JP2006134587A - Electric field concentration control material, electric field concentration control member, and electric apparatus - Google Patents

Electric field concentration control material, electric field concentration control member, and electric apparatus Download PDF

Info

Publication number
JP2006134587A
JP2006134587A JP2004318875A JP2004318875A JP2006134587A JP 2006134587 A JP2006134587 A JP 2006134587A JP 2004318875 A JP2004318875 A JP 2004318875A JP 2004318875 A JP2004318875 A JP 2004318875A JP 2006134587 A JP2006134587 A JP 2006134587A
Authority
JP
Japan
Prior art keywords
electric field
field concentration
filler
concentration suppressing
suppressing material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2004318875A
Other languages
Japanese (ja)
Inventor
Tetsushi Okamoto
徹志 岡本
Hiroshi Kaneiwa
浩志 金岩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP2004318875A priority Critical patent/JP2006134587A/en
Publication of JP2006134587A publication Critical patent/JP2006134587A/en
Withdrawn legal-status Critical Current

Links

Images

Landscapes

  • Organic Insulating Materials (AREA)
  • Insulating Bodies (AREA)
  • Inorganic Insulating Materials (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide an electric field concentration control material relaxing concentration of an electric field when one is impressed, effectively restraining generation of partial discharge, treeing or the like, capable of maintaining an excellent insulation property for a long time. <P>SOLUTION: The electric field concentration control material is a complex material made by dispersing filling material in resin material. The filling material is relatively conductive comparing with the resin material. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、電界が印加された際の電界の集中を緩和することによって電気的絶縁の劣化が抑制された電界集中抑制材料およびそれを用いた電界集中抑制部材、電気機器に関する。   The present invention relates to an electric field concentration suppressing material in which deterioration of electrical insulation is suppressed by relaxing electric field concentration when an electric field is applied, an electric field concentration suppressing member using the same, and an electric device.

電気機器に使用される絶縁材料の劣化形態として電気的な劣化があり、その一部はトリーイングを伴う劣化パターンを示す。トリーイングとは、絶縁材料中に高電界が生じると電極端や絶縁材料中の不純物などを起点として放電を伴いながら絶縁材料を溶解あるいは炭化させる現象を言う。   There is an electrical deterioration as a deterioration form of an insulating material used for an electric device, and a part thereof shows a deterioration pattern with treeing. Treeing refers to a phenomenon in which when a high electric field is generated in an insulating material, the insulating material is dissolved or carbonized while being accompanied by discharge starting from an electrode end or impurities in the insulating material.

従来より、トリーの進展を止めるためにフィルム材料を積層した構造やマイカやシリカ等を充填した絶縁材料が使用されている。例えば、絶縁コイルにおいて、小さなマイカフレークを有する層を含むテープ形状またはシート形状の絶縁材料につき、マイカフレーク層の空間に配置される樹脂層中に、窒化ホウ素、窒化アルミニウム、窒化珪素、酸化アルミニウム、酸化マグネシウム、酸化ベリリウム、炭化珪素等の5W/mK以上の熱伝導率を有し、その少なくとも90重量%が粒径0.1〜15μmである粒子を含有させることが行われている(例えば、特許文献1参照。)。   Conventionally, in order to stop the progress of the tree, a structure in which film materials are laminated and an insulating material filled with mica, silica or the like are used. For example, in an insulating coil, for a tape-shaped or sheet-shaped insulating material including a layer having small mica flakes, boron nitride, aluminum nitride, silicon nitride, aluminum oxide, in a resin layer disposed in the space of the mica flake layer, Inclusion of particles having a thermal conductivity of 5 W / mK or more, such as magnesium oxide, beryllium oxide, silicon carbide, etc., at least 90% by weight of which has a particle size of 0.1 to 15 μm (for example, (See Patent Document 1).

また、棒状のコアおよびこのコアの外周に設けられる一次スプール、二次スプールからなる点火コイルにおいて、これら一次スプール、二次スプールの少なくともいずれか一方を樹脂基材にガラス繊維およびシリカを添加して形成し、絶縁材料であるスプールの絶縁破壊を抑制している(例えば、特許文献2参照。)。   Further, in an ignition coil composed of a rod-shaped core and a primary spool and a secondary spool provided on the outer periphery of the core, glass fiber and silica are added to a resin base at least one of the primary spool and the secondary spool. The insulation breakdown of the spool, which is an insulating material, is formed (see, for example, Patent Document 2).

しかしながら、フィルムを積層したような構造の絶縁材料では、製造法の制限が大きく、適用できる部材が限定されてしまう。また、マイカやシリカ等を充填した絶縁材料では、電気的劣化に対する寿命が十分でないなどの課題がある。
特開昭63−110929号公報 特開2002−374646号公報
However, in the insulating material having a structure in which films are laminated, the manufacturing method is greatly limited, and applicable members are limited. In addition, the insulating material filled with mica, silica or the like has a problem that the life against electrical deterioration is not sufficient.
Japanese Unexamined Patent Publication No. 63-110929 JP 2002-374646 A

本発明は上述したような課題を解決するためになされたものであって、電界が印加された際の電界の集中を緩和することによってトリーイングの発生を抑制し、長寿命化が可能な電界集中抑制材料およびそれを用いた電界集中抑制部材、電気機器を提供することを目的としている。   The present invention has been made to solve the above-described problems, and it is possible to suppress the occurrence of treeing by relaxing the concentration of the electric field when an electric field is applied, and to extend the lifetime. An object of the present invention is to provide a concentration suppressing material, an electric field concentration suppressing member using the same, and an electric device.

本発明の電界集中抑制材料は、樹脂材料中に充填材を分散させた複合材料であって、充填材は樹脂材料と比較して導電性を有するものであることを特徴とする。また、本発明の電界集中抑制材料は、樹脂材料中に充填材を分散させた複合材料であって、充填材は印加電界に対して非線形抵抗特性を有するものであることを特徴とする。   The electric field concentration suppressing material of the present invention is a composite material in which a filler is dispersed in a resin material, and the filler has conductivity as compared with the resin material. The electric field concentration suppressing material of the present invention is a composite material in which a filler is dispersed in a resin material, and the filler has a nonlinear resistance characteristic with respect to an applied electric field.

本発明の電界集中抑制部材は、上述したような電界集中抑制材料を塗料状、フィルム状もしくはテープ状、または、型に入れ硬化させてなることを特徴とする。また、本発明の電気機器は上述したような電界集中抑制材料または電界集中抑制部材を用いてなることを特徴とする。   The electric field concentration suppressing member of the present invention is characterized in that the electric field concentration suppressing material as described above is cured by placing it in a paint, film or tape or mold. Moreover, the electric device of the present invention is characterized by using the electric field concentration suppressing material or the electric field concentration suppressing member as described above.

本発明の電界集中抑制材料によれば、樹脂材料中にこれよりも導電性の高い充填材または印加電界に対して非線形抵抗特性を有する充填材を含有させることで、電界が印加された際の電界の集中を緩和し、部分放電、トリーイング等の発生を抑制し、優れた絶縁特性を長期間維持することが可能となる。   According to the electric field concentration suppressing material of the present invention, by adding a filler having higher conductivity to the resin material or a filler having nonlinear resistance characteristics with respect to the applied electric field in the resin material, It is possible to alleviate the concentration of the electric field, suppress the occurrence of partial discharge, treeing, etc., and maintain excellent insulating characteristics for a long period of time.

また、このような電界集中抑制材料を用いて電界集中抑制部材、電気機器を作製することで、電界集中抑制部材、電気機器の製造が容易になると共に、それらの絶縁特性を維持し、長寿命化することも可能となる。   In addition, by producing an electric field concentration suppressing member and an electric device using such an electric field concentration suppressing material, it becomes easy to manufacture the electric field concentration suppressing member and the electric device, while maintaining their insulation characteristics, and a long life. It is also possible to make it.

以下、本発明について、図面を参照して説明する。   The present invention will be described below with reference to the drawings.

図1は本発明の電界集中抑制材料1の一例を示した概略図である。本発明の電界集中抑制材料1は、樹脂材料2と、この樹脂材料2に分散された充填材3とからなるものである。   FIG. 1 is a schematic view showing an example of the electric field concentration suppressing material 1 of the present invention. The electric field concentration suppressing material 1 of the present invention is composed of a resin material 2 and a filler 3 dispersed in the resin material 2.

樹脂材料2としては、例えばエポキシ樹脂、不飽和ポリエステル樹脂、フェノール樹脂等が用いられる。エポキシ樹脂としては、例えばビスフェノールA型エポキシ樹脂、ビスフェノールF型エポキシ樹脂、ビスフェノールAD型エポキシ樹脂、フェノールノボラック型エポキシ樹脂、クレゾールノボラック型エポキシ樹脂等を用いることができる。   As the resin material 2, for example, an epoxy resin, an unsaturated polyester resin, a phenol resin, or the like is used. As the epoxy resin, for example, bisphenol A type epoxy resin, bisphenol F type epoxy resin, bisphenol AD type epoxy resin, phenol novolac type epoxy resin, cresol novolak type epoxy resin, and the like can be used.

充填材3は、上述した樹脂材料2と比較して導電性を有するものである。上述した樹脂材料2の抵抗率ρがおおよそ1019〜1024[μΩ・cm]であるため、導電性を有する充填材3はこれよりも抵抗率ρが低いものであればよい。導電性を有する充填材3は、例えば抵抗率ρが100[μΩ・cm]以下であれば好ましく、10[μΩ・cm]以下であればより好ましい。 The filler 3 has conductivity compared to the resin material 2 described above. Since the resistivity ρ of the resin material 2 described above is approximately 10 19 to 10 24 [μΩ · cm], the conductive filler 3 only needs to have a resistivity ρ lower than this. For example, the conductive filler 3 preferably has a resistivity ρ of 100 [μΩ · cm] or less, and more preferably 10 [μΩ · cm] or less.

このような充填材3としては、例えばカーボン(10[μΩ・cm])、四三酸化鉄(10[μΩ・cm])、酸化クロム(1013[μΩ・cm])、酸化チタン(1018[μΩ・cm])、金(2.35[μΩ・cm])、銀(1.59[μΩ・cm])、銅(1.673[μΩ・cm])および鉄(9.71[μΩ・cm])が挙げられ、これは1種のみで用いてもよいし、2種以上を混合して用いてもよい。 Examples of such a filler 3 include carbon (10 2 [μΩ · cm]), triiron tetroxide (10 6 [μΩ · cm]), chromium oxide (10 13 [μΩ · cm]), titanium oxide ( 10 18 [μΩ · cm]), gold (2.35 [μΩ · cm]), silver (1.59 [μΩ · cm]), copper (1.673 [μΩ · cm]) and iron (9.71). [μΩ · cm]), which may be used alone or in combination of two or more.

上述した充填材3としては市販されているものを用いてもよく、このようなものとしては例えば酸化クロムとしてCRO 01PB((株)高純度化学研究所製 商品名)、酸化チタンとしてTIO 06PB((株)高純度化学研究所製 商品名)等が挙げられる。   As the filler 3 described above, a commercially available material may be used. For example, CRO 01PB (trade name, manufactured by Kojundo Chemical Laboratory Co., Ltd.) is used as chromium oxide, and TIO 06PB (trade name, manufactured by Kojundo Chemical Laboratory Co., Ltd.). (Trade name, manufactured by Kojundo Chemical Laboratory Co., Ltd.).

本発明の電界集中抑制材料1では、充填材3の導電性を樹脂材料2の導電性よりも高いものとすることで、高電界が印加された場合であってもその集中を緩和し、部分的な放電、トリーイングの発生を抑制し、絶縁特性を長期間維持することが可能となる。   In the electric field concentration suppressing material 1 of the present invention, the conductivity of the filler 3 is higher than that of the resin material 2, so that the concentration is relaxed even when a high electric field is applied. It is possible to suppress the occurrence of typical discharge and treeing and maintain the insulation characteristics for a long time.

本発明においては充填材3として上述したような導電性を有するものと共に、あるいはこれに代えて、印加電界に対して非線形抵抗特性を有するものを用いてもよい。印加電界に対して非線形抵抗特性を持つとは、一定の電界未満のときには導電性を示さず、一定の電界以上となったときに一定の導電性を示すものをいう。   In the present invention, the filler 3 may have a conductivity as described above, or alternatively, may have a nonlinear resistance characteristic with respect to an applied electric field. Having a non-linear resistance characteristic with respect to an applied electric field refers to a substance that does not exhibit conductivity when less than a certain electric field and exhibits certain conductivity when the electric field exceeds a certain electric field.

電界集中抑制材料1にこのような非線形抵抗特性を有する充填材3を分散させることで、高い電界が印加された際にその部分の充填材3のみを導電性を有するものとすることができ、電界集中抑制材料1全体として高い絶縁特性を維持したまま、電界の集中を有効に緩和し、部分的な放電、トリーイングの発生を抑制し、絶縁特性を長期間維持することが可能となる。   By dispersing the filler 3 having such a nonlinear resistance characteristic in the electric field concentration suppressing material 1, only a portion of the filler 3 can have conductivity when a high electric field is applied, The electric field concentration suppressing material 1 as a whole can maintain the insulating characteristics for a long period of time by effectively relaxing the concentration of the electric field and suppressing the occurrence of partial discharge and treeing while maintaining the high insulating characteristics.

非線形抵抗特性を持つ充填材3は、例えば電界の強さが10[kV・m−1]以上となったときに、抵抗率ρが100[μΩ・cm]以下となるものであれば好ましく、10[μΩ・cm]以下となるものであればさらに好ましい。 The filler 3 having non-linear resistance characteristics is preferable as long as the resistivity ρ is 100 [μΩ · cm] or less when, for example, the electric field strength is 10 3 [kV · m −1 ] or more. More preferably, it is 10 [μΩ · cm] or less.

このような非線形抵抗特性を持つ充填材3としては、具体的には酸化亜鉛、炭化珪素および酸化錫等が挙げられる。酸化亜鉛は電界の強さが2×10[kV・m−1]以上で抵抗率ρが100[μΩ・cm]以下となり、炭化珪素は電界の強さが10[kV・m−1]以上で抵抗率ρが100[μΩ・cm]以下となり、酸化錫は電界の強さが10[kV・m−1]以上で抵抗率ρが100[μΩ・cm]以下となる。このような非線形抵抗特性を持つ充填材3は、1種のみで用いてもよいし、2以上を混合して用いてもよい。 Specific examples of the filler 3 having such nonlinear resistance characteristics include zinc oxide, silicon carbide, and tin oxide. Zinc oxide has an electric field strength of 2 × 10 3 [kV · m −1 ] or more and a resistivity ρ of 100 [μΩ · cm] or less, and silicon carbide has an electric field strength of 10 3 [kV · m −1]. ] The resistivity ρ is 100 [μΩ · cm] or less, and tin oxide has an electric field strength of 10 3 [kV · m −1 ] or more and a resistivity ρ of 100 [μΩ · cm] or less. The filler 3 having such nonlinear resistance characteristics may be used alone or in combination of two or more.

上述した非線形抵抗特性を持つ充填材3としては市販されているものを用いてもよく、酸化亜鉛としてZNO 01PB((株)高純度化学研究所製 商品名)、炭化珪素として#3000 SiC(信濃電気製錬(株)製 商品名)、酸化錫としてSNO 01PB((株)高純度化学研究所製 商品名)等が挙げられる。   As the filler 3 having the nonlinear resistance characteristic described above, a commercially available material may be used. ZNO 01PB (trade name, manufactured by Kojundo Chemical Laboratory Co., Ltd.) is used as zinc oxide, and # 3000 SiC (Shinano) is used as silicon carbide. Electric Smelting Co., Ltd., trade name), SNO 01PB (trade name, manufactured by Kojundo Chemical Laboratory Co., Ltd.) and the like can be cited as tin oxide.

導電性または非線形抵抗特性を有する充填材3は、平均粒径が0.001μm〜100μmであれば好ましく、0.1μm〜10μmであればより好ましい。平均粒径が0.001μm未満であると高電界が印加された際に電界の集中が十分に緩和されず、部分的な放電の発生を十分に抑制することが困難となるおそれがあり好ましくない。平均粒径が100μmを超えると、電界集中抑制材料1全体として見た場合の絶縁特性が十分でなくなり、またフィルム状への成形が困難となるおそれがあるため好ましくない。   The filler 3 having conductivity or non-linear resistance characteristics preferably has an average particle diameter of 0.001 μm to 100 μm, and more preferably 0.1 μm to 10 μm. If the average particle size is less than 0.001 μm, the concentration of the electric field is not sufficiently relaxed when a high electric field is applied, and it may be difficult to sufficiently suppress the occurrence of partial discharge. . When the average particle diameter exceeds 100 μm, the insulating properties when viewed as the whole electric field concentration suppressing material 1 are not sufficient, and it may be difficult to form into a film shape.

電界集中抑制材料1における充填材3の含有量は、電界集中抑制材料1の全体体積に対して5体積%以上、33体積%以下とすることが好ましい。充填材3の含有量が5体積%未満であると高電界が印加された際に電界の集中を十分に緩和することができず、部分的な放電の発生を抑制することが困難となるおそれがあるため好ましくない。33体積%を超えると、電界集中抑制材料1全体として見た場合の絶縁特性が十分でなくなるおそれがあるため好ましくない。   The content of the filler 3 in the electric field concentration suppressing material 1 is preferably 5% by volume or more and 33% by volume or less with respect to the entire volume of the electric field concentration suppressing material 1. If the content of the filler 3 is less than 5% by volume, the concentration of the electric field cannot be sufficiently relaxed when a high electric field is applied, and it may be difficult to suppress partial discharge. This is not preferable. Exceeding 33% by volume is not preferable because the insulating properties when viewed as the entire electric field concentration suppressing material 1 may be insufficient.

本発明の電界集中抑制材料1においては、上述したような樹脂材料2および充填材3の他に、必要に応じて樹脂材料を硬化させるための硬化剤、硬化促進剤、粘度を調整するための溶剤等を適宜添加することが好ましい。   In the electric field concentration suppressing material 1 of the present invention, in addition to the resin material 2 and the filler 3 as described above, a curing agent for curing the resin material, a curing accelerator, and a viscosity for adjusting the viscosity as necessary. It is preferable to add a solvent or the like as appropriate.

また、本発明の電界集中抑制材料1には、例えば図2に示すように、樹脂材料2および導電性あるいは非線形抵抗特性を有する充填材3の他に、無機充填材4を含有させてもよい。   In addition, the electric field concentration suppressing material 1 of the present invention may contain an inorganic filler 4 in addition to the resin material 2 and the filler 3 having conductive or nonlinear resistance characteristics, as shown in FIG. .

このような無機充填材4を含有させることで、電界が印加された際の電界の集中をさらに緩和し、部分的な放電を抑制することができると共に、電界集中抑制材料1全体として見た場合の絶縁特性も向上させることができる。   When such an inorganic filler 4 is included, the concentration of the electric field when an electric field is applied can be further relaxed, partial discharge can be suppressed, and the electric field concentration suppressing material 1 as a whole can be suppressed. Insulation characteristics can also be improved.

無機充填材4は絶縁物であればよく、例えばマイカ、アルミナ(Al)、窒化ホウ素(BN)が挙げられ、これらは1種のみを用いてもよいし、2種以上を混合して用いてもよい。 The inorganic filler 4 may be an insulating material such as mica, alumina (Al 2 O 3 ), and boron nitride (BN). These may be used alone or in combination of two or more. May be used.

無機充填材4はアスペクト比1:10以上の鱗片状無機充填材が好適に用いられる。このようなアスペクト比を有する鱗片状無機充填材4を用いることで、電界集中抑制材料1の部分的な放電をさらに抑制し、電界集中抑制材料1全体として見た場合の絶縁特性も向上させることができる。   As the inorganic filler 4, a scale-like inorganic filler having an aspect ratio of 1:10 or more is preferably used. By using the scale-like inorganic filler 4 having such an aspect ratio, the partial discharge of the electric field concentration suppressing material 1 is further suppressed, and the insulation characteristics when viewed as the electric field concentration suppressing material 1 as a whole are improved. Can do.

電界集中抑制材料1に無機充填材4を含有させる場合には、電界集中抑制材料1の全体体積に対して無機充填材4の含有量が60体積%以上となるようにすれば好ましい。無機充填材4の含有量をこのようなものとすることで、電界集中抑制材料1の部分的な放電の抑制および電界集中抑制材料1全体として見た場合の絶縁特性を十分なものとすることができる。   In the case where the inorganic filler 4 is contained in the electric field concentration suppressing material 1, it is preferable that the content of the inorganic filler 4 is 60% by volume or more with respect to the entire volume of the electric field concentration suppressing material 1. By making the content of the inorganic filler 4 as described above, the partial discharge suppression of the electric field concentration suppressing material 1 and the insulation characteristics when viewed as the electric field concentration suppressing material 1 as a whole are made sufficient. Can do.

なお、電界集中抑制材料1に無機充填材4を含有させる場合、導電性あるいは非線形抵抗特性を持つ充填材3は、電界集中抑制材料1の全体体積から無機充填材4の体積を除いた体積に対して5体積%以上、33体積%以下の含有量とすることが好ましい。   In addition, when the electric field concentration suppressing material 1 contains the inorganic filler 4, the filler 3 having conductive or non-linear resistance characteristics has a volume obtained by subtracting the volume of the inorganic filler 4 from the entire volume of the electric field concentration suppressing material 1. On the other hand, the content is preferably 5% by volume or more and 33% by volume or less.

上述した本発明の電界集中抑制材料1は、例えば樹脂材料2中に導電性を有する充填材3および非線形抵抗特性を持つ充填材3のうち少なくとも一方を所定量添加して十分に混合することによって製造することができる。また、無機充填材4を含有させる場合には、樹脂材料2中に導電性を有する充填材3および非線形抵抗特性を持つ充填材3のうち少なくとも一方を所定量添加するとともに、無機充填材4を所定量添加して十分に混合することによって製造することができる。   The electric field concentration suppressing material 1 of the present invention described above is obtained by adding a predetermined amount of, for example, a filler 3 having conductivity and a filler 3 having nonlinear resistance characteristics to a resin material 2 and mixing them sufficiently. Can be manufactured. When the inorganic filler 4 is contained, at least one of the conductive filler 3 and the filler 3 having nonlinear resistance characteristics is added to the resin material 2 in a predetermined amount, and the inorganic filler 4 is added. It can be produced by adding a predetermined amount and mixing well.

このようにして得られた電界集中抑制材料1は、例えばそのままの状態でコイルに含浸、硬化させて用いることができる。また、本発明の電界集中抑制材料1は樹脂材料2中に導電性を有する充填材3および非線形抵抗特性を持つ充填材3のうち少なくとも一方を添加したものであるため、従来のフィルムを積層したような構造の絶縁材料に比べて適用できる用途、部材の制限が少なく、各種の用途、部材に適用することが可能である。   The electric field concentration suppressing material 1 obtained in this way can be used by, for example, impregnating and curing a coil as it is. In addition, the electric field concentration suppressing material 1 of the present invention is obtained by adding at least one of a conductive filler 3 and a non-linear filler 3 to the resin material 2, and thus a conventional film is laminated. Applications and members that can be applied are smaller than those of the insulating material having such a structure, and can be applied to various applications and members.

例えば電界集中抑制材料1に他の樹脂材料、溶剤等を添加して塗料状とし、絶縁させようとする物に塗布して絶縁性の塗膜を形成するようにして用いてもよい。また、電界集中抑制材料1は薄く延ばした後に硬化させてフィルム状部材としてもよいし、このようにフィルム状部材とした後に少なくとも一方の主面に粘着性材料を塗布してテープ状部材とし、絶縁させようとする物に巻回、貼着するようにして用いてもよい。これらフィルム状部材、テープ状部材は単独で用いてもよいし、複数枚を積層して用いてもよい。   For example, another resin material, a solvent, or the like may be added to the electric field concentration suppressing material 1 to form a paint and applied to an object to be insulated to form an insulating coating film. In addition, the electric field concentration suppressing material 1 may be thinly stretched and then cured to form a film-like member, and after forming a film-like member in this manner, an adhesive material is applied to at least one main surface to obtain a tape-like member, It may be used by winding and sticking on an object to be insulated. These film-like members and tape-like members may be used alone, or a plurality of them may be laminated.

さらに、電界集中抑制材料1はガラスクロス等に含浸、硬化させてシート状部材として用いてもよい。また、電界集中抑制材料1を型に注入し、硬化させて所定の形状を有する部材の作製に用いてもよい。   Furthermore, the electric field concentration suppressing material 1 may be used as a sheet-like member by impregnating and curing glass cloth or the like. Alternatively, the electric field concentration suppressing material 1 may be injected into a mold and cured to produce a member having a predetermined shape.

以下、本発明の電界集中抑制材料、電界集中抑制部材、電気機器について、実施例を参照して具体的に説明する。   Hereinafter, the electric field concentration suppressing material, the electric field concentration suppressing member, and the electric apparatus of the present invention will be specifically described with reference to examples.

(実施例1)
樹脂材料としてのビスフェノールA型エポキシ樹脂 EP828(油化シェル製 商品名)、この樹脂材料に比較して導電性を有する充填材として、平均粒径1μmの酸化クロム CRO 01PB((株)高純度化学研究所製 商品名)を用意した。
Example 1
Bisphenol A type epoxy resin EP828 (trade name made by Yuka Shell) as a resin material, and chromium oxide CRO 01PB (Co., Ltd.) with an average particle diameter of 1 μm as a filler having conductivity compared to this resin material (Trade name, manufactured by Research Institute) was prepared.

ビスフェノールA型エポキシ樹脂と酸化クロムとの合計体積に対して酸化クロムが20体積%となるように、ビスフェノールA型エポキシ樹脂と酸化クロムとを配合し、混練して電界集中抑制材料を得た。   A bisphenol A-type epoxy resin and chromium oxide were blended and kneaded so that the chromium oxide was 20% by volume with respect to the total volume of the bisphenol A-type epoxy resin and chromium oxide, to obtain an electric field concentration suppressing material.

図3、図4に示すように、10μmのギャップを開けたガラス平板5a、5b間に電界集中抑制材料1を充填するとともに、針電極6および平面電極7をそれらの間隔が2mmとなるように挟み込み、針−平面電極を形成した。この針−平面電極に交流電圧を印加し、2kV/sで上昇させて部分放電発生電圧を測定した。なお、部分放電発生電圧の測定は、電流パルス法を用いて行った。   As shown in FIGS. 3 and 4, the electric field concentration suppressing material 1 is filled between the glass flat plates 5 a and 5 b with a gap of 10 μm, and the distance between the needle electrode 6 and the planar electrode 7 is 2 mm. A needle-planar electrode was formed by sandwiching. An AC voltage was applied to the needle-planar electrode and the voltage was increased at 2 kV / s to measure the partial discharge generation voltage. The partial discharge generation voltage was measured using a current pulse method.

また比較のために、酸化クロムを含有させずに、ビスフェノールA型エポキシ樹脂のみを用いて同様の測定を行った。結果を図5に示す。   For comparison, the same measurement was performed using only bisphenol A type epoxy resin without containing chromium oxide. The results are shown in FIG.

図5に示すように、酸化クロムを含有させたものは、酸化クロムを含有させなかったものに比較して、部分放電発生電圧が約2倍となることが認められた。一般に部分放電は針電極の先端部分から発生するものであるため、本発明のように樹脂材料中に導電性の充填材を含有させることで、針電極の先端部分の電界を緩和し、部分放電が発生する電圧を上昇させることが可能となる。   As shown in FIG. 5, it was recognized that the partial discharge generation voltage was approximately doubled in the case of containing chromium oxide as compared with the case of not containing chromium oxide. In general, partial discharge is generated from the tip portion of the needle electrode. Therefore, by including a conductive filler in the resin material as in the present invention, the electric field at the tip portion of the needle electrode is relaxed and partial discharge is performed. It becomes possible to raise the voltage which generate | occur | produces.

なお、本実施例では樹脂材料に比較して導電性を有する充填材として酸化クロムを用いた例を示したが、このような効果は酸化クロムに限られず、導電性を有するものであれば得られるものであり、例えばカーボン、四三酸化鉄、酸化チタン、金、銀、銅および鉄等の充填材を用いても同様の効果が得られる。   In this example, chromium oxide was used as the filler having conductivity compared to the resin material. However, this effect is not limited to chromium oxide, and any material having conductivity can be obtained. For example, the same effect can be obtained by using fillers such as carbon, iron trioxide, titanium oxide, gold, silver, copper, and iron.

(実施例2)
樹脂材料としてのビスフェノールA型エポキシ樹脂 EP828(油化シェル製 商品名)、印加電界に対して非線形抵抗特性を有する充填材としての平均粒径1μmの酸化亜鉛 ZNO 01PB((株)高純度化学研究所製 商品名)を用意した。
(Example 2)
Bisphenol A type epoxy resin EP828 (trade name, manufactured by Yuka Shell) as a resin material, zinc oxide ZNO 01PB with an average particle diameter of 1 μm as a filler having a nonlinear resistance characteristic against an applied electric field (high purity chemical research) (Product name).

ビスフェノールA型エポキシ樹脂と酸化亜鉛との合計体積に対して酸化亜鉛が20体積%となるように、ビスフェノールA型エポキシ樹脂に酸化亜鉛を添加し、混練して電界集中抑制材料を得た。   Zinc oxide was added to the bisphenol A type epoxy resin and kneaded so that the zinc oxide was 20% by volume with respect to the total volume of the bisphenol A type epoxy resin and zinc oxide, thereby obtaining an electric field concentration suppressing material.

図3、図4に示すように、10μmのギャップを開けたガラス平板5a、5b間に電界集中抑制材料1を充填するとともに、針電極6および平面電極7をそれらの間隔が2mmとなるように挟み込み、針−平面電極を形成した。この針−平面電極に交流電圧を印加し、絶縁破壊するまでの時間を測定した。なお、印加電圧は周波数50Hz、20kVrmsとした。   As shown in FIGS. 3 and 4, the electric field concentration suppressing material 1 is filled between the glass flat plates 5 a and 5 b with a gap of 10 μm, and the distance between the needle electrode 6 and the planar electrode 7 is 2 mm. A needle-planar electrode was formed by sandwiching. An AC voltage was applied to the needle-plane electrode, and the time until dielectric breakdown was measured. The applied voltage was a frequency of 50 Hz and 20 kVrms.

また比較のために、ビスフェノールA型エポキシ樹脂のみのもの、ビスフェノールA型エポキシ樹脂に平均粒径1μmのアルミナ ALO 01PB((株)高純度化学研究所製 商品名)を全体体積に対して20体積%となるように含有させたものを作製し、同様の測定を行った。結果を図6に示す。   For comparison, only bisphenol A type epoxy resin, alumina bisphenol A type epoxy resin with an average particle diameter of 1 μm, ALO 01PB (trade name, manufactured by Kojundo Chemical Laboratory Co., Ltd.), 20 volumes with respect to the total volume. What was contained so that it might become% was produced, and the same measurement was performed. The results are shown in FIG.

図6に示すように、アルミナを含有させたものに比べて、酸化亜鉛を含有させたものは、絶縁破壊するまでの時間が5割程度長くなることが認められた。絶縁破壊は針電極先端から電気トリーが成長し、電極間を短絡することによって起きる。本発明のように樹脂材料中に印加電界に対して非線形抵抗特性を有する充填材を含有させることで、針電極の先端部分の電界を緩和し、トリーの進展を抑制することにより絶縁破壊までの時間を大幅に延長することが可能となる。   As shown in FIG. 6, it was recognized that the time until dielectric breakdown of the material containing zinc oxide was about 50% longer than that containing alumina. Dielectric breakdown occurs when an electrical tree grows from the tip of the needle electrode and short-circuits between the electrodes. By including a filler having non-linear resistance characteristics with respect to the applied electric field in the resin material as in the present invention, the electric field at the tip of the needle electrode is relaxed, and the progress of the tree is suppressed to suppress the breakdown. The time can be greatly extended.

なお、本実施例では印加電界に対して非線形抵抗特性を有する充填材として酸化亜鉛を用いた例を示したが、このような効果は酸化亜鉛に限られず、印加電界に対して非線形抵抗特性を有するものであれば得られるものであり、例えば炭化珪素や酸化錫等の充填材についても同様の効果が得られる。   In this example, zinc oxide was used as a filler having nonlinear resistance characteristics with respect to the applied electric field. However, this effect is not limited to zinc oxide, and nonlinear resistance characteristics with respect to the applied electric field are exhibited. If it has, it will be obtained, and the same effect is acquired also about fillers, such as a silicon carbide and a tin oxide, for example.

(実施例3)
図7は、マイカ板8の作製例を示したものである。以下、マイカ板8の作製例について説明する。
(Example 3)
FIG. 7 shows an example of manufacturing the mica plate 8. Hereinafter, a production example of the mica plate 8 will be described.

まず、印加電界に対して非線形抵抗を持つ充填材3として酸化亜鉛 ZNO 01PB((株)高純度化学研究所製 商品名)、無機充填材4としてアスペクト比1:2000、平均最大粒径200μmの鱗片状マイカを用意し、両者を溶媒中に均一に分散させた後、目の細かいクロスですき、マイカと酸化亜鉛とからなるマイカペーパー9を作製した。   First, zinc oxide ZNO 01PB (trade name, manufactured by Kojundo Chemical Laboratory Co., Ltd.) is used as the filler 3 having a nonlinear resistance to the applied electric field, and the aspect ratio is 1: 2000 and the average maximum particle size is 200 μm as the inorganic filler 4. After scaly mica was prepared and both were uniformly dispersed in a solvent, mica paper 9 made of mica and zinc oxide was prepared by finely crushed cloth.

このマイカペーパー9とガラスクロス10とを張り合わせた後、エポキシ樹脂2を含浸させ、プレス処理することによりマイカ板8を得た。   After the mica paper 9 and the glass cloth 10 were bonded together, the mica plate 8 was obtained by impregnating the epoxy resin 2 and pressing.

無機充填材4として鱗片状のマイカを用いることで、バリア効果によるトリー成長抑制効果を得ることができる。さらに、非線形抵抗を持つ充填材3としての酸化亜鉛の効果により、マイカ間の電気トリーの成長も抑制することもできる。   By using scaly mica as the inorganic filler 4, a tree growth suppression effect due to the barrier effect can be obtained. Furthermore, the growth of electric trees between mica can also be suppressed by the effect of zinc oxide as the filler 3 having a non-linear resistance.

なお、本実施例では無機充填材4としてマイカを用いたが、マイカに代えてシリカやアルミナなどを用いても同様の効果を得ることができる。また、マイカと共にあるいはそれに代えてナノ微粒子を用いても、トリー成長抑制効果が期待できる。   In this example, mica was used as the inorganic filler 4, but the same effect can be obtained by using silica or alumina instead of mica. In addition, even if nanoparticle is used together with or instead of mica, a tree growth suppressing effect can be expected.

(実施例4)
本発明の電界集中抑制材料を塗料として用いた例について説明する。樹脂材料としてのビスフェノールA型エポキシ樹脂 EP828(油化シェル製 商品名)、硬化剤としての酸無水物硬化剤および印加電界に対して非線形抵抗を持つ充填材としての酸化亜鉛 ZNO 01PB((株)高純度化学研究所製 商品名)を、遊星型混練機で混練して電界集中抑制材料を得た。なお、酸化亜鉛は全体体積に対して60体積%となるようにした。
Example 4
An example in which the electric field concentration suppressing material of the present invention is used as a paint will be described. Bisphenol A type epoxy resin EP828 (trade name, manufactured by Yuka Shell) as a resin material, acid anhydride curing agent as a curing agent, and zinc oxide ZNO 01PB as a filler having a non-linear resistance against an applied electric field (Corporation) High purity chemical laboratory product name) was kneaded with a planetary kneader to obtain an electric field concentration suppressing material. Zinc oxide was 60% by volume with respect to the total volume.

さらに、トルエンとメチルエチルケトンとを重量比で7:3の割合で配合した溶剤を用意し、上述した電界集中抑制材料と溶剤とを重量比で8:2となるように配合し、フラスコ内で1時間混練し塗料を得た。   Furthermore, a solvent in which toluene and methyl ethyl ketone are blended at a weight ratio of 7: 3 is prepared, and the above-described electric field concentration suppressing material and the solvent are blended so as to have a weight ratio of 8: 2. Kneading for a time gave a paint.

図8に示すように、導体層11の両面に形成された絶縁層12、13上にこの塗料を塗布し、約180℃にて5時間硬化させて塗膜14、15を形成し、さらに電極16を設けた。この導体層11と電極16との間に50Hz交流電圧をかけ、放電の発生を観測した。また、比較のため塗膜を形成しない以外は同様の構成を有するものを作製し、測定を行った。   As shown in FIG. 8, this paint is applied on the insulating layers 12 and 13 formed on both surfaces of the conductor layer 11, and cured at about 180 ° C. for 5 hours to form the coating films 14 and 15, and further the electrodes 16 was provided. A 50 Hz AC voltage was applied between the conductor layer 11 and the electrode 16, and the occurrence of discharge was observed. For comparison, a sample having the same configuration except that no coating film was formed was prepared and measured.

その結果、本塗料を塗布しなかったものは約40kVrmsで電極から放電が発生したのに対して、本塗料を塗布したものは75kVrmsで放電が発生し、本塗料を用いることにより放電の発生電圧を大幅に向上できることが認められた。   As a result, a discharge was generated from the electrode at about 40 kV rms when the paint was not applied, whereas a discharge was generated at 75 kV rms when the paint was applied. It has been found that can be greatly improved.

(実施例5)
本発明の電界集中抑制材料をフィルム状の部材とした例について説明する。樹脂材料として高密度ポリエチレンを用意し、印加電界に対して非線形抵抗を持つ充填材として酸化亜鉛 ZNO 01PB((株)高純度化学研究所製 商品名)を用意した。酸化亜鉛は吸着水分を取り除くため100℃で1時間加熱処理した。
(Example 5)
An example in which the electric field concentration suppressing material of the present invention is a film-like member will be described. High-density polyethylene was prepared as a resin material, and zinc oxide ZNO 01PB (trade name, manufactured by Kojundo Chemical Laboratory Co., Ltd.) was prepared as a filler having a nonlinear resistance to an applied electric field. Zinc oxide was heat-treated at 100 ° C. for 1 hour to remove adsorbed moisture.

高密度ポリエチレンと酸化亜鉛とを、全体体積に対して酸化亜鉛が10体積%となるように配合し、140℃で15分間混練し、30℃に冷却した後、3mm角に裁断した。このような140℃での混練、冷却、裁断を3度行った後、これを150℃で10分間ホットプレスし、フィルム状の電界集中抑制部材を作製した。   High density polyethylene and zinc oxide were blended so that the zinc oxide was 10% by volume with respect to the entire volume, kneaded at 140 ° C. for 15 minutes, cooled to 30 ° C., and then cut into 3 mm squares. After such kneading, cooling and cutting at 140 ° C. were performed three times, this was hot pressed at 150 ° C. for 10 minutes to produce a film-like electric field concentration suppressing member.

このようにして作製したフィルム状電界集中抑制部材は、印加電界に対して非線形抵抗を持つ充填材を含有するため、トリーが進展する際のトリー先端部分の電界を緩和し、トリーの進展を有効に抑制することができる。   The film-like electric field concentration suppressing member produced in this way contains a filler having a non-linear resistance to the applied electric field, so that the electric field at the tip of the tree when the tree progresses is relaxed, and the tree progress is effective. Can be suppressed.

(実施例6)
本発明の電界集中抑制材料をガラスクロスに含浸させたシート状部材の例について説明する。樹脂材料としてのビスフェノールA型エポキシ樹脂 EP828(油化シェル製 商品名)、印加電界に対して非線形抵抗を持つ充填材としての酸化亜鉛 ZNO 01PB((株)高純度化学研究所製 商品名)を、溶剤であるメチルエチルケトンに添加し、攪拌器で30分間混合して電界集中抑制材料を作製した。なお、酸化亜鉛は全体体積に対して10体積%となるように配合した。
(Example 6)
An example of a sheet-like member obtained by impregnating a glass cloth with the electric field concentration suppressing material of the present invention will be described. Bisphenol A type epoxy resin EP828 (trade name, manufactured by Yuka Shell) as a resin material, and zinc oxide ZNO 01PB (trade name, manufactured by Kojundo Chemical Laboratory Co., Ltd.) as a filler having a nonlinear resistance to an applied electric field. Then, it was added to methyl ethyl ketone as a solvent and mixed with a stirrer for 30 minutes to prepare an electric field concentration suppressing material. Zinc oxide was blended so as to be 10% by volume with respect to the entire volume.

図9に示すように、この電界集中抑制材料をガラスクロス17に含浸させ、150℃でプレス硬化することによって、シート状部材を得た。   As shown in FIG. 9, a glass cloth 17 was impregnated with this electric field concentration suppressing material and press-cured at 150 ° C. to obtain a sheet-like member.

このようなシート状部材は印加電界に対して非線形抵抗を持つ充填材を含むためトリーの成長が抑制でき、またガラスクロスに含浸させているため機械的強度も確保することができる。また、このようなシート状部材は複数枚積層してプレス硬化して、積層板とすることも可能である。   Since such a sheet-like member includes a filler having a non-linear resistance to an applied electric field, growth of trees can be suppressed, and mechanical strength can be ensured because glass cloth is impregnated. Also, a plurality of such sheet-like members can be laminated and press-cured to form a laminated plate.

(実施例7)
図10は、本発明の電界集中抑制材料を用いた樹脂板18の作製例を示したものである。樹脂板18は、例えば次のようにして作製される。
(Example 7)
FIG. 10 shows an example of manufacturing the resin plate 18 using the electric field concentration suppressing material of the present invention. The resin plate 18 is produced as follows, for example.

樹脂材料としてのビスフェノールA型エポキシ樹脂 EP828(油化シェル製 商品名)、印加電界に対して非線形抵抗を持つ充填材としての酸化亜鉛 ZNO 01PB((株)高純度化学研究所製 商品名)を、全体体積に対して酸化亜鉛が10体積%となるように配合して攪拌器で30分間混合して電界集中抑制材料を作製する。   Bisphenol A type epoxy resin EP828 (trade name made by Yuka Shell) as a resin material, zinc oxide ZNO 01PB (trade name made by Kojundo Chemical Laboratory Co., Ltd.) as a filler having a nonlinear resistance to an applied electric field Then, the zinc oxide is mixed at 10% by volume with respect to the whole volume, and mixed with a stirrer for 30 minutes to produce an electric field concentration suppressing material.

図10に示すように、上型19と下型20との間に電界集中抑制材料を流し込み、150℃で加熱硬化することにより樹脂板18を作製する。このようにして作製された樹脂板18は、印加電界に対して非線形抵抗を持つ充填材を含むため、優れたトリー成長抑制機能を示す。   As shown in FIG. 10, an electric field concentration suppressing material is poured between the upper mold 19 and the lower mold 20, and the resin plate 18 is produced by heat curing at 150 ° C. The resin plate 18 produced in this manner includes a filler having a non-linear resistance to the applied electric field, and thus exhibits an excellent tree growth suppressing function.

(実施例8)
図11は、電気機器の一例としてのモールドコイル21の作製例を示した断面図である。このようなモールドコイル21は、例えば以下のようして作製することができる。
(Example 8)
FIG. 11 is a cross-sectional view illustrating an example of manufacturing a molded coil 21 as an example of an electric device. Such a molded coil 21 can be manufactured as follows, for example.

まず、実施例7と同様にして一方の面に凹凸部を有する樹脂板18を作製する。樹脂板18の一方の面に凹凸部を形成するには、例えば図10に示されるように、一方の金型である下型20に凹凸部を設けて成形を行えばよい。   First, in the same manner as in Example 7, a resin plate 18 having a concavo-convex portion on one surface is produced. In order to form the concavo-convex portion on one surface of the resin plate 18, for example, as shown in FIG. 10, the concavo-convex portion may be provided in the lower mold 20 that is one mold.

樹脂板18を角筒22の外側に貼り付けた後、樹脂板18の凹部に沿って銅線23を巻きつけ、これらを金型に入れエポキシ樹脂24を流し込み硬化させる。   After the resin plate 18 is affixed to the outside of the square tube 22, the copper wire 23 is wound along the concave portion of the resin plate 18, and these are put into a mold and the epoxy resin 24 is poured and cured.

このようなモールドコイル21によれば、銅線23から発生したトリーの成長を有効に抑制することにより、寿命の長いモールドコイルとすることができる。   According to such a molded coil 21, by effectively suppressing the growth of trees generated from the copper wire 23, a molded coil having a long life can be obtained.

(実施例9)
図12は、電気機器の一例としての固定子コイル25の作製例を示したものである。固定子コイル25は、実施例3と同様にして作製したマイカ板と実施例5と同様にして作製したシート状部材とを張り合わせた積層部材26を、積み重ねた角型導体27の周囲に配することによって作製することができる。
Example 9
FIG. 12 shows an example of manufacturing a stator coil 25 as an example of an electric device. The stator coil 25 is arranged around a rectangular conductor 27 in which a laminated member 26 in which a mica plate produced in the same manner as in the third embodiment and a sheet-like member produced in the same manner as in the fifth embodiment are laminated is laminated. Can be produced.

このようにして製造した固定子コイル25においては、積層部材26が優れたトリー成長抑制機能を示し、積層部材26の厚さを薄くすることもできるため、寿命が長くかつ小型な固定子コイル25とすることが可能となる。   In the stator coil 25 manufactured as described above, the laminated member 26 exhibits an excellent tree growth suppressing function, and the thickness of the laminated member 26 can be reduced. It becomes possible.

なお、本実施例ではマイカ板とシート状部材とを組み合わせた例を示したが、このようなものに限られず上述したようなフィルム状部材、テープ状部材、マイカ板、シート状部材等を適宜選択して組み合わせて使用することができ、また従来のマイカペーパー等と組み合わせて用いてもよい。   In addition, although the example which combined the mica board and the sheet-like member was shown in a present Example, it is not restricted to such a thing, A film-like member, a tape-like member, a mica board, a sheet-like member, etc. which were mentioned above suitably It can be selected and used in combination, or may be used in combination with conventional mica paper or the like.

本発明の電界集中抑制材料を示した断面図Sectional drawing which showed the electric field concentration suppression material of this invention 本発明の他の電界集中抑制材料を示した断面図Sectional drawing which showed the other electric field concentration suppression material of this invention 本発明の電界集中抑制材料の特性評価に用いた装置を示した平面図The top view which showed the apparatus used for the characteristic evaluation of the electric field concentration suppression material of this invention 本発明の電界集中抑制材料の特性評価に用いた装置を示した断面図Sectional drawing which showed the apparatus used for the characteristic evaluation of the electric field concentration suppression material of this invention トリー発生電圧を示した図Diagram showing tree generation voltage 絶縁破壊までの時間を示した図Diagram showing time to dielectric breakdown マイカ板の作製例を示した断面図Cross-sectional view showing an example of making mica plate 塗膜の特性評価に用いた装置を示した断面図Sectional view showing the equipment used to evaluate the properties of the coating シート状部材の作製例を示した断面図Sectional drawing which showed the example of preparation of a sheet-like member 樹脂板の作製過程を示した断面図Sectional view showing the process of making a resin plate モールドコイルの作製例を示した断面図Sectional view showing an example of mold coil fabrication 固定子コイルの作製例を示した断面図Sectional view showing an example of stator coil production

符号の説明Explanation of symbols

1…電界集中抑制材料、2…樹脂材料、3…樹脂材料に対して導電性を有する充填材または印加電界に対して非線形抵抗特性を有する充填材、4…無機充填材   DESCRIPTION OF SYMBOLS 1 ... Electric field concentration suppression material, 2 ... Resin material, 3 ... Filler which has electroconductivity with respect to resin material, or filler which has nonlinear resistance characteristic with respect to applied electric field, 4 ... Inorganic filler

Claims (10)

樹脂材料中に充填材を分散させた複合材料であって、前記充填材は前記樹脂材料と比較して導電性を有するものであることを特徴とする電界集中抑制材料。   An electric field concentration suppressing material, comprising: a composite material in which a filler is dispersed in a resin material, wherein the filler has conductivity as compared with the resin material. 前記導電性を有する充填材は、カーボン、四三酸化鉄、酸化クロム、酸化チタン、金、銀、銅および鉄から選ばれる少なくとも1種からなることを特徴とする請求項1記載の電界集中抑制材料。   2. The electric field concentration suppression according to claim 1, wherein the conductive filler is made of at least one selected from carbon, iron tetroxide, chromium oxide, titanium oxide, gold, silver, copper, and iron. material. 樹脂材料中に充填材を分散させた複合材料であって、前記充填材は印加電界に対して非線形抵抗特性を有するものであることを特徴とする電界集中抑制材料。   An electric field concentration-suppressing material, which is a composite material in which a filler is dispersed in a resin material, wherein the filler has nonlinear resistance characteristics with respect to an applied electric field. 前記印加電界に対して非線形抵抗特性を有する充填材は、酸化亜鉛、炭化珪素および酸化錫から選ばれる少なくとも1種からなることを特徴とする請求項3記載の電界集中抑制材料。   4. The electric field concentration suppressing material according to claim 3, wherein the filler having nonlinear resistance characteristics with respect to the applied electric field is at least one selected from zinc oxide, silicon carbide, and tin oxide. アスペクト比1:10以上の鱗片状無機充填材を含むことを特徴とする請求項1乃至4のいずれか1項記載の電界集中抑制材料。   The electric field concentration-suppressing material according to any one of claims 1 to 4, further comprising a scale-like inorganic filler having an aspect ratio of 1:10 or more. 請求項1乃至5のいずれか1項記載の電界集中抑制材料を塗料状にしてなることを特徴とする電界集中抑制部材。   An electric field concentration suppressing member comprising the electric field concentration suppressing material according to claim 1 in a paint form. 請求項1乃至5のいずれか1項記載の前記電界集中抑制材料をフィルム状またはテープ状にしてなることを特徴とする電界集中抑制部材。   The electric field concentration suppressing member according to claim 1, wherein the electric field concentration suppressing material according to claim 1 is formed in a film shape or a tape shape. 請求項1乃至5のいずれか1項記載の前記電界集中抑制材料をガラスクロスに含浸してなることを特徴とする電界集中抑制部材。   An electric field concentration suppressing member obtained by impregnating a glass cloth with the electric field concentration suppressing material according to any one of claims 1 to 5. 請求項1乃至5のいずれか1項記載の前記電界集中抑制材料を型に入れ、硬化してなることを特徴とする電界集中抑制部材。   6. An electric field concentration suppressing member, wherein the electric field concentration suppressing material according to claim 1 is placed in a mold and cured. 請求項1乃至9のいずれか1項記載の電界集中抑制材料または電界集中抑制部材を用いてなることを特徴とする電気機器。   An electric device comprising the electric field concentration suppressing material or the electric field concentration suppressing member according to any one of claims 1 to 9.
JP2004318875A 2004-11-02 2004-11-02 Electric field concentration control material, electric field concentration control member, and electric apparatus Withdrawn JP2006134587A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2004318875A JP2006134587A (en) 2004-11-02 2004-11-02 Electric field concentration control material, electric field concentration control member, and electric apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2004318875A JP2006134587A (en) 2004-11-02 2004-11-02 Electric field concentration control material, electric field concentration control member, and electric apparatus

Publications (1)

Publication Number Publication Date
JP2006134587A true JP2006134587A (en) 2006-05-25

Family

ID=36727944

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004318875A Withdrawn JP2006134587A (en) 2004-11-02 2004-11-02 Electric field concentration control material, electric field concentration control member, and electric apparatus

Country Status (1)

Country Link
JP (1) JP2006134587A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013065752A1 (en) * 2011-10-31 2013-05-10 昭和電工株式会社 Composite material, transmission sheet, transmission unit, and non-contact electric-power transmission system provided therewith
JP2014013786A (en) * 2012-07-03 2014-01-23 Toshiba Corp Nonlinear resistance material and method for producing the same
WO2017109811A1 (en) * 2015-12-21 2017-06-29 東芝三菱電機産業システム株式会社 Electrical tree test method, electrode structure, and electrode setting assembly

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013065752A1 (en) * 2011-10-31 2013-05-10 昭和電工株式会社 Composite material, transmission sheet, transmission unit, and non-contact electric-power transmission system provided therewith
JPWO2013065752A1 (en) * 2011-10-31 2015-04-02 昭和電工株式会社 Composite material, transmission sheet, transmission unit, and non-contact power transmission system including them
JP2014013786A (en) * 2012-07-03 2014-01-23 Toshiba Corp Nonlinear resistance material and method for producing the same
WO2017109811A1 (en) * 2015-12-21 2017-06-29 東芝三菱電機産業システム株式会社 Electrical tree test method, electrode structure, and electrode setting assembly
EP3396395A4 (en) * 2015-12-21 2019-08-21 Toshiba Mitsubishi-Electric Industrial Systems Corporation Electrical tree test method, electrode structure, and electrode setting assembly
US10928347B2 (en) 2015-12-21 2021-02-23 Toshiba Mitsubishi-Electric Industrial Systems Corporation Electrical tree test method, electrode structure, and electrode setting assembly

Similar Documents

Publication Publication Date Title
JP4922018B2 (en) Coil insulation for rotating electrical machines
JP4190595B2 (en) Electrical and thermal conductive laminate
JP5611485B1 (en) Insulating tape, manufacturing method thereof, and stator coil
EP2982721B1 (en) Coating material for electrical equipment, method for manufacturing coating material for electrical equipment, and encapsulated type insulating device
CN107646163B (en) Protective coating for corona shielding of electrical machines
US20130157042A1 (en) Electrically insulating material, insulating paper, and insulating tape for a high voltage rotary machine
Reading et al. An investigation into improving the breakdown strength and thermal conduction of an epoxy system using boron nitride
Yanashima et al. Effects of addition of MgO fillers with various sizes and co-addition of nano-sized SiO2 fillers on the dielectric properties of epoxy resin
Awais et al. Investigating optimal region for thermal and electrical properties of epoxy nanocomposites under high frequencies and temperatures
JP6479034B2 (en) Conductive corona shield paper, especially for outer corona shield
JP6338686B2 (en) Corona shield system for electrical machines, especially outer corona shield system
Chenyuan et al. Improvement of the electrical resistivity of epoxy resin at elevated temperature by adding a positive temperature coefficient BaTiO3-based compound
JP2003105108A (en) Heat conductive sheet
JP2006134587A (en) Electric field concentration control material, electric field concentration control member, and electric apparatus
WO2018003950A1 (en) Coil for rotary electric machine, method for producing coil for rotary electric machine, mica tape, method for producing mica tape, cured product of mica tape, and insulating article
JP6891887B2 (en) Coil for rotary electric machine, manufacturing method of coil for rotary electric machine, mica tape, cured product of mica tape and insulator
JP5159812B2 (en) Rotating electric machine
KR20170097340A (en) A planar heating film using carbon nanotube
Nagaraju et al. Investigation on the impact of nano MgO addition on dielectric properties and space charge behavior of epoxy resin AlN nanocomposites
JP2007200986A (en) Electromagnetic coil, its manufacturing method and rotating electrical machine
Cho et al. Improvement of electrical and thermal characteristics of nano-micro epoxy composite
JP2009187817A (en) Insulation sheet, stator coil and rotary electrical machine
WO2022201279A1 (en) Semiconductive member, stator coil, and rotating electric machine
Xie et al. Expanded graphite–epoxy composites with high dielectric constant
JP4091402B2 (en) Electric field relaxation material, electric field relaxation member using this material, and electromagnetic coil

Legal Events

Date Code Title Description
A300 Withdrawal of application because of no request for examination

Free format text: JAPANESE INTERMEDIATE CODE: A300

Effective date: 20080108