JP2006281470A - Original lithographic printing plate - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for manufacturing an original lithographic printing plate which has no waste liquid generation, extremely excellent workability in a bright room and specially excellent smear resistance even in terms of printability in dealing with a direct thermal drawing method, as a technique for manufacturing the original lithographic printing plate. <P>SOLUTION: In this original lithographic printing plate comprising a layer which turns hydrophobic by heat and a hydrophilic layer as an outermost layer, formed on a support, the hydrophilic layer comprises a polyacrylic acid compound with not less than 10,000 average molecular weight. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to a printing plate used for lithographic printing, which can obtain an image having high resolution, does not require a handling and processing solution in a bright room, and has a particularly low manufacturing cost. .

  The lithographic printing plate is composed of an oleophilic image portion that accepts oil-based ink and an oleophobic non-image portion that does not accept ink, and the non-image portion is generally composed of a hydrophilic portion that accepts water. In normal lithographic printing, both water and ink are supplied to the printing plate, ink is selectively received in the image area, and water is selectively received in the non-image area, and the ink on the image area is transferred to a printing medium such as paper. Printing is done by things.

  Currently, a lithographic printing original plate is produced by providing an oleophilic ink-receiving layer on a substrate such as an aluminum plate, a zinc plate, or paper whose surface has been hydrophilized. Among these, a photosensitive material such as a diazo compound or a photopolymer is used on a metal support having a hydrophilic surface treated as a PS plate, or silver halide is used as a photosensitive material on a paper or plastic support. In general, an image is formed using a silver complex diffusion transfer method (DTR method).

  In order to form an ink receiving layer (hereinafter referred to as an image layer) with a diazo compound or a photopolymer, first, a photosensitive material such as a diazo compound or a photopolymer is coated on a substrate such as a metal plate, paper, laminated plate, or insulating substrate. To do. Next, light is irradiated to cause a chemical change in the photosensitive material, thereby changing the solubility in the developer. Photosensitive materials are classified into two types depending on the type of chemical change. The negative part that becomes polymerized and hardened when irradiated with light and becomes insoluble in the developer, and conversely the functional group of the part that is irradiated with light changes to have solubility in the developer. It is a positive type. In any case, the photosensitive material insoluble in the developer that remains on the substrate after processing with the developer becomes the image layer.

  On the other hand, a lithographic printing original plate using the DTR method, particularly a lithographic printing original plate having a physical development nucleus layer on a silver halide emulsion layer is described in, for example, US Pat. No. 3,728,114 (Patent Document 1). The exposed silver halide crystals undergo chemical development by DTR development to form black silver and form hydrophilic non-image areas, while unexposed silver halide crystals are complex in the developer. It becomes a silver salt complex by the agent and diffuses to the physical development nucleus layer on the surface, and the physical development is caused by the presence of the nucleus to form an image portion mainly composed of ink-accepting physical development silver.

  When forming an image layer using the photosensitive material as described above, the exposure method is one of the important factors that determine the resolution. Conventionally, it has been the mainstream to produce a film for exposure and then perform a contact exposure method using ultraviolet light or white light. However, with the advancement of computers, a laser direct writing method in which a digital signal from computer information is transmitted to an exposure apparatus (computer-to-plate) and a photosensitive material is directly exposed using a laser has been performed. ing. The laser direct writing method has advantages such as low cost, high speed, and high productivity with many kinds and small lots.

In order to cope with this laser direct writing method, the optical sensitivity of the photosensitive material must be increased. Since diazo compounds and photopolymers involve a photochemical reaction, the optical sensitivity is low, being several to several hundred mJ / cm ² . For this reason, the laser output device must have a high output, which causes problems such as an increase in size and cost.

In addition, in the case of forming an image by the DTR method using silver halide, the sensitivity is several μJ / cm ² and it can be sufficiently exposed even with a simple semiconductor laser or the like. In addition, there has been a drawback that the efficiency of manufacturing and plate-making operations is remarkably deteriorated, in that the coating process on the substrate must be performed in the dark or under a safety light. In addition, in diazo compounds and photopolymers, the reaction proceeds even under room light or sunlight, and the reactivity changes even at high temperatures. In addition, the presence of oxygen becomes an inhibitor of the reaction. Therefore, before exposure and development, it is necessary to store in a dark room treatment or in a low oxygen state.

  Further, in the above-described image forming method, liquid processing such as using a developing solution is generally performed, and there is a defect that waste liquid processing is an environmental problem.

  On the other hand, a method of making a lithographic printing plate simply by heating with a laser without using a treatment liquid is also known. As ablation types, for example, there are JP-A-8-507727 (Patent Document 2) and JP-A-6-186750 (Patent Document 3). However, since the contamination inside the exposure apparatus due to the scattered material on the ablated surface layer becomes a problem, a water-soluble protective layer is provided on the top layer to prevent the ablated surface layer from scattering and the surface layer ablated together with the protective layer on the printing press There has also been proposed a method for removing the above.

   As a processless printing plate other than the ablation type, there is a heat fusion image layer on-machine development type, which is described in, for example, JP-A-2004-42531 (Patent Document 4). In this method, because of the on-press development type, the non-image area is peeled off on the printing press, and the accumulation of peeled material on the ink roller or the like becomes a problem.

In addition, as another processless printing plate, there is Japanese Patent No. 3522450 (Patent Document 5). Although this type has no problem in plate making, inconvenience such as poor stain resistance at the time of printing may occur. .
U.S. Pat. No. 3,728,114 JP-A-8-507727 JP-A-6-186750 JP 2004-42531 A Patent No. 3522450

  The object of the present invention is to make a planographic printing plate that corresponds to a direct drawing method by heat, has no waste liquid, has excellent workability in a bright room, and has excellent stain resistance in terms of printability. It is to provide a method.

As a result of intensive studies, the above object of the present invention has been basically achieved by the following invention.
1) In a lithographic printing original plate in which a layer which is converted to hydrophobicity by heat on a support and a hydrophilic layer as an outermost layer are provided, the hydrophilic layer contains a polyacrylic acid compound having an average molecular weight of 10,000 or more. A lithographic printing plate characterized by
2) The lithographic printing plate precursor as described in 1) above, wherein the layer which is converted to hydrophobicity by heat contains heat-fusible fine particles or heat-meltable fine particles.
3) The lithographic printing plate precursor as described in 1) or 2) above, wherein a light absorber is contained in at least one layer of the lithographic printing plate precursor.

  According to the present invention, a lithographic printing plate precursor corresponding to a direct drawing method by heat, having no waste liquid, having excellent workability in a bright room, and having particularly excellent stain resistance in terms of printability is provided. It becomes possible to do.

  As an example of the lithographic printing original plate according to the present invention, a layer that is converted to hydrophobicity by heat on the surface of a support, and a hydrophilic layer as an outermost layer is provided thereon. On the other hand, the back surface is provided with a back layer for adjusting the curl balance. The layer that is converted to hydrophobicity by heat of the present invention maintains hydrophilicity when no heat is applied, but when heat is applied, the layer at that site melts and converts to hydrophobicity. On the other hand, for the hydrophilic layer provided on the upper layer, the hydrophilic layer is taken into the lower layer when the lower layer (layer that converts to hydrophobicity by heat) is melted by heat. When the hydrophilic layer is destroyed by ablation or the like, the lower layer melted by heat is converted to hydrophobic and exposed to the surface. Therefore, in this system, since the part to which heat is applied is converted into hydrophobicity, it becomes possible to accept ink during printing. Examples of the method for making a lithographic printing plate of the principle shown in the above-mentioned example of the present invention include contact with a lithographic printing original plate by a thermal printing head and laser irradiation. On the other hand, the lower layer (layer that converts to hydrophobicity by heat) and the upper layer (hydrophilic layer) maintain the hydrophilicity in the region that is not irradiated with heat. After that, if it is mounted on a lithographic printing machine, ink is received in the portion that has been heated and converted to hydrophobic, and water is received in the portion that has not been heated to enable printing.

  The hydrophilic layer of the lithographic printing plate precursor according to the present invention needs to contain a polyacrylic acid compound having an average molecular weight of 10,000 or more. Preferably, the polyacrylic acid compound has an average molecular weight of 50,000 or more, more preferably 100,000 or more. When the average molecular weight of the polyacrylic acid is less than 10,000, the function of preventing smudges during printing is low and it is not suitable for printing.

The content of the polyacrylic acid compound used in the present invention is suitably 0.001 to 3 g / m ^{2 in} terms of solid matter, and preferably 0.01 to ² g / m ^2. Applied. More preferably, it is the range of 0.1-1 g / m < ² >.

  Next, the polyacrylic acid compound necessary for improving the stain resistance, which is preferably contained in the hydrophilic layer of the present invention, is exemplified, but it is not limited thereto.

  In addition, polyacrylic acid compounds having an average molecular weight of 10,000 or more used in the present invention are generally marketed as known industrial chemicals, such as Jurimer, Aronbis and Toagosei Co., Ltd. There are Aaron, Aaron flock and the like, and the use of a commercial product is preferable in terms of production cost.

  The hydrophilic layer of the lithographic printing plate according to the present invention may be used in combination with a hydrophilic polymer having a binder-like element having film-forming ability in addition to the polyacrylic acid compound capable of improving the stain resistance described above. The surface layer is coated so as to be a hydrophilic layer. The amount used is 200% by mass or less based on the polyacrylic acid compound capable of improving the stain resistance described above. Preferably, it is 100 mass% or less, More preferably, it is 10 mass% or less. If it exceeds 200% by mass, the effect of improving the stain resistance is reduced. The hydrophilic layer may be applied at the same time as the layer that is converted to hydrophobicity by heat, or may be applied after the layer that is converted to hydrophobicity by heat is once applied.

  Examples of the hydrophilic polymer having a binder-like element that can be used in combination with the hydrophilic layer of the present invention include the following.

  Natural products include starches, seaweed mannan, agar, and algae such as sodium alginate, mannan, pectin, tragacanth gum, karaya gum, xanthine gum, guarbin gum, locust bin gum, gum arabic, and other plant mucus, dextran, glucan , Such as homopolysaccharides such as xanthan gum and levan, microbial mucilage such as heteropolysaccharides such as succinoglucan, pullulan, curdlan and xanthan gum, glue, proteins such as gelatin, casein and collagen, chitin and its derivatives, etc. It is done.

  Semi-natural products (semi-synthetic products) include cellulose derivatives, modified gums such as carboxymethyl guar gum, cultured starches such as dextrin, processed starches such as oxidized starches and esterified starches. .

  Synthetic products include polyvinyl alcohol, modified polyvinyl alcohol, partially acetalized polyvinyl alcohol, allyl-modified polyvinyl alcohol, modified polyvinyl alcohol such as polyvinyl methyl ether, polyvinyl ethyl ether, polyvinyl isobutyl ether, polyacrylate, polyacrylate portion Polyacrylic acid derivatives and polymethacrylic acid derivatives such as saponified products, polymethacrylates, and polyacrylamides, polyethylene glycol, polyethylene oxide, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, carboxyvinyl polymer, styrene / malein Examples thereof include acid copolymers and styrene / crotonic acid copolymers.

  Among these, gelatin, modified or unmodified polyvinyl alcohol, and cellulose derivatives can be advantageously used.

  As the gelatin used for the hydrophilic layer related to the lithographic printing original plate of the present invention, any gelatin can be used as long as it is made from animal collagen, but collagen derived from pig skin, cow skin, and cow bone is used as a raw material. Gelatin is preferred. The type of gelatin is not particularly limited, but in addition to lime-processed gelatin and acid-processed gelatin, JP-B-38-4854, JP-B-39-5514, JP-B-40-12237, and JP-B-42-26345. Publication, US Pat. No. 2,525,753, US Pat. No. 2,594,293, US Pat. No. 2,614,928, US Pat. No. 2,763,639, US Pat. No. 3,118,766 No. 3, US Pat. No. 3,132,945, US Pat. No. 3,186,846, US Pat. No. 3,312,553, British Patent 1,033,189, etc. A derivative etc. are mentioned, These can be used 1 type or in combination of 2 or more types.

  When gelatin is used for the hydrophilic layer, it can be hardened with a gelatin hardener. Gelatin hardeners include, for example, inorganic compounds such as chromium alum, aldehydes such as formalin, glyoxal, malealdehyde, glutaraldehyde, N-methylal compounds such as urea and ethylene urea, mucochloric acid, 2, 3 Aldehyde-related compounds such as dihydroxy-1,4-dioxane, active halogens such as 2,4-dichloro-6-hydroxy-S-triazine salt and 2,4-dihydroxy-6-chloro-S-triazine salt , Divinyl sulfone, divinyl ketone, N, N, N-triacryloyl hexahydrotriazine, compounds having two or more active three-membered ethyleneimino groups and epoxy groups in the molecule, and polymer dura mater Use one or more of various compounds such as dialdehyde starch as an agent. Can.

  The hydrophilic layer of the lithographic printing original plate according to the present invention may contain an inorganic substance such as titanium oxide, silicon dioxide, aluminum oxide or the like for the purpose of preventing printing stains. The ratio to be contained is appropriately determined in a desired range depending on various conditions such as printing ink, dampening water, printing speed, and printing pressure used for printing.

  In order to coat the hydrophilic layer of the lithographic printing plate precursor according to the present invention, an anionic, cationic or nonionic surfactant may be used as an auxiliary agent, a matting agent, a thickening agent. An antistatic agent or the like can also be used.

  As the layer that is converted into hydrophobicity by heat of the lithographic printing plate according to the present invention, a constitution containing heat-fusible fine particles or heat-melting fine particles is preferably used. More preferably, heat fusible particles are used.

  Specific examples of the heat-fusible fine particles according to the present invention include, for example, polypropylene, polybutadiene, polyisoprene, polychloroprene, diene (co) polymers such as ethylene-butadiene copolymer, styrene-butadiene copolymer, Synthetic rubbers such as methyl methacrylate-butadiene copolymer, acrylonitrile-butadiene copolymer, polymethyl methacrylate, methyl methacrylate-methacrylic acid copolymer, methyl acrylate- (N-methylolacrylamide) copolymer, polyacrylonitrile, etc. (Meth) acrylic acid ester, (meth) acrylic acid copolymer, polyvinyl acetate, vinyl acetate-vinyl propionate copolymer, vinyl ester (co) polymer such as vinyl acetate-ethylene copolymer, polyvinyl chloride , Polyvinylidene chloride, poly Styrene and the like, and copolymers thereof. Of these, synthetic rubbers such as a (meth) acrylic acid-ester copolymer, a styrene-butadiene copolymer, a methyl methacrylate-butadiene copolymer, and an acrylonitrile-butadiene copolymer are preferable. These resins can be used in the form of powder, but the water dispersion type is particularly preferable in production. In addition, two or more kinds can be mixed and used as necessary for production, and a plurality of layers may be used.

  The heat-fusible fine particles according to the present invention are preferably of a type that self-crosslinks when heated. With the self-crosslinking type, it is possible to form a three-dimensional network by heat without the presence of a crosslinking agent, and when preparing the heat-fusible fine particles according to the present invention, as a copolymerization component, a carboxyl group, a hydroxyl group, It can be obtained by the presence of a reactive functional group such as a methylolamide group, an epoxy group, a carbonyl group, or an amino group.

  The average particle diameter of the heat-fusible fine particles used in the present invention is preferably 0.005 μm to 2.0 μm. More preferably, the thickness is 0.01 μm to 1.5 μm. When the average particle size is too large, the resolution is inferior, and when it is too small, the temporal stability is deteriorated. Further, the glass transition point of the heat-fusible fine particles used in the present invention is preferably 20 ° C. or higher, more preferably 30 ° C. or higher. The heat-fusible fine particles having a glass transition point of less than 20 ° C. are inferior in the ink receiving performance of the portion converted to hydrophobicity by heat, and the printing durability during printing is also lowered.

  The heat-meltable fine particles according to the present invention are fine particles formed of a material that has a low viscosity when melted, and is generally classified as a wax, among thermoplastic materials. Specific examples include paraffin, polyolefin, polyethylene wax, microcrystalline wax, fatty acid wax and the like.

  The heat-meltable fine particles according to the present invention preferably have a softening point of 40 ° C to 150 ° C and a melting point of 50 ° C to 170 ° C, and a softening point of 40 ° C to 130 ° C and a melting point of 60 ° C to 150 ° C. Further preferred.

  The average particle diameter of the heat-meltable fine particles according to the present invention is preferably 0.05 μm to 8.0 μm. More preferably, it is 0.5 μm to 6 μm. If the average particle size is too large, it is difficult to convert to hydrophobicity after heat melting and the printing durability is inferior. If it is too small, the stability over time deteriorates.

The heat-fusible fine particles or heat-meltable fine particles contained in the layer that is converted into hydrophobicity by heat of the lithographic printing plate precursor according to the present invention may be in the range of 0.1 to 100 g / m ² , preferably 5 ˜80 g / m ² . More preferably, it is 10-50 g / m < ² >. The heat fusible fine particles and the heat fusible fine particles can be used in combination, but it is preferable that the content of the heat fusible fine particles is larger than that of the heat fusible fine particles. In this case, the mixing amount of the heat-fusible fine particles and the heat-fusible fine particles may be in the range described above.

  The layer that is converted to hydrophobicity by the heat of the lithographic printing plate according to the present invention may be composed of the above-mentioned heat-fusible fine particles and / or heat-fusible fine particles alone, but for application to a support. On the other hand, it is preferable to contain a hydrophilic polymer, and it may be in a range of 100% by mass or less with respect to the amount of heat-fusible fine particles and / or heat-meltable fine particles added. Preferably it is 80 mass% or less, More preferably, it is 40 mass% or less. If it exceeds 100% by mass, the conversion efficiency to hydrophobicity is deteriorated by heat, and the printing durability is inferior. Typical examples of the hydrophilic polymer are listed below, but are not limited thereto.

  Natural products include starches, seaweed mannan, agar, and algae such as sodium alginate, mannan, pectin, tragacanth gum, karaya gum, xanthine gum, guarbin gum, locust bin gum, gum arabic, and other plant mucus, dextran, glucan , Such as homopolysaccharides such as xanthan gum and levan, microbial mucilage such as heteropolysaccharides such as succinoglucan, pullulan, curdlan and xanthan gum, glue, proteins such as gelatin, casein and collagen, chitin and its derivatives, etc. It is done.

  Semi-natural products (semi-synthetic products) include cellulose derivatives, modified gums such as carboxymethyl guar gum, cultured starches such as dextrin, processed starches such as oxidized starches and esterified starches. .

  Synthetic products include polyvinyl alcohol, partially acetalized polyvinyl alcohol, allyl-modified polyvinyl alcohol, modified polyvinyl alcohol such as polyvinyl methyl ether, polyvinyl ethyl ether, and polyvinyl isobutyl ether, polyacrylate, polyacrylic ester partial saponified product, poly Polyacrylic acid derivatives and polymethacrylic acid derivatives such as methacrylate and polyacrylamide, polyethylene glycol, polyethylene oxide, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymer, carboxyvinyl polymer, styrene / maleic acid copolymer And styrene / crotonic acid copolymer.

  Among these, gelatin, modified and non-modified polyvinyl alcohol, and cellulose derivatives can be advantageously used.

  Further, the layer of the lithographic printing original plate according to the present invention that is converted to hydrophobicity by heat can be added with a matting agent such as silica for improving the transportability of the output machine and the slipperiness of the thermal head. In this case, the type of particles is not particularly limited, but the average particle size is preferably 10 μm or less.

  The support of the lithographic printing original plate according to the present invention may be a resin-coated paper, synthetic paper, a synthetic or semi-synthetic polymer film such as polyethylene terephthalate, or a metal plate such as aluminum or iron that can withstand lithographic printing. . In addition, the surface of these supports can be subjected to a surface treatment for improving adhesion with a layer to be coated as an upper layer, or can be subjected to a dyeing treatment to improve laser light absorption. In the present invention, preferred supports are resin-coated paper, synthetic paper, polyethylene terephthalate, and the like.

As a direct drawing method by heat which is a plate making method of the lithographic printing original plate of the present invention, for example, a thermal print head, a laser as a carbon dioxide laser, a nitrogen laser, an Ar laser, a He / Ne laser, a He / Cd laser, a Kr laser, etc. Gas laser, liquid (dye) laser, solid laser such as ruby laser, Nd / YAG laser, semiconductor laser such as GaAs / GaAlAs, InGaAs laser, excimer laser such as KrF laser, XeCl laser, XeF laser, Ar ₂ etc. But is not limited to the above.

  In the plate making method of the lithographic printing plate precursor according to the present invention, in order to improve the drawing efficiency by heat (that is, the sensitivity of the lithographic printing plate precursor in the method of the present invention), a photothermal conversion agent may be contained in any layer. it can.

  The photothermal conversion agent may generally be a dye or a pigment, and examples thereof include carbon black, cyanine, metal-free or metal phthalocyanine, metal dithiolene, and anthraquinone.

  EXAMPLES Hereinafter, the present invention will be specifically described with reference to examples, but it is needless to say that the present invention is not limited by this description.

Example 1
A 135 g / m ² double-sided polyethylene-coated paper (RC paper) was subjected to corona discharge processing, and then a layer having a formulation shown below (a layer to be converted to hydrophobicity by heat) and a hydrophilic layer were coated thereon.

(Coating liquid formulation for layers that are converted to hydrophobicity by heat)
Gelatin 35g
2,4-dichloro-6-hydroxy-S-triazine sodium 5 g
Carbon black 30g
Styrene / butadiene copolymer (40% dispersion) 400g
(Nipol-LX855EX1 manufactured by Nippon Zeon Co., Ltd.)
Activator (coating aid) 10g
Water was added to make the total amount 500 g. The coating liquid obtained as described above was applied at 50 g / m ² (moisture application amount). Thereafter, the following hydrophilic layer was further applied.

(Hydrophilic layer coating formulation)
50 g of the polyacrylic acid compound of the present invention (described in Table 1 as solid content)
2,4-dichloro-6-hydroxy-S-triazine sodium 2g
Activator (coating aid) 10g
Water was added to make the total amount 2000g.
The coating liquid obtained above was applied at 15 g / m ² (moisture application amount) to prepare a lithographic printing original plate. (Samples 1 to 7 of the present invention)

  As a comparative example, a coating solution was prepared in the same manner as Samples 1 to 7 of the present invention except that the following compounds (Chemical Formulas 8 and 9) and gelatin were used instead of the polyacrylic acid compound of the present invention. A lithographic printing original plate was produced under the same conditions except for the above. (Comparison 1 to 3 of the present invention)

  Next, laser irradiation of a portion corresponding to an image portion is performed on the original plate (side having a layer that is converted into hydrophobicity by heat) with a semiconductor laser irradiation apparatus (830 nm) to expose the hydrophobic surface to obtain a printing plate. It was. Using this printing plate, printing was performed with an offset printing machine (3200CD manufactured by Ryobi Magics Co., Ltd.).

The soiled state and printing durability of the printed material were evaluated according to the following criteria.
<Evaluation of dirt on printed matter>
1: Not dirty at all.
2: Partially dirty.
3: The entire surface is thin and dirty.
4: The entire surface is dirty.
<Evaluation of printing durability of printed matter>
1: Print image does not change at all.
2: The printed image is hardly changed, but the fine line image is slightly thinned.
3: Slightly lower ink density in the image area.
4: The ink density in the image area is lowered and the thin line portion is thinned.

The moisturizing liquid and ink used for evaluating the soiled state and printing durability of the printed material are shown below.
<Evaluation of dirt>
1: Moisturizer Nitro Chemical Co., Ltd. Astro Mark III 1% (Use water supply to make 1%.)
2: Ink Dai Nippon Ink Chemical Co., Ltd. New Champion Purple 68N
<Evaluation of printing durability>
1: Dampening solution Mitsubishi Paper Industries SLM-OD30 3% (Use water supply to make 3%.)
2: Ink Dai Nippon Ink Chemical Co., Ltd. New Champion Ink 85H
The evaluation of the dirt state is evaluated with the background dirt state of the 2000th sheet. The printing durability was evaluated in a state where the fine line image part (50 micron fine line) of the printed matter after printing 10,000 sheets was thin and the density of the image part was lowered. These results are shown in Table 1.

  As is clear from the above results, the lithographic printing plate precursor according to the present invention was able to obtain a printed matter with improved stain resistance.

Example 2
The coating liquid of the layer which is converted into hydrophobicity by heat used in the preparation of Samples 1 to 7 and Comparative Examples 1 to 3 of the present invention on one side of a 175 μm thick PET (polyethylene terephthalate) film does not add 30 g of carbon black. A coating solution was prepared under the same conditions except for the above. Thereafter, a lithographic printing original plate was produced in the same manner as in Example 1. (Samples 8 to 14 of the present invention, comparisons 4 to 6 of the present invention)

  Next, Okura Electric Co., Ltd. equipped with a thermal head having a resistance value of 1645 Ω on the surface of the lithographic printing original plate of Samples 8 to 14 of the present invention and Comparative Planes 4 to 6 on which the layer which is converted into hydrophobicity by heat is provided ) Using a thermosensitive facsimile printing test apparatus, printing was performed under conditions of a dot density of 8 dots / mm, an applied voltage of 21 V, and a pulse width of 1.2 ms. Using this printing plate, printing was performed with an offset printing machine (3200CD manufactured by Ryobi Magics Co., Ltd.). The print evaluation items and conditions are the same as those in the first embodiment. These evaluation results are shown in Table 2.

  As is clear from the above results, the lithographic printing plate precursor of the present invention can not only obtain a printed matter with improved stain resistance, but also a lithographic printing plate precursor using a conventional diazo compound, photopolymer, or silver salt. Unlike the light room, the work can be performed and the developer is not used, so the environment is very good. In addition, it is possible to cope with a direct drawing method using a low-power laser or a thermal printer, and it is possible to obtain a printing plate that is excellent in high resolution and can be realized at low cost.

Claims (3)

  In a lithographic printing original plate in which a layer to be converted to hydrophobicity by heat on a support and a hydrophilic layer as an outermost layer are provided, the hydrophilic layer contains a polyacrylic acid compound having an average molecular weight of 10,000 or more. A lithographic printing plate.   The lithographic printing plate precursor according to claim 1, wherein the layer that is converted to hydrophobicity by heat contains heat-fusible fine particles or heat-meltable fine particles.   The lithographic printing plate precursor according to claim 1 or 2, wherein a photothermal conversion agent is contained in at least one layer of the lithographic printing plate precursor.