JP2006298833A - Pencil-like or stick-like cosmetic material - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a pencil-like or stick-like cosmetic material having extraordinarily high water resistance/washing resistance (cosmetic preservation effect), excellent in close adhesiveness to the skin and usability (no sticky and rigid feeling) and cuttability. <P>SOLUTION: The pencil-like or stick-like cosmetic material comprises (a) one or more species selected from specific amino-modified or ammonium-modified high molecular silicones, (b) a wax which is solid-semisolid at room temperature (25°C), (c) a nonvolatile silicone-based liquid oil and (d) a powdery component. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to a pencil or stick cosmetic. More specifically, a pencil-shaped or stick-shaped makeup with excellent water resistance and washing resistance (make-up moisturizing effect), as well as excellent adhesion to the skin, feeling of use (no stickiness, no stickiness), and machinability Regarding fees. The present invention is particularly suitably applied to eyebrow.

  One of the properties required for cosmetics is “make-up mochi”. To improve this make-up, traditionally, a silicone-based film agent (silicone resin, etc.) has been blended, and make-up mochi has been improved by its film-forming ability. The technique to improve is known (for example, refer patent documents 1-3). In many cases, the silicone-based film agent is dissolved in a volatile oil and used to form a film by volatilization of the volatile oil. For this reason, it is necessary to increase the sealing property and confidentiality of the cosmetic container, and there are problems such as restrictions on the design of the container and production cost. In addition, there are problems in terms of feeling of use such as stickiness in the film formation process and wrinkle after film formation (film formation feeling). Furthermore, there is a problem that blending a silicone resin and a volatile oil deteriorates the machinability and is unsuitable for pencil-like or stick-like cosmetics.

JP 2003-119110 A JP-A-6-199630 Japanese Examined Patent Publication No. 61-1284

  The present invention has been made in view of the above-mentioned conventional circumstances, and has extremely excellent water resistance and washing resistance (make-up mochi effect), and also has adhesion to the skin and a feeling of use (no stickiness or stiffness). An object of the present invention is to provide a pencil-shaped or stick-shaped cosmetic material having excellent machinability.

  In order to solve the above problems, the present invention provides (a) the following general formula (I):

{Wherein, R ₁ represents a methyl group remaining R ₁ is a methyl group or a phenyl group part of R _1,; R ₂ represents a methyl group, a hydroxyl group or R ₃ and same group; R ₃ Is R ₄ Z [wherein R ₄ represents a divalent alkylene group having 3 to 6 carbon atoms; Z represents —N (R ₅ ) ₂ , —N ⁺ (R ₅ ) ₃ A ⁻ , —NR ₅ ( _{CH 2) a N (R 5} ) 2, -NR 5 (CH 2) a N + (R 5) 3 A -, and _{-NR 5 (CH 2) a N} (R 5) C = O (R 6) (Wherein R ₅ represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; R ₆ represents an alkyl group having 1 to 4 carbon atoms; A represents a halogen atom; a represents an integer of 2 to 6) Represents a monovalent group selected from the group consisting of: an amino group or an ammonium group; and m and n are each a positive integer, and m + n is 3,000. Is 20,000, n / m is 1 / 500-1 / 10,000}
1 type or 2 or more types selected from amino-modified or ammonium-modified polymeric silicone represented by: (b) a solid to semi-solid wax at room temperature (25 ° C.), and (c) a non-volatile property A pencil-like or stick-like cosmetic containing a silicone-based liquid oil and (d) a powder component is provided.

  Further, the present invention provides the above-mentioned pencil-shaped or stick-shaped makeup wherein the blending ratio of the component (a) and the component (d) is (a) component: (d) component = 1: 50 to 1: 2 (mass ratio). Provide a fee.

  The present invention further provides the pencil-shaped or stick-shaped cosmetic described above, further comprising (e) a polar oil.

  Moreover, this invention provides the said pencil-shaped or stick-shaped cosmetics which do not contain volatile silicone oil.

  The present invention also provides the pencil or stick cosmetic described above, which does not contain a silicone coating agent.

  The pencil-like or stick-like cosmetic of the present invention has extremely high water resistance and washing resistance (make-up moisturizing effect) that is difficult to be removed even with washing with soap and cleansing oil as well as water, and adheres to the skin. Excellent in use and feel (no stickiness or stickiness) and excellent in machinability. On the other hand, makeup can be easily removed using a volatile silicone oil (such as decamethylpentasiloxane), which can be used properly according to the purpose, and is extremely easy to use.

  Hereinafter, the present invention will be described in detail.

  In the present invention, as the component (a), one or more selected from amino-modified or ammonium-modified polymeric silicones represented by the following general formula (I) are used.

  In said general formula (I), each substituent and code | symbol show the following meanings.

R ₁ represents a methyl group, or a part of R ₁ represents a phenyl group and the remaining R ₁ represents a methyl group.

R ₂ represents a methyl group, a hydroxyl group, or the same group as R ₃ .

R ₃ represents R ₄ Z [wherein R ₄ represents a divalent alkylene group having 3 to 6 carbon atoms; Z represents —N (R ₅ ) ₂ , —N ⁺ (R ₅ ) ₃ A ⁻ , —NR _{5 (CH 2) a N (} R 5) 2, -NR 5 (CH 2) a N + (R 5) 3 A -, and _{-NR 5 (CH 2) a N} (R 5) C = O (R ₆ ) (wherein R ₅ represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; R ₆ represents an alkyl group having 1 to 4 carbon atoms; A represents a halogen atom; Represents a monovalent group selected from the group consisting of: an amino group or an ammonium group.

  m and n are each a positive integer, and m + n (degree of polymerization) is 3,000 to 20,000, preferably 4,000 to 10,000. If m + n is less than 3,000, the makeup-improving effect is not sufficient. On the other hand, if m + n exceeds 20,000, the solubility in the component (c) (described later) is poor and cannot be blended into the cosmetic.

  n / m is 1/500 to 1 / 10,000, preferably 1/500 to 2,000. When n / m exceeds 1/500, the content of the amino group or ammonium group in the component (a) becomes high, a crosslinking reaction or the like occurs during production, and it is not preferable from the viewpoint of raw material odor. If it is less than 1 / 10,000, the interaction with the skin is weakened and the makeup lasts worse.

In the present invention, aminopropyl dimethicone (degree of polymerization: 3,000 to 20) in which R ₁ and R ₂ are methyl groups and R ₃ is — (CH ₂ ) ₃ N (CH ₃ ) ₂ in the general formula (I). , 000) is most preferable from the viewpoints of feeling of use, adhesion to the skin and the like.

  (A) A component can be manufactured by a conventional method. That is, for example, it can be produced by subjecting γ-aminopropylmethyldiethoxysilane, cyclic dimethylpolysiloxane, and hexamethyldisiloxane to a polycondensation reaction in the presence of an alkali catalyst, but it is of course not limited thereto. It is. These modified polymeric silicones are in the form of a soft rubber and do not feel sticky even when used in large amounts or used for a long time, and an excellent usability can be obtained.

  (A) When mix | blending a component in this invention cosmetics, it is preferable to melt | dissolve and mix | blend with (c) component (after-mentioned). Of course, it may be blended separately in the cosmetic and dissolved in the system. The component (a) is insoluble in hydrocarbon oils (non-polar oil components) such as liquid paraffin, squalene, and petroleum jelly.

  (A) 0.1-30 mass% is preferable in this invention cosmetics whole quantity, and, as for the compounding quantity of a component, 1-10 mass% is especially preferable. If the blending amount is too low, the makeup-moistening effect tends to be poor, whereas if the blending amount is too high, it tends to cause deterioration in usability and poor molding.

  The component (b) wax may be any of natural and synthetic products, as long as it is solid to semi-solid at room temperature (25 ° C.) and is usually used in cosmetics. Hydrocarbon waxes such as paraffin wax, polyethylene wax, ethylene propylene copolymer, microcrystalline wax, ceresin, ozokerite, or Fischer-Tropsch wax, as well as silicone wax, moscow, cured beef tallow, carnauba wax, candelilla wax, rice Examples thereof include wax, beeswax, hydrogenated jojoba oil, lanolin, and petroleum jelly, but are not limited to these examples. In the present invention, microcrystalline wax, polyethylene wax, silicone wax and the like are preferably used in terms of moldability and usability. (B) A component can use 1 type (s) or 2 or more types.

  In addition, although there are higher fatty acids, higher alcohols, etc. as solid to semi-solid oil components at room temperature, in the present invention, hardness can be obtained even if these higher fatty acids and higher alcohols are blended in place of the component (b) (= wax). Since it does not appear, it does not become a pencil shape or a stick shape, and the effects of the present invention cannot be achieved.

  The blending amount of the component (b) is preferably 5 to 30% by mass and particularly preferably 10 to 20% by mass in the total amount of the cosmetic of the present invention. If the blending amount is too low, it tends to be difficult to mold or break, while if it is too high, it tends to be hard and unusable.

  The non-volatile silicone-based liquid oil component (c) serves as a solvent for dissolving the component (a) and preferably has a viscosity of 5 to 500 mPa · s at room temperature (25 ° C.). Specific examples include polysiloxanes such as dimethylpolysiloxane and methylphenylpolysiloxane. The viscosity of these non-volatile silicone oils is preferably 5 to 500 mPa · s, more preferably 10 to 100 mPa · s. If the viscosity is too low, the adhesion to the skin is lowered, and if it is too high, a smooth usability cannot be obtained. (C) A component can use 1 type (s) or 2 or more types.

(C) The compounding quantity of a component has preferable 10-50 mass% in this invention cosmetics whole quantity, and 20-40 mass% is especially preferable. If the blending amount is too low, smooth usability cannot be obtained, which tends to cause breakage. On the other hand, if the blending amount is too high, it tends to cause molding defects.

  As the powder component of component (d), powders, pigments and the like that are usually used in cosmetics can be arbitrarily used. For example, talc, mica, kaolin, mica, sericite (sericite), muscovite, gold Mica, Synthetic mica, Red mica, Biotite, Lithia mica, Vermiculite, Magnesium carbonate, Calcium carbonate, Aluminum silicate, Barium silicate, Calcium silicate, Magnesium silicate, Strontium silicate, Metal tungstate, Magnesium, Spherical Inorganic powders such as silica, zeolite, barium sulfate, calcined calcium sulfate (baked gypsum), calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, metal soap (such as zinc myristate, calcium palmitate, aluminum stearate), boron nitride; Polyamide spherical resin powder (Nylon spherical powder), spherical polyethylene, cross-linked poly (meth) acrylic acid methyl spherical resin powder, spherical polyester, crosslinked polystyrene spherical resin powder, copolymer spherical resin powder of styrene and acrylic acid, benzoguanamine spherical resin powder, poly four Spherical organic powders such as spherical ethylene fluoride powder and spherical cellulose; inorganic white pigments such as titanium dioxide and zinc oxide; inorganic red pigments such as iron oxide (Bengara) and iron titanate; inorganic browns such as γ-iron oxide Pigments: inorganic yellow pigments such as yellow iron oxide and ocher; inorganic black pigments such as black iron oxide, carbon black and low-order titanium oxide; inorganic purple pigments such as mango violet and cobalt violet; chromium oxide, hydroxide Inorganic green pigments such as chromium and cobalt titanate; inorganic blue pigments such as ultramarine and bitumen; titanium oxide coated mica, Titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, pearl pigments such as fish scale foil; metal powder pigments such as aluminum powder and copper powder; red, yellow, orange, yellow, green, Color materials such as blue, or color materials (organic pigments) obtained by lacquering these with zirconium, barium, aluminum, or the like; natural pigments such as chlorophyll and β-caroline are exemplified, but the invention is not limited to these examples . (D) 1 type (s) or 2 or more types can be used for a component.

  In addition, you may use what hydrophobized the powder as (d) component. As a method of hydrophobizing treatment, any method can be used as long as it can impart water repellency, and any method can be used. For example, a usual surface treatment such as a gas phase method, a liquid phase method, an autoclave method, a mechanochemical method, etc. The method can be used.

  For example, when a hydrophobizing agent is added to the raw material powder for treatment, it may be diluted with an appropriate solvent (dichloromethane, chloroform, hexane, ethanol, xylene, volatile silicone, etc.) or added directly. May be. For mixing and stirring the powder and the treatment agent, a ball mill, a hoger sight ball mill, a vibrating ball mill, an attritor, a pot mill, a rod mill, a pan mill, a homomixer, a homodisper, a Henschel mixer, a nauter mixer, and the like can also be used. In addition to this, by utilizing the activity of the powder surface, a method of polymerizing cyclic organosiloxane on the powder surface at a low temperature of 100 ° C. or lower by gas phase reaction (Japanese Patent Publication No. 1-54380), A method of adding a pendant group such as glycerol monoallyl ether to the Si—H portion of the silicone polymer (Japanese Patent Publication No. 1-54381) can also be used.

  The hydrophobizing agent is not particularly limited, but it is fatty acid dextrin-treated powder, trimethylsiloxysilicate-treated powder, fluorine-modified trimethylsiloxysilicate-treated powder, methylphenylsiloxysilicate-treated powder, fluorine-modified methylphenylsiloxy. Silica-treated powder, low viscosity to high viscosity oily polysiloxane treated powder such as dimethylpolysiloxane, diphenylpolysiloxane, methylphenylpolysiloxane, gum-like polysiloxane treated powder, methylhydrogenpolysiloxane treated powder, fluorine-modified methylhydrogen Polysiloxane-treated powder, methyltrichlorosilane, methyltrialkoxysilane, hexamethyldisilane, dimethyldichlorosilane, dimethyldialkoxysilane, trimethylchlorosilane, trimethylalkoxy Treatment powders with organic silyl compounds such as orchid or their fluorine-substituted products, ethyltrichlorosilane, ethyltrialkoxysilane, propyltrichlorosilane, propyltrialkoxysilane, hexyltrichlorosilane, hexyltrialkoxysilane, long-chain alkyltrichlorosilane, long Examples thereof include treatment powders with organically modified silanes such as chain alkyltriethoxysilane or fluorine-substituted products thereof, amino-modified polysiloxane-treated powders, fluorine-modified polysiloxane-treated powders, and fluorinated alkyl phosphate-treated powders.

  The cosmetic of the present invention is excellent in the dispersibility of the component (d). (D) The compounding quantity of a component has preferable 20-50 mass% in this invention cosmetics whole quantity, and 30-40 mass% is especially preferable. If the blending amount is too low, the color development is weak and the makeup effect tends to be weak. On the other hand, if the blending amount is too high, the operability tends to be poor due to the powdery usability.

  Furthermore, in this invention, it is preferable that the compounding ratio (mass ratio) of (a) component and (d) component is (a) component: (d) component = 1: 50-1: 2, especially 1: 5 to 1: 3 (mass ratio) is preferable. By setting the blending ratio of the component (a) to the component (d) within the above range, it is possible to obtain the cleaning resistance (mochimochi effect) particularly effectively.

  In the present invention, in addition to the components (a) to (d), a polar oil component (e) may be blended as desired. Examples of the component (e) include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, Myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearylate, ethylene glycol di-2-ethylhexylate, dipentaerythritol fatty acid ester, monoisostearate N-alkylglycol, neopentylglycol dicaprate, Diisostearyl malate, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexylate, triisos Trimethylol propane acrylate, pentane erythritol tetra-2-ethylhexylate, glycerin tri-2-ethylhexylate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, glyceryl trimyristate, tris 2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleic oil, cetostearyl alcohol, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester , Di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyl palmitate Synthetic ester oils such as decyl, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, ethyl acetate, butyl acetate, amyl acetate, triethyl citrate, etc. are preferably used, but are not limited to these examples Not. (E) 1 type (s) or 2 or more types can be used for a component.

  (E) When mix | blending a component, it is preferable that the compounding quantity shall be 20 mass% or less, More preferably, it is 10 mass% or less. (E) When there are too many compounding quantities, it will become sticky usability and there is a possibility that the makeup and the effect may worsen. By blending component (e), component (b) can be more effectively dissolved.

  The pencil-like or stick-like cosmetic of the present invention is a combination of the above components (a) to (d), or if desired, by further adding (e) to the components (a) to (d), It has very high adhesion to the skin, and has outstanding water resistance and washing resistance (makeup lasting effect) that does not fall off even with normal washing. In the past, a silicone film agent was formulated to improve the makeup and moisturizing effect, and this was dissolved in volatile silicone oil. However, it requires container confidentiality to prevent volatilization of volatile silicone oil, There were problems in use such as stickiness during film formation and wrinkle after film formation (film feeling). In the present invention, even if it does not contain a silicone-based film agent or a volatile silicone oil, it has a makeup effect that is far superior to cosmetics using conventional silicone-based film agents. There are no problems in use feeling due to blending (stickiness, wrinkle), and these conventional problems can be solved.

  In addition, as said silicone type coating agent which does not need to mix | blend in this invention cosmetics, a silicone resin, silicone rubber, a fluorine modified silicone resin, an alkyl modified silicone resin etc. are mentioned, for example. Specifically, as the silicone resin, the average formula (II):

RnSiO _{(4-n) / 2} (II)

(R represents a hydrocarbon group or phenyl group from 1 to 6, and n represents a value from 1.0 to 1.8.)
The silicone resin represented by these is mentioned. This silicone resin comprises an appropriate combination of R ₃ SiO _1/2 units, R ₂ SiO units, RSiO _2/3 units and SiO ₂ units, and has an average molecular weight of about 1,500 to 20,000. Is mentioned.

  Moreover, as said volatile silicone oil which does not need to mix | blend in this invention cosmetics, the low boiling point silicone oil which has the boiling point in the range of 60-260 degreeC at room temperature is mentioned. Specific examples include chain polysiloxanes such as decamethyltetrasiloxane, hexamethyldisiloxane, and dodecamethylpentahexasiloxane, and cyclic polysiloxanes such as octamethyltetracyclotetrasiloxane and decamethylcyclopentasiloxane. It is not limited to these examples.

  The pencil-shaped or stick-shaped cosmetic of the present invention is excellent enough not to be removed even by washing with soap and cleansing oil (about 50 times) as well as not being removed by washing with ordinary hot water or water. Has a moisturizing effect. On the other hand, if you intend to remove cosmetics, you can easily remove makeup by using volatile silicone oil (such as decamethylcyclopentasiloxane). It can be used appropriately and is extremely easy to use.

  The pencil-shaped or stick-shaped cosmetics of the present invention may further optionally include optional additives that can be generally added to cosmetics, for example, polymer compounds, perfumes, surfactants, oxidizing agents, as long as the effects of the present invention are not impaired. An inhibitor, an antiseptic, a cosmetic ingredient, and the like can be appropriately blended.

  The pencil-shaped or stick-shaped cosmetic of the present invention is a pencil-shaped or solid-molded mold that is solidified and molded into a bar-shaped core material, which is solidified and molded in a feeding container, with the periphery of the rod-shaped core material fixed with wood or resin. It takes the form of a stick to be used by shaving the tip of the rod-shaped core material itself. The pencil-shaped or stick-shaped cosmetic of the present invention is suitably applied as a makeup cosmetic such as an eyebrow pencil, an eyeliner pencil, a lip pencil, and an eye shadow, but is not limited to these examples.

  Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited thereto. All blending amounts are mass% unless otherwise specified.

(Example 1, Comparative Examples 1-2)
Samples shown in Tables 1 and 2 below were prepared. In Tables 1 and 2, “amino-modified silicone” ^{(* 1)} means that in general formula (I), R ₁ is a methyl group, R ₂ is a methyl group, and R ₃ is — (CH ₂ ) ₃ N (CH ₃₎ using the samples prepared in these tables 1 and 2 with those of _2. it aminopropyl dimethicone (m + n = 10000, n / m = 1/1000), the following evaluation method, the evaluation criteria, cosmetic has the effect (Water resistance and washing resistance), feeling of use (no stickiness, no stickiness), skin adhesion, and machinability were evaluated. The results are shown in Table 3.

[Make-up effect (water resistance, wash resistance)]
Each sample was applied to the arm of a panel (10 persons) by 3 cm × 3 cm.
Next, (1) cleansing with cleansing oil 50 times [= cleaning method 1], (2) cleaning with soap 100 times + rubbing 50 times with sponge [= cleaning method 2], (3) volatile silicone oil (“EXECOAL” D-5 "; manufactured by Shin-Etsu Chemical Co., Ltd.) [= washing method 3] was used to visually evaluate the wash resistance (make-up mochi effect) according to the following evaluation criteria.
(Evaluation)
◎: 8 or more out of 10 responded that there was almost no color fading ○: 6-7 out of 10 responded that there was almost no fading △: 3-5 out of 10 were almost discolored No answer ×: Less than 2 out of 10 respondents say there is almost no discoloration

[Usage feeling (no feeling of stiffness)]
Each sample was applied 3 cm × 3 cm to the arm of a panel (10 persons) and evaluated according to the following evaluation criteria.
(Evaluation)
◎: More than 8 out of 10 responded that they did not feel sticky ○: 6-7 out of 10 responded that they did not feel sticky △: 3-5 out of 10 responded that they did not feel sticky ×: Less than 2 out of 10 responded that they did not feel stiff

[Usage feeling (no stickiness)]
Each sample was applied 3 cm × 3 cm to the arm of a panel (10 persons) and evaluated according to the following evaluation criteria.
(Evaluation)
◎: 8 or more out of 10 responded that there was no stickiness ○: 6-7 out of 10 responded that there was no stickiness △: 3-5 out of 10 responded that there was no stickiness ×: Less than 2 out of 10 responded that there was no stickiness

[Adhesion to skin]
Each sample was applied 3 cm × 3 cm to the arm of a panel (10 persons) and evaluated according to the following evaluation criteria.
(Evaluation)
◎: 8 or more out of 10 responded that the adhesion to the skin was excellent ○: 6 to 7 out of 10 responded that the adhesion to the skin was excellent Δ: 3 to 5 out of 10 Answer that skin adhesion is excellent ×: Less than 2 out of 10 responded that skin adhesion is excellent

[Machinability]
After the core of each sample was cut off with a cutter, it was shaved with a shapner and evaluated from the number of breaks of the core according to the following evaluation criteria.
(Evaluation)
◎: Cutting 20 times, broken core 0 times ○: Cutting 20 times, broken core 1-2 times Δ: Cutting 20 times, broken core 3-4 times ×: Cutting 20 times, broken core 5 times or more

  As is apparent from the results shown in Table 3 above, the pencil-like or stick-like cosmetic according to the present invention has extremely excellent water resistance / detergency (makeup effect), while using a volatile silicone oil. You can easily remove makeup. In addition, it has excellent adhesion to the skin, feeling of use (no stickiness, no stickiness), and machinability.

Claims (5)

(A) The following general formula (I):

{Wherein, R ₁ represents a methyl group remaining R ₁ is a methyl group or a phenyl group part of R _1,; R ₂ represents a methyl group, a hydroxyl group or R ₃ and same group; R ₃ Is R ₄ Z [wherein R ₄ represents a divalent alkylene group having 3 to 6 carbon atoms; Z represents —N (R ₅ ) ₂ , —N ⁺ (R ₅ ) ₃ A ⁻ , —NR ₅ ( _{CH 2) a N (R 5} ) 2, -NR 5 (CH 2) a N + (R 5) 3 A -, and _{-NR 5 (CH 2) a N} (R 5) C = O (R 6) (Wherein R ₅ represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; R ₆ represents an alkyl group having 1 to 4 carbon atoms; A represents a halogen atom; a represents an integer of 2 to 6) Represents a monovalent group selected from the group consisting of: an amino group or an ammonium group; and m and n are each a positive integer, and m + n is 3,000. Is 20,000, n / m is 1 / 500-1 / 10,000}
1 type or 2 or more types selected from amino-modified or ammonium-modified polymeric silicone represented by: (b) a solid to semi-solid wax at room temperature (25 ° C.), and (c) a non-volatile property A pencil-like or stick-like cosmetic comprising a silicone-based liquid oil and (d) a powder component.   The pencil-shaped or stick-shaped cosmetic according to claim 1, wherein the blending ratio of the component (a) to the component (d) is (a) component: (d) component = 1: 50 to 1: 2 (mass ratio). .   The pencil-shaped or stick-shaped cosmetic according to claim 1 or 2, further comprising (e) a polar oil.   The pencil-shaped or stick-shaped cosmetic according to any one of claims 1 to 3, which does not contain volatile silicone oil.   The pencil-shaped or stick-shaped cosmetic according to any one of claims 1 to 4, which does not contain a silicone-based film agent.