JP2006230334A - Method for producing frozen egg boiled plain and method for producing frozen processed food including egg boiled plain - Google Patents

Method for producing frozen egg boiled plain and method for producing frozen processed food including egg boiled plain Download PDF

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JP2006230334A
JP2006230334A JP2005052538A JP2005052538A JP2006230334A JP 2006230334 A JP2006230334 A JP 2006230334A JP 2005052538 A JP2005052538 A JP 2005052538A JP 2005052538 A JP2005052538 A JP 2005052538A JP 2006230334 A JP2006230334 A JP 2006230334A
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egg
frozen
saccharide
boiled
processed food
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JP4365797B2 (en
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Kano Tsuda
佳乃 津田
Yukio Sakane
幸雄 坂根
Toshihiko Hagiwara
俊彦 萩原
Masao Sawada
政男 澤田
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Nichirei Foods Inc
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Priority to PCT/JP2005/018280 priority patent/WO2006092879A1/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B5/00Preservation of eggs or egg products
    • A23B5/04Freezing; Subsequent thawing; Cooling
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L15/00Egg products; Preparation or treatment thereof

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Food Science & Technology (AREA)
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a frozen egg boiled plain prevented from or suppressed in freezing deterioration and retaining the palate feeling and shape even if freezing for a long period, and to provide a method for producing a frozen processed food including the frozen egg boiled plain. <P>SOLUTION: A method for producing the frozen egg boiled plain comprises (A) a process of preparing an egg boiled plain, (B) a process of soaking the egg boiled plain in 0-10°C saccharide-containing aqueous solution containing phosphate, trehalose and sorbitol, (C) a process of soaking the soaked egg boiled plain in 80-100°C saccharide-containing heated solution containing phosphate, trehalose and sorbitol, and (D) a process of freezing the egg boiled plain subjected to at least (A)-(C) processes. The method for producing the frozen processed food comprises (X) a process of preparing processed food retaining the form of the egg boiled plain through using the egg boiled plain subjected to at least (A)-(C) processes, and (D-1) a process of freezing the processed food. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、冷凍変性に伴う水煮卵の形態、色彩及び食感の低下を抑制又は防止可能な冷凍水煮卵の製造法及び、水煮卵の形態を保持した、冷凍串揚げ卵、冷凍中華丼の具、冷凍スコッチエッグ等の水煮卵を含む冷凍加工食品の製造法に関する。   The present invention relates to a method for producing a frozen boiled egg capable of suppressing or preventing a decrease in the form, color and texture of the boiled egg accompanying freezing denaturation, and a frozen skewered egg that retains the form of the boiled egg, frozen The present invention relates to a method for producing frozen processed foods including boiled eggs such as rice bowl and frozen scotch eggs.

近年、冷凍食品の進展に伴い、茹で卵を利用した各種冷凍加工食品や冷凍茹で卵の需要が業務用を含めて伸びている。一方、水煮卵も茹で卵と同様にその冷凍品の需要拡大が望まれている。
茹で卵や水煮卵は、そのまま急速凍結すると冷凍変性を起こし、その解凍物は、卵白部分がゴム状又はスポンジ状の硬い食感になったり、色が透明化し、更に、卵黄部分が水っぽくなるという現象が生じる。特に、水煮卵の場合、その製造法が茹で卵と異なり、ボイル、殻剥き後に、酸処理工程、塩水を用いた巻き締め工程及び加圧加熱殺菌工程を行うため、凍結前の状態でも茹で卵に比してその食感等が低下しており、冷凍変性が茹で卵に比べて顕著に生じ易い。このため、市場において冷凍水煮卵については極僅かしか流通しておらず、そのものの食感は冷凍変性が改善されているとは言い難い。
In recent years, with the progress of frozen foods, the demand for eggs in various frozen processed foods using frozen eggs and frozen eggs has increased, including for commercial use. On the other hand, boiled eggs are also expected to increase in demand for frozen products like boiled eggs.
Boiled eggs and boiled eggs undergo freezing and denaturation when rapidly frozen as they are, and the thawed product becomes hard or rubbery in the egg white part, the color becomes transparent, and the egg yolk part becomes watery This occurs. In particular, in the case of boiled eggs, the manufacturing method is different from boiled eggs, and after boiling, shelling, an acid treatment process, a tightening process using salt water and a pressure heat sterilization process are performed. The texture and the like of the egg is reduced, and freezing denaturation is more likely to occur compared to boiled eggs. For this reason, there are very few frozen boiled eggs on the market, and it is difficult to say that the texture of the frozen eggs is improved in freezing denaturation.

ところで、茹で卵の冷凍変性を抑制する方法として、例えば、特許文献1に、リン酸塩、必要によりデキストリンやデキストリンアルコールを含む水溶液中に茹で卵を浸漬する方法が開示されている。また、特許文献2には、殻を除去した茹で卵を、DE=30以上のデキストリン、トレハロース、ソルビトール等を含む40〜75℃の糖溶液に、20分〜120分間浸漬し、常温に放置した後、凍結する冷凍茹で卵の製造法が開示されている。
しかし、これらの方法は、冷凍茹で卵の場合にある程度の冷凍変性を改善しうるが、冷凍水煮卵においてはその効果がほとんど得られないのが実状である。
特開平7−135926号公報 特開2001−346507号公報
By the way, as a method for suppressing freezing denaturation of eggs by boil, for example, Patent Document 1 discloses a method of dipping eggs in an aqueous solution containing phosphate, and if necessary, dextrin or dextrin alcohol. In Patent Document 2, boiled eggs from which shells have been removed are immersed in a sugar solution at 40 to 75 ° C. containing dextrin of DE = 30 or more, trehalose, sorbitol, etc. for 20 to 120 minutes and left at room temperature. Later, a method for producing eggs with frozen frozen rice cakes is disclosed.
However, these methods can improve the degree of freezing and denaturation to some extent in the case of an egg with a frozen cocoon, but the effect is hardly obtained in a frozen boiled egg.
JP-A-7-135926 JP 2001-346507 A

従って、本発明の課題は、解凍後において、卵白部分がゴム状又はスポンジ状の硬い食感になったり、卵白部分の色が透明化したり、更に、卵黄部分が水っぽくなるという冷凍変性が防止又は抑制され、長期冷凍保存した場合にも、その食感や形態を維持しうる冷凍水煮卵の製造法を提供することにある。
本発明の別の課題は、冷凍水煮卵の冷凍変性が防止又は抑制され、長期冷凍保存した場合にもその食感や形態を維持した冷凍水煮卵を含む冷凍加工食品の製造法を提供することにある。
Therefore, the object of the present invention is to prevent the freezing denaturation that the egg white part becomes a rubbery or sponge-like hard texture after thawing, the egg white part becomes transparent, and the egg yolk part becomes watery. An object of the present invention is to provide a method for producing a frozen boiled egg that is suppressed and can maintain its texture and form even when stored frozen for a long period of time.
Another object of the present invention is to provide a method for producing a frozen processed food containing a frozen boiled egg that is prevented or suppressed from being frozen and denatured in frozen frozen boiled eggs and maintains its texture and form even when stored frozen for a long time. There is to do.

即ち、本発明によれば、水煮卵を準備する工程(A)、水煮卵を、リン酸塩とトレハロースとソルビトールとを含む0〜10℃の糖類含有水溶液に浸漬する工程(B)、工程(B)で調製した浸漬水煮卵を、リン酸塩とトレハロースとソルビトールとを含む80〜100℃の糖類含有加熱溶液に浸漬する工程(C)、及び少なくとも前記工程(A)〜(C)を行った後の水煮卵を凍結する工程(D)を含むことを特徴とする冷凍水煮卵の製造法が提供される。
また本発明によれば、上記工程(A)、工程(B)、工程(C)、少なくとも前記工程(A)〜(C)を行った後の水煮卵を用いて、該水煮卵の形態を保持した加工食品を調製する工程(X)、及び工程(X)で調製した加工食品を凍結する工程(D-1)を含むことを特徴とする水煮卵を含む冷凍加工食品の製造法が提供される。
That is, according to the present invention, a step (A) of preparing a boiled egg, a step (B) of immersing the boiled egg in a 0-10 ° C. saccharide-containing aqueous solution containing phosphate, trehalose and sorbitol, Step (C) of immersing the soaked soaked egg prepared in step (B) in a saccharide-containing heated solution at 80 to 100 ° C. containing phosphate, trehalose and sorbitol, and at least the steps (A) to (C The method for producing frozen boiled eggs is provided, which includes the step (D) of freezing the boiled eggs after performing (1).
Moreover, according to the present invention, using the boiled egg after performing the above steps (A), (B), (C), at least the steps (A) to (C), Production of frozen processed foods including boiled eggs, characterized in that it comprises a step (X) of preparing a processed food retaining its form and a step (D-1) of freezing the processed food prepared in step (X) Law is provided.

本発明の冷凍水煮卵の製造法は、上記工程(A)〜(D)を含み、特に、工程(B)及び(C)を含むので、得られる冷凍水煮卵は、冷凍変性が防止又は抑制され、長期冷凍保存した場合にもその食感や形態を維持しうる。従って、得られる冷凍水煮卵は、従来の常温タイプ又はチルドタイプの水煮卵に代わっての需要が期待できる。
また、本発明の冷凍加工食品の製造法は、上記工程(A)〜(C)、(X)及び(D-1)を含み、特に工程(B)、(C)及び(X)を含むので、得られる冷凍加工食品中の冷凍水煮卵は、冷凍変性が防止又は抑制され、長期冷凍保存した場合にもその食感や形態を維持しうる。従って、得られる冷凍水煮卵を含む冷凍加工食品は、従来品より食感及び見た目に優れ、冷凍串揚げ卵、冷凍中華丼の具、冷凍スコッチエッグ等の水煮卵を含む冷凍加工食品を提供することができる。
The method for producing a frozen boiled egg of the present invention includes the above steps (A) to (D), and particularly includes the steps (B) and (C). Or even if it is suppressed and stored frozen for a long time, its texture and form can be maintained. Therefore, the demand for the frozen boiled eggs obtained can be expected in place of conventional room temperature type or chilled type boiled eggs.
Further, the method for producing a frozen processed food of the present invention includes the above steps (A) to (C), (X) and (D-1), particularly including steps (B), (C) and (X). Therefore, the frozen boiled egg in the obtained frozen processed food is prevented or suppressed from being frozen and denatured, and can maintain its texture and form even when stored frozen for a long time. Therefore, the frozen processed food containing the frozen boiled egg obtained is better in texture and appearance than the conventional product, and the frozen processed food containing the boiled egg such as frozen skewered egg, frozen Chinese rice bowl, frozen scotch egg, etc. Can be provided.

以下、本発明を更に詳細に説明する。
本発明の冷凍水煮卵又は冷凍加工食品の製造法(以下、本発明の製造法と略す)は、水煮卵を準備する工程(A)を含む。
水煮卵としては、鶏卵又はうずらの卵等の常温タイプ又はチルドタイプの市販の水煮卵を用いることができる他、公知の方法等に準じて調製した水煮卵を用いることができる。
水煮卵の調製法としては、例えば、卵をボイル後、殻剥きし、クエン酸溶液等で酸処理する。次いで、薄皮取り、選別、計量後、0.4〜0.7質量%塩水等を用いて巻き締めし、加圧加熱殺菌する方法等が挙げられる。この際、加圧加熱殺菌条件を調整することにより、水煮卵を常温タイプ又はチルドタイプとすることができる。
ここで、常温タイプとは、115℃、30分間程度の加圧加熱殺菌処理を行なったもので、常温又は冷所に保管し、チルドタイプより長い約1〜2年間の賞味期限を有するものを意味する。一方、チルドタイプとは、常温タイプより弱い殺菌条件での加熱処理を行なったもので、殺菌条件としては、95℃、30分間程度の加熱処理を行ったもの等であり、10℃以下のチルドの温度帯で保管し、常温タイプより短い賞味期限を有するものを意味する。
Hereinafter, the present invention will be described in more detail.
The method for producing a frozen boiled egg or frozen processed food of the present invention (hereinafter abbreviated as the production method of the present invention) includes a step (A) of preparing a boiled egg.
As boiled eggs, commercially available boiled eggs of normal temperature type or chilled type such as chicken eggs or quail eggs can be used, and boiled eggs prepared according to known methods and the like can be used.
As a method for preparing the boiled egg, for example, the egg is boiled, then the shell is peeled off, and acid treatment is performed with a citric acid solution or the like. Subsequently, after thinning, screening, and weighing, a method of wrapping with 0.4 to 0.7% by mass salt water or the like and sterilizing under pressure and heat may be used. At this time, the boiled egg can be made into a normal temperature type or a chilled type by adjusting the pressure and heat sterilization conditions.
Here, the normal temperature type is a product that has been subjected to pressure heat sterilization treatment at 115 ° C. for about 30 minutes, stored at normal temperature or in a cold place, and has a shelf life of about 1 to 2 years longer than the chilled type. means. On the other hand, the chilled type is one that has been subjected to heat treatment under weaker sterilization conditions than the room temperature type, and the sterilization condition is one that has been subjected to heat treatment at 95 ° C. for about 30 minutes, etc. Means a product having a shelf life shorter than that of the normal temperature type.

本発明の製造法は、工程(A)で準備した水煮卵を、リン酸塩とトレハロースとソルビトールとを含む特定温度の糖類含有水溶液に浸漬する工程(B)と、該工程(B)で調製した浸漬水煮卵を、リン酸塩とトレハロースとソルビトールとを含む特定温度の糖類含有加熱溶液に浸漬する工程(C)とを含む。工程(B)又は工程(C)の一方を行わない場合には、冷凍変性を抑制する効果が、特に常温タイプの水煮卵に対して十分でない。   The production method of the present invention includes a step (B) of immersing the boiled egg prepared in step (A) in a saccharide-containing aqueous solution having a specific temperature containing phosphate, trehalose and sorbitol, and the step (B). A step (C) of immersing the prepared immersed boiled egg in a saccharide-containing heated solution at a specific temperature containing phosphate, trehalose and sorbitol. When one of the step (B) or the step (C) is not performed, the effect of suppressing freezing denaturation is not sufficient particularly for a normal temperature type boiled egg.

工程(B)又は工程(C)に用いるリン酸塩は、水煮卵の保水性を維持し、冷凍変性による、卵白部分の弾力性低下、並びに卵黄が水っぽくなることを抑制、防止する成分であって、例えば、リン酸一ナトリウム、リン酸一カリウム、リン酸二ナトリウム、リン酸二カリウム、リン酸三ナトリウム、リン酸三カリウム、ピロリン酸ナトリウム、ピロリン酸カリウム、ポリリン酸ナトリウム、ポリリン酸カリウム又はこれらの2種以上の混合物等が挙げられる。
工程(B)に用いる糖類含有水溶液においてリン酸塩の濃度は、0.2〜3質量%が好ましく、0.5〜2質量%が特に好ましい。リン酸塩の濃度が0.2質量%未満では、所望の効果が得られない恐れがあり、3質量%を超えると所望の効果がそれ以上向上せず、逆にリン酸塩による異味等が生じる恐れがある。
工程(C)に用いる糖類含有加熱溶液においてリン酸塩の濃度は、0.2〜3質量%が好ましく、0.5〜2質量%が特に好ましい。リン酸塩の濃度が0.2質量%未満では、所望の効果が得られない恐れがあり、3質量%を超えると所望の効果がそれ以上向上せず、逆にリン酸塩による異味等が生じる恐れがある。
Phosphate used in step (B) or step (C) is a component that maintains the water retention of boiled eggs and suppresses and prevents the egg white portion from becoming less elastic due to freezing and denaturation, and the yolk becoming watery. For example, monosodium phosphate, monopotassium phosphate, disodium phosphate, dipotassium phosphate, trisodium phosphate, tripotassium phosphate, sodium pyrophosphate, potassium pyrophosphate, sodium polyphosphate, potassium polyphosphate Or the mixture of these 2 or more types is mentioned.
In the saccharide-containing aqueous solution used in the step (B), the concentration of phosphate is preferably 0.2 to 3% by mass, and particularly preferably 0.5 to 2% by mass. If the phosphate concentration is less than 0.2% by mass, the desired effect may not be obtained. If the phosphate concentration exceeds 3% by mass, the desired effect will not be further improved. May occur.
In the saccharide-containing heated solution used in step (C), the concentration of phosphate is preferably 0.2 to 3% by mass, and particularly preferably 0.5 to 2% by mass. If the phosphate concentration is less than 0.2% by mass, the desired effect may not be obtained. If the phosphate concentration exceeds 3% by mass, the desired effect will not be further improved. May occur.

工程(B)又は工程(C)に用いるトレハロースは、後述するソルビトールと共に、解凍後の卵白の透明化を抑制し、前述のリン酸塩と共に、卵白及び卵黄の食感を向上させることを可能にする成分である。
工程(B)に用いる糖類含有水溶液においてトレハロースの濃度は、5〜30質量%が好ましく、10〜25質量%が特に好ましい。トレハロースの濃度が5質量%未満では、所望の効果が得られない恐れがあり、30質量%を超えると所望の効果がそれ以上向上せず、逆に甘味等が著しく強調される恐れがある。
工程(C)に用いる糖類含有加熱溶液においてトレハロースの濃度は、5〜30質量%が好ましく、10〜25質量%が特に好ましい。トレハロースの濃度が5質量%未満では、所望の効果が得られない恐れがあり、30質量%を超えると所望の効果がそれ以上向上せず、逆に甘味が著しく強調される恐れがある。
Trehalose used in step (B) or step (C), together with sorbitol described later, suppresses the clarification of egg white after thawing, and together with the aforementioned phosphate, it is possible to improve the texture of egg white and egg yolk. It is an ingredient to do.
In the saccharide-containing aqueous solution used in the step (B), the concentration of trehalose is preferably 5 to 30% by mass, particularly preferably 10 to 25% by mass. If the concentration of trehalose is less than 5% by mass, the desired effect may not be obtained, and if it exceeds 30% by mass, the desired effect will not be further improved, and conversely, sweetness and the like may be significantly emphasized.
In the saccharide-containing heated solution used in the step (C), the trehalose concentration is preferably 5 to 30% by mass, particularly preferably 10 to 25% by mass. If the concentration of trehalose is less than 5% by mass, the desired effect may not be obtained, and if it exceeds 30% by mass, the desired effect is not further improved, and conversely, sweetness may be significantly emphasized.

工程(B)又は工程(C)に用いるソルビトールは、前述のトレハロースと共に、解凍後の卵白の透明化を抑制し、前述のリン酸塩と共に、卵白及び卵黄の食感を向上させることを可能にする成分である。
工程(B)に用いる糖類含有水溶液においてソルビトールの濃度は、5〜30質量%が好ましく、10〜25質量%が特に好ましい。ソルビトールの濃度が5質量%未満では、所望の効果が得られない恐れがあり、30質量%を超えると所望の効果がそれ以上向上せず、逆に甘味等が著しく強調される恐れがある。
工程(C)に用いる糖類含有加熱溶液においてソルビトールの濃度は、5〜30質量%が好ましく、10〜25質量%が特に好ましい。ソルビトールの濃度が5質量%未満では、所望の効果が得られない恐れがあり、30質量%を超えると所望の効果がそれ以上向上せず、逆に甘味が著しく強調される恐れがある。
Sorbitol used in step (B) or step (C), together with the above-mentioned trehalose, can suppress the clarification of egg white after thawing, and together with the above-mentioned phosphate, can improve the texture of egg white and egg yolk. It is an ingredient to do.
In the saccharide-containing aqueous solution used in the step (B), the concentration of sorbitol is preferably 5 to 30% by mass, particularly preferably 10 to 25% by mass. If the concentration of sorbitol is less than 5% by mass, the desired effect may not be obtained. If the concentration exceeds 30% by mass, the desired effect will not be further improved, and conversely, sweetness and the like may be significantly emphasized.
In the saccharide-containing heated solution used in the step (C), the concentration of sorbitol is preferably 5 to 30% by mass, and particularly preferably 10 to 25% by mass. If the concentration of sorbitol is less than 5% by mass, the desired effect may not be obtained. If the concentration exceeds 30% by mass, the desired effect will not be further improved, and conversely, sweetness may be significantly emphasized.

工程(B)に用いる糖類含有水溶液及び工程(C)に用いる糖類含有加熱溶液においては、上記リン酸塩、トレハロース及びソルビトールの他に、本願発明の所望の効果を損なわない範囲で適宜選択して他の成分を含有させることもできる。但し、後述する比較例に示すように、DEが40程度に高いデキストリンの使用は、工程(C)における糖類含有加熱溶液の温度が高いため、卵白部の食感が低下すると共に、卵白部が必要以上に着色するので好ましくない。従って、少なくとも工程(C)に用いる糖類含有加熱溶液においては、DE=30以上のデキストリンを含まないことが好ましい。
また、他の成分として、トレハロース及びソルビトール以外の糖類を含有させる場合には、得られる冷凍水煮卵の甘味が著しく強調されること等を抑制するために、糖類含有水溶液及び糖類含有加熱溶液中のBrix値が20〜40の範囲になるように他の糖類の含有量を調整することが好ましい。
In the saccharide-containing aqueous solution used in the step (B) and the saccharide-containing heated solution used in the step (C), in addition to the phosphate, trehalose and sorbitol, the saccharide-containing aqueous solution is appropriately selected within a range that does not impair the desired effect of the present invention. Other components can also be included. However, as shown in a comparative example described later, the use of dextrin having a DE as high as about 40 is because the temperature of the saccharide-containing heated solution in the step (C) is high, so that the texture of the egg white part is lowered and the egg white part is Since it colors more than necessary, it is not preferable. Therefore, it is preferable that at least the dextrin of DE = 30 or more is not contained in the saccharide-containing heated solution used in step (C).
In addition, when other saccharides other than trehalose and sorbitol are contained as other components, the saccharide-containing aqueous solution and the saccharide-containing heated solution are used in order to prevent the sweetness of the resulting frozen boiled egg from being significantly emphasized. It is preferable to adjust the content of the other saccharides so that the Brix value of the saccharide is in the range of 20-40.

工程(B)において、水煮卵を浸漬させる前記糖類含有水溶液の温度は、通常0〜10℃の範囲で行うことができるが、該溶液が凍結しなければ0℃未満であっても良く、また、微生物による水煮卵の劣化が生じる恐れがなければ10℃を超えていても良い。
前記糖類含有水溶液に水煮卵を浸漬させる時間は、該水溶液の濃度、水煮卵の大きさや種類等に応じて、本発明の効果が達成しうるように適宜決定でき特に限定されないが、通常10時間以上、好ましくは12〜24時間の範囲が好ましい。
In the step (B), the temperature of the saccharide-containing aqueous solution in which the boiled eggs are immersed can be usually in the range of 0 to 10 ° C, but may be less than 0 ° C if the solution does not freeze, Further, the temperature may exceed 10 ° C. if there is no fear that the boiled eggs are deteriorated by microorganisms.
The time for immersing the boiled egg in the saccharide-containing aqueous solution is not particularly limited and can be appropriately determined so that the effects of the present invention can be achieved according to the concentration of the aqueous solution, the size and type of the boiled egg, etc. The range is 10 hours or more, preferably 12 to 24 hours.

工程(C)において、工程(B)で浸漬した水煮卵を更に浸漬させる前記糖類含有加熱溶液の温度は、80〜100℃、好ましくは85〜98℃である。この温度が80℃未満の場合には、冷凍変性による食感低下の抑制効果が十分でなく、100℃を越える場合には、逆に水煮卵の食感が硬くなるとともに卵が着色する恐れがある。
前記糖類含有加熱溶液に工程(B)で浸漬した水煮卵を更に浸漬させる時間は、該加熱溶液の濃度、水煮卵の大きさや種類等に応じて、本発明の効果が達成しうるように適宜決定でき特に限定されないが、通常15〜60分間、好ましくは20〜40分間の範囲が好ましい。
In the step (C), the temperature of the heated saccharide-containing solution in which the boiled eggs immersed in the step (B) are further immersed is 80 to 100 ° C, preferably 85 to 98 ° C. When this temperature is less than 80 ° C., the effect of suppressing the decrease in texture due to freezing denaturation is not sufficient, and when it exceeds 100 ° C., the texture of boiled eggs becomes harder and the eggs may be colored. There is.
The time for further immersing the boiled egg soaked in the step (B) in the saccharide-containing heated solution is such that the effect of the present invention can be achieved depending on the concentration of the heated solution, the size and type of the boiled egg, etc. Although it can be suitably determined and is not particularly limited, it is usually in the range of 15 to 60 minutes, preferably 20 to 40 minutes.

本発明の冷凍水煮卵の製造法は、少なくとも前記工程(A)〜(C)を行った後の水煮卵を凍結する工程(D)を含む。
工程(D)の凍結を実施する水煮卵は、少なくとも前記工程(A)〜(C)を行った水煮卵であれば良く、例えば、工程(C)の後、水煮卵を10〜30℃に冷却する工程(C-1)を行った後の水煮卵に対して実施することもできる。
ここで、前記工程(C-1)において、冷却は、自然冷却、強制冷却のいずれでも良いが、通常、常温程度の放冷が好ましい。このような冷却を行うことで、工程(D)における凍結前の水煮卵を適度に乾燥させることができ、凍結期間中における卵黄部分が水っぽくなるという冷凍変性を更に抑制することが可能になるので好ましい。
工程(D)の凍結は、通常、−35℃程度で急速冷凍することにより行うことができる。
The method for producing a frozen boiled egg of the present invention includes at least a step (D) of freezing the boiled egg after performing the steps (A) to (C).
The boiled egg that performs the freezing in the step (D) may be at least a boiled egg that has been subjected to the steps (A) to (C). It can also carry out with respect to the boiled egg after performing the process (C-1) cooled to 30 degreeC.
Here, in the step (C-1), the cooling may be either natural cooling or forced cooling, but it is usually preferable to cool at room temperature. By performing such cooling, the boiled egg before freezing in the step (D) can be appropriately dried, and it becomes possible to further suppress freezing denaturation that the yolk portion becomes watery during the freezing period. Therefore, it is preferable.
The freezing in the step (D) can be usually performed by rapid freezing at about -35 ° C.

本発明の冷凍加工食品の製造法は、少なくとも前記工程(A)〜(C)を行った後の水煮卵を用いて、該水煮卵の形態を保持した加工食品を調製する工程(X)を含む。
前記少なくとも前記工程(A)〜(C)を行った後の水煮卵は、そのまま、若しくは液切り等した後に工程(X)に供することができる他、前記工程(C-1)の冷却を行った後に、工程(X)に供することもできる。
工程(X)で調製する加工食品としては、水煮卵を、その形態を保持した状態で使用する加工食品であれば特に限定されず、例えば、冷凍串揚げ卵、冷凍中華丼の具、冷凍スコッチエッグ等が挙げることができ、これらの調製方法は、公知の方法に準じて行なうことができる。この際、加工食品の調製は、最終的に加熱調理する前の状態であっても、加熱調理後の状態であっても良く、例えば、冷凍串揚げ卵の場合、水煮卵に衣付けし、油ちょうする前の状態であっても油ちょうした後の状態であっても良い。
The method for producing a frozen processed food of the present invention is a process for preparing a processed food that retains the form of the boiled egg using at least the boiled egg after the steps (A) to (C) (X )including.
The boiled egg after performing at least the steps (A) to (C) can be subjected to the step (X) as it is or after being drained, and the cooling of the step (C-1) can be performed. After performing, it can also use for process (X).
The processed food prepared in step (X) is not particularly limited as long as it is a processed food that uses boiled eggs while maintaining the form thereof, for example, frozen skewered eggs, frozen Chinese rice bowl, frozen food A scotch egg etc. can be mentioned, These preparation methods can be performed according to a well-known method. At this time, the preparation of the processed food may be in a state before finally being cooked or in a state after being cooked. For example, in the case of a frozen skewered egg, it is applied to a boiled egg. The state before oiling or after oiling may be used.

本発明の冷凍加工食品の製造法は、工程(X)で調製した加工食品を凍結する工程(D-1)を含む。
工程(D-1)の凍結は、通常、−35℃程度で急速冷凍することにより行うことができる。
The method for producing a frozen processed food of the present invention includes a step (D-1) of freezing the processed food prepared in the step (X).
Freezing in the step (D-1) can usually be performed by rapid freezing at about -35 ° C.

本発明の製造法では、上述の各工程の他に、本発明の所望の効果を損なわない範囲で、更に他の効果を得るために、追加の工程を含んでいても良い。
本発明の製造法により得られる冷凍水煮卵及び冷凍加工食品は、長期冷凍貯蔵が可能であり、加熱調理、自然解凍等することにより食することができる。
In the manufacturing method of the present invention, in addition to the above-described steps, an additional step may be included in order to obtain further effects within a range that does not impair the desired effects of the present invention.
The frozen boiled egg and frozen processed food obtained by the production method of the present invention can be stored for a long period of time and can be eaten by cooking, natural thawing, or the like.

以下、本発明を実施例及び比較例により更に詳細に説明するが、本発明はこれらに限定されない。
実施例1
市販の常温タイプ水煮うずら卵を用意した。一方、トリポリリン酸ナトリウム濃度1質量%、トレハロース濃度15質量%及びソルビトール濃度15質量%の糖類含有水溶液を調製した。この水溶液のBrix値は31%であった。
次に、得られた糖類含有水溶液を4℃に保持し、上記水煮うずら卵2kgを16時間浸漬した。尚、浸漬中4時間毎に軽く攪拌操作を行った。また、浸漬中の水溶液の温度は4℃に保持した。
得られた浸漬水煮うずら卵を、上記と同様に調製した糖類含有水溶液を85℃に加熱した糖類含有加熱溶液に移し、30分間浸漬した。この浸漬中の加熱溶液の温度は85℃に保持した。
次いで、加熱溶液に浸漬した水煮うずら卵の液切りを行い、常温で60分間放冷した。放冷後の卵の外表面温度は25℃前後であった。続いて−35℃で急速凍結して冷凍水煮うずら卵を調製した。
Hereinafter, although an example and a comparative example explain the present invention still in detail, the present invention is not limited to these.
Example 1
Commercially available room temperature type boiled quail eggs were prepared. On the other hand, a saccharide-containing aqueous solution having a sodium tripolyphosphate concentration of 1% by mass, a trehalose concentration of 15% by mass and a sorbitol concentration of 15% by mass was prepared. The Brix value of this aqueous solution was 31%.
Next, the obtained saccharide-containing aqueous solution was kept at 4 ° C., and 2 kg of the boiled quail egg was soaked for 16 hours. During the immersion, a light stirring operation was performed every 4 hours. Moreover, the temperature of the aqueous solution during immersion was kept at 4 ° C.
The soaked quail eggs soaked in water were transferred to a saccharide-containing heated solution prepared by heating the saccharide-containing aqueous solution prepared in the same manner as described above to 85 ° C. and immersed for 30 minutes. The temperature of the heated solution during the immersion was maintained at 85 ° C.
Next, the boiled quail eggs immersed in the heated solution were drained and allowed to cool at room temperature for 60 minutes. The outer surface temperature of the egg after standing to cool was around 25 ° C. Subsequently, it was snap frozen at −35 ° C. to prepare quail eggs boiled in frozen water.

得られた冷凍水煮うずら卵を、−5℃で3日間貯蔵した後、室温で自然解凍し、専門のパネルにより、外観(全体の形状(変形)等、着色)、卵白部分の食感(硬さ、弾力性)、卵黄部分の食感(水っぽさ)及び総合点の評価を行った。
尚、評価は、上記で用意した市販の常温タイプの水煮うずら卵をそのまま評価した場合を8点とし、それとの比較で行なった。従って、点数が高いほど冷凍変性が抑制されていることを意味する。また、外観の着色評価は、前記常温タイプの水煮うずら卵そのままのものと変化が無いものを「−」とし、着色があるが許容範囲であるものを「M」、着色が気になるものについては、その程度が低い方から高い方へ順に、「M1」、「M2」、「M3」とした。結果を表2に示す。
The resulting frozen water-boiled quail eggs are stored at −5 ° C. for 3 days, and then thawed naturally at room temperature. The appearance (the overall shape (deformation, etc.), coloring), egg white texture ( (Hardness, elasticity), texture of egg yolk (wateriness) and overall score were evaluated.
The evaluation was performed by comparing the commercially available room-temperature-type boiled quail eggs prepared above with 8 points. Therefore, it means that freezing denaturation is suppressed, so that a score is high. In addition, the evaluation of the appearance color is "-" for the normal temperature type boiled quail eggs as they are and "-" for those that have no change, "M" for those that are colored but within an acceptable range, For “”, “M1”, “M2”, and “M3” were assigned in order from the lowest to the highest. The results are shown in Table 2.

実施例2、3及び比較例1〜18
表1に示す糖類含有水溶液及び糖類含有加熱溶液を用いて、実施例1と同様に冷凍水煮うずら卵を調製し、同様な評価を行った。評価は、実施例1と同様な基準で行った。結果を表2に示す。
尚、糖類含有水溶液の温度と浸漬時間、糖類含有加熱溶液への浸漬時間、放冷条件及び凍結条件は、実施例1と同様とした。また、実施例3及び比較例17は、市販の常温タイプ水煮うずら卵の代わりに、市販のチルドタイプうずら卵を用いた例であり、表1において、糖類含有水溶液又は糖類含有加熱溶液の欄が「−」のものは、これら溶液への浸漬を行っていないことを意味する。更に、比較例18は、市販の常温タイプの水煮うずら卵を処理しないでそのまま凍結したものを評価した例である。
Examples 2, 3 and Comparative Examples 1-18
Using the saccharide-containing aqueous solution and saccharide-containing heating solution shown in Table 1, frozen simmered quail eggs were prepared in the same manner as in Example 1, and the same evaluation was performed. Evaluation was performed according to the same criteria as in Example 1. The results are shown in Table 2.
The temperature and immersion time of the saccharide-containing aqueous solution, the immersion time in the saccharide-containing heated solution, the cooling condition, and the freezing condition were the same as in Example 1. Moreover, Example 3 and Comparative Example 17 are examples in which a commercially available chilled type quail egg is used instead of a commercially available room temperature type water-boiled quail egg. "-" Means that the film is not immersed in these solutions. Furthermore, the comparative example 18 is the example which evaluated what was frozen as it was, without processing the commercially available normal temperature type boiled quail egg.

Figure 2006230334
Figure 2006230334

Figure 2006230334
Figure 2006230334

表2の結果から、本発明における実施例の冷凍水煮うずら卵は、比較例に比して冷凍変性抑制効果に優れることが判る。従って、各種冷凍加工食品に用いた場合であっても同様な効果が得られることが容易に予測できる。一方、比較例の結果から、本発明で規定する、工程(B)及び/又は工程(C)を行わない場合、糖類含有溶液及び糖類含有加熱溶液の組成が異なる場合には、冷凍変性抑制効果が大きく劣ることが判る。
更にまた、15質量%のDE=40のデキストリンを用い、且つ糖類含有加熱溶液の温度を、本願発明の工程(C)の範囲内の温度とした場合には、外観卵白への着色が著しいことが判る。
From the results in Table 2, it can be seen that the frozen water-boiled quail eggs of the examples in the present invention are superior in the effect of inhibiting freezing denaturation as compared with the comparative examples. Therefore, it can be easily predicted that similar effects can be obtained even when used for various frozen processed foods. On the other hand, from the result of the comparative example, when the step (B) and / or the step (C) specified in the present invention is not performed, when the composition of the saccharide-containing solution and the saccharide-containing heating solution is different, the effect of inhibiting freezing denaturation Can be seen to be greatly inferior.
Furthermore, when 15% by mass of DE = 40 dextrin is used and the temperature of the heated saccharide-containing solution is set within the range of the step (C) of the present invention, the appearance egg white is markedly colored. I understand.

Claims (5)

水煮卵を準備する工程(A)、
水煮卵を、リン酸塩とトレハロースとソルビトールとを含む0〜10℃の糖類含有水溶液に浸漬する工程(B)、
工程(B)で調製した浸漬水煮卵を、リン酸塩とトレハロースとソルビトールとを含む80〜100℃の糖類含有加熱溶液に浸漬する工程(C)、及び
少なくとも前記工程(A)〜(C)を行った後の水煮卵を凍結する工程(D)を含むことを特徴とする冷凍水煮卵の製造法。
Preparing the boiled egg (A),
(B) a step of immersing the boiled egg in a saccharide-containing aqueous solution at 0 to 10 ° C. containing phosphate, trehalose and sorbitol,
Step (C) of immersing the soaked soaked egg prepared in step (B) in a heated saccharide-containing solution at 80 to 100 ° C. containing phosphate, trehalose and sorbitol, and at least the steps (A) to (C The method for producing a frozen boiled egg, comprising the step (D) of freezing the boiled egg after performing the step (1).
工程(D)の前に、工程(C)で調製した水煮卵を10〜30℃に冷却する工程(C-1)を含む請求項1記載の製造法。   The process according to claim 1, further comprising a step (C-1) of cooling the boiled egg prepared in the step (C) to 10 to 30 ° C before the step (D). 工程(B)で用いる前記糖類含有水溶液及び工程(C)で用いる前記糖類含有加熱溶液のそれぞれにおいて、リン酸塩濃度が0.2〜3質量%、トレハロース濃度が5〜30質量%、ソルビトール濃度が5〜30質量%であることを特徴とする請求項1又は2記載の製造法。   In each of the saccharide-containing aqueous solution used in step (B) and the saccharide-containing heated solution used in step (C), the phosphate concentration is 0.2 to 3% by mass, the trehalose concentration is 5 to 30% by mass, and the sorbitol concentration. The production method according to claim 1, wherein the content is 5 to 30% by mass. 工程(B)における糖類含有水溶液への浸漬時間が10時間以上であり、工程(C)における糖類含有加熱溶液への浸漬時間が15〜60分間であることを特徴とする請求項1〜3のいずれか1項記載の製造法。   The immersion time in the saccharide-containing aqueous solution in the step (B) is 10 hours or more, and the immersion time in the saccharide-containing heating solution in the step (C) is 15 to 60 minutes. The manufacturing method of any one of Claims. 水煮卵を準備する工程(A)、
水煮卵を、リン酸塩とトレハロースとソルビトールとを含む0〜10℃の糖類含有水溶液に浸漬する工程(B)、
工程(B)で調製した浸漬水煮卵を、リン酸塩とトレハロースとソルビトールとを含む80〜100℃の糖類含有加熱溶液に浸漬する工程(C)、
少なくとも前記工程(A)〜(C)を行った後の水煮卵を用いて、該水煮卵の形態を保持した加工食品を調製する工程(X)、及び
工程(X)で調製した加工食品を凍結する工程(D-1)を含むことを特徴とする水煮卵を含む冷凍加工食品の製造法。
Preparing the boiled egg (A),
(B) a step of immersing the boiled egg in a saccharide-containing aqueous solution at 0 to 10 ° C. containing phosphate, trehalose and sorbitol,
Step (C) of immersing the soaked soaked egg prepared in step (B) in a saccharide-containing heated solution at 80 to 100 ° C. containing phosphate, trehalose and sorbitol,
Using the boiled egg after performing at least the steps (A) to (C), preparing the processed food retaining the form of the boiled egg (X), and the process prepared in the step (X) The manufacturing method of the frozen processed food containing the boiled egg characterized by including the process (D-1) which freezes food.
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