JP2006312243A - Precoated aluminum alloy plate excellent in radiation properties, scratch resistance and conductivity - Google Patents

Precoated aluminum alloy plate excellent in radiation properties, scratch resistance and conductivity Download PDF

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JP2006312243A
JP2006312243A JP2005134946A JP2005134946A JP2006312243A JP 2006312243 A JP2006312243 A JP 2006312243A JP 2005134946 A JP2005134946 A JP 2005134946A JP 2005134946 A JP2005134946 A JP 2005134946A JP 2006312243 A JP2006312243 A JP 2006312243A
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coating film
aluminum alloy
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JP4681345B2 (en
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Takanori Michiki
隆徳 道木
Kazuhiro Hosomi
和弘 細見
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Sumitomo Light Metal Industries Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a double-side precoated aluminum alloy plate excellent in press moldability and radiation properties. <P>SOLUTION: The precoated aluminum alloy plate is composed of: a substrate 10 comprising an Al-Mg-Cu type aluminum alloy plate; the lubricating coating film 2 formed on one side of the substrate 10; and the radiant coating film 3 formed on the other surface of the substrate 10. The lubricating coating film 2 is formed by coating one side of the substrate 10 with a first organic resin coating containing inner wax and curing the coating layer on the substrate 10. The radiant coating film 3 is formed by coating the other side of the substrate 10 with a second organic resin coating containing a radiant substance 35, which comprises at least one kind of a substance among titanium oxide, carbon black, silica and zirconium oxide, and by curing the coating layer on the substrate 10. It is preferable to add at least one kind of the radiant substance among titanium oxide, carbon black, silica and zirconium oxide to the lubricating coating film 2. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、プレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板とそのプレス加工方法に関する。特に、パソコン、CD−ROMドライブ、PDP(プラズマディスプレイパネル)バックパネルなどの筐体、ハイブリッド自動車や電気自動車のインバーター及びECUの筐体、あるいは、電池ケース等に好適に採用され、優れた放熱効果を実現しうる一方、プレス加工時において、塗膜割れや塗膜剥離の発生が有利に防止され、きわめて優れた成形性を実現する両面プレコートアルミニウム合金板に関する。   The present invention relates to a double-sided precoated aluminum alloy plate excellent in press formability and heat dissipation and a press working method thereof. In particular, it is suitable for housings such as personal computers, CD-ROM drives, and PDP (plasma display panel) back panels, inverters and ECU housings for hybrid and electric vehicles, and battery cases. On the other hand, the present invention relates to a double-sided pre-coated aluminum alloy sheet that advantageously prevents the occurrence of coating film cracking and coating film peeling during press working and realizes extremely excellent formability.

電子機器の高機能化、高性能化に伴い、電子部品周辺で発生する熱量が増大する傾向にあり、電子部品筐体内部からの熱の放出対策が課題となっている。一方で、小型化、省スペース化の要求から、従来から用いられているファン付きヒートシンクの採用も現実的ではない。
また、電子機器の小型化、軽量化及び形状の複雑化から、高強度のアルミニウム合金を用いながらも優れたプレス加工性及び加工技術が要求されつつある。
したがって、電子部品筐体内の熱をより効率的に放出するために筐体を構成する材料自体に放熱機能を持たせながらも、高強度かつ高プレス成形性の実現が所望されるに至った。
As electronic devices have higher functionality and higher performance, the amount of heat generated around the electronic component tends to increase, and countermeasures for releasing heat from the inside of the electronic component housing have become an issue. On the other hand, the use of a heat sink with a fan, which has been conventionally used, is not realistic due to demands for miniaturization and space saving.
Also, due to the downsizing, weight reduction, and complexity of electronic devices, excellent press workability and processing technology are being demanded while using high-strength aluminum alloys.
Therefore, in order to release the heat in the electronic component casing more efficiently, it has been desired to realize high strength and high press formability while providing the material itself constituting the casing with a heat dissipation function.

例えば、基盤表裏面に導電性フィラーを含有しない放熱性塗膜が被覆された塗装体を用いた場合に、これを用いない場合に比べ、所定の放熱評価装置内の温度を2.6℃以上低下させ得るもの(特許文献1)、アルミニウム板の片面に、有機樹脂微粒子を含有する有機樹脂皮膜を設けたもの(特許文献2)、カーボンブラック、酸化チタン及び亜鉛華を特定量含有し、熱放射率を65%以上としたもの(特許文献3)、一方の面に潤滑性塗膜を、他方の面に導電性塗膜を形成することにより、高い成形性と導電性を実現したもの(特許文献4)、酸化チタン、カーボンブラックを含有する下塗り層の上に樹脂ビーズを分散させた上塗り層を設け、他方の面に導電性塗膜を被覆することにより、優れた放熱性、耐傷つき性及び導電性を実現しようとしたもの(特許文献5)などがある。   For example, when using a coated body in which a heat-dissipating coating film containing no conductive filler is used on the front and back surfaces of the substrate, the temperature in the predetermined heat-dissipation evaluation apparatus is 2.6 ° C. or higher compared to the case where this is not used. One that can be reduced (Patent Document 1), one surface of an aluminum plate provided with an organic resin film containing organic resin fine particles (Patent Document 2), carbon black, titanium oxide, and zinc white are contained in specific amounts, An emissivity of 65% or higher (Patent Document 3), a lubricous coating film formed on one surface, and a conductive coating film formed on the other surface to achieve high moldability and conductivity ( Patent Document 4), by providing an overcoat layer in which resin beads are dispersed on an undercoat layer containing titanium oxide and carbon black, and covering the other surface with a conductive coating film, excellent heat dissipation and scratch resistance Realize conductivity and conductivity And the ones (Patent Document 5), and the like.

しかしながら、電子機器筐体等に用いられるアルミニウム合金板としては、特に、その成形性と放熱性が重要であるが、未だ改善の余地があり、その特性をさらに向上させることが必要である。   However, as an aluminum alloy plate used for an electronic device casing or the like, its formability and heat dissipation are particularly important, but there is still room for improvement, and it is necessary to further improve its characteristics.

特開2004−74145号公報JP 2004-74145 A 特開2002−149083号公報JP 2002-149083 A 特開2004−160979号公報Japanese Patent Laid-Open No. 2004-160979 特開2004−093964号公報JP 2004-093964 A 特開2003−311791号公報JP 2003-311791 A

本発明は、かかる従来の問題点に鑑みてなされたもので、プレス成形性、放熱性に優れた両面プレコートアルミニウム合金板を提供しようとするものである。   The present invention has been made in view of such conventional problems, and an object of the present invention is to provide a double-side pre-coated aluminum alloy plate excellent in press formability and heat dissipation.

第1の発明は、Al−Mg−Cu系アルミニウム合金板よりなる基板と、該基板の一方の面に形成した潤滑性塗膜と、上記基板の他方の面に形成した放熱性塗膜とよりなり、
上記潤滑性塗膜は、ベース樹脂100重量部に対して、インナーワックスを0.2〜5.0重量部含有させた第1の有機樹脂系塗料を塗布して硬化させることにより形成してあり、
上記放熱性塗膜は、ベース樹脂100重量部に対して、必須の放熱性物質として、酸化チタンを3〜60重量部とカーボンブラックを0.2〜15重量部含有させた第2の有機樹脂系塗料を塗布して硬化させることにより形成してあることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板にある(請求項1)。
According to a first aspect of the present invention, there is provided a substrate made of an Al-Mg-Cu-based aluminum alloy plate, a lubricating coating film formed on one surface of the substrate, and a heat dissipating coating film formed on the other surface of the substrate. Become
The lubricating coating is formed by applying and curing a first organic resin-based paint containing 0.2 to 5.0 parts by weight of an inner wax with respect to 100 parts by weight of the base resin. ,
The heat-radiating coating film is a second organic resin containing 3 to 60 parts by weight of titanium oxide and 0.2 to 15 parts by weight of carbon black as essential heat-dissipating substances with respect to 100 parts by weight of the base resin. A double-side pre-coated aluminum alloy plate excellent in press formability and heat dissipation, characterized in that it is formed by applying and curing a system paint (claim 1).

本発明の両面プレコートアルミニウム合金板は、上記基板として、Al−Mg−Cu系アルミニウム合金板を積極的に採用する。これにより、Al−Mg−Cu系アルミニウム合金の高強度でかつ優れた成形性を有する特性を生かし、電子機器筐体等に最適な小型軽量化を実現することができる。   The double-side pre-coated aluminum alloy plate of the present invention positively employs an Al—Mg—Cu-based aluminum alloy plate as the substrate. Thereby, it is possible to realize a small size and light weight optimal for an electronic device casing and the like by taking advantage of the characteristics of the Al—Mg—Cu-based aluminum alloy having high strength and excellent formability.

また、上記両面プレコートアルミニウム合金板は、上記基板の一方の面に、特に金型との潤滑性(成形性)に優れた上記潤滑性塗膜を設け、他方の面に特に放熱性を重視した上記放熱性塗膜を設けている。そして、この構成を用いることによって、優れた放熱性と優れた成形性を十分に得ることができるのである。
すなわち、後述する加工方法にもあるように、成形時に特に潤滑性能が必要な側に上記潤滑性塗膜を配置して加工することによって、上記インナーワックスの潤滑作用によって非常に優れた成形性を確保することができる。そして、一方、放熱性については、上記放熱性塗膜に含有される放熱性物質の作用によって優れた放熱性をも確保することができる。
In addition, the double-side pre-coated aluminum alloy plate is provided with the lubricating coating film having excellent lubricity (formability) particularly with a mold on one surface of the substrate, and particularly on the other surface, heat dissipation is emphasized. The heat-radiating coating film is provided. And by using this structure, the outstanding heat dissipation and the outstanding moldability can fully be acquired.
That is, as shown in the processing method described later, by arranging and processing the above-mentioned lubricating coating film on the side particularly requiring lubrication performance at the time of molding, very excellent moldability is achieved by the lubricating action of the inner wax. Can be secured. And about heat dissipation, the heat dissipation excellent also by the effect | action of the heat dissipation substance contained in the said heat dissipation coating film is securable.

上記放熱性塗膜には、必須の放熱性物質として、上記特定量の酸化チタンとカーボンブラックとを選択している。これにより、放熱性塗膜における適度な成形性および塗膜の健全性を維持しつつ非常に優れた放熱性を確保することができるのである。
また、上記潤滑性塗膜に含有させるインナーワックスの量も、上記特定の量に限定している。これにより、塗膜の健全性を維持しつつ非常に優れた成形性を確保することができるのである。
For the heat-dissipating coating film, the specific amounts of titanium oxide and carbon black are selected as essential heat-dissipating substances. Thereby, the very outstanding heat dissipation can be ensured, maintaining the moderate moldability in a heat-radiating coating film, and the soundness of a coating film.
Further, the amount of the inner wax contained in the lubricating coating film is also limited to the specific amount. Thereby, very excellent moldability can be secured while maintaining the soundness of the coating film.

第2の発明は、加工穴を有するダイスと、上記加工穴に挿入可能なポンチとにより第1の発明の両面プレコートアルミニウム合金板をプレス加工する方法において、
上記両面プレコートアルミニウム合金板における上記潤滑性塗膜が形成された面を上記ダイス側に位置させ、上記放熱性塗膜が形成された面を上記ポンチ側に位置させることを特徴とするプレス加工方法にある(請求項14)。
A second invention is a method of pressing the double-side precoated aluminum alloy plate of the first invention with a die having a processed hole and a punch that can be inserted into the processed hole.
A press working method characterized in that the surface on which the lubricating coating film is formed on the double-side precoated aluminum alloy plate is positioned on the die side, and the surface on which the heat-radiating coating film is formed is positioned on the punch side. (Claim 14).

このプレス加工方法によれば、上記のごとく、上記両面プレコートアルミニウム合金板における上記潤滑性塗膜が形成された面をダイス側に位置させ、放熱性塗膜側をポンチ側に位置させてプレス加工する。そのため、得ようとするプレス品が例えば筐体の場合に、その内面側すなわち熱源側に放熱性塗膜を配置することができ、放熱性すなわち熱吸収性に優れた筐体を得ることができる。また、筐体外面側すなわちプレス加工の際のダイスと接する側に潤滑性塗膜を配置することができ、プレス成形性に優れ、かつ潤滑性塗膜中に含まれる樹脂ビーズにより塗膜の傷付きを防止することができ、意匠性にも優れた筐体を得ることができる。さらに、アルミニウム合金板よりなる基板と上記潤滑性塗膜との間に顔料不含の塗膜を配置した場合には、潤滑性塗膜の密着性をさらに高めることができ、よりいっそう塗膜割れや塗膜剥離、欠損等の発生を抑制することができる。   According to this pressing method, as described above, the surface of the double-sided precoated aluminum alloy plate on which the lubricating coating film is formed is positioned on the die side, and the heat dissipating coating film side is positioned on the punch side, and pressing is performed. To do. Therefore, when the press product to be obtained is, for example, a housing, a heat dissipating coating film can be disposed on the inner surface side, that is, the heat source side, and a housing excellent in heat dissipation, that is, heat absorption can be obtained. . In addition, a lubricious coating film can be disposed on the outer surface of the housing, that is, the side in contact with the die during press processing, and is excellent in press moldability and is damaged by the resin beads contained in the lubricating coating film. Adhesion can be prevented, and a housing with excellent design can be obtained. Furthermore, when a pigment-free coating film is disposed between the substrate made of an aluminum alloy plate and the lubricating coating film, the adhesion of the lubricating coating film can be further increased, and the coating film cracking can be further improved. And the occurrence of film peeling and defects can be suppressed.

本発明の両面プレコートアルミニウム合金板においては、上記のごとく、上記第1の有機樹脂系塗料として、ベース樹脂100重量部に対して、インナーワックスを0.2〜5.0重量部含有させたものを用いる。
上記インナーワックスの含有量が上記ベース樹脂100重量部に対し0.2重量部未満では成形性が低下し、インナーワックスの含有量がベース樹脂100重量部に対して5.0重量部を超える場合には、成形時に板同士がくっついた状態になるブロッキングが発生してトラブルが生じやすくなるおそれがある。
なお、上記インナーワックスとしては、例えば、ラノリン、カルナバ、ポリエチレン等がある。
In the double-side pre-coated aluminum alloy plate of the present invention, as described above, the first organic resin-based paint contains 0.2 to 5.0 parts by weight of inner wax with respect to 100 parts by weight of the base resin. Is used.
When the content of the inner wax is less than 0.2 parts by weight with respect to 100 parts by weight of the base resin, the moldability is deteriorated, and the content of the inner wax exceeds 5.0 parts by weight with respect to 100 parts by weight of the base resin. In such a case, there is a possibility that troubles are likely to occur due to blocking in which the plates are bonded to each other during molding.
Examples of the inner wax include lanolin, carnauba, polyethylene, and the like.

また、上記第2の有機樹脂系塗料としては、上記ベース樹脂100重量部に対して、必須の放熱性物質として、酸化チタンを3〜60重量部とカーボンブラックを0.2〜15重量部含有させたものを用いる。
上記放熱性物質としての酸化チタンの含有量が上記ベース樹脂100重量部に対して3重量部未満の場合には放熱性が十分に得られないおそれがあり、一方、60重量部を超える場合には、プレス成形時に塗膜から酸化チタンが脱落する割合が増加するおそれがある。また放熱性物質としてのカーボンブラックの含有量が上記ベース樹脂100重量部に対して0.2重量部未満では放熱性が十分に得られないおそれがあり、一方、15重量部を超える場合には、プレス成形時に塗膜からカーボンブラックが脱落する割合が増加するおそれがある。
なお、酸化チタンおよびカーボンブラックという必須の放熱性物質の他に、シリカ、酸化ジルコニウム等の他の放熱性物質を含有させることも可能である。
Moreover, as said 2nd organic resin-type coating material, 3-60 weight part of titanium oxide and 0.2-15 weight part of carbon black are contained as an essential heat-radiating substance with respect to 100 weight part of said base resins. Use
When the content of titanium oxide as the heat-dissipating material is less than 3 parts by weight with respect to 100 parts by weight of the base resin, there is a risk that heat dissipation may not be sufficiently obtained, while when it exceeds 60 parts by weight. May increase the proportion of titanium oxide falling off the coating during press molding. Further, if the content of carbon black as a heat-dissipating material is less than 0.2 parts by weight with respect to 100 parts by weight of the base resin, there is a risk that sufficient heat dissipation may not be obtained. There is a possibility that the ratio of carbon black falling off from the coating film during press molding increases.
In addition to the essential heat-dissipating materials such as titanium oxide and carbon black, other heat-dissipating materials such as silica and zirconium oxide can be contained.

また、上記第1の有機樹脂系塗料は、数平均分子量5000〜30000のポリエステル樹脂よりなるベース樹脂を主成分として含有するポリエステル樹脂系塗料を用いてなり、硬化後の上記潤滑性塗膜の膜厚が1〜40μmであることが好ましい(請求項2)。
上記ポリエステル樹脂の数平均分子量が5000未満では塗膜が硬くなりすぎるため、成形性が悪くなり、一方、数平均分子量が30000を超える場合には塗膜が軟らかく耐傷つき性が低下するおそれがある。
上記潤滑性塗膜の硬化後の膜厚が1μm未満では成形性が低下し、40μmを超える場合にはコストの上昇を招くおそれがある。
Further, the first organic resin-based paint is a polyester resin-based paint containing a base resin composed of a polyester resin having a number average molecular weight of 5000 to 30000 as a main component, and the film of the lubricating coating film after curing. The thickness is preferably 1 to 40 μm (Claim 2).
When the number average molecular weight of the polyester resin is less than 5,000, the coating film becomes too hard and the moldability is deteriorated. On the other hand, when the number average molecular weight exceeds 30,000, the coating film is soft and the scratch resistance may be lowered. .
If the film thickness after curing of the lubricating coating film is less than 1 μm, the moldability is lowered, and if it exceeds 40 μm, the cost may increase.

また、上記第2の有機樹脂系塗料は、数平均分子量5000〜30000のポリエステル樹脂よりなるベース樹脂を主成分として含有するポリエステル樹脂系塗料を用いてなり、硬化後の上記放熱性塗膜の膜厚が0.5〜40μmであることが好ましい(請求項3)。
上記ポリエステル樹脂の数平均分子量が5000未満では塗膜が硬くなりすぎるため、成形性が悪くなり、一方、数平均分子量が30000を超える場合には塗膜が軟らかく耐傷つき性が低下するおそれがある。
上記放熱性塗膜の硬化後の膜厚が0.5μm未満の場合には放射率が低く、放熱性が劣るという問題があり、一方、40μmを超える場合には、コストの上昇を招くおそれがある。
The second organic resin-based paint is a polyester resin-based paint containing a base resin composed of a polyester resin having a number average molecular weight of 5000 to 30000 as a main component, and the film of the heat-dissipating coating film after being cured. The thickness is preferably 0.5 to 40 μm (Claim 3).
When the number average molecular weight of the polyester resin is less than 5,000, the coating film becomes too hard and the moldability is deteriorated. On the other hand, when the number average molecular weight exceeds 30,000, the coating film is soft and the scratch resistance may be lowered. .
When the film thickness after curing of the heat-dissipating coating film is less than 0.5 μm, there is a problem that the emissivity is low and heat dissipation is inferior, whereas when it exceeds 40 μm, the cost may increase. is there.

また、上記潤滑性塗膜には、酸化チタン、カーボンブラック、シリカ、酸化ジルコニウムの1種または2種以上よりなる放熱性物質を含有させていることが好ましい(請求項4。すなわち、上記放熱性物質を、上記放熱性塗膜だけでなく、上記潤滑性塗膜にも含有させることが好ましい。これにより、放熱性をさらに高めることができる。   Further, the lubricating coating film preferably contains a heat dissipating material composed of one or more of titanium oxide, carbon black, silica, and zirconium oxide (Claim 4). It is preferable to contain the substance not only in the heat-dissipating coating film but also in the lubricating coating film, thereby further improving the heat-dissipating property.

また、上記放熱性塗膜には、導電性物質を含有させていることが好ましい(請求項5)。これにより、上記放熱性塗膜は、放熱性に加えて導電性にも優れたものとなり、導電性が要求される用途への適用も可能となる。また、導電性物質は、一般に放熱性にも優れる場合が多いので、放熱性向上効果も高めることができる。   Moreover, it is preferable that the heat-radiating coating film contains a conductive substance. Thereby, the said heat-radiation coating film becomes the thing excellent also in electroconductivity in addition to heat dissipation, and the application to the use for which electroconductivity is required is also attained. In addition, since the conductive substance is generally excellent in heat dissipation, the effect of improving heat dissipation can be enhanced.

また、上記放熱性塗膜には、粒子状合成樹脂よりなる樹脂ビーズを含有させていることが好ましい(請求項6)。この場合には、上記樹脂ビーズの存在によって耐傷付き性を格段に向上させることができる。   The heat-radiating coating film preferably contains resin beads made of particulate synthetic resin. In this case, the scratch resistance can be remarkably improved by the presence of the resin beads.

また、上記第2の有機樹脂系塗料には、0.2〜5μmの平均厚さ及び2〜50μmの平均長径を有する鱗片状のNiフィラー、または1〜40μmの平均粒径を有する球状のNiフィラーの1種又は2種よりなる導電性物質が含有されており、その含有量は、上記ベース樹脂100重量部に対して1〜70重量部であることが好ましい(請求項7)。   In addition, the second organic resin-based paint includes a scaly Ni filler having an average thickness of 0.2 to 5 μm and an average major axis of 2 to 50 μm, or spherical Ni having an average particle diameter of 1 to 40 μm. A conductive substance composed of one or two fillers is contained, and the content thereof is preferably 1 to 70 parts by weight with respect to 100 parts by weight of the base resin.

上記燐片状のNiフィラーの平均厚みが0.2μm未満もしくは平均長径が2μm未満の場合には導電性が不足し、一方、平均厚みが5μmを超える場合もしくは平均長径が50μmを超える場合には鱗片状Niフィラーが塗膜から脱落する割合が増加するおそれがある。
上記球状Niフィラーの平均粒径が1μm未満の場合には導電性が不足し、40μmを超える場合には球状Niフィラーがプレス成形時に塗膜から脱落する割合が増加するおそれがある。
上記導電性物質の含有量(上記2種含有させる場合にはその合計)が、ベース樹脂100重量部に対して1重量部未満の場合には導電性が不足し、70重量部を超える場合にはプレス成形時に導電性物質が塗膜から脱落する割合が増加するおそれがある。
When the average thickness of the flake-like Ni filler is less than 0.2 μm or the average major axis is less than 2 μm, the conductivity is insufficient. On the other hand, when the average thickness exceeds 5 μm or the average major axis exceeds 50 μm There is a possibility that the rate at which the scaly Ni filler falls off from the coating film increases.
When the average particle size of the spherical Ni filler is less than 1 μm, the conductivity is insufficient, and when it exceeds 40 μm, the proportion of the spherical Ni filler falling off from the coating film during press molding may increase.
When the content of the conductive material (the total when the two types are included) is less than 1 part by weight with respect to 100 parts by weight of the base resin, the conductivity is insufficient, and when the content exceeds 70 parts by weight. May increase the rate at which the conductive material is removed from the coating during press molding.

また、上記第2の有機樹脂系塗料には、粒径1〜120μmであると共に上記放熱性塗膜の膜厚の1〜3倍の粒径を有する粒子状合成樹脂よりなる樹脂ビーズが含有されており、その含有量は、上記ベース樹脂100重量部に対して1〜100重量部であることが好ましい(請求項8)。   The second organic resin-based paint contains resin beads made of particulate synthetic resin having a particle size of 1 to 120 μm and a particle size of 1 to 3 times the film thickness of the heat-dissipating coating film. The content thereof is preferably 1 to 100 parts by weight with respect to 100 parts by weight of the base resin (claim 8).

上記樹脂ビーズの粒径が1μm未満の場合には耐傷つき性が不足し、120μmを超える場合には、塗膜から樹脂ビーズが脱膜する割合が増加するおそれがある。
上記樹脂ビーズの粒径が上記放熱性塗膜の膜厚の1倍未満の場合には耐傷つき性が十分に得られない場合があり、一方、上記放熱性塗膜の膜厚の3倍を超える場合には塗膜から樹脂ビーズが脱落する割合が増加するおそれがある。
上記樹脂ビーズの含有量が、上記ベース樹脂100重量部に対して1重量部未満の場合には耐傷つき性が増大し、100重量部を超える場合には塗膜から樹脂ビーズが脱落する割合が増加するおそれがある。
When the particle size of the resin beads is less than 1 μm, the scratch resistance is insufficient, and when it exceeds 120 μm, there is a possibility that the ratio of the resin beads being removed from the coating film may increase.
If the particle size of the resin beads is less than 1 times the film thickness of the heat-dissipating coating film, scratch resistance may not be obtained sufficiently, while the film thickness of the heat-dissipating coating film may be 3 times the film thickness. When exceeding, there exists a possibility that the ratio which the resin bead falls from a coating film may increase.
When the content of the resin beads is less than 1 part by weight with respect to 100 parts by weight of the base resin, the scratch resistance increases. May increase.

また、上記第2の有機樹脂系塗料には、インナーワックスが含有されており、その含有量は、上記ベース樹脂100重量部に対して0.5〜5.0重量部であることが好ましい(請求項9)。
この場合には、上記放熱性塗膜側の成形性も格段に向上させることができる。上記インナーワックスの含有量が上記ベース樹脂100重量部に対し0.5重量部以下ではインナーワックスによる上記放熱性塗膜側の成形性向上効果が少なく、5.0重量部を超える場合にはコストの上昇を招くおそれがある。
Further, the second organic resin-based paint contains an inner wax, and the content thereof is preferably 0.5 to 5.0 parts by weight with respect to 100 parts by weight of the base resin ( Claim 9).
In this case, the moldability on the side of the heat radiating coating film can be remarkably improved. When the content of the inner wax is 0.5 parts by weight or less with respect to 100 parts by weight of the base resin, the effect of improving the moldability on the heat-dissipating coating film side by the inner wax is small. May increase.

また、上記基板の表面には、基板と塗膜との密着性を向上させる下地処理層が形成されていることが好ましい(請求項10)。
この場合には、上記下地処理層の存在によって、基板と塗膜の密着性を高めることができるので、優れた成形性を確保することができる。
上記下地処理層としては、クロム酸クロメートやリン酸クロメート等によるクロメート処理、クロム化合物以外のリン酸チタンやリン酸ジルコニウム、リン酸モリブデン、リン酸亜鉛等によるノンクロメート処理等の従来からの化学皮膜処理、化成処理等により形成することができる。
Moreover, it is preferable that the surface of the said board | substrate is formed with the base-treatment layer which improves the adhesiveness of a board | substrate and a coating film (Claim 10).
In this case, since the adhesion between the substrate and the coating film can be enhanced by the presence of the base treatment layer, excellent moldability can be ensured.
As the above-mentioned undercoat layer, conventional chemical coatings such as chromate treatment with chromate chromate or phosphate chromate, non-chromate treatment with titanium phosphate other than chromium compounds, zirconium phosphate, molybdenum phosphate, zinc phosphate, etc. It can be formed by treatment, chemical conversion treatment or the like.

また上記潤滑性塗膜と上記基板との間には、顔料不含の第3の有機樹脂系塗料を塗布して硬化させることにより形成した中間塗膜層を有していることが好ましい(請求項11)。この場合には、上記中間塗膜層の存在によって、成形時の塗膜の追従性が向上し、さらに成形性を高めることができる。
また、上記下地処理層を設けた場合には、基板と上記中間塗膜層との間に上記下地処理層が存在することとなる。
Moreover, it is preferable to have an intermediate coating layer formed by applying and curing a third organic resin-based paint containing no pigment between the lubricating coating and the substrate. Item 11). In this case, due to the presence of the intermediate coating layer, the followability of the coating during molding is improved, and the moldability can be further improved.
Moreover, when the said base treatment layer is provided, the said base treatment layer will exist between a board | substrate and the said intermediate coating film layer.

また、上記第3の有機樹脂系塗料は、数平均分子量5000〜30000のポリエステル樹脂よりなるベース樹脂を主成分として含有するポリエステル樹脂系塗料を用いてなり、硬化後の上記中間塗膜層の膜厚が1〜20μmであることが好ましい(請求項12)。
上記第3の有機樹脂系塗料における上記ポリエステル樹脂の数平均分子量が5000未満では塗膜が硬くなりすぎるため、成形性が悪くなり、一方、数平均分子量が30000を超える場合には塗膜が軟らかく塗膜が剥離するおそれがある。
上記中間塗膜層の膜厚が1μm未満の場合には、成形時における塗膜の追従性が不足して成形性が低下するおそれがあり、20μmを超える場合には、コスト上昇を招くおそれがある。
The third organic resin-based paint is a polyester resin-based paint containing a base resin composed of a polyester resin having a number average molecular weight of 5000 to 30000 as a main component, and the film of the intermediate coating layer after curing. The thickness is preferably 1 to 20 μm (claim 12).
If the number average molecular weight of the polyester resin in the third organic resin-based paint is less than 5000, the coating film becomes too hard and the moldability is deteriorated. On the other hand, if the number average molecular weight exceeds 30000, the coating film is soft. There is a risk of the film peeling off.
When the film thickness of the intermediate coating layer is less than 1 μm, the followability of the coating film at the time of molding may be insufficient, and the moldability may decrease. When the thickness exceeds 20 μm, the cost may increase. is there.

また、上記基板は、Mg:4.0〜5.5%(質量%、以下同じ)、Cu:0.25〜0.45%を含有し、残部は不可避的不純物とAlとからなると共に、JIS5号試験片による引張強さが250〜350MPa、耐力が80〜190MPa、伸びが20〜40%であることが好ましい(請求項13)。   The substrate contains Mg: 4.0 to 5.5% (mass%, the same applies hereinafter), Cu: 0.25 to 0.45%, and the balance is inevitable impurities and Al. It is preferable that the tensile strength according to a JIS No. 5 test piece is 250 to 350 MPa, the proof stress is 80 to 190 MPa, and the elongation is 20 to 40%.

Mg含有量が4.0%未満の場合には、所定の強度が得にくくなるというおそれがあり、一方、5.5%を超える場合には、熱間圧延がしにくくなるおそれがある。
Cu含有量が0.25%未満の場合には、所定の強度が得にくくなるというおそれがあり、一方、0.45%を超える場合には、成形性が劣り、かつ耐食性も劣るおそれがある。
If the Mg content is less than 4.0%, the predetermined strength may be difficult to obtain, whereas if it exceeds 5.5%, hot rolling may be difficult.
If the Cu content is less than 0.25%, the predetermined strength may be difficult to obtain. On the other hand, if it exceeds 0.45%, the moldability may be inferior and the corrosion resistance may be inferior. .

上記引張強さが250MPa未満の場合には、筐体として充分な引張強度を得られないがために、成形はできるものの、その後の衝撃等で割れやすくなるおそれがあり、一方、350MPaを超える場合には、プレス加工時に割れやすくなるおそれがある。
上記耐力が80MPa未満の場合には、筐体として充分な耐力を得られないがために、成形はできるもののその後の衝撃等で変形しやすくなるおそれがあり、一方、190MPaを超える場合には、プレス加工時に割れやすくなるおそれがある。
上記伸びが20%未満の場合には、プレス加工時に割れやすくなるおそれがあり、一方、40%を超える場合には、成形はできるものの、軟らかすぎることから、その後の衝撃で変形しやすくなるおそれがある。
When the tensile strength is less than 250 MPa, sufficient tensile strength cannot be obtained as a casing, so that molding can be performed, but there is a risk of being easily broken by a subsequent impact or the like. On the other hand, when it exceeds 350 MPa In such a case, there is a risk of being easily broken during press working.
When the proof stress is less than 80 MPa, sufficient proof strength cannot be obtained as a housing, so that although it can be molded, it may be easily deformed by a subsequent impact or the like, whereas when it exceeds 190 MPa, There is a risk of cracking during press working.
If the elongation is less than 20%, there is a risk of being easily broken at the time of press working. On the other hand, if it exceeds 40%, molding is possible, but it is too soft and may be easily deformed by a subsequent impact. There is.

以下に実施例を掲げて本発明をさらに詳しく説明するが、本発明はこれらの実施例によってのみ限定されるものではない。
本例では、本発明の実施例及び比較例として複数種類の試料(両面プレコートアルミニウム合金板)を作製しその特性を評価した。
The present invention will be described in more detail with reference to the following examples, but the present invention is not limited only to these examples.
In this example, a plurality of types of samples (double-side pre-coated aluminum alloy plates) were produced as examples and comparative examples of the present invention, and their characteristics were evaluated.

各試料を作製するに当たっては、まず、基板として、Mg:4.0〜5.5%(質量%、以下同じ)、Cu:0.25〜0.45%を含有し、JIS5号試験片による引張り強さが250〜350MPa、耐力が80〜190MPa、伸びが20〜40%を満たす厚さ1mmのアルミニウム合金板を使用した。   In preparing each sample, first, as a substrate, Mg: 4.0 to 5.5% (mass%, the same applies hereinafter), Cu: 0.25 to 0.45%, and according to JIS No. 5 test piece An aluminum alloy plate having a thickness of 1 mm that satisfies a tensile strength of 250 to 350 MPa, a proof stress of 80 to 190 MPa, and an elongation of 20 to 40% was used.

また、上記基板には、塗装前の下地処理を施した。具体的には、市販のアルカリ系脱脂剤で上記基板を脱脂後、リン酸クロメート浴中でリン酸クロメート処理を実施した。クロメート皮膜量は皮膜中のCr含有量として20±5mg/m2である。 Further, the substrate was subjected to a ground treatment before coating. Specifically, the substrate was degreased with a commercially available alkaline degreasing agent, and then subjected to phosphoric acid chromate treatment in a phosphoric acid chromate bath. The amount of chromate film is 20 ± 5 mg / m 2 as the Cr content in the film.

塗装処理は、下地処理後の上記基板の一方の面に対して所定の塗料をバーコーターを用いて塗布し、アルミニウム表面の温度が230℃になるよう240℃のオーブンの中で60秒焼付、硬化することにより各塗膜を形成した。また、同様に他方の面に対しても所定の塗料をバーコーターを用いて塗布し、アルミニウム表面の温度が230℃になるよう240℃のオーブンの中で60秒焼付、硬化することにより各塗膜を形成した。
なお、形成された塗膜は表1および表2に示す。
The coating treatment is performed by applying a predetermined paint to one side of the substrate after the base treatment using a bar coater, and baking in an oven at 240 ° C. for 60 seconds so that the temperature of the aluminum surface becomes 230 ° C. Each coating film was formed by curing. Similarly, a predetermined paint is applied to the other surface using a bar coater, and each coating is performed by baking and curing in an oven at 240 ° C. for 60 seconds so that the temperature of the aluminum surface becomes 230 ° C. A film was formed.
In addition, the formed coating film is shown in Table 1 and Table 2.

また、作製した試料(両面プレコートアルミニウム合金板1)の代表的な構成を図1に示す。同図に示すごとく、各試料は、Al−Mg−Cu系アルミニウム合金板よりなる基板10と、該基板10の一方の面に形成した潤滑性塗膜2と、上記基板10の他方の面に形成された放熱性塗膜3とよりなる。潤滑性塗膜2は、インナーワックスを含有させた第1の有機樹脂系塗料を塗布して硬化させることにより形成してあり、放熱性塗膜3は、酸化チタンとカーボンブラックよりなる放熱性物質35を含有させた第2の有機樹脂系塗料を塗布して硬化させることにより形成してある。また、各塗膜2、3は、基板10の表面に形成された化成皮膜層8を介して形成してある。なお、各塗膜2、3内には、Niフィラーや樹脂ビーズを含有させる場合もある(図示略)。   Moreover, the typical structure of the produced sample (double-side pre-coated aluminum alloy plate 1) is shown in FIG. As shown in the figure, each sample is composed of a substrate 10 made of an Al—Mg—Cu-based aluminum alloy plate, a lubricating coating 2 formed on one surface of the substrate 10, and the other surface of the substrate 10. It consists of the formed heat-radiating coating film 3. The lubricious coating film 2 is formed by applying and curing a first organic resin-based paint containing an inner wax, and the heat radiation coating film 3 is a heat radiation material composed of titanium oxide and carbon black. The second organic resin paint containing 35 is applied and cured. Each coating film 2, 3 is formed via a chemical conversion film layer 8 formed on the surface of the substrate 10. Each coating film 2 and 3 may contain Ni filler or resin beads (not shown).

Figure 2006312243
Figure 2006312243

Figure 2006312243
Figure 2006312243

本例では、各試料について、プレス成形性、放熱性(赤外線積分放射率)、導電性、および耐傷つき性についての評価を実施し、それぞれレベル3以上を合格とした。
<プレス成形性>
潤滑性塗膜が形成された側の面をダイス側に位置させ、下記の条件で深絞り加工を施し、ダイス側の面に塗膜割れの発生しない最大の深さを成形高さと定義しプレス成形性の評価を行った。
(加工条件)
ダイス径:φ52.8mm、ポンチ径:φ50mm、ポンチ肩部の曲率半径:5mm、板押えダイス肩部の曲率半径:5mm、板押え力:34kN、潤滑油:使用せず。
(評価基準)
レベル1:12mm以下、レベル2:12mm超え13mm以下、レベル3:13mm超え14mm以下、レベル4:14mm超え15mm以下、レベル5:15mm超え
In this example, each sample was evaluated for press formability, heat dissipation (infrared integrated emissivity), electrical conductivity, and scratch resistance, and each of the samples was evaluated as pass 3 or higher.
<Press formability>
The surface on which the lubricious coating film is formed is positioned on the die side, deep drawing is performed under the following conditions, and the maximum depth at which no coating film cracks occur on the die side surface is defined as the molding height. The moldability was evaluated.
(Processing conditions)
Die diameter: φ52.8 mm, punch diameter: φ50 mm, radius of curvature of punch shoulder: 5 mm, radius of curvature of plate pressing die shoulder: 5 mm, plate pressing force: 34 kN, lubricating oil: not used.
(Evaluation criteria)
Level 1: 12 mm or less, Level 2: over 12 mm to 13 mm, Level 3: over 13 mm to 14 mm, Level 4: over 14 mm to 15 mm, Level 5: over 15 mm

<赤外線積分放射率>
赤外線積分放射率は、PERKIN ELMER FT-IR Spectrometer 1725Xを用い、波長が2.5〜25μmの範囲で、各波長の赤外線反射率を測定し、各波長の入射光から反射光を差し引いたものを各波長の吸収率≒反射率と定義した。各波長の反射率を波長が2.5〜25μmの範囲で積分し赤外線積分放射率とした。評価基準は以下の通りであり、レベル3以上を合格とした。
(評価基準)
レベル1:60%未満、レベル2:60%以上70%未満、レベル3:70%以上80%未満、レベル4:80%以上90%未満、レベル5:90%以上
<Infrared integrated emissivity>
Infrared integrated emissivity is measured by measuring the infrared reflectance of each wavelength in the range of 2.5-25 μm using PERKIN ELMER FT-IR Spectrometer 1725X, and subtracting the reflected light from the incident light of each wavelength. The absorptivity of each wavelength was defined as reflectance. The reflectance at each wavelength was integrated in the wavelength range of 2.5 to 25 μm to obtain infrared integrated emissivity. The evaluation criteria are as follows, and level 3 or higher was regarded as acceptable.
(Evaluation criteria)
Level 1: Less than 60%, Level 2: 60% or more and less than 70%, Level 3: 70% or more and less than 80%, Level 4: 80% or more and less than 90%, Level 5: 90% or more

<導電性>:導電性塗装板の評価に使用
塗装板の塗膜の一部をスクレイパーで削り落とし、アルミニウム素地に直接にテスターの一方の端子を接続し、もう一方の端子には、先端が球状で、自重100gの銅製電極を接続し、塗装板に垂直に接触するよう、補助具で電極を支持した。そのときの電気抵抗値を読み取り評価に用いた。評価基準は以下の通りであり、レベル3以上を合格とした。
(評価基準)
レベル1:1000Ω以上、レベル2:500Ω以上1000Ω未満、レベル3:50Ω以上500Ω未満、レベル4:10Ω以上50Ω未満、レベル5:10Ω未満
<Conductivity>: Used for the evaluation of the conductive paint board. Part of the paint film on the paint board is scraped off with a scraper, and one terminal of the tester is directly connected to the aluminum substrate. A spherical electrode having a weight of 100 g was connected to the electrode, and the electrode was supported by an auxiliary tool so as to contact the painted plate vertically. The electrical resistance value at that time was read and used for evaluation. The evaluation criteria are as follows, and level 3 or higher was regarded as acceptable.
(Evaluation criteria)
Level 1: 1000Ω or more, Level 2: 500Ω or more and less than 1000Ω, Level 3: 50Ω or more and less than 500Ω, Level 4: 10Ω or more and less than 50Ω, Level 5: Less than 10Ω

<耐傷つき性>:耐傷つき性塗装板の評価に使用
バウデン試験にて、荷重500g、1/4インチの鋼球を100回摺動させたときの摺動痕跡の幅を評価に用いた。評価基準は、以下の通りであり、レベル2以上を合格とした。
(評価基準)
レベル1:1.0mm以上、レベル2:0.5mm以上1.0mm未満、レベル3:0.3mm以上0.5mm未満、レベル4:0.1mm以上0.3mm未満、レベル5:0.1未満
<Scratch resistance>: Used for evaluation of scratch-resistant coated plate In the Bowden test, the width of a sliding trace when a steel ball having a load of 500 g and a 1/4 inch was slid 100 times was used for evaluation. The evaluation criteria are as follows, and level 2 or higher was regarded as acceptable.
(Evaluation criteria)
Level 1: 1.0 mm or more, Level 2: 0.5 mm or more and less than 1.0 mm, Level 3: 0.3 mm or more and less than 0.5 mm, Level 4: 0.1 mm or more and less than 0.3 mm, Level 5: 0.1 Less than

Figure 2006312243
Figure 2006312243

評価の結果は表3に示すとおりである。   The results of evaluation are as shown in Table 3.

実施例における、両面プレコートアルミニウム合金板の構成を示す説明図。Explanatory drawing which shows the structure of the double-sided precoat aluminum alloy plate in an Example.

符号の説明Explanation of symbols

1 プレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板
10 基板
2 潤滑性塗膜
3 放熱性塗膜
35 放熱性物質
DESCRIPTION OF SYMBOLS 1 Double-sided precoat aluminum alloy plate excellent in press moldability and heat dissipation 10 Substrate 2 Lubricant coating 3 Heat dissipation coating 35 Heat dissipation material

Claims (14)

Al−Mg−Cu系アルミニウム合金板よりなる基板と、該基板の一方の面に形成した潤滑性塗膜と、上記基板の他方の面に形成した放熱性塗膜とよりなり、
上記潤滑性塗膜は、ベース樹脂100重量部に対して、インナーワックスを0.2〜5.0重量部含有させた第1の有機樹脂系塗料を塗布して硬化させることにより形成してあり、
上記放熱性塗膜は、ベース樹脂100重量部に対して、必須の放熱性物質として、酸化チタンを3〜60重量部とカーボンブラックを0.2〜15重量部含有させた第2の有機樹脂系塗料を塗布して硬化させることにより形成してあることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。
It consists of a substrate made of an Al-Mg-Cu-based aluminum alloy plate, a lubricating coating film formed on one surface of the substrate, and a heat dissipating coating film formed on the other surface of the substrate,
The lubricating coating is formed by applying and curing a first organic resin-based paint containing 0.2 to 5.0 parts by weight of an inner wax with respect to 100 parts by weight of the base resin. ,
The heat-radiating coating film is a second organic resin containing 3 to 60 parts by weight of titanium oxide and 0.2 to 15 parts by weight of carbon black as essential heat-dissipating substances with respect to 100 parts by weight of the base resin. A double-sided pre-coated aluminum alloy plate excellent in press formability and heat dissipation, characterized in that it is formed by applying and curing a system paint.
請求項1において、上記第1の有機樹脂系塗料は、数平均分子量5000〜30000のポリエステル樹脂よりなるベース樹脂を主成分として含有するポリエステル樹脂系塗料を用いてなり、硬化後の上記潤滑性塗膜の膜厚が1〜40μmであることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。   2. The first organic resin-based paint according to claim 1, wherein the first organic resin-based paint is a polyester resin-based paint containing a base resin made of a polyester resin having a number average molecular weight of 5000 to 30000 as a main component. A double-side pre-coated aluminum alloy plate excellent in press formability and heat dissipation, wherein the film thickness is 1 to 40 μm. 請求項1又は2において、上記第2の有機樹脂系塗料は、数平均分子量5000〜30000のポリエステル樹脂よりなるベース樹脂を主成分として含有するポリエステル樹脂系塗料を用いてなり、硬化後の上記放熱性塗膜の膜厚が0.5〜40μmであることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。   3. The heat radiation after curing according to claim 1 or 2, wherein the second organic resin-based paint is a polyester resin-based paint containing as a main component a base resin made of a polyester resin having a number average molecular weight of 5000 to 30000. A double-sided precoated aluminum alloy plate excellent in press formability and heat dissipation, characterized in that the film thickness of the adhesive coating is 0.5 to 40 μm. 請求項1〜3のいずれか1項において、上記潤滑性塗膜には、酸化チタン、カーボンブラック、シリカ、酸化ジルコニウムの1種または2種以上よりなる放熱性物質を含有させていることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。   4. A heat-dissipating material comprising one or more of titanium oxide, carbon black, silica, and zirconium oxide in the lubricating coating film according to claim 1. A double-sided pre-coated aluminum alloy plate excellent in press formability and heat dissipation. 請求項1〜4のいずれか1項において、上記放熱性塗膜には、導電性物質を含有させていることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。   5. The double-side precoated aluminum alloy plate excellent in press formability and heat dissipation, wherein the heat dissipating coating film contains a conductive substance in any one of claims 1 to 4. 請求項1〜5のいずれか1項において、上記放熱性塗膜には、粒子状合成樹脂よりなる樹脂ビーズを含有させていることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。   The double-sided precoated aluminum excellent in press formability and heat dissipation, characterized in that the heat dissipation coating film contains resin beads made of particulate synthetic resin in any one of claims 1-5. Alloy plate. 請求項1〜6のいずれか1項において、上記第2の有機樹脂系塗料には、0.2〜5μmの平均厚さ及び2〜50μmの平均長径を有する鱗片状のNiフィラー、または1〜40μmの平均粒径を有する球状のNiフィラーの1種又は2種よりなる導電性物質が含有されており、その含有量は、上記ベース樹脂100重量部に対して1〜70重量部であることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。   In any one of Claims 1-6, scaly Ni filler which has an average thickness of 0.2-5 micrometers and an average major axis of 2-50 micrometers in said 2nd organic resin-type coating material, or 1- A conductive material composed of one or two spherical Ni fillers having an average particle diameter of 40 μm is contained, and the content thereof is 1 to 70 parts by weight with respect to 100 parts by weight of the base resin. A double-sided precoated aluminum alloy plate excellent in press formability and heat dissipation. 請求項1〜7のいずれか1項において、上記第2の有機樹脂系塗料には、粒径1〜120μmであると共に上記放熱性塗膜の膜厚の1〜3倍の粒径を有する粒子状合成樹脂よりなる樹脂ビーズが含有されており、その含有量は、上記ベース樹脂100重量部に対して1〜100重量部であることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。   8. The particle according to claim 1, wherein the second organic resin-based paint has a particle diameter of 1 to 120 μm and a particle diameter of 1 to 3 times the film thickness of the heat radiation coating film. A double-sided precoat excellent in press moldability and heat dissipation, characterized in that resin beads made of a synthetic resin are contained and the content thereof is 1 to 100 parts by weight with respect to 100 parts by weight of the base resin. Aluminum alloy plate. 請求項1〜8のいずれか1項において、上記第2の有機樹脂系塗料には、インナーワックスが含有されており、その含有量は、上記ベース樹脂100重量部に対して0.5〜5.0重量部であることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。   In any 1 item | term of Claims 1-8, the inner wax is contained in the said 2nd organic resin-type coating material, The content is 0.5-5 with respect to 100 weight part of said base resins. A double-side precoated aluminum alloy plate excellent in press formability and heat dissipation, characterized by being 0.0 part by weight. 請求項1〜9のいずれか1項において、上記基板の表面には、基板と塗膜との密着性を向上させる下地処理層が形成されていることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。   In any 1 item | term of Claims 1-9, in the surface of the said board | substrate, the base-treatment layer which improves the adhesiveness of a board | substrate and a coating film is formed. Excellent double-sided pre-coated aluminum alloy sheet. 請求項1〜10のいずれか1項において、上記潤滑性塗膜と上記基板との間には、顔料不含の第3の有機樹脂系塗料を塗布して硬化させることにより形成した中間塗膜層を有していることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。   The intermediate coating film formed by applying and curing a pigment-free third organic resin coating material between the lubricating coating film and the substrate according to any one of claims 1 to 10. A double-side pre-coated aluminum alloy plate excellent in press formability and heat dissipation, characterized by having a layer. 請求項11において、上記第3の有機樹脂系塗料は、数平均分子量5000〜30000のポリエステル樹脂よりなるベース樹脂を主成分として含有するポリエステル樹脂系塗料を用いてなり、硬化後の上記中間塗膜層の膜厚が1〜20μmであることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。   12. The intermediate coating film according to claim 11, wherein the third organic resin-based paint is a polyester resin-based paint containing, as a main component, a base resin made of a polyester resin having a number average molecular weight of 5000 to 30000. A double-sided precoated aluminum alloy plate excellent in press formability and heat dissipation, characterized in that the layer thickness is 1 to 20 μm. 請求項1〜12のいずれか1項において、上記基板は、Mg:4.0〜5.5%(質量%、以下同じ)、Cu:0.25〜0.45%を含有し、残部は不可避的不純物とAlとからなると共に、JIS5号試験片による引張強さが250〜350MPa、耐力が80〜190MPa、伸びが20〜40%であることを特徴とするプレス成形性及び放熱性に優れた両面プレコートアルミニウム合金板。   In any 1 item | term of Claims 1-12, the said board | substrate contains Mg: 4.0-5.5% (mass%, hereafter the same), Cu: 0.25-0.45%, The remainder is It consists of inevitable impurities and Al, and is excellent in press formability and heat dissipation, characterized by a tensile strength of 250 to 350 MPa, a proof stress of 80 to 190 MPa, and an elongation of 20 to 40% according to a JIS No. 5 test piece. Double-sided pre-coated aluminum alloy plate. 加工穴を有するダイスと、上記加工穴に挿入可能なポンチとにより請求項1〜13のいずれか1項に記載の両面プレコートアルミニウム合金板をプレス加工する方法において、
上記両面プレコートアルミニウム合金板における上記潤滑性塗膜が形成された面を上記ダイス側に位置させ、上記放熱性塗膜が形成された面を上記ポンチ側に位置させることを特徴とするプレス加工方法。
In the method of press-working the double-sided pre-coated aluminum alloy plate according to any one of claims 1 to 13, with a die having a processed hole and a punch that can be inserted into the processed hole.
A press working method characterized in that the surface on which the lubricating coating film is formed on the double-side precoated aluminum alloy plate is positioned on the die side, and the surface on which the heat-radiating coating film is formed is positioned on the punch side. .
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