JP2006111776A - Apparatus for producing gas hydrate - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To realize stable operation of a dehydrator and realize operation in definite dehydration ratio by preventing clogging of a draining part caused by a gas hydrate. <P>SOLUTION: Gas hydrate slurry obtained by mixing a gas hydrate with unreacted water is drained by a dehydrator 12 to produce the gas hydrate having low water content. The dehydrator 12 is composed of a vertical type cylindrical body 21 formed from an introduction part 18 for introducing gas hydrate slurry (s), a draining part 19 for dehydrating the unreacted water of the gas hydrate slurry and a lead-out part 20 for leading out the gas hydrate dehydrated in the draining part 19, and a removed water-collecting part 22 for collecting a filtrate separated from the gas hydrate in the draining part. A clear water (w) is charged into the removed water-collecting part 22 to block contact of the draining part 19 with a raw material gas (g). <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a gas hydrate production apparatus for producing a gas hydrate by reacting a raw material gas and water and draining the gas hydrate by a dehydrator to produce a gas hydrate having a low water content. .

  As a method of storing and transporting natural gas mainly composed of hydrocarbons such as methane, generally, after collecting natural gas from a gas field, it is cooled to a liquefaction temperature and stored in a liquefied natural gas (LNG) state. Although the method of transporting is taken, as mentioned above, in order to store or transport natural gas as LNG, a large amount of cost is required.

  Therefore, in recent years, it has been studied to hydrate natural gas with water to produce a solid state hydrate, that is, natural gas hydrate (NGH), which is stored or transported as it is. This natural gas hydrate can be produced under conditions of temperature and pressure that are relatively easily obtained, thus reducing manufacturing, storage and transportation costs, and has attracted attention from the world.

  By the way, natural gas hydrate is obtained by bringing a raw material gas and water into contact with each other to be solidified as a hydrate. Usually, it becomes a slurry containing a large amount of water. Therefore, if the slurry-like natural gas hydrate is stored and transported, the cost for storage and transport becomes enormous.

Therefore, in order to produce natural gas hydrate with a low water content and reduce the cost of storage and transportation, slurry-like natural gas hydrate is introduced into the dehydrator to dehydrate and remove unreacted water. There is a need to. And as this dehydrator, a horizontal screw press type dehydrator is known (for example, refer to patent documents 1).
JP 2003-105362 A (page 7-10, FIG. 2)

  However, such a screw press type dewatering device has a double structure of a meshed inner wall and a cylindrical body that is outside the inner wall and constitutes the outer shell, and is provided by a screw shaft installed in the inner wall. Water is removed from the mesh processed on the inner wall by forcibly advancing the slurry-like natural gas hydrate.

  For this reason, during dehydration, most of the natural gas hydrate passes through the mesh holes in the inner wall together with water, resulting in a problem that the recovery rate of natural gas hydrate is lowered.

  Further, there is a problem that a power cost is required to rotate the screw shaft with a high torque. Further, since high torque is generated in a state where the inside is at a high pressure, the entire equipment is overloaded, and it is necessary to seal the screw shaft in a region from high pressure to atmospheric pressure.

  In order to solve such a problem, the present inventors examined a natural gas hydrate slurry dehydrator using gravity instead of the conventional mechanical dehydration. As shown in FIG. 3, the dehydrator 1 includes an introduction unit 4 for introducing the gas hydrate slurry s, a draining unit 6 for dehydrating the water w of the gas hydrate slurry s, and a gas dehydrated by the draining unit 6. A vertical cylindrical main body 2 including a derivation unit 5 for deriving a hydrate n and a dehydration aggregation unit 3 for collecting water (filtrate) w separated from the gas hydrate n by a draining unit 6 are configured.

  However, the water (filtrate) w filtered by the draining unit 6 reacts with the raw material gas at the part of the wire mesh or the perforated plate constituting the draining unit 6 to become gas hydrate, and this gas hydrate is converted into the draining unit 6. There is a problem that the dewatering performance of the dehydrator gradually decreases because the metal mesh and the perforated plate are gradually deposited on the wire mesh and the perforated plate constituting the structure.

  The present invention has been made to solve such a problem, and an object of the present invention is to prevent clogging of the drainage portion due to gas hydrate and realize stable operation of the dehydrator. A further object is to provide a gas hydrate production apparatus that realizes a constant dehydration rate operation.

  In order to solve the above problems, the present invention is configured as follows.

  In the first aspect of the present invention, a gas hydrate is produced by reacting a raw material gas and water, and a gas hydrate slurry in which the gas hydrate and unreacted water are mixed is drained by a dehydrator to reduce water content. In the gas hydrate production apparatus for producing a high rate gas hydrate, the dehydrator includes an introduction unit for introducing the gas hydrate slurry, a draining unit for dehydrating unreacted water in the gas hydrate slurry, and the draining unit. The vertical cylindrical main body formed by the lead-out part for leading out the gas hydrate dehydrated in the above and the dehydration gathering part for collecting the filtrate separated from the gas hydrate by the draining part, and in the dehydration gathering part A gas hydrate production apparatus characterized in that fresh water is applied to block contact between the draining part and the raw material gas.

  In the invention according to claim 2, a weir comparable to the height of the draining portion is provided in the dewatering gathering portion, and fresh water is supplied between the weir and the draining portion. 2. The gas hydrate manufacturing apparatus according to claim 1, wherein the apparatus is submerged under water.

  The invention according to claim 3 is characterized in that a liquid level sensor is provided in the dewatering assembly part and the supply amount of fresh water is controlled so that the draining part is submerged below the liquid level at all times or when the draining part is clogged. The gas hydrate production apparatus according to claim 1.

  As described above, according to the first aspect of the present invention, a gas hydrate is produced by reacting a raw material gas and water, and a gas hydrate slurry in which the gas hydrate and unreacted water are mixed is obtained by a dehydrator. In the gas hydrate production apparatus for producing a gas hydrate having a low water content by draining, the dehydrator includes an introduction unit for introducing the gas hydrate slurry and a draining unit for dehydrating unreacted water in the gas hydrate slurry. And a vertical cylindrical main body formed by a lead-out portion for deriving the gas hydrate dehydrated at the draining portion, and a dehydration collecting portion for collecting the filtrate separated from the gas hydrate at the draining portion, Since fresh water is put in the dewatering assembly part to block contact between the draining part and the raw material gas, water (filtrate) filtered by the draining part constitutes the draining part. It was possible to avoid the problem of becoming a gas hydrate by reacting a raw material gas in a portion of the wire mesh or perforated plate you are.

  Therefore, clogging of the metal mesh and perforated plate in the draining portion due to the accumulation of gas hydrate on the part of the metal mesh and perforated plate constituting the draining portion is reduced. As a result, stable operation of the dehydrator could be realized and constant dehydration rate operation could be realized.

  In the invention according to claim 2, a weir comparable to the height of the draining portion is provided in the dewatering gathering portion, and fresh water is supplied between the weir and the draining portion. Since it is submerged in the bottom, it is possible to prevent clogging of the wire mesh and the perforated plate constituting the draining portion by a relatively simple method.

  The invention according to claim 3 is provided with a liquid level sensor in the dewatering gathering part, and controls the supply amount of fresh water so that the draining part is submerged under the liquid level at all times or when the draining part is clogged. It is possible to prevent clogging of the part of the metal mesh and the perforated plate constituting the part, to suppress the amount of fresh water used, and to reduce the operating cost.

Hereinafter, embodiments of the present invention will be described with reference to the drawings.
(1) First Embodiment First, the first embodiment will be described. In FIG. 1, 11 is a gas hydrate generator, 12 is a dehydrator for dehydrating the slurry-like gas hydrate s generated by the gas hydrate generator 11, and 13 is a gas hydrate almost dehydrated by the dehydrator 12. It is a gas hydrate transfer device that transfers n laterally to the next step (not shown).

  The gas hydrate generator 11 includes a pressure vessel 14, a gas jet nozzle 15 that blows out natural gas g, which is a raw material gas, in the form of bubbles, and a stirrer 16 that stirs the inside of the pressure vessel 14.

  In addition to natural gas, which is a mixed gas such as methane, ethane, propane, or butane, gas that forms a gas hydrate such as carbon dioxide gas or chlorofluorocarbon gas can be used as the source gas.

  The dehydrator 12 includes an introduction unit 18 for introducing the gas hydrate slurry s, a draining unit 19 for dehydrating the water w in the gas hydrate slurry, and a deriving unit for deriving the gas hydrate n dehydrated by the draining unit 19. A vertical cylindrical main body 21 composed of 20 and a dehydration collecting portion 22 for collecting water (filtrate) w separated from the gas hydrate n by the draining portion 19 are constituted.

  The draining portion 19 is a cylindrical shape made of a wire mesh or a perforated plate, and the small holes 23 are formed so that the hole diameter is 0.1 to 5 mm. When the hole diameter of the small hole 23 is less than 0.1 mm, clogging is likely to occur, and conversely, when it exceeds 5 mm, the gas hydrate tends to flow out and the recovery rate decreases.

  And while providing the water supply nozzle 24 in the upper part of the dehydration gathering part 22, the water supply nozzle 24, the fresh water tank 25, and the feed water pump 26 are connected by the feed water line 27, and the fresh water (fresh water) in the fresh water tank 25 is connected. w ′ is supplied to the water jet nozzle 24 by the water supply pump 26 so that the draining portion 20 is always submerged below the liquid level X.

  For this reason, the dehydration collecting unit 22 includes a liquid level sensor 35 and controls the water supply pump 26 so that the liquid level X maintains the set water level. Then, the mixed water w ″ in which the unreacted water (filtrate) filtered by the draining unit 19 and the fresh water are mixed is returned to the gas hydrate generator 11 via the return line 28 provided with the pump 29.

  Here, the dehydrator 1 requires a drainage height H, that is, a difference between the upper end of the vertical cylindrical main body 21 and the upper end of the liquid level of the gas hydrate slurry s in the vertical cylindrical main body 21. is there. In the figure, 33 indicates a controller.

  On the other hand, normally, the drainer 19 is operated only when the liquid level X is positioned below the drainer 19 and the measurement value detected by the flow meter 36 provided in the return line 28 falls below the set value. The liquid level X may be submerged.

  Next, the operation of this gas hydrate production apparatus will be described.

  The gas hydrate n generated by the gas hydrate generator 11 is in the form of a slurry having a gas hydrate concentration of about 20%. This gas hydrate slurry s is supplied by the slurry pump 30 into the inlet 18 at the lower end of the dehydrator.

  When the liquid level reaches above the draining portion 19, the unreacted water w in the gas hydrate slurry s flows out from the small holes 23 of the draining portion 19 into the dewatering collecting portion 22. The gas hydrate n having a moisture content of about 50% ascends in the dehydrator 12 and reaches the outlet 20 where it is transferred to the next process by the gas hydrate discharger 13.

As described above, the draining part 19 is located below the liquid surface X of the fresh water injected into the dewatering collecting part 22 and is not in contact with the raw material gas g, so that the gas hydrate is generated. No clogging caused by.
(2) Second Embodiment Next, the second embodiment will be described. The same equipment as the equipment of the first embodiment is denoted by the same reference numeral, and detailed description thereof is omitted.

  In FIG. 1, 11 is a gas hydrate production | generation. FIG. 3 shows other embodiment of the gas hydrate manufacturing apparatus based on this invention, and attaches | subjects the same code | symbol to the same member as FIG.1 and FIG.2. Detailed explanation was omitted.

  In the present invention, as shown in FIG. 2, a weir 37 comparable to the height of the draining portion 19 is provided in the dewatering gathering portion 22, and fresh water w ′ is supplied between the weir 37 and the draining portion 19. Since the draining portion 19 is always submerged under the liquid level X, clogging of the wire mesh or the perforated plate constituting the draining portion 19 can be prevented by a relatively simple method.

It is a schematic block diagram of the 1st gas hydrate manufacturing apparatus which concerns on this invention. It is a schematic block diagram of the 2nd gas hydrate manufacturing apparatus which concerns on this invention. It is sectional drawing of the dehydrator using gravity.

Explanation of symbols

g Raw material gas n Gas hydrate s Gas hydrate slurry w Water 1,12 Dehydrator 18 Introducing section 19 Draining section 20 Deriving section 21 Vertical cylindrical body 22 Dehydrating assembly section

Claims (3)

Gas that produces gas hydrate by reacting raw material gas and water, and gas hydrate slurry mixed with this gas hydrate and unreacted water is drained by a dehydrator to produce gas hydrate with low water content In the hydrate production apparatus, the dehydrator is configured to introduce an introduction unit for introducing a gas hydrate slurry, a draining unit for dehydrating unreacted water in the gas hydrate slurry, and a gas hydrate dehydrated by the draining unit. A vertical cylindrical main body formed by the lead-out portion, and a dewatering collecting portion that collects the filtrate separated from the gas hydrate in the draining portion, and the fresh draining portion and the raw material are stretched with fresh water in the dehydrating collecting portion A gas hydrate manufacturing apparatus characterized by blocking contact with gas. In the dewatering assembly, a weir comparable to the height of the draining part is provided, and fresh water is supplied between the weir and the draining part so that the draining part is always submerged below the liquid level. The gas hydrate manufacturing apparatus according to claim 1, wherein 2. The gas hydride according to claim 1, wherein a liquid level sensor is provided in the dewatering assembly part, and the supply amount of fresh water is controlled so that the draining part is submerged below the liquid level at all times or when the draining part is clogged. Rate production equipment.

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