JP2006222037A - Components for vehicle - Google Patents

Components for vehicle Download PDF

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JP2006222037A
JP2006222037A JP2005036454A JP2005036454A JP2006222037A JP 2006222037 A JP2006222037 A JP 2006222037A JP 2005036454 A JP2005036454 A JP 2005036454A JP 2005036454 A JP2005036454 A JP 2005036454A JP 2006222037 A JP2006222037 A JP 2006222037A
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film
adhesion
vehicle component
synthetic resin
base material
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Hironori Shibazaki
洋範 柴崎
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Ichikoh Industries Ltd
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Ichikoh Industries Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To solve a problem that colors can not b obtained with conventional components for a vehicle. <P>SOLUTION: The component for a vehicle 1 is structured of a base material 2 of synthetic resin, a first adhesive film 3 formed on the surface of the base material 2 of the synthetic resin, a reflecting film 4 formed on the surface of the first adhesive film 3, a protective film 5 formed on the surface of the reflecting film 4, a second adhesive film 6 formed on the surface of the protective film 5, and a colored coating film 7 formed on the surface of the second adhesive film 6. As a result, the component for the vehicle 1 can have color as it has the colored coating film on the second adhesive layer 6. Further, the component for the vehicle 1 is excellent in durability since the colored coating film 7 will not be peeled off the base material 2 due to the first adhesive film 3 and the second adhesive film 6. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

この発明は、合成樹脂の基材に有色塗料を施してなる車両用部品であって、たとえば、リフレクタ、インナーパネル、エクステンション、化粧板、ハウジングなどの車両用部品に関するものである。   The present invention relates to a vehicle component obtained by applying a colored paint to a base material of a synthetic resin, and relates to a vehicle component such as a reflector, an inner panel, an extension, a decorative board, and a housing.

この種の車両用部品は、従来からある(たとえば、特許文献1)。以下、この車両用部品について説明する。なお、括弧つきの符号は、特許文献1にそれぞれ対応する。この車両用部品である反射基板(1)は、合成樹脂製の基板(2)と、前記基板(2)の表面に形成されたチタンやクロムからなる中間層(6)と、前記中間層(6)の表面に形成されたアルミニウムや銀からなる反射膜(4)と、前記反射膜(4)の表面に形成された膜厚200〜300nmのプラズマ重合膜の保護膜(5)と、から構成されているものである。この車両用部品は、量産性がよく、製造コストを安価にすることができる。また、この車両用部品は、前記保護膜(5)にスモーク色を付加すれば、スモーク色が得られる。   Conventionally, this type of vehicle component is known (for example, Patent Document 1). Hereinafter, the vehicle component will be described. In addition, the code | symbol with a parenthesis respond | corresponds to patent document 1, respectively. The reflective substrate (1), which is a vehicle component, includes a synthetic resin substrate (2), an intermediate layer (6) made of titanium or chromium formed on the surface of the substrate (2), and the intermediate layer ( A reflective film (4) made of aluminum or silver formed on the surface of 6) and a protective film (5) of a plasma polymerized film having a thickness of 200 to 300 nm formed on the surface of the reflective film (4). It is configured. This vehicle component has good mass productivity and can be manufactured at low cost. Moreover, this vehicle component can obtain a smoke color by adding a smoke color to the protective film (5).

特開2001−133613号公報JP 2001-133613 A

この発明は、前記の車両用部品の改良にかかるものであって、この発明が解決しようとする問題点は、従来の車両用部品では有色が得られない点にある。   The present invention relates to the improvement of the vehicle parts described above, and the problem to be solved by the present invention is that the conventional vehicle parts cannot provide color.

この発明(請求項1にかかる発明)は、合成樹脂の基材と、合成樹脂の基材の表面に形成された第1密着膜と、第1密着膜の表面に形成された反射膜と、反射膜に表面に形成された保護膜と、保護膜の表面に形成された第2密着膜と、第2密着膜の表面に形成された有色塗膜と、から構成されている、ことを特徴とする。   This invention (invention according to claim 1) is a synthetic resin base material, a first adhesive film formed on the surface of the synthetic resin base material, a reflective film formed on the surface of the first adhesive film, It is composed of a protective film formed on the surface of the reflective film, a second adhesive film formed on the surface of the protective film, and a colored coating film formed on the surface of the second adhesive film. And

また、この発明(請求項2にかかる発明)は、合成樹脂の基材がポリカーボネートやシクロオレフィンポリマーからなり、第1密着膜がクロムやチタンをスパッタもしくは蒸着により形成されており、反射膜がアルミニウムや銀をスパッタもしくは蒸着により形成されており、保護膜がプラズマ重合膜からなり、第2密着膜が親水処理膜やプラズマ処理層からなり、有色塗膜がアクリル系やウレタン系の塗膜からなる、ことを特徴とする。   In the present invention (the invention according to claim 2), the base material of the synthetic resin is made of polycarbonate or cycloolefin polymer, the first adhesion film is formed by sputtering or vapor deposition of chromium or titanium, and the reflection film is made of aluminum. Or silver is formed by sputtering or vapor deposition, the protective film is made of a plasma polymerized film, the second adhesion film is made of a hydrophilic treatment film or a plasma treatment layer, and the colored coating film is made of an acrylic or urethane coating film. It is characterized by that.

さらに、この発明(請求項3にかかる発明)は、第1密着膜の膜厚が2〜5nmであり、保護膜の膜厚が2〜10nmであり、有色塗膜の膜厚が5〜20μmである、ことを特徴とする。   Further, in the present invention (the invention according to claim 3), the thickness of the first adhesion film is 2 to 5 nm, the thickness of the protective film is 2 to 10 nm, and the thickness of the colored coating film is 5 to 20 μm. It is characterized by being.

この発明(請求項1にかかる発明)の車両用部品は、第2密着層に有色塗膜が形成されるので、有色が得られる。しかも、この発明(請求項1にかかる発明)の車両用部品は、第1密着膜および第2密着膜により、有色塗膜が合成樹脂の基材から剥がれず、耐久性がよい。   In the vehicle component of this invention (the invention according to claim 1), a colored coating film is formed on the second adhesion layer, so that a color is obtained. Moreover, the vehicle component of the present invention (the invention according to claim 1) has good durability because the colored coating film is not peeled off from the base material of the synthetic resin by the first adhesion film and the second adhesion film.

また、この発明(請求項2にかかる発明)の車両用部品は、ポリカーボネートやシクロオレフィンポリマーとアルミニウムや銀との密着性が非常によいクロムやチタンの第1密着膜により、反射膜が合成樹脂性の基材に密着し、かつ、アクリル系やウレタン系の塗膜が撥水性のプラズマ重合膜に非常によく密着するために保護膜に親水処理膜やプラズマ処理層からなる第2密着膜を形成することにより、有色塗膜が反射膜に形成された保護膜に密着する。この結果、この発明(請求項2にかかる発明)の車両用部品は、有色塗膜と合成樹脂基材との密着性が非常によい。   In addition, the vehicle component of the present invention (the invention according to claim 2) is made of a first adhesive film of chromium or titanium that has a very good adhesion between polycarbonate or cycloolefin polymer and aluminum or silver, and the reflective film is a synthetic resin. In order for the acrylic or urethane coating film to adhere to the water-repellent plasma polymerized film very well, the protective film is provided with a second adhesion film comprising a hydrophilic treatment film or a plasma treatment layer. By forming, a colored coating film adheres to the protective film formed on the reflective film. As a result, the vehicle component of this invention (the invention according to claim 2) has very good adhesion between the colored coating film and the synthetic resin substrate.

さらに、この発明(請求項3にかかる発明)の車両用部品は、第1密着膜の膜厚を2〜5nmに、保護膜の膜厚を2〜10nmに、有色塗膜の膜厚を5〜20μmにすることにより、有色塗膜をムラ無く均一に塗布することができ、しかも、有色塗料と合成樹脂基材との密着性が日本工業規格JIS K 5600−5−6:1999(ISO 2409:1992)の試験による付着性能を満足することができる。すなわち、試験結果の評価において、表1「試験結果の分類」中の「0」分類を得ることができる。   Furthermore, in the vehicle component of this invention (the invention according to claim 3), the thickness of the first adhesion film is 2 to 5 nm, the thickness of the protective film is 2 to 10 nm, and the thickness of the colored coating film is 5. By setting the thickness to ˜20 μm, the colored coating film can be uniformly applied without unevenness, and the adhesion between the colored paint and the synthetic resin base material is Japanese Industrial Standard JIS K 5600-5-6: 1999 (ISO 2409). : Adhesion performance by the test of 1992) can be satisfied. That is, in the evaluation of the test results, the “0” classification in Table 1 “Classification of test results” can be obtained.

以下、この発明にかかる車両用部品の実施例を図面に基づいて詳細に説明する。なお、この実施例によりこの発明が限定されるものではない。なお、図面中の基材の厚さや膜厚は、実際のものと異なって図示されている。   Embodiments of a vehicle component according to the present invention will be described below in detail with reference to the drawings. Note that the present invention is not limited to the embodiments. In addition, the thickness and film thickness of the base material in the drawings are illustrated differently from actual ones.

図1は、この発明にかかる車両用部品の実施例を示す。以下、この実施例における車両用部品の構成について説明する。図中、符号1は、この実施例における車両用部品ある。前記車両用部品1は、図1に示すように、合成樹脂の基材2と、前記合成樹脂の基材2の表面に形成された第1密着膜3と、前記第1密着膜3の表面に形成された反射膜4と、前記反射膜4に表面に形成された保護膜5と、前記保護膜5の表面に形成された第2密着膜6と、前記第2密着膜6の表面に形成された有色塗膜7と、から構成されているものである。   FIG. 1 shows an embodiment of a vehicle component according to the present invention. Hereinafter, the configuration of the vehicle component in this embodiment will be described. In the figure, reference numeral 1 denotes a vehicle component in this embodiment. As shown in FIG. 1, the vehicle component 1 includes a synthetic resin base material 2, a first adhesive film 3 formed on the surface of the synthetic resin base material 2, and a surface of the first adhesive film 3. A reflective film 4 formed on the surface, a protective film 5 formed on the surface of the reflective film 4, a second adhesive film 6 formed on the surface of the protective film 5, and a surface of the second adhesive film 6. The colored coating film 7 is formed.

前記合成樹脂の基材2は、リフレクタ、インナーパネル、エクステンション、化粧板、ハウジングなどの車両用部品の基材であって、この例では、ポリカーボネート(PC)やシクロオレフィンポリマー(COP)などからなるものである。   The base material 2 of the synthetic resin is a base material for vehicle parts such as a reflector, an inner panel, an extension, a decorative board, and a housing. In this example, the base material 2 is made of polycarbonate (PC) or cycloolefin polymer (COP). Is.

前記第1密着膜3は、この例では、クロムやチタンをスパッタもしくは蒸着により形成されてなるものであり、前記第1密着膜の膜厚は、2〜5nmである。   In this example, the first adhesion film 3 is formed by sputtering or vapor deposition of chromium or titanium, and the film thickness of the first adhesion film is 2 to 5 nm.

前記反射膜4は、この例では、アルミニウムや銀をスパッタもしくは蒸着により形成されてなるものであり、前記反射膜4の膜厚は、約100nmである。   In this example, the reflective film 4 is formed by sputtering or vapor deposition of aluminum or silver, and the thickness of the reflective film 4 is about 100 nm.

前記保護膜5は、この例では、ヘキサメチルジシロキサン(HMDSO)などのモノマーをプラズマ重合されてなるものであり、前記保護膜5の膜厚は、2〜10nmである。   In this example, the protective film 5 is formed by plasma polymerization of a monomer such as hexamethyldisiloxane (HMDSO), and the protective film 5 has a thickness of 2 to 10 nm.

前記第2密着膜6は、この例では、撥水性のプラズマ重合膜の前記保護膜5の表面を親水処理してなる親水化の親水処理膜やプラズマ処理層からなるものである。   In this example, the second adhesion film 6 is composed of a hydrophilic treatment film or a plasma treatment layer obtained by hydrophilic treatment of the surface of the protective film 5 of a water-repellent plasma polymerization film.

前記有色塗膜7は、この例では、アクリル系(アクリルやアクリルシリコーン)やウレタン系(ウレタンやウレタンシリコーン)の塗膜からなるものであり、前記有色塗膜7の膜厚は、5〜20μmである。   In this example, the colored coating 7 is made of an acrylic (acrylic or acrylic silicone) or urethane (urethane or urethane silicone) coating, and the colored coating 7 has a thickness of 5 to 20 μm. It is.

つぎに、この実施例における車両用部品の製造工程について説明する。まず、成形工程において、合成樹脂の基材2を成形する。   Next, the manufacturing process of the vehicle component in this embodiment will be described. First, in the molding step, the base material 2 of synthetic resin is molded.

つぎに、真空工程において、真空中で、合成樹脂の基材2の表面にクロムやチタンをスパッタもしくは蒸着して膜厚が2〜5nmの第1密着膜3を形成する。つづいて、真空中で、第1密着膜3の表面にアルミニウムや銀をスパッタもしくは蒸着して膜厚が約100nmの反射膜4を形成する。   Next, in a vacuum process, chromium or titanium is sputtered or vapor-deposited on the surface of the synthetic resin base material 2 in vacuum to form a first adhesion film 3 having a thickness of 2 to 5 nm. Next, in a vacuum, aluminum or silver is sputtered or deposited on the surface of the first adhesion film 3 to form the reflective film 4 having a thickness of about 100 nm.

また、RFやDCの電源を用い、プラズマ中(プラズマ真空中)で、ヘキサメチルジシロキサン(HMDSO)などのモノマー(モノマーガス)を導入してプラズマ重合を行って、反射膜4の表面にプラズマ重合膜を析出させて膜厚が2〜10nmの保護膜5を形成する。さらに、同様に、プラズマ中で、大気やエアーまたはアルゴン(アルゴンガス)を導入して保護膜5の表面を親水処理し、保護膜5の表面に第2密着膜6を形成する。   In addition, plasma is polymerized by introducing a monomer (monomer gas) such as hexamethyldisiloxane (HMDSO) in plasma (in plasma vacuum) using an RF or DC power source, and plasma is applied to the surface of the reflective film 4. A polymer film is deposited to form a protective film 5 having a thickness of 2 to 10 nm. Further, similarly, in the plasma, air, air or argon (argon gas) is introduced to hydrophilically treat the surface of the protective film 5 to form the second adhesion film 6 on the surface of the protective film 5.

そして、塗装と乾燥工程において、第2密着膜6の表面にアクリル系(アクリルやアクリルシリコーン)やウレタン系(ウレタンやウレタンシリコーン)の塗料を用いて塗装を施して膜厚が5〜20μmの塗膜7を形成する。つづけて、塗膜7を乾燥させる。これにより、この実施例における車両用部品1が製造される。ここで、塗装工程において、マスクを用いることにより、塗膜7を部分的に形成することができる。なお、図中の符号8および二点鎖線にしめすように、マスクを用いずに塗膜7および8を全体に形成してもよい。   In the painting and drying process, the surface of the second adhesion film 6 is coated with an acrylic (acrylic or acrylic silicone) or urethane (urethane or urethane silicone) coating to form a coating having a thickness of 5 to 20 μm. A film 7 is formed. Subsequently, the coating film 7 is dried. Thereby, the vehicle component 1 in this embodiment is manufactured. Here, the coating film 7 can be partially formed by using a mask in the painting process. It should be noted that the coating films 7 and 8 may be entirely formed without using a mask, as indicated by reference numeral 8 and a two-dot chain line in the figure.

この実施例における車両用部品1は、上記のごとき構成からなり、以下、この実施例における車両用部品1の作用効果について説明する。   The vehicle component 1 in this embodiment is configured as described above. Hereinafter, the operational effects of the vehicle component 1 in this embodiment will be described.

この実施例における車両用部品1は、第2密着層6に有色塗膜7が形成されるので、有色が得られる。これにより、この実施例における車両用部品1は、見栄えなどの意匠性が向上される。特に、この実施例のように、マスクを用いて有色塗膜を形成すれば、さらに意匠性が向上される。しかも、反射膜4により、金属光沢感が得られる。その上、有色塗膜7および8にスモーク有色を用いることによりスモーク有色が得られる。   Since the colored coating film 7 is formed on the second adhesion layer 6 in the vehicle component 1 in this embodiment, a color is obtained. Thus, the design of the vehicle component 1 in this embodiment is improved, such as appearance. In particular, if a colored coating film is formed using a mask as in this embodiment, the design is further improved. In addition, the reflective film 4 provides a metallic luster. In addition, a smoke color is obtained by using a smoke color for the colored coatings 7 and 8.

また、この実施例における車両用部品1は、第1密着膜3および第2密着膜6により、有色塗膜7が合成樹脂の基材2から剥がれず、耐久性がよい。以下、この実施例における車両用部品1における試験結果の評価について説明する。この試験は、日本工業規格JIS K 5600−5−6:1999(ISO 2409:1992)、すなわち、塗料一般試験方法−第5部:堵膜の機械的性質−第6節:付着性(クロスカット法)によるものである。この試験結果の評価は、表1「試験結果の分類」中の「0」分類を得ることができた。これにより、この実施例における車両用部品1は、有色塗膜7が合成樹脂の基材2から剥がれないものである。   Further, the vehicle component 1 in this embodiment has good durability because the colored coating film 7 is not peeled off from the base material 2 of the synthetic resin by the first adhesion film 3 and the second adhesion film 6. Hereinafter, the evaluation of the test result in the vehicle component 1 in this embodiment will be described. This test was conducted in accordance with Japanese Industrial Standard JIS K 5600-5-6: 1999 (ISO 2409: 1992), that is, paint general test method-Part 5: Mechanical properties of the capsule-Section 6: Adhesiveness (cross cut) Act). The evaluation of this test result was able to obtain the “0” classification in Table 1 “Classification of test results”. As a result, the vehicle component 1 in this embodiment is such that the colored coating film 7 is not peeled off from the base material 2 of the synthetic resin.

さらに、この実施例における車両用部品1は、成形工程で合成樹脂の基材2を形成し、真空工程で第1密着膜3および反射膜4および保護膜5および第2密着膜6を形成し、塗装乾燥工程で有色塗膜7を形成するものである。このために、この実施例における車両用部品1は、成形工程と、真空工程と、塗装乾燥工程との3工程で構成されるので、成形設備と、真空設備と、塗装乾燥設備との少なくとも3設備で製造可能である。この結果、この実施例における車両用部品1は、製造コストを安価にすることができる。   Furthermore, the vehicle component 1 in this embodiment forms the synthetic resin base material 2 in the molding process, and forms the first adhesion film 3, the reflection film 4, the protective film 5 and the second adhesion film 6 in the vacuum process. The colored coating film 7 is formed in the paint drying process. For this reason, since the vehicle component 1 in this embodiment is composed of three processes including a molding process, a vacuum process, and a paint drying process, at least three of a molding facility, a vacuum facility, and a paint drying facility. It can be manufactured with equipment. As a result, the vehicle component 1 in this embodiment can be manufactured at low cost.

この発明にかかる車両用部品の実施例を示す模擬断面図である。It is a simulation sectional view showing an example of parts for vehicles concerning this invention.

符号の説明Explanation of symbols

1 車両用部品
2 合成樹脂の基材
3 第1密着膜
4 反射膜
5 保護膜
6 第2密着膜
7 塗膜
8 マスクを用いない場合の塗膜
DESCRIPTION OF SYMBOLS 1 Vehicle parts 2 Base material of synthetic resin 3 1st adhesion film 4 Reflective film 5 Protective film 6 2nd adhesion film 7 Coating film 8 Coating film when not using mask

Claims (3)

合成樹脂の基材に有色塗料を施してなる車両用部品において、
前記合成樹脂の基材と、
前記合成樹脂の基材の表面に形成された第1密着膜と、
前記第1密着膜の表面に形成された反射膜と、
前記反射膜に表面に形成された保護膜と、
前記保護膜の表面に形成された第2密着膜と、
前記第2密着膜の表面に形成された有色塗膜と、
から構成されている、ことを特徴とする車両用部品。
In vehicle parts made by applying colored paint to the base material of synthetic resin,
A base material of the synthetic resin;
A first adhesion film formed on the surface of the synthetic resin substrate;
A reflective film formed on the surface of the first adhesion film;
A protective film formed on the surface of the reflective film;
A second adhesion film formed on the surface of the protective film;
A colored coating film formed on the surface of the second adhesion film;
It is comprised from these, The components for vehicles characterized by the above-mentioned.
前記合成樹脂の基材は、ポリカーボネートやシクロオレフィンポリマーからなり、
前記第1密着膜は、クロムやチタンをスパッタもしくは蒸着により形成されており、
前記反射膜は、アルミニウムや銀をスパッタもしくは蒸着により形成されており、
前記保護膜は、プラズマ重合膜からなり、
前記第2密着膜は、親水処理膜からなり、
前記有色塗膜は、アクリル系やウレタン系の塗膜からなる、
ことを特徴とする請求項1に記載の車両用部品。
The base material of the synthetic resin is made of polycarbonate or cycloolefin polymer,
The first adhesion film is formed by sputtering or vapor deposition of chromium or titanium,
The reflective film is formed by sputtering or vapor deposition of aluminum or silver,
The protective film comprises a plasma polymerization film,
The second adhesion film comprises a hydrophilic treatment film,
The colored coating consists of an acrylic or urethane coating,
The vehicle component according to claim 1.
前記第1密着膜の膜厚は、2〜5nmであり、
前記保護膜の膜厚は、2〜10nmであり、
前記有色塗膜の膜厚は、5〜20μmである、
ことを特徴とする請求項1または2に記載の車両用部品。
The film thickness of the first adhesion film is 2 to 5 nm,
The thickness of the protective film is 2 to 10 nm,
The film thickness of the colored coating film is 5 to 20 μm.
The vehicle component according to claim 1, wherein the vehicle component is a vehicle component.
JP2005036454A 2005-02-14 2005-02-14 Components for vehicle Pending JP2006222037A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008066068A (en) * 2006-09-06 2008-03-21 Ichikoh Ind Ltd Vehicular lamp apparatus
JP2008066069A (en) * 2006-09-06 2008-03-21 Ichikoh Ind Ltd Vehicular lamp apparatus
JP2008077888A (en) * 2006-09-19 2008-04-03 Sharp Corp Illumination device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008066068A (en) * 2006-09-06 2008-03-21 Ichikoh Ind Ltd Vehicular lamp apparatus
JP2008066069A (en) * 2006-09-06 2008-03-21 Ichikoh Ind Ltd Vehicular lamp apparatus
JP2008077888A (en) * 2006-09-19 2008-04-03 Sharp Corp Illumination device
JP4718405B2 (en) * 2006-09-19 2011-07-06 シャープ株式会社 Lighting equipment

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