JP2006249514A - HOT-ROLLED STEEL PLATE OF Cr-CONTAINING ALLOY HAVING HIGH STRENGTH AND SUPERIOR WORKABILITY, AND MANUFACTURING METHOD THEREFOR - Google Patents

HOT-ROLLED STEEL PLATE OF Cr-CONTAINING ALLOY HAVING HIGH STRENGTH AND SUPERIOR WORKABILITY, AND MANUFACTURING METHOD THEREFOR Download PDF

Info

Publication number
JP2006249514A
JP2006249514A JP2005068330A JP2005068330A JP2006249514A JP 2006249514 A JP2006249514 A JP 2006249514A JP 2005068330 A JP2005068330 A JP 2005068330A JP 2005068330 A JP2005068330 A JP 2005068330A JP 2006249514 A JP2006249514 A JP 2006249514A
Authority
JP
Japan
Prior art keywords
hot
less
rolled
containing alloy
rolled steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2005068330A
Other languages
Japanese (ja)
Inventor
Masayuki Kasai
正之 笠井
Yoshihiro Yazawa
好弘 矢沢
Osamu Furukimi
古君  修
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
JFE Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JFE Steel Corp filed Critical JFE Steel Corp
Priority to JP2005068330A priority Critical patent/JP2006249514A/en
Publication of JP2006249514A publication Critical patent/JP2006249514A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Heat Treatment Of Sheet Steel (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a hot-rolled steel plate of a Cr-containing alloy having high strength and superior workability, and to provide a manufacturing method therefor. <P>SOLUTION: The hot-rolled steel plate of the Cr-containing alloy comprises 0.003% to 0.03% C, 0.003% to 0.02% N, more than 1.0% but at most 3.0% Si, more than 1.0% but at most 3.0% Mn, at most 0.05% P, at most 0.01% S, 11% to 18% Cr, more than 1.0% but at most 3.0% Ni, 0.005% or more but less than 0.030% V, at most 0.05% Al, at most 0.0050% O by mass%, and the balance Fe with unavoidable impurities; and has a metallurgic structure comprising, by a volume fraction, a ferritic phase in an amount of 50% or more and a martensitic phase in an amount of less than 50%. The manufacturing method comprises the steps of: hot-rolling the steel having the above composition at a finish-rolling end temperature of 800 to 1,000°C and a winding temperature of 900°C or lower; and annealing the hot-rolled plate at an annealing temperature of 600 to 900°C. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、高強度かつ加工性に優れた熱延鋼板に係り、電気電子機器部品や自動車部品などとして好適な、高強度かつ加工性に優れたCr含有合金熱延鋼板ならびにその製造方法に関する。   The present invention relates to a hot-rolled steel sheet having high strength and excellent workability, and more particularly to a Cr-containing alloy hot-rolled steel sheet having high strength and excellent workability, which is suitable for electrical and electronic equipment parts and automobile parts, and a method for producing the same.

近年、自動車産業では、地球環境の保全という観点から、車体重量を軽量化し燃費向上で排出ガス量を低減することが強く求められている。その対策の一つとして、足回りや車体補強部品などの構造部材への高強度鋼板の適用が推進されている。   In recent years, in the automobile industry, from the viewpoint of the preservation of the global environment, it has been strongly demanded to reduce the amount of exhaust gas by reducing the weight of the vehicle body and improving the fuel consumption. As one of the countermeasures, the application of high-strength steel plates to structural members such as undercarriages and body reinforcement parts is being promoted.

自動車用の構造部材は、プレス成形後に防錆処理として、アクリルやウレタン、エポキシ系樹脂等の塗装が施される。塗装は脱脂、化成処理、塗装、水洗、乾燥(焼き付け)と多くの工程を要し、塗装ラインの建設には多額の資金が必要となる。このため近年の生産工場の海外進出に伴い、塗装工程の簡略化が重要な課題と考えられている。さらに、塗装による防錆は部品端部の膜厚が薄くなりやすく、耐食性が局所的に低下するという問題がある。また、足回りに用いる場合は路面からの石の跳ね返りにより塗膜が欠損し、耐食性が急激に低下するという問題があり、材料自身の耐食性を向上させることが求められている。   The structural member for automobiles is coated with acrylic, urethane, epoxy resin or the like as a rust prevention treatment after press molding. Painting requires many steps such as degreasing, chemical conversion, painting, washing, drying (baking), and construction of a painting line requires a large amount of funds. For this reason, simplification of the painting process is considered an important issue with the recent expansion of production plants overseas. Furthermore, the rust prevention by painting has a problem that the film thickness at the end of the component tends to be thin, and the corrosion resistance is locally lowered. Moreover, when using for suspension, there exists a problem that a coating film lose | disappears by the bounce of the stone from a road surface, and corrosion resistance falls rapidly, and improving the corrosion resistance of material itself is calculated | required.

また、電気部品や家電製品のケ−ス等の部品においても、素材の薄肉化で容積を増し、製品の高機能化に対応することが求められている。高機能化に伴い、部品の形状も多様化しており、高い加工性と耐食性を兼備した材料の開発が臨まれている。   In addition, in parts such as electrical parts and cases of household electrical appliances, it is required to increase the volume by reducing the thickness of the material and cope with higher functionality of the product. Along with higher functionality, the shape of parts is also diversifying, and development of materials that combine high workability and corrosion resistance is underway.

以上のように、高強度化し、高耐食化を目的として、種々の産業において構造部材にCr含有鋼が無垢で使用され始めている。しかし、Cr含有鋼を加工度が高い構造部材として適用するためには、さらに優れた加工性を兼備する必要がある。   As described above, Cr-containing steel has begun to be used as a structural member in various industries for the purpose of increasing strength and increasing corrosion resistance. However, in order to apply Cr-containing steel as a structural member having a high workability, it is necessary to have further excellent workability.

一般的な高強度Cr含有鋼として、SUS301等のオーステナイト系ステンレス鋼を冷間圧延あるいは熱処理し硬質化させたばね材や、SUS410等のマルテンサイト系ステンレス鋼が広く用いられている。このうち、オーステナイト系ステンレス鋼製のばね材は、高価なNiを多量に含むことに加え、構造材として用いた場合には応力腐食割れ感受性が高いという問題がある。また、マルテンサイト系ステンレス鋼は、価格が安いという利点があるが、引張強さTSが600MPaを越えるような高強度を志向する場合は、最終焼鈍でAc1点以上まで加熱して焼入れ処理を行うか、マルテンサイト状態から低温処理(ハーフ焼鈍)を行う必要がある。しかし、いずれの処理によるマルテンサイト系ステンレス鋼も伸びが低く、十分な加工性が得られないという問題がある。 As a general high-strength Cr-containing steel, a spring material obtained by hardening austenitic stainless steel such as SUS301 by cold rolling or heat treatment, and martensitic stainless steel such as SUS410 are widely used. Among these, the spring material made of austenitic stainless steel has a problem of high stress corrosion cracking sensitivity when used as a structural material in addition to containing a large amount of expensive Ni. In addition, martensitic stainless steel has the advantage of low price, but if it is intended to have a high strength such that the tensile strength TS exceeds 600MPa, it is heated to Ac1 point or higher in the final annealing. It is necessary to perform the low temperature treatment (half annealing) from the martensite state. However, the martensitic stainless steel produced by any treatment has a problem that the elongation is low and sufficient workability cannot be obtained.

また、高強度鋼板を各種部材として適用するに際し、種々の成形に適応することを目的としたステンレス鋼板が開発されている。   In addition, when a high-strength steel plate is applied as various members, a stainless steel plate has been developed for the purpose of adapting to various forming.

例えば、特許文献1では、重量%でCr:6〜18%を含有し、さらにC, Nの合計を0.025%以下に調整し、Si:2%以下、Mn:1%越5%以下、P:0.05%以下、S:0.02%以下、Ni:0.1〜3%、Al:0.1%以下、V:0.03〜0.3%を含有しかつ、γp=420C+470N+23Ni+9Cu+7Mn-11.5Cr-11.5Si-12Mo-23V-47Nb-49Ti-52Al+189で定義されるγpを50以上70以下に調整することによって、加工性と溶接性に優れるステンレス鋼を得る技術が開示されている。 For example, Patent Document 1 contains Cr: 6 to 18% by weight, and further adjusts the total of C and N to 0.025% or less, Si: 2% or less, Mn: 1% over 5%, P : 0.05% or less, S: 0.02% or less, Ni: 0.1 to 3%, Al: 0.1% or less, V: 0.03 to 0.3%, and γ p = 420C + 470N + 23Ni + 9Cu + 7Mn-11.5Cr A technique for obtaining stainless steel excellent in workability and weldability by adjusting γ p defined by -11.5Si-12Mo-23V-47Nb-49Ti-52Al + 189 to 50 or more and 70 or less is disclosed.

特許文献2では、重量%でCr:6〜15%を含有し、さらにC:0.02%以下、Si:1%以下、Mn:1〜5%以下、P:0.05%以下、S:0.02%以下、Ni:1%以下、Al:0.1%以下、N:0.02%以下、V:0.03〜0.3%を含有しかつ、F値=Cr+0.4×Si+0.2×Al+5×P-0.4×Mn-0.7×Ni-35×C-10×N+10×Vで定義されるF値に、各成分の含有量の値を代入し算出したF値を13.5以下に調整することによって、HAZの靭性、強度および耐食性が優れたステンレス鋼を得る技術が開示されている。   Patent Document 2 contains Cr: 6 to 15% by weight, C: 0.02% or less, Si: 1% or less, Mn: 1 to 5% or less, P: 0.05% or less, S: 0.02% or less Ni: 1% or less, Al: 0.1% or less, N: 0.02% or less, V: 0.03-0.3%, and F value = Cr + 0.4 × Si + 0.2 × Al + 5 × P-0.4 × Mn The toughness of HAZ is adjusted by substituting the calculated F value to 13.5 or less by substituting the content value of each component into the F value defined by -0.7 × Ni-35 × C-10 × N + 10 × V. A technique for obtaining stainless steel having excellent strength and corrosion resistance is disclosed.

特許文献3では、重量%でCr:8越え15%未満を含有し、さらにC:0.01以上0.54%未満、V:0.01%以上0.5%未満、W:0.001%以上0.05%未満の範囲で含有させるとともに、X=Cr+Mo+1.5Si+0.5Nb+0.2V+8Al-Ni-0.6Co-0.5Mn-30C-30N-0.5Cuで定義されるX値に関して11.0以下を満足するように調整することで、初期発錆性、加工性および溶接性に優れるステンレス鋼を得る技術が開示されている。
特開2002-167653号公報 特開2002-121652号公報 特開2002-53938号公報
According to Patent Document 3, Cr: more than 8 and less than 15% is contained, and C: 0.01 or more and less than 0.54%, V: 0.01% or more and less than 0.5%, W: 0.001% or more and less than 0.05% At the same time, adjust so that X value defined by X = Cr + Mo + 1.5Si + 0.5Nb + 0.2V + 8Al-Ni-0.6Co-0.5Mn-30C-30N-0.5Cu satisfies 11.0 or less Thus, a technique for obtaining stainless steel excellent in initial rusting property, workability and weldability is disclosed.
JP 2002-167653 A JP 2002-121652 JP JP 2002-53938 A

しかしながら、特許文献1に記載された技術では、V含有量を0.03%以上とする必要があり、その結果、V炭窒化物の量が多くなるため、600MPaを越える高強度材として適用する場合には、延性が低下し加工性が劣化するという問題がある。   However, in the technique described in Patent Document 1, it is necessary to make the V content 0.03% or more, and as a result, the amount of V carbonitride increases, so when applied as a high strength material exceeding 600 MPa. Has a problem that ductility is lowered and workability is deteriorated.

特許文献2に記載された技術では、Si含有量が少ないため、高強度材として適用するには、多量のMnを含有する必要がある。そのため、熱延板を600〜900℃程度で箱焼鈍した場合でも、延性が低下し、十分な加工性が得られないという問題がある。   In the technique described in Patent Document 2, since the Si content is small, it is necessary to contain a large amount of Mn in order to be applied as a high-strength material. Therefore, even when the hot-rolled sheet is subjected to box annealing at about 600 to 900 ° C., there is a problem that ductility is lowered and sufficient workability cannot be obtained.

特許文献3に記載された技術では、Co, VおよびWを複合添加する必要があり、これらの元素の固溶強化作用によって、文献1、2と同様に、延性が低下し加工性が劣化するという問題がある。また、原料コストが高いという問題がある。   In the technique described in Patent Document 3, it is necessary to add Co, V and W in combination, and due to the solid solution strengthening action of these elements, the ductility is lowered and the workability is deteriorated as in References 1 and 2. There is a problem. Moreover, there is a problem that the raw material cost is high.

本発明は上記問題点を解決するためになされたもので、高強度かつ高延性で、かつ構造部材として重要な特性である伸びフランジ性に優れたCr含有合金熱延鋼板ならびにその製造方法を提供することを目的とする。   The present invention has been made to solve the above problems, and provides a Cr-containing alloy hot-rolled steel sheet having high strength and high ductility and excellent stretch flangeability, which is an important characteristic as a structural member, and a method for producing the same. The purpose is to do.

本発明者らは、上記の課題を解決すべく、強度と加工性に影響を与える各種要因について鋭意研究した。その結果、一般的なCによる強化機構を用いた鋼ではなく、適正量のCrを含有させた上で、C、N、Si、Mn、P、S、Ni、V、Al含有量を規制した鋼組成とし、さらに、製造時の熱間圧延条件と熱延板焼鈍条件を調整することにより、フェライト相をベースとし、第2相としてマルテンサイト相を均一に分散させた組織とすることで、ベース相の延性を保ちながら、第2相との強度差を比較的少なくし、強度および加工性が飛躍的に向上することを見出した。   In order to solve the above-mentioned problems, the present inventors have intensively studied various factors affecting the strength and workability. As a result, the content of C, N, Si, Mn, P, S, Ni, V, and Al was regulated after containing an appropriate amount of Cr, not steel using a general C strengthening mechanism. By making the steel composition, and further by adjusting the hot rolling conditions and hot rolled sheet annealing conditions at the time of manufacture, the ferrite phase is the base, and the second phase is a structure in which the martensite phase is uniformly dispersed, While maintaining the ductility of the base phase, it was found that the difference in strength from the second phase was relatively small, and the strength and workability were dramatically improved.

本発明は、以上の知見に基づきなされたもので、その要旨は以下のとおりである。   The present invention has been made based on the above findings, and the gist thereof is as follows.

[1]mass%で、C:0.003%以上0.03%以下、N:0.003%以上0.02%以下、Si:1.0%越え3.0%以下、Mn:1.0%越え3.0%以下、P:0.05%以下、S:0.01%以下、Cr:11%以上18%以下、Ni: 1.0%越え3.0%以下、V:0.005%以上0.030%未満、Al: 0.05%以下、O:0.0050%以下を含有し、残部がFeおよび不可避的不純物からなり、金属組織として、体積分率で、フェライト相:50%以上、マルテンサイト相:50%未満の組織を有することを特徴とする引張強さ600MPa以上である高強度かつ加工性に優れたCr含有合金熱延鋼板。   [1] In mass%, C: 0.003% to 0.03%, N: 0.003% to 0.02%, Si: 1.0% to 3.0%, Mn: 1.0% to 3.0%, P: 0.05% or less, S : 0.01% or less, Cr: 11% to 18%, Ni: 1.0% to 3.0%, V: 0.005% to less than 0.030%, Al: 0.05% or less, O: 0.0050% or less, the balance being Fe It consists of unavoidable impurities, and has a tensile strength of 600 MPa or more, characterized by having a metal structure with a volume fraction of ferrite phase: 50% or more and martensite phase: less than 50%. Cr-containing alloy hot-rolled steel sheet with excellent properties.

[2]前記[1]において、mass%で、Ti:0.05%以上0.3%以下、Nb:0.05%以上0.3%以下、Zr:0.05%以上0.3%以下のうちから選ばれた1種または2種以上を含有することを特徴とする引張強さ600MPa以上である高強度かつ加工性に優れたCr含有合金熱延鋼板。   [2] In the above [1], one or two selected in mass% from Ti: 0.05% to 0.3%, Nb: 0.05% to 0.3%, Zr: 0.05% to 0.3% A Cr-containing alloy hot-rolled steel sheet having a high strength and excellent workability with a tensile strength of 600 MPa or more, characterized by containing the above.

[3]前記[1]または[2]において、さらに、mass%で、Cu:2.0%以下を含有することを特徴とする引張強さ600MPa以上である高強度かつ加工性に優れたCr含有合金熱延鋼板。   [3] In the above [1] or [2], the Cr-containing alloy having a high tensile strength of 600 MPa or more and excellent workability, further comprising mass% and Cu: 2.0% or less Hot rolled steel sheet.

[4]Crを含有する鋼素材に熱間圧延を施し熱延板とした後、該熱延板に焼鈍を施しCr含有合金熱延鋼板を製造するに際し、前記鋼素材を、前記[1]〜[3]のいずれかに記載の組成を有する鋼素材とし、前記熱間圧延を、仕上げ圧延終了温度を800〜1000℃、巻取り温度を900℃以下で行い、前記熱延板焼鈍を、焼鈍温度を600〜900℃で行うことを特徴とする引張強さ600MPa以上である高強度かつ加工性に優れたCr含有合金熱延鋼板の製造方法。   [4] When a steel material containing Cr is hot-rolled to form a hot-rolled sheet, the hot-rolled sheet is annealed to produce a Cr-containing alloy hot-rolled steel sheet. To the steel material having the composition according to any one of [3], the hot rolling is performed at a finish rolling finish temperature of 800 to 1000 ° C. and a winding temperature of 900 ° C. or less, and the hot rolled sheet annealing is performed. A method for producing a Cr-containing alloy hot-rolled steel sheet having a tensile strength of 600 MPa or more and excellent workability, characterized in that the annealing temperature is 600 to 900 ° C.

なお、本明細書において、鋼の成分を示す%はすべてmass%である。   In addition, in this specification, all% which shows the component of steel is mass%.

本発明によれば、600MPa以上の引張り強さ、および伸びElが16%以上、穴拡げ率λが80%を有する、高強度でかつ加工性に優れたCr含有合金熱延鋼板を得ることができる。   According to the present invention, it is possible to obtain a Cr-containing alloy hot-rolled steel sheet having a tensile strength of 600 MPa or more, an elongation El of 16% or more, a hole expansion ratio λ of 80%, and high strength and excellent workability. it can.

そして、本発明によるCr含有合金熱延鋼板は、例えば自動車、電気電子機器の構造部材として要求される強度、延性、伸びフランジ性の全ての特性を満足しており、産業上格段の効果を有する。   The Cr-containing alloy hot-rolled steel sheet according to the present invention satisfies all the characteristics of strength, ductility and stretch flangeability required as structural members for automobiles, electrical and electronic equipment, and has remarkable industrial effects. .

本発明のCr含有合金熱延鋼板は、下記に示す組成に制御し、体積分率で、フェライト相:50%以上、マルテンサイト相:50%未満の組織を有することを特徴とする。そして、これらの特徴は、上記鋼板を製造するに際し、熱間圧延を、仕上げ終了温度:800〜1000℃、巻取り温度:900℃以下で行い、熱延板焼鈍を焼鈍温度:600〜900℃で行うことにより得られ、本発明においてはこの熱間圧延における仕上圧延条件および熱延板焼鈍条件を製造方法の特徴とする。以上のように、組成、組織が最適化されることにより、高強度かつ加工性に優れたCr含有合金熱延鋼板が得られる。   The Cr-containing alloy hot-rolled steel sheet of the present invention is controlled to the following composition, and has a volume fraction of a ferrite phase: 50% or more and a martensite phase: less than 50%. And when these characteristics manufacture the said steel plate, hot rolling is performed by finishing finishing temperature: 800-1000 degreeC, coiling temperature: 900 degrees C or less, and hot-rolled sheet annealing is annealing temperature: 600-900 degreeC In the present invention, the finish rolling conditions and hot-rolled sheet annealing conditions in the hot rolling are the characteristics of the manufacturing method. As described above, a Cr-containing alloy hot-rolled steel sheet having high strength and excellent workability can be obtained by optimizing the composition and the structure.

以下、本発明を詳細に説明する。   Hereinafter, the present invention will be described in detail.

まず、本発明における鋼の化学成分(組成)の限定理由は以下の通りである。   First, the reasons for limiting the chemical composition (composition) of steel in the present invention are as follows.

C:0.003%以上0.03%以下、
Cは、鋼の強度上昇に極めて有効に作用する元素であるが、過剰な含有は加工性や靭性を低下させる。よって、本発明では、Cは0.003%以上0.03%以下とする。好ましくは0.004%以上0.025%以下である。
C: 0.003% to 0.03%,
C is an element that works extremely effectively in increasing the strength of steel, but excessive inclusion reduces workability and toughness. Therefore, in the present invention, C is made 0.003% to 0.03%. Preferably it is 0.004% or more and 0.025% or less.

N:0.003%以上0.02%以下、
Nは、Cと同様に鋼の強度上昇に有効に作用する元素であるが、過剰な含有は靭性を低下させるだけでなく、加工性をも低下させる。よって、本発明では、Nは0.003%以上0.02%以下とする。好ましくは0.004%以上0.015%以下である。
N: 0.003% to 0.02%,
N, like C, is an element that effectively acts to increase the strength of steel. However, excessive content not only reduces toughness but also reduces workability. Therefore, in the present invention, N is set to 0.003% or more and 0.02% or less. Preferably it is 0.004% or more and 0.015% or less.

Si:1.0%越え3.0%以下、
Siは、鋼の強化元素であると同時に、耐酸化性ならびに耐食性高めるのに有効に作用する元素である。また、フェライト相を安定化させ、高強度化する効果を有する。さらに、オーステナイト相安定化元素であるMnと複合添加することで、熱間圧延中にオ−ステナイト相が安定になり、オ−ステナイト相中にC, Nを多量に固溶することが出来る。その後の冷却過程でオ−ステナイト相はマルテンサイト相へ変態するが、その際、Cr炭窒化物の析出を抑制することが考えられる。以上の効果を得るためには、Siは1.0%超えの含有を必要とする。一方、3.0%を超えて過剰に含有すると、伸びや靭性の低下、あるいは加工割れが発生する危険性が大きくなる。よって、上限は3.0%以下とする。すなわち、本発明では、Siは、1.0%超え3.0%以下とする。好ましくは1.2%以上2.8%以下である。
Si: more than 1.0% and less than 3.0%,
Si is a strengthening element of steel, and at the same time, an element that effectively acts to increase oxidation resistance and corrosion resistance. Moreover, it has the effect of stabilizing the ferrite phase and increasing the strength. Furthermore, the composite addition of Mn, which is an austenite phase stabilizing element, stabilizes the austenite phase during hot rolling, so that a large amount of C and N can be dissolved in the austenite phase. In the subsequent cooling process, the austenite phase transforms into a martensite phase, and at this time, it is considered that the precipitation of Cr carbonitride is suppressed. In order to acquire the above effect, Si needs to contain more than 1.0%. On the other hand, if the content exceeds 3.0%, the risk of elongation, toughness deterioration, or processing cracking increases. Therefore, the upper limit is 3.0% or less. That is, in the present invention, Si is more than 1.0% and not more than 3.0%. Preferably they are 1.2% or more and 2.8% or less.

Mn:1.0%越え3.0%以下、
Mnは、高温でオーステナイト相を安定化させ、その後の冷却中にマルテンサイト相を生成させる作用がある。したがって、鋼の強度上昇に有効であり、本発明においては重要な元素である。このような効果は1.0%を越える含有で顕著となる。一方、3.0%を越えて多量に含有すると、靭性を低下させるばかりでなく、耐食性を劣化させる。以上より、本発明では、Mnは、1.0%越え3.0%以下とする。好ましくは1.2%以上2.5%以下である。
Mn: more than 1.0% and less than 3.0%,
Mn has the effect of stabilizing the austenite phase at high temperatures and generating a martensite phase during subsequent cooling. Therefore, it is effective for increasing the strength of steel and is an important element in the present invention. Such an effect becomes remarkable when the content exceeds 1.0%. On the other hand, if the content exceeds 3.0%, not only the toughness is lowered, but also the corrosion resistance is deteriorated. From the above, in the present invention, Mn is set to more than 1.0% and not more than 3.0%. Preferably they are 1.2% or more and 2.5% or less.

P:0.05%以下、
Pは、鋼を高強度化するが、含有量が多くなるほど伸びと靭性を低下させる。よって、本発明では、Pは0.05%以下とする。好ましくは0.04%以下である。
P: 0.05% or less,
P increases the strength of steel, but as the content increases, the elongation and toughness decrease. Therefore, in the present invention, P is set to 0.05% or less. Preferably it is 0.04% or less.

S:0.01%以下、
Sは、Mnと結合しやすいため、MnSを形成して鋼板の曲げ加工性を劣化させるばかりでなく、耐食性を著しく劣化させる。このため本発明ではSはできるだけ低減することが望ましいが、0.01%までの含有であれば許容できる。よって、本発明では、Sは0.01%以下とする。好ましくは0.005%以下である。
S: 0.01% or less,
Since S is easy to bond with Mn, not only does MnS form and the bending workability of the steel sheet deteriorates, but also the corrosion resistance significantly deteriorates. For this reason, in the present invention, it is desirable to reduce S as much as possible, but if it is contained up to 0.01%, it is acceptable. Therefore, in the present invention, S is set to 0.01% or less. Preferably it is 0.005% or less.

Cr:11%以上18%以下、
Crは、耐食性の向上ならびに耐酸化性の向上に不可欠な元素である。このような効果は、11%以上の含有で顕著となる。また、Crはフェライト相の高強度化も非常に有効であり、フェライト相と第2相のマルテンサイト相との強度差を減少させ、Crを十分含まない一般のDP鋼板で問題となる、フェライト相と第2相との強度差による割れを防止する効果をも有する。一方で、18%を超える含有は、本発明で重要なマルテンサイト相の形成を阻害するばかりでなく、靭性の低下を招く。よって、本発明では、Crは11%以上18%以下とする。好ましくは11.5%以上17.5%以下である。
Cr: 11% to 18%,
Cr is an element indispensable for improving corrosion resistance and oxidation resistance. Such an effect becomes remarkable when the content is 11% or more. Cr is also very effective in increasing the strength of the ferrite phase, reducing the difference in strength between the ferrite phase and the second martensite phase, which is a problem with ordinary DP steel sheets that do not contain enough Cr. It also has the effect of preventing cracking due to the strength difference between the phase and the second phase. On the other hand, the content exceeding 18% not only inhibits the formation of the martensite phase important in the present invention, but also causes a decrease in toughness. Therefore, in the present invention, Cr is 11% or more and 18% or less. Preferably they are 11.5% or more and 17.5% or less.

Ni:1.0%超え3.0%以下、
Niは、靭性ならびに耐食性の向上に寄与し、かつ高温でγ相を形成する。γ相は冷却中にマルテンサイト変態し、高強度化に有効に寄与する。この効果を得るためには、1.0%を超えて含有することが望ましい。一方で、Niは高価であり、多量の含有は材料コストの高騰を招く。よって、本発明では、Niは3.0%以下とする。好ましくは1.1%以上2.8%以下である。
Ni: more than 1.0% and less than 3.0%,
Ni contributes to improvement of toughness and corrosion resistance, and forms a γ phase at a high temperature. The γ phase undergoes martensitic transformation during cooling and contributes effectively to increasing the strength. In order to acquire this effect, it is desirable to contain exceeding 1.0%. On the other hand, Ni is expensive, and the inclusion of a large amount leads to an increase in material cost. Therefore, in the present invention, Ni is set to 3.0% or less. Preferably they are 1.1% or more and 2.8% or less.

V:0.005%以上0.030%未満、
Vは、本発明鋼のようにMnを多く含有する場合、熱間圧延中に(α+γ)2相域を通過し、冷却される際に、大部分は炭窒化物あるいはりん化物としてフェライト相中に分散析出し、フェライト相を安定化させる作用がある。また、Vは、TiやNb、Zrといった、その他の安定化元素に比べると、C, Nとの化学結合力が弱く、V炭窒化物はCrを含んだ形態(例えば、(Cr, V)2(C, N))で析出する場合がある。これらのV炭窒化物がフェライト相中に適度に分散している場合は、マトリクスとの相性が良く、変形が加えられた際にマトリクスとの界面で破壊の起点となりにくい。このため、フェライト相の延性を高く保ちつつ、高強度化することが可能となる。このような高強度化されかつ延性に優れるフェライト相は、本発明において、強度と加工性の両特性向上に対して極めて重要であり、このような効果は、0.005%以上の含有で顕著となる。一方で、0.030%以上の含有はV炭窒化物の量が多くなり過ぎ、またVの固溶量も増すため、本発明のような600MPaを越える高強度材を志向する場合は、延性が低下し加工性が劣化する。以上より、本発明では、Vは、0.005%以上0.030%未満とする。好ましくは0.01%以上0.025%未満である。
V: 0.005% or more and less than 0.030%,
When V contains a large amount of Mn as in the steel of the present invention, it passes through the (α + γ) 2 phase region during hot rolling, and when cooled, most of the ferrite is carbonitride or phosphide. Disperses and precipitates in the phase and stabilizes the ferrite phase. V is weaker in chemical bonding with C and N than other stabilizing elements such as Ti, Nb and Zr, and V carbonitride contains Cr (for example, (Cr, V) 2 (C, N)). When these V carbonitrides are appropriately dispersed in the ferrite phase, the compatibility with the matrix is good, and when deformation is applied, it is unlikely to become a starting point of fracture at the interface with the matrix. For this reason, it is possible to increase the strength while keeping the ductility of the ferrite phase high. Such a high-strength and excellent ductility ferrite phase is extremely important for improving both strength and workability in the present invention, and such an effect becomes significant when the content is 0.005% or more. . On the other hand, if the content is 0.030% or more, the amount of V carbonitride increases too much, and the solid solution amount of V also increases. Therefore, when aiming for a high strength material exceeding 600 MPa as in the present invention, ductility decreases. However, the workability deteriorates. From the above, in the present invention, V is set to 0.005% or more and less than 0.030%. Preferably it is 0.01% or more and less than 0.025%.

Al: 0.05%以下、
Alは非常に強力な酸化物形成元素であり、0.05%を超えて含有すると、Al2O3系酸化物がクラスター状になり表面欠陥が発生しやすくなる。よって、本発明では、Alは、0.05%以下とする。好ましくは0.04%以下である。なお、本発明では、Alを意図的に脱酸剤として添加しない場合も含むものとする。その場合、Alは不可避的不純物として0.004%未満程度が許容される。
Al: 0.05% or less,
Al is a very strong oxide-forming element. If it contains more than 0.05%, the Al 2 O 3 oxide is clustered and surface defects are likely to occur. Therefore, in the present invention, Al is made 0.05% or less. Preferably it is 0.04% or less. In the present invention, the case where Al is not intentionally added as a deoxidizer is included. In that case, Al is allowed to be less than 0.004% as an inevitable impurity.

O:0.0050%以下、
Oは、介在物あるいは固溶状態で鋼中に存在し、溶接時に酸化物を生成するため、本発明ではできるだけ低減することが好ましい。また、Oを0.0050%越えて含有すると酸化物の量が増加し、母材自体の加工性を低下させるだけでなく、耐食性の劣化を招く。よって、本発明では、Oは、0.0050%以下とする。好ましくは0.0040%以下である。
O: 0.0050% or less,
O is present in the steel in the form of inclusions or in a solid solution state, and generates an oxide during welding. Therefore, it is preferable to reduce it as much as possible in the present invention. Further, if O is contained in an amount exceeding 0.0050%, the amount of oxide increases, not only lowering the workability of the base material itself, but also causing deterioration in corrosion resistance. Therefore, in the present invention, O is made 0.0050% or less. Preferably it is 0.0040% or less.

本発明の鋼板は、上記の必須添加元素で目的とする特性が得られるが、所望の特性に応じて以下の元素を含有することができる。   The steel sheet of the present invention can achieve the desired characteristics with the above-mentioned essential additive elements, but can contain the following elements depending on the desired characteristics.

Ti:0.05%以上0.3%以下、Nb:0.05%以上0.3%以下、Zr:0.05%以上0.3%以下の1種または2種以上、
Ti、NbおよびZrは、いずれも溶接による熱影響部の鋭敏化を抑制し、耐食性を向上させるのに有効な元素であり、必要に応じて1種または2種以上を選択して含有することできる。上記した効果は、Ti:0.05%以上、Nb:0.05%以上、Zr:0.05%以上の含有で顕著となる。一方で、Ti: 0.3%超え、Nb:0.3%超え、Zr:0.3%超えの含有は、母材および溶接部熱影響部の靭性を低下させる。よって、含有する場合は、Ti:0.05%以上0.3%以下、Nb:0.05%以上0.3%以下、Zr:0.05%以上0.3%以下とする。好ましくはTi:0.08%以上0.25%以下、Nb:0.1%以上0.25%以下、Zr:0.08%以上0.25%以下である。
Ti: 0.05% to 0.3%, Nb: 0.05% to 0.3%, Zr: 0.05% to 0.3%, one or more,
Ti, Nb, and Zr are elements that are effective in suppressing the sensitization of the heat-affected zone by welding and improving the corrosion resistance, and contain one or more as required. it can. The above-described effects become significant when Ti: 0.05% or more, Nb: 0.05% or more, and Zr: 0.05% or more. On the other hand, the inclusion of Ti: more than 0.3%, Nb: more than 0.3%, and Zr: more than 0.3% lowers the toughness of the base metal and the heat affected zone of the weld zone. Therefore, when contained, Ti: 0.05% to 0.3%, Nb: 0.05% to 0.3%, Zr: 0.05% to 0.3%. Preferably, Ti is 0.08% to 0.25%, Nb is 0.1% to 0.25%, and Zr is 0.08% to 0.25%.

Cu:2.0%以下、
Cuは、耐食性を向上させる元素であり、より高耐食を具備させることを志向する場合に必要に応じて適宜含有することできる。このような効果を得るためには、0.2%以上含有することが望ましい。一方、2.0%を超える含有は、熱間加工性の低下による表面品質の劣化、ならびに溶接部の靭性の劣化を招く。よって、含有する場合は、Cuは2.0%以下とする。好ましくは0.2%以上1.5%以下である。
Cu: 2.0% or less,
Cu is an element that improves the corrosion resistance, and can be appropriately contained as required when it is intended to provide higher corrosion resistance. In order to acquire such an effect, it is desirable to contain 0.2% or more. On the other hand, if the content exceeds 2.0%, the surface quality is deteriorated due to a decrease in hot workability, and the toughness of the weld is deteriorated. Therefore, when it contains, Cu shall be 2.0% or less. Preferably they are 0.2% or more and 1.5% or less.

上記した成分以外の残部は、Feおよび不可避的不純物である。不可避的不純物として、は、製鋼工程までに混入が予想される、Mg、Ca、B等の元素が挙げられ、それぞれMg:0.0015%以下、Ca:0.0020%以下、B:0.0020%以下が許容される。   The balance other than the above components is Fe and inevitable impurities. Inevitable impurities include elements such as Mg, Ca, and B that are expected to be mixed before the steelmaking process, and Mg: 0.0015% or less, Ca: 0.0020% or less, and B: 0.0020% or less are allowed. The

次に、本発明にとって重要な要件の一つである鋼の組織の限定理由について説明する。
本発明のCr含有合金熱延鋼板は、上記した組成に加えて、体積分率で、フェライト相:50%以上、マルテンサイト相:50%未満の組織を有する。
Next, the reason for limiting the steel structure, which is one of the important requirements for the present invention, will be described.
In addition to the composition described above, the Cr-containing alloy hot-rolled steel sheet of the present invention has a structure with a volume fraction of ferrite phase: 50% or more and martensite phase: less than 50%.

フェライト相は加工性を向上させる相であり、所望の加工性を確保するために、本発明では体積分率で50%以上の含有を必要とする。好ましくは60%以上である。   The ferrite phase is a phase that improves workability, and in order to ensure the desired workability, the present invention needs to contain 50% or more by volume fraction. Preferably it is 60% or more.

また、第2相は、強度上昇および伸びフランジ性の向上を目的とし、マルテンサイト相を体積分率で50%未満とする。第2相であるマルテンサイト相を50%を越えて含有すると、強度が高くなりすぎ、同時に延性、加工性が低下する。好ましくは40%未満である。また、上述の通り、マルテンサイト相はフェライト相と比較して硬質であるが、塑性異方性が小さいため、均一変形を促進させ、伸びフランジ性を向上させる相である。よって、本発明では、マルテンサイト相を体積分率で3%以上含有することが望ましい。   The second phase is intended to increase strength and improve stretch flangeability, and the martensite phase should be less than 50% in volume fraction. If the martensite phase that is the second phase exceeds 50%, the strength becomes too high, and at the same time, ductility and workability deteriorate. Preferably it is less than 40%. In addition, as described above, the martensite phase is harder than the ferrite phase, but since the plastic anisotropy is small, it is a phase that promotes uniform deformation and improves stretch flangeability. Therefore, in the present invention, it is desirable to contain the martensite phase in a volume fraction of 3% or more.

上記以外の残部組織は、特に限定しない。例えば、炭窒化物、りん化物、脱酸生成物等を含むことができる。   The remaining structure other than the above is not particularly limited. For example, carbonitrides, phosphides, deoxidation products and the like can be included.

次に、本発明の高強度かつ加工性に優れたCr含有合金熱延鋼板の製造方法について説明する。   Next, the method for producing a Cr-containing alloy hot-rolled steel sheet having high strength and excellent workability according to the present invention will be described.

本発明のCr含有合金熱延鋼板は、上記した組成を有する鋼素材に熱間圧延を施し熱延板とした後、該熱延板に焼鈍を施すことにより得られる。この時、前記熱間圧延を、仕上げ圧延終了温度:800〜1000℃、巻取り温度:900℃以下で行い、前記熱延板焼鈍を、焼鈍温度:600〜900℃で行うこととする。   The Cr-containing alloy hot-rolled steel sheet of the present invention is obtained by subjecting a steel material having the above composition to hot rolling to obtain a hot-rolled sheet, and then annealing the hot-rolled sheet. At this time, the hot rolling is performed at a finish rolling finish temperature of 800 to 1000 ° C. and a winding temperature of 900 ° C. or less, and the hot rolled sheet annealing is performed at an annealing temperature of 600 to 900 ° C.

例えば、上記した組成を有する鋼素材に加熱処理を施し、次いで、粗圧延と仕上げ圧延(仕上げ圧延終了温度:800〜1000℃、巻取り温度:900℃以下)とからなる熱間圧延により熱延板とした後、該熱延板に焼鈍(焼鈍温度:600〜900℃)を施して製造される。   For example, the steel material having the above composition is subjected to heat treatment, and then hot-rolled by hot rolling including rough rolling and finish rolling (finish rolling finishing temperature: 800 to 1000 ° C., winding temperature: 900 ° C. or less). After making into a plate, it is manufactured by subjecting the hot-rolled plate to annealing (annealing temperature: 600 to 900 ° C.).

まず、上記した組成を有する溶鋼を、例えば、転炉、電気炉等の通常公知の溶製方法により溶製し、造塊-分塊圧延法あるいは連続鋳造法でスラブ等の鋼素材とする。   First, the molten steel having the above-described composition is melted by a generally known melting method such as a converter or an electric furnace, and is made into a steel material such as a slab by an ingot-bundling rolling method or a continuous casting method.

鋼素材に対して加熱処理を行う場合の加熱温度については、本発明では特に限定しないが、1050℃以上とするのが好ましい。加熱温度が1050℃未満では、所望の仕上げ圧延終了温度を確保できなくなるとともに、鋼帯表面温度の低下による割れ、ロール疵等により表面品質が劣化する場合がある。   The heating temperature when the heat treatment is performed on the steel material is not particularly limited in the present invention, but is preferably 1050 ° C. or higher. When the heating temperature is less than 1050 ° C., the desired finish rolling end temperature cannot be secured, and the surface quality may be deteriorated due to cracks, roll wrinkles, etc. due to a decrease in the steel strip surface temperature.

鋼素材は加熱後、粗圧延により所望厚さのシートバーとされることが好ましい。そして、シートバーは粗圧延まま、あるいは必要に応じて加熱または温度保定処理を施したのち、仕上げ圧延を施し、熱延板とするのが好ましい。   The steel material is preferably heated to a sheet bar having a desired thickness by rough rolling. The sheet bar is preferably subjected to rough rolling or, if necessary, subjected to heating or temperature holding treatment, and then subjected to finish rolling to form a hot-rolled sheet.

仕上げ圧延終了温度(FDT)は、表面品質の劣化防止および粗大組織形成の抑制という観点から、800〜1000℃とする。なお、上記した仕上げ圧延終了温度を確保し、かつ加工性を向上さるためには、仕上げ圧延前にシートバー加熱、あるいはシートバーの保熱処理や、シートバーを複数本数接合して圧延するなどの連続圧延をすることが有効である。   The finish rolling finish temperature (FDT) is set to 800 to 1000 ° C. from the viewpoint of preventing the deterioration of the surface quality and suppressing the formation of a coarse structure. In addition, in order to ensure the above finish rolling finish temperature and improve the workability, the sheet bar is heated before the finish rolling, or the heat treatment of the sheet bar, or a plurality of sheet bars are joined and rolled. It is effective to perform continuous rolling.

巻取り温度は、900℃以下とする。巻取り温度が900℃を越えて高くなると、バンド状組織が形成され、熱延鋼板の加工性が低下する。なお、好ましくは加工性の観点から750℃以下である。   The coiling temperature is 900 ° C or lower. When the coiling temperature is higher than 900 ° C., a band-like structure is formed and the workability of the hot rolled steel sheet is lowered. The temperature is preferably 750 ° C. or lower from the viewpoint of workability.

熱間圧延終了後、熱延板に焼鈍を施す。この場合の加熱温度は、600〜900℃とする。600℃未満では加工性が低下し、900℃超えでは軟質化し強度が低下する。また、この場合の焼鈍は、連続焼鈍であってもバッチ焼鈍であってもどちらでもよい。   After the hot rolling is finished, the hot rolled sheet is annealed. In this case, the heating temperature is 600 to 900 ° C. If it is less than 600 ° C, the workability is lowered, and if it is more than 900 ° C, it becomes soft and the strength is lowered. Further, the annealing in this case may be either continuous annealing or batch annealing.

その後、必要に応じてショットブラスト処理を行った後、スケール除去のため酸洗処理をし、また必要に応じてスキンパス圧延による平滑化処理を行っても良い。   Then, after performing shot blasting as necessary, pickling may be performed for scale removal, and smoothing by skin pass rolling may be performed as necessary.

また、本発明のCr含有熱延鋼板の表面に、ZnやAl等の種々の金属粉と顔料からなる犠牲防食塗料を塗布し、更なる高耐食化を図ることも使用上何ら問題はない。   In addition, there is no problem in use in applying a sacrificial anticorrosive coating composed of various metal powders such as Zn and Al and pigments to the surface of the Cr-containing hot rolled steel sheet of the present invention to further increase the corrosion resistance.

なお、上述したところは、この発明形態の一例を示したのみであり、請求の範囲において種々の変更を加えることができる。   The above description is only an example of the present invention, and various modifications can be made within the scope of the claims.

表1に示す化学組成を有する鋼を転炉にて溶製し、連続鋳造法により鋼素材(スラブ)とした。これらスラブに、加熱温度1170℃とする加熱処理を施したのち、表2に示す粗圧延と仕上げ圧延とからなる熱間圧延を施し、2.5mm厚の熱延板とした。次いで、得られた熱延板に対して、表2に示す温度で10h保持後徐冷する熱延板焼鈍を施した。次いで、ショットブラスト、酸洗処理により表面スケールを除去した。その後、1%程度のスキンパス圧延を行い、2.5mm厚の熱延焼鈍板とした。   Steel having the chemical composition shown in Table 1 was melted in a converter and used as a steel material (slab) by a continuous casting method. These slabs were subjected to heat treatment at a heating temperature of 1170 ° C., and then subjected to hot rolling consisting of rough rolling and finish rolling shown in Table 2 to obtain 2.5 mm thick hot rolled sheets. Next, the obtained hot-rolled sheet was subjected to hot-rolled sheet annealing that was held for 10 hours at the temperature shown in Table 2 and then gradually cooled. Subsequently, the surface scale was removed by shot blasting and pickling treatment. Then, about 1% skin pass rolling was performed to obtain a 2.5 mm thick hot-rolled annealed sheet.

得られた熱延焼鈍板から各種試験片を採取し、組織観察、引張特性、伸びフランジ性を調査した。試験方法は次の通りである。
(1)組織観察
得られた熱延焼鈍板から組織観察用試験片を採取し、これら試験片を研磨したのち、腐食液:村上試薬を用いてエッチングし、鋼板の圧延方向の板厚方向中央部について光学顕微鏡および走査型電子顕微鏡(100、400倍)で観察し、30視野撮影して、各視野についてそれぞれ、画像解析装置を用いて、フェライト相の組織分率を求め、各視野の平均値を算出し、各試験片の組織分率とした。なお、粒内に炭窒化物を含むフェライト相が観察された場合は、粒内の炭窒化物はフェライト相に含まれるものとした。また、フェライト相とその他の相との区別を明確にするために、EPMA(電子線マイクロアナリシス)による測定を行った。EPMA分析は、Cr、Si、Mn、Ni(あるいはCu)のカラ−マッピングを鋼板の圧延方向の板厚方向中央部について、倍率×500、加速電圧15kVで行った。この際、Cr、Siが凝縮している組織をフェライト相とし、Mn、Ni(あるいはCu)が濃縮している組織をマルテンサイト相とした。
(2)引張特性
得られた熱延焼鈍板より、JIS Z 2201に準拠した13号B試験片を圧延方向と垂直な方向から採取し、JIS Z 2241に準拠して引張試験を実施し、引張強さTSと破断伸びElを測定した。
(3)伸びフランジ性
伸びフランジ性は熱延焼鈍板より試験片(大きさ:2.5mm×100mm×100mm)試料にクリアランス13%で10mmΦの初期穴d0を打ち抜き加工し、この穴に頂角60°の円錐ポンチを打ち抜きバリが出た面と反対の面側から加圧装入し、打ち抜き端面に板厚を貫通する割れが生じた時点での穴径dを測定した。これらの値から、次式
λ(%)=(d-d0)/d0×100
で定義される穴拡げ率λを求め、伸びフランジ性を評価した。
Various test pieces were collected from the obtained hot-rolled annealed plate and examined for structure observation, tensile characteristics, and stretch flangeability. The test method is as follows.
(1) Microstructure observation Sample specimens for microstructural observation were collected from the obtained hot-rolled annealed plates, and after polishing these specimens, etching was performed using a corrosive solution: Murakami reagent, and the thickness direction center in the rolling direction of the steel sheet. Observed with an optical microscope and scanning electron microscope (100, 400 times), photographed 30 fields of view, and obtained the structure fraction of the ferrite phase for each field of view using an image analyzer. The value was calculated and used as the tissue fraction of each test piece. In addition, when the ferrite phase containing a carbonitride was observed in a grain, the carbonitride in a grain shall be contained in a ferrite phase. In addition, in order to clarify the distinction between the ferrite phase and other phases, measurement was performed by EPMA (electron beam microanalysis). In the EPMA analysis, color mapping of Cr, Si, Mn, Ni (or Cu) was performed at a magnification of 500 and an acceleration voltage of 15 kV at the central portion in the plate thickness direction in the rolling direction of the steel plate. At this time, the structure in which Cr and Si are condensed is defined as a ferrite phase, and the structure in which Mn and Ni (or Cu) is concentrated is defined as a martensite phase.
(2) Tensile properties From the obtained hot-rolled annealed sheet, a No. 13 B test piece based on JIS Z 2201 was taken from the direction perpendicular to the rolling direction, and a tensile test was carried out based on JIS Z 2241. The strength TS and elongation at break El were measured.
(3) stretch flangeability stretch flangeability specimens than hot-rolled annealed sheets (size: 2.5mm × 100mm × 100mm) and punching out the initial hole d 0 of 10mmΦ 13% clearance in the sample, the apex angle in the hole A 60 ° conical punch was press-fitted from the side opposite to the surface where the burrs appeared, and the hole diameter d was measured when a crack penetrating the plate thickness occurred on the punched end surface. From these values,
λ (%) = (dd 0 ) / d 0 × 100
The hole expansion ratio λ defined in (1) was obtained, and the stretch flangeability was evaluated.

得られた結果を表3に示す。   The results obtained are shown in Table 3.

Figure 2006249514
Figure 2006249514

Figure 2006249514
Figure 2006249514

Figure 2006249514
Figure 2006249514

表3より、本発明例はいずれも、引張り強さTSが600MPa以上の高強度を有し、かつ、16%以上の伸びElと80%以上の穴拡げ率λを示し、高強度で、延性及び伸びフランジ性に優れた熱延鋼板となっているのがわかる。   From Table 3, all of the inventive examples have a high strength with a tensile strength TS of 600 MPa or more, an elongation El of 16% or more, and a hole expansion ratio λ of 80% or more. And it turns out that it is a hot-rolled steel plate excellent in stretch flangeability.

一方、比較例では、強度、延性、伸びフランジ性のいずれか一つ以上の特性が劣っている。   On the other hand, the comparative example is inferior in any one or more of strength, ductility, and stretch flangeability.

本発明のCr含有合金熱延鋼板は、電気電子機器部品や自動車部品以外の高強度及び優れた加工性が必要とされる分野にも好適である。   The Cr-containing alloy hot-rolled steel sheet of the present invention is also suitable for fields requiring high strength and excellent workability other than electrical and electronic equipment parts and automobile parts.

Claims (4)

mass%で、C:0.003%以上0.03%以下、N:0.003%以上0.02%以下、Si:1.0%越え3.0%以下、Mn:1.0%越え3.0%以下、P:0.05%以下、S:0.01%以下、Cr:11%以上18%以下、Ni: 1.0%越え3.0%以下、V:0.005%以上0.030%未満、Al: 0.05%以下、O:0.0050%以下を含有し、残部がFeおよび不可避的不純物からなり、金属組織として、体積分率で、フェライト相:50%以上、マルテンサイト相:50%未満の組織を有することを特徴とする引張強さ600MPa以上である高強度かつ加工性に優れたCr含有合金熱延鋼板。   In mass%, C: 0.003% to 0.03%, N: 0.003% to 0.02%, Si: 1.0% to 3.0%, Mn: 1.0% to 3.0%, P: 0.05%, S: 0.01% Contains Cr: 11% to 18%, Ni: 1.0% to 3.0%, V: 0.005% to less than 0.030%, Al: 0.05% or less, O: 0.0050% or less, the balance being Fe and inevitable It consists of impurities, and has a metal structure with a volume fraction of ferrite phase: 50% or more and martensite phase: less than 50%. It has a tensile strength of 600 MPa or more and excellent workability. Cr-containing alloy hot-rolled steel sheet. さらに、mass%で、Ti:0.05%以上0.3%以下、Nb:0.05%以上0.3%以下、Zr:0.05%以上0.3%以下のうちから選ばれた1種または2種以上を含有することを特徴とする請求項1に記載の引張強さ600MPa以上である高強度かつ加工性に優れたCr含有合金熱延鋼板。   Furthermore, it is characterized by containing at least one selected from mass: Ti: 0.05% to 0.3%, Nb: 0.05% to 0.3%, Zr: 0.05% to 0.3%. The Cr-containing alloy hot-rolled steel sheet having high tensile strength and excellent workability, having a tensile strength of 600 MPa or more. さらに、mass%で、Cu:2.0%以下を含有することを特徴とする請求項1または2に記載の引張強さ600MPa以上である高強度かつ加工性に優れたCr含有合金熱延鋼板。   The Cr-containing alloy hot-rolled steel sheet having high tensile strength and excellent workability, having a tensile strength of 600 MPa or more, according to claim 1 or 2, further comprising Cu: 2.0% or less in mass%. Crを含有する鋼素材に熱間圧延を施し熱延板とした後、該熱延板に焼鈍を施しCr含有合金熱延鋼板を製造するに際し、前記鋼素材を、請求項1〜3のいずれかに記載の組成を有する鋼素材とし、
前記熱間圧延を、仕上げ圧延終了温度を800〜1000℃、巻取り温度を900℃以下で行い、
前記熱延板焼鈍を、焼鈍温度を600〜900℃で行う
ことを特徴とする引張強さ600MPa以上である高強度かつ加工性に優れたCr含有合金熱延鋼板の製造方法。
After hot-rolling a steel material containing Cr to form a hot-rolled sheet, the hot-rolled sheet is annealed to produce a Cr-containing alloy hot-rolled steel sheet. A steel material having the composition of crab,
The hot rolling is performed at a finish rolling end temperature of 800 to 1000 ° C. and a winding temperature of 900 ° C. or less,
A method for producing a Cr-containing alloy hot-rolled steel sheet having a high strength and excellent workability with a tensile strength of 600 MPa or more, wherein the hot-rolled sheet annealing is performed at an annealing temperature of 600 to 900 ° C.
JP2005068330A 2005-03-11 2005-03-11 HOT-ROLLED STEEL PLATE OF Cr-CONTAINING ALLOY HAVING HIGH STRENGTH AND SUPERIOR WORKABILITY, AND MANUFACTURING METHOD THEREFOR Pending JP2006249514A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005068330A JP2006249514A (en) 2005-03-11 2005-03-11 HOT-ROLLED STEEL PLATE OF Cr-CONTAINING ALLOY HAVING HIGH STRENGTH AND SUPERIOR WORKABILITY, AND MANUFACTURING METHOD THEREFOR

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005068330A JP2006249514A (en) 2005-03-11 2005-03-11 HOT-ROLLED STEEL PLATE OF Cr-CONTAINING ALLOY HAVING HIGH STRENGTH AND SUPERIOR WORKABILITY, AND MANUFACTURING METHOD THEREFOR

Publications (1)

Publication Number Publication Date
JP2006249514A true JP2006249514A (en) 2006-09-21

Family

ID=37090311

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005068330A Pending JP2006249514A (en) 2005-03-11 2005-03-11 HOT-ROLLED STEEL PLATE OF Cr-CONTAINING ALLOY HAVING HIGH STRENGTH AND SUPERIOR WORKABILITY, AND MANUFACTURING METHOD THEREFOR

Country Status (1)

Country Link
JP (1) JP2006249514A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012133833A1 (en) * 2011-03-31 2012-10-04 日新製鋼株式会社 Stainless-steel sheet for metal mask
JP2014189862A (en) * 2013-03-28 2014-10-06 Jfe Steel Corp Stainless steel sheet for structure and manufacturing method therefor
WO2015064128A1 (en) * 2013-10-31 2015-05-07 Jfeスチール株式会社 Ferrite-martensite two-phase stainless steel exhibiting low-temperature toughness, and method for producing same

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012133833A1 (en) * 2011-03-31 2012-10-04 日新製鋼株式会社 Stainless-steel sheet for metal mask
CN103476958A (en) * 2011-03-31 2013-12-25 日新制钢株式会社 Stainless-steel sheet for metal mask
JP2014080688A (en) * 2011-03-31 2014-05-08 Nisshin Steel Co Ltd Stainless steel plate for metal mask and metal mask
JP2014189862A (en) * 2013-03-28 2014-10-06 Jfe Steel Corp Stainless steel sheet for structure and manufacturing method therefor
WO2015064128A1 (en) * 2013-10-31 2015-05-07 Jfeスチール株式会社 Ferrite-martensite two-phase stainless steel exhibiting low-temperature toughness, and method for producing same
EP3029170A4 (en) * 2013-10-31 2016-10-05 Jfe Steel Corp Ferrite-martensite two-phase stainless steel, and method for producing same
US10745774B2 (en) 2013-10-31 2020-08-18 Jfe Steel Corporation Ferrite-martensite dual-phase stainless steel and method of manufacturing the same

Similar Documents

Publication Publication Date Title
KR101617505B1 (en) Steel sheet for hot stamping members and method for producing same
JP5888476B2 (en) Material for stainless cold-rolled steel sheet and manufacturing method thereof
JP5396752B2 (en) Ferritic stainless steel with excellent toughness and method for producing the same
CN109642286B (en) Ferritic stainless steel hot-rolled annealed steel sheet and method for producing same
EP2578718A1 (en) High-strength molten-zinc-plated steel sheet having excellent bendability and weldability, and process for production thereof
KR20140116936A (en) Hot-dip galvanized steel sheet and production method therefor
JP5987996B2 (en) Ferritic stainless steel and manufacturing method thereof
JP2010059452A (en) Cold-rolled steel sheet and producing method therefor
WO2001083839A1 (en) High tensile cold-rolled steel sheet excellent in ductility and in strain aging hardening properties, and method for producing the same
WO2017169870A1 (en) Thin steel plate and plated steel plate, hot rolled steel plate manufacturing method, cold rolled full hard steel plate manufacturing method, heat-treated plate manufacturing method, thin steel plate manufacturing method and plated steel plate manufacturing method
JP6265108B2 (en) Hot-rolled steel sheet for cold-rolled steel sheet or hot-dip galvanized steel sheet and method for producing the same
KR101850231B1 (en) Ferritic stainless steel and method for producing same
KR101606946B1 (en) High-strength stainless steel material and process for production of the same
TW201435096A (en) Ferritic stainless steel sheet
KR20220005572A (en) Cold-rolled martensitic steel sheet and manufacturing method thereof
WO2014147655A1 (en) Ferritic stainless steel sheet
WO2016113781A1 (en) High-strength steel sheet and production method therefor
JPWO2018199062A1 (en) Ferritic stainless hot rolled annealed steel sheet and method for producing the same
JP2023182698A (en) Hot rolled steel and manufacturing method thereof
JP5483916B2 (en) High-strength galvannealed steel sheet with excellent bendability
JP4513552B2 (en) High-tensile hot-rolled steel sheet excellent in bake hardenability and room temperature aging resistance and method for producing the same
JP5073966B2 (en) Age-hardening ferritic stainless steel sheet and age-treated steel using the same
EP3978643A2 (en) Austenitic stainless steel having improved strength, and method for manufacturing same
JP2016113670A (en) Ferritic stainless steel and method for producing the same
JP4606113B2 (en) Austenitic stainless steel with high proportional limit stress and manufacturing method

Legal Events

Date Code Title Description
RD01 Notification of change of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7421

Effective date: 20060921