JP2006266548A - Ash melting method - Google Patents

Ash melting method Download PDF

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JP2006266548A
JP2006266548A JP2005082910A JP2005082910A JP2006266548A JP 2006266548 A JP2006266548 A JP 2006266548A JP 2005082910 A JP2005082910 A JP 2005082910A JP 2005082910 A JP2005082910 A JP 2005082910A JP 2006266548 A JP2006266548 A JP 2006266548A
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ash
melting
carbide
molten
melting method
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Yasuaki Kurokawa
康明 黒川
Motoki Yamazaki
元樹 山崎
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NGK Insulators Ltd
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NGK Insulators Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an ash melting method capable of effectively melting the melting object ash by a surface melting system. <P>SOLUTION: Carbide is mixed in the melting object ash to be charged into an ash melting furnace 6 of the surface melting system in advance. The carbide is a powder body or a granulated material of which particle diameter is 10 mm or less, the mixing ratio is preferably 30% or less, and the carbide is preferably derived from the waste. In the ash melting furnace 6, the melting object ash is heated or melted from both of the inner and outer surfaces by heating from a surface of a melting object ash layer by a burner 9 and combustion heat of the carbide mixed into the inside of the melting object ash layer, and thereby melting excellent in heat efficiency is possible. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、汚泥、都市ごみ、産業廃棄物などの焼却炉から排出される焼却灰や、その溶融炉から出る溶融飛灰などの廃棄物由来の灰を、表面溶融方式の灰溶融炉において効率よく溶融するための灰溶融方法に関するものである。   The present invention is an efficient method for incineration ash discharged from incinerators such as sludge, municipal waste and industrial waste, and waste-derived ash such as molten fly ash from the melting furnace in an ash melting furnace of the surface melting type. The present invention relates to an ash melting method for melting well.

汚泥や都市ごみなどの焼却灰は従来は専ら埋め立て処分されてきたが、埋め立てに適する用地の確保が困難となっているうえ、焼却灰中から溶出する重金属が地下水に移行するなどの問題が指摘されているため、最近では焼却灰を1200〜1400℃の高温で溶融してスラグ化し、重金属を安定なガラス質中に封じ込める方法が普及している。   Conventionally, incineration ash such as sludge and municipal waste has been exclusively disposed of in landfills, but it is difficult to secure a suitable site for landfilling, and problems such as the migration of heavy metals eluted from the incineration ash to groundwater are pointed out Therefore, recently, a method of melting incineration ash at a high temperature of 1200 to 1400 ° C. to form slag and enclosing heavy metals in a stable glassy material has become widespread.

このためには例えば特許文献1に記載されているように灰溶融炉が用いられている。この特許文献1の灰溶融炉は旋回溶融と表面溶融とを組み合わせた構造となっているが、燃料式灰溶融炉の多くは炉内に投入した被溶融灰層の表面をバーナーにより加熱し、表面溶融を行う方式のものである。この表面溶融方式は、炉底部を緩やかに傾斜させておけば溶融スラグを自然に流下させることができる利点があるため、広く用いられている。   For this purpose, for example, an ash melting furnace is used as described in Patent Document 1. Although the ash melting furnace of this Patent Document 1 has a structure combining swirl melting and surface melting, most of the fuel type ash melting furnaces heat the surface of the molten ash layer charged into the furnace with a burner, This is a method of melting the surface. This surface melting method is widely used because there is an advantage that the molten slag can flow down naturally if the bottom of the furnace is gently inclined.

ところがこの方式は、図3に模式的に示すように被溶融灰層の表面のみから加熱される方式であるため、熱伝導率の小さい被溶融灰層の内部にまで熱が伝わりにくく、溶融に時間がかかるため、処理能力を高めようとするとかなり広い溶融面積を必要とするという問題があった。
特許第3071171号公報
However, since this method is a method in which heating is performed only from the surface of the ash layer to be melted as schematically shown in FIG. 3, heat is not easily transmitted to the inside of the ash layer to be melted with low thermal conductivity. Since it takes time, there is a problem that a considerably large melting area is required to increase the processing capacity.
Japanese Patent No. 3071171

本発明は上記した従来の問題点を解決して、表面溶融方式により被溶融灰を従来よりも短時間で効率よく溶融させることができる灰溶融方法を提供することを目的とするものである。   An object of the present invention is to solve the above-mentioned conventional problems and to provide an ash melting method capable of melting molten ash by a surface melting method in a shorter time than in the prior art.

上記の課題を解決するためになされた本発明の灰溶融方法は、表面溶融方式の灰溶融炉に投入される被溶融灰中に、予め炭化物を混合しておき、バーナーによる被溶融灰層の表面からの加熱と、被溶融灰層の内部に混合された炭化物の燃焼熱とによって、被溶融灰を内外両面から加熱溶融することを特徴とするものである。   In the ash melting method of the present invention made to solve the above-mentioned problems, carbides are mixed in advance into the molten ash charged into the ash melting furnace of the surface melting type, and the molten ash layer by the burner is mixed. The molten ash is heated and melted from both inside and outside by heating from the surface and combustion heat of carbide mixed in the molten ash layer.

なお、被溶融灰に対する炭化物の混合率は、炭化物性状により異なるが30%以下とすることが好ましく、炭化物の粒径は、10mm以下の粉体や造粒品とすることが好ましい。また炭化物は廃棄物由来のものであることが廃棄物処理の観点からは好ましい。   In addition, although the mixing rate of the carbide | carbonized_material with respect to a molten ash changes with carbide | carbonized_material properties, it is preferable to set it as 30% or less, and it is preferable that the particle size of a carbide | carbonized_material is 10 mm or less powder and granulated goods. Further, it is preferable from the viewpoint of waste treatment that the carbide is derived from waste.

本発明の灰溶融方法によれば、被溶融灰層をバーナーによる表面からの加熱と、被溶融灰層の内部に混合された炭化物の燃焼熱とによって、内外両面から加熱溶融することができる。特に炭化物は被溶融灰層の内部に混合されており溶融対象物に隣接した位置で発熱するので、非常に効率よく溶融させることが可能となる。特に炭化物として廃棄物の熱分解残渣、あるいは炭化炉で炭化処理した廃棄物などを用いれば、バーナー燃料の削減と廃棄物処理とを兼ねることができ、バーナー燃料である重油等を削減することができる。   According to the ash melting method of the present invention, the molten ash layer can be heated and melted from both the inside and outside by heating from the surface with a burner and the combustion heat of the carbide mixed in the molten ash layer. In particular, the carbide is mixed in the molten ash layer and generates heat at a position adjacent to the object to be melted, so that it can be melted very efficiently. In particular, if the pyrolysis residue of the waste or the waste carbonized in the carbonization furnace is used as the carbide, the burner fuel can be reduced and the waste can be treated, and the heavy oil that is the burner fuel can be reduced. it can.

以下に本発明の好ましい実施形態を示す。
図1において、1は被溶融灰の貯留槽であり、その内部には汚泥、都市ごみ、産業廃棄物などの焼却炉から排出される焼却灰や、その溶融炉から出る溶融飛灰などの廃棄物由来の灰が貯留されている。なおストーカー炉の灰のように塊状の灰は破砕機により破砕した状態としておくことが好ましい。
Preferred embodiments of the present invention are shown below.
In FIG. 1, reference numeral 1 denotes a molten ash storage tank, in which incineration ash discharged from an incinerator such as sludge, municipal waste, industrial waste, and molten fly ash discharged from the melting furnace is disposed. Ashes derived from things are stored. In addition, it is preferable to keep the massive ash like the ash of the stalker furnace crushed by a crusher.

貯留槽1内の灰は、その下部に設けられたスクリューフィーダ等の切り出し装置2によって、コンベヤ3上に一定量ずつ切り出される。この実施形態ではコンベヤ3として、無端チェーンに多数の送り板を取り付け、被溶融灰をこれらの送り板により押しながら移送するフライトコンベヤが用いられている。しかしコンベヤ3の構造は特に限定されるものではなく、例えばスクリューコンベヤを用いても差し支えない。   The ash in the storage tank 1 is cut out by a fixed amount on the conveyor 3 by a cutting device 2 such as a screw feeder provided in the lower part thereof. In this embodiment, as the conveyor 3, a flight conveyor is used in which a large number of feed plates are attached to an endless chain and the molten ash is transferred while being pushed by these feed plates. However, the structure of the conveyor 3 is not particularly limited, and for example, a screw conveyor may be used.

4は炭化物の貯留槽であり、その下部に設けられた切り出し装置5によって、炭化物がコンベヤ3上に一定量ずつ切り出される。炭化物としては、市販の炭化物を用いることもできるが、廃棄物由来の炭化物を用いることが好ましい。例えば木材、汚泥やごみなどを熱分解して製造した炭化物を用いることができる。炭化物の粒径は10mm以下であることが好ましい。これよりも粒径が大きいと均一に混合しにくいためである。   4 is a carbide storage tank, and a carbide is cut out on the conveyor 3 by a predetermined amount by a cutting device 5 provided in the lower part thereof. Although a commercially available carbide can be used as the carbide, it is preferable to use a carbide derived from waste. For example, a carbide produced by pyrolyzing wood, sludge, garbage, or the like can be used. The particle size of the carbide is preferably 10 mm or less. This is because if the particle size is larger than this, uniform mixing is difficult.

被溶融灰に対する炭化物の混合率は、炭化物性状により異なるが重量比で30%以下とすることが好ましい。これよりも多いと溶融スラグの量が増加し、スラグ化により廃棄物を減容処理するという本来の目的に反するためである。   The mixing ratio of the carbide to the ash to be melted varies depending on the properties of the carbide, but is preferably 30% or less by weight. If the amount is larger than this, the amount of molten slag increases, which is against the original purpose of volume reduction of waste by slag formation.

コンベヤ3上に一定量ずつ切り出された炭化物はその前段の貯留槽1から供給された被溶融灰と混合され、灰溶融炉6に投入される。上記したフライトコンベヤやスクリューコンベヤ等を用いれば、特別な混合手段を用いなくても炭化物と被溶融灰とはほぼ均一に混合される。これは両者のみかけ比重がほぼ等しいためである。   The carbides cut out by a certain amount on the conveyor 3 are mixed with the ash to be melted supplied from the preceding storage tank 1 and put into the ash melting furnace 6. If the above-described flight conveyor, screw conveyor or the like is used, the carbide and the molten ash are mixed almost uniformly without using any special mixing means. This is because the apparent specific gravity is almost equal.

灰溶融炉6は表面溶融方式の灰溶融炉であれば、その形状は特に限定されるものではない。この実施形態では、傾斜させた炉体の上部に投入口7を備え、下部に溶融スラグ排出口8を備えた灰溶融炉6が用いられている。投入された炭化物と被溶融灰との混合物は、炉体内部を層状に流下する間にバーナー9によって1200〜1400℃に加熱され、表面溶融される。   The shape of the ash melting furnace 6 is not particularly limited as long as it is a surface melting type ash melting furnace. In this embodiment, an ash melting furnace 6 having an inlet 7 at the top of the inclined furnace body and a molten slag outlet 8 at the bottom is used. The mixture of the introduced carbide and molten ash is heated to 1200 to 1400 ° C. by the burner 9 while flowing down in a layered manner inside the furnace body, and the surface is melted.

このとき、図2に示すように被溶融灰はバーナー9による被溶融灰層の表面からの加熱を受けるのみならず、被溶融灰層の内部に混合された炭化物の燃焼熱とによって、内外両面から加熱溶融される。炭化物は被溶融灰に接触した位置で燃焼するため、その燃焼熱は被溶融灰の溶融に効率よく寄与し、被溶融灰を速やかに溶融させる。なお、炭化物を微粉炭バーナーのようにバーナーフレーム中で燃焼させることも考えられるが、その場合にはその燃焼熱が被溶融灰の溶融に寄与する以外に、炉壁からの放熱や排ガスの加熱によっても消費されるため、本発明のように炭化物を被溶融灰中に混合する方法に比較して、熱効率が悪くなる。   At this time, as shown in FIG. 2, the molten ash is not only heated from the surface of the molten ash layer by the burner 9, but also by the combustion heat of the carbide mixed inside the molten ash layer. It is melted by heating. Since the carbide burns at a position in contact with the molten ash, the heat of combustion efficiently contributes to the melting of the molten ash and melts the molten ash quickly. It is also conceivable to burn the carbide in a burner frame like a pulverized coal burner. In that case, the heat of combustion contributes to the melting of the molten ash, and in addition, heat dissipation from the furnace wall and heating of the exhaust gas. Therefore, the thermal efficiency is deteriorated as compared with the method of mixing carbide in the molten ash as in the present invention.

このようにして被溶融灰は熱効率よく溶融されて溶融スラグとなり、炉体下部の溶融スラグ排出口8から流下する。この溶融スラグは路盤材をはじめ各種の用途に有効利用される。   In this way, the molten ash is melted efficiently and becomes molten slag, and flows down from the molten slag discharge port 8 at the lower part of the furnace body. This molten slag is effectively used for various applications including roadbed materials.

灰溶融炉に、炭化物を重量比で0%、10%、20%、30%の比率で混合した。被溶融灰と炭化物との性状は表1のとおりである。炭化物を添加しない場合には被溶融灰を完全にスラグ化するために、バーナー燃料として被溶融灰1tonあたり202Lの灯油を必要としたが、炭化物を10%添加した場合には灯油の使用量を17.7%減少させることができ、炭化物を20%添加した場合には灯油の使用量を34.8%減少させることができ、炭化物を30%添加した場合には灯油の使用量を53.2%減少させることができた。   Carbides were mixed in the ash melting furnace at a weight ratio of 0%, 10%, 20%, and 30%. Table 1 shows the properties of the molten ash and the carbide. In the case where no carbide is added, 202 L of kerosene per 1 ton of molten ash is required as burner fuel in order to completely slag the molten ash, but when 10% of carbide is added, the amount of kerosene used is reduced. The amount of kerosene used can be reduced by 34.8% when carbonized is added to 20%, and the amount of kerosene used is reduced by 53. 2% could be reduced.

Figure 2006266548
Figure 2006266548

本発明の第1の実施形態を示す説明図である。It is explanatory drawing which shows the 1st Embodiment of this invention. 本発明における要部説明図である。It is principal part explanatory drawing in this invention. 従来法における要部説明図である。It is principal part explanatory drawing in the conventional method.

符号の説明Explanation of symbols

1 被溶融灰の貯留槽
2 切り出し装置
3 コンベヤ
4 炭化物の貯留槽
5 切り出し装置
6 灰溶融炉
7 投入口
8 溶融スラグ排出口
9 バーナー
DESCRIPTION OF SYMBOLS 1 Storage tank of molten ash 2 Cutting device 3 Conveyor 4 Carbide storage tank 5 Cutting device 6 Ash melting furnace 7 Input port 8 Molten slag discharge port 9 Burner

Claims (4)

表面溶融方式の灰溶融炉に投入される被溶融灰中に、予め炭化物を混合しておき、バーナーによる被溶融灰層の表面からの加熱と、被溶融灰層の内部に混合された炭化物の燃焼熱とによって、被溶融灰を内外両面から加熱溶融することを特徴とする灰溶融方法。   Carbide is mixed in advance into the molten ash to be charged into the ash melting furnace of the surface melting method, heating from the surface of the molten ash layer by a burner, and the carbide mixed inside the molten ash layer An ash melting method characterized in that molten ash is heated and melted from both inside and outside by combustion heat. 被溶融灰に対する炭化物の混合率を、30%以下とすることを特徴とする請求項1記載の灰溶融方法。   2. The ash melting method according to claim 1, wherein a mixing ratio of the carbide to the molten ash is set to 30% or less. 炭化物の粒径を、10mm以下としたことを特徴とする請求項1記載の灰溶融方法。   The ash melting method according to claim 1, wherein the particle size of the carbide is 10 mm or less. 炭化物が廃棄物由来のものであることを特徴とする請求項1記載の灰溶融方法。   The ash melting method according to claim 1, wherein the carbide is derived from waste.
JP2005082910A 2005-03-23 2005-03-23 Ash melting method Pending JP2006266548A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008170091A (en) * 2007-01-12 2008-07-24 Jfe Engineering Kk Simultaneous treating method for combustible waste and low heating value waste

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008170091A (en) * 2007-01-12 2008-07-24 Jfe Engineering Kk Simultaneous treating method for combustible waste and low heating value waste

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