JP2006166745A - Method for controlling landing of insect pest, volatilization apparatus and volatile preparation - Google Patents
Method for controlling landing of insect pest, volatilization apparatus and volatile preparation Download PDFInfo
- Publication number
- JP2006166745A JP2006166745A JP2004361118A JP2004361118A JP2006166745A JP 2006166745 A JP2006166745 A JP 2006166745A JP 2004361118 A JP2004361118 A JP 2004361118A JP 2004361118 A JP2004361118 A JP 2004361118A JP 2006166745 A JP2006166745 A JP 2006166745A
- Authority
- JP
- Japan
- Prior art keywords
- landing
- insecticide
- volatilization
- wind
- fan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 39
- 241000607479 Yersinia pestis Species 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 29
- 241000238631 Hexapoda Species 0.000 title abstract description 7
- 239000002917 insecticide Substances 0.000 claims abstract description 58
- 230000000694 effects Effects 0.000 claims abstract description 8
- 230000000749 insecticidal effect Effects 0.000 claims abstract description 8
- 239000011347 resin Substances 0.000 claims description 42
- 229920005989 resin Polymers 0.000 claims description 42
- 230000001629 suppression Effects 0.000 claims description 23
- 238000009423 ventilation Methods 0.000 claims 1
- 239000003039 volatile agent Substances 0.000 claims 1
- -1 1-ethynyl-2-methyl-2-pentenyl Chemical group 0.000 description 18
- 239000000203 mixture Substances 0.000 description 16
- 238000009472 formulation Methods 0.000 description 15
- 238000011156 evaluation Methods 0.000 description 13
- 241000255925 Diptera Species 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 241000256173 Aedes albopictus Species 0.000 description 9
- 238000007664 blowing Methods 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 241000256118 Aedes aegypti Species 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- AGMMRUPNXPWLGF-AATRIKPKSA-N (2,3,5,6-tetrafluoro-4-methylphenyl)methyl 2,2-dimethyl-3-[(e)-prop-1-enyl]cyclopropane-1-carboxylate Chemical compound CC1(C)C(/C=C/C)C1C(=O)OCC1=C(F)C(F)=C(C)C(F)=C1F AGMMRUPNXPWLGF-AATRIKPKSA-N 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 4
- 239000005871 repellent Substances 0.000 description 4
- 230000002940 repellent Effects 0.000 description 4
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 4
- LLMLSUSAKZVFOA-UJURSFKZSA-N (1S,3R)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@@H]1C(O)=O LLMLSUSAKZVFOA-UJURSFKZSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 241000282412 Homo Species 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 239000000077 insect repellent Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 244000144972 livestock Species 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 3
- 239000002861 polymer material Substances 0.000 description 3
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 3
- 239000002759 woven fabric Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical compound C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 229920000592 inorganic polymer Polymers 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 229960000490 permethrin Drugs 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 229960003536 phenothrin Drugs 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 229960005199 tetramethrin Drugs 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- ZCVAOQKBXKSDMS-OIISXLGYSA-N (+)-trans-(R)-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@H]1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-OIISXLGYSA-N 0.000 description 1
- YATDSXRLIUJOQN-SVRRBLITSA-N (2,3,4,5,6-pentafluorophenyl)methyl (1r,3s)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=C(F)C(F)=C1F YATDSXRLIUJOQN-SVRRBLITSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- ZFHGXWPMULPQSE-SZGBIDFHSA-N (Z)-(1S)-cis-tefluthrin Chemical compound FC1=C(F)C(C)=C(F)C(F)=C1COC(=O)[C@@H]1C(C)(C)[C@@H]1\C=C(/Cl)C(F)(F)F ZFHGXWPMULPQSE-SZGBIDFHSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- VTJMSIIXXKNIDJ-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-methylbutyric acid Chemical compound CC(C)C(C(O)=O)C1=CC=C(Cl)C=C1 VTJMSIIXXKNIDJ-UHFFFAOYSA-N 0.000 description 1
- RWLALWYNXFYRGW-UHFFFAOYSA-N 2-Ethyl-1,3-hexanediol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- UMHYVXGZRGOICM-AUYXYSRISA-N 2-[(z)-octadec-9-enoyl]oxypropyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(C)OC(=O)CCCCCCC\C=C/CCCCCCCC UMHYVXGZRGOICM-AUYXYSRISA-N 0.000 description 1
- MQBGNZBSQKLFQG-UHFFFAOYSA-N 3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethyl-1-[(2,3,5,6-tetrafluoro-4-methylphenyl)methyl]cyclopropane-1-carboxylic acid Chemical compound FC1=C(F)C(C)=C(F)C(F)=C1CC1(C(O)=O)C(C)(C)C1C=C(Cl)C(F)(F)F MQBGNZBSQKLFQG-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 241001503987 Clematis vitalba Species 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 241000276699 Seriola Species 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- 239000005939 Tefluthrin Substances 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000011354 acetal resin Substances 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical compound C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- DQYBDCGIPTYXML-UHFFFAOYSA-N ethoxyethane;hydrate Chemical compound O.CCOCC DQYBDCGIPTYXML-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229950006668 fenfluthrin Drugs 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229940010310 propylene glycol dioleate Drugs 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Abstract
Description
本発明は、蚊などの飛翔性害虫が人、家畜等の体表面にランディング(着地)するのを抑制してランディング抑制効果を得る害虫のランディング抑制方法、これに使用する揮散装置および揮散製剤に関する。 The present invention relates to a pest landing suppression method for suppressing landing of landing insects such as mosquitoes on the body surface of humans, livestock, etc., and obtaining a landing suppression effect, and a volatilization apparatus and a volatilization preparation used therefor .
従来、害虫の刺咬行動による被害から人や家畜、ペット等の動物を保護するため、種々の薬剤や防除方法が検討されてきた。その一つとして、害虫を忌避することを目的としたものがある。例えば、N,N−ジエチル−m−トルアミド、ジアルキルフタレート、2−エチル−1,3−ヘキサンジオール等が忌避剤として知られ、これらを用いた例として、N,N−ジエチル−m−トルアミドとヒマシ油を配合した刺咬性害虫忌避剤(特許文献1)、N,N−ジエチル−m−トルアミドと1S,3R,4R,6R−カラン−3,4−ジオールを配合した害虫忌避剤(特許文献2)等が挙げられる。 Conventionally, various drugs and control methods have been studied in order to protect animals such as humans, livestock, and pets from damage caused by pest biting behavior. One of them is aimed at repelling pests. For example, N, N-diethyl-m-toluamide, dialkyl phthalate, 2-ethyl-1,3-hexanediol and the like are known as repellents, and examples using these include N, N-diethyl-m-toluamide and Pest repellent containing castor oil (Patent Document 1), pest repellent containing N, N-diethyl-m-toluamide and 1S, 3R, 4R, 6R-curan-3,4-diol (patent) Reference 2) and the like.
しかし、これらの害虫忌避剤では、飛翔性害虫が人、家畜等の体表面にランディングするのを抑制することができない。このため、たとえ害虫の吸血行動は抑制できるとしても、害虫がランディングすることによる不快感が残るという問題がある。 However, these pest repellents cannot suppress flying pests from landing on the body surface of humans, livestock and the like. For this reason, even if the pest sucking action can be suppressed, there is a problem that the discomfort caused by the pest landing remains.
本発明の課題は、飛翔性害虫が体表面にランディングするのを抑制し、ランディングによる不快感をなくすことができる害虫のランディング抑制方法、これに使用する揮散装置および揮散製剤を提供することである。 An object of the present invention is to provide a pest landing suppression method capable of suppressing flying pests from landing on the body surface and eliminating discomfort caused by landing, and a volatilization apparatus and a volatilization preparation used therefor. .
本発明者らは上記課題を解決すべく鋭意研究を重ねた結果、ノックダウン活性または殺虫活性が発現する量より少ない極微量の殺虫剤を揮散させる場合には、体表面へのランディング数を低減させることができるという、従来知られていなかった新たな事実を見出した。 As a result of intensive studies to solve the above problems, the present inventors have reduced the number of landings on the body surface when volatilizing a trace amount of insecticide that is less than the amount that produces knockdown activity or insecticidal activity. I found a new fact that was not known before.
本発明は、このような知見に基づいて完成されたものであって、以下の構成からなる。
(1)殺虫剤をノックダウン活性または殺虫活性が発現する量よりも極めて低い揮散量でかつ害虫のランディング抑制するのに有効な揮散量で揮散させることを特徴とする害虫のランディング抑制方法。
(2)殺虫剤を常温下、風で揮散させる(1)記載のランディング抑制方法。
(3)常温下、風で瞬間的に前記殺虫剤を揮散させる(2)記載のランディング抑制方法。
(4)殺虫剤を樹脂に含有・保持させ、常温下、風で揮散させる(1)〜(3)のいずれかに記載のランディング抑制方法。
(5)前記殺虫剤が高温揮散性の薬剤である(1)〜(4)のいずれかに記載のランディング抑制方法。
(6)前記(1)〜(5)のいずれかに記載のランディング抑制方法に使用するための揮散装置であって、移動することにより風を起す担体の少なくとも一部に殺虫剤を保持していることを特徴とする揮散装置。
(7)前記(1)〜(5)のいずれかに記載のランディング抑制方法に使用するための揮散装置であって、殺虫剤を保持した担体を通風路内に設置したことを特徴とする揮散装置。
(8)前記殺虫剤は樹脂に含有された形態で担体の少なくとも一部に保持されている(6)または(7)記載の揮散装置。
(9)殺虫剤を少なくとも一部に保持した起風手段からなる揮散装置。
(10)前記起風手段が団扇または扇子である(9)記載の揮散装置。
(11)前記(1)〜(5)のいずれかに記載のランディング抑制方法に使用するための揮散製剤であって、殺虫剤を樹脂に含有していることを特徴とする揮散製剤。
The present invention has been completed based on such knowledge and has the following configuration.
(1) A pest landing suppression method characterized by causing an insecticide to volatilize at a volatilization amount that is extremely lower than the amount at which knockdown activity or insecticidal activity is manifested and is effective in suppressing the pest landing.
(2) The landing control method according to (1), wherein the insecticide is volatilized by wind at room temperature.
(3) The landing suppression method according to (2), wherein the insecticide is instantaneously volatilized by wind at room temperature.
(4) The landing suppression method according to any one of (1) to (3), wherein the resin contains and retains an insecticide and is volatilized by wind at room temperature.
(5) The landing suppression method according to any one of (1) to (4), wherein the insecticide is a high-temperature volatile chemical.
(6) A volatilization device for use in the landing suppression method according to any one of (1) to (5) above, wherein an insecticide is held on at least a part of the carrier that causes wind by moving. Volatilization device characterized by being.
(7) A volatilization device for use in the landing suppression method according to any one of (1) to (5) above, wherein the volatilization device is characterized in that a carrier holding an insecticide is installed in the air passage. apparatus.
(8) The volatilization device according to (6) or (7), wherein the insecticide is held in at least a part of the carrier in a form contained in a resin.
(9) A volatilization device consisting of wind-generating means holding at least part of the insecticide.
(10) The volatilization device according to (9), wherein the wind generating means is a fan or a fan.
(11) A volatilization preparation for use in the landing suppression method according to any one of (1) to (5), wherein the volatilization preparation contains an insecticide in a resin.
本発明において「常温」とは、通常、屋内の場合は室温を、屋外の場合は外気温度を意味するが、極微量の揮散でかつ害虫のランディングを抑制できる限りにおいて室温または外気温が15℃以上となるように加温する場合も含む概念である。また、本発明において「風」とは自然の風や、ファンなどによる送風のほか、団扇や扇子などのように移動によって発生する風をも意味する。 In the present invention, `` normal temperature '' usually means room temperature in the case of indoors and outside air temperature in the case of outdoors, but the room temperature or the outside temperature is 15 ° C. as long as it is a trace amount of volatilization and can suppress the pest landing. It is a concept including the case where it heats so that it may become the above. In the present invention, “wind” means natural wind, air blown by a fan, or the like, and wind generated by movement such as a fan or a fan.
本発明によれば、ノックダウン活性または殺虫活性が発現する量より少ない極微量の殺虫剤を揮散させる場合には、飛翔性害虫が体表面にランディングする数が低減し、その結果、害虫が体表面に接触する不快感をなくすことができ、しかも極微量の揮散であるから安全性および持続性に優れているという効果がある。特に、本発明の方法および装置は、飛翔性害虫の活動が活発な屋外での使用に適している。 According to the present invention, when an extremely small amount of insecticide that is smaller than the amount that exhibits knockdown activity or insecticidal activity is volatilized, the number of flying insect pests landing on the body surface is reduced. There is an effect that it is possible to eliminate discomfort coming into contact with the surface, and since it is a very small amount of volatilization, it is excellent in safety and sustainability. In particular, the method and apparatus of the present invention is suitable for outdoor use where flying pests are active.
本発明にかかる害虫のランディング抑制方法は、極微量の殺虫剤を揮散させて害虫のランディングを抑制するものである。殺虫剤の揮散量は、害虫のランディングを抑制するのに有効な揮散量であり、具体的には、ノックダウン活性または殺虫活性が発現する量の1/5〜1/200程度であるのがよい。好ましくは1/10〜1/30である。 The pest landing suppression method according to the present invention suppresses pest landing by volatilizing a trace amount of an insecticide. The amount of volatilization of the insecticide is the amount of volatilization that is effective in suppressing the pest landing, and specifically, it is about 1/5 to 1/200 of the amount that the knockdown activity or the insecticidal activity is expressed. Good. Preferably, it is 1/10 to 1/30.
本発明で使用される殺虫剤は、上記のように揮散量が極微量となるように制御されている限り、特にその種類が限定されるものではなく、常温ないし高温揮散性殺虫剤がいずれも使用可能である。このような殺虫剤としては、以下に示すようなピレスロイド系化合物が例示されるが、これに限定されるものではない。 The insecticide used in the present invention is not particularly limited as long as the amount of volatilization is controlled as described above, and any normal or high temperature volatilizing insecticide can be used. It can be used. Examples of such insecticides include pyrethroid compounds as shown below, but are not limited thereto.
・dl−3−アリル−2−メチル−4−オキソ−2−シクロペンテニル dl−シス/トランス−クリサンテマート(一般名アレスリン:商品名ピナミン(以下、「アレスリン」という))
・1−エチニル−2−メチル−2−ペンテニル d−シス/トランス−クリサンテマート(一般名エンペントリン(以下、「エンペントリン」という)
・(+)−2−メチル−4−オキソ−3−(2−プロピニル)−2−シクロペンテニル(+)−シス/トランス−クリサンテマート(一般名d・d−T80−プラレトリン:商品名エトック(以下、「プラレトリン」という))
・dl−3−アリル−2−メチル−4−オキソ−2−シクロペンテニル d−シス/トランス−クリサンテマート(一般名dl・d−T80−アレスリン:商品名ピナミンフォルテ)
・dl−3−アリル−2−メチル−4−オキソ−2−シクロペンテニル d−トランス−クリサンテマート(商品名バイオアレスリン)
・d−3−アリル−2−メチル−4−オキソ−2−シクロペンテニル d−トランス−クリサンテマート(商品名エキスリン)
・(1,3,4,5,6,7−ヘキサヒドロ−1,3−ジオキソ−2−インドリル)メチル dl−シス/トランス−クリサンテマート(一般名フタルスリン:商品名ネオピナミン)
・(1,3,4,5,6,7−ヘキサヒドロ−1,3−ジオキソ−2−インドリル)メチル d−シス/トランス−クリサンテマート(一般名d−T80−フタルスリン:商品名ネオピナミンフォルテ)
・(5−ベンジル−3−フリル)メチル d−シス/トランス−クリサンテマート(一般名レストメリン:商品名クリスロンフォルテ)
・5−プロパルギル−2−フリルメチル d−シス/トランス−クリサンテマート(商品名ピナミンDフォルテ)
・3−フェノキシベンジル−dl−シス/トランス−3−(2,2−ジクロロビニル)−2,2−ジメチル−1−シクロプロパンカルボキシラート(一般名ペルメトリン:商品名エクスミン)
・3−フェノキシベンジル d−シス/トランス−クリサンテマート(一般名フェノトリン:商品名スミスリン)
・α−シアノ−3−フェノキシベンジル 2−(4−クロロフェニル)−3−メチルブチレート(一般名フェンバレレート)
・2,3,5,6−テトラフルオロ−4−メチルベンジル−3−(2−クロロ−3,3,3−トリフルオロ−1−プロペニル)−2,2−ジメチル−1−シクロプロパンカルボキシラート(一般名テフルスリン)
・d−トランス−2,3,5,6−テトラフルオロベンジル−3−(2,2−ジクロロビニル)−2,2−ジメチル−1−シクロプロパンカルボキシラート(一般名ベンフルスリン(以下、「ベンフルスリン」という))
・(±)−α−シアノ−3−フェノキシベンジル (+)−シス/トランス−クリサンテマート(一般名d−T80−シフェノトリン:商品名ゴキラート)
・α−シアノ−3−フェノキシベンジル シス/トランス−2,2,3,3−テトラメチルシクロプロパンカルボキシラート(一般名フェンプロパトリン)
・2,3,4,5,6−ペンタフルオロベンジル−dl−シス/トランス 3−(2,2−ジクロロビニル)−2,2−ジメチル−1−シクロプロパンカルボキシラート(一般名フェンフルスリン)
・1−エチニル−2−メチル−2−ペンテニル dl−シス/トランス−3−(2,2−ジクロロビニル)−2,2−ジメチル−1−シクロプロパンカルボキシラート
・dl−3−アリル−2−メチル−4−オキソ−2−シクロペンテニル d1−シス/トランス−2,2,3,3−テトラメチル−1−シクロプロパンカルボキシラート(一般名テラレスリン)が挙げられ、
さらに一般名トランスフルトリン(商品名バイオスリン)、一般名メトフルトリン(商品名エミネンス)、一般名プロフルトリン(商品名フェアリテール)等も好適に使用可能である。
Dl-3-allyl-2-methyl-4-oxo-2-cyclopentenyl dl-cis / trans-chrysantemate (generic name: allesrin: trade name pinamine (hereinafter referred to as “areslin”))
1-ethynyl-2-methyl-2-pentenyl d-cis / trans-chrysantemate (generic name empentrin (hereinafter referred to as “empentrin”)
(+)-2-Methyl-4-oxo-3- (2-propynyl) -2-cyclopentenyl (+)-cis / trans-chrysantemate (generic name d · d-T80-praretrin: trade name Etoc (Hereafter referred to as “praretrin”)
Dl-3-allyl-2-methyl-4-oxo-2-cyclopentenyl d-cis / trans-chrysantemate (generic name dl dT80-areslin: trade name pinamine forte)
Dl-3-allyl-2-methyl-4-oxo-2-cyclopentenyl d-trans-chrysanthemate (trade name Bioareslin)
D-3-allyl-2-methyl-4-oxo-2-cyclopentenyl d-trans-chrysanthemate (trade name exrin)
・ (1,3,4,5,6,7-Hexahydro-1,3-dioxo-2-indolyl) methyl dl-cis / trans-chrysantemate (generic name phthalusrin: trade name neopinamine)
(1,3,4,5,6,7-hexahydro-1,3-dioxo-2-indolyl) methyl d-cis / trans-chrysantemate (generic name d-T80-phthalthrin: trade name neopinamine) Forte)
(5-benzyl-3-furyl) methyl d-cis / trans-chrysantemate (generic name restmelin: trade name chryslonforte)
・ 5-propargyl-2-furylmethyl d-cis / trans-Chrysantemate (trade name: Pinamine D Forte)
3-phenoxybenzyl-dl-cis / trans-3- (2,2-dichlorovinyl) -2,2-dimethyl-1-cyclopropanecarboxylate (generic name permethrin: trade name Exmin)
3-phenoxybenzyl d-cis / trans-chrysantemate (generic name phenothrin: trade name Smithlin)
.Alpha.-cyano-3-phenoxybenzyl 2- (4-chlorophenyl) -3-methylbutyrate (generic name fenvalerate)
2,3,5,6-tetrafluoro-4-methylbenzyl-3- (2-chloro-3,3,3-trifluoro-1-propenyl) -2,2-dimethyl-1-cyclopropanecarboxylate (Generic name Tefluthrin)
D-trans-2,3,5,6-tetrafluorobenzyl-3- (2,2-dichlorovinyl) -2,2-dimethyl-1-cyclopropanecarboxylate (generic name benfluthrin (hereinafter “benfluthrin”) ))
(±) -α-cyano-3-phenoxybenzyl (+)-cis / trans-chrysantemate (generic name d-T80-cyphenothrin: trade name gokylate)
Α-Cyano-3-phenoxybenzyl cis / trans-2,2,3,3-tetramethylcyclopropanecarboxylate (generic name phenpropatoline)
2,3,4,5,6-pentafluorobenzyl-dl-cis / trans 3- (2,2-dichlorovinyl) -2,2-dimethyl-1-cyclopropanecarboxylate (generic name fenfluthrin)
1-ethynyl-2-methyl-2-pentenyl dl-cis / trans-3- (2,2-dichlorovinyl) -2,2-dimethyl-1-cyclopropanecarboxylate dl-3-allyl-2- Methyl-4-oxo-2-cyclopentenyl d1-cis / trans-2,2,3,3-tetramethyl-1-cyclopropanecarboxylate (generic name: terareslin),
Furthermore, the generic name transfluthrin (trade name Biothrin), the generic name methfluthrin (trade name Eminence), the generic name profluthrin (trade name Fair Retail) and the like can be suitably used.
殺虫剤をノックダウン活性または殺虫活性が発現する量よりも極めて低い揮散量しか揮散させないためには、様々な方法が採用可能であり、例えば以下のような方法が挙げられる。
(1)高温揮散性殺虫剤等の殺虫剤を担体に保持させ、常温下、風で揮散させる。
(2)常温ないし高温揮散性殺虫剤を樹脂に含有・保持させ、常温下、風で揮散させる。
In order to volatilize an insecticide by a volatilization amount that is extremely lower than the amount at which knockdown activity or insecticidal activity is manifested, various methods can be employed, and examples include the following methods.
(1) Hold an insecticide such as a high-temperature volatile insecticide on a carrier and volatilize it with air at room temperature.
(2) A room-temperature or high-temperature volatile insecticide is contained and retained in the resin, and is volatilized by wind at room temperature.
前記(1)に記載の高温揮散性殺虫剤とは、蒸気圧が1.34×10-3Pa(20℃)以下の殺虫剤をいい、通常は加熱しないと蒸散しないものである。このような高温揮散性殺虫剤、すなわち常温で難揮散性の薬剤としては、上記殺虫剤のうち、一般名がフタルスリン、レスメトリン、ペルメトリン、フェノトリン、フェンバレレート、ベンフルスリン、フェンプロパトリンである殺虫剤などが挙げられる。このような高温揮散性殺虫剤は担体に保持させて使用する。担体が、固体担体である場合は、殺虫剤をそのまま、または適当な溶剤に溶解させて担体の表面に塗布するなどして、担体の表面に保持させるか、担体内部に含浸させ乾燥させて用いればよい。 The high-temperature volatile insecticide described in (1) above refers to an insecticide having a vapor pressure of 1.34 × 10 −3 Pa (20 ° C.) or less, and normally does not evaporate unless heated. As such high-temperature volatile insecticides, that is, agents that are hardly volatile at room temperature, among the above-mentioned insecticides, insecticides whose general names are phthalthrin, resmethrin, permethrin, phenothrin, fenvalerate, benfluthrin, fenpropatoline, etc. Is mentioned. Such a high-temperature volatile insecticide is used by being held on a carrier. When the carrier is a solid carrier, the pesticide is used as it is or dissolved in a suitable solvent and applied to the surface of the carrier, for example, held on the surface of the carrier, or impregnated inside the carrier and dried. That's fine.
このような担体としては、特に制限されるものではなく、例えば紙、不織布、織布、木材、パルプ、無機高分子物質、無機多孔質物質(ケイ酸塩、シリカ、ゼオライト等)、有機高分子物質(セルロース、ポリエチレン、ポリプロピレン、ポリビニルアルコール等)、ゲル化物質(寒天、カラギーナン、ゼラチン等)、昇華性物質(アダマンタン、シクロドデカン、パラジクロロベンゼン、ナフタリン、樟脳等)、樹脂類、油性溶剤、水性溶剤などが挙げられ、これらの1種または2種以上を組み合わせて使用することができる。 Such a carrier is not particularly limited. For example, paper, nonwoven fabric, woven fabric, wood, pulp, inorganic polymer material, inorganic porous material (silicate, silica, zeolite, etc.), organic polymer, etc. Substances (cellulose, polyethylene, polypropylene, polyvinyl alcohol, etc.), gelling substances (agar, carrageenan, gelatin, etc.), sublimable substances (adamantane, cyclododecane, paradichlorobenzene, naphthalene, camphor, etc.), resins, oil-based solvents, aqueous A solvent etc. are mentioned, These 1 type (s) or 2 or more types can be used in combination.
また、担体の形状も限定されるものではなく、屋内、屋外、車内、テント、物置小屋などで使用するために各種の形態、形状で使用することができるが、特に常温で風が当たるような使用形態であるのがよい。このような形態としては、例えば殺虫剤を紙部分に含浸させた団扇もしくは扇子、さらに不織布や織布で作られる衣服(シャツ、パンツ、スカート、ジャケット、作業着など)、帽子、日傘、手袋、靴下、リストバンド、浴衣、アウトドア用品(テント、パーカー、シュラフなど)、腕章、腕抜き、ペットウェア、蚊帳、ハンモック、幟(のぼり)、旗などが挙げられる。また、上記担体の他の形状として、通気性、薬剤の十分な保持性などの点から、例えば筒状、ハニカム状、スノコ状、格子状、網状等の構造であってもよい。この場合は、特に送風手段によって強制的に発生した風が通過する通路に設置するのに適している。送風手段としては、例えば扇風機、エアコンディショナ、空気清浄機、冷風扇などが上げられる。また、繊維マットに含浸させてもよい。高温揮散性殺虫剤は、担体100重量部に対して0.5〜50重量部、好ましくは1〜20重量部の割合で保持される。 In addition, the shape of the carrier is not limited, and can be used in various forms and shapes for use indoors, outdoors, in the car, tents, storage sheds, etc. It should be used. Such forms include, for example, a fan or fan in which a paper portion is impregnated with an insecticide, clothes made of nonwoven fabric or woven fabric (shirts, pants, skirts, jackets, work clothes, etc.), hats, parasols, gloves, Socks, wristbands, yukata, outdoor equipment (tents, hoodies, shruffs, etc.), armbands, armbands, pet wear, mosquito nets, hammocks, climbers, flags, etc. Other shapes of the carrier may be, for example, a tubular shape, a honeycomb shape, a slat-like shape, a lattice shape, or a net shape from the viewpoint of air permeability and sufficient drug retention. In this case, it is particularly suitable for installation in a passage through which the wind forcedly generated by the blowing means passes. Examples of the air blowing means include a fan, an air conditioner, an air cleaner, and a cold air fan. Further, the fiber mat may be impregnated. The high temperature volatile insecticide is held at a ratio of 0.5 to 50 parts by weight, preferably 1 to 20 parts by weight, with respect to 100 parts by weight of the carrier.
また、前記(2)の常温ないし高温揮散性殺虫剤を樹脂に含有・保持させ、常温下、風で揮散させる態様について以下説明する。殺虫剤、特に常温揮散性殺虫剤は、常温下で容易に揮散するため、前記樹脂に含有させて、揮散量を制御する。ここで、常温揮散性殺虫剤とは、前記した高温揮散性殺虫剤を除く殺虫剤であって、蒸気圧が1.34×10-3Pa(20℃)を下回る殺虫剤をいう。 Moreover, the aspect which makes a resin contain and hold | maintain the said (2) normal temperature thru | or high temperature volatile insecticide, and volatilizes with a wind at normal temperature is demonstrated below. Insecticides, in particular, room temperature volatile insecticides, volatilize easily at room temperature, and thus are contained in the resin to control the volatilization amount. Here, the room temperature volatile insecticide is an insecticide excluding the above-described high temperature volatile insecticide, and means an insecticide having a vapor pressure lower than 1.34 × 10 −3 Pa (20 ° C.).
樹脂としては、例えばポリエチレン、ポリプロピレン、ポリ塩化ビニル、ポリウレタン、アセタール樹脂、ポリスチレン、ポリアミド、ポリカーボネートなどが挙げられる。使用する樹脂は、揮散量を制御するうえで、比表面積が10〜500g/m2、厚さ0.01〜5mm、開口面積比0.3〜0.8の樹脂製剤の形態で使用するのがよく、使用する殺虫剤に応じて比表面積や開口面積の大きさを調整し、揮散量を制御する。なお、開口面積比は投影面積あたりの開口面積から求めることができる。 Examples of the resin include polyethylene, polypropylene, polyvinyl chloride, polyurethane, acetal resin, polystyrene, polyamide, polycarbonate, and the like. The resin to be used is used in the form of a resin preparation having a specific surface area of 10 to 500 g / m 2 , a thickness of 0.01 to 5 mm, and an opening area ratio of 0.3 to 0.8 in order to control the volatilization amount. However, the amount of volatilization is controlled by adjusting the specific surface area and the size of the open area according to the insecticide used. The opening area ratio can be obtained from the opening area per projected area.
これらの樹脂製剤に殺虫剤を含有させるには、原料樹脂に所定量の殺虫剤を練り込み、必要に応じて所定形状に成形する。殺虫剤の含有量は、樹脂製剤100重量部に対して0.5〜50重量部、好ましくは1〜20重量部である。樹脂製剤はそのまま使用するほか、担体の少なくとも一部に含浸、貼着などにより保持させて使用される。 In order to contain an insecticide in these resin preparations, a predetermined amount of an insecticide is kneaded into the raw material resin and shaped into a predetermined shape as necessary. Content of an insecticide is 0.5-50 weight part with respect to 100 weight part of resin preparations, Preferably it is 1-20 weight part. In addition to using the resin preparation as it is, it is used by retaining at least a part of the carrier by impregnation or sticking.
得られた樹脂製剤は、屋内、屋外、車内、小屋、物置、テントなどで使用するために様々な形態で使用することができ、例えば虫除けネット製剤、団扇製剤、扇子製剤、エアコンディショナ取付け製剤、空気清浄機取付け製剤、扇風機取付け製剤、冷風扇取付け製剤、ドア取付け製剤、網戸取付け製剤、送風手段(ピエゾファン、軸流ファン、シロッコファンなど)への極微量滴下装置、前記送風手段の送風路への樹脂製剤の繰出し・巻取り装置などが挙げられる。 The obtained resin preparation can be used in various forms for indoor, outdoor, in-car, shed, storeroom, tent, etc. For example, insect repellent net preparation, fan fan preparation, fan fan preparation, air conditioner mounting preparation , Air purifier mounting formulations, fan mounting formulations, cold air fan mounting formulations, door mounting formulations, screen door mounting formulations, micro-dropping devices for blowing means (piezo fans, axial fans, sirocco fans, etc.), blowing of the blowing means Examples thereof include a device for feeding and winding the resin formulation to the road.
虫除けネット製剤は、前記樹脂製剤でネットを形成したり、ネットの片面または両面に樹脂製剤を貼り付けるなどして使用する。団扇製剤および扇子製剤は、それらの片面または両面に樹脂製剤を貼り付けるなどして使用する。虫除けネットは自然の風で、団扇および扇子はそれらをあおぐときに発生する風で、それぞれ殺虫剤成分が揮散する。 Insect repellent net formulations are used by forming a net with the resin formulation or by attaching a resin formulation to one or both sides of the net. Fan fan preparations and fan fan preparations are used by sticking a resin preparation on one or both sides thereof. Insect repellent nets are a natural wind, and fan fans and fans are winds generated when they are blown.
エアコンディショナ取付け製剤、空気清浄機取付け製剤、扇風機取付け製剤、冷風扇取付け製剤は、例えばそれらの風吹き出し口の前に樹脂製剤を設置して、風が樹脂製剤に当たるようにすればよい。ドア取付け製剤は、ドアの片面または両面の少なくとも一部に樹脂製剤を貼り付けるなどして、ドアの開閉時に発生する風で薬剤を揮散させるものである。網戸取付け製剤は、片面または両面の少なくとも一部に樹脂製剤を貼り付けるなどして、網戸の開閉時および網戸を通る風によって薬剤を揮散させる。 For the air conditioner mounting preparation, the air cleaner mounting preparation, the fan mounting preparation, and the cold air fan mounting preparation, for example, a resin preparation may be installed in front of the air outlets so that the wind hits the resin preparation. In the door-attached preparation, a chemical preparation is attached to at least a part of one or both sides of the door, and the medicine is volatilized by wind generated when the door is opened and closed. In the screen door-attached preparation, the chemical agent is volatilized by opening and closing the screen door and by the wind passing through the screen door by sticking a resin preparation on at least a part of one side or both sides.
送風手段への極微量滴下装置は、送風手段のファン部分に極微量の殺虫剤成分を滴下して揮散させるものである。この場合、殺虫剤成分は溶剤を含有しない殺虫剤原体、溶剤に溶解した溶液の形態などで滴下される。送風手段の送風路への樹脂製剤の繰出し・巻取り装置は、テープ状の製剤を必要量繰出し、露出させ、殺虫成分が揮散した後に露出部分を順次巻取るものである。また、揮散量が極めて低く保たれ、かつ害虫のランディングを抑制するのに有効な揮散量である限りにおいて、これを吸液芯で吸い上げて室温または加熱して揮散させる形態で用いることもできる。 The very small amount dropping device to the blowing means drops a very small amount of the insecticide component on the fan portion of the blowing means and volatilizes it. In this case, the insecticide component is added dropwise in the form of a pesticide raw material not containing a solvent, a solution dissolved in a solvent, or the like. The device for feeding and winding the resin formulation to the air passage of the blowing means feeds out a necessary amount of the tape-like formulation and exposes it, and after the insecticidal components are volatilized, the exposed portions are sequentially wound. Further, as long as the volatilization amount is kept extremely low and the volatilization amount is effective for suppressing the pest landing, the volatilization amount can be used by sucking it up with a liquid absorbent core and volatilizing it at room temperature or heating.
また、樹脂製剤は、前記した紙、不織布、織布、木材、パルプ、無機高分子物質、無機多孔質物質、有機高分子物質、ゲル化物質、昇華性物質、樹脂類などの担体に貼着、含浸などにより保持させることができる。そして、担体は、前記した衣服、帽子、日傘、手袋、靴下、リストバンド、浴衣、アウトドア用品、腕章、腕抜き、ペットウェア、蚊帳、ハンモック、幟などの各種形態で使用することができる。また、樹脂製剤を所定形状に成形し、または所定形状の担体に保持させて、これを体表面に付けるようにしてもよい。例えば、帯状成形して、腰から吊下げる、腰に巻きつける、肩に掛ける、ワッペンのように粘着剤等を使用して体表面に貼り付ける、クリップ状のもので挟持するなどである。 In addition, the resin preparation is attached to a carrier such as paper, nonwoven fabric, woven fabric, wood, pulp, inorganic polymer material, inorganic porous material, organic polymer material, gelling material, sublimation material, and resins. It can be retained by impregnation. The carrier can be used in various forms such as clothes, hats, parasols, gloves, socks, wristbands, yukata, outdoor equipment, armbands, armbands, pet wear, mosquito nets, hammocks, and bags. Alternatively, the resin preparation may be molded into a predetermined shape or held on a carrier having a predetermined shape and attached to the body surface. For example, it is formed into a band shape, hung from the waist, wrapped around the waist, hung on the shoulder, attached to the body surface using an adhesive or the like like a emblem, or sandwiched by a clip-like object.
本発明に係る揮散製剤は、前記したように殺虫剤原体や、有機溶剤などの溶剤に殺虫剤成分を溶解させた液体製剤の形態でも使用可能である。液体製剤を調製するための溶剤としては、例えば水、メタノール、エタノール、イソプロパノール、エチレングリコールモノメチルエーテル等のアルコール類、アセトン、メチルエチルケトン、メチルイソブチルケトン等のケトン類、酢酸メチル、酢酸エチル、酢酸ブチル、フタル酸ジエチル、ミリスチン酸イソプロピル、ステアリン酸ブチル等のエステル類、へキサン、ケロシン、パラフィン、灯油、n−ペンタン、イソペンタン、シクロペンタン等の脂肪族炭化水素類、ベンゼン、キシレン等の芳香族炭化水素類、エチルエーテル、エチレングリコール、エチレングリコールジエチル等のエーテル類が挙げられる。これらの溶媒は2種以上を混合して使用してもよい。 The volatilization preparation according to the present invention can also be used in the form of a liquid preparation in which an insecticide component is dissolved in an insecticide base or a solvent such as an organic solvent as described above. Examples of the solvent for preparing the liquid preparation include alcohols such as water, methanol, ethanol, isopropanol, and ethylene glycol monomethyl ether, ketones such as acetone, methyl ethyl ketone, and methyl isobutyl ketone, methyl acetate, ethyl acetate, butyl acetate, Esters such as diethyl phthalate, isopropyl myristate, butyl stearate, aliphatic hydrocarbons such as hexane, kerosene, paraffin, kerosene, n-pentane, isopentane and cyclopentane, and aromatic hydrocarbons such as benzene and xylene And ethers such as ethyl ether, ethylene glycol, and ethylene glycol diethyl. Two or more of these solvents may be mixed and used.
前記有効成分を可溶化ないし乳化するために可溶化剤または乳化剤を用いることができる。可溶化剤または乳化剤としては、例えば、ソルビタントリオレエート、ポリオキシエチレンモノオレエート、ポリオキシエチレンノニルフェニルエーテル、ポリオキシエチレン(10モルから40モル)硬化ヒマシ油、トリポリオキシエチレンアルキルエーテル、1,3−ブチレングリコール、デカグリセリンモノオレエート、ジオレイン酸プロピレングリコール、ポリオキシエチレン(16モルから20モル)ステアリル酸アミド、ポリオキシエチレンポリオキシプロピレングリコール、ポリオキシエチレンラウリルエーテルリン酸、グリセリン脂肪酸エステルなどが挙げられ、その他にもステアリルアルコール、ポリビニルピロリドン、ラノリン脂肪酸など各種界面活性剤が挙げられ、これらは2種以上を混合して使用してもよい。 A solubilizer or emulsifier can be used to solubilize or emulsify the active ingredient. Examples of the solubilizer or emulsifier include sorbitan trioleate, polyoxyethylene monooleate, polyoxyethylene nonylphenyl ether, polyoxyethylene (10 to 40 mol) hydrogenated castor oil, tripolyoxyethylene alkyl ether, 1, 3-butylene glycol, decaglycerin monooleate, propylene glycol dioleate, polyoxyethylene (16 to 20 mol) stearic acid amide, polyoxyethylene polyoxypropylene glycol, polyoxyethylene lauryl ether phosphate, glycerin fatty acid ester, etc. In addition, various surfactants such as stearyl alcohol, polyvinyl pyrrolidone, and lanolin fatty acid may be used, and these may be used in combination of two or more.
本発明方法は、各種の衛生害虫、農業害虫、不快害虫による被害を防止ないし抑制するために使用することができる。本発明方法が適用される害虫としては、例えばシナハマダラカ、アカイエカ、コガカアカイエカ、ネッタイシマカ、ヒトスジシマカ、トウゴウヤブカ等の蚊;イエバエ、チョウバエ、サシバエ等のハエもしくはコバエ;シクロアブ、ウシアブ、ゴマフアブ等のアブ;クロオオブユ、キアシオオブユ、アオキツメトゲブユ等のブユ;トクナガクロヌカカ、オオシマヌカカ、ニワトリヌカカ等のヌカカ;キイロスズメバチ、セグロアシナガバチ、ミツバチ等のハチ;カメムシ、その他の害虫が挙げられる。 The method of the present invention can be used to prevent or suppress damage caused by various sanitary pests, agricultural pests, and unpleasant pests. Pests to which the method of the present invention is applied include, for example, mosquitoes such as Sinohada araka, Akaieka, Kogaka Aikaeka, Aedes aegypti, Aedes albopictus, Aedes albopictus, etc .; , Yellowtails such as Kioshiobyu, Aokitsugegebuyu; Nukaka such as Tokunagaronukaka, Oshimamanukaka, chicknutka;
以下、実施例を挙げて本発明を詳細に説明するが、本発明は以下の実施例のみに限定されるものではない。 EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated in detail, this invention is not limited only to a following example.
EMMA(エチル−メタアクリレート共重合体)樹脂を150℃で溶融させ、これにエンペントリンを10重量%練り合わせ、金型に流して速やかに冷却させてネット状(網状)に成形した樹脂製剤を得た。このネット状樹脂製剤6.5gを通常の汎用団扇の片面に貼り付け、検体(処理団扇)を得た。 An EMMA (ethyl-methacrylate copolymer) resin was melted at 150 ° C., and 10% by weight of empentrin was kneaded with this, and the mixture was poured into a mold and quickly cooled to obtain a resin formulation molded into a net (network). . 6.5 g of this net-form resin formulation was affixed to one side of a normal general fan, and a sample (processing fan) was obtained.
<評価試験>
予めヒトスジシマカが多く発生している屋外で、まず被験者の体表面へのヒトスジシマカ雌成虫の誘引個体数およびランディング個体数を10分間調べた(ブランク)。
ついで、同じ場所で、前記樹脂製剤を貼り付けていない未処理団扇をあおいで被験者の体表面に風を送り、被験者の体表面へのヒトスジシマカ雌成虫の誘引個体数およびランディング個体数を10分間調べた。
その後、5分間の間隔をあけて、実施例1で得た処理団扇を用いて、未処理団扇と同様にして、被験者の体表面へのヒトスジシマカ雌成虫の誘引個体数およびランディング個体数を10分間調べた。試験は2回反復して行ない、その平均値を求めた。なお、試験は、気温26℃、微風の環境下で行った。試験結果を表1に示す。
In the outdoors where a large number of Aedes albopictus was pre-existing, the number of attracted individuals and landings of adult Aedes aegypti on the subject's body surface was first examined for 10 minutes (blank).
Next, in the same place, blow the untreated fan with the resin formulation on it and blow the wind on the subject's body surface, and examine the number of attracted and landing individuals of the female white stripe moth on the subject's body surface for 10 minutes. It was.
Then, using the treatment fan obtained in Example 1 with an interval of 5 minutes, in the same manner as the untreated fan, the number of attracted individuals and landing individuals of the female Aedes albopictus on the subject's body surface was 10 minutes. Examined. The test was repeated twice and the average value was determined. The test was conducted in an environment with a temperature of 26 ° C. and a slight wind. The test results are shown in Table 1.
実施例1と同様にして、プロフルトリンをEMMA樹脂に8.7重量%練り込み、ネット状樹脂製剤を得た。この樹脂製剤8.0gを通常の汎用団扇の片面に貼り付け、検体(処理団扇)を得た。ついで、実施例1と同様にしてヒトスジシマカ雌成虫の誘引個体数およびランディング個体数を調べた。試験は2回反復して行ない、その平均値を求めた。なお、試験は、気温26℃、微風の環境下で行った。試験結果を表2に示す。
実施例1、2の評価試験結果から明らかなように、ブランクでは、被験者の体表面に誘引されたヒトスジシマカ雌成虫の個体数は多く、ランディングする個体数も多かった。未処理団扇をあおいだ場合も、同様に誘引個体数およびランディング個体数が多かった。これに対して、処理団扇であおぐと、被験者の体表面へのランディング個体数は激減し、高いランディング抑制効果が認められた。 As is clear from the evaluation test results of Examples 1 and 2, in the blank, the number of adult human mosquitoes attracted to the subject's body surface was large, and the number of individuals landing was also large. Similarly, when untreated fan was covered, the number of attracted and landing individuals was large. In contrast, the treatment fan fan drastically decreased the number of subjects landing on the body surface, and a high landing suppression effect was observed.
実施例1と同様にして、プロフルトリンをEMMA樹脂に8.7重量%練り込み、ネット状樹脂製剤を得、これを検体として以下の評価試験を行った。 In the same manner as in Example 1, 8.7% by weight of profluthrin was kneaded into EMMA resin to obtain a net-like resin preparation, and the following evaluation test was performed using this as a specimen.
〈評価試験〉
予めヒトスジシマカが多く発生している屋外で、まず被験者2名(イ、ロ)の体表面へのヒトスジシマカ雌成虫の誘引個体数およびランディング個体数を2分間調べた(ブランク)。ついで、同じ場所で、被験者の片方の脛部に実施例3で得た検体(重量:6.5g、大きさ:長さ14cm×幅23cm×厚さ0.8mm)を吊下げ、ブランクと同様にして体表面へのヒトスジシマカ雌成虫の誘引個体数およびランディング個体数を2分間調べた。なお、試験中は、被験者に試験場所内を通常の歩行速度で歩いてもらった。また、試験はA、Bの2箇所で実施した。なお、試験は、気温26℃、微風の環境下で行った。試験結果を表3に示す。
実施例3の評価試験結果から明らかなように、ブランクでは、被験者2名とも体表面に誘引されたヒトスジシマカ雌成虫の個体数は多く、ランディングする個体数も多かった。これに対して、検体を吊下げた場合には、被験者の体表面へのランディング個体数は激減し、高いランディング抑制効果が認められた。
<Evaluation test>
In the outdoors where a large number of Aedes albopictus was pre-existing, the number of attracted individuals and landings of female Aedes aegypti on the body surface of 2 subjects (I, B) were examined for 2 minutes (blank). Next, the specimen (weight: 6.5 g, size: length 14 cm × width 23 cm × thickness 0.8 mm) obtained in Example 3 was suspended on one shin part of the subject at the same place, and the same as the blank. The number of attracted and landing individuals of female female mosquitoes on the body surface was examined for 2 minutes. During the test, the subject walked at the normal walking speed in the test place. The test was conducted at two locations A and B. The test was conducted in an environment with a temperature of 26 ° C. and a slight wind. The test results are shown in Table 3.
As is clear from the evaluation test results of Example 3, in the blank, both the two test subjects were attracted to the surface of the body, and the number of female adults of human mosquito attracted to the body surface was large. On the other hand, when the specimen was suspended, the number of individuals landing on the body surface of the subject decreased dramatically, and a high landing suppression effect was observed.
実施例1と同様にして、プロフルトリンをEMMA樹脂に9.2重量%練り込み、ネット状樹脂製剤を得、これを検体として以下の評価試験を行った。 In the same manner as in Example 1, 9.2% by weight of profluthrin was kneaded into EMMA resin to obtain a net-like resin preparation, and the following evaluation test was performed using this as a specimen.
〈評価試験〉
予めヒトスジシマカが多く発生している場所に被験者が立って、ヒトスジシマカ雌成虫の誘引行動を確認した後、被験者の腰に上記検体(重量:22g、大きさ:長さ100cm×幅11cm×厚さ0.8mm)を2つ折りにして吊下げ、ヒトスジシマカ雌成虫の行動を観察した。なお、試験は、気温26℃、微風の環境下で行った。試験結果を表4に示す。
実施例4の評価試験結果から明らかなように、ブランクでは、被験者の体表面に誘引されたヒトスジシマカ雌成虫の個体数は多く、ランディングする個体数も多かった。これに対して、検体を吊下げた場合には、被験者の体表面へのランディング個体数は激減し、高いランディング抑制効果が認められた。
<Evaluation test>
After the subject stands in advance in a place where a large number of Aedes albopictus has occurred in advance and confirms the attracting behavior of adult Aedes albopictus, the above specimen (weight: 22 g, size: length 100 cm × width 11 cm × thickness 0.8) is placed on the subject's waist. mm) was folded in half, and the behavior of adult females of Aedes albopictus was observed. The test was conducted in an environment with a temperature of 26 ° C. and a slight wind. The test results are shown in Table 4.
As is clear from the evaluation test results of Example 4, in the blank, the number of adult human striped mosquitoes attracted to the body surface of the subject was large, and the number of individuals landing was also large. On the other hand, when the specimen was suspended, the number of individuals landing on the body surface of the subject decreased dramatically, and a high landing suppression effect was observed.
実施例1と同様にして、エンペントリンをEMMA樹脂に9.7重量%練り込み、ネット状樹脂製剤を得、これを検体として以下の評価試験を行った。 In the same manner as in Example 1, 9.7% by weight of empentrin was incorporated into EMMA resin to obtain a net-like resin preparation, and the following evaluation test was performed using this as a specimen.
〈評価試験〉
予めヒトスジシマカ(雌)が多く発生している場所に被験者が立って、ヒトスジシマカ雌成虫の誘引行動を確認した後、被験者の腰に上記検体(重量:22g、大きさ:長さ100cm×幅11cm×厚さ0.8mm)を2つ折りにして吊下げ、ヒトスジシマカ雌成虫の行動を観察した。なお、試験は、気温26℃、微風の環境下で行った。試験結果を表5に示す。
実施例5の評価試験結果から明らかなように、ブランクでは、被験者の体表面に誘引されたヒトスジシマカ雌成虫の個体数は多く、ランディングする個体数も多かった。これに対して、検体を吊下げた場合には、被験者の体表面へのランディング個体数は激減し、高いランディング抑制効果が認められた。
<Evaluation test>
After the subject stands in advance in a place where a large number of Aedes aegypti (female) has been generated in advance and confirms the attraction behavior of adult Aedes aegypti, the above-mentioned specimen (weight: 22 g, size: length 100 cm × width 11 cm ×) The thickness of 0.8 mm) was folded in half and suspended, and the behavior of adult human mosquitoes was observed. The test was conducted in an environment with a temperature of 26 ° C. and a slight wind. The test results are shown in Table 5.
As is clear from the evaluation test results of Example 5, in the blank, the number of adult human striped mosquitoes attracted to the body surface of the subject was large, and the number of individuals landing was also large. On the other hand, when the specimen was suspended, the number of individuals landing on the body surface of the subject decreased dramatically, and a high landing suppression effect was observed.
[試験例]
効力試験現場での風速とランディング抑制との関係を調べた。すなわち、実施例4の評価試験を行った効力試験現場周辺の風速を、当該場所で1時間にわたって風速センサを用いて測定し、平均風速を求めた。そして、実施例4で得たネット状樹脂製剤を用いて、かつ実施例4の評価試験と同様にして、風速の異なる時間および場所でのヒトスジシマカ雌成虫に対するランディング抑制率を求めた。その結果を表6に示す。
表6から、平均風速が0.08m/秒から3.3m/秒までの範囲でヒトスジシマカ雌成虫の誘引行動が観察されたが、いずれの風速域でも高いランディング抑制効果が認められた。
[Test example]
The relationship between wind speed and landing suppression at the efficacy test site was investigated. That is, the wind speed around the efficacy test site where the evaluation test of Example 4 was performed was measured using the wind speed sensor at the place for 1 hour, and the average wind speed was obtained. Then, using the net-like resin preparation obtained in Example 4, and in the same manner as in the evaluation test of Example 4, the landing suppression rate for adult female Aedes albopictus at different times and locations of the wind speed was determined. The results are shown in Table 6.
Table 6 shows that attracting behavior of female adult white stripe moths was observed when the average wind speed was in the range of 0.08 m / sec to 3.3 m / sec, and a high landing suppression effect was observed in any wind speed range.
Claims (11)
A volatilization preparation for use in the landing suppression method according to any one of claims 1 to 5, wherein the resin contains an insecticide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004361118A JP2006166745A (en) | 2004-12-14 | 2004-12-14 | Method for controlling landing of insect pest, volatilization apparatus and volatile preparation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004361118A JP2006166745A (en) | 2004-12-14 | 2004-12-14 | Method for controlling landing of insect pest, volatilization apparatus and volatile preparation |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2006166745A true JP2006166745A (en) | 2006-06-29 |
Family
ID=36668111
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004361118A Pending JP2006166745A (en) | 2004-12-14 | 2004-12-14 | Method for controlling landing of insect pest, volatilization apparatus and volatile preparation |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2006166745A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010090047A (en) * | 2008-10-07 | 2010-04-22 | Dainippon Jochugiku Co Ltd | Drug carrier to be mounted on air cleaner |
JPWO2009104770A1 (en) * | 2008-02-22 | 2011-06-23 | アース製薬株式会社 | Plant for chemical volatilization |
JP2013070638A (en) * | 2011-09-27 | 2013-04-22 | Fumakilla Ltd | Insect-controlling agent diffuser |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0422819U (en) * | 1990-06-14 | 1992-02-25 | ||
JPH09154470A (en) * | 1995-12-04 | 1997-06-17 | Okamoto Ind Inc | Insect repellent tool |
JPH1128040A (en) * | 1997-07-10 | 1999-02-02 | Earth Chem Corp Ltd | Vermin controlling apparatus |
JP2000325005A (en) * | 1999-05-18 | 2000-11-28 | Kyushu Medical:Kk | Method for killing larva of insect of family psychodidae and other dipterous insect and killing tool |
JP2004242668A (en) * | 2003-01-20 | 2004-09-02 | Dainippon Jochugiku Co Ltd | Agent vaporizer and method for controlling noxious insect |
-
2004
- 2004-12-14 JP JP2004361118A patent/JP2006166745A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0422819U (en) * | 1990-06-14 | 1992-02-25 | ||
JPH09154470A (en) * | 1995-12-04 | 1997-06-17 | Okamoto Ind Inc | Insect repellent tool |
JPH1128040A (en) * | 1997-07-10 | 1999-02-02 | Earth Chem Corp Ltd | Vermin controlling apparatus |
JP2000325005A (en) * | 1999-05-18 | 2000-11-28 | Kyushu Medical:Kk | Method for killing larva of insect of family psychodidae and other dipterous insect and killing tool |
JP2004242668A (en) * | 2003-01-20 | 2004-09-02 | Dainippon Jochugiku Co Ltd | Agent vaporizer and method for controlling noxious insect |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPWO2009104770A1 (en) * | 2008-02-22 | 2011-06-23 | アース製薬株式会社 | Plant for chemical volatilization |
JP2010090047A (en) * | 2008-10-07 | 2010-04-22 | Dainippon Jochugiku Co Ltd | Drug carrier to be mounted on air cleaner |
JP2013070638A (en) * | 2011-09-27 | 2013-04-22 | Fumakilla Ltd | Insect-controlling agent diffuser |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69532035T2 (en) | METHOD FOR COMBATING PAD INSECTS | |
US20040154214A1 (en) | Method and apparatus for dispersing a volatile composition | |
JPH11504627A (en) | Insecticide impregnated products for controlling flying insects | |
JP6663228B2 (en) | Volatile enclosed space pesticide | |
JP4554008B2 (en) | How to control adult mosquitoes | |
JP2002249405A (en) | Miticide composition and miticiding method | |
JP6576643B2 (en) | Volatile closed space insecticide | |
JP2009131243A (en) | Pest control device | |
JP5385501B2 (en) | Transpiration material, pre-sucking action reducing agent for blood-sucking pests, and method | |
JP2604239B2 (en) | Liquid absorption wick and chemical evaporation method | |
JP2006166745A (en) | Method for controlling landing of insect pest, volatilization apparatus and volatile preparation | |
Sugano et al. | The biological activity of a novel pyrethroid: metofluthrin | |
JPH0344305A (en) | Vermin-controlling composition | |
JP2964432B2 (en) | Acaricide composition | |
JP2002234804A (en) | Method for controlling flying insect in open air | |
JPH09308421A (en) | Insect repellent material | |
JP2001181105A (en) | Repellent | |
JP4445459B2 (en) | Chemical transpiration device | |
JP2000336007A (en) | Mite-attracting agent, miticide and mite-trapping material | |
JPH08231321A (en) | Suppressant for stinging and biting behavior of insect pest and method for suppressing stinging and biting behavior of insect pest | |
KR100763862B1 (en) | Method for controlling insect pests by vaporization of pesticides | |
JP2006070037A (en) | Insect-proof material | |
JP2001103899A (en) | Device for diffusing chemical agent | |
JP2006188527A (en) | Insect repellent | |
JP2004242668A (en) | Agent vaporizer and method for controlling noxious insect |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Effective date: 20070906 Free format text: JAPANESE INTERMEDIATE CODE: A621 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20090309 |
|
A131 | Notification of reasons for refusal |
Effective date: 20100629 Free format text: JAPANESE INTERMEDIATE CODE: A131 |
|
A02 | Decision of refusal |
Effective date: 20101026 Free format text: JAPANESE INTERMEDIATE CODE: A02 |