JP2006182698A - Detergent composition for finger - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a detergent composition for finger, having excellent detergency to an oil stain and capable of giving a rinse feeling with mildness and cleanliness to the skin, scarcely causing a residual fragrance on the hand. <P>SOLUTION: This detergent composition for finger contains (A) at least one kind selected from ampholytic surfactants and (B) a fatty acid salt, wherein a mass ratio of a content of the component (A) to a content of the component (B) [(A)/(B)] is in a range of 90/10 to 10/90 and a total content of all surfactants, including the components (A) and (B), is less than 15%. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a detergent composition for fingers that has an excellent detergency for oil stains, has a mild and refreshing rinsing feel on the skin, and does not easily leave a fragrance in the hand.

  Conventionally, cleaning compositions used for fingers have good detergency against dirt on hands, especially persistent oil stains caused by ingredients such as meat and fish during cooking, and at the same time are rinsed. There is no need for stickiness, a refreshing bubble, and a mildness to the skin.

  In addition, it is required that the cleaning agent for fingers does not leave the scent of the cleaning agent in the hand. In particular, it is a great dissatisfaction for consumers that the scent remaining in the hand is transferred to the foodstuff, and it is an important quality for the hand cleaning agent used in the cooking scene that there is little residual scent in the hand. On the other hand, it is also important to remove the smell of food such as fish and garlic from the hands.

As a method for realizing good detergency against oil stains, for example, a detergent composition using a combination of a surfactant and a compound having a specific alkylene oxide addition mole number and addition form and having an average molecular weight of 1200 or less. (For example, refer to Patent Document 1), a specific amide ether carboxylic acid, and amide ether and a specific nonionic surfactant in a specific ratio and not containing glycerin or a specific glyceryl ether, or A cleaning composition containing a small amount (for example, see Patent Document 2) is known.
However, in any of the inventions described in Patent Documents 1 and 2, since the synthetic surfactant is used at a high concentration of 15% by mass or more, there is a dullness during rinsing, and mildness to the skin. There is a problem with sex.

  Moreover, the detergent composition (for example, refer patent document 3) containing the alkyl phosphate monoester and alkyl phosphate diester which are hypoallergenic surfactant and an amine oxide in a specific ratio, and a specific glycine derivative By using a combination of nonionic surfactants, a detergent composition that is less irritating and has an excellent feel during and after washing (see, for example, Patent Document 4) and a detergent composition containing a fatty acid salt (For example, refer to Patent Document 5).

  However, the cleaning composition described in Patent Document 3 has high detergency against oil stains and good mildness, but uses a synthetic surfactant at a high concentration of 20% by mass or more. For this reason, there are problems such as the presence of luster when rinsing, and the detergent composition described in Patent Document 4 also has no luster when rinsing and mildness to the skin, but oil stains. In addition, there is a problem in that the cleaning power against water is insufficient. Further, in the cleaning composition described in Patent Document 5, the non-slipping property at the time of rinsing and the mildness to the skin are good. There is a problem in that the detergency against the water is insufficient.

On the other hand, in order not to leave a fragrance in the hands, unscented hand washing agents that do not contain fragrance are also commercially available, but the raw material odor of the product is strong, you can not enjoy the scent, or the odor of food ingredients such as fish is masked There is a problem that it cannot be performed (see, for example, Patent Document 6).
Moreover, although the method of reducing a fragrance | flavor compounding amount and reducing a residual fragrance property is also known, a fragrance | flavor tone and a fragrance | flavor compounding amount are restrict | limited by the strength of raw material odor. Conventionally, many techniques aimed at deodorization (for example, see Patent Document 7) and improvement of the remaining fragrance properties (for example, see Patent Document 8) have been introduced. There is no current situation.
JP-A-11-148091 (Claims, Examples, etc.) JP-A-8-259992 (claims, examples, etc.) JP 2003-313588 A (Claims, Examples, etc.) Japanese Patent Laid-Open No. 9-87684 (Claims, Examples, etc.) Japanese Patent Laid-Open No. 9-1000049 (claims, examples, etc.) JP-A-01-272503 (Claims, Examples, etc.) Special Table 2002-519368 gazette (Claims, Examples, etc.) JP-A-10-045553 (Claims, Examples, etc.)

  The present invention is to solve this problem in view of the above-described problems of the prior art and the current state of the art, is excellent in oil stain cleaning power, has a mild and refreshing rinsing feel on the skin, It aims at providing the detergent composition for fingers which a fragrance is hard to remain in a hand.

As a result of intensive studies to solve the above-described conventional problems, the present inventors have found that at least one selected from amphoteric surfactants and fatty acids that are anionic surfactants having a refreshing rinsing feel By containing the salt in a specific ratio, mixed micelles large enough to solubilize the oil are formed, the detergency is increased, and the effect of the fatty acid salt has a refreshing rinse feel. In addition to finding out and having excellent detergency, the present invention (claims) finds that the surfactant concentration necessary for removing oil stains is milder than that of the prior art, so that it is mild to the skin. 1) has been completed.
In addition, as described above, the present inventors have found that the hand cleaning composition of the present invention has an excellent detergency against oil stains, but the present invention further solubilizes in hydrophobic substances other than oils and fats. I found out that it is excellent in power. That is, since the fragrance is less likely to be released from the micelles in the washing and rinsing process, the residual fragrance is less than in the past. However, by itself, a further sufficient residual scent reduction effect cannot be obtained, and as a result of further studies, one or more components selected from hydrocarbons having a specific number of carbon atoms in a specific range are contained in a specific amount in the fragrance composition. In addition to having high volatility in itself, it can synergistically increase the volatility of low volatility ingredients essential for the composition of the perfume composition, and it has extremely low residual fragrance. The inventors have found that a cleaning composition can be obtained, and have completed the present invention (Claim 2).

That is, the present invention resides in the following (1) and (2).
(1) (A) Contains at least one selected from amphoteric surfactants and (B) fatty acid salt, and the content ratio of the components (A) and (B) [(A) / (B) ] In a mass ratio of 90/10 to 10/90, and the total content of all surfactants including the component (A) + the component (B) is less than 15% by mass. A cleaning composition for fingers.
(2) The finger according to (1), further comprising a fragrance containing at least one component selected from hydrocarbons having 5 to 15 carbon atoms in an amount of 50% by mass or more of the fragrance composition. Cleaning composition.

  ADVANTAGE OF THE INVENTION According to this invention, it is excellent in the detergency with respect to oil stain | pollution | contamination, has a mild and refreshing rinse feeling with respect to skin, and provides the detergent composition for fingers which a fragrance does not remain in a hand easily.

Hereinafter, embodiments of the present invention will be described in detail.
The hand detergent composition of the present invention contains (A) at least one selected from amphoteric surfactants and (B) a fatty acid salt, and the content ratio of the above-mentioned (A) component and (B) component. [(A) / (B)] is a mass ratio in the range of 90/10 to 10/90, and the total content of all surfactants including the component (A) + component (B) is 15%. It is characterized by being less than.

The amphoteric surfactant of the component (A) used in the present invention is not particularly limited as long as it is used in a normal cleaning composition. For example, imidazoline type (amidoamine type), amide amino acid salt, carbobetaine type (Alkylbetaine, alkylamidobetaine), sulfobetaine type (alkylsulfobetaine, alkylhydroxysulfobetaine), phosphobetaine type, acyl tertiary amine oxide, acyl tertiary phosphine oxide, and the like can be used.
Examples of the imidazoline type include coconut oil alkyl-N-hydroxyethyl imidazolinium betaine, etc. Examples of alkyl betaines include, for example, lauryldimethylaminoacetic acid betaine, etc. Examples of alkyl amide betaines include coconut oil fatty acid amide propyl betaine. .
Examples of the alkylsulfobetaine include coconut oil fatty acid dimethylsulfopropylbetaine; examples of the alkylhydroxysulfobetaine include lauryldimethylaminohydroxysulfobetaine; examples of the phosphobetaine type include laurylhydroxyphosphobetaine.

Further, examples of the acyl tertiary amine oxide include lauryl dimethyl amine oxide, and examples of the acyl tertiary phosphine oxide include lauryl dimethyl phosphine oxide, which are also called semipolar surfactants. It is.
These amphoteric surfactants can be used alone or in combination of two or more (hereinafter, simply referred to as “at least one”).
Preferred amphoteric surfactants are preferably alkylbetaines, alkylamidobetaines, acyl tertiary amine oxides and the like from the standpoint of foaming and cost.

The fatty acid salt of the component (B) used in the present invention is not particularly limited as long as it is used in a normal cleaning composition, and examples thereof include saturated and unsaturated fatty acids having 12 to 18 carbon atoms (C12 to C18). Besides these, fatty acids such as coconut oil fatty acid, hardened coconut oil fatty acid, palm oil fatty acid, hardened palm oil fatty acid, beef tallow fatty acid, hardened beef tallow fatty acid, potassium salts, sodium salts, triethanolamine salts, ammonium salts, etc. At least one kind of soap or the like can be used.
Moreover, fatty acid soap itself may be contained as a fatty acid salt, and a fatty acid and an alkali may be separately contained in a detergent composition and neutralized for use.

In the present invention, the content ratio of the amphoteric surfactant of the component (A) and the fatty acid salt of the component (B) is (A) / (B) = 90 in terms of mass ratio in terms of detergency and rinsing feel. It is necessary to make it the range of / 10-10 / 90, Preferably, it is desirable to set it as 50 / 50-15 / 85.
When the content ratio (A) / (B) is out of the range of 90/10 to 10/90, the effect of the present invention cannot be exhibited.

Moreover, the total content of the total surfactant containing the amphoteric surfactant of the component (A) and the fatty acid salt of the component (B) is based on the total amount of the detergent composition from the viewpoint of mildness to the skin. Therefore, it is necessary to make it less than 15% by mass (hereinafter, simply referred to as “%”), and preferably 7 to 13%.
In the present invention, if the total content of all the surfactants including the component (A) and the component (B) exceeds 15%, the effects of the present invention cannot be exhibited, whereas if the total content is less than 7% There is a problem in terms of cleaning power, which is not preferable.

In this invention, the said (A) component, (B) component, and arbitrary components can be suitably contained in the range which does not inhibit the effect of this invention.
Optional components include, for example, surfactants other than those mentioned above, oils such as silicones and higher alcohols, lanolin derivatives, protein derivatives, water-soluble polymer compounds, drugs such as vitamins, preservatives, pH adjusters, metal sequestering agents. , Ultraviolet absorbers, animal and plant extracts or derivatives thereof, fragrances, pigments and the like. In addition, content of these arbitrary components can be contained in a normal amount as long as the effects of the present invention are not hindered. The balance is adjusted with water (clean water, purified water, ion exchange water, distilled water, pure water, etc.).

In the present invention, at least one component selected from hydrocarbons having 5 to 15 carbon atoms is preferably contained in the fragrance composition in an amount of 50% or more from the viewpoint of further obtaining a hand cleaning composition with very little residual fragrance. It is desirable to include a fragrance.
The “fragrance composition” defined in the present invention means a mixture comprising at least a fragrance component, a solvent, a fragrance stabilizer, and the like.
In the present invention, the above-mentioned “hydrocarbons” particularly refers to components composed of hydrocarbons contained in the natural essential oil and synthetic perfume oil of Citrus Note. Examples of limonene, α-pinene, β-pinene, myrcene, terpinene, terpinolene, cymene, camphene, sabinene, osymene and the like described in “6. It is not limited.

Examples of the fragrance component that can be used other than the components selected from the hydrocarbons having 5 to 15 carbon atoms include those selected from a list of fragrance raw materials used as the fragrance.
This list of perfume ingredients can be found in various publications such as “Perfume and Flavor Chemicals”, Vol. I and II, Steffen Arctander, Allured Pub. Co. (1994) and "Synthetic fragrance chemistry and commercial knowledge", Motoichi Into, Chemical Industry Daily (1996) and "Perfume and Flavor Materials of Natural Origin", Stephen Arctander, Allred Pub. Co. (1994) and "Encyclopedia of Scents", edited by Japan Fragrance Association, Asakura Shoten (1989) and "Performer Material Performance V.3.3", Boelens Aroma Chemical Information Service (1996) and "Flower oil". , Danute Lajaujis Anonis, Allured Pub. Co. (1993), etc., each of which is incorporated herein by reference.

Examples of the perfume solvent include ethanol, benzyl benzoate, acetin (triacetin), MMB acetate (3-methoxy-3-methylbutyl acetate), ethylene glycol dibutyrate, hexylene glycol, dibutyl sebacate, and deltile extra. (Isopropyl myristate), methyl carbitol (diethylene glycol monomethyl ether), carbitol (diethylene glycol monoethyl ether), TEG (triethylene glycol), benzyl benzoate, propylene glycol, diethyl phthalate, tripropylene glycol, aboline (dimethyl phthalate) ), Deltyl prime (isopropyl palmitate), dipropylene glycol DPG-FC (dipropylene glycol), farnese , Dioctyl adipate, tributyrin (glyceryl tributanoate), hydrolite-5 (1,2-pentanediol), propylene glycol diacetate, cetyl acetate (hexadecyl acetate), ethyl abiate, avaline (methyl abietate), citro Flex A-2 (acetyl triethyl citrate), Citroflex A-4 (tributyl acetyl citrate), Citroflex No. 2 (triethyl citrate), Citroflex No. 4 (tributyl citrate), durafix (methyl dihydroabietate), MITD (isotridecyl myristate), polylimonene (limonene polymer), 1,3-butylene glycol and the like.
These fragrance solvents are preferably contained in the fragrance composition in an amount of 0.1 to 99%, more preferably 0.1 to 10%.

  Examples of the fragrance stabilizer include dibutylhydroxytoluene, butylhydroxyanisole, vitamin E and its derivatives, catechin compounds, flavonoid compounds, polyphenol compounds, and the like. These contents are preferably contained in the fragrance composition. Is contained in an amount of 0.0001 to 10%, more preferably 0.001 to 5%. Among these, a preferable stabilizer is dibutylhydroxytoluene.

The detergent composition for fingers of the present invention contains a fragrance composition containing at least one component selected from hydrocarbons having 5 to 15 carbon atoms in a fragrance composition at 50% or more, and the detergent composition. It is preferable to contain 0.01 to 1% with respect to the total amount, and more preferably 0.1 to 0.5%.
The use of hydrocarbons other than those having 5 to 15 carbon atoms or the use of hydrocarbons having 5 to 15 carbon atoms in less than 50% of the fragrance composition, the desired hand washing composition with very little residual fragrance Things cannot be obtained. In addition, when the fragrance containing at least one component selected from hydrocarbons having 5 to 15 carbon atoms in the fragrance composition is 50% or more with respect to the total amount of the cleaning composition, the fragrance Insufficient masking of the base odor due to the above, on the other hand, if it exceeds 1%, the desired detergent composition for fingers with very little residual fragrance cannot be obtained.

  The hand cleaning composition of the present invention can be prepared in accordance with the conventional method of cleaning composition, and the apparatus for preparing the cleaning composition of the present invention includes a plurality of agitation that can be mixed with shear force. A stirrer equipped with blades, such as propellers, turbines, dispersers, etc. is desirable.

The hand cleaning composition of the present invention thus configured is at least one selected from the amphoteric surfactants as component (A) and an anionic surfactant having a refreshing rinse feel ( By containing the fatty acid salt of the component B) in a specific ratio, mixed micelles large enough to solubilize the oil are formed and the detergency is increased, and the effect of the fatty acid salt of the component (B) As it has a refreshing rinsing feel and excellent cleaning power, the necessary surfactant concentration can be set lower than before to remove oil stains. It will have.
Furthermore, in the said detergent composition for fingers, by making the fragrance | flavor composition which contains 50 mass% or more in a fragrance | flavor composition at least 1 sort (s) chosen from C5-C15 hydrocarbons, Not only is it highly volatile, but it can synergistically increase the volatility of the low-volatile perfume ingredients that are essential for the composition of the perfume composition. Things will be obtained.

  Next, the present invention will be described more specifically based on examples and comparative examples, but the present invention is not limited to the following examples. In the following examples, the description of “%” represents “% by mass”, the total amount is 100% by mass, and the component amounts described in the examples are all in terms of pure matter.

[Examples 1 to 13 and Comparative Examples 1 to 9]
The finger cleaning compositions of Examples and Comparative Examples, each having the composition shown in Table 1 and Table 2 below, were prepared according to a conventional method.
About the obtained detergent composition for fingers, the following evaluation methods evaluated the cleaning power with respect to an oil stain, the non-stickiness at the time of a rinse, the mildness with respect to skin, and the scent which remains in a hand.
These results are shown in Tables 1 and 2 below. The perfume compositions used in Tables 1 and 2 are shown in Table 3 below.

[(1) Detergency against oil stains, (2) Evaluation method of non-stickiness during rinsing]
After extending 1 g of beef tallow over both hands and wetting both hands with water, rubbing the hands with 1 g of the detergent composition for hands of Examples and Comparative Examples for 20 seconds, rinsing with running water, and rinsing at the time of rinsing The lack of adhesion was evaluated according to the following evaluation criteria. Moreover, after towel drying, the cleaning power was evaluated according to the following evaluation criteria based on the feel of oil remaining in the hand. The score was the average of 10 panelists.

Evaluation criteria for non-stickiness during rinsing:
5 points: No sliminess 4 points: The slime disappears from the side of the rinse 3 points: The slime remains after the foam flows, but then disappears immediately 2 points: The slime remains after the foam flows , It takes time to rinse out 1 point: Luster does not disappear even after rinsing Evaluation criteria for detergency against greasy dirt:
5 points: The grease stains are completely removed. 4 points: The grease stains feel slightly attached. 3 points: The grease stains feel slightly. 2 points: The grease stains feel 1 point. Hardly falls

[(3) Method for evaluating mildness to skin]
The inner part of the forearm is cup-shaked for 1 minute with 5 mL of an aqueous solution obtained by diluting the hand detergent compositions of Examples and Comparative Examples 6 times with water, and then rinsed with running water. This treatment was repeated 5 times a day for 10 days, and then the skin condition was observed and evaluated according to the following evaluation criteria. The score was the average of 10 panelists.
Evaluation criteria for mildness to skin:
4 points: No change in skin condition 3 points: Slightly rough skin is observed in the part subjected to cup shake treatment 2 points: Rough skin is observed in the part subjected to cup shake treatment 1 point: Cup shake treatment is performed Rough skin and erythema are observed

[(4) Evaluation method of fragrance remaining in hand]
Immediately after the evaluation of the non-stickiness at the time of rinsing, the scent remaining in the hand was immediately sniffed by the same panelist, and the scent remaining in the hand was evaluated according to the following evaluation criteria. The score was the average of 10 panelists.
Evaluation criteria for remaining fragrance:
5 points: no scent left in hand 4 points: little scent left in hand 3 points: scent left slightly in hand 2 points: scent left in hand considerably 1 point: scent left in hand

  As is clear from the results of Tables 1 to 3, Examples 1 to 13, which are within the scope of the present invention, are compared with Comparative Examples 1 to 9 that are outside the scope of the present invention. It was found to be excellent in mildness, refreshing rinse feeling, and less fragrance on the hands.

[Examples 14 to 20]
Next, according to the composition shown below, the cleaning composition was prepared according to a conventional method to prepare cleaning compositions for fingers of Examples 14 to 20. When these detergent compositions for fingers were evaluated in the same manner as in Examples 1 to 13, as in Examples 1 to 13, cleaning power against oil stains, mildness to skin, refreshing rinse feel, It turns out that it is excellent in the difficulty of remaining the scent on the hand.

[Example 14] Liquid detergent composition Lauryldimethylamine oxide * 3 2
Potassium laurate 4
Potassium myristate 4
POE (3) sodium lauryl ether sulfate * 8 0.5
POE (8) stearyl ether * 9 1
Alkyl acrylate copolymer emulsion * 10 2.5
Bentonite * 11 0.2
Hydroxypropyl methylcellulose * 12 0.2
Propylene glycol 15
Squalane 2
Silicone emulsion * 13 2
Edetate tetrasodium tetrahydrate 0.2
Melissa extract * 14 1
Darbilia extract * 15 1
Styrene polymer emulsion * 16 2
Dipotassium glycyrrhizinate 0.1
Isopropylmethylphenol 0.1
Fragrance 1 (Table 3) 0.3
Dibutylhydroxytoluene 0.01
Blue No. 403 appropriate amount Yellow No. 4 appropriate amount Potassium hydroxide Adjusted to pH 10 Purified water balance (A) / (B) 20/80
(A) + (B) 10
Total surfactant amount 11.5 (%)

[Example 15] Liquid detergent composition Lauryldimethylaminoacetic acid betaine * 1 2
Lauryldimethylamine oxide * 3 3
Palm oil fatty acid triethanolamine 6
Bentonite * 17 0.3
Sodium chloride 0.5
Alkyl acrylate copolymer emulsion * 6 1.5
Hexylene glycol 7
Cationized cellulose * 18 0.5
Ethanol 1
Methylparaben 0.2
Propylparaben 0.1
Oil-soluble licorice extract * 19 2
1-menthol 0.3
α-olefin oligomer 2
Silicone emulsion * 20 2
1,3-butylene glycol 5
Ethylene glycol distearate 1
Piroctone olamine * 21 0.1
Triclosan 0.05
Isopropylmethylphenol 0.1
Fragrance 5 (Table 3) 0.5
Dibutylhydroxytoluene 0.05
Blue No. 403 Appropriate amount Purified water balance (A) / (B) 45/55
(A) + (B) 11
Total surfactant amount 11 (%)

[Example 16] Liquid detergent composition Amidopropyl betaine laurate * 2 2.5
Potassium laurate 4
Potassium myristate 3
Potassium palmitate 0.5
N-lauroyl-potassium L-glutamate * 22 1
Bentonite * 23 0.1
Sorbitan sesquioleate * 24 1
Silicone emulsion * 25 2
Alkyl acrylate copolymer emulsion * 10 2
Dimethyldiallylammonium chloride / acrylamide copolymer * 26 3
Cationized guar gum * 27 0.5
Ethylene glycol distearate 2
Hexylene glycol 2
Rosemary extract * 28 1
Sodium benzoate 1
Hydroxyethane diphosphonic acid 0.1
Benzalkonium chloride 0.1
Isopropylmethylphenol 0.2
Fragrance 4 (Table 3) 0.4
Dibutylhydroxytoluene 0.01
Potassium hydroxide adjusted to pH 10 Purified water balance (A) / (B) 25/75
(A) + (B) 10
Total surfactant amount 12 (%)

[Example 17] Cleaner composition for non-aerosol foam discharge container Lauryldimethylamine oxide * 3 5
Potassium laurate 3
Potassium myristate 3
N-lauroyl-N-methyl-β-alanine potassium 1
Styrene polymer emulsion * 7 2
POE (11) stearyl ether * 4 1
Propylene glycol 15
Squalane 2
Silicone emulsion * 13 2
Edetate tetrasodium tetrahydrate 0.2
Dibutylhydroxytoluene 0.1
Chamomile extract * 29 1
Dipotassium glycyrrhizinate 0.1
Isopropylmethylphenol 0.1
Blue No. 403 proper amount Yellow No. 4 proper amount Fragrance 5 (Table 3) 0.4
Potassium hydroxide adjusted to pH 10 Purified water balance (A) / (B) 45/55
(A) + (B) 11
Total surfactant amount 13 (%)
Container: The same as the former pump container defined in Japanese Patent Application No. 2003-409537

[Example 18] Cleaner composition for non-aerosol foam discharge container Lauryldimethylaminoacetic acid betaine * 12
Lauric acid triethanolamine 6
Myristic acid triethanolamine 2
Alkyl (11, 13, 15) potassium phosphate 0.5
Polyoxyethylene glyceryl isostearate (15EO) * 30 2
Bentonite * 23 0.1
Dimethylpolysiloxane * 31 2
Isononyl isononanoate 2
Propylene glycol 5
Glycerin 5
Chamomile extract * 29 0.1
Isopropylmethylphenol 0.1
Benzalkonium chloride 0.2
Dipotassium glycyrrhizinate 0.1
Ellagic acid 0.1
Fragrance 1 (Table 3) 0.5
Red No. 401 Appropriate amount Triethanolamine Adjusted to pH 8 Purified water balance (A) / (B) 20/80
(A) + (B) 10
Total surfactant amount 12.5 (%)
Container: Squeeze foamer pump (Toyo Seikan Co., Ltd.)

[Example 19] Non-aerosol type foam discharge container cleaning composition Amidopropyl betaine laurate * 2 3
Lauryldimethylamine oxide * 3 1
Palm oil fatty acid potassium 6
Palm oil fatty acid sodium taurine * 32 1
POE (40) hydrogenated castor oil * 33 1
Sodium chloride 0.2
Propylene glycol 20
Vinyl acetate resin emulsion * 34 0.1
Rosemary extract * 28 1
Jojoba oil * 35 0.5
POE (2) Lauric acid monoethanolamide * 36 1
Methylparaben 0.3
Sodium benzoate 0.1
Edetate tetrasodium tetrahydrate 0.2
Hydroxyethane diphosphonic acid 0.1
Triclosan 0.1
Isopropylmethylphenol 0.1
Fragrance 5 (Table 3) 0.3
Purified water balance (A) / (B) 40/60
(A) + (B) 10
Total surfactant amount 13 (%)
Container: Mist dispenser (Z-35-ST (NT5), manufactured by Mitani Valve Co., Ltd.)

[Example 20] Liquid detergent composition Amidopropyl betaine laurate * 2 1
Lauryldimethylamine oside * 3 1
Potassium laurate 5
Potassium myristate 3
POE (11) stearyl ether 1
POE (2) Lauric acid monoethanolamide * 36 1
POE (2) Palm oil fatty acid monoethanolamide * 37 1
Propylene glycol 15
Alkyl acrylate copolymer emulsion * 6 4
Styrene polymer emulsion * 7 0.7
Dimethyldiallylammonium chloride / acrylamide copolymer * 26 1
Cationized cellulose * 18 0.5
Chamomile extract * 29 0.01
Sodium benzoate 0.1
Edetate tetrasodium tetrahydrate 0.2
Hydroxyethane diphosphonic acid 0.1
Benzalkonium chloride 0.1
Isopropylmethylphenol 0.1
Fragrance 5 (Table 3) 0.5
Potassium hydroxide pH adjusted to 10 Purified water balance (A) / (B) 20/80
(A) + (B) 10
Total surfactant amount 13 (%)

Various components (* 1 to * 37) used in Examples 1 to 20 and Comparative Examples 1 to 6 are as follows.
* 1: Obazoline LB-SF, manufactured by Toho Chemical Industry * 2: Enagicol L-30B, manufactured by Lion Chemical Co., Ltd. * 3: Aromox DM12DW (C), manufactured by Lion Chemical Co., Ltd. * 4: EMALEX 611, manufactured by Nippon Emulsion * 5: EMALEX OD-5 * 6: Leoir MS-200, manufactured by Lion Chemical Co., Ltd. * 7: Cybinol PE-3, manufactured by Saiden Chemical * 8: Sunnol LMT-1430 (manufactured by Lion Chemical)
* 9: EMALEX 608, manufactured by Nippon Emulsion Co., Ltd. * 10: Reoir MS-100, manufactured by Lion Chemical Co., Ltd. * 11: Kunipia G, manufactured by Kunimine Industries * 12: Metroles HPMC 60SH-4000, manufactured by Shin-Etsu Chemical Co., Ltd. * 13: BY22-055 , Manufactured by Toray Dow Corning, Silicone * 14: Melissa Extract BG-50, manufactured by Koei Kogyo * 15: Seaweed extract powder, manufactured by Alps Pharmaceutical Co., Ltd. * 16: Cybinol PE-21, manufactured by Seiden Chemical * 17: Bengel FW, * 18: Leo Guard GP, Lion Chemical * 19: Oil-soluble licorice extract P-T40N, Maruzen Pharmaceutical * 20: BY22-020, Toray Dow Corning Silicone * 21: Octopirox, Clariant * Made in Japan * 22: Amisoft LK-12, Ajinomoto * 23: Kunipia F, manufactured by Kunimine Industries * 24: EMALEX SPO-150, HLB5, manufactured by Nippon Emulsion * 25: BY22-060, manufactured by Toray Dow Corning Silicone Co., Ltd. * 26: Kayacrill Resin M-50, manufactured by Nippon Kayaku * 27 : Jaguar C14S, Sansei Co., Ltd. * 28: Rosemary water, manufactured by Maruzen Pharmaceutical Co., Ltd. * 29: Camellia Liquid, manufactured by Ichimaru Falcos * 30: EMALEX GWIS-115, HLB12, manufactured by Nippon Emulsion * 31: SH200-10000cs, Toray Made by Dow Corning Silicone * 32: HOSTAPON KTW NEW, made by Clariant Japan * 33: EMALEX HC-40, HLB12, made by Nippon Emulsion * 34: Made by Cybinol X-201-840E, Made by Seiden Chemical * 35: Refined jojoba oil, Kaoe Industry * 36: Amidette 2L-Y, manufactured by Kawaken Fine Chemical * 37: Amidette 2C, manufactured by Kawaken Fine Chemical

Claims (2)

  (A) Contains at least one selected from amphoteric surfactants and (B) fatty acid salt, and the content ratio [(A) / (B)] of the above (A) component and (B) component is mass. The ratio is 90/10 to 10/90, and the total content of all surfactants including the component (A) + the component (B) is less than 15% by mass. Cleaning composition.   The finger cleaning composition according to claim 1, further comprising a fragrance containing at least one component selected from hydrocarbons having 5 to 15 carbon atoms in an amount of 50% by mass or more of the fragrance composition. .