JP2006211928A - Modifier, premix and batter liquid each for coating for frozen fried food - Google Patents
Modifier, premix and batter liquid each for coating for frozen fried food Download PDFInfo
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- Grain Derivatives (AREA)
Abstract
Description
本発明は、天ぷら、磯部揚げ、フリッター、トンカツ、その他フライ類といった揚物のための衣(ころも)の材料に配合される改質剤、並びに、このような衣の材料としてのプリミックス(バッターミックス)、及びバッター液(衣の原料液)に関する。特には、衣付けの後に冷凍またはチルド状態で保存する冷凍揚げ物のためのものに関する。 The present invention relates to a modifier compounded in a material for clothing such as tempura, fried buttocks, fritters, tonkatsu and other fries, and a premix (batter) as a material for such clothing. Mix) and batter liquid (raw material liquid for clothes). In particular, it relates to frozen fried food that is stored frozen or chilled after clothing.
近年、食生活の多様化、簡便化に伴い、冷凍又はチルド状態で保存され、電子レンジで加熱するか、または、簡単な油揚げ操作(油ちょう)を行うだけで食べることができる食品の需要が高まってきている。 In recent years, with the diversification and simplification of eating habits, there is a demand for foods that are stored in a frozen or chilled state and can be eaten simply by heating in a microwave oven or by performing a simple frying operation (oil frying). It is increasing.
天ぷらその他の揚物を手作りするには、具材(揚げ種)を下ごしらえし、バッター付けし、場合によりバッター付けの前に打ち粉をまぶし、あるいは場合によりバッター付け後にパン粉付けし、さらに油ちょう(加熱した油による調理)を行う必要がある。このように調理に手間がかかる他、油を扱う危険性や、油の後始末の面倒さ等もある。また、最近では、核家族化や独身世帯、老夫婦世帯の比率の増加等もあって、少量の総菜を簡便に用意することのできる、いわゆる「中食」製品が好まれる傾向にある。 To make tempura and other deep-fried foods, prepare ingredients (fried seeds), batter, sprinkle flour before battering, or bread crumb after battering, and then add oil ( Cooking with heated oil). In addition to the time and effort required for cooking, there are dangers of handling oil and the troublesomeness of cleaning up oil. Recently, there is a tendency to favor so-called “meal” products that can easily prepare a small amount of prepared meals due to the increase in the ratio of nuclear families, single households, and elderly couple households.
一方では、食材の多様化や食生活の豊かさの向上もあって、食味及び食感の優れた冷凍食品が求められている。特に、冷凍揚げ物は、サクサクとした歯触り、いわゆるクリスピーな食感が好まれる。しかしながら、唐揚げ、てんぷら、フリッターなどの揚げ物の衣は、フライ直後の食感がクリスピーであっても、冷凍保存して加熱した際には、フライ直後のようなクリスピーな食感が復元できないという問題が生じがちである。これは、揚物を冷凍すると、揚げ種から衣へと水分が移行することが主な原因である。 On the other hand, there is a demand for frozen foods with excellent taste and texture due to diversification of food ingredients and improvement in the richness of eating habits. In particular, frozen fried foods are preferred for their crisp texture, so-called crispy texture. However, fried foods such as deep-fried food, tempura, and fritters cannot be restored to the crispy texture immediately after frying, even when the texture immediately after frying is crispy. Problems tend to arise. This is mainly due to the transfer of moisture from the fried seeds to the clothes when the fried food is frozen.
簡単な油揚げ操作で食べることのできる半油ちょう冷凍揚物の場合、「引き」が出るのをある程度抑制したり、「しんなり」するのを防ぐことができる。したがって、電子レンジ等の加熱のみで食べることのできる冷凍揚げ物の場合に比べて一般には有利であるが、衣が硬くてもろくなってしまい食感が失われるということも、往々にして生じる。これは、冷凍中に衣の水分が昇華して乾燥しているところへ、再油ちょうによってさらに衣の水分が失われるのが主な原因と思われる。同様の理由から、衣の外観が白っぽくなり、美味そうな外観が損なわれるという「冷凍やけ」の問題も生じていた。 In the case of a semi-frozen deep-fried deep-fried food that can be eaten by a simple frying operation, the occurrence of “pull” can be suppressed to a certain extent, and “smooth” can be prevented. Therefore, although it is generally advantageous as compared with the case of frozen fried food that can be eaten only by heating such as a microwave oven, it often happens that the clothes become brittle and lose their texture. This seems to be mainly due to the fact that the moisture of the clothes is further lost due to the re-oiling to the place where the moisture of the clothes is sublimated and dried during freezing. For the same reason, the appearance of clothes became whitish, and the problem of “frozen burns” that the appearance that looks delicious was damaged was also caused.
また、一方では、衣の密着性が低いために、揚げ種(具材)と衣とが容易に分離し商品性が低下したり、食感が低下するという問題も、往々にして生じていた。 On the other hand, due to the low adhesiveness of clothing, problems such as fried seeds (ingredients) and clothing are easily separated, resulting in a decrease in merchantability and a decrease in texture are often caused. .
そこで、カードラン、寒天、ゼラチンといった増粘剤を比較的多量に添加することで食感の悪化や冷凍やけを回避することが提案されている(特許文献1)。また、特定の油脂、大豆タンパク質及び特定の可食性乳化剤等を配合することも提案されている(特許文献2〜3)。しかし、このように各種の結合剤その他の添加剤を比較的多量に用いた場合、食味に影響を与え、商品性に悪影響を与える場合もある他、コストの上昇等の原因ともなりうる。
本発明は、油ちょうまたは半油ちょうの後、冷凍又はチルド状態で保存してから、加熱または再油ちょうを行うという場合にも、衣のサクサク感等の食感や外観が損なわれることを防止できるとともに、揚げ種に対する衣の結着性を高く保つこができる、冷凍揚げ物用衣用改質剤、プリミックス及びバッター液を提供することを目的とする。 The present invention also shows that the texture and appearance of the crispness of clothing is impaired even when heating or re-oiling after storing in a frozen or chilled state after oil or semi-oil. An object of the present invention is to provide a clothes modifier for frozen fried food, a premix and a batter liquid that can be prevented and can maintain high binding properties of the clothes to the fried seeds.
本発明の冷凍揚げ物衣用改質剤は、エーテル化度が0.3〜0.8であって、かつ、1%水溶液粘度が5〜1000mPa・sのカルボキシメチルセルロース・ナトリウムからなることを特徴とする。 The modifier for frozen fried food of the present invention is characterized by comprising carboxymethylcellulose sodium having a degree of etherification of 0.3 to 0.8 and a 1% aqueous solution viscosity of 5 to 1000 mPa · s. To do.
また、本発明の冷凍揚げ物衣用プリミックス、及び冷凍揚げ物衣用バッター液は、エーテル化度が0.3〜0.8であって、かつ、1%水溶液粘度が5〜1000mPa・sのカルボキシメチルセルロース・ナトリウムを、0.1〜2.0重量%含むことを特徴とする。 Moreover, the pre-mix for frozen fried food clothes and the batter for frozen fried food clothes of the present invention have a degree of etherification of 0.3 to 0.8 and a 1% aqueous solution viscosity of 5 to 1000 mPa · s. It contains 0.1 to 2.0% by weight of methylcellulose sodium.
冷凍又はチルド状態で保存後に、単に加熱調理する場合、及び再油ちょうを行う場合のいずれの場合にも、衣のサクサク感等の食感や外観が損なわれることを防止できるとともに、衣の結着性を高く保つこができる。 In both cases of cooking by heating and re-oiling after storage in a frozen or chilled state, the crispy texture and appearance of the clothing can be prevented from being impaired, and the clothing Wearability can be kept high.
本発明の揚げ物衣用の改質剤は、エーテル化度が0.3〜0.8、好ましくは0.5〜0.80であって、かつ、1%水溶液粘度が5〜1000mPa・s、好ましくは50〜800mPa・sのカルボキシメチルセルロース・ナトリウムからなる。エーテル化度または水溶液粘度が、これよりも低いと改質効果が不充分であり、特には衣の結着性を高く保つことができない。また、エーテル化度が上記範囲よりも高い場合や、1%水溶液粘度が上記範囲より高い場合も、食感等を保持するための改質効果が不充分となる。 The modifier for fried clothes of the present invention has a degree of etherification of 0.3 to 0.8, preferably 0.5 to 0.80, and a 1% aqueous solution viscosity of 5 to 1000 mPa · s. Preferably, it consists of sodium carboxymethylcellulose of 50 to 800 mPa · s. If the degree of etherification or aqueous solution viscosity is lower than this, the modification effect is insufficient, and in particular, the binding property of the garment cannot be kept high. Also, when the degree of etherification is higher than the above range, or when the 1% aqueous solution viscosity is higher than the above range, the modification effect for maintaining the texture and the like becomes insufficient.
上記のような特定のカルボキシメチルセルロース・ナトリウムが、衣の材料であるプリミックス(バッターミックス粉)またはバッター液中に、水分を除いた乾燥固形分ベースで、0.1〜2.0重量%、好ましくは0.3〜1.0重量%含まれるように配合される。すなわち、乾燥粉末の状態、または水に溶いた液の状態のバッター中に、固形分100重量部中、0.1〜2.0重量部といった量が含まれるように配合される。この範囲より少ない配合量では充分な改質効果が得られず、また、この範囲を超える量を添加する場合には、衣に過度の粘りが生じてサクサク感が失われてしまう。 Specific carboxymethylcellulose sodium as described above is 0.1 to 2.0% by weight on a dry solid basis excluding moisture in a premix (batter mix powder) or batter liquid that is a material of clothing. Preferably, it is blended so as to contain 0.3 to 1.0% by weight. That is, it mix | blends so that the quantity of 0.1-2.0 weight part in 100 weight part of solid content may be contained in the batter of the state of a dry powder or the liquid dissolved in water. If the blending amount is less than this range, a sufficient reforming effect cannot be obtained, and if an amount exceeding this range is added, excessive stickiness occurs in the garment and the crispy feeling is lost.
本発明の冷凍揚げ物衣用の改質剤等において、上記特定のカルボキシメチルセルロース・ナトリウムとともに、各種天然糊剤等の安定剤または増粘剤を配合することができる。例えば、グアガム、ペクチン、ローカストビンガム、アルギン酸ソーダ、寒天、ゼラチン、キサンタンガム等を、本発明の目的を損なわない範囲で適宜配合することができる。 In the modifier for frozen fried food of the present invention, a stabilizer or thickener such as various natural pastes can be blended together with the specific carboxymethylcellulose / sodium. For example, guar gum, pectin, locust bin gum, sodium alginate, agar, gelatin, xanthan gum and the like can be appropriately blended within a range not impairing the object of the present invention.
本発明のプリミックスまたはバッター液には、通常のプリミックスまたはバッター液に使用されている各種原料を適宜配合して使用することができる。すなわち、薄力粉等の小麦粉その他の穀物粉を主原料として、でんぷん、米粉等の他の穀物粉、大豆粉、膨張剤(ベーキングパウダー)、グルタミン酸ナトリウム等の調味料等を適宜配合して調製することができる。さらには、例えば、化工澱粉、糖類、デキストリン、油脂、粉末油脂、マーガリン、ショートニング、バター・クリーム・牛乳・脱脂粉乳・乳蛋白質等の乳製品、全卵粉末・卵黄粉末・卵白粉末等の卵製品、乳化剤、酸化防止剤、膨張剤、保存料、調味料、酸味料、苦味料、香辛料、香辛料抽出物、香料、食塩等の無機塩類、酵素等の副原料を、本発明の目的を損なわない限り、任意に使用することができる。 In the premix or batter liquid of the present invention, various raw materials used in normal premix or batter liquid can be appropriately blended and used. That is, using wheat flour such as wheat flour and other cereal flour as the main raw material, other cereal flour such as starch, rice flour, soy flour, expansion agent (baking powder), and seasonings such as sodium glutamate, etc. Can do. Furthermore, for example, dairy products such as modified starch, saccharides, dextrin, fats and oils, powdered fats and oils, margarine, shortening, butter, cream, milk, skimmed milk powder, milk protein, egg products such as whole egg powder, egg yolk powder, egg white powder, etc. Additives such as emulsifiers, antioxidants, swelling agents, preservatives, seasonings, acidulants, bitters, spices, spice extracts, fragrances, and salt, and auxiliary materials such as enzymes, do not impair the purpose of the present invention As long as it can be used arbitrarily.
上記特定のカルボキシメチルセルロース・ナトリウムは、プリミックスの状態で配合しておく以外に、バッター液の段階で添加しても何ら支障はない。乾燥粉体の状態で混合するには、例えば、小麦粉その他の粉体原料と、カルボキシメチルセルロース・ナトリウムの粉末とを粉体混合機にて混合する。また、本発明のバッター液を調製するには、小麦粉等を含むプリミックスに、水その他の液体原料を加え、均一に混合する。この段階で、上記特定のカルボキシメチルセルロース・ナトリウムを添加する場合には、水溶液の状態で添加することができる。なお、本発明のバッター液を調製する際には、好ましくは、プリミックス100重量部に対し、液体原料100〜600重量部を添加する。 The specific sodium carboxymethyl cellulose / sodium may be added at the stage of the batter solution in addition to the premixed state. For mixing in a dry powder state, for example, wheat flour and other powder raw materials and carboxymethyl cellulose / sodium powder are mixed in a powder mixer. Moreover, in order to prepare the batter liquid of the present invention, water and other liquid raw materials are added to a premix containing wheat flour and mixed uniformly. At this stage, when adding the specific sodium carboxymethyl cellulose, it can be added in the state of an aqueous solution. In addition, when preparing the batter liquid of this invention, Preferably, 100-600 weight part of liquid raw materials are added with respect to 100 weight part of premixes.
本発明のプリミックスないしバッター液は、通常の冷凍しない揚物と同程度まで完全に油ちょうを行ってから冷凍又はチルド状態で流通し保存され、電子レンジ等で加熱するだけで食べられるタイプの冷凍揚げ物にも、また、軽度の油ちょうが行われてから冷凍又はチルド状態で流通し保存され、再油ちょう後に食事に供するタイプのもの(いわゆる「プリフライ冷凍揚げ物」)であっても、同様に適用できる。 The premix or batter of the present invention is a type of frozen that can be eaten only by heating in a microwave oven etc. The same applies to deep-fried foods that have been distributed and stored in a frozen or chilled state after a light oil frying (so-called “pre-fried frozen fried food”). Applicable.
本発明のバッター液等が適用可能な冷凍揚げ物としては、天ぷら、磯部揚げ、フリッター、トンカツ、えびフライ、あじフライ等を挙げることができるが、衣付けして油ちょうするものであれば、いずれのタイプの揚げ物の衣にも用いることができる。揚げ物(フライ食品)の製造の際には、例えば、イカ、エビ、その他魚貝類、食肉(豚、牛、鶏)、かぼちゃ、イモその他の野菜類等の各種具材(揚げ種)に、必要により小麦粉をまぶし、これを上記バッター液に浸漬する。そして必要に応じてパン粉を着け、油で揚げる。油ちょうは、常法に従って行えばよく、揚げ種の種類にもよるが、例えば170〜180℃の食用油中で3〜4分間行えばよい。 Examples of the frozen fried food to which the batter liquid etc. of the present invention can be applied include tempura, fried salmon, fritter, tonkatsu, shrimp fried fish, fried chicken, etc. It can also be used for clothes of fried foods. When manufacturing deep-fried food (fried food), for example, it is necessary for various ingredients (fried seeds) such as squid, shrimp, other fish and shellfish, meat (pig, cow, chicken), pumpkin, potato and other vegetables. Sprinkle the flour and immerse it in the batter solution. Then apply breadcrumbs and fry as needed. Oil cooking may be performed according to a conventional method, and may be performed in edible oil at 170 to 180 ° C. for 3 to 4 minutes, depending on the type of fried seed.
<カルボキシメチルセルロース・ナトリウム(CMC−Na)>
第一工業製薬(株)の「セロゲン」(登録商標)シリーズにおける所定のエーテル化度及び粘度のものを用いた。CMC−Naは、予め、エーテル化度及び1%水溶液粘度の測定を、以下のようにして行っている。
<Carboxymethylcellulose sodium (CMC-Na)>
A product having a predetermined degree of etherification and viscosity in “Serogen” (registered trademark) series of Daiichi Kogyo Seiyaku Co., Ltd. was used. CMC-Na has previously measured the degree of etherification and the viscosity of a 1% aqueous solution as follows.
エーテル化度:灰化測定法を用いた。詳しくは、約1g(絶乾重量)の粉末試料を精秤し、ろ紙に包んで磁性ルツボ中に入れ、600℃で充分に灰化させた。次いで、生成した水酸化ナトリウムを、0.1N硫酸により、フェノールフタレインを指示薬として中和滴定し、次式により算出した。
エーテル化度=162×A/(1000−80×A)
ここで、Aは、滴定に要した0.1N硫酸のml数をその力価により補正したものである。
Etherification degree: Ashing measurement method was used. Specifically, about 1 g (absolute dry weight) of the powder sample was precisely weighed, wrapped in filter paper, placed in a magnetic crucible, and sufficiently ashed at 600 ° C. Next, the produced sodium hydroxide was neutralized and titrated with 0.1N sulfuric acid using phenolphthalein as an indicator, and calculated according to the following formula.
Degree of etherification = 162 × A / (1000-80 × A)
Here, A is a value obtained by correcting the ml number of 0.1 N sulfuric acid required for titration by the titer.
1%水溶液粘度:105℃4時間の乾燥により水分含量を測定しておく。そして、約2.2gの試料を栓付きの300ml容の三角フラスコにとり、水分含量補正後の重量(絶乾重量)を基準として1重量%となるように水を加えた。一昼夜放置後、さらにマグネチックスターラーで約5分間撹拌して、均一な液とした後、フタ付きのトールビーカー状容器に移した。30分間25℃の恒温水槽に静置後、BM型粘度計((株)トキメック)により、回転数60rpmで適当なローターを回転させ、3分後の読みから粘度を測定した。 1% aqueous solution viscosity: moisture content is measured by drying at 105 ° C. for 4 hours. Then, about 2.2 g of the sample was placed in a 300 ml Erlenmeyer flask with a stopper, and water was added so as to be 1% by weight based on the weight after moisture content correction (absolute dry weight). After being left for a whole day and night, the mixture was further stirred with a magnetic stirrer for about 5 minutes to obtain a uniform solution, and then transferred to a tall beaker container with a lid. After standing in a constant temperature water bath at 25 ° C. for 30 minutes, an appropriate rotor was rotated at a rotation speed of 60 rpm with a BM type viscometer (Tokimec Co., Ltd.), and the viscosity was measured from the reading after 3 minutes.
<冷凍天ぷら食品の調製及び評価>
1.バッター液及び揚げ物種(具材)
市販の天ぷら粉(小麦の薄力粉:(株)日清製粉の「日清天ぷら粉」)100gに、下記表1の左欄に記載の所定の品種及び配合量のカルボキシメチルセルロース・ナトリウム(CMC−Na)の粉末を混合した後、水180gを加えて均一に混合しバッター液とした。揚げ物種(具材)としては、生イカの切り身(約8×8cmの)、及び、サツマイモの輪切り(直径6〜8cm、厚さ約1cm)を用いた。
<Preparation and evaluation of frozen tempura food>
1. Batter liquid and deep-fried seeds (ingredients)
To 100 g of commercially available tempura flour (weak wheat flour: “Nisshin Tempura Flour” of Nisshin Flour Milling Co., Ltd.), carboxymethylcellulose sodium (CMC-Na) having a predetermined variety and blending amount described in the left column of Table 1 below. ) Was mixed, and then 180 g of water was added and mixed uniformly to obtain a batter solution. As fried food seeds (ingredients), raw squid fillets (about 8 × 8 cm) and sweet potato slices (diameter 6-8 cm, thickness about 1 cm) were used.
2.油ちょう(半油ちょう)→冷凍保存→再油ちょう
生イカの切り身、またはサツマイモの輪切りをバッタ付けした後、175℃3分間の油ちょうを行うことにより、天ぷらを得た。そして、このように得られた天ぷらを、家庭用冷蔵庫の冷凍室(約−20℃)にて3カ月保存した。次いで、175℃3分間の再度の油ちょうを行った。
2. Oil butter (semi-oil butter) → cryopreservation → re-oiled butter After cutting raw squid fillets or sweet potato slices, tempura was obtained by oil-stirring at 175 ° C. for 3 minutes. And the tempura obtained in this way was preserve | saved for three months in the freezer compartment (about -20 degreeC) of a household refrigerator. Subsequently, the oil was again squeezed at 175 ° C. for 3 minutes.
3.評価
このように得られた天ぷらについて、外観、揚げ物種と衣との結着状態、及び、食感について、官能評価を行った。また、冷凍保存前の外観についても評価した。下記表1に評価結果をまとめて示す。
表1に示すように、所定のCMC−Naを所定範囲で配合した実施例のバッター液を用いた場合、再油ちょう後の衣は、食感(歯触り)、及び、結着性のいずれも良好であった。また、再油ちょう後の衣の色調は、黄色、または、黄色〜淡褐色となり、美味な印象を与えるものであった。また、冷凍ショーケースに並べられる状態に対応する、半油ちょう後の状態においても、適当な黄色の色調を有していた。 As shown in Table 1, when the batter solution of the example in which a predetermined CMC-Na is blended in a predetermined range is used, the garment after re-oiling has either a texture (touch) or a binding property. Was also good. Moreover, the color tone of the clothes after re-oiling became yellow or yellow to light brown, and gave a delicious impression. Moreover, it had an appropriate yellow color tone even after the semi-oiled state corresponding to the state of being arranged in the frozen showcase.
これに対して、CMC−Naを添加せず、市販天ぷら粉のみを用いた比較例1の場合、得られた天ぷら衣は、軟らかく、サクサク感のないものであった。また、衣は、押さえるか、または衝撃を与えると簡単に剥がれてしまった。さらに、衣の外観は、再油ちょう後にも白っぽく、美味な感を与えないものであった。 On the other hand, in the case of Comparative Example 1 using only commercially available tempura powder without adding CMC-Na, the obtained tempura garment was soft and had no crispy feeling. Also, the garment easily peeled off when pressed or shocked. Furthermore, the appearance of the clothes was whitish after re-oiling and did not give a delicious taste.
また、実施例1〜2と同様のCMC−Naを5重量%添加した比較例2の場合、衣の歯触りが過度に硬く食感に劣ることとなった。また、衣が脆いために、衝撃を受けた場合に衣が剥がれやすくなっていた。さらに、油ちょう後の外観は、実施例2のものよりも褐色が強く、多少焦げ過ぎたような印象を与えがちのものであった。 Moreover, in the case of the comparative example 2 which added 5 weight% of CMC-Na similar to Examples 1-2, the touch of the clothes was too hard and it was inferior to food texture. Moreover, since the garment is brittle, the garment is easily peeled off when subjected to an impact. Further, the appearance after oiling was more brownish than that of Example 2 and was likely to give an impression that it was slightly burnt.
Claims (3)
0.1 to 2.0% by weight of carboxymethyl cellulose sodium having a degree of etherification of 0.3 to 0.8 and a 1% aqueous solution viscosity of 5 to 1000 mPa · s on a solid basis. Batter liquid for frozen deep-fried clothing.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2007105824A1 (en) | 2006-03-16 | 2007-09-20 | Matsushita Electric Industrial Co., Ltd. | Variable focal lens and imaging apparatus |
JP2011152087A (en) * | 2010-01-28 | 2011-08-11 | Asahi Kasei Chemicals Corp | Batter coating composition |
JP2012527238A (en) * | 2009-05-18 | 2012-11-08 | ダウ グローバル テクノロジーズ エルエルシー | Method for reducing oil absorption in oil-cooked food |
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2005
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007105824A1 (en) | 2006-03-16 | 2007-09-20 | Matsushita Electric Industrial Co., Ltd. | Variable focal lens and imaging apparatus |
JP2012527238A (en) * | 2009-05-18 | 2012-11-08 | ダウ グローバル テクノロジーズ エルエルシー | Method for reducing oil absorption in oil-cooked food |
US8999418B2 (en) | 2009-05-18 | 2015-04-07 | Dow Global Technologies Llc | Methods for reducing oil uptake of fried foods |
JP2011152087A (en) * | 2010-01-28 | 2011-08-11 | Asahi Kasei Chemicals Corp | Batter coating composition |
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