JP2006298963A - Grease for constant velocity joint and constant velocity joint - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a grease for constant velocity joint reduced in abrasion and friction and capable of preventing occurrence of vibration and a constant velocity joint in which the grease is sealed. <P>SOLUTION: The grease for constant velocity joint comprises an alkali metal salt of molybdic acid and a layered compound as essential components in a base grease obtained by formulating a base oil with a thickening agent and the thickening agent is a diurea compound represented by formula (1): R<SP>1</SP>-NHCONH-R<SP>2</SP>-NHCONH-R<SP>3</SP>(wherein R<SP>1</SP>and R<SP>3</SP>are each a 4-24C straight-chain alkyl group or a cyclohexyl group and they may be the same or different and R<SP>2</SP>is a 6-15C aromatic hydrocarbon group) and grease for constant velocity joint is sealed in the constant velocity joint. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to a grease for a constant velocity joint used in an automobile and a constant velocity joint in which this grease is sealed, and particularly to a tripod type constant velocity joint.

  With the recent increase in output and weight of automobile engines, the lubrication conditions inside the constant velocity joint have shifted to the higher surface pressure side. In particular, recently, a low-vibration constant velocity joint (see Patent Document 1) that receives torque by point contact between a journal, an inner roller, and the like has appeared, and the load applied to the joint has become increasingly severe. As the lubrication condition becomes higher, wear becomes a problem inside the constant velocity joint. When wear increases, it causes a problem of deterioration of durability (flaking resistance) and deterioration of vibration. On the other hand, in the constant velocity joint for automobiles, not only the durability is improved, but also the quietness (low vibration) is required to be further improved in consideration of the ride comfort of the passenger.

  Conventionally, lithium-based extreme pressure grease containing a sulfur-phosphorus extreme pressure agent and lithium-based extreme pressure grease containing molybdenum disulfide are used for the constant velocity joint. These greases have very large wear under high surface pressure, are not satisfactory in terms of durability, and are not sufficient in terms of low vibration. In recent years, in order to improve wear resistance and durability, a grease in which an extreme pressure agent or an antiwear agent is added to a urea-based grease has been proposed. For example, for the purpose of suppressing wear and preventing flaking, a grease comprising a combination of an overbased sodium sulfonate and a sulfur-based additive is known (see Patent Document 2). These are not sufficient in terms of wear resistance, and low vibration is not considered. We have also proposed to use both molybdate and molybdenum oxide in combination with friction modifiers and extreme pressure agents to achieve both wear resistance and low friction under severe conditions. Molybdenum oxide, calcium molybdate, molybdenum A combination of an acid and a friction modifier or an extreme pressure agent is known (see Patent Document 3). In the contents shown in these, it cannot be said that neither wear resistance nor low vibration is sufficient.

In addition, as the demand for quietness in automobiles increases, the reduction of vibrations generated from constant velocity joints is more demanded, and there is a problem that the conventional constant velocity joint grease cannot satisfy the requirements.
In particular, continuous quietness in automobiles is required, and there is a problem that the conventional constant velocity joint grease cannot satisfy the demand for reducing vibration with time.
JP 2000-320563 A JP 2002-20776 A JP 2000-53989 A

  The present invention has been made to cope with such a problem, and is a constant velocity joint that can efficiently and continuously lubricate a constant velocity joint, effectively reduce wear and friction, and prevent occurrence of vibration. The purpose is to provide grease for use and a constant velocity joint filled with this grease.

(式中、R¹ および R³ は、炭素原子数 4〜24 の直鎖アルキル基またはシクロヘキシル基であり、R¹ および R³ は、同一であっても異なっていてもよい。R² は、炭素原子数 6〜15 の芳香族系炭化水素基である。)
上記層状化合物は、二硫化モリブデン、二硫化タングステン、メラミンシアヌレート、グラファイト、窒化ホウ素およびセリサイトから選ばれた少なくとも1つの物質であることを特徴とする。
等速ジョイントに用いられる等速ジョイント用グリースであって、該グリースは、等速ジョイントにおける摩擦摩耗面または摩耗により露出した鉄系金属新生面において酸化鉄とともにモリブデン化合物を含有する膜を形成できるモリブデン酸のアルカリ金属塩を含有することを特徴とする。 The grease for constant velocity joints of the present invention is characterized in that a base grease obtained by blending a base oil with a thickener contains an alkali metal salt of molybdic acid and a layered compound as essential components.
The thickener is a diurea compound represented by the following formula (1).

(In the formula, R ¹ and R ³ is a linear alkyl group or a cyclohexyl group having a carbon number of 4 to 24, R ¹ and R ³ may .R ² be different even identical, (It is an aromatic hydrocarbon group having 6 to 15 carbon atoms.)
The layered compound is at least one substance selected from molybdenum disulfide, tungsten disulfide, melamine cyanurate, graphite, boron nitride, and sericite.
A grease for a constant velocity joint used for a constant velocity joint, wherein the grease is capable of forming a film containing a molybdenum compound together with iron oxide on a friction wear surface or a new ferrous metal surface exposed by wear in the constant velocity joint. It contains the alkali metal salt of.

  The constant velocity joint of the present invention is a constant velocity joint in which rotational torque is transmitted by the engagement between the track groove and the rolling element, and the rolling element rolls along the track groove to move in the axial direction. The grease filled in the constant velocity joint is the constant velocity joint grease.

  The grease for constant velocity joints of the present invention contains the alkali metal salt of molybdic acid and a layered compound as essential components in the base grease formed by adding a thickener to the base oil. Wear and friction can be suppressed, induced thrust can be reduced, and vibration generated in the constant velocity joint can be suppressed.

  Since the constant velocity joint of the present invention is a constant velocity joint in which the above grease is sealed, vibration can be sufficiently suppressed and the quietness and durability of the automobile can be improved.

In order to provide constant velocity joint grease that can reduce wear and friction and prevent vibrations, and constant velocity joints filled with this grease, samples of constant velocity joints incorporating various constant velocity joint greases are provided. In addition to conducting an endurance test, an induced thrust test was performed to evaluate the wear resistance and vibration resistance. The present invention is based on the knowledge obtained by such an evaluation test.
As a result of intensive investigations on various constant velocity joint greases, it was found that among the molybdates, the alkali metal salts of molybdic acid have significant wear resistance. Moreover, by blending the alkali metal salt of molybdic acid, a thickener with good wear resistance, and a layered compound as essential components, it is possible to effectively prevent wear of each sliding portion of the constant velocity joint, etc. The vibration reduction of the high speed joint was achieved, and the present invention was completed.

Regarding the effect of blending the alkali metal salt of molybdic acid, when the alkali metal salt of molybdic acid is blended with grease for constant velocity joints, molybdate oxide on the frictional wear surface of the constant velocity joint or the newly formed iron metal surface exposed by wear. As a result of the surface analysis of the sliding surface, it was found that the alkali metal salt reacted to produce a film containing a molybdenum compound together with iron oxide on the sliding surface. This molybdenum oxide film is considered to suppress wear.
In addition, with regard to the effect of blending layered compounds as essential components, by combining the alkali metal salt of molybdate and the layered compound, in addition to wear resistance, vibration of the constant velocity joint can be reduced in a wide angle range. I found it to be achieved. This is because a layered compound having a cleavage property intervenes between wear-resistant sliding surfaces on which a molybdenum compound film is formed by reaction of an alkali metal salt of molybdic acid, and the layered compound is cleaved by shearing. Therefore, it is considered that it acts as a solid lubricant and exhibits low friction.
In other words, by achieving both wear resistance and low vibration characteristics, long life can be ensured and passengers feel uncomfortable even if the sliding part becomes high surface pressure due to high output and compactness of the engine. The applied vibration can be reduced. The present invention has been completed based on such findings.

Base oils of base grease components that can be used in the present invention include mineral oils such as naphthenic, paraffinic, liquid paraffin, hydrodewaxed oil, polyglycol oils such as polyalkylene glycol, ethers such as alkyldiphenyl ether and polyphenyl ether. Synthetic oil, diester oil, ester synthetic oil such as polyol ester oil, silicone oil such as polydimethylsiloxane and polyphenylmethylsiloxane, hydrocarbon synthetic oil such as GTL base oil, poly-α-olefin oil, etc. , And these mixed oils.
Of these, mineral oils such as naphthenic and paraffinic ones are preferable because they are inexpensive and easy to use industrially and have excellent boot resistance that does not deteriorate the boots of constant velocity joints.

(式中、R¹ および R³ は、炭素原子数 4〜24 の直鎖アルキル基またはシクロヘキシル基であり、R¹ および R³ は、同一であっても異なっていてもよい。R² は、炭素原子数 6〜15 の芳香族系炭化水素基である。) Thickeners that can be used in the present invention include soaps such as lithium soaps, lithium complex soaps, strong lucium soaps, calcium complex soaps, aluminum soaps, aluminum complex soaps, and urea compounds such as diurea compounds and polyurea compounds. However, it is not particularly limited. However, considering wear resistance, it is desirable to use a diurea compound represented by the following formula (1).

(In the formula, R ¹ and R ³ is a linear alkyl group or a cyclohexyl group having a carbon number of 4 to 24, R ¹ and R ³ may .R ² be different even identical, (It is an aromatic hydrocarbon group having 6 to 15 carbon atoms.)

  A diurea compound is obtained by reaction of diisocyanate and a monoamine, for example. Examples of the diisocyanate include phenylene diisocyanate, diphenyl diisocyanate, phenyl diisocyanate, diphenylmethane diisocyanate, octadecane diisocyanate, decane diisocyanate, and hexane diisocyanate. Examples of the monoamine include octylamine, dodecylamine, hexadecylamine, octadecylamine, stearylamine, oleylamine, aniline, p-toluidine, cyclohexylamine and the like. Among these, particularly preferred monoamines are octylamine, octadecylamine and cyclohexylamine.

A urea compound is obtained by reacting an isocyanate compound and an amine compound. In order not to leave a reactive free radical, the isocyanate group of the isocyanate compound and the amino group of the amine compound are preferably blended so as to be approximately equivalent.
Base grease for blending various compounding agents by blending a urea compound with a base oil can be obtained. The base grease is produced by reacting an isocyanate compound and an amine compound in a base oil.

  Typical examples of the alkali metal salt of molybdic acid that can be used in the present invention include potassium molybdate, sodium molybdate, and lithium molybdate. Since the alkali metal salt of molybdic acid is a solid insoluble in oil, it exists in the grease in a dispersed state in the same manner as a solid lubricant such as molybdenum disulfide. The alkali metal salt of molybdic acid reacts at the lubrication interface of each sliding portion in the constant velocity joint to form molybdenum oxide on the metal surface. The mechanism by which the wear resistance is exhibited by the alkali metal salt of molybdic acid has not been clarified, but it is thought that the produced molybdenum oxide has wear resistance. Alkali metal salts of molybdic acid are usually industrial products with a particle size of about 200μm. However, the smaller the particle size, the easier it is to exist at the lubrication interface, and the effect is easily exhibited. Therefore, the particle size of the alkali metal salt of molybdic acid is preferably 50 μm or less.

The layered compound that can be used in the present invention is not particularly limited, but examples include molybdenum disulfide, tungsten disulfide, graphite, melamine cyanurate, boron nitride, sericite, mica, zinc sulfide, calcium carbonate, talc. , Montmorillonite, kaolinite, magnesium potassium titanate, and potassium potassium titanate. Of these, particularly preferred layered compounds are molybdenum disulfide, tungsten disulfide, melamine cyanurate, graphite, boron nitride, and sericite. The layered compounds can be used alone or in combination of two or more.
The particle size of the layered compound is not particularly limited, but it is preferably 20 μm or less in consideration of intervening in the sliding portion to exert its effect.

  The grease for constant velocity joints of the present invention can contain known additives as necessary in order to enhance its excellent performance. Examples of this additive include solid lubricants such as polytetrafluoroethylene resin, antioxidants such as amines, phenols, and sulfur compounds, rust inhibitors such as petroleum sulfonates, dinonylnaphthalene sulfonates, and sorbitan esters. Extreme pressure agents such as organic molybdenum compounds, sulfurized fats and oils, sulfur compounds typified by sulfurized olefins, thiophosphates, sulfur-phosphorus compounds typified by thiophosphites, phosphorus compounds typified by tricresyl phosphate , Phosphorus compounds, anti-wear agents such as organic zinc, detergents and dispersants such as metal sulfonates and metal phosphates, friction reducers such as organic molybdenum, oil-based agents such as wax compounds, fatty acid amides, fatty acids, amines and fats and oils Inactive metals such as benzotriazole and sodium nitrite , Polymethacrylates, viscosity index improvers such as polystyrene and the like. These can be added alone or in combination of two or more.

The blending ratio of the grease for constant velocity joints is preferably 20-98.8% by weight of base oil, more preferably 45-96.4% by weight, and preferably 1-40% by weight of thickener, more preferably 3-25% by weight. The alkali metal salt of molybdic acid is 0.1 to 10% by weight, more preferably 0.1 to 5% by weight, the layered compound is preferably 0.1 to 30% by weight, more preferably 0.5 to 25% by weight. Each is blended.
In the above composition, if the blending amount of the thickener is less than 1% by weight, the thickening effect is reduced and it is difficult to form a grease. If it exceeds 40% by weight, the obtained grease becomes too hard and the desired effect is obtained. It becomes difficult to be.
If the blending amount of the alkali metal salt of molybdic acid is less than 0.1% by weight, it will be difficult to obtain the desired effect, and if it is more than 10% by weight, the effect will not increase. Also, the price is high and not practical.
If the amount of the layered compound is less than 0.1% by weight, it is difficult to obtain the desired effect sufficiently, and if it is more than 30% by weight, the effect is not increased. Also, the price is high and not practical.

An example of a constant velocity joint using the grease for constant velocity joints of the present invention will be described with reference to FIG. 1A is a cross-sectional view of a tripod type constant velocity joint, FIG. 1B is a vertical cross-sectional view of the constant velocity joint of FIG. 1A, and FIG. 1C is FIG. It is a perspective view which shows the mutual relationship of the roller guide surface in FIG.
As shown in FIG. 1A, the constant velocity joint includes three cylindrical track grooves 2 in the axial direction of the inner peripheral surface of the outer joint member 1, and the triport member 4 inserted into the outer joint member 1. An annular roller 7 is rotatably inserted into the track groove 2 through a plurality of needle rollers 6 on the cylindrical outer peripheral surface of the three leg shafts 5 projecting in the radial direction. . The pair of roller guide surfaces 3 facing each other in the circumferential direction of each track groove 2 is a concave curved surface parallel to the axial direction, and the outer peripheral surfaces of the rollers 7 of the three leg shafts 5 are convex to fit the roller guide surface 3. It is a curved surface. Each roller 7 is movable along the track groove 2 while engaging with the roller guide surface 3 of the corresponding track groove 2 and rotating around the leg shaft 5. Further, as shown in FIG. 1B, the outer periphery of the outer ring 11 and the outer periphery of the shaft 10 are covered with a boot 12, and the constant velocity joint grease 13 is hermetically filled therein.

  As shown in FIG. 1B, when the rotational force is transmitted with the shaft 10 at the operating angle θ, the roller 7 and the roller guide surface 3 cross each other as shown in FIG. 1C. It becomes a relationship. In this case, the roller 7 tries to roll and move in the direction indicated by the arrow t in FIG. 1B, whereas the track groove 2 is a part of a cylindrical surface parallel to the axis of the constant velocity joint. 7 moves while being restrained by the track groove 2. As a result, a slip occurs between the roller guide surface 3 and the roller 7 to generate a slide resistance, and this slip generates an induced thrust in the axial direction. Such sliding resistance and induced thrust cause vibration and noise of the vehicle body, and affect the NVH (N: Noise noise, V: Vibration vibration, H: Harshness riding comfort) performance of the automobile. The grease for constant velocity joints of the present invention reduces this sliding resistance and induced thrust.

  Further, another example of the sliding tripod type constant velocity joint for the purpose of reducing the sliding resistance and the induced thrust will be described with reference to FIG. 2A is a cross-sectional view of another tripod type constant velocity joint, FIG. 2B is a cross-sectional view taken along the line AA of FIG. 2A, and FIG. 2C is a cross-sectional view of the ring. As shown in FIG. 2, the constant velocity joint includes an outer joint member 1 and a tripart member 4, one of the two shafts to be coupled is connected to the outer joint member 1, and the other is connected to the triport member 4.

  The outer joint member 1 has three track grooves 2 extending in the axial direction on the inner peripheral surface. Roller guide surfaces 3 are formed on the side walls of each track groove 2 facing each other in the circumferential direction. The triport member 4 has three leg shafts 5 projecting in the radial direction, and a roller 7 is attached to each leg shaft 5, and this roller 7 is accommodated in the track groove 2 of the outer joint member 1. . The outer peripheral surface of the roller 7 is a convex curved surface that fits the roller guide surface 3.

  The outer peripheral surface of the roller 7 is a convex curved surface having an arc having a center of curvature at a position radially away from the axis of the leg shaft 5 as a generating line, and the cross-sectional shape of the roller guide surface 3 is a Gothic arch shape. The roller 7 and the roller guide surface 3 make an angular contact. Even if the cross-sectional shape of the roller guide surface 3 is tapered with respect to the outer peripheral surface of the spherical roller, the angular contact between them can be realized. By adopting a configuration in which the roller 7 and the roller guide surface 3 form an angular contact in this manner, the posture of the roller is stabilized because the roller is less likely to shake. When the angular contact is not employed, for example, the roller guide surface 3 is constituted by a part of a cylindrical surface whose axis is parallel to the axis of the outer joint member 1, and the cross-sectional shape thereof is a generatrix of the outer peripheral surface of the roller 7. It can also be a corresponding arc.

  A ring 8 is fitted on the outer peripheral surface of the leg shaft 5. The ring 8 and the roller 7 are unitized via a plurality of needle rollers 6 to constitute a roller assembly that can be relatively rotated. That is, the cylindrical outer peripheral surface of the ring 8 is an inner raceway surface, and the cylindrical inner peripheral surface of the roller 7 is an outer raceway surface, and the needle rollers 6 are rotatably interposed between these inner and outer raceway surfaces. As shown in FIG. 2B, the needle roller 6 is incorporated in a so-called full roller state in which as many rollers as possible are inserted and no cage is provided. Reference numerals 9 and 9 indicate a pair of washers mounted in an annular groove formed on the inner peripheral surface of the roller 7 to prevent the needle roller 6 from falling off. These washers 9, 9 have a cut at one place in the circumferential direction, and are fitted in an annular groove on the inner peripheral surface of the roller 7 in a state of being elastically reduced in diameter.

  The outer peripheral surface of the leg shaft 5 has a straight shape parallel to the axis of the leg shaft 5 when viewed in a longitudinal section (FIG. 2A), and the long axis is a joint when viewed in a transverse section (FIG. 2B). The shape of the ellipse is perpendicular to the axis. The cross-sectional shape of the leg shaft 5 is substantially elliptical by reducing the thickness seen in the axial direction of the tripart member 4. In other words, the cross-sectional shape of the leg shaft 5 is such that the surfaces of the triport member 4 facing each other in the axial direction are retracted in the mutual direction, that is, on the smaller diameter side than the virtual cylindrical surface.

The inner peripheral surface of the ring 8 has an arcuate convex cross section. That is, the generatrix of the inner peripheral surface is a convex arc with a radius r (FIG. 2C). Since the cross-sectional shape of the leg shaft 5 is substantially elliptical as described above and a predetermined clearance is provided between the leg shaft 5 and the ring 8, the ring 8 is connected to the leg shaft 5. In addition to being able to move in the axial direction, it can swing and swing with respect to the leg shaft 5. Further, as described above, the ring 8 and the roller 7 are unitized so as to be rotatable relative to each other via the needle roller 6, so that the ring 8 and the roller 7 can swing as a unit with respect to the leg shaft 5. It is in. Here, swinging means that the axes of the ring 8 and the roller 7 are inclined with respect to the axis of the leg shaft 5 in a plane including the axis of the leg shaft 5.
In the present invention, in addition to the above structure in which the roller 7 is guided by the roller guide surface 3 and rolls correctly on the roller guide surface 3 while maintaining a posture parallel to the axis of the outer joint member 1, the constant velocity joint grease is used. Since 13 is enclosed in the outer joint member 1, the induced thrust of the sliding surface between the roller 7 and the roller guide surface 3 can be reduced, and the wear resistance can be maintained. Further, wear of the sliding portion between the leg shaft 5 and the ring 8 can be prevented.

The present invention will be specifically described with reference to examples and comparative examples, but is not limited to these examples.
Example 1, Example 4, Example 6, Example 8, Example 10 to Example 15, Comparative Example 1, Comparative Example 2, Comparative Example 4 and Comparative Example 6
It was produced by reacting 60.6 g of diphenylmethane-4,4'-diisocyanate, 31.3 g of octylamine and 66.2 g of stearylamine in 2000 g of mineral oil (kinematic viscosity at 100 ° C of 13.5 mm ² / sec). A base grease 1 was obtained by uniformly dispersing the urea compound. In this base grease 1, additives are blended according to the blending shown in Table 1 and Table 2, and the resulting compound is subjected to JIS consistency No. 1 using a three-stage roll mill. The grease for the constant velocity joint was obtained by adjusting to one grade (consistency: 310 to 340).

Example 2, Example 5 and Example 7
It was produced by reacting 60.3 g of diphenylmethane-4,4′-diisocyanate, 65.5 g of stearylamine and 24.1 g of cyclohexylamine in 2000 g of mineral oil (kinematic viscosity at 100 ° C .: 13.5 mm ² / sec) A base grease 2 was obtained by uniformly dispersing the urea compound. Additives were blended into this base grease 2 in the formulation shown in Table 1, and the resulting compound was JIS consistency No. 1 with a three-stage roll mill. The grease for the constant velocity joint was obtained by adjusting to one grade (consistency: 310 to 340).

Example 3, Example 9, Comparative Example 3, Comparative Example 5 and Comparative Example 7
Urea formed by reacting 158.2 g of diphenylmethane-4,4′-diisocyanate, 81.3 g of octylamine and 58.9 g of aniline in 2000 g of mineral oil (kinematic viscosity at 100 ° C .: 13.5 mm ² / sec) The base grease 3 was obtained by uniformly dispersing the compound. Additives were added to this base grease 3 in accordance with the formulation shown in Table 1, and the resulting compound was subjected to JIS consistency No. 3 using a three-stage roll mill. The grease for the constant velocity joint was obtained by adjusting to one grade (consistency: 310 to 340).

Comparative Example 8
In Comparative Example 8, base grease 4 was obtained by uniformly dispersing 150 g of 12-hydroxylithium stearate in 2000 g of mineral oil (kinematic viscosity at 100 ° C. of 13.5 mm ² / sec). In this base grease 4, molybdenum disulfide is blended as an extreme pressure agent in the blending shown in Table 2, and the resulting compound is subjected to JIS consistency No. 1 using a three-stage roll mill. The grease for the constant velocity joint was obtained by adjusting to one grade (consistency: 310 to 340).
These greases are subjected to an induced thrust test by the following test method, and the obtained results are also shown in Tables 1 and 2.

Induced thrust test;
Using an actual triport type constant velocity joint, the force generated in the axial direction when rotating with an operating angle and torque was measured as an induced thrust.
Measurement conditions: Rotation speed 150 rpm
Torque 392 Nm
Joint angle 4 ° and 10 °
Operating time 15 minutes
Joint type NTN: PTJ
Evaluation criteria: Indicated as a percentage (%) of induced thrust when the comparative example 8 is a reference grease and its initial performance is 100. Triport type constant velocity joints with an induced thrust ratio of less than 50% were evaluated as having excellent low vibration characteristics.

An endurance test;
Using an actual tripod type constant velocity joint, the wear depth of the journal portion (leg shaft) generated when rotating by applying an operating angle and torque was measured.
Test condition: 240 rpm
Torque 774 Nm
Joint angle 0 ° ~ 10 °
300 hours of operation time
Joint type NTN: PTJ
Evaluation Criteria: Triport type constant velocity joints with a wear depth of 30 μm or less after the test was evaluated as having excellent durability.

  Comprehensive evaluation: Tripport type constant velocity joints with an induced thrust ratio of less than 50% in the induced thrust test and a wear depth of the journal part of 30 μm or less in the durability test are excellent in low vibration and durability. In Table 1 and Table 2, “◯” was evaluated, and the others were evaluated as “impossible”.

  As shown in Tables 1 and 2, each example had low induced thrust and excellent durability. As for the comparative example, comparative example 1 does not reach the evaluation criteria for both induced thrust and durability performance, and comparative examples 2 to 7 have excellent durability due to the addition of the alkali metal salt of molybdic acid, but the induced thrust is an evaluation criterion. Was significantly below.

  The grease for constant velocity joints of the present invention can reduce the induced thrust, has excellent durability performance, and can maintain the effect for a long period of time. For this reason, it can be used for various constant velocity joints, preferably for automotive constant velocity joints. Among the constant velocity joints for automobiles, the present invention can be suitably used for plunging type constant velocity joints having more slipping elements than rolling.

It is a perspective view which shows the cross-sectional view of a triport type | mold constant velocity joint, the longitudinal cross-sectional view of a constant velocity joint, and the mutual relationship of a roller guide surface and a roller. It is a cross-sectional view of another triport type constant velocity joint, AA cross-sectional view in the figure, and a cross-sectional view of the ring.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Outer joint member 2 Track groove 3 Roller guide surface 4 Tripport member 5 Leg shaft 6 Needle roller 7 Roller 8 Ring 9 Washer 10 Shaft 11 Outer ring 12 Boot 13 Grease for constant velocity joint

Claims (5)

  A grease for constant velocity joints characterized in that an alkali metal salt of molybdic acid and a layered compound are contained as essential components in a base grease obtained by blending a thickener with a base oil. The constant velocity joint grease according to claim 1, wherein the thickener is a diurea compound represented by the following formula (1).

(In the formula, R ¹ and R ³ is a linear alkyl group or a cyclohexyl group having a carbon number of 4 to 24, R ¹ and R ³ may .R ² be different even identical, (It is an aromatic hydrocarbon group having 6 to 15 carbon atoms.)   3. The constant velocity according to claim 1, wherein the layered compound is at least one substance selected from molybdenum disulfide, tungsten disulfide, melamine cyanurate, graphite, boron nitride, and sericite. Grease for joints.   A grease for a constant velocity joint used for a constant velocity joint, wherein the grease is capable of forming a film containing a molybdenum compound together with iron oxide on a friction wear surface or a new ferrous metal surface exposed by wear in the constant velocity joint. A constant-velocity joint grease characterized by containing an alkali metal salt. A constant velocity joint in which rotational torque is transmitted by the engagement between the track groove and the rolling element, and the rolling element rolls along the track groove to move in the axial direction.
5. The constant velocity joint according to claim 1, wherein the grease sealed in the constant velocity joint is the grease for a constant velocity joint according to any one of claims 1 to 4.

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