JP2006218524A - Method for manufacturing metallic foil having roughened surface and metallic foil having roughened surface which is manufactured by using the same - Google Patents
Method for manufacturing metallic foil having roughened surface and metallic foil having roughened surface which is manufactured by using the same Download PDFInfo
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- JP2006218524A JP2006218524A JP2005035546A JP2005035546A JP2006218524A JP 2006218524 A JP2006218524 A JP 2006218524A JP 2005035546 A JP2005035546 A JP 2005035546A JP 2005035546 A JP2005035546 A JP 2005035546A JP 2006218524 A JP2006218524 A JP 2006218524A
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- metal foil
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Abstract
Description
本発明は、金属箔の製造方法に関し、特に粗面を有する金属箔の製造方法、およびそれを用いて製造してなる粗面を有する金属箔に関する。 The present invention relates to a method for producing a metal foil, and more particularly, to a method for producing a metal foil having a rough surface, and a metal foil having a rough surface produced using the method.
表面粗さの大きな金属板を得る場合、複数スタンドの圧延機を用いて各スタンドで金属板材を順次圧延して薄化し、最終スタンドで金属板の表面粗さが得られる粗面を有するロールで調質圧延し、目的とする厚さと表面粗さを有する金属板を得ている。しかし、板厚の小さな金属板を、表面粗さの大きなロールで圧延して、粗面の極薄の金属箔に成形しようとする場合、座屈現象が生じて縦皺と呼ばれる欠陥が発生する。また、この縦皺の発生を抑制または軽減するためにテンションレベラー等を用いて張力を付与した場合、極薄であるために破断しやすく、安定して生産ができない。 In order to obtain a metal plate with a large surface roughness, a roll having a rough surface that can be rolled and thinned sequentially at each stand using a multi-stand rolling mill and the surface roughness of the metal plate can be obtained at the final stand. Temper rolling is performed to obtain a metal plate having the desired thickness and surface roughness. However, when a metal plate with a small thickness is rolled with a roll with a large surface roughness to be formed into a very thin metal foil with a rough surface, a buckling phenomenon occurs and a defect called warp is generated. . In addition, when tension is applied using a tension leveler or the like in order to suppress or reduce the occurrence of the vertical wrinkles, it is extremely thin, and is easily broken and cannot be stably produced.
このような欠点を克服するため、例えば特許文献1は、縦筋が発生しない板厚に適合する表面粗さを有するロールを用いて調質圧延する方法を開示している。しかしこの方法によると、ロールの表面粗さによって縦皺を生じることなく圧延可能な板厚の範囲が限定されてしまうため、厚さによらずに所望の表面粗さを有する金属箔、特に厚さが0.05mm以下でRaが1.0μm以上の表面粗さを有する金属箔を製造することは不可能である。 In order to overcome such drawbacks, for example, Patent Document 1 discloses a method of temper rolling using a roll having a surface roughness suitable for a plate thickness in which no vertical bars are generated. However, according to this method, the range of the plate thickness that can be rolled without causing vertical wrinkles is limited by the surface roughness of the roll, so that the metal foil having the desired surface roughness regardless of the thickness, particularly the thickness It is impossible to manufacture a metal foil having a surface roughness of 0.05 mm or less and Ra of 1.0 μm or more.
本発明は、使用するロールの表面粗さに依存することなく、所望の厚さの粗面を有する金属箔を製造する方法、および大きな表面粗さを有する金属箔を提供することを目的とする。 An object of the present invention is to provide a method for producing a metal foil having a rough surface having a desired thickness without depending on the surface roughness of a roll to be used, and a metal foil having a large surface roughness. .
上記問題点を解決するために、本発明の粗面を有する金属箔の製造方法は、表面に粗面加工を施したロールを用いて金属板を圧延して表面を粗面化した後、前記粗面化した金属板の両面に有機樹脂を被覆し、次いで前記金属板が所定の厚さの金属箔になるように前記の有機樹脂被覆金属板を再圧延した後、前記有機樹脂を剥離することを特徴とする粗面を有する金属箔の製造方法(請求項1)であり、
上記(請求項1)の粗面を有する金属箔の製造方法において、前記再圧延は、前記粗面加工を施したロールの表面よりも表面粗さの小さな表面を有するロールを用いて行うこと(請求項2)を特徴とし、また
上記(請求項1)の粗面を有する金属箔の製造方法において、前記金属板は、圧延前の厚さが0.10mm以上であること(請求項3)を特徴とし、また
上記(請求項1)の粗面を有する金属箔の製造方法において、前記金属箔は厚さがが0.05mm以下であること(請求項4)を特徴とする。
In order to solve the above problems, the method for producing a metal foil having a rough surface according to the present invention, after rolling a metal plate using a roll having a rough surface processed to roughen the surface, The organic resin is coated on both surfaces of the roughened metal plate, and then the organic resin-coated metal plate is re-rolled so that the metal plate becomes a metal foil having a predetermined thickness, and then the organic resin is peeled off. A method for producing a metal foil having a rough surface characterized in that (Claim 1),
In the method for producing a metal foil having a rough surface as described above (Claim 1), the re-rolling is performed using a roll having a surface with a surface roughness smaller than that of the surface of the roll subjected to the rough surface processing ( (2) In the method for producing a metal foil having a rough surface according to (Claim 1), the metal plate has a thickness before rolling of 0.10 mm or more (Claim 3). In the method for producing a metal foil having a rough surface according to (Claim 1), the metal foil has a thickness of 0.05 mm or less (Claim 4).
また、本発明の粗面を有する金属箔は、上記(請求項1〜4)のいずれかの金属箔の製造方法を用いて製造してなる粗面を有する金属箔(請求項5)であり、
上記(請求項5)の粗面を有する金属箔において、表面粗さRaが1.0μm(JIS B 0601)以上であること(請求項6)ことを特徴とする。
Moreover, the metal foil having a rough surface of the present invention is a metal foil having a rough surface (Claim 5) produced by using any one of the metal foil production methods described above (Claims 1 to 4). ,
The metal foil having a rough surface as described above (Claim 5) has a surface roughness Ra of 1.0 μm (JIS B 0601) or more (Claim 6).
本発明においては、任意の表面粗さを有するロールを用いて金属板を圧延して表面を粗面化した後、金属板の両面に有機樹脂を被覆し、次いで金属板が所定の厚さの金属箔になるように前記の有機樹脂被覆金属板を再圧延した後、前記有機樹脂を剥離するので、ロールの表面粗さに依存することなく、縦皺を発生させずに任意の厚さの表面粗さを有する金属箔、特に厚さが0.05mm以下でRaが1.0μm以上の表面粗さを有する金属箔を製造することが可能である。 In the present invention, a metal plate is rolled using a roll having an arbitrary surface roughness to roughen the surface, and then an organic resin is coated on both surfaces of the metal plate, and then the metal plate has a predetermined thickness. After re-rolling the organic resin-coated metal plate so as to become a metal foil, the organic resin is peeled off, so that it does not depend on the surface roughness of the roll and has any thickness without causing vertical wrinkles. It is possible to produce a metal foil having a surface roughness, particularly a metal foil having a surface roughness with a thickness of 0.05 mm or less and an Ra of 1.0 μm or more.
以下、本発明の内容を説明する。
本発明の粗面を有する金属箔の製造方法において、原板として適用する金属板としては、鋼板、めっき鋼板、表面処理鋼板、ステンレス鋼板、アルミニウム板、アルミニウム合金板、銅板、銅合金板など、通常の圧延工程で製造されている金属板を挙げることができる。板厚としてはロールの表面粗さに関わりなく縦皺を発生させることなく圧延可能な最小限の厚さまで、最終の調質圧延ロールで所望の表面粗さで圧延した粗面化金属板を用いることが好ましい。例えば鋼板の場合は0.1〜0.2mm程度の厚さまで圧延した粗面化したものを用いることが好ましい。
The contents of the present invention will be described below.
In the method for producing a metal foil having a rough surface according to the present invention, the metal plate applied as the original plate is usually a steel plate, a plated steel plate, a surface-treated steel plate, a stainless steel plate, an aluminum plate, an aluminum alloy plate, a copper plate, a copper alloy plate, etc. The metal plate manufactured by the rolling process of this can be mentioned. As the plate thickness, use a roughened metal plate rolled with the desired surface roughness with the final temper rolling roll to the minimum thickness that can be rolled without causing vertical wrinkles regardless of the surface roughness of the roll. It is preferable. For example, in the case of a steel plate, it is preferable to use a roughened surface rolled to a thickness of about 0.1 to 0.2 mm.
次いで、公知の被覆方法を用いて、この粗面化金属板の両面に有機樹脂を被覆する。有機樹脂としては汎用のポリオレフィン樹脂、ポリエステル樹脂、ポリアミド樹脂などの熱可塑性樹脂からなるフィルムを用い、熱接着法により被覆することが好ましい。有機樹脂の厚さとしては有機樹脂を被覆した後の再圧延に用いるロールの表面粗さにもよるが、10〜100μm程度であることが好ましい。有機樹脂の熱接着は、再圧延後に容易に剥離可能な条件、例えばガラス転移温度以上でかつ溶融温度以下の温度範囲で熱接着することが好ましい。 Next, an organic resin is coated on both surfaces of the roughened metal plate using a known coating method. As the organic resin, it is preferable to use a film made of a thermoplastic resin such as a general-purpose polyolefin resin, polyester resin, or polyamide resin and coat it by a thermal bonding method. The thickness of the organic resin is preferably about 10 to 100 μm, although it depends on the surface roughness of the roll used for re-rolling after coating the organic resin. The thermal bonding of the organic resin is preferably performed by thermal bonding in a condition where it can be easily peeled after re-rolling, for example, in a temperature range above the glass transition temperature and below the melting temperature.
このようにして得られる有機樹脂被覆金属板を、所望の厚さの金属箔となるように再圧延する。再圧延に用いるロールの表面粗さとしては、被覆する有機樹脂が薄い場合は再圧延ロールの粗面が金属板表面に転写されることがないように、ブライトロールなど、原板の金属板の粗面化に用いた調質圧延用のロールの表面粗さより小さな表面粗さを有するロールを用いることが好ましいが、被覆する有機樹脂が厚く、再圧延ロールの粗面が金属板表面に転写されるおそれが無い場合は、ロールの表面粗さについて特に限定する必要はない。 The organic resin-coated metal plate thus obtained is re-rolled so as to obtain a metal foil having a desired thickness. The surface roughness of the roll used for re-rolling is such that the rough surface of the re-rolling roll is not transferred to the surface of the metal plate when the organic resin to be coated is thin. It is preferable to use a roll having a surface roughness smaller than the surface roughness of the roll for temper rolling used for surface treatment, but the organic resin to be coated is thick, and the rough surface of the re-rolling roll is transferred to the surface of the metal plate. When there is no fear, it is not necessary to specifically limit the surface roughness of the roll.
このようにして再圧延した後、有機樹脂を剥離することにより、本発明の大きな表面粗さを有する金属箔を得ることができる。 After rerolling in this manner, the metal foil having a large surface roughness according to the present invention can be obtained by peeling off the organic resin.
以下、実施例を示して本発明をさらに詳細に説明する。
[金属板]
厚さ1.8mmの熱延鋼板を5段スタンドのタンデムミルで0.5mmの厚さに冷間圧延し焼鈍した後、2段スタンドのタンデムミルを用いて0.1mmの厚さに再圧延した。次いで再焼鈍した後、ワークロールとして表面粗さRaが2.4μmのロールを有する1段スタンドの調質圧延ミルを用い、Raが1.8μmの表面粗さを有する厚さ0.1mmの冷延鋼板を作成した。
Hereinafter, the present invention will be described in more detail with reference to examples.
[Metal plate]
A 1.8 mm thick hot-rolled steel sheet is cold-rolled and annealed to a thickness of 0.5 mm with a 5-stage tandem mill and then re-rolled to a thickness of 0.1 mm with a 2-stage tandem mill. did. Then, after re-annealing, a temper rolling mill having a single-stage stand having a roll having a surface roughness Ra of 2.4 μm as a work roll was used, and a 0.1 mm thick cold having a surface roughness Ra of 1.8 μm. A rolled steel sheet was created.
[樹脂被覆金属板]
上記の冷延鋼板の両面に、20μmの厚さのポリエチレンテレフタレートの無延伸フィルムを加熱温度230℃で熱接着し、樹脂被覆金属板とした。
[Resin-coated metal plate]
An unstretched film of polyethylene terephthalate having a thickness of 20 μm was thermally bonded to both surfaces of the cold-rolled steel plate at a heating temperature of 230 ° C. to obtain a resin-coated metal plate.
[再圧延]
上記の樹脂被覆金属板を、ワークロールとして表面粗さRaが0.3μmのロールを有する2段スタンドのタンデムミルを用いて、圧延後の金属箔部分の厚さが0.04mmとなるように圧延した。その後、樹脂を剥離して0.04mmの厚さでRaが1.6μmの表面粗さを有する鋼箔を得た。
[Re-rolling]
Using the above-mentioned resin-coated metal plate as a work roll, a two-stand tandem mill having a roll with a surface roughness Ra of 0.3 μm, so that the thickness of the rolled metal foil portion is 0.04 mm Rolled. Thereafter, the resin was peeled off to obtain a steel foil having a thickness of 0.04 mm and a surface roughness of Ra of 1.6 μm.
任意の表面粗さを有するロールを用いて金属板を圧延して表面を粗面化した後、金属板の両面に有機樹脂を被覆し、次いで金属板が所定の厚さの金属箔になるように前記の有機樹脂被覆金属板を再圧延した後、前記有機樹脂を剥離する一連の工程からなる本発明の粗面を有する金属箔の製造方法によれば、ロールの表面粗さに依存することなく、縦皺を発生させずに任意の厚さの表面粗さを有する金属箔、特に厚さが0.05mm以下で、表面粗さRaが1.0μm以上を有する金属箔を製造することができる。また、縦皺の発生を抑制するための張力付与が不要であるので金属箔が破断することがなく、安定して粗面を有する金属箔を製造することができる。
After rolling a metal plate using a roll having an arbitrary surface roughness to roughen the surface, coat both sides of the metal plate with an organic resin, and then the metal plate becomes a metal foil of a predetermined thickness According to the method for producing a metal foil having a rough surface of the present invention comprising a series of steps of peeling the organic resin after re-rolling the organic resin-coated metal plate, it depends on the surface roughness of the roll. A metal foil having a surface roughness of an arbitrary thickness without causing vertical wrinkles, particularly a metal foil having a thickness of 0.05 mm or less and a surface roughness Ra of 1.0 μm or more. it can. In addition, since it is not necessary to apply tension to suppress the occurrence of vertical wrinkles, the metal foil is not broken and a metal foil having a rough surface can be produced stably.
Claims (6)
6. The metal foil having a rough surface according to claim 5, wherein the surface roughness Ra (JIS B 0601) is 1.0 μm or more.
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Cited By (3)
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WO2008143150A1 (en) | 2007-05-11 | 2008-11-27 | Kabushiki Kaisha Toyota Jidoshokki | Gene-disrupted strain, recombinant plasmid, transformant and method of producing 3-carboxymuconolactone |
WO2010030026A1 (en) | 2008-09-12 | 2010-03-18 | 株式会社豊田自動織機 | Polyester, polyurethane and methods for producing same |
US20230214074A1 (en) * | 2021-12-30 | 2023-07-06 | Micron Optoelectronics Co., Ltd. | Metal mesh touch screen and method for manufacturing metal mesh touch screen |
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2005
- 2005-02-14 JP JP2005035546A patent/JP2006218524A/en not_active Withdrawn
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008143150A1 (en) | 2007-05-11 | 2008-11-27 | Kabushiki Kaisha Toyota Jidoshokki | Gene-disrupted strain, recombinant plasmid, transformant and method of producing 3-carboxymuconolactone |
WO2010030026A1 (en) | 2008-09-12 | 2010-03-18 | 株式会社豊田自動織機 | Polyester, polyurethane and methods for producing same |
US20230214074A1 (en) * | 2021-12-30 | 2023-07-06 | Micron Optoelectronics Co., Ltd. | Metal mesh touch screen and method for manufacturing metal mesh touch screen |
US11966551B2 (en) * | 2021-12-30 | 2024-04-23 | Micron Optoelectronics Co., Ltd. | Metal mesh touch screen and method for manufacturing metal mesh touch screen |
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