JP2006307380A - Fiber-processing agent and fiber product using the same - Google Patents
Fiber-processing agent and fiber product using the same Download PDFInfo
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- JP2006307380A JP2006307380A JP2005131270A JP2005131270A JP2006307380A JP 2006307380 A JP2006307380 A JP 2006307380A JP 2005131270 A JP2005131270 A JP 2005131270A JP 2005131270 A JP2005131270 A JP 2005131270A JP 2006307380 A JP2006307380 A JP 2006307380A
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Description
本発明は衣料、寝装繊維製品、インテリア繊維製品、自動車・車両内装繊維製品などにおいては、美肌効果、老化防止効果などのスキンケア用途や、かぶれ防止、抗アレルギー、抗菌防臭、消臭効果などの介護用途を目的としたもので、一方、紙などの繊維ウエブにおいては、食品などの抗酸化・鮮度保持狙い、美肌効果、老化防止効果、抗アレルギー効果などを付与したティッシュペーパー、ウエットティッシュ用途分野などへの展開を目的としたものである。 The present invention is applied to clothing, bedding textile products, interior textile products, automobile / vehicle interior textile products, etc. for skin care applications such as skin beautifying effect, anti-aging effect, anti-rash, anti-allergy, antibacterial deodorizing, deodorizing effect, etc. For the purpose of nursing use, on the other hand, in the case of fiber webs such as paper, tissue paper and wet tissue fields that have been given anti-oxidation and freshness preservation for foods, skin beautifying effects, anti-aging effects, anti-allergic effects, etc. The purpose is to expand to.
カテキン、柿渋エキスなどのポリフェノール、ビタミンＥ、フェルラ酸、γ−オリザノールなどが酸化や変色を防止する生理活性物質として食品、化粧品、医療品などの業界で広く知られている。また、繊維業界においても、フェルラ酸及びその誘導体を繊維素材に固着して、耐久性に優れた紫外線吸収効果を有する繊維製品を提供しようとする試みがある（特許文献１）。ここでは、防縮剤、撥水剤、抗菌防虫剤、防炎剤、耐電防止剤、染料などの他の薬剤との併用も可能であるとされているが、各薬剤に期待される以外の薬効を望めるものではなかった。また、フェルラ酸などを繊維に付着させて、肌の抗酸化を目的にしたものがあるが、人体細胞とは全く別個の化合物でもって抗酸化効果を狙ったものであり、真の意味での肌に優しい加工剤と言えなかった（特許文献２）。さらには、人体細胞に関係した補酵素を用いたものがあり、ある程度の抗酸化性による美肌効果、老化防止効果が期待できるが有効に効果効能を発揮させうる形態とはなっていないのが実情である（特許文献３〜５）。 Polyphenols such as catechin and persimmon extract, vitamin E, ferulic acid, γ-oryzanol and the like are widely known in the food, cosmetics, medical and other industries as bioactive substances that prevent oxidation and discoloration. Also in the textile industry, there is an attempt to provide a fiber product having an ultraviolet absorption effect excellent in durability by fixing ferulic acid and its derivative to a fiber material (Patent Document 1). Here, it is said that it can be used in combination with other chemicals such as shrink-proofing agents, water repellents, antibacterial insecticides, flameproofing agents, antistatic agents, and dyes. It was not something you could hope for. In addition, there is a substance that attaches ferulic acid etc. to the fiber for the purpose of anti-oxidation of the skin, but it is aimed at the antioxidant effect with a completely separate compound from human cells, in the true sense It could not be said to be a skin-friendly processing agent (Patent Document 2). Furthermore, there are those that use coenzymes related to human body cells, and it can be expected to have a skin beautifying effect and anti-aging effect due to a certain degree of antioxidant properties, but it is not in a form that can effectively demonstrate its efficacy (Patent Documents 3 to 5).
本発明は酵素及び補酵素、ならびにそれらの誘導体を使用して、繊維製品に美肌効果、老化防止効果（鮮度保持性、肌の活性酸素などによる酸化防止効果）、抗アレルギー、抗アトピーなどの機能性を人体細胞に近い化合物を主体にすることにより、より肌に優しく前記機能を付与することの出来る機能性付与剤ならびに該機能性付与剤を付着せしめた繊維製品を提供することを課題とする。 The present invention uses enzymes, coenzymes, and derivatives thereof to provide functions such as skin-beautifying effects, anti-aging effects (freshness retention, antioxidant effects due to active oxygen on the skin), anti-allergy, anti-atopy, etc. It is an object of the present invention to provide a functionality-imparting agent capable of imparting the above-mentioned function more gently to the skin and a textile product to which the functionality-imparting agent is attached by mainly using a compound whose properties are close to human cells. .
本発明では、酵素、中でもアポ酵素と言われる酵素（酵素（Ａ）とする）は、低分子量化合物である補酵素（補酵素（Ｂ）とする）と結合して本来の酵素の機能・性能を発揮し、本発明の課題である美肌効果、老化防止効果（肌の活性酸素による酸化防止効果）、抗アレルギー、抗アトピーなどの課題を解決した。 In the present invention, an enzyme, particularly an apoenzyme (enzyme (A)) is combined with a low-molecular weight compound coenzyme (coenzyme (B)) to combine the function and performance of the original enzyme. And solved the problems of the present invention, such as skin beautifying effect, anti-aging effect (antioxidation effect by active oxygen of skin), anti-allergy and anti-atopy.
本発明において、酵素・補酵素の組み合わせ、あるいはレスチンなどの添加剤を組み合わせることにより、人体の肌の抗酸化効果などのより、肌のはり、艶を高める効果が期待できる。 In the present invention, by combining an enzyme / coenzyme combination or an additive such as restin, it is possible to expect an effect of enhancing the skin elasticity and gloss rather than the antioxidant effect of human skin.
本発明を実施するにあたり、酵素、補酵素の組み合わせ、レシチンなどの添加剤の組み合わせをするが、ここについて説明する。すなわち、酵素（Ａ）として、オキシドレダクターゼ、トランスフェラーゼ、ヒドロラーゼ、リアーゼ、イソメラーゼ、リガーゼなどの酵素、ならびに蛋白質、アミノ酸に関連する酵素の少なくとも一種と、補酵素（Ｂ）として、乳酸デヒドロゲナーゼ、アデノシン三リン酸、ホスホエノールピルビン酸、アセチルリン酸、グルコースリン酸、補酵素Ａ、テトラヒドロ葉酸、ニコチンアミドアデニンジヌクレオテド、補酵素Ｑ（ユビカレノン：ＣｏＱ１０）、リポ酸（α−リポ酸）、補酵素Ｂ１２などの補酵素の少なくとも一種を反応・坦治させ、本発明の課題を的確に解決するものである。中でも、蛋白質、ペプチド、アミノ酸に関連する酵素（Ａ）と、補酵素Ｑ、またはリポ酸などの補酵素（Ｂ）との坦治体は、本発明の課題をより明確に解決することが出来る。その際、後述するが、レシチン類（Ｃ）を配合・坦治させておくと、さらに 本発明の課題達成効果を高めるものである。
ところで、本発明に言うアミノ酸とは、グルタミン酸、アスパラギン酸、グリシン、シスチン、セリン、ヒスチジン、リジン、アルギニン、ロイシンなどを言い、さらには シルクプロテイン、セリシンなどのシルクアミノ酸も含めるものであるが、これらに限定されるものではない。
なお、本発明において前記 酵素（Ａ）類と補酵素（Ｂ）類の坦治体に、併用剤（Ｃ）として、ビタミン類、セラミド類、レシチン類、甘草エキスのグリチルリチン酸類、ラズベリー類、ラベンダー、ジャスミン、ペパーミント、ローズマリー、ローマンカモミール、ユーカリ、ヒノキチオール、竹エキス、アロエエキス、カテキン、グレープフルーツ、レモン、ホホバ油、オリーブ油、柑橘油、海藻エキス、スクワラン類、ソルビトール、ブドウ糖類、ならびに コラーゲンなどのアミノ酸類の内の少なくとも一種を併用することにより、より効率よく本発明の課題を解決することが出来るが、中でもレシチン類を配合・坦治させると、該レシチン類が酵素、補酵素を経皮吸収させる効果を高め、本発明の課題である皮膚・肌の張り・艶を高める効果が助長される。
なお、本発明において、酵素（Ａ）類と、補酵素（Ｂ）類の坦治割合としては、１：９９から９９：１と広範囲で良いが、その中では１０：９０〜５０：５０の配合割合が良い。繊維に対する付着量としては、固形分にして０．００５〜１．０００％で良いが、工業化ベースでは０．０１〜０．５％で十分である。
また、前述の酵素と補酵素の坦治体 あるいは 補酵素とレシチンなどの併用剤（Ｃ）の併用割合としては、３０：７０から９５：５が良いが、中でも４０：６０〜８０：２０が本発明の課題達成のために良い。繊維に対する付着量としては、酵素ならびに補酵素の添加量で異なるが、実質的には固形分にして、０．０１〜１．００％で良いが、工業化ベースでは０．０２〜０．７０％で十分である。
この際、併用剤（Ｃ）の効果は極めて顕著であり、併用剤（Ｃ）中でもレシチンを併用使用すると、酵素・補酵素の坦治体 あるいは 補酵素成分の皮膚からの浸透、いわゆる経皮吸収性を高め、併用剤（Ｃ）を使用しないものに対し、歴然とした効果の差異が生じる。
本発明において、前述の加工剤は通常の状態でも良いが、加工方法によってはマイクロカプセル、サイクロデキストリンによる包接体、あるいは ベシクル構造体化された形で使用する方法もある。
また 本発明において、マイナスイオン加工剤、光触媒加工剤、抗菌防臭加工剤、消臭加工剤などと組み合わせても、何ら問題発生はなく、むしろ 両者の機能・性能が発現できるため、好ましい組合わせと言える。
本発明においてマイナスイオン加工剤とは、トルマリン、古代海底堆積物質（隆起物）、微弱放射線を発する天然鉱石などを微粉砕して、繊維類や不織布などの繊維ウエブなどに付着・加工をし易くしたモノを言うが、これらに限定されるものではない。
また 本発明に言う光触媒加工剤とは、ナノもしくはミクロン微粒子のアナターゼ型二酸化チタン、アパタイトで被覆した二酸化チタン、チタンとケイ素の複合酸化物などの光触媒活性を有するもので、繊維類や不織布などの繊維ウエブなどに付着・加工をし易くしたモノを言うが、これらに限定されるものではない。
また 本発明に言う抗菌防臭加工剤とは、銀や銅、亜鉛などの無機イオンをアパタイトやゼオライトなどに担持させた無機化合物、塩化ベンザルコニウムやセチルピリジニュム塩などの第４級アンモニウム塩、ビグアナイド系化合物、ジンクピリチオン、ホウ素系化合物、ベンゾイミダゾール系化合物、キチン・キトサン類などで、繊維類や不織布などの繊維ウエブなどに付着・加工をし易くしたモノを言うが、これらに限定されるものではない。
また 本発明に言う消臭加工剤とは、ポリカルボン酸化合物、ならびに それの銅、鉄、亜鉛などの置換体、ポリフェノール系化合物、ならびにそれの銅、鉄、亜鉛置換体、カテキン、ヒノキチオール、微多孔質な無機系ゼオライト、活性炭などを言うが、これらに限定されるものではない。
本発明に言う繊維素材は、木綿、麻、絹、羊毛などの天然繊維、レーヨン、テンセル、リヨセルなどの半合成繊維、ポリエステル、ポリアミド、ポリアクリルニトリル系合成繊維、ならびに それらの複合体などを意味するが、特にこれらに限定されるものではない。
また 繊維素材の形態としては、ステープル、フィラメント糸ならびに その加工糸などからなる織物、編物を言うが、さらには繊維ウエブ形態でも良い。
なお、繊維ウエブとは、不織布やティッシュペーパー、ウエットティッシュ、食品包装紙などの紙類などを言う。本願で対象とする繊維ウエブは、用途によって異なるが、介護用途ではマット類は目付が５０〜５００ｇ／ｍ２（５０未満では破れや尿漏れなど機能しにくく、５００以上ではごわごわして取り扱い性が悪く、実用性に乏しいため、せっかく機能を付与しても効果が生かせない）、オムツ類は１０〜１００ｇ／ｍ２が好ましく（１０未満では、破れ、尿漏れなど機能性が悪く、１００を越えるとごわごわで実用風合いからかけ離れてものになる）、ティッシュペーパーは５〜３０ｇ／ｍ２（５未満では使用時に破れやすく、３０を越えると分厚すぎて実用上問題がある）、ウエットティッシュ１０〜１００ｇ／ｍ２（ティッシュペーパーと同様に１０未満では破れやすく、１００を越えると分厚すぎて実使用上好ましくない）、食品包装紙は５〜５０ｇ／ｍ２（５未満では破れやすく実用性がない。また、５０を越えると分厚すぎて作業性が悪いばかりではなく、価格的にも実用性の低いものになる）が良い。
本発明に言う繊維用加工剤の形態としては、通常の水溶液形態、エマルジョン形態など いずれの形態でも良く、これらに限定されるものではない。
本発明において、加工剤を繊維に付着させる方法としては、パディング法、液中処理法、スプレー法、ならびに コーティング法などいずれの方法でも良く、加工後は風乾（自然乾燥）、乾燥−熱処理など いずれの方法でも良いが、乾燥−熱処理をした方が効果の洗濯耐久性を高める意味からも良い。なお、熱処理条件としては、１３０〜１８０℃で０．５〜３．０分間が良い。
なお、本発明において 繊維に加工する場合、洗濯耐久性を向上させるために、バインダーを併用する場合があるが、そのバインダーとしては、アクリル酸エステル系、ウレタン系、シリコン系、フッ素系、エポキシ系などのポリマー、ならびに アクリル・シリコン系、ウレタン・シリコン系などの複合系バインダーが良く、単独使用あるいは併用使用いずれでも良い。
次に、本発明の繊維用加工剤のメイン機能・性能である抗酸化性は元大阪市立大学大学院の中谷教授が開発した方法で、リノール酸メチルの加熱強制通気抑制活性測定法（ＯＳＩ法）を用いて測定した。コントロール対比 ２．０以上あれば、抗酸化効果が認められる。
また、本発明の保湿効果、美肌効果は実際にマイクロスコープで肌を１５０倍に拡大し、写真撮影によって目視判定した。その際 通常の何もしていない乾燥荒れ肌の状態を基準にして級別判定した。５級：保湿性、美肌効果 極めて良好。４級：保湿性、美肌効果 良好。３級：保湿性、美肌効果 普通。２級：保湿性、美肌効果 やや不良。１級：保湿性、美肌効果 不良。
以下 実施例でもって、さらに本発明について説明する。
In practicing the present invention, an enzyme, a combination of coenzymes, and a combination of additives such as lecithin will be described. That is, as an enzyme (A), at least one of enzymes such as oxidoreductase, transferase, hydrolase, lyase, isomerase, ligase, and proteins and amino acids, and as a coenzyme (B), lactate dehydrogenase, adenosine triphosphate Acid, phosphoenolpyruvate, acetyl phosphate, glucose phosphate, coenzyme A, tetrahydrofolate, nicotinamide adenine dinucleotide, coenzyme Q (ubicurenone: CoQ10), lipoic acid (α-lipoic acid), coenzyme B12 The present invention is intended to accurately solve the problems of the present invention by reacting and curing at least one coenzyme such as. Among them, a carrier of an enzyme (A) related to a protein, peptide, or amino acid and a coenzyme (B) such as coenzyme Q or lipoic acid can solve the problem of the present invention more clearly. . At that time, as will be described later, when the lecithins (C) are blended and cured, the problem achievement effect of the present invention is further enhanced.
By the way, the amino acid referred to in the present invention means glutamic acid, aspartic acid, glycine, cystine, serine, histidine, lysine, arginine, leucine and the like, and further includes silk amino acids such as silk protein and sericin. It is not limited to.
In the present invention, the carrier of the enzyme (A) and coenzyme (B) is used as a concomitant agent (C) as vitamins, ceramides, lecithins, licorice extract glycyrrhizic acids, raspberries, lavender. , Jasmine, peppermint, rosemary, roman chamomile, eucalyptus, hinokitiol, bamboo extract, aloe extract, catechin, grapefruit, lemon, jojoba oil, olive oil, citrus oil, seaweed extract, squalane, sorbitol, glucose, collagen, etc. By using at least one of the amino acids in combination, the problem of the present invention can be solved more efficiently. Among these, when lecithins are blended and cured, the lecithins transdermally convert the enzymes and coenzymes. Increases the effect of absorption and enhances skin, skin tension and gloss, which are the subject of the present invention. That effect is promoted.
In the present invention, the treatment ratio of the enzyme (A) and the coenzyme (B) may be in a wide range from 1:99 to 99: 1. Among them, 10:90 to 50:50 Good blending ratio. The adhesion amount to the fiber may be 0.005 to 1.000% in terms of solid content, but 0.01 to 0.5% is sufficient on an industrialized basis.
In addition, as a combination ratio of the above-mentioned enzyme and coenzyme carrier or a combination agent (C) such as coenzyme and lecithin, 30:70 to 95: 5 is preferable, and 40:60 to 80:20 is particularly preferable. It is good for achieving the object of the present invention. The amount of adhesion to the fiber differs depending on the amount of enzyme and coenzyme added, but it may be substantially 0.01 to 1.00% in terms of solid content, but 0.02 to 0.70% on an industrialized basis. Is enough.
At this time, the effect of the concomitant (C) is extremely remarkable. When lecithin is used in combination with the concomitant (C), penetration of the enzyme / coenzyme carrier or coenzyme component from the skin, so-called percutaneous absorption. As a result, the effect is remarkably different from that in which the combination drug (C) is not used.
In the present invention, the above-mentioned processing agent may be in a normal state, but depending on the processing method, there is a method of using it in the form of a microcapsule, an inclusion body with cyclodextrin, or a vesicle structure.
In the present invention, there is no problem even if combined with a negative ion processing agent, a photocatalyst processing agent, an antibacterial and deodorizing processing agent, a deodorizing processing agent, etc. I can say that.
In the present invention, the negative ion processing agent is easy to adhere and process on fiber webs such as fibers and non-woven fabrics by pulverizing tourmaline, ancient seabed sediment (raised matter), natural ore that emits weak radiation, etc. However, it is not limited to these.
In addition, the photocatalytic processing agent referred to in the present invention has photocatalytic activity such as nano- or micron fine particle anatase-type titanium dioxide, titanium dioxide coated with apatite, titanium-silicon composite oxide, and the like such as fibers and non-woven fabrics. Although the thing which made it easy to adhere and process to a fiber web etc. is said, it is not limited to these.
The antibacterial and deodorizing agent referred to in the present invention is an inorganic compound in which an inorganic ion such as silver, copper or zinc is supported on apatite or zeolite, or a quaternary ammonium salt such as benzalkonium chloride or cetylpyridinum salt. , Biguanide compounds, zinc pyrithione, boron compounds, benzimidazole compounds, chitin / chitosans, etc. that are easy to adhere and process on fiber webs such as fibers and non-woven fabrics, but are limited to these It is not a thing.
In addition, the deodorant processing agent referred to in the present invention is a polycarboxylic acid compound and its substitute, such as copper, iron, and zinc, a polyphenol compound, and its copper, iron, zinc substitute, catechin, hinokitiol, fine Although porous inorganic zeolite, activated carbon, etc. are said, it is not limited to these.
The fiber material referred to in the present invention means natural fibers such as cotton, hemp, silk, and wool, semi-synthetic fibers such as rayon, tencel, and lyocell, polyester, polyamide, polyacrylonitrile-based synthetic fibers, and composites thereof. However, it is not particularly limited to these.
The form of the fiber material is a woven fabric or a knitted fabric made of staples, filament yarns and processed yarns, but may be in the form of a fiber web.
In addition, a fiber web means papers, such as a nonwoven fabric, tissue paper, wet tissue, food packaging paper, etc. The fiber web used in the present application differs depending on the application, but in mating applications, mats have a basis weight of 50 to 500 g / m 2 (below 50, it is difficult to function such as tearing or urine leakage, and 500 or more is stiff and easy to handle. It is bad and lacks practicality, so even if it is given a function, the effect cannot be utilized. The diaper is preferably 10 to 100 g / m 2 (If it is less than 10, the functionality such as tearing and urine leakage is bad, and it exceeds 100. Tissue paper is 5 to 30 g / m 2 (less than 5 is easy to tear when used, and more than 30 is too thick to cause practical problems), 10 to 100 g of wet tissue / M 2 (Similar to tissue paper, it is easy to tear if it is less than 10, and if it exceeds 100, it is too thick to be practically used), food packaging Paper is 5 to 50 g / m 2 (less than 5 is easy to tear and has no practicality. If it exceeds 50, it is too thick and not only poor in workability but also low in practicality in price) .
The form of the fiber processing agent referred to in the present invention may be any form such as a normal aqueous solution form or an emulsion form, but is not limited thereto.
In the present invention, as a method of attaching the processing agent to the fiber, any method such as padding method, submerged treatment method, spray method, and coating method may be used, and after processing, air drying (natural drying), drying-heat treatment, etc. However, the method of drying and heat treatment may be effective from the viewpoint of increasing the durability of washing. In addition, as heat processing conditions, it is good for 0.5 to 3.0 minutes at 130-180 degreeC.
In addition, when processing into a fiber in this invention, in order to improve washing durability, a binder may be used together, but as the binder, acrylate ester type, urethane type, silicon type, fluorine type, epoxy type Polymers such as these, and composite binders such as acrylic / silicone and urethane / silicone may be used alone or in combination.
Next, the antioxidant function, which is the main function and performance of the fiber processing agent of the present invention, is a method developed by former Professor Nakatani of Osaka City University graduated. It measured using. If the control contrast is 2.0 or more, an antioxidant effect is observed.
In addition, the moisturizing effect and the skin beautifying effect of the present invention were actually determined visually by photographic enlargement of the skin 150 times with a microscope. At that time, the judgment was made according to the classification based on the condition of dry and rough skin, which is usually nothing. Grade 5: Moisturizing, skin beautifying effect very good. Fourth grade: good moisturizing and skin beautifying effect. 3rd class: Moisturizing, skin beautifying effect. Second grade: Moisturizing property, skin beautifying effect, somewhat poor. 1st grade: Moisturizing property and skin beautifying effect are poor.
Hereinafter, the present invention will be further described with reference to examples.
プロテアーゼ（酵素Ａ）２０重量％、α−リポ酸（補酵素Ｂ）２０重量％、ソルビット１０重量％、クエン酸５重量％、水４５重量％からなる混合物を４０℃で２時間ミキシングを行い、繊維用加工剤とした。次いで、木綿１００％からなる丸編みニットに前記加工剤を１０重量％、アクリル酸エステル系バインダーを３重量％、残りが水の割合で配合した加工液を作製し、マングルにてピックアップが１００％になるようにパディングを行い、次いで、１００℃で３分間 乾燥後、１５０℃で１分間熱処理を施した。かかる加工ニットで肌着を作成し、実着用テストをした結果、保湿性、美肌効果（肌のハリ・艶）が高くスキンケア性の良好な製品であった。
（比較例１）
比較として、実施例１の繊維用加工剤において、プロテアーゼ（酵素Ａ）を省き、その分を水に置き変えた加工剤を製造し、後は実施例１と同様に加工、縫製、実着用テストを実施したが、実施例１ほどの保湿性、肌の美肌効果（肌のハリ・艶）は得られなかった。
（比較例２）
実施例１の繊維用加工剤において、プロテアーゼ（酵素Ａ）２０重量部 ならびに、α―リポ酸（補酵素Ｂ）２０重量部の代わりに水を４０重量部用い、後は実施例１と同様に実施したが、保湿性、美肌効果は全く得られなかった。
Mixing a mixture of protease (enzyme A) 20% by weight, α-lipoic acid (coenzyme B) 20% by weight, sorbit 10% by weight, citric acid 5% by weight, water 45% by weight at 40 ° C. for 2 hours, It was set as the textile processing agent. Next, a processing liquid is prepared by blending 10% by weight of the above processing agent, 3% by weight of an acrylate ester binder, and the remaining water in a circular knitting knit made of 100% cotton. Then, padding was performed, followed by drying at 100 ° C. for 3 minutes and then heat treatment at 150 ° C. for 1 minute. As a result of creating an underwear with such a processed knit and carrying out an actual wearing test, it was a product with high skin retention and moisturizing properties and skin effect (skin and gloss).
(Comparative Example 1)
As a comparison, in the fiber processing agent of Example 1, a protease (enzyme A) was omitted, and a processing agent in which the amount was replaced with water was manufactured. Thereafter, processing, sewing, and actual wearing test were performed in the same manner as in Example 1. However, the moisture retention and skin beautifying effects (skin and gloss) of the skin as in Example 1 were not obtained.
(Comparative Example 2)
In the fiber processing agent of Example 1, 40 parts by weight of water was used instead of 20 parts by weight of protease (enzyme A) and 20 parts by weight of α-lipoic acid (coenzyme B). Although it was carried out, no moisturizing properties and skin beautifying effects were obtained.
ホスファチジルコリン系レシチン（併用剤Ｃ）２０重量％、コエンザイムα−リポ酸（補酵素Ｂ）２０重量％、ポリオキシエチレン系乳化剤１０重量％、液安定化剤ソルビット１０重量％、残りが水からなる混合物を４０℃で２時間ミキシングし、繊維用加工剤となした。かかる加工剤を実施例１と同様に、木綿１００％平織物に１０重量％、アクリル酸エステル系バインダー３重量％、残りが水の割合で配合した加工液を作製した。後は実施例１と同様に加工を行い、布団側地にして実着用テストを行った結果、手足に対し、極めて良好な保湿性、美肌効果（肌のハリ・艶）が得られた。
（比較例３）
比較として、実施例２の繊維用加工剤において、ホスファチジルコリン系レシチン（併用剤Ｃ）２０重量％を除き、その代わりに水を加えた繊維用加工剤を製造した。かかる繊維用加工剤を用い、後は実施例２と同様に加工、布団側地に縫製、実着用テストを行ったが、比較例１と同様に、実施例２に比べ、良好な保湿性、美肌効果（肌のハリ・艶）は得られなかった。
（比較例４）
実施例２において、ホスファチジルコリン系レシチン（併用剤Ｃ）２０重量％、コエンザイムα−リポ酸（補酵素Ｂ）２０重量％を水に置き換え、後は実施例２と同様に行ったが、全く良好な保湿性、美肌効果は得られなかった。
A mixture comprising 20% by weight of phosphatidylcholine-based lecithin (concomitant C), 20% by weight of coenzyme α-lipoic acid (coenzyme B), 10% by weight of polyoxyethylene emulsifier, 10% by weight of liquid stabilizer sorbit, and the balance water Was mixed at 40 ° C. for 2 hours to obtain a fiber processing agent. In the same manner as in Example 1, a processing liquid was prepared by blending 10% by weight of such a processing agent into 100% cotton plain woven fabric, 3% by weight of an acrylate-based binder, and the balance being water. Thereafter, processing was performed in the same manner as in Example 1 and an actual wearing test was performed on the futon side. As a result, extremely good moisture retention and skin beautifying effects (skin and gloss of skin) were obtained for the limbs.
(Comparative Example 3)
As a comparison, the fiber processing agent of Example 2 was manufactured by adding 20% by weight of phosphatidylcholine-based lecithin (combination agent C) and adding water instead. After using such a fiber processing agent, processing was performed in the same manner as in Example 2, sewing was performed on the futon side, and an actual wearing test was performed. As in Comparative Example 1, better moisture retention than in Example 2, No skin effect (skin / gloss) was obtained.
(Comparative Example 4)
In Example 2, 20% by weight of phosphatidylcholine-based lecithin (Concomitant C) and 20% by weight of coenzyme α-lipoic acid (Coenzyme B) were replaced with water. Thereafter, the same procedure as in Example 2 was performed. Moisturizing and skin beautifying effects were not obtained.
ペプチダーゼ（酵素Ａ）１５重量％、アデノシン三リン酸（補酵素Ｂ）１５重量％、ホスファチジルノシトール系レシチン（併用剤Ｃ）１０重量％、液安定剤として乳酸３重量％、ソルビット１０重量％残りが水からなる混合物を４０℃で２時間ミキシングを行い、繊維用加工剤を製造した。かかる繊維用加工剤１０重量％、アクリル・シリコーン系バインダー３重量％残りが水からなる加工液を調整し、該加工液に木綿５５％／ポリエステル４０％／スパンデックス５％からなるニットを浸漬後、マングルで絞り、後は実施例１と同様に加工、縫製、実着用テストを実施した結果、極めて保湿性に優れ、美肌効果（肌のハリ／艶）が高かった。 Peptidase (enzyme A) 15% by weight, adenosine triphosphate (coenzyme B) 15% by weight, phosphatidylnositol lecithin (combination agent C) 10% by weight, lactic acid 3% by weight, sorbite 10% by weight remaining The mixture consisting of water was mixed at 40 ° C. for 2 hours to produce a fiber processing agent. A processing liquid comprising 10% by weight of the fiber processing agent and 3% by weight of the acrylic / silicone binder, and the rest being water, was prepared, and after immersing a knit made of 55% cotton / 40% polyester / 5% spandex in the processing liquid, As a result of squeezing with a mangle and then processing, sewing and actual wearing test in the same manner as in Example 1, it was found to be extremely excellent in moisturizing properties and high skin beautifying effect (skin / gloss).
実施例３において、ホスファチジルノシトール系レシチン（併用剤Ｃ）の代わりに水を１０重量％添加し、後は実施例３と同様に加工を行い、実着用テストを行ったが、実施例３に比べ、保湿性、美肌効果は小さく、実施例１に類似の効果であった。
（比較例５）
比較として、実施例３におけるペプチダーゼ（酵素Ａ）１５重量％、アデノシン三リン酸（補酵素Ｂ）１５重量％、ホスファチジルノシトール系レシチン（併用剤Ｃ）１０重量％の代わりに水を４０重量％置き換えたもので、後は実施例３と同様に行ったが、良好な保湿性、美肌効果は得られなかった。
In Example 3, 10% by weight of water was added instead of the phosphatidylnositol-based lecithin (Concomitant C), and after that, processing was performed in the same manner as in Example 3 and an actual wearing test was performed. In comparison, the moisturizing property and the skin beautifying effect were small and similar to Example 1.
(Comparative Example 5)
As a comparison, 40% by weight of water was used instead of 15% by weight of peptidase (enzyme A), 15% by weight of adenosine triphosphate (coenzyme B), and 10% by weight of phosphatidylnositol lecithin (combination agent C) in Example 3. After replacement, the same procedure as in Example 3 was performed, but good moisture retention and skin beautifying effects were not obtained.
下記成分をエアゾール噴射用耐圧ガラス容器に入れ、エアゾール組成物を製造した。
実施例２で得た加工剤 ５重量％
エタノール ２５重量％
精製水 バランス
ジメチルエーテル／ＬＰＧ（混合ガス ５／５） ８重量％
このエアゾール組成物をアクリル繊維１００％からなる毛布にスプレー加工をし得られた製品で実着用テストを実施した。その結果、保湿性に優れ、美肌効果の高いものであることが判った。
The following components were put into a pressure-resistant glass container for aerosol injection to produce an aerosol composition.
5% by weight of the processing agent obtained in Example 2
Ethanol 25% by weight
Purified water Balance dimethyl ether / LPG (mixed gas 5/5) 8% by weight
An actual wearing test was conducted on a product obtained by spraying the aerosol composition on a blanket made of 100% acrylic fiber. As a result, it was found that the skin was excellent in moisture retention and had a high skin beautifying effect.
実施例３に用いた繊維用加工剤を微多孔な二酸化ケイ素からなるセルに内包したマイクロカプセルとした。かかるマイクロカプセルを１０重量％、アクリル酸エステル系バインダー３重量％、残りが水からなる加工液を調整し、該加工液に木綿１００％からなるブロード生地を浸漬−マングル絞り−１００℃×５分間乾燥−１６０℃×１分間熱処理を行い、加工製品とした。かかる加工製品をブラウスに縫製し、実着用テストをした結果、保湿性、美肌効果の高い衣類であった。
上述の実施例、比較例、参考例の保湿性、美肌効果 ならびに、抗酸化性データを一覧表にして示す。
The moisturizing property, skin beautifying effect and antioxidant data of the above-mentioned Examples, Comparative Examples and Reference Examples are shown in a list.
Claims (9)
The fiber processing agent according to claim 1, wherein the processing agent is a composite of at least one of a negative ion processing agent, a photocatalytic processing agent, an antibacterial deodorizing processing agent, and a deodorizing processing agent. Adhered textile products.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR100961670B1 (en) | 2009-02-02 | 2010-06-09 | 주식회사 태평양산업 | Method for preparation of fabric coating composition |
| WO2022168894A1 (en) * | 2021-02-05 | 2022-08-11 | 日産化学株式会社 | Cloth or paper anti-pollution material |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100961670B1 (en) | 2009-02-02 | 2010-06-09 | 주식회사 태평양산업 | Method for preparation of fabric coating composition |
| WO2022168894A1 (en) * | 2021-02-05 | 2022-08-11 | 日産化学株式会社 | Cloth or paper anti-pollution material |
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