JP2006221134A5 - - Google Patents

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JP2006221134A5
JP2006221134A5 JP2005262256A JP2005262256A JP2006221134A5 JP 2006221134 A5 JP2006221134 A5 JP 2006221134A5 JP 2005262256 A JP2005262256 A JP 2005262256A JP 2005262256 A JP2005262256 A JP 2005262256A JP 2006221134 A5 JP2006221134 A5 JP 2006221134A5
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retardation
retardation film
refractive index
film according
index anisotropy
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JP2005262256A
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JP4191711B2 (en
JP2006221134A (en
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高分子フィルム内に屈折率異方性を有する材料が浸透されてなることを特徴とする位相差フィルム。   A retardation film, wherein a material having refractive index anisotropy is permeated into a polymer film. 高分子フィルム内に屈折率異方性を有する材料が含有されてなる位相差フィルムであって、前記屈折率異方性を有する材料が、前記高分子フィルムの厚み方向に濃度勾配を有しており、当該濃度勾配が連続的に変化することを特徴とする位相差フィルム。   A retardation film in which a material having refractive index anisotropy is contained in a polymer film, wherein the material having refractive index anisotropy has a concentration gradient in the thickness direction of the polymer film. A retardation film, wherein the density gradient changes continuously. 前記高分子フィルムは、面内リタデーション及び/又は厚み方向リタデーションを有することを特徴とする請求項1または2に記載の位相差フィルム。 The retardation film according to claim 1 , wherein the polymer film has in- plane retardation and / or thickness direction retardation . 前記屈折率異方性を有する材料が、液晶性を有する材料であることを特徴とする請求項1乃至のいずれか記載の位相差フィルム。 Material having a refractive index anisotropy, the retardation film according to any one of claims 1 to 3, characterized in that a material having liquid crystallinity. 前記屈折率異方性を有する材料の分子構造が、棒状であることを特徴とする請求項1乃至のいずれかに記載の位相差フィルム。 The retardation film according to any one of claims 1 to 4 , wherein the molecular structure of the material having refractive index anisotropy is rod-shaped. 前記屈折率異方性を有する材料が、重合性官能基を有するものであることを特徴とする請求項1乃至のいずれかに記載の位相差フィルム。 The retardation film according to the material having the refractive index anisotropy, any one of claims 1 to 5, characterized in that those having a polymerizable functional group. 前記屈折率異方性を有する材料が、重合性官能基を有するものと重合性官能基を有しないものを含むことを特徴とする請求項1乃至のいずれかに記載の位相差フィルム。 The retardation film according to any one of claims 1 to 5 wherein the material having refractive index anisotropy, characterized in that those that do not have a polymerizable functional group and having a polymerizable functional group. 前記屈折率異方性を有する材料の前記高分子フィルムの厚み方向の濃度勾配が、前記高分子フィルムの一方の表面側が高濃度であり、他方の表面側に向かって低濃度となる濃度勾配であることを特徴とする請求項1乃至のいずれかに記載の位相差フィルム。 The concentration gradient in the thickness direction of the polymer film of the material having refractive index anisotropy is a concentration gradient in which one surface side of the polymer film has a high concentration and decreases toward the other surface side. the retardation film according to any one of claims 1 to 7, characterized in that. 前記位相差フィルムの純水に対する接触角が、一方の表面と他方の表面とで異なることを特徴とする請求項に記載の位相差フィルム。 The retardation film according to claim 8 , wherein a contact angle of the retardation film with respect to pure water is different between one surface and the other surface. 前記屈折率異方性を有する材料の前記高分子フィルムの厚み方向の濃度勾配が、前記高分子フィルムの両表面側が高濃度であり、中央部に向かって低濃度となる濃度勾配であることを特徴とする請求項1乃至のいずれかに記載の位相差フィルム。 The concentration gradient in the thickness direction of the polymer film of the material having refractive index anisotropy is a concentration gradient in which both surface sides of the polymer film have a high concentration and become a low concentration toward the center. the retardation film according to any one of claims 1 to 7, characterized. 前記屈折率異方性を有する材料の濃度勾配が緩やかな領域と、前記屈折率異方性を有する材料の濃度勾配が急な領域を有することを特徴とする請求項1乃至10のいずれかに記載の位相差フィルム。 And concentration gradient gentle region of material having a refractive index anisotropy, in any one of claims 1 to 10 gradient material having a refractive index anisotropy and having a steep region The retardation film described. 前記屈折率異方性を有する材料が含有されてない領域を有することを特徴とする請求項1乃至11のいずれかに記載の位相差フィルム。 The retardation film according to any one of claims 1 to 11, characterized in that it has a region where the material having the refractive index anisotropy is not contained. 前記フィルムの面内方向における遅相軸方向の屈折率をnx、フィルム面内方向における進相軸方向の屈折率をny、及びフィルムの厚み方向の屈折率をnz、並びに厚みをdとし、Rth[nm]={(nx+ny)/2−nz}×dで表されるRthを厚み方向リタデーションとした時に、前記厚み方向リタデーションが70〜300nmであることを特徴とする請求項1乃至12のいずれかに記載の位相差フィルム。 The refractive index in the slow axis direction in the in-plane direction of the film is nx, the refractive index in the fast axis direction in the in-plane direction of the film is ny, the refractive index in the thickness direction of the film is nz, and the thickness is d. [nm] = {(nx + ny) / 2-nz} of Rth represented by × d when the thickness direction retardation, any of claims 1 to 12 wherein the thickness direction retardation is equal to or is 70~300nm The retardation film of crab. JIS−K7105に準拠して測定した際のヘイズ値が1%以下であることを特徴とする請求項1乃至13のいずれかに記載の位相差フィルム。 The retardation film according to any one of claims 1 to 13 , wherein a haze value when measured in accordance with JIS-K7105 is 1% or less. 前記位相差フィルムの可視光領域におけるリタデーション値が、短波長側の方が長波長側よりも大きいことを特徴とする請求項1乃至14のいずれかに記載の位相差フィルム。 The retardation film according to any one of claims 1 to 14 the retardation value in the visible light region, towards the short wavelength side being larger than the long wavelength side of the retardation film. 前記位相差フィルムの可視光領域におけるリタデーション値が、長波長側の方が短波長側よりも大きいことを特徴とする請求項1乃至14のいずれかに記載の位相差フィルム。 The retardation film according to any one of claims 1 to 14 the retardation value in the visible light region, towards the long wavelength side is equal to or greater than the short wavelength side of the retardation film. 前記位相差フィルムの波長550nmで測定した厚み方向リタデーション(Rth)のフィルム面方向におけるばらつきがRthの平均値を基準として±5nmの範囲内であることを特徴とする請求項1乃至16のいずれかに記載の位相差フィルム。 17. The variation in thickness direction retardation (Rth) measured at a wavelength of 550 nm of the retardation film in the film surface direction is within a range of ± 5 nm based on the average value of Rth. 17 . The retardation film described in 1. 最小直径が6インチ以下のロール状に巻くことが可能であることを特徴とする請求項1乃至17のいずれかに記載の位相差フィルム。 The retardation film according to any one of claims 1 to 17, wherein the minimum diameter being rollable on 6 inches or less in rolls. 請求項1乃至18のいずれかに記載の単層の位相差フィルム2枚以上を、互いに貼り合わせてなることを特徴とする位相差フィルム。 The retardation film according to claim 1 in which 18 one or more two retardation films of the monolayer according to the, characterized by comprising adhered to each other. 請求項1乃至19のいずれかに記載の位相差フィルムを、位相差フィルム以外の光学機能層と直接貼り合わせてなることを特徴とする光学機能フィルム。 An optical functional film obtained by directly bonding the retardation film according to any one of claims 1 to 19 to an optical functional layer other than the retardation film. 請求項1乃至19のいずれかに記載の位相差フィルムを、偏光層と直接貼り合わせてなることを特徴とする偏光フィルム。 Polarizing film retardation film according to any one of claims 1 to 19, characterized by comprising bonded directly with a polarizing layer. 請求項1乃至19のいずれかに記載の位相差フィルム、請求項20に記載の光学機能フィルム、又は、請求項21に記載の偏光フィルムのいずれかを、光路に配置したことを特徴とする表示装置。 A retardation film according to any one of claims 1 to 19 , an optical functional film according to claim 20 , or a polarizing film according to claim 21 is disposed in an optical path. apparatus. 高分子フィルムの少なくとも一方の表面に、屈折率異方性を有する材料が溶媒に溶解もしくは分散されてなる位相差強化領域形成用塗工液を塗布する塗布工程と、前記塗布工程により塗布された前記位相差強化領域形成用塗工液中の前記屈折率異方性を有する材料を前記高分子フィルムに浸透させる浸透工程と、前記塗布工程により塗布された前記位相差強化領域形成用塗工液中の前記溶媒を乾燥させる乾燥工程とを有することを特徴とする位相差フィルムの製造方法。   A coating step for applying a coating solution for forming a retardation enhancement region in which a material having refractive index anisotropy is dissolved or dispersed in a solvent is applied to at least one surface of the polymer film, and the coating step is applied. A permeation step for allowing the material having refractive index anisotropy in the retardation enhancement region forming coating solution to penetrate into the polymer film, and the retardation enhancement region forming coating solution applied by the coating step. And a drying step for drying the solvent therein. A method for producing a retardation film. 前記浸透工程が、前記乾燥工程中に行われることを特徴とする請求項23に記載の位相差フィルムの製造方法。 The method for producing a retardation film according to claim 23 , wherein the permeation step is performed during the drying step. 前記乾燥工程の後に、前記高分子フィルム内に浸透した前記屈折率異方性材料を固定化する固定化工程を有することを特徴とする請求項23又は24に記載の位相差フィルムの製造方法。 After said drying step, method for producing a retardation film according to claim 23 or 24, characterized in that it has a fixing step of fixing the refractive index anisotropic material infiltrated into the polymer film.
JP2005262256A 2004-09-10 2005-09-09 Retardation film and method for producing the same, optical functional film, polarizing film, and display device Active JP4191711B2 (en)

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JP2008242292A (en) * 2007-03-28 2008-10-09 Dainippon Printing Co Ltd Retardation film and liquid crystal display device
US8305524B2 (en) 2007-07-11 2012-11-06 Dai Nippon Printing Co., Ltd. Liquid crystal display polarizing plate, method for producing liquid crystal display polarizing plate, and liquid crystal display
JP2009128637A (en) * 2007-11-22 2009-06-11 Dainippon Printing Co Ltd Liquid crystal display device
JP5428264B2 (en) * 2008-09-22 2014-02-26 東ソー株式会社 Optical compensation film and manufacturing method thereof
JP5428282B2 (en) * 2008-10-20 2014-02-26 東ソー株式会社 Optical compensation film and manufacturing method thereof
WO2012082576A1 (en) * 2010-12-16 2012-06-21 3M Innovative Properties Company Interpenetrated polymer layer
JP7166353B2 (en) * 2018-09-26 2022-11-07 富士フイルム株式会社 Transfer film, polarizing plate, image display device, and method for producing polarizing plate

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