JP2006058867A - Clay for handicraft - Google Patents
Clay for handicraft Download PDFInfo
- Publication number
- JP2006058867A JP2006058867A JP2005209367A JP2005209367A JP2006058867A JP 2006058867 A JP2006058867 A JP 2006058867A JP 2005209367 A JP2005209367 A JP 2005209367A JP 2005209367 A JP2005209367 A JP 2005209367A JP 2006058867 A JP2006058867 A JP 2006058867A
- Authority
- JP
- Japan
- Prior art keywords
- clay
- weight
- casein
- parts
- red
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004927 clay Substances 0.000 title claims abstract description 59
- 239000005018 casein Substances 0.000 claims abstract description 22
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims abstract description 22
- 235000021240 caseins Nutrition 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003086 colorant Substances 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 7
- 235000020183 skimmed milk Nutrition 0.000 claims abstract description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011575 calcium Substances 0.000 claims abstract description 4
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 4
- 239000011777 magnesium Substances 0.000 claims abstract description 4
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 4
- 239000011591 potassium Substances 0.000 claims abstract description 4
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 3
- 239000011734 sodium Substances 0.000 claims abstract description 3
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims description 16
- 235000002864 food coloring agent Nutrition 0.000 claims description 2
- 238000004040 coloring Methods 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 2
- 102000011632 Caseins Human genes 0.000 description 16
- 108010076119 Caseins Proteins 0.000 description 16
- 239000012153 distilled water Substances 0.000 description 14
- 239000000049 pigment Substances 0.000 description 11
- 239000000975 dye Substances 0.000 description 8
- 241000209140 Triticum Species 0.000 description 7
- 235000021307 Triticum Nutrition 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 235000013312 flour Nutrition 0.000 description 6
- UBVSIAHUTXHQTD-UHFFFAOYSA-N 2-n-(4-bromophenyl)-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(NC=2C=CC(Br)=CC=2)=N1 UBVSIAHUTXHQTD-UHFFFAOYSA-N 0.000 description 5
- 229920001817 Agar Polymers 0.000 description 5
- 239000008272 agar Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 235000012732 erythrosine Nutrition 0.000 description 5
- 239000001509 sodium citrate Substances 0.000 description 5
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 4
- 244000111489 Gardenia augusta Species 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- CEZCCHQBSQPRMU-UHFFFAOYSA-L chembl174821 Chemical compound [Na+].[Na+].COC1=CC(S([O-])(=O)=O)=C(C)C=C1N=NC1=C(O)C=CC2=CC(S([O-])(=O)=O)=CC=C12 CEZCCHQBSQPRMU-UHFFFAOYSA-L 0.000 description 3
- 239000000989 food dye Substances 0.000 description 3
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 3
- 229940080237 sodium caseinate Drugs 0.000 description 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 3
- 229940038773 trisodium citrate Drugs 0.000 description 3
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 3
- WLDHEUZGFKACJH-ZRUFZDNISA-K Amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1\N=N\C1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-ZRUFZDNISA-K 0.000 description 2
- 244000236655 Diospyros kaki Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 240000004584 Tamarindus indica Species 0.000 description 2
- 235000004298 Tamarindus indica Nutrition 0.000 description 2
- 235000010208 anthocyanin Nutrition 0.000 description 2
- 239000004410 anthocyanin Substances 0.000 description 2
- 229930002877 anthocyanin Natural products 0.000 description 2
- 150000004636 anthocyanins Chemical class 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 239000001055 blue pigment Substances 0.000 description 2
- 235000012745 brilliant blue FCF Nutrition 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 235000019804 chlorophyll Nutrition 0.000 description 2
- 229930002875 chlorophyll Natural products 0.000 description 2
- JFVXEJADITYJHK-UHFFFAOYSA-L disodium 2-(3-hydroxy-5-sulfonato-1H-indol-2-yl)-3-oxoindole-5-sulfonate Chemical compound [Na+].[Na+].Oc1c([nH]c2ccc(cc12)S([O-])(=O)=O)C1=Nc2ccc(cc2C1=O)S([O-])(=O)=O JFVXEJADITYJHK-UHFFFAOYSA-L 0.000 description 2
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 2
- OOYIOIOOWUGAHD-UHFFFAOYSA-L disodium;2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [Na+].[Na+].O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(Br)=C([O-])C(Br)=C1OC1=C(Br)C([O-])=C(Br)C=C21 OOYIOIOOWUGAHD-UHFFFAOYSA-L 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 2
- KINGXFAMZNIVNL-SXQDSXCISA-N safflor yellow A Natural products OC[C@@H]1O[C@H]2[C@H](OC3=C2C(=O)C(=C(O)C=Cc4ccc(O)cc4)C(=O)[C@]3(O)[C@@H]5O[C@H](CO)[C@@H](O)[C@H](O)[C@H]5O)[C@@H](O)[C@H]1O KINGXFAMZNIVNL-SXQDSXCISA-N 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000012756 tartrazine Nutrition 0.000 description 2
- 239000004149 tartrazine Substances 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 2
- 235000019801 trisodium phosphate Nutrition 0.000 description 2
- SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 description 2
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- RHAXKFFKGZJUOE-UHFFFAOYSA-N 7-acetyl-6-ethyl-3,5,8-trihydroxy-9,10-dioxoanthracene-1,2-dicarboxylic acid Chemical compound O=C1C2=CC(O)=C(C(O)=O)C(C(O)=O)=C2C(=O)C2=C1C(O)=C(CC)C(C(C)=O)=C2O RHAXKFFKGZJUOE-UHFFFAOYSA-N 0.000 description 1
- PMTBZAVERRPRHU-YGVNLFKFSA-N CC1(C)CCCC(C)=C1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C.CC1(C)CCCC(C)=C1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C Chemical compound CC1(C)CCCC(C)=C1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C.CC1(C)CCCC(C)=C1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C PMTBZAVERRPRHU-YGVNLFKFSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- WLYGSPLCNKYESI-RSUQVHIMSA-N Carthamin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1[C@@]1(O)C(O)=C(C(=O)\C=C\C=2C=CC(O)=CC=2)C(=O)C(\C=C\2C([C@](O)([C@H]3[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O3)O)C(O)=C(C(=O)\C=C\C=3C=CC(O)=CC=3)C/2=O)=O)=C1O WLYGSPLCNKYESI-RSUQVHIMSA-N 0.000 description 1
- 241000208809 Carthamus Species 0.000 description 1
- 244000020518 Carthamus tinctorius Species 0.000 description 1
- 235000003255 Carthamus tinctorius Nutrition 0.000 description 1
- 244000163122 Curcuma domestica Species 0.000 description 1
- 235000003392 Curcuma domestica Nutrition 0.000 description 1
- 235000011511 Diospyros Nutrition 0.000 description 1
- 235000008597 Diospyros kaki Nutrition 0.000 description 1
- 239000000940 FEMA 2235 Substances 0.000 description 1
- RZSYLLSAWYUBPE-UHFFFAOYSA-L Fast green FCF Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC(O)=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 RZSYLLSAWYUBPE-UHFFFAOYSA-L 0.000 description 1
- 229930192967 Laccaic acid Natural products 0.000 description 1
- 241000228347 Monascus <ascomycete fungus> Species 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 235000012741 allura red AC Nutrition 0.000 description 1
- 239000004191 allura red AC Substances 0.000 description 1
- WLDHEUZGFKACJH-UHFFFAOYSA-K amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1N=NC1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-UHFFFAOYSA-K 0.000 description 1
- 235000012735 amaranth Nutrition 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000012733 azorubine Nutrition 0.000 description 1
- 235000019481 bixa orellana extract Nutrition 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- 239000001325 capsicum annuum l. var. longum oleoresin Substances 0.000 description 1
- 235000013736 caramel Nutrition 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- DGQLVPJVXFOQEV-JNVSTXMASA-N carminic acid Chemical compound OC1=C2C(=O)C=3C(C)=C(C(O)=O)C(O)=CC=3C(=O)C2=C(O)C(O)=C1[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O DGQLVPJVXFOQEV-JNVSTXMASA-N 0.000 description 1
- OIQPTROHQCGFEF-UHFFFAOYSA-L chembl1371409 Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 OIQPTROHQCGFEF-UHFFFAOYSA-L 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 239000001752 chlorophylls and chlorophyllins Substances 0.000 description 1
- 235000003373 curcuma longa Nutrition 0.000 description 1
- 239000001081 curcuma longa l. root oleoresin Substances 0.000 description 1
- VQHHOXOLUXRQFQ-UHFFFAOYSA-L dipotassium;4,5,6,7-tetrachloro-2',4',5',7'-tetraiodo-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [K+].[K+].O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(I)=C([O-])C(I)=C1OC1=C(I)C([O-])=C(I)C=C21 VQHHOXOLUXRQFQ-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- IINNWAYUJNWZRM-UHFFFAOYSA-L erythrosin B Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 IINNWAYUJNWZRM-UHFFFAOYSA-L 0.000 description 1
- 235000019240 fast green FCF Nutrition 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000576 food coloring agent Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- KHLVKKOJDHCJMG-QDBORUFSSA-L indigo carmine Chemical compound [Na+].[Na+].N/1C2=CC=C(S([O-])(=O)=O)C=C2C(=O)C\1=C1/NC2=CC=C(S(=O)(=O)[O-])C=C2C1=O KHLVKKOJDHCJMG-QDBORUFSSA-L 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 235000012658 paprika extract Nutrition 0.000 description 1
- DYUUPIKEWLHQGQ-SDXBLLFJSA-N paprika oleoresin Chemical compound C(\[C@]12[C@@](O1)(C)C[C@@H](O)CC2(C)C)=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=C[C@H]1C(C)=C[C@H](O)CC1(C)C DYUUPIKEWLHQGQ-SDXBLLFJSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229940099402 potassium metaphosphate Drugs 0.000 description 1
- 235000019828 potassium polyphosphate Nutrition 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- AZJPTIGZZTZIDR-UHFFFAOYSA-L rose bengal Chemical compound [K+].[K+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 AZJPTIGZZTZIDR-UHFFFAOYSA-L 0.000 description 1
- 229960003138 rose bengal sodium Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- 235000019263 trisodium citrate Nutrition 0.000 description 1
- 235000013976 turmeric Nutrition 0.000 description 1
- 235000013975 turmeric oleoresin Nutrition 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
Description
本発明は、色移りを防止できるカラー工作用粘土に関するものである。 The present invention relates to a clay for color work that can prevent color transfer.
従来より、学校や家庭で使用されている工作用粘土としては、特開昭４８−０７６６２３号、特開昭５３−１２８４２６号、特開平０１−２８５９８２号など種々の材料を混練した人工粘土が知られており、また、色調を与えるために種々の着色された粘土が提案されている。
これらの粘土は無機物質や小麦粉やセルロースなどを主材料とし、充填材、糊剤、防腐防かび剤などを添加混練して作られている。そして、カラー粘土を要するときは、更に染料、顔料などの着色剤を添加して作製している。
しかし、カラー粘土はその取り扱い中に着色剤が手や工作具に色移りしたり、様々な色に着色した粘土を用いてカラフルに仕上げた作品の粘土同士が、経時的に色移りして色が混じってしまう欠点があった。
Conventionally, artificial clays kneaded with various materials such as Japanese Patent Laid-Open No. 48-076623, Japanese Patent Laid-Open No. 53-128426, Japanese Patent Laid-Open No. 01-259882 are known as work clay used in schools and homes. In addition, various colored clays have been proposed to provide color tone.
These clays are made by mixing and kneading fillers, pastes, antiseptics, etc. with inorganic substances, wheat flour and cellulose as the main materials. And when color clay is required, it is made by adding colorants such as dyes and pigments.
However, the color clay is transferred to the hands and tools during the handling of the color clay, or the clays of the works that are colorfully finished using clay colored in various colors are transferred to each other over time. There was a fault that would be mixed.
そこで、本発明は、べとつきが少なく、鮮やかな色彩となる粘土であって、着色剤が手や工作具に色移りしたり、接触する粘土同士が経時的に色移りして色が混じり合うことがない工作用粘土を提供するものである。 Therefore, the present invention is a clay that has less stickiness and has a vivid color, and the colorant is transferred to the hand or the tool, or the colors of the clay in contact with each other are transferred over time, and the colors are mixed. It is intended to provide a clay for work.
前記課題を解決するために、水性粘土材料、食用色素及び/又は天然色素、水からなる工作用粘土に、脱脂粉乳、カゼイン、カゼインナトリウム、カゼインカルシウム、カゼインカリウム、カゼインマグネシウムから選ばれる１種又は２種以上を添加したことを特徴とする工作用粘土を提供する。 In order to solve the above-mentioned problems, a work clay composed of an aqueous clay material, a food color and / or a natural color, water, and one kind selected from skim milk powder, casein, casein sodium, casein calcium, casein potassium, and casein magnesium Provided is a work clay characterized by adding two or more kinds.
本発明によれば、べとつきが少なく、均一で鮮やかな色彩となる工作用粘土が得られ、かつ、着色剤が手や工作具に色移りしたり、接触する粘土同士が経時的に色移りして色が混じり合うことがない工作用粘土が得られた。 According to the present invention, a work clay having a low stickiness and a uniform and vivid color is obtained, and the colorant is transferred to the hand or the tool, or the clay in contact with each other is transferred over time. As a result, a clay for work that does not mix colors was obtained.
以下、本発明の詳細を説明する。
本発明に用いられる水性粘土材料は、水と混練りすると粘土状になる物質を総称したものであって、セルロースを主材料としたパルプ粉末、小麦を主材料とした小麦粉、カンテンを主材料としたカンテン粘土の粉末、デンプンを主材料としたデンプン粘土の粉末などを例示することができる。水性粘土材料は粘土全体量に対し、好ましくは１０〜８０重量％を用いることができる。
Details of the present invention will be described below.
The aqueous clay material used in the present invention is a generic term for substances that become clay-like when kneaded with water, and is a pulp powder mainly composed of cellulose, wheat flour mainly composed of wheat, and agar. Examples thereof include powdered agar clay, starch clay powder mainly composed of starch, and the like. The aqueous clay material is preferably used in an amount of 10 to 80% by weight based on the total amount of clay.
本発明に用いられる着色剤としては、食用色素及び/又は天然色素が用いられ、食用赤色２号（C.I.Number : C.I.16185、Color Index Name : Acid Red 27）、食用赤色３号（C.I.Number : C.I.45430、Color Index Name : Acid Red 51）、食用赤色４０号（C.I.Number : C.I.16035、Color Index Name : Food Red 17）、食用赤色１０２号（C.I.Number : C.I.16255、Color Index Name : Acid Red 18）、食用赤色１０４号（C.I.Number : C.I.45410、Color Index Name : Acid Red 92）、食用赤色１０５号（C.I.Number : C.I.45440、Color Index Name : Acid Red 94）、食用赤色１０６号（C.I.Number : C.I.45100、Color Index Name : Acid Red 52）、食用黄色４号（C.I.Number : C.I.19140、Color Index Name : Acid Yellow 23）、食用黄色５号（C.I.Number : C.I.15985、Color Index Name : Food Yellow 3）、食用緑色３号（C.I.Number : C.I.42053、Color Index Name : Food Green 3）、食用青色１号（C.I.Number : C.I.42090、Color Index Name : Food Blue 2）、食用青色２号（C.I.Number : C.I.73015、Color Index Name : Acid Blue 74）などの食用染料色素や、食用赤色２号アルミニウムレーキ、食用赤色３号アルミニウムレーキ、食用赤色４０号アルミニウムレーキ、食用黄色４号アルミニウムレーキ、食用黄色５号アルミニウムレーキ、食用緑色３号アルミニウムレーキ、食用青色１号アルミニウムレーキ、食用青色２号アルミニウムレーキなどの食用顔料色素や、ベニコウジ色素（Monascus Color）、β-カロテン（beta-Carotene ）、ラック色素（Laccaic Acid）、コチニール色素（Cochineal Extract）、パプリカ色素（Paprika Oleoresin）、ビートレッド（Beet Red）、アントシアニン色素（Anthocyanins）、クチナシ色素（Gardenia Extract）、ベニバナ色素（Carthamus Extract）、ウコン色素（Turmeric Oleoresin）、アナトー色素（Annatto Extracts）、クロロフィル（Chlorophylls）、カキ色素（Japanese Persimmon Color）、タマリンド色素（Tamarind Color）、カラメル色素（Caramel）などの天然色素を用いることができる。前記食用色素及び/又は天然色素から選ばれる着色剤は、１又は２以上を用いることができ、粘土全体量に対し好ましくは０．００１〜２０重量％を用いることができる。 As the colorant used in the present invention, edible pigments and / or natural pigments are used. Edible Red No. 2 (CINumber: CI16185, Color Index Name: Acid Red 27), Edible Red No. 3 (CINumber: CI 45430, Color Index Name: Acid Red 51), Food Red 40 (CINumber: CI16035, Color Index Name: Food Red 17), Food Red 102 (CINumber: CI16255, Color Index Name: Acid Red 18) Food Red 104 (CINumber: CI45410, Color Index Name: Acid Red 92), Food Red 105 (CINumber: CI45440, Color Index Name: Acid Red 94), Food Red 106 (CINumber: CI 45100, Color Index Name: Acid Red 52), Food Yellow 4 (CINumber: CI19140, Color Index Name: Acid Yellow 23), Food Yellow 5 (CINumber: CI15985, Color Index Name: Food Yellow 3) , Edible Green 3 (CINumber: CI42053, Color Index Name: Food Green 3), Edible Blue 1 (CINumber: CI420) 90, Color Index Name: Food Blue 2), Food Dye Colors such as Food Blue 2 (CINumber: CI73015, Color Index Name: Acid Blue 74), Food Red 2 Aluminum Lake, Food Red 3 Aluminum Lake Edible pigment dyes such as edible red No. 40 aluminum lake, edible yellow No. 4 aluminum rake, edible yellow No. 5 aluminum rake, edible green No. 3 aluminum rake, edible blue No. 1 aluminum rake, edible blue No. 2 aluminum rake, Benikouji Dye (Monascus Color), β-Carotene (beta-Carotene), Laccaic Acid, Cochineal Extract, Paprika Oleoresin, Beet Red, Anthocyanins Dye (Anthocyanins), Gardenia Pigment (Gardenia Extract), safflower pigment (Carthamus Extract), turmeric pigment (Turmeric Oleoresin), Over dyes (Annatto Extracts), chlorophyll (Chlorophylls), persimmon dye (Japanese Persimmon Color), tamarind pigment (Tamarind Color), it is possible to use natural dyes such as caramel color (Caramel). 1 or 2 or more can be used for the coloring agent chosen from the said food coloring and / or a natural coloring matter, Preferably 0.001-20 weight% can be used with respect to the clay whole quantity.
本発明に用いられる水としては、水道水、蒸留水、精製水、純水などを用いることができるが、腐敗やかびの発生の観点から精製蒸留水が好ましく用いられる。水は粘土全体量に対し、好ましくは１０〜９０重量％を用いることができる。 As water used in the present invention, tap water, distilled water, purified water, pure water and the like can be used, but purified distilled water is preferably used from the viewpoint of the occurrence of decay and mold. Water is preferably used in an amount of 10 to 90% by weight based on the total amount of clay.
また、本発明には色移り防止剤として、脱脂粉乳、カゼイン、カゼインナトリウム、カゼインカルシウム、カゼインカリウム、カゼインマグネシウムから選ばれる１種又は２種以上を添加することが必須となる。これらは粘土全体量に対し、好ましくは０．０１〜３０重量％を用いることができる。
これらの色移り防止剤が、前記食用色素の色移りを防止するメカニズムは明らかではないが、カゼイン蛋白質が食用色素と強く結び付くことによって水溶液への再溶解が阻害されるためと思われる。
なお、前記脱脂粉乳やカゼインを可溶容易にするため、溶解助剤として塩化カルシウム、クエン酸カルシウム、クエン酸三ナトリウム、炭酸水素ナトリウム、結晶化炭酸ナトリウム、無水炭酸ナトリウム、結晶化ピロリン酸四ナトリウム、無水ピロリン酸四ナトリウム、ポリリン酸カリウム、ポリリン酸ナトリウム、メタリン酸カリウム、メタリン酸ナトリウム、結晶化リン酸水素二ナトリウム、無水リン酸水素二ナトリウム、結晶化リン酸二水素ナトリウム、無水リン酸二水素ナトリウム、結晶化リン酸三ナトリウム、無水リン酸三ナトリウムを更に添加することができる。
In the present invention, it is essential to add one or more selected from skim milk powder, casein, sodium caseinate, casein calcium, casein potassium, and casein magnesium as a color transfer inhibitor. These are preferably used in an amount of 0.01 to 30% by weight based on the total amount of clay.
Although the mechanism by which these color transfer inhibitors prevent the color transfer of the food dye is not clear, it is thought that re-dissolution in the aqueous solution is inhibited by the strong binding of the casein protein to the food dye.
In order to facilitate the solubilization of the skim milk powder and casein, calcium chloride, calcium citrate, trisodium citrate, sodium bicarbonate, crystallized sodium carbonate, anhydrous sodium carbonate, crystallized tetrasodium pyrophosphate are used as a solubilizer. , Anhydrous tetrasodium pyrophosphate, potassium polyphosphate, sodium polyphosphate, potassium metaphosphate, sodium metaphosphate, crystallized disodium hydrogen phosphate, anhydrous disodium hydrogen phosphate, crystallized sodium dihydrogen phosphate, anhydrous diphosphate Sodium hydrogen, crystallized trisodium phosphate, and anhydrous trisodium phosphate can be further added.
更に、本発明には、防腐防かび剤や、安定剤や、香料などを添加しても良い。
以下、本発明を実施例および比較例により説明する。
Furthermore, antiseptic / antifungal agents, stabilizers, perfumes and the like may be added to the present invention.
Hereinafter, the present invention will be described with reference to examples and comparative examples.
（実施例１）
小麦粉６５重量部、塩１重量部、食用青色１号０．０１重量部、精製蒸留水３２重量部、脱脂粉乳１重量部、クエン酸ナトリウム１重量部を混練りし、青色の工作用粘土を得た。
当該粘土を５分間手でこねても、手が青色に染まることはなかった。
（比較例１）
小麦粉６６重量部、塩１重量部、食用青色１号０．０１重量部、精製蒸留水３３重量部を混練りし、青色の工作用粘土を得た。
当該粘土を５分間手でこねたところ、手が青色に染まった。
Example 1
65 parts by weight of wheat flour, 1 part by weight of salt, 0.01 part by weight of edible blue No. 1, 32 parts by weight of purified distilled water, 1 part by weight of skim milk powder and 1 part by weight of sodium citrate are kneaded to obtain blue working clay. Obtained.
Even if the clay was kneaded by hand for 5 minutes, the hand did not stain blue.
(Comparative Example 1)
66 parts by weight of wheat flour, 1 part by weight of salt, 0.01 part by weight of edible blue No. 1 and 33 parts by weight of purified distilled water were kneaded to obtain blue working clay.
When the clay was kneaded by hand for 5 minutes, the hands were stained blue.
（実施例２）
パルプ粉末１５重量部、タルク３０重量部、中空発泡体１０重量部、カルボキシメチルセルロース（ＣＭＣ）１０重量部、食用色素黄色４号０．１重量部、カゼイン１重量部、クエン酸三ナトリウム１重量部、精製蒸留水３３重量部を混練りし、黄色の工作用粘土を得た。
当該粘土を５分間手でこねても、手が黄色に染まることはなかった。
（比較例２）
パルプ粉末１５重量部、タルク３０重量部、中空発泡体１０重量部、カルボキシメチルセルロース（ＣＭＣ）１０重量部、食用色素黄色４号０．１重量部、精製蒸留水３５重量部を混練りし、黄色の工作用粘土を得た。
当該粘土を５分間手でこねたところ、手が黄色に染まった。
(Example 2)
15 parts by weight of pulp powder, 30 parts by weight of talc, 10 parts by weight of hollow foam, 10 parts by weight of carboxymethyl cellulose (CMC), 0.1 part by weight of edible dye yellow No. 4, 1 part by weight of casein, 1 part by weight of trisodium citrate Then, 33 parts by weight of purified distilled water was kneaded to obtain yellow work clay.
Even if the clay was kneaded by hand for 5 minutes, the hand did not stain yellow.
(Comparative Example 2)
15 parts by weight of pulp powder, 30 parts by weight of talc, 10 parts by weight of a hollow foam, 10 parts by weight of carboxymethylcellulose (CMC), 0.1 part by weight of edible dye yellow No. 4, and 35 parts by weight of purified distilled water are kneaded, yellow The clay for work was obtained.
When the clay was kneaded by hand for 5 minutes, the hands became yellow.
（実施例３）
カンテンを用いた粘土の粉末４９．５重量部、食用赤色３号０．１重量部、精製蒸留水４９．５重量部、カゼインナトリウム１重量部を混練りし、赤色の工作用粘土を得た。
当該粘土を５分間手でこねても、手が赤色に染まることはなかった。
（比較例３）
カンテンを用いた粘土の粉末５０重量部、食用赤色３号０．１重量部、精製蒸留水５０重量部を混練りし、赤色の工作用粘土を得た。
当該粘土を５分間手でこねたところ、手が赤色に染まった。
(Example 3)
49.5 parts by weight of clay powder using agar, 0.1 part by weight of edible red No. 3, 49.5 parts by weight of purified distilled water and 1 part by weight of sodium caseinate were kneaded to obtain a red working clay. .
Even if the clay was kneaded by hand for 5 minutes, the hand did not stain red.
(Comparative Example 3)
50 parts by weight of clay powder using agar, 0.1 parts by weight of edible red No. 3 and 50 parts by weight of purified distilled water were kneaded to obtain red working clay.
When the clay was kneaded by hand for 5 minutes, the hands were stained red.
（実施例４）
小麦粉６５重量部、塩１重量部、クチナシ青色素１重量部、食用青色１号０．０１重量部、精製蒸留水３０重量部、脱脂粉乳１重量部、クエン酸ナトリウム１重量部を混練りし、青色の工作用粘土を得た。
当該粘土を５分間手でこねても、手が青色に染まることはなかった。
（比較例４）
小麦粉６５重量部、塩１重量部、クチナシ青色素１重量部、食用青色１号０．０１重量部、精製蒸留水３２重量部を混練りし、青色の工作用粘土を得た。
当該粘土を５分間手でこねたところ、手が青色に染まった。
Example 4
65 parts by weight of wheat flour, 1 part by weight of salt, 1 part by weight of gardenia blue pigment, 0.01 part by weight of edible blue 1, 30 parts by weight of purified distilled water, 1 part by weight of skim milk powder, 1 part by weight of sodium citrate A blue working clay was obtained.
Even if the clay was kneaded by hand for 5 minutes, the hand did not stain blue.
(Comparative Example 4)
65 parts by weight of wheat flour, 1 part by weight of salt, 1 part by weight of gardenia blue pigment, 0.01 part by weight of edible blue No. 1 and 32 parts by weight of purified distilled water were kneaded to obtain blue working clay.
When the clay was kneaded by hand for 5 minutes, the hands were stained blue.
（実施例５）
パルプ粉末１５重量部、タルク３０重量部、中空発泡体１０重量部、カルボキシメチルセルロース（ＣＭＣ）１０重量部、ベニバナ黄色素１重量部、食用色素黄色４号０．１重量部、カゼイン１重量部、クエン酸三ナトリウム１重量部、精製蒸留水３１重量部を混練りし、黄色の工作用粘土を得た。
当該粘土を５分間手でこねても、手が黄色に染まることはなかった。
（比較例５）
パルプ粉末１５重量部、タルク３０重量部、中空発泡体１０重量部、カルボキシメチルセルロース（ＣＭＣ）１０重量部、ベニバナ黄色素１重量部、食用色素黄色４号０．１重量部、精製蒸留水３３重量部を混練りし、黄色の工作用粘土を得た。
当該粘土を５分間手でこねたところ、手が黄色に染まった。
(Example 5)
15 parts by weight of pulp powder, 30 parts by weight of talc, 10 parts by weight of hollow foam, 10 parts by weight of carboxymethylcellulose (CMC), 1 part by weight of safflower yellow dye, 0.1 part by weight of edible pigment yellow No. 4, 1 part by weight of casein, 1 part by weight of trisodium citrate and 31 parts by weight of purified distilled water were kneaded to obtain yellow work clay.
Even if the clay was kneaded by hand for 5 minutes, the hand did not stain yellow.
(Comparative Example 5)
15 parts by weight of pulp powder, 30 parts by weight of talc, 10 parts by weight of hollow foam, 10 parts by weight of carboxymethylcellulose (CMC), 1 part by weight of safflower yellow pigment, 0.1 part by weight of Edible Dye Yellow No. 4, 33 parts by weight of purified distilled water The parts were kneaded to obtain yellow work clay.
When the clay was kneaded by hand for 5 minutes, the hands became yellow.
（実施例６）
カンテンを用いた粘土の粉末４９重量部、ベニコウジ色素１重量部、食用赤色３号０．１重量部、精製蒸留水４８重量部、カゼインナトリウム１重量部を混練りし、赤色の工作用粘土を得た。
当該粘土を５分間手でこねても、手が赤色に染まることはなかった。
（比較例６）
カンテンを用いた粘土の粉末４９重量部、ベニコウジ色素１重量部、食用赤色３号０．１重量部、精製蒸留水４９重量部を混練りし、赤色の工作用粘土を得た。
当該粘土を５分間手でこねたところ、手が赤色に染まった。
(Example 6)
Kneaded 49 parts by weight of clay powder, 1 part by weight of Benikouji pigment, 0.1 part by weight of edible red No. 3, 48 parts by weight of purified distilled water and 1 part by weight of sodium caseinate were mixed into a red working clay. Obtained.
Even if the clay was kneaded by hand for 5 minutes, the hand did not stain red.
(Comparative Example 6)
49 parts by weight of clay powder using agar, 1 part by weight of Benikouji pigment, 0.1 part by weight of edible red No. 3 and 49 parts by weight of purified distilled water were kneaded to obtain a red working clay.
When the clay was kneaded by hand for 5 minutes, the hands were stained red.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005209367A JP4684782B2 (en) | 2004-07-21 | 2005-07-20 | Clay for work |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004212805 | 2004-07-21 | ||
| JP2005209367A JP4684782B2 (en) | 2004-07-21 | 2005-07-20 | Clay for work |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006058867A true JP2006058867A (en) | 2006-03-02 |
| JP4684782B2 JP4684782B2 (en) | 2011-05-18 |
Family
ID=36106335
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005209367A Active JP4684782B2 (en) | 2004-07-21 | 2005-07-20 | Clay for work |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4684782B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106504628A (en) * | 2016-10-27 | 2017-03-15 | 南丹县青少年学生校外活动中心 | A kind of color mud that can be used to make teaching aid |
| JP2018159040A (en) * | 2017-03-23 | 2018-10-11 | シヤチハタ株式会社 | Water-color ink for skin |
| JP2020091457A (en) * | 2018-12-08 | 2020-06-11 | 有限会社アドバンス | Crafting clay |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0753100Y2 (en) * | 1991-01-14 | 1995-12-06 | 株式会社松井色素化学工業所 | Flour clay |
| JPH091284A (en) * | 1995-06-15 | 1997-01-07 | Nippon Flour Mills Co Ltd | Clay for casting mold and casting method using the same |
| JPH10319834A (en) * | 1997-05-22 | 1998-12-04 | Mitsubishi Pencil Co Ltd | Clay composition containing light accumulating fluorescent body and its production |
| JP2000327324A (en) * | 1999-05-19 | 2000-11-28 | Mizusawa Ind Chem Ltd | Sauconite type synthetic clay, its production and use thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6027640A (en) * | 1983-07-21 | 1985-02-12 | 株式会社信和サ−ビス | Composition for color developing clay |
-
2005
- 2005-07-20 JP JP2005209367A patent/JP4684782B2/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0753100Y2 (en) * | 1991-01-14 | 1995-12-06 | 株式会社松井色素化学工業所 | Flour clay |
| JPH091284A (en) * | 1995-06-15 | 1997-01-07 | Nippon Flour Mills Co Ltd | Clay for casting mold and casting method using the same |
| JPH10319834A (en) * | 1997-05-22 | 1998-12-04 | Mitsubishi Pencil Co Ltd | Clay composition containing light accumulating fluorescent body and its production |
| JP2000327324A (en) * | 1999-05-19 | 2000-11-28 | Mizusawa Ind Chem Ltd | Sauconite type synthetic clay, its production and use thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106504628A (en) * | 2016-10-27 | 2017-03-15 | 南丹县青少年学生校外活动中心 | A kind of color mud that can be used to make teaching aid |
| JP2018159040A (en) * | 2017-03-23 | 2018-10-11 | シヤチハタ株式会社 | Water-color ink for skin |
| JP2020091457A (en) * | 2018-12-08 | 2020-06-11 | 有限会社アドバンス | Crafting clay |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4684782B2 (en) | 2011-05-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2572323C (en) | Use of water-soluble acrylic copolymers in optionally pigmented aqueous formulations and resulting formulations | |
| JPS5888103A (en) | Colored aqueous alkali metal hypochlorite composition | |
| JP2007297596A5 (en) | Ink set | |
| JP2013510048A (en) | Pre-cured joint compound and cure initiator in compartmented pouch | |
| CA2403489A1 (en) | Tooth whitening composition comprising a salt | |
| JP4684782B2 (en) | Clay for work | |
| RU2017121322A (en) | Oral Care Product Intended for Teeth Whitening | |
| KR20110093678A (en) | Tooth coating material | |
| CA2488581A1 (en) | Hair bleach kit comprising a colorant for improved visual application | |
| CN106074193A (en) | The hair of a kind of dark color floats shallow compositions | |
| JPWO2004045565A1 (en) | Pack cosmetic | |
| JP5170820B2 (en) | Clay for work | |
| CN106349811A (en) | Six-color full-color soft printing ink and preparation method thereof | |
| NO129030B (en) | ||
| JP2010047626A5 (en) | ||
| US2568752A (en) | Dental impression composition | |
| WO2010074660A2 (en) | Working liquid that makes porcelain powder doughy and its method | |
| JPH11228364A (en) | Hair dyeing composition | |
| JPS6048918A (en) | Toothpaste | |
| JP6848969B2 (en) | Multicolor toothpaste | |
| JP6719962B2 (en) | Processed wasabi | |
| JP6671675B1 (en) | Craft clay | |
| JP7176734B2 (en) | craft clay | |
| BRPI1005083A2 (en) | paint mine | |
| JP3169652B2 (en) | Craft clay composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080610 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20101122 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110207 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110209 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140218 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4684782 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140218 Year of fee payment: 3 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |