JP2006166904A - Method for producing tea extracted solution - Google Patents
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Abstract
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本発明は、茶抽出液の製造法に関する。 The present invention relates to a method for producing a tea extract.
烏龍茶や緑茶などを抽出する際に炭酸水素ナトリウムや炭酸ナトリウムを溶解した熱水でアルカリ抽出すると、風味が良好な抽出液が得られることが知られている(特許文献1〜3)。また、烏龍茶葉を籠体に入れて抽出した後、茶葉を洗浄することによってこくのある烏龍茶が得られることが知られている(特許文献4)。
しかしながら、これらの方法を用いても抽出液の風味は薄く、十分満足できるものではなく、特に容器詰茶飲料とした場合、深みのある風味が得られなかった。また、非重合体カテキン類の抽出効率も十分ではなかった。
However, even when these methods are used, the flavor of the extract is thin and not sufficiently satisfactory, and a deep flavor was not obtained particularly when it is used as a packaged tea beverage. Moreover, the extraction efficiency of non-polymer catechins was not sufficient.
本発明の目的は、非重合体カテキン類の抽出効率が高く、かつ、深みがあって雑味のない良好な風味の茶抽出液の製造法及び該製造法で製造した抽出液を用いた容器詰茶飲料を提供することにある。 An object of the present invention is to provide a method for producing a tea extract having a good flavor with high extraction efficiency of non-polymer catechins and being deep and free of taste, and a container using the extract produced by the production method It is to provide a stuffed tea beverage.
本発明者は、カラム式抽出機内に茶葉を仕込み、次いで炭酸水素ナトリウム又は炭酸ナトリウムを0.2〜19重量%溶解した水又は熱水を茶葉仕込み重量に対して0.1〜10倍重量を供給し、更に水又は熱水をカラム内に供給しながら抽出液を抜き出すと、非重合体カテキン類の抽出効率が高く、かつ深みがあって、雑味のない良好な風味を持つ茶抽出液が得られることを見出した。 The present inventor charged tea leaves in a column type extractor, and then added water or hot water in which sodium hydrogen carbonate or sodium carbonate was dissolved in an amount of 0.2 to 19% by weight to 0.1 to 10 times the weight of the tea leaves charged. When the extract is extracted while supplying water and hot water into the column, the tea extract with high non-polymer catechins extraction efficiency, depth, and good taste without miscellaneous taste It was found that can be obtained.
すなわち、本発明は、カラム式抽出機内に茶葉を仕込み、次いで炭酸水素ナトリウム又は炭酸ナトリウムを0.2〜19重量%溶解した水又は熱水を茶葉仕込み重量に対して0.1〜10倍重量を供給し、更に水又は熱水をカラム内に供給しながら抽出液を抜き出す茶抽出液の製造法及び本発明の製造法で製造した茶抽出液を容器に充填した容器詰茶飲料を提供するものである。 That is, in the present invention, tea leaves are charged into a column type extractor, and then water or hot water in which 0.2 to 19% by weight of sodium hydrogen carbonate or sodium carbonate is dissolved is 0.1 to 10 times the weight of the tea leaves charged. A tea extract for extracting the extract while further supplying water or hot water into the column, and a packaged tea beverage filled with the tea extract produced by the production method of the present invention Is.
本発明の茶抽出液の製造法は、非重合体カテキン類の抽出効率が高く、かつ、深みがあって、雑味のない風味が良好な、透明な茶抽出液が得られ、特に容器詰茶飲料とすることにより深みがあって、雑味がなく風味がよい茶飲料が得られる。 The method for producing a tea extract of the present invention provides a transparent tea extract having a high extraction efficiency of non-polymer catechins and a deep, good taste with no miscellaneous taste. By making a tea beverage, there is a depth, and a tea beverage having a good taste and no miscellaneous taste can be obtained.
本発明で非重合体カテキン類とは、カテキン、ガロカテキン、カテキンガレート、ガロカテキンガレート等の非エピ体カテキン類及びエピカテキン、エピガロカテキン、エピカテキンガレート、エピガロカテキンガレート等のエピ体カテキン類をあわせての総称を指す。 Non-polymer catechins in the present invention are non-epimeric catechins such as catechin, gallocatechin, catechin gallate, and gallocatechin gallate, and epicatechins such as epicatechin, epigallocatechin, epicatechin gallate, and epigallocatechin gallate. It is a generic name that includes
本発明に使用する茶葉としては、Camellia属、例えばC.sinensis及びC.assaimica、やぶきた種又はそれらの雑種から得られる茶葉から製茶された、煎茶、玉露、てん茶等の緑茶類や;総称して烏龍茶と呼ばれる鉄観音、色種、黄金桂、武夷岩茶等の半発酵茶;紅茶と呼ばれるダージリン、アッサム、スリランカ等の発酵茶の茶葉が挙げられる。茶葉としては、特に烏龍茶葉が、得られる烏龍茶の風味の向上効果が高く好ましい。 The tea leaves used in the present invention include Camellia genus such as C.I. sinensis and C.I. green teas such as Sencha, Gyokuro, Tencha, etc. made from tea leaves obtained from assaimica, Yabukita seeds or their hybrids; Semi-fermented tea; tea leaves of fermented tea such as Darjeeling, Assam, Sri Lanka and so on called black tea. As the tea leaves, oolong tea leaves are particularly preferable because of the high effect of improving the flavor of the obtained oolong tea.
本発明の茶葉からの茶の抽出は、カラム式の抽出機内に茶葉、又は茶葉と水もしくは熱水を仕込み、次いで炭酸水素ナトリウム又は炭酸ナトリウムを0.2〜19重量%溶解した水又は熱水を茶葉仕込み重量に対して0.1〜10倍重量供給し、水又は熱水をカラム内に供給しながら抽出液を抜き出すことにより行われる。 Extraction of tea from tea leaves of the present invention is carried out by adding tea leaves, tea leaves and water or hot water in a column type extractor, and then water or hot water in which 0.2 to 19% by weight of sodium hydrogen carbonate or sodium carbonate is dissolved. Is carried out by extracting 0.1 to 10 times the weight of the tea leaves charged and extracting the extract while supplying water or hot water into the column.
カラム式の抽出機としては、カラム上部から水等を供給するタイプ、カラム下部から水等を供給するタイプが利用できる。好ましい抽出機としては、図1に示すように、カラム内部に金網を備え、上部に水等の供給口、下部に水等の供給口及び抜き出し口を有するものが好ましい。例えば三友機器(株)製コーヒー抽出機SK−EXT10、SK-EXT−15や(株)イズミフードマシナリ製多機能抽出装置TEX1512、TEX2015等が使用できる。茶葉を保持する金網(メッシュ)は、フラット、円錐状、角錐状等の形状の物を用いることができる。 As the column type extractor, a type that supplies water and the like from the upper part of the column and a type that supplies water and the like from the lower part of the column can be used. As a preferred extractor, as shown in FIG. 1, it is preferable to provide a wire mesh inside the column, and to have a supply port for water or the like in the upper part and a supply port for water or the like in the lower part and an extraction port. For example, Mitsui Equipment Co., Ltd. coffee extractors SK-EXT10, SK-EXT-15, Izumi Food Machinery Co., Ltd. multifunction extraction devices TEX1512, TEX2015, etc. can be used. As the wire mesh (mesh) for holding tea leaves, a flat, conical, pyramidal or other shape can be used.
まず、金網(メッシュ)を備えたカラム式抽出機に茶葉を仕込み、平らにならす。 First, tea leaves are charged into a column type extractor equipped with a mesh (mesh) and leveled.
茶葉をカラム式抽出機に仕込んだ際、カラム内部に水又は熱水を供給し、メッシュ下の空気溜りをなくしておくと抽出が安定に進行し好ましい。特に、カラム下部から水又は熱水をカラム内に上昇流で供給すると、茶葉が上方に向かって膨潤していくため、圧密化することがなく好ましい。供給する水又は熱水の温度は、0〜100℃、更に3〜98℃、特に5〜95℃であるのが好ましい。この水又は熱水は、カラム内の茶葉仕込み重量(a)(kg)とメッシュより上部の水又は熱水体積(b)(L)の比(b)/(a)が0〜15、好ましくは2〜12、さらに好ましくは3〜10になるように供給する。この比率の範囲であると茶葉層が十分に膨潤し、適度の抽出液の抜き出し速度が得られ、非重合体カテキン類の抽出効率もよい。メッシュより上部の水又は熱水体積(b)(L)は、カラムに供給した全水又は熱水体積からカラム内のメッシュより下の容積を引いて求められる。 When the tea leaves are charged into the column type extractor, it is preferable to supply water or hot water to the inside of the column and eliminate the air pool under the mesh, so that the extraction proceeds stably. In particular, it is preferable to supply water or hot water from the lower part of the column in an upward flow into the column, because the tea leaves swell upward, and thus do not become compacted. The temperature of the supplied water or hot water is preferably 0 to 100 ° C, more preferably 3 to 98 ° C, and particularly preferably 5 to 95 ° C. In this water or hot water, the ratio (b) / (a) of the tea leaf charge weight (a) (kg) in the column and the water or hot water volume (b) (L) above the mesh is 0-15, preferably Is supplied so as to be 2 to 12, more preferably 3 to 10. When the ratio is within this range, the tea leaf layer swells sufficiently, a moderate extraction liquid extraction rate is obtained, and the extraction efficiency of non-polymer catechins is good. The water or hot water volume (b) (L) above the mesh is obtained by subtracting the volume below the mesh in the column from the total water or hot water volume supplied to the column.
水又は熱水供給時の上昇流体の線速度(=流量/カラム断面積)は10〜120mm/min、好ましくは30〜100mm/min、さらに好ましくは40〜90mm/minがよい。速すぎると茶葉の膨潤が不均一になる。遅すぎると操作時間が長くなって生産性が低くなる。 The linear velocity (= flow rate / column cross-sectional area) of the rising fluid when supplying water or hot water is 10 to 120 mm / min, preferably 30 to 100 mm / min, and more preferably 40 to 90 mm / min. If it is too fast, the tea leaves will swell unevenly. If it is too slow, the operation time becomes longer and the productivity becomes lower.
供給する水又は熱水には、炭酸水素ナトリウム又は炭酸ナトリウムを添加してもよい。また、アスコルビン酸ナトリウム等の有機酸又は有機酸塩類を添加してもよい。添加量は、水又は熱水中に0.2重量%以下、更に0.001〜0.15重量%であるのが好ましい。 Sodium hydrogen carbonate or sodium carbonate may be added to the supplied water or hot water. Moreover, you may add organic acids or organic acid salts, such as sodium ascorbate. The addition amount is preferably 0.2% by weight or less, more preferably 0.001 to 0.15% by weight in water or hot water.
次いで、カラム式抽出機には、炭酸水素ナトリウム又は炭酸ナトリウムを溶解した水又は熱水溶液が供給される。炭酸水素ナトリウム又は炭酸ナトリウム熱水溶液は、カラム内に仕込んだ茶葉と水又は熱水が接触を開始してから0.1〜30分、更に0.3〜25分後にカラム上部から供給するのが好ましい。また、炭酸水素ナトリウム又は炭酸ナトリウム熱水溶液は0.1〜5分で供給するのが好ましい。炭酸水素ナトリウム又は炭酸ナトリウム熱水溶液の濃度は、0.2〜19重量%であるが、更に0.3〜15重量%、特に0.4〜10重量%であるのが、得られる茶抽出液の風味の点で好ましい。炭酸水素ナトリウム又は炭酸ナトリウム熱水溶液の温度は、50〜100℃、更に60〜98℃、特に65〜95℃であるのが、風味の点で好ましい。炭酸水素ナトリウム又は炭酸ナトリウム水又は熱水溶液の供給量は、茶葉仕込み重量の0.1〜10倍重量、更に0.2〜8倍重量、特に0.5〜5倍重量供給するのが好ましい。供給は、カラム上方からシャワーするのが好ましい。
炭酸ナトリウムを使用する場合は、水溶液のpHを、塩酸、クエン酸等の無機酸又は有機酸で7〜10、特に好ましくは8〜9に調整して使用するのが好ましい。
Next, water or hot aqueous solution in which sodium bicarbonate or sodium carbonate is dissolved is supplied to the column type extractor. Sodium hydrogen carbonate or a sodium carbonate hot water solution is supplied from the top of the column 0.1 to 30 minutes after the tea leaves and water or hot water charged in the column start contact, and further 0.3 to 25 minutes later. preferable. Moreover, it is preferable to supply sodium hydrogencarbonate or a sodium carbonate hot aqueous solution in 0.1 to 5 minutes. The concentration of the sodium hydrogen carbonate or hot sodium carbonate aqueous solution is 0.2 to 19% by weight, but 0.3 to 15% by weight, particularly 0.4 to 10% by weight, is obtained tea extract. It is preferable in terms of flavor. The temperature of the sodium hydrogen carbonate or the hot sodium carbonate aqueous solution is preferably 50 to 100 ° C, more preferably 60 to 98 ° C, and particularly preferably 65 to 95 ° C in terms of flavor. The amount of sodium hydrogen carbonate, sodium carbonate aqueous solution or hot water solution to be supplied is preferably 0.1 to 10 times, more preferably 0.2 to 8 times, particularly 0.5 to 5 times the weight of tea leaves. The supply is preferably showered from above the column.
When using sodium carbonate, it is preferable to adjust the pH of the aqueous solution to 7 to 10, particularly preferably 8 to 9, with an inorganic or organic acid such as hydrochloric acid or citric acid.
次いで、カラム式抽出機の上部から水又は熱水を供給しながら、カラム下部から茶抽出液を抜き出す。抽出液の抜き出しは、前工程の炭酸水素ナトリウム又は炭酸ナトリウム熱水溶液の供給と同時に開始してもよいが、炭酸水素ナトリウム又は炭酸ナトリウム水又は熱水溶液を供給終了後、0.5〜2.8分後、特に1.0〜2.5分後に水又は熱水の供給と抽出液の抜出を開始するのが、風味の点で好ましい。水又は熱水の温度は、0〜100℃、更に3〜98℃、特に5〜95℃であるのが風味の点で好ましい。水又は熱水には、アスコルビン酸ナトリウム等の有機酸又は有機酸塩類を添加してもよい。カラム上部から水又は熱水を供給するにはシャワーを使用するのが好ましい。 Next, the tea extract is extracted from the lower part of the column while supplying water or hot water from the upper part of the column type extractor. Extraction of the extract may be started at the same time as the supply of the sodium hydrogen carbonate or aqueous sodium carbonate solution in the previous step, but after the completion of the supply of the sodium hydrogen carbonate, sodium carbonate aqueous solution or the hot aqueous solution, 0.5 to 2.8. It is preferable from the viewpoint of flavor that the supply of water or hot water and the extraction of the extract are started after 1.0 minute, especially after 1.0 to 2.5 minutes. The temperature of water or hot water is preferably 0 to 100 ° C., more preferably 3 to 98 ° C., and particularly preferably 5 to 95 ° C. in terms of flavor. You may add organic acids or organic acid salts, such as sodium ascorbate, to water or hot water. It is preferable to use a shower to supply water or hot water from the top of the column.
カラム下部からの茶抽出液の抜き出し速度は、カラム内の茶葉仕込み重量(a)(kg)とメッシュより上部の水又は熱水体積(b)(L)の比(b)/(a)が0〜15、更に2〜12、特に3〜10の範囲内になるように、カラム上部からの水又は熱水の供給量及び抽出液の抜き出し速度を調整するのが好ましい。この茶抽出液の抜き出し比率範囲内であると、茶葉層が圧密化して抽出液抜き出し速度が低下することなく、また閉塞してしまうこともなく、安定な抽出を行うことができ、更に茶葉が不必要に膨潤しすぎず、非重合体カテキンの抽出効率が高い茶抽出液が得られる。 The extraction speed of the tea extract from the lower part of the column is determined by the ratio (b) / (a) of the tea leaf charge weight (a) (kg) in the column and the water or hot water volume (b) (L) above the mesh. It is preferable to adjust the supply amount of water or hot water from the top of the column and the extraction liquid extraction rate so that it falls within the range of 0 to 15, more preferably 2 to 12, particularly 3 to 10. If the tea extraction liquid is within the extraction ratio range, the tea leaf layer is compacted and the extraction liquid extraction speed does not decrease and does not become clogged, and stable extraction can be performed. A tea extract that does not swell unnecessarily and has high extraction efficiency of non-polymer catechins can be obtained.
このような製造プロセスをとることにより、茶葉層を圧密化せずに均一に膨潤させることができ、茶葉による閉塞もなく、安定した通液抽出操作で、非重合体カテキン類を抽出効率よく抽出し、深みのある、透明で雑味のない風味のよい茶抽出液を製造することができる。 By taking such a manufacturing process, the tea leaf layer can be uniformly swelled without being consolidated, and non-polymer catechins can be extracted efficiently by a stable liquid extraction operation without clogging with tea leaves. In addition, it is possible to produce a deep, transparent and tasteless tea extract.
本発明の茶抽出液の製造法における抽出倍率(カラムから出た茶抽出液重量/茶葉の仕込み重量)は、大きすぎると非重合体カテキン類の抽出率は高まるが、得られる茶抽出液中の非重合体カテキン類濃度は低くなり、一方小さすぎると得られる茶抽出液中の非重合体カテキン類濃度は高くなるが、非重合体カテキン類の抽出率は低い。この抽出倍率としては、非重合体カテキン類を高濃度に含有する風味の良好な茶抽出液を得る観点から、茶葉仕込み重量に対して10〜100倍重量、好ましくは15〜80倍重量、特に20〜65倍重量であるのが好ましい。 If the extraction ratio (the weight of the tea extract from the column / the charged weight of the tea leaves) in the method for producing the tea extract of the present invention is too large, the extraction rate of non-polymer catechins will increase, but in the resulting tea extract The concentration of the non-polymer catechins in the tea extract obtained when the concentration of the non-polymer catechins is low, while the concentration of the non-polymer catechins in the tea extract obtained is high, but the extraction rate of the non-polymer catechins is low. As this extraction ratio, from the viewpoint of obtaining a tea extract having a good flavor containing non-polymer catechins at a high concentration, it is 10 to 100 times by weight, preferably 15 to 80 times by weight, especially the tea leaf preparation weight. The weight is preferably 20 to 65 times.
本発明方法における抽出処理時間は、非重合体カテキン類の濃度により決定されるが、6〜100分、更に10〜60分、特に20〜50分が好ましい。 The extraction treatment time in the method of the present invention is determined by the concentration of non-polymer catechins, but is preferably 6 to 100 minutes, more preferably 10 to 60 minutes, and particularly preferably 20 to 50 minutes.
本発明方法においては、非重合体カテキン類濃度0.05〜0.7重量%の茶抽出液が得られる。非重合体カテキン類濃度が0.05重量%未満では、高濃度カテキン含有飲料の製造に利用できない。また、非重合体カテキン類濃度0.7重量%を超えると、低濃度に希釈しても風味が低下する。 In the method of the present invention, a tea extract having a non-polymer catechin concentration of 0.05 to 0.7% by weight is obtained. When the non-polymer catechin concentration is less than 0.05% by weight, it cannot be used for the production of a beverage containing a high concentration catechin. Moreover, if the non-polymer catechin concentration exceeds 0.7% by weight, the flavor is lowered even when diluted to a low concentration.
このようにして得られた茶抽出液は、0.05〜0.7重量%という高濃度の非重合体カテキン類を含有し、かつ、深みがあり、雑味がなく風味がよいので、このまま又は希釈することにより容器詰茶飲料とすることができる。また、非重合体カテキン類を加えて濃度調整して容器詰茶飲料としてもよい。カテキン濃度の調整方法としては、前記茶抽出液と茶抽出物の濃縮物とを併用することができる。茶抽出物の濃縮物を溶解する媒体は、水、炭酸水、市販されているレベルのカテキン類を含有する茶類の抽出液等が挙げられる。また、ここでいう茶抽出物の濃縮物とは、茶葉から熱水又は水溶性有機溶媒により抽出された抽出物を濃縮したものであって、特開昭59−219384号公報、特開平4−20589号公報、特開平5−260907号公報、特開平5−306279号公報等に詳細に例示されている方法で調製したものをいう。市販の三井農林(株)「ポリフェノン」、伊藤園(株)「テアフラン」、太陽化学(株)「サンフェノン」、サントリー(株)「サンウーロン」等が挙げられる。そのほか、カテキンは他の原料起源のもの、カラム精製品及び化学合成品でも使用できる。 The tea extract thus obtained contains a high concentration of non-polymer catechins of 0.05 to 0.7% by weight, and is deep, free from miscellaneous taste, and has a good flavor. Or it can be set as a container-packed tea drink by diluting. In addition, non-polymer catechins may be added to adjust the concentration to provide a packaged tea beverage. As a method for adjusting the catechin concentration, the tea extract and the tea extract concentrate can be used in combination. Examples of the medium for dissolving the concentrate of tea extract include water, carbonated water, tea extracts containing commercially available levels of catechins, and the like. The concentrate of the tea extract referred to here is a concentrate obtained by concentrating an extract extracted from tea leaves with hot water or a water-soluble organic solvent. It is prepared by the method exemplified in detail in No. 20589, JP-A-5-260907, JP-A-5-306279, and the like. Commercially available Mitsui Norin Co., Ltd. “Polyphenone”, ITO EN Co., Ltd. “Theafranc”, Taiyo Kagaku Co., Ltd. “Sunphenon”, Suntory Co., Ltd. “Sun Oolong” and the like. In addition, catechins can be used from other raw materials, column purified products, and chemically synthesized products.
容器詰茶飲料の非重合体カテキン類濃度を0.05〜0.5重量%、好ましくは0.06〜0.5重量%、更に0.08〜0.5重量%、更に好ましくは0.092〜0.4重量%、殊更に好ましくは0.11〜0.3重量%、特に好ましくは0.12〜0.3重量%に調整すると、深みがあり、雑味がなく良好な風味の容器詰茶飲料が得られるの点で好ましい。 The non-polymer catechin concentration of the packaged tea beverage is 0.05 to 0.5% by weight, preferably 0.06 to 0.5% by weight, more preferably 0.08 to 0.5% by weight, and still more preferably 0.8. When adjusted to 092 to 0.4% by weight, more preferably 0.11 to 0.3% by weight, and particularly preferably 0.12 to 0.3% by weight, the depth is deep, there is no miscellaneous taste, and the flavor is good. This is preferable in that a packaged tea beverage can be obtained.
また、本発明の容器詰茶飲料中のカテキンガレート、エピカテキンガレート、ガロカテキンガレート及びエピガロカテキンガレートからなる総称ガレート体の全非重合体カテキン類中での割合が35〜100重量%、更に35〜98重量%、特に35〜95重量%の方が、非重合体カテキン類の生理効果の有効性上好ましい。 Further, the ratio of the generic gallate body consisting of catechin gallate, epicatechin gallate, gallocatechin gallate and epigallocatechin gallate in the non-categorized catechins in the packaged tea beverage of the present invention is 35 to 100% by weight, The amount of 35 to 98% by weight, particularly 35 to 95% by weight, is preferable in view of the effectiveness of physiological effects of non-polymer catechins.
本発明の容器詰茶飲料は、苦渋味抑制剤を配合すると飲用しやすくなり好ましい。用いる苦渋味抑制剤としては、サイクロデキストリンが好ましい。サイクロデキストリンとしては、α−、β−、γ−サイクロデキストリン及び分岐α−、β−、γ−サイクロデキストリンが使用できる。サイクロデキストリンは飲料中に0.005〜0.6重量%、好ましくは0.01〜0.4重量%含有するのがよい。本発明の容器詰茶飲料には、茶由来の成分にあわせて、処方上添加してよい成分として、酸化防止剤、香料、各種エステル類、有機酸類、有機酸塩類、無機酸類、無機酸塩類、無機塩類、色素類、乳化剤、保存料、調味料、甘味料、酸味料、ガム、油、ビタミン、アミノ酸、果汁エキス類、野菜エキス類、花蜜エキス類、pH調整剤、品質安定剤等の添加剤を単独、あるいは併用して配合してもよい。 The packaged tea beverage of the present invention is preferably mixed with a bitter and astringent taste suppressant because it is easy to drink. As the bitter and astringent taste inhibitor to be used, cyclodextrin is preferable. As the cyclodextrin, α-, β-, γ-cyclodextrin and branched α-, β-, γ-cyclodextrin can be used. The cyclodextrin is contained in the beverage in an amount of 0.005 to 0.6% by weight, preferably 0.01 to 0.4% by weight. In the container-packed tea beverage of the present invention, antioxidants, fragrances, various esters, organic acids, organic acid salts, inorganic acids, inorganic acid salts as components that may be added in accordance with the ingredients derived from tea , Inorganic salts, pigments, emulsifiers, preservatives, seasonings, sweeteners, acidulants, gums, oils, vitamins, amino acids, fruit juice extracts, vegetable extracts, nectar extracts, pH adjusters, quality stabilizers, etc. You may mix | blend an additive individually or in combination.
本発明の容器詰茶飲料のpHは、25℃で3〜7、好ましくは4〜7、特に5〜7とするのが味及びカテキン類の安定性の点で好ましい。 The pH of the packaged tea beverage of the present invention is preferably 3 to 7, preferably 4 to 7, particularly 5 to 7 at 25 ° C. from the viewpoint of taste and catechin stability.
本発明の容器詰茶飲料においても、カテキンの生理効果を得るための一日当りの必要摂取量を確保する意味からも、本発明の容器詰飲料1本(350〜500mL)当り300mg以上、好ましくは450mg以上、更に好ましくは500mg以上の配合量であるものがよい。 In the case of the packaged tea beverage of the present invention, 300 mg or more per one packaged beverage (350 to 500 mL) of the present invention, preferably from the viewpoint of securing the necessary daily intake for obtaining the physiological effect of catechin, The amount is 450 mg or more, more preferably 500 mg or more.
本発明の容器詰茶飲料に使用される容器は、一般の飲料と同様にポリエチレンテレフタレートを主成分とする成形容器(いわゆるPETボトル)、金属缶、金属箔やプラスチックフィルムと複合された紙容器、瓶等の通常の形態で提供することができる。 The container used for the container-packed tea beverage of the present invention is a molded container mainly composed of polyethylene terephthalate (so-called PET bottle), a metal can, a paper container combined with a metal foil or a plastic film, like a general beverage, It can be provided in a normal form such as a bottle.
本発明の容器詰茶飲料は、例えば、金属缶のように容器に充填後、加熱殺菌できる場合にあっては食品衛生法に定められた殺菌条件で製造されるが、PETボトル、紙容器のようにレトルト殺菌できないものについては、あらかじめ上記と同等の殺菌条件、例えばプレート式熱交換器等で高温短時間殺菌後、一定の温度迄冷却して容器に充填する等の方法が採用される。また無菌下で、充填された容器に別の成分を配合して充填してもよい。更に、酸性下で加熱殺菌後、無菌下でpHを中性に戻すことや、中性下で加熱殺菌後、無菌下でpHを酸性に戻す等の操作も可能である。 The container-packed tea beverage of the present invention is manufactured under the sterilization conditions stipulated in the Food Sanitation Law if it can be sterilized by heating after filling the container like a metal can. For those that cannot be sterilized by retort, the same sterilization conditions as described above, for example, a high-temperature and short-time sterilization using a plate heat exchanger or the like, followed by cooling to a certain temperature and filling into a container are adopted. Moreover, you may mix | blend another component with the filled container under aseptic conditions. Furthermore, after sterilization by heating under acidic conditions, the pH can be returned to neutrality under aseptic conditions, or after sterilization by heating under neutral conditions, the pH can be returned to acidic conditions under aseptic conditions.
実施例1
80メッシュの金網を備えた内径97mmのカラム式抽出機(図1)に烏龍茶葉281gを仕込み、高さが均一になるように茶葉上面を平らにした。イオン交換水(90℃)をカラム下部から供給し、烏龍茶葉仕込み重量(a)(kg)とメッシュより上部の熱水体積(b)(L)の比(b)/(a)が5.3になったときに給湯を停止した。0.40重量%炭酸水素ナトリウムイオン交換水溶液(70℃)を、カラム上方からシャワーして供給すると同時に、抽出液をカラム下方から抜き出した。烏龍茶葉仕込み重量に対して5倍重量を供給した後、シャワーをイオン交換水(90℃)に変えて供給しながら、ひき続き抽出液をカラム下方から抜き出した。この間(b)/(a)比が5.3になるように抜出速度を調整した。抜き出した抽出液の重量が仕込み烏龍茶葉重量の50倍になったところで終了し、烏龍茶抽出液を均一に混合して分析を行った。
Example 1
281 g of Oolong tea leaves were charged into a column type extractor (FIG. 1) having an inner diameter of 97 mm equipped with an 80 mesh wire netting, and the top surface of the tea leaves was flattened so that the height was uniform. Ion-exchanged water (90 ° C.) is supplied from the bottom of the column, and the ratio (b) / (a) of the oolong tea leaf charge weight (a) (kg) to the hot water volume (b) (L) above the mesh is 5. When it reached 3, the hot water supply was stopped. A 0.40% by weight sodium bicarbonate ion exchange aqueous solution (70 ° C.) was supplied by showering from above the column, and at the same time, the extract was withdrawn from the bottom of the column. After supplying 5 times the weight of the oolong tea leaves, the extract was continuously extracted from the bottom of the column while supplying the shower with ion-exchanged water (90 ° C.). During this time, the extraction speed was adjusted so that the ratio (b) / (a) was 5.3. The test was terminated when the weight of the extracted extract became 50 times the weight of the prepared oolong tea leaves, and the oolong tea extract was uniformly mixed for analysis.
実施例2
実施例1と同様にカラム内に烏龍茶葉を仕込んだ。イオン交換水(90℃)をカラム下部から供給し、比(b)/(a)が5.3になったときに給湯を停止した。1.96重量%炭酸水素ナトリウムイオン交換水溶液(72℃)をカラム上方からシャワーして供給した。烏龍茶葉仕込み重量に対して1倍重量を供給した後、1分間保持し、次いでカラム上方からイオン交換水(90℃)をシャワーして供給しながら、抽出液をカラム下方から抜き出した。この間(b)/(a)比が5.3になるように抜出速度を調整した。抜き出した抽出液の重量が仕込み烏龍茶葉重量の50倍になったところで終了し、烏龍茶抽出液を均一に混合して分析を行った。
Example 2
In the same manner as in Example 1, oolong tea leaves were charged into the column. Ion exchange water (90 ° C.) was supplied from the bottom of the column, and the hot water supply was stopped when the ratio (b) / (a) reached 5.3. 1.96 wt% sodium bicarbonate ion exchange aqueous solution (72 ° C.) was supplied by showering from above the column. After supplying 1 times the weight of the oolong tea leaves, the extract was extracted from the bottom of the column while maintaining for 1 minute and then showering and supplying ion-exchanged water (90 ° C.) from the top of the column. During this time, the extraction speed was adjusted so that the ratio (b) / (a) was 5.3. The test was terminated when the weight of the extracted extract became 50 times the weight of the prepared oolong tea leaves, and the oolong tea extract was uniformly mixed for analysis.
実施例3
実施例2と同様の操作を行った。ただし炭酸水素ナトリウムを90℃のイオン交換水に溶解した後、温度を25℃に調整してシャワーした。
Example 3
The same operation as in Example 2 was performed. However, after sodium bicarbonate was dissolved in 90 ° C. ion exchange water, the temperature was adjusted to 25 ° C. and showered.
比較例1
実施例1と同様にカラム内に烏龍茶葉を仕込んだ。0.04重量%炭酸水素ナトリウムイオン交換水(90℃)をカラム下部から供給し、比(b)/(a)が4.4になったときに供給を停止した。次いで同濃度の炭酸水素ナトリウムイオン交換水溶液(90℃)をカラム上方からシャワーして供給すると同時に、抽出液をカラム下方から抜き出した。この間(b)/(a)比が4.4になるように抜出速度を調整した。抜き出した烏龍茶抽出液の重量が仕込み茶葉重量の50倍になったところで終了し、烏龍茶抽出液を均一に混合して分析を行った。
Comparative Example 1
In the same manner as in Example 1, oolong tea leaves were charged into the column. 0.04 wt% sodium hydrogen carbonate ion exchange water (90 ° C) was supplied from the bottom of the column, and the supply was stopped when the ratio (b) / (a) reached 4.4. Next, a sodium hydrogen carbonate ion exchange aqueous solution (90 ° C.) having the same concentration was supplied by showering from above the column, and at the same time, the extract was extracted from the bottom of the column. During this time, the extraction speed was adjusted so that the ratio (b) / (a) was 4.4. The test was terminated when the weight of the extracted oolong tea extract was 50 times the weight of the charged tea leaves, and the oolong tea extract was uniformly mixed for analysis.
比較例2
実施例1と同様にカラム内に烏龍茶葉を仕込んだ。イオン交換水(90℃)をカラム下部から供給し、比(b)/(a)が4.4になったときに給湯を停止した。0.10重量%炭酸水素ナトリウムイオン交換水溶液(76℃)をカラム上方からシャワーして供給すると同時に、抽出液をカラム下方から抜き出した。烏龍茶葉仕込み重量に対して20倍重量を供給した後、カラム上方からイオン交換水(90℃)をシャワーして供給しながら、ひき続き抽出液をカラム下方から抜き出した。この間(b)/(a)比が4.4になるように抜出速度を調整した。抜き出した抽出液の重量が仕込み茶葉重量の50倍になったところで終了し、烏龍茶抽出液を均一に混合して分析を行った。
Comparative Example 2
In the same manner as in Example 1, oolong tea leaves were charged into the column. Ion exchange water (90 ° C.) was supplied from the lower part of the column, and hot water supply was stopped when the ratio (b) / (a) reached 4.4. A 0.10 wt% aqueous solution of sodium bicarbonate ion exchange (76 ° C.) was supplied by showering from above the column, and at the same time, the extract was withdrawn from the bottom of the column. After supplying 20 times the weight of the oolong tea leaves, the extract was continuously extracted from below the column while supplying ion-exchanged water (90 ° C.) by showering from above the column. During this time, the extraction speed was adjusted so that the ratio (b) / (a) was 4.4. The test was terminated when the weight of the extracted extract was 50 times the weight of the charged tea leaves, and the oolong tea extract was uniformly mixed for analysis.
比較例3
実施例1と同様にカラム内に烏龍茶葉を仕込んだ。イオン交換水(90℃)をカラム下部から供給し、比(b)/(a)が4.4になったときに給湯を停止した。次いでイオン交換水(90℃)をカラム上方からシャワーして供給すると同時に、抽出液をカラム下方から抜き出した。抜き出した抽出液の重量が仕込み茶葉重量の40倍になったところで供給を止めた。次いで1.96重量%炭酸水素ナトリウムイオン交換水溶液(70℃)をカラム上方からシャワーして供給しながら、抽出液をカラム下方から抜き出した。烏龍茶茶葉仕込み重量に対して1倍重量を供給した後、カラム上方から再びイオン交換水(90℃)をシャワーして供給しながら、ひき続き抽出液をカラム下方から抜き出した。抜き出した抽出液の重量が仕込み烏龍茶葉重量の50倍になったところで終了し、烏龍茶抽出液を均一に混合して分析を行った。
Comparative Example 3
In the same manner as in Example 1, oolong tea leaves were charged into the column. Ion exchange water (90 ° C.) was supplied from the lower part of the column, and hot water supply was stopped when the ratio (b) / (a) reached 4.4. Subsequently, ion-exchanged water (90 ° C.) was supplied by showering from above the column, and at the same time, the extract was extracted from below the column. The supply was stopped when the weight of the extracted extract became 40 times the weight of the charged tea leaves. Next, the extract was extracted from the bottom of the column while supplying 1.96 wt% aqueous sodium bicarbonate ion exchange solution (70 ° C.) by showering from the top of the column. After supplying 1 times the weight of the oolong tea leaves, the extract was continuously extracted from the bottom of the column while ion-exchanged water (90 ° C.) was showered again from the top. The test was terminated when the weight of the extracted extract became 50 times the weight of the prepared oolong tea leaves, and the oolong tea extract was uniformly mixed for analysis.
以上の烏龍茶抽出液の製造操作条件、抽出液中の非重合体カテキン類濃度及び風味評価結果を表1に示す。 Table 1 shows the manufacturing operation conditions of the above oolong tea extract, the concentration of non-polymer catechins in the extract, and the flavor evaluation results.
風味の評価は、次の方法で行った。
風味評価
烏龍茶抽出液を非重合体カテキン類濃度が0.019重量%になるようにイオン交換水で希釈し、4名の専門パネラーが次の評価基準で風味を評価した。なお、表1にはその平均評価結果を示す。
(評価基準)
◎:発酵感と深みが豊富で、非常に良好。
〇:発酵感と深みがあり、良好。
△:発酵感と深みが乏しく薄く感じられ、やや不良。
×:発酵感がなくアロマも乏しく薄く感じられ、不良。
Evaluation of flavor was performed by the following method.
Flavor Evaluation Oolong tea extract was diluted with ion-exchanged water so that the concentration of non-polymer catechins was 0.019% by weight, and four expert panelists evaluated the flavor according to the following evaluation criteria. Table 1 shows the average evaluation results.
(Evaluation criteria)
A: Rich in fermentation and depth, very good.
○: Fermentation and depth are good.
(Triangle | delta): A feeling of fermentation and a depth are scarce, and it feels thin, and is somewhat inferior.
X: There is no fermentation feeling and the aroma is poor and it is felt thin.
本発明の茶抽出液の製造法で調製した烏龍茶抽出液は、非重合体カテキン濃度が高く、発酵感と深みがある風味で良好であった。一方、比較例は烏龍茶抽出液中の非重合体カテキン類濃度が高かったが、発酵感及び深みの風味が劣っていた。 The oolong tea extract prepared by the method for producing a tea extract of the present invention had a high non-polymer catechin concentration, and was good in a flavor with a feeling of fermentation and depth. On the other hand, the comparative example had a high concentration of non-polymer catechins in the oolong tea extract, but the fermentation feeling and deep flavor were inferior.
実施例4
実施例1〜3で製造した烏龍茶抽出液を夫々1600g計量し、βシクロデキストリン28gおよびアスコルビン酸ナトリウム5.6gおよび炭酸水素ナトリウム0.4gを配合し、市販茶抽出物の精製濃縮物を添加した後イオン交換水で全体を8000gにした。茶抽出物の添加量は、非重合体カテキン類濃度が0.18重量%になるように調整した。これを加熱殺菌し、PETボトルに充填した。風味は、いずれも発酵感と深みがあって良好であった。
Example 4
1600 g of each oolong tea extract produced in Examples 1 to 3 was weighed, blended with 28 g of β-cyclodextrin, 5.6 g of sodium ascorbate and 0.4 g of sodium bicarbonate, and added a purified concentrate of a commercial tea extract. The whole was made up to 8000 g with deionized water. The amount of tea extract added was adjusted so that the non-polymer catechin concentration was 0.18% by weight. This was heat sterilized and filled into a PET bottle. The flavors were all good with a feeling of fermentation and depth.
実施例5
実施例1と同様にカラム内に烏龍茶葉を仕込んだ。イオン交換水(90℃)をカラム下部から供給し、比(b)/(a)が4.4になったときに給湯を停止した。1.96重量%炭酸水素ナトリウムイオン交換水溶液(72℃)をカラム上方からシャワーして供給した。烏龍茶葉仕込み重量に対して1倍重量を供給した後、0〜5分間保持し、次いでカラム上方からイオン交換水(90℃)をシャワーして供給しながら、抽出液をカラム下方から抜き出した。抜き出した抽出液の重量が仕込み烏龍茶葉重量の50倍になったところで終了し、烏龍茶抽出液を均一に混合して分析を行った。このときの製造操作条件、抽出液中の非重合体カテキン類濃度及び風味評価結果を表2に示す。
Example 5
In the same manner as in Example 1, oolong tea leaves were charged into the column. Ion exchange water (90 ° C.) was supplied from the lower part of the column, and hot water supply was stopped when the ratio (b) / (a) reached 4.4. 1.96 wt% sodium bicarbonate ion exchange aqueous solution (72 ° C.) was supplied by showering from above the column. After supplying 1 times the weight of the oolong tea leaves, the extract was withdrawn from the bottom of the column while maintaining ion-exchanged water (90 ° C.) by showering from the top of the column. The test was terminated when the weight of the extracted extract became 50 times the weight of the prepared oolong tea leaves, and the oolong tea extract was uniformly mixed for analysis. Table 2 shows the production operation conditions, the concentration of non-polymer catechins in the extract, and the flavor evaluation results.
炭酸水素ナトリウムイオン交換水溶液を供給後の保持時間が0分の場合は発酵感があって良好であったがコクが少なかった。保持時間が0.5、1、2分の場合はいずれも発酵感と深みが豊富で、非常に良好であった。保持時間が5分の場合にはコクがあり良好であったがアロマが低減していた。 When the retention time after supplying the sodium hydrogen carbonate ion exchange aqueous solution was 0 minutes, there was a feeling of fermentation and it was good, but there was little richness. When the holding time was 0.5, 1 or 2 minutes, both fermentation feeling and depth were abundant and very good. When the retention time was 5 minutes, the body was rich and good, but the aroma was reduced.
実施例6
実施例1と同様にカラム内に緑茶葉376gを仕込んだ。イオン交換水(75℃)をカラム下部から供給し、比(b)/(a)が4.4になったときに給湯を停止した。1.96重量%炭酸水素ナトリウムイオン交換水溶液(80℃)をカラム上方からシャワーして供給すると同時に、抽出液をカラム下方から抜き出した。緑茶葉仕込み重量に対して0.45倍重量を供給した後、カラム上方からイオン交換水(75℃)をシャワーして供給しながら、ひき続き抽出液をカラム下方から抜き出した。この間(b)/(a)比が4.4になるように抜出速度を調整した。抜き出した抽出液の重量が仕込み茶葉重量の13.5倍になったところで終了し、緑茶抽出液を均一に混合して分析を行った。抽出液のpHは6.6であった。
Example 6
In the same manner as in Example 1, 376 g of green tea leaves were charged in the column. Ion exchange water (75 ° C.) was supplied from the bottom of the column, and hot water supply was stopped when the ratio (b) / (a) reached 4.4. A 1.96 wt% aqueous solution of sodium bicarbonate ion exchange (80 ° C.) was supplied by showering from above the column, and at the same time, the extract was extracted from below the column. After supplying 0.45 times the weight of the green tea leaves charged, the extract was continuously extracted from the bottom of the column while supplying ion-exchanged water (75 ° C.) by showering from the top of the column. During this time, the extraction speed was adjusted so that the ratio (b) / (a) was 4.4. The process was terminated when the weight of the extracted extract was 13.5 times the weight of the charged tea leaves, and the green tea extract was uniformly mixed for analysis. The pH of the extract was 6.6.
比較例4
実施例1と同様にカラム内に緑茶葉376gを仕込んだ。イオン交換水(75℃)をカラム下部から供給し、比(b)/(a)が4.4になったときに給湯を停止した。次いでカラム上方からイオン交換水(75℃)をシャワーして供給しながら、ひき続き抽出液をカラム下方から抜き出した。この間(b)/(a)比が4.4になるように抜出速度を調整した。抜き出した抽出液の重量が仕込み茶葉重量の13.5倍になったところで終了し、緑茶抽出液を均一に混合して分析を行った。抽出液のpHは5.8であった。
Comparative Example 4
In the same manner as in Example 1, 376 g of green tea leaves were charged in the column. Ion exchange water (75 ° C.) was supplied from the bottom of the column, and hot water supply was stopped when the ratio (b) / (a) reached 4.4. Next, while supplying ion-exchanged water (75 ° C.) by showering from above the column, the extract was continuously extracted from below the column. During this time, the extraction speed was adjusted so that the ratio (b) / (a) was 4.4. The process was terminated when the weight of the extracted extract was 13.5 times the weight of the charged tea leaves, and the green tea extract was uniformly mixed for analysis. The pH of the extract was 5.8.
以上の緑茶抽出液の製造操作条件、抽出液中の非重合体カテキン類濃度及び風味評価結果を表3に示す。 Table 3 shows the manufacturing operation conditions of the above green tea extract, the concentration of non-polymer catechins in the extract, and the flavor evaluation results.
風味の評価は、次の方法で行った。
風味評価
緑茶抽出液を非重合体カテキン類濃度が0.06重量%になるようにイオン交換水で希釈した。比較例5で得た抽出液は炭酸水素ナトリウム溶液を用いてpHを6.6に調整した。4名の専門パネラーが次の評価基準で風味を評価し、表3にはその平均評価結果を示す。
(評価基準)
◎:緑茶の深みが豊富で、非常に良好。
〇:緑茶の深みがあり、良好。
△:緑茶の深みが乏しく薄く感じられ、やや不良。
×:深みがなくアロマも乏しく薄く感じられ、不良。
Evaluation of flavor was performed by the following method.
Flavor Evaluation Green tea extract was diluted with ion-exchanged water so that the non-polymer catechin concentration was 0.06% by weight. The extract obtained in Comparative Example 5 was adjusted to pH 6.6 using a sodium hydrogen carbonate solution. Four expert panelists evaluated the flavor according to the following evaluation criteria, and Table 3 shows the average evaluation results.
(Evaluation criteria)
A: The green tea has a great depth and is very good.
◯: Green tea is deep and good.
(Triangle | delta): The depth of green tea is scarce and is felt thin, and it is a little bad.
X: There is no depth and the aroma is scarce and thin, and it is poor.
本発明の茶抽出液の製造法で調製した緑茶抽出液は、非重合体カテキン濃度が高く、緑茶特有の深みが豊富で良好な風味であった。一方、比較例は緑茶抽出液中の非重合体カテキン類濃度が高かったが、深みが乏しく薄く感じられた。 The green tea extract prepared by the method for producing a tea extract of the present invention had a high non-polymer catechin concentration, abundant depth unique to green tea, and a good flavor. On the other hand, in the comparative example, the concentration of non-polymer catechins in the green tea extract was high, but the depth was poor and felt thin.
実施例7
実施例6で製造した緑茶抽出液を1330g計量し、βシクロデキストリン28gおよびアスコルビン酸ナトリウム5.6gおよび炭酸水素ナトリウムを配合し、市販茶抽出物の精製濃縮物を添加した後イオン交換水で全体を8000gにした。茶抽出物の添加量は、非重合体カテキン類濃度が0.18重量%になるように調整した。これを加熱殺菌し、PETボトルに充填した。風味は、深みが豊富で良好であった。
Example 7
1330 g of the green tea extract prepared in Example 6 was weighed, blended with 28 g of β-cyclodextrin, 5.6 g of sodium ascorbate and sodium bicarbonate, and after adding a purified concentrate of a commercial tea extract, Was 8000 g. The amount of tea extract added was adjusted so that the non-polymer catechin concentration was 0.18% by weight. This was heat sterilized and filled into a PET bottle. The flavor was rich and rich.
1 カラム式抽出機
2 炭酸水素ナトリウム水又は熱水溶液供給ライン
3 水又は熱水供給ライン
4 茶葉保持金網
5 茶抽出液抜き出しライン
6 茶葉
7 水又は熱水供給ライン
DESCRIPTION OF SYMBOLS 1 Column type extractor 2 Sodium hydrogen carbonate water or hot water supply line 3 Water or hot water supply line 4 Tea leaf holding wire net 5 Tea extract extraction line 6 Tea leaf 7 Water or hot water supply line
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JP2008099623A (en) * | 2006-10-20 | 2008-05-01 | Kao Corp | Method for producing tea extracted solution |
JP2010057377A (en) * | 2008-09-01 | 2010-03-18 | Kao Corp | Method for producing tea extract |
CN114391591A (en) * | 2022-01-27 | 2022-04-26 | 上海康识食品科技有限公司 | Tea extract, preparation method thereof and tea product |
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