JP2006199974A5 - - Google Patents

Download PDF

Info

Publication number
JP2006199974A5
JP2006199974A5 JP2006125108A JP2006125108A JP2006199974A5 JP 2006199974 A5 JP2006199974 A5 JP 2006199974A5 JP 2006125108 A JP2006125108 A JP 2006125108A JP 2006125108 A JP2006125108 A JP 2006125108A JP 2006199974 A5 JP2006199974 A5 JP 2006199974A5
Authority
JP
Japan
Prior art keywords
polyester resin
content
injection molding
dicarboxylic acid
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2006125108A
Other languages
Japanese (ja)
Other versions
JP2006199974A (en
Filing date
Publication date
Application filed filed Critical
Priority to JP2006125108A priority Critical patent/JP2006199974A/en
Priority claimed from JP2006125108A external-priority patent/JP2006199974A/en
Publication of JP2006199974A publication Critical patent/JP2006199974A/en
Publication of JP2006199974A5 publication Critical patent/JP2006199974A5/ja
Pending legal-status Critical Current

Links

Description

本発明は、前記目的を達成すべくなされたものであって、即ち、本発明は、芳香族ジカルボン酸又はそのエステル形成性誘導体を主成分とするジカルボン酸成分と、エチレングリコールを主成分とするジオール成分とを、エステル化反応又はエステル交換反応を経て、少なくともチタン化合物の存在下に重縮合させることにより製造されたポリエステル樹脂であって、280℃での射出成形後の成形体における樹脂の環状三量体含有量(CTS;重量%)と、射出成形前の樹脂の環状三量体含有量(CT0;重量%)との差(CTS−CT0)が0.10重量%以下であり、かつ、コバルト化合物の含有量が、ポリエステル樹脂1トン当たり、コバルト原子(Co)として1モル以下であるポリエステル樹脂、を要旨とする。 The present invention has been made to achieve the above object, that is, the present invention has a dicarboxylic acid component mainly composed of an aromatic dicarboxylic acid or an ester-forming derivative thereof, and ethylene glycol as the main component. A polyester resin produced by subjecting a diol component to a polycondensation through an esterification reaction or a transesterification reaction in the presence of at least a titanium compound, and the cyclic state of the resin in a molded article after injection molding at 280 ° C. The difference (CT S −CT 0 ) between the trimer content (CT S ; wt%) and the cyclic trimer content (CT 0 ; wt%) of the resin before injection molding is 0.10 wt% or less. der is, and the content of the cobalt compound is, per ton polyester resin, to 1 mole der Ru polyester resin as a cobalt atom (Co), and the gist.

Claims (1)

芳香族ジカルボン酸又はそのエステル形成性誘導体を主成分とするジカルボン酸成分と、エチレングリコールを主成分とするジオール成分とを、エステル化反応又はエステル交換反応を経て、少なくともチタン化合物の存在下に重縮合させることにより製造されたポリエステル樹脂であって、280℃での射出成形後の成形体における樹脂の環状三量体含有量(CTS ;重量%)と、射出成形前の樹脂の環状三量体含有量(CT0 ;重量%)との差(CTS −CT0 )が0.10重量%以下であり、かつ、コバルト化合物の含有量が、ポリエステル樹脂1トン当たり、コバルト原子(Co)として1モル以下であることを特徴とするポリエステル樹脂。 A dicarboxylic acid component mainly composed of an aromatic dicarboxylic acid or an ester-forming derivative thereof and a diol component mainly composed of ethylene glycol are subjected to an esterification reaction or transesterification reaction, and at least in the presence of a titanium compound. Polyester resin produced by condensation, the cyclic trimer content (CT S ; wt%) of the resin in the molded article after injection molding at 280 ° C., and the cyclic trimer of the resin before injection molding body content: the difference (CT S -CT 0) and (CT 0 wt%) of Ri der 0.10 wt% or less, and the content of the cobalt compound, the polyester resin per ton, a cobalt atom (Co ) as 1 mole der polyester resin, wherein Rukoto.
JP2006125108A 2000-05-01 2006-04-28 Polyester resin Pending JP2006199974A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006125108A JP2006199974A (en) 2000-05-01 2006-04-28 Polyester resin

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2000131999 2000-05-01
JP2006125108A JP2006199974A (en) 2000-05-01 2006-04-28 Polyester resin

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP2001029133A Division JP4155716B2 (en) 2000-05-01 2001-02-06 Polyester resin and method for producing the same

Publications (2)

Publication Number Publication Date
JP2006199974A JP2006199974A (en) 2006-08-03
JP2006199974A5 true JP2006199974A5 (en) 2008-03-21

Family

ID=36958236

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006125108A Pending JP2006199974A (en) 2000-05-01 2006-04-28 Polyester resin

Country Status (1)

Country Link
JP (1) JP2006199974A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006022341A (en) * 2000-05-01 2006-01-26 Mitsubishi Chemicals Corp Polyester resin
JP5511129B2 (en) * 2007-06-25 2014-06-04 三井化学株式会社 Production method of polyester resin
JP5245753B2 (en) * 2008-11-20 2013-07-24 東レ株式会社 Polyester composition and film using the same
JP7187774B2 (en) * 2017-02-09 2022-12-13 東レ株式会社 polyester film

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08283394A (en) * 1995-04-10 1996-10-29 Mitsui Petrochem Ind Ltd Production of polyethylene terephthalate
JPH11310629A (en) * 1998-02-27 1999-11-09 Mitsui Chem Inc New polyester and production of polyester
JP4897130B2 (en) * 1999-06-17 2012-03-14 東洋紡績株式会社 Polyester, sheet-like material comprising the same, hollow molded body and stretched film
JP2001048972A (en) * 1999-08-12 2001-02-20 Mitsui Chemicals Inc Blow molded product and its production
JP2001261806A (en) * 2000-03-21 2001-09-26 Toray Ind Inc Polyester excellent in moldability
JP4155716B2 (en) * 2000-05-01 2008-09-24 三菱化学株式会社 Polyester resin and method for producing the same
JP2006022341A (en) * 2000-05-01 2006-01-26 Mitsubishi Chemicals Corp Polyester resin

Similar Documents

Publication Publication Date Title
WO2011145899A3 (en) Blend of polylactic acid resin and copolyester resin, and molded product using same
CA2691598A1 (en) Molded article having heat resistance and impact resistance
WO2010062082A3 (en) Copolymer polyester resin and molded product using same
WO2008051321A8 (en) Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor
WO2009072462A1 (en) Polyester with improved heat resistance produced from biomass ethylene glycol
ES2963525T3 (en) Polymeric composition for the manufacture of thermoformed articles
MX2013003502A (en) High functionality aromatic polyesters, polyol blends comprising the same and resultant products therefrom.
WO2002062869A1 (en) Polyester resin and method for production thereof
JP2006199974A5 (en)
MX2011009329A (en) Thermoplastic polyurethane with reduced tendency to bloom.
MX2010009905A (en) Bio-based polyethylene terephthalate polymer and method of making the same.
TW200911914A (en) Polylactic acid composition
WO2010062081A3 (en) Copolymer polyester resin and molded product using same
EP2966126B1 (en) Oxygen-absorbing resin composition, oxygen-absorbing multilayer-injection-molded body using same, and oxygen-absorbing multiwall container using said oxygen-absorbing resin composition
WO2011049390A3 (en) Clay-reinforced poly(lactic acid)-polyolefin alloy composition
WO2008133262A1 (en) Polyester elastomer composition, and method for production thereof
WO2012134152A3 (en) Polyester resin resulting from the copolymerisation of lactic acid and isosorbide, and a production method therefor
JP2006022341A5 (en)
DE602004010887D1 (en) Process for the preparation of copolyesters of polyethylene terephthalate
Zeng et al. A tough bio-adhesive inspired by pearl layer and arthropod cuticle structure with desirable water resistance, flame-retardancy, and antibacterial property
JP2006152315A5 (en)
JP2017090717A5 (en)
WO2013028008A3 (en) Biodegradable resin composition, and draining board core material and draining board produced therefrom
WO2008155980A1 (en) Molded article having heat resistance and impact resistance
WO2010062083A3 (en) Copolymer polyester resin and molded product using same