレイン酸とリノール酸との比が1.0:0.9である油脂を得、この油脂100%を用い液状の速乾性木材表面処理剤を得た。
Example 1
Rice bran and rice germ are squeezed (cold pressure) and purified by decoloring, deodorizing, etc. using methods usually used for fats and oils, saponification value is 187.0, oleic acid and linoleic acid among fatty acids constituting fats and oils To obtain a liquid quick-drying wood surface treatment agent using 100% of the fats and oils in a total amount of 79.0% and a ratio of oleic acid to linoleic acid of 1.0: 0.9.

実施例2
前記液状の速乾性木材表面処理剤85部に対し、キャンデリラワックスを15部配合し、80〜90℃にて攪拌溶解後、30℃以下まで冷却し、ワックス状の速乾性木材表面処理剤を得た。
Example 2
15 parts of candelilla wax is added to 85 parts of the liquid quick-drying wood surface treatment agent, stirred and dissolved at 80 to 90 ° C., and then cooled to 30 ° C. or less to obtain a waxy quick-drying wood surface treatment agent. Obtained.

実施例3〜5
表1に示す組成の速乾性木材表面処理剤を調製し、以下の評価方法に従い評価した。その結果を表1に示す。
Examples 3-5
A quick-drying wood surface treatment agent having the composition shown in Table 1 was prepared and evaluated according to the following evaluation methods. The results are shown in Table 1.

温度23℃、湿度55%の環境下において、50cm×50cm四方(厚さ1cm)の檜板に、実施例1〜5の速乾性木材表面処理剤を15.0g塗布し、その時の「塗布のし易さ」、「塗布時及び乾燥後の臭気」、「乾燥時間」、及び「乾燥後の板表面の状態(木目の際立ち具合や艶)」について、20名のパネラーによる官能評価を行った。尚、評価点数を5点満点とし、20名の平均点を算出し、以下の基準に従い評価した。また、実施例1、2の結果も表1に示す。
<評価基準>
◎:4.5点以上(非常に良好である)
○:4.0点以上、4.5点未満(良好である)
△:3.0点以上、4.0点未満(やや悪い)
×:3.0点未満(悪い)
In an environment of a temperature of 23 ° C. and a humidity of 55%, 15.0 g of the quick-drying wood surface treatment agent of Examples 1 to 5 was applied to a 50 cm × 50 cm square (1 cm thickness) slab. Sensory evaluation was performed by 20 panelists on “ease of handling”, “odor during application and after drying”, “drying time”, and “the state of the plate surface after drying (standing condition and gloss)”. . The evaluation score was set to a maximum of 5 points, and the average score of 20 people was calculated and evaluated according to the following criteria. The results of Examples 1 and 2 are also shown in Table 1.
<Evaluation criteria>
A: 4.5 or more (very good)
○: 4.0 points or more and less than 4.5 points (good)
Δ: 3.0 points or more and less than 4.0 points (somewhat bad)
X: Less than 3.0 points (bad)

Figure 2006326886
Figure 2006326886

比較例1〜5
表2に示す組成の木材表面処理剤を調製し、上記評価方法に従い評価した。その結果を表2に示す。
Comparative Examples 1-5
Wood surface treating agents having the compositions shown in Table 2 were prepared and evaluated according to the above evaluation methods. The results are shown in Table 2.

Figure 2006326886
Figure 2006326886

実施例1〜5の速乾性木材表面処理剤は、荏胡麻油や桐油に比べ、乾燥時間が大幅に短縮化され、且つ乾燥後の板表面の木目の際立ち具合や艶においても優れていた。更には、塗布もし易く、塗布時及び乾燥後の臭気も良好であった。一方、比較例1〜5の木材表面処理剤は、評価項目の全てを満足するものではなかった。 The quick-drying wood surface treating agents of Examples 1 to 5 were drastically shortened in drying time as compared with sesame sesame oil and tung oil, and were also excellent in terms of the graininess and gloss of the plate surface after drying. Furthermore, it was easy to apply, and the odor during application and after drying was also good. On the other hand, the wood surface treatment agents of Comparative Examples 1 to 5 did not satisfy all the evaluation items.

本発明の速乾性木材表面処理剤は、人体に無害な天然成分100%で構成され、荏胡麻油や亜麻仁油、桐油等の乾性油を主成分とした従来の「エコ塗料」より、乾燥時間が大幅に短縮化されると共に、木材の木目を際立たせたり、表面の艶を出す等、木材の美感を向上させる機能を有する速乾性木材表面処理剤である。
The quick-drying wood surface treatment agent of the present invention is composed of 100% natural ingredients that are harmless to the human body, and has a drying time longer than the conventional “eco-paint” mainly composed of drying oils such as sesame oil, linseed oil, and paulownia oil. It is a quick-drying wood surface treatment agent that has a function of improving the aesthetics of wood, such as greatly shortening the wood grain and making the surface glossy.

Claims (1)

油脂の鹸化価が170〜200の範囲である動植物油脂において、その油脂を構成する脂肪酸の内、オレイン酸とリノール酸との総量が65.0%以上で、且つそのオレイン酸とリノール酸との比が1.0:0.6〜1.1である動植物油脂を5.0重量%以上、天然ワックスであるカルナバワックス、キャンデリラワックス、ライスワックス、ホホバワックス、木蝋、セラック蝋、イボタ蝋、蜜蝋、鯨蝋、ラノリン、モンタンロウ、オゾケライト、パラフィンワックス、マイクロクリスタリンワックスの1種又は2種以上を40.0重量%以下配合する速乾性木材表面処理剤。
In animal and vegetable fats and oils whose saponification value is in the range of 170 to 200, the total amount of oleic acid and linoleic acid among the fatty acids constituting the fat is 65.0% or more, and the oleic acid and linoleic acid More than 5.0% by weight of animal and vegetable oils and fats in a ratio of 1.0: 0.6 to 1.1, carnauba wax, candelilla wax, rice wax, jojoba wax, wood wax, shellac wax, ibota wax, A quick-drying wood surface treatment agent containing 40.0% by weight or less of one or more of beeswax, spermaceti, lanolin, montan wax, ozokerite, paraffin wax, and microcrystalline wax.
JP2005150348A 2005-05-24 2005-05-24 Quick-drying wood surface treatment agent Pending JP2006326886A (en)

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Cited By (10)

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JP2008231260A (en) * 2007-03-20 2008-10-02 Able Engineering Kk Water-based coating and method for producing the same
JP2008297413A (en) * 2007-05-30 2008-12-11 Washin Paint Kk Water-based coating
JP2009148914A (en) * 2007-12-19 2009-07-09 Sumitomo Forestry Co Ltd Resin composition for lumber processing
JP2010043141A (en) * 2008-08-08 2010-02-25 Sumitomo Forestry Co Ltd Coating for wood
CN104290158A (en) * 2014-10-09 2015-01-21 苏州市相城区阳澄湖镇工耕堂家具工作室 Wax cooking process for dehydrating rosewood boards
JP2015203059A (en) * 2014-04-14 2015-11-16 太田油脂株式会社 Combined cleaner and wax composition
CN106945141A (en) * 2017-03-28 2017-07-14 安徽中煦环保新材料科技有限公司 Environmentally friendly conserving material of a kind of Wood craft and preparation method thereof
CN109849135A (en) * 2019-01-12 2019-06-07 安徽泓森高科林业股份有限公司 A kind of simple and easy method of the fresh juggle sample anti-chap of locust tree
CN110283530A (en) * 2019-07-04 2019-09-27 深圳市迪凯隆科技有限公司 The resistance to boiling hot property hard wood wax oil of the pure erasing of Diamond Search, production method and application method
KR20210084959A (en) * 2019-12-30 2021-07-08 주식회사 손끝 Beeswax cream for wood coating and method for preparing thereof

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008231260A (en) * 2007-03-20 2008-10-02 Able Engineering Kk Water-based coating and method for producing the same
JP2008297413A (en) * 2007-05-30 2008-12-11 Washin Paint Kk Water-based coating
JP2009148914A (en) * 2007-12-19 2009-07-09 Sumitomo Forestry Co Ltd Resin composition for lumber processing
JP2010043141A (en) * 2008-08-08 2010-02-25 Sumitomo Forestry Co Ltd Coating for wood
JP2015203059A (en) * 2014-04-14 2015-11-16 太田油脂株式会社 Combined cleaner and wax composition
CN104290158A (en) * 2014-10-09 2015-01-21 苏州市相城区阳澄湖镇工耕堂家具工作室 Wax cooking process for dehydrating rosewood boards
CN106945141A (en) * 2017-03-28 2017-07-14 安徽中煦环保新材料科技有限公司 Environmentally friendly conserving material of a kind of Wood craft and preparation method thereof
CN109849135A (en) * 2019-01-12 2019-06-07 安徽泓森高科林业股份有限公司 A kind of simple and easy method of the fresh juggle sample anti-chap of locust tree
CN110283530A (en) * 2019-07-04 2019-09-27 深圳市迪凯隆科技有限公司 The resistance to boiling hot property hard wood wax oil of the pure erasing of Diamond Search, production method and application method
KR20210084959A (en) * 2019-12-30 2021-07-08 주식회사 손끝 Beeswax cream for wood coating and method for preparing thereof
KR102340177B1 (en) 2019-12-30 2021-12-17 주식회사 손끝 Beeswax cream for wood coating and method for preparing thereof

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