JP2006053501A - Silver halide photographic sensitive material - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a silver halide photographic sensitive material which uses a solid disperse dye excellent in photographic properties and is manufactured because spring liable to occur in high-speed coating is suppressed. <P>SOLUTION: The silver halide photographic sensitive material comprises a support, and one photosensitive silver halide emulsion layer and one non-photosensitive hydrophilic colloidal layer disposed on one and the same surface of the support, and contains the solid disperse dye, one of the compounds represented by formula (1), one of the compounds represented by formulae (2) and (3) and a fluorine-containing surfactant on the surface side of the support on which the photosensitive silver halide emulsion layer and the non-photosensitive hydrophilic colloidal layer are disposed. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a silver halide photographic light-sensitive material, and more particularly to a silver halide photographic light-sensitive material having high sensitivity and good coated surface.

Technical background

Conventionally, the use of solid disperse dyes advantageous in photographic characteristics in silver halide photographic light-sensitive materials has been studied. For example, Patent Document 1 discloses a silver halide photographic light-sensitive material containing a solid disperse dye in an undercoat layer. However, in a silver halide photographic light-sensitive material, for example, when a solid disperse dye is used for the following purposes, the surface condition is deteriorated.
(1) To have proper spectral absorption according to the purpose of use.
(2) Photochemically inactive. In other words, avoid adverse effects in the chemical sense on the performance of the silver halide photographic emulsion layer, such as lowering of sensitivity, latent image regression, or fogging.
(3) In the process of photographic processing, it should be decolorized or dissolved and removed so as not to leave harmful coloring on the surface of the photographic photosensitive material after processing.

  On the other hand, from the viewpoint of improving antistatic properties and the like, studies have been made on silver halide photographic light-sensitive materials containing a fluorine-based surfactant and other various surfactants (Patent Documents 2 to 4). However, these methods have a problem that when a solid disperse dye is used, the surface condition is deteriorated due to repellency generated during high-speed application.

Japanese Patent Laid-Open No. 6-238881 JP 2003-270754 A Japanese Patent Laid-Open No. 8-21526 JP 2004-77661 A

  The present invention aims to solve the above-mentioned problems, and uses a solid disperse dye excellent in photographic characteristics, reduces repelling that occurs during high-speed coating, etc., and can be produced stably. An object is to provide a light-sensitive material.

As a result of intensive studies by the present inventors based on the above problems, surprisingly, an anionic surfactant containing polyethylene oxide, a nonionic surfactant containing a glycerol group, and a fluorosurfactant are combined. Thus, it was found that the surface shape can be specifically improved.
Specifically, it was achieved by the following means.

（一般式（１）中、Ｒ¹は炭素数６〜２５のアルキル基またはアルケニル基を表し、ｍ¹は２〜４のいずれかの整数を表し、ｎ¹は０〜３０のいずれかの整数を表し、ａは０または１を表す。Ｚ¹はＯＳＯ₃ＭまたはＳＯ₃Ｍを表し、Ｍはカチオンを表す。）
一般式（２）

（一般式（２）中、Ｒ² は、炭素数１〜４０の脂肪族基を表し、Ａ²は、アリーレン基を表し、Ｘ²は２価の連結基を表し、Ｇは、

を表し、Ｙ²は水素原子、−(ＣＨ₂ＣＨ₂Ｏ)_i−Ｈ(ｉは１〜５００の整数を表す）またはアニオン性基を表し、ｔ２は０または１を表し、ｍ２は１〜５０の整数を表す。)
一般式（３）

（一般式（３）中、Ｒ³ は炭素数１〜４０の脂肪族基を表し、Ａ³はアリーレン基を表し、Ｘ³ は酸素原子、または−(ＯＣＨ₂ＣＨ₂)_j−Ｏ −（ｊは１〜５００の整数を表す）で表される基を表し、Ｇは、

を表し、Ｙ³ は水素原子、−(ＣＨ₂ＣＨ₂Ｏ)_i−Ｈ(ｉは１〜５００の整数を表す）またはアニオン性基を表す。ｔ３は０または１を表し、ｍ３は１〜５０の整数を表す。)
（２）前記フッ素系界面活性剤が下記一般式（４）および／または（５）で表される化合物である（１）に記載のハロゲン化銀写真感光材料。
一般式（４）

（一般式（４）中、Ｒ^A1およびＲ^A2はそれぞれ置換もしくは無置換のアルキル基を表し、かつ、Ｒ^A1およびＲ^A2の少なくとも１つはフッ素原子で置換されたアルキル基を表す。Ｒ^A3、Ｒ^A4およびＲ^A5はそれぞれ水素原子または置換基を表し、Ｌ^A1、Ｌ^A2およびＬ^A3はそれぞれ単結合または２価の連結基を表し、Ｘ⁺はカチオン性の置換基を表す。Ｙ^-は対アニオンを表すが、分子内で荷電が０になる場合にはＹ^-はなくてもよい。ｍ^Aは０または１である。）
一般式（５）

（一般式（５）中、Ｒ^B3、Ｒ^B4およびＲ^B5はそれぞれ水素原子または置換基を表す。ＡおよびＢはそれぞれフッ素原子または水素原子を表す。ｎ^B3およびｎ^B4はそれぞれ４〜８の整数を表す。Ｌ^B1およびＬ^B2はそれぞれ、置換もしくは無置換のアルキレン基、置換もしくは無置換のアルキレンオキシ基またはこれらを組み合わせてできる２価の連結基を表す。ｍ^Bは０または１を表す。Ｍはカチオンを表す。） (1) a support, and at least one photosensitive silver halide emulsion layer and at least one non-photosensitive hydrophilic colloid layer provided on the same surface of the support; and On the side of the support on which the photosensitive silver halide emulsion layer and the non-photosensitive hydrophilic colloid layer are provided, a solid disperse dye and at least one compound represented by the following general formula (1): A silver halide photographic light-sensitive material comprising at least one compound represented by the following general formulas (2) and (3) and a fluorosurfactant.
General formula (1)

(In the general formula (1), R ¹ represents an alkyl group or alkenyl group having 6 to 25 carbon atoms, m ¹ represents any integer of 2 to 4, and n ¹ represents any integer of 0 to 30. A represents 0 or 1. Z ¹ represents OSO ₃ M or SO ₃ M, and M represents a cation.)
General formula (2)

(In the general formula (2), R ² Represents an aliphatic group having 1 to 40 carbon atoms, A ² represents an arylene group, X ² represents a divalent linking group, G represents

Y ² represents a hydrogen atom, — (CH ₂ CH ₂ O) _i —H (i represents an integer of 1 to 500) or an anionic group, t2 represents 0 or 1, m2 represents 1 to Represents an integer of 50. )
General formula (3)

(In the general formula (3), R ³ Represents an aliphatic group having 1 to 40 carbon atoms, A ³ represents an arylene group, X ³ Represents an oxygen atom or a group represented by — (OCH ₂ CH ₂ ) _j —O— (j represents an integer of 1 to 500);

Y ³ Represents a hydrogen atom, — (CH ₂ CH ₂ O) _i —H (i represents an integer of 1 to 500) or an anionic group. t3 represents 0 or 1, and m3 represents an integer of 1 to 50. )
(2) The silver halide photographic light-sensitive material according to (1), wherein the fluorine-based surfactant is a compound represented by the following general formula (4) and / or (5).
General formula (4)

(In General Formula (4), R ^A1 and R ^A2 each represent a substituted or unsubstituted alkyl group, and at least one of R ^A1 and R ^A2 represents an alkyl group substituted with a fluorine atom. R ^A3 , R ^A4 and R ^A5 each represent a hydrogen atom or a substituent, L ^A1, L ^A2 and L ^A3 represents a single bond or a divalent linking group, respectively, X ⁺ represents a cationic substituent .Y ^- Represents a counter anion, but Y ⁻ may not be present when the charge in the molecule is 0. m ^A is 0 or 1.)
General formula (5)

(In the general formula (5), R ^B3 , R ^B4 and R ^B5 each represent a hydrogen atom or a substituent. A and B each represent a fluorine atom or a hydrogen atom. N ^B3 and n ^B4 each represent 4-8. L ^B1 and L ^B2 each represent a substituted or unsubstituted alkylene group, a substituted or unsubstituted alkyleneoxy group, or a divalent linking group formed by a combination thereof, m ^B represents 0 or 1 M represents a cation.)

  In the silver halide photographic light-sensitive material of the present invention, even when a solid disperse dye advantageous for photographic properties is used, the repellency at the time of high-speed coating is reduced and the surface state is not deteriorated.

  Hereinafter, the contents of the present invention will be described in detail. In the present specification, “to” is used to mean that the numerical values described before and after it are included as a lower limit value and an upper limit value.

（一般式（１）中、Ｒ¹は炭素数６〜２５のアルキル基またはアルケニル基を表し、ｍ¹は２〜４のいずれかの整数を表し、ｎ¹は０〜３０のいずれかの整数を表し、ａは０または１を表す。Ｚ¹はＯＳＯ₃ＭまたはＳＯ₃Ｍを表し、Ｍはカチオンを表す。） General formula (1)

(In the general formula (1), R ¹ represents an alkyl group or alkenyl group having 6 to 25 carbon atoms, m ¹ represents any integer of 2 to 4, and n ¹ represents any integer of 0 to 30. A represents 0 or 1. Z ¹ represents OSO ₃ M or SO ₃ M, and M represents a cation.)

R ¹ represents an alkyl group or alkenyl group having 6 to 25 carbon atoms, the carbon number of R ¹ is preferably 6 to 22, more preferably 6 to 20, 8 to 18 are particularly preferred. The alkyl group and alkenyl group may have a cyclic structure, but a chain alkyl group and a chain alkenyl group are preferred. The alkyl group and alkenyl group may have a substituent, but preferably an unsubstituted alkyl group and alkenyl group. The chain alkyl group and the chain alkenyl group may have a branch. The position of the double bond of the alkenyl group is not particularly limited. Alkyl groups are preferred over alkenyl groups.
In the general formula (1), m ¹ represents an integer of 2 to 4. n ¹ represents an integer of 0 to 30, preferably 0 to 25, more preferably 0 to 20, particularly preferably 0 to 15, and most preferably 0 to 5.
In the general formula (1), Z ¹ represents OSO ₃ M or SO ₃ M, and M represents a cation. As the cation represented by M, for example, alkali metal ions (lithium ions, sodium ions, potassium ions, etc.), alkaline earth metal ions (barium ions, calcium ions, etc.), ammonium ions and the like are preferably applied. Of these, lithium ions, sodium ions, potassium ions, and ammonium ions are particularly preferable.
In the general formula (1), a represents 0 or 1, and 0 is preferable.

  Preferred examples of the compound represented by the general formula (1) include those described in paragraph numbers 0033 to 0037 of JP-A-2003-270754. Among these, (WS-31 to WS-37) is preferable.

（一般式（２）中、Ｒ² は、炭素数１〜４０の脂肪族基を表し、Ａ²は、アリーレン基を表し、Ｘ²は２価の連結基を表し、Ｇは、

を表し、Ｙ²は水素原子、−(ＣＨ₂ＣＨ₂Ｏ)_i−Ｈ(ｉは１〜５００の整数を表す）またはアニオン性基を表し、ｔ２は０または１を表し、ｍ２は１〜５０の整数を表す。) General formula (2)

(In the general formula (2), R ² Represents an aliphatic group having 1 to 40 carbon atoms, A ² represents an arylene group, X ² represents a divalent linking group, G represents

Y ² represents a hydrogen atom, — (CH ₂ CH ₂ O) _i —H (i represents an integer of 1 to 500) or an anionic group, t2 represents 0 or 1, m2 represents 1 to Represents an integer of 50. )

（一般式（３）中、Ｒ³ は炭素数１〜４０の脂肪族基を表し、Ａ³はアリーレン基を表し、Ｘ³ は酸素原子、または−(ＯＣＨ₂ＣＨ₂)_j−Ｏ −（ｊは１〜５００の整数を表す）で表される基を表し、Ｇは、

を表し、Ｙ³ は水素原子、−(ＣＨ₂ＣＨ₂Ｏ)_i−Ｈ(ｉは１〜５００の整数を表す）またはアニオン性基を表す。ｔ３は０または１を表し、ｍ３は１〜５０の整数を表す。) General formula (3)

(In the general formula (3), R ³ Represents an aliphatic group having 1 to 40 carbon atoms, A ³ represents an arylene group, X ³ Represents an oxygen atom or a group represented by — (OCH ₂ CH ₂ ) _j —O— (j represents an integer of 1 to 500);

Y ³ Represents a hydrogen atom, — (CH ₂ CH ₂ O) _i —H (i represents an integer of 1 to 500) or an anionic group. t3 represents 0 or 1, and m3 represents an integer of 1 to 50. )

R ² and R ³ Represents an aliphatic group having 1 to 40 carbon atoms, and the aliphatic group includes a linear or branched unsubstituted alkyl group having 1 to 40 carbon atoms (for example, a methyl group, an ethyl group, an n-propyl group, iso-propyl group, n-butyl group, sec-butyl group, tert-butyl group, n-amyl group, tert-amyl group, n-hexyl group, n-heptyl group, n-octyl group, tert-octyl group, 2-ethylhexyl group, n-nonyl group, 1,1,3-trimethylhexyl group, n-decyl group, n-dodecyl group, cetyl group, hexadecyl group, 2-hexyldecyl group, octadecyl group, eicosyl group, 2- Octyldodecyl group, docosyl group, tetracosyl group, 2-decyltetradecyl group, tricosyl group, etc.), linear or branched substituted alkyl group having 1 to 40 carbon atoms (substituent is alkoxyl group, aryl Group, halogen atom, carboxylic ester group, carbonamido group, carbamoyl group, oxycarbonyl group, phosphate ester group, etc.) (for example, benzyl group, β-phenethyl group, 2-methoxyethyl group, 4-phenylbutyl group, 4- Acetoxyethyl group, 6-phenoxyhexyl group, 12-phenyldodecyl group, 18-phenyloctadecyl group, heptadecylfluorooctyl group, 12- (p-chlorophenyl) dodecyl group, 2- (diphenyl phosphate) ethyl group, etc.), direct A chain or branched unsubstituted alkenyl group having 2 to 40 carbon atoms (for example, vinyl group, allyl group, 3-butenyl group, 2-methyl-2-butenyl group, 4-pentenyl group, 3-pentenyl group, 3- Methyl-3-pentenyl group, 5-hexenyl group, 4-hexenyl group, 3-hexenyl group, 2-hexenyl group Group, 7-octenyl group, 9-decenyl group, oleyl group, linoleyl group, linolenyl group, etc.), linear or branched substituted alkenyl group having 2 to 40 carbon atoms (for example, 2-phenylvinyl group, 4-acetyl group) 2-butenyl group, 13-methoxy-9-octadecenyl group, 9,10-dibromo-12-octadecenyl group, etc.), linear or branched C2-C40 unsubstituted alkynyl group (for example, acetylene group, Propargyl group, 3-butynyl group, 4-pentynyl group, 5-hexynyl group, 4-hexynyl group, 3-hexynyl group, 2-hexynyl group, etc.), linear or branched substituted alkynyl group having 2 to 40 carbon atoms (As the substituent, an alkoxyl group, an aryl group, etc.) (for example, 2-phenylacetylene group, 3-phenylpropargyl group, etc.) and the like are preferable.

  Among these, a linear, cyclic or branched unsubstituted alkyl group having 6 to 24 carbon atoms (for example, n-hexyl group, cyclohexyl group, n-heptyl group, n-octyl group, 2-ethylhexyl group, n-nonyl) Group, 1,1,3-trimethylhexyl group, n-decyl group, n-dodecyl group, cetyl group, hexadecyl group, 2-hexyldecyl group, octadecyl group, eicosyl group, 2-octyldodecyl group, docosyl group, tetracosyl Group, 2-decyltetradecyl group, etc.), a substituted, alkyl group having 6 to 24 carbon atoms excluding the substituent carbon number (for example, 6-phenoxyhexyl group, 12-phenyldodecyl) Group, 18-phenyloctadecyl group, heptadecylfluorooctyl group, 12- (p-chlorophenyl) dodecyl group, 4-tert-butylcyclohexane Xyl group, etc.), straight-chain, cyclic or branched unsubstituted alkenyl groups having 6 to 24 carbon atoms (for example, 5-hexenyl group, 3-hexenyl group, 3-cyclohexenyl group, 7-octenyl group, 9-decenyl group) Group, oleyl group, linoleyl group, linolenyl group, etc.) and straight-chain, cyclic or branched substituted alkenyl groups having 6 to 24 carbon atoms (for example, 9,10-dibromo-12-octadecenyl group, etc.) are particularly preferred.

A ² and A ³ represent an arylene group, preferably an arylene group having 6 to 14 carbon atoms, and particularly preferably a phenylene group.
Both t2 and t3 are preferably 0.

X ² represents a divalent linking group, preferably a group represented by the following general formula (2-2).

General formula (2-2)

In general formula (2-2), Y ²¹ , Y ²² and Y ²³ may be the same or different, each having a substituted or unsubstituted alkylene group having 1 to 40 carbon atoms, a substituted or unsubstituted arylene group having 6 to 40 carbon atoms (as a substituent) Are the same as those shown in the definition of R ² above, and the alkylene group is a methylene group, an ethylene group, a propylene group, a trimethylene group, a tetramethylene group, a pentamethylene group, a hexamethylene group, 1,4-cyclohexene. Silylene group, octamethylene group, decamethylene group, 2-methoxy-1,3-propylene group and the like, and arylene groups include o-phenylene group, m-phenylene group, p-phenylene group, 3-chloro-1,4-phenylene Group, 1,4-naphthylene group, 1,5-naphthylene group and the like are preferable. Of these, ethylene group, propylene group, trimethylene group, tetramethylene group, pentamethylene group, hexamethylene group, 1,4-cyclohexylene group, octamethylene group, decamethylene group, m-phenylene group, p- A phenylene group.

J ²¹ , J ²² And J ²³ Each represents a divalent linking unit that may be the same or different, and represents a single bond, —O—, —S—, —CO—, —COO—, —OCO—, —CON (R ²⁵ ) —. (R ²⁵ Represents a hydrogen atom, an unsubstituted alkyl group having 1 to 6 carbon atoms, or a substituted alkyl group having 1 to 6 carbon atoms excluding the carbon number of the substituent (such as an aryl group, an alkoxyl group, or a halogen atom). . ), -N (R ²⁵ ) CO- (R ²⁵ Is the same as shown above, -CON (R ²⁵ ) CO- (R ²⁵ is the same as shown above), -N (R ²⁵ ) CON (R ²⁶ )-(R ²⁵ , R ²⁶ is Each may be the same or different and is the same as defined above for R ²⁵ ), —OCON (R ²⁵ ) — (R ²⁵ is the same as shown above), —N (R ²⁵ ) COO -(R ²⁵ Are the same as those shown above), —SO ₂ —, —SO ₂ N (R ²⁵ ) — (R ²⁵ is the same as shown above), —N (R ²⁵ ) SO ₂ — (R ²⁵ is the same as Same as above, -N (COR ²⁵ )-(R ²⁵ is the same as above), -OP (= O) (OR ² ) O- (R ² is as defined above) Are the same). Among these, a single bond, —O—, —S—, —CO—, —COO—, —OCO—, —CON (R ²⁵ ) — (R ²⁵ is a hydrogen atom, a methyl group, an ethyl group, or a propyl group. -N (R ²⁵ ) CO- (R ²⁵ is the same as shown above), -SO ₂ N (R ²⁵ )-(R ²⁵ is the same as shown above), -N (R ²⁵ ) SO ₂ — (R ²⁵ is the same as described above) and the like are particularly preferable.

  p, q, and r are each an integer of 0-5. Preferably, p, q and r are each an integer of 0 to 3, and it is particularly preferable that p, q and r each take an integer of 0 or 1. s2 is an integer of 1 to 10, preferably 1 to 5, particularly preferably an integer of 1 to 3. a2 and b2 are each an integer of 0-50. Among these, it is preferable that a2 and b2 each independently take an integer value of 0 to 20, and it is particularly preferable that a2 and b2 take an integer of 0 to 10.

X ² Particularly preferred is an oxygen atom or a group represented by — (OCH ₂ CH ₂ ) _j —O—. In the general formula (2), j preferably takes a value of 1 to 50, particularly preferably 3 to 20.

X ³ is preferably an oxygen atom or a group represented by — (OCH ₂ CH ₂ ) _j —O— (j is a value of 1 to 50), particularly preferably an oxygen atom or — (OCH ₂ CH ₂ ) _j. This is a case of a group represented by -O- (j is a value of 3 to 20).

を表す。 G is

Represents.

Y ² and Y ³ are a hydrogen atom, — (CH ₂ CH ₂ O) _i —H (i represents an integer of 1 to 500, preferably an integer of 3 to 100, particularly preferably an integer of 5 to 50.) Or an anionic group.
Preferred anionic groups _{-COOM, -SO 3 M, -OSO 3} M, -PO (OM) 2, -OPO (OM) 2 (M represents a counter cation, is preferably an alkali metal ion or an ammonium ion ) it can be mentioned, particularly preferably -SO ₃ M, -OSO ₃ M. Particularly preferred as Y ² and Y ³ are a hydrogen atom, —SO ₃ Na, and —SO ₃ NH ₄ .

m2 or m3 represents an integer of 1 to 50, preferably 2 to 30, particularly preferably 3 to 15.
Preferred examples of the compound represented by the general formula (2) or (3) include those described in paragraph Nos. 0037 to 0042 of JP-A No. 08-21526. Preferably Among them, (W-2, W- 3, W-4, W-13, W-21, W-23, W-28 and _{C 12 H 25 O (CH 2} CH (OH) CH 2 O) ₁₀ H).

（一般式（４）中、Ｒ^A1およびＲ^A2はそれぞれ置換もしくは無置換のアルキル基を表し、かつ、Ｒ^A1およびＲ^A2の少なくとも１つはフッ素原子で置換されたアルキル基を表す。Ｒ^A3、Ｒ^A4およびＲ^A5はそれぞれ水素原子または置換基を表し、Ｌ^A1、Ｌ^A2およびＬ^A3はそれぞれ単結合または２価の連結基を表し、Ｘ⁺はカチオン性の置換基を表す。Ｙ^-は対アニオンを表すが、分子内で荷電が０になる場合にはＹ^-はなくてもよい。ｍ^Aは０または１である。） General formula (4)

(In General Formula (4), R ^A1 and R ^A2 each represent a substituted or unsubstituted alkyl group, and at least one of R ^A1 and R ^A2 represents an alkyl group substituted with a fluorine atom. R ^A3 , R ^A4 and R ^A5 each represent a hydrogen atom or a substituent, L ^A1, L ^A2 and L ^A3 represents a single bond or a divalent linking group, respectively, X ⁺ represents a cationic substituent .Y ^- Represents a counter anion, but Y ⁻ may not be present when the charge in the molecule is 0. m ^A is 0 or 1.)

In the general formula (4), R ^A1 and R ^A2 each represent a substituted or unsubstituted alkyl group. The alkyl group has 1 or more carbon atoms and may be linear, branched or cyclic. Examples of the substituent include a halogen atom, an alkenyl group, an aryl group, an alkoxyl group, a halogen atom other than fluorine, a carboxylic acid ester group, a carbonamido group, a carbamoyl group, an oxycarbonyl group, and a phosphoric acid ester group. However, at least one of R ^A1 and R ^A2 represents an alkyl group substituted with a fluorine atom (hereinafter, the alkyl group substituted with a fluorine atom is referred to as “Rf”).

  Rf is an alkyl group substituted with at least one fluorine atom having 1 or more carbon atoms. Rf only needs to be substituted with at least one fluorine atom, and may have any of linear, branched and cyclic structures. Further, it may be further substituted with a substituent other than a fluorine atom, or may be substituted only with a fluorine atom. Examples of the substituent other than the fluorine atom of Rf include an alkenyl group, an aryl group, an alkoxyl group, a halogen atom other than fluorine, a carboxylic acid ester group, a carbonamido group, a carbamoyl group, an oxycarbonyl group, and a phosphoric acid ester group.

Rf is preferably a fluorine-substituted alkyl group having 1 to 16 carbon atoms, more preferably 1 to 12 carbon atoms, and still more preferably 4 to 10 carbon atoms. As a preferable example of Rf,
_{- (CH 2) 2 - (} CF 2) 4 F, - (CH 2) 2 - (CF 2) 6 F, - (CH 2) 2 - (CF 2) 8 F, - (CH 2) - (CF _{2) 4 H, - (CH} 2) - (CF 2) 6 H, - (CH 2) - (CF 2) 8 H, - (CH 2) 3 - (CF 2) 4 F, - (CH 2) _{6 - (CF 2) 4 F} , -CH (CF 3) CF 3,
Etc.

Rf is more preferably an alkyl group having 4 to 10 carbon atoms, the terminal of which is substituted with a trifluoromethyl group, and particularly preferably 3 to 3 carbon atoms represented by — (CH ₂ ) α- (CF ₂ ) βF. 10 represents an alkyl group (α represents an integer of 1 to 6; β represents an integer of 3 to 8). Specifically, —CH ₂ — (CF ₂ ) ₂ F, — (CH ₂ ) ₆ — (CF ₂ ) ₄ F, — (CH ₂ ) ₃ — (CF ₂ ) ₄ F, —CH ₂ — (CF _{2) 3 F, - (CH} 2) 2 - (CF 2) 4 F, - (CH 2) 3 - (CF 2) 4 F, - (CH 2) 6 - (CF 2) 4 F, - (CH _{2) 2 - (CF 2)} 6 F, - (CH 2) 3 - (CF 2) 6 F, - (CH 2) 2 - (CF 2) 6 F, and the like. Among these, in _{particular, - (CH 2) 2 -} (CF 2) 4 F and _{- (CH 2) 2 - (} CF 2) 6 F is most preferred.

In the general formula (4), both R ^A1 and R ^A2 preferably represent Rf.

When R ^A1 and R ^A2 each represents an alkyl group other than Rf, that is, an alkyl group not substituted with a fluorine atom, the alkyl group is preferably a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms, A substituted or unsubstituted alkyl group having 6 to 24 carbon atoms is more preferable. Preferred examples of the unsubstituted alkyl group having 6 to 24 carbon atoms include n-hexyl group, n-heptyl group, n-octyl group, tert-octyl group, 2-ethylhexyl group, n-nonyl group, 1,1, 3-trimethylhexyl group, n-decyl group, n-dodecyl group, cetyl group, hexadecyl group, 2-hexyldecyl group, octadecyl group, eicosyl group, 2-octyldodecyl group, docosyl group, tetracosyl group, 2-decyltetra A decyl group, a tricosyl group, a cyclohexyl group, a cycloheptyl group, etc. are mentioned. Preferred examples of the alkyl group having 6 to 24 carbon atoms having a substituent include 2-hexenyl group, oleyl group, linoleyl group, linolenyl group, benzyl group, β-phenethyl group, 2-methoxyethyl group, 4-phenylbutyl group, 4-acetoxyethyl group, 6-phenoxyhexyl group, 12-phenyldodecyl group, 18-phenyloctadecyl group, 12- (p-chlorophenyl) dodecyl group, 2- (diphenyl phosphate) ethyl group, etc. Can be mentioned.

The alkyl group other than Rf represented by R ^A1 and R ^A2 is more preferably a substituted or unsubstituted alkyl group having 6 to 18 carbon atoms. Preferred examples of the unsubstituted alkyl group having 6 to 18 carbon atoms include n-hexyl group, cyclohexyl group, n-heptyl group, n-octyl group, 2-ethylhexyl group, n-nonyl group, 1,1,3- Examples include trimethylhexyl group, n-decyl group, n-dodecyl group, cetyl group, hexadecyl group, 2-hexyldecyl group, octadecyl group, 4-tert-butylcyclohexyl group and the like. Preferable examples of the substituted alkyl group having 6 to 18 carbon atoms having a substituent include phenethyl group, 6-phenoxyhexyl group, 12-phenyldodecyl group, oleyl group, linoleyl group, and linolenyl group. .

The alkyl group other than Rf represented by R ^A1 and R ^A2 is particularly preferably an n-hexyl group, a cyclohexyl group, an n-heptyl group, an n-octyl group, a 2-ethylhexyl group, an n-nonyl group, 1,1,3-trimethylhexyl group, n-decyl group, n-dodecyl group, cetyl group, hexadecyl group, 2-hexyldecyl group, octadecyl group, oleyl group, linoleyl group, linolenyl group, most preferably carbon It is a linear, cyclic or branched unsubstituted alkyl group of formula 8-16.

In the general formula (4), R ^A3 , R ^A4 and R ^A5 each independently represent a hydrogen atom or a substituent. Substituent T described later can be applied as the substituent. R ^A3 , R ^A4 and R ^A5 preferably represent an alkyl group or a hydrogen atom, more preferably represent an alkyl group having 1 to 12 carbon atoms or a hydrogen atom, and more preferably represent a methyl group or a hydrogen atom. And particularly preferably represents a hydrogen atom.

In the general formula (4), L ^A1 and L ^A2 each independently represent a single bond or a divalent linking group. There is no particular limitation as long as it is a single bond or a divalent linking group, but preferably an arylene group, —O—, —S— or —NR ^A100 — (R ^A100 represents a hydrogen atom or a substituent. R ^A100 is the same as the substituent T described later, preferably an alkyl group, the aforementioned Rf or hydrogen atom, more preferably a hydrogen atom), or a group obtained by combining them alone. Preferred is —O—, —S— or —NR ^A100 —. L ^A1 and L ^A2 are more preferably —O— or —NR ^A100 —, still more preferably —O— or —NH—, and particularly preferably —O—.

In the general formula (4), L ^A3 represents a divalent linking group. The divalent linking group is not particularly limited, but is preferably an alkylene group, an arylene group, -C (= O)-, -O-, -S-, -S (= O)-, -S (= O) ₂ — or —NR ^A100 — (R ^A100 represents a hydrogen atom or a substituent, and the substituent is the same as the substituent T described later. R ^A100 is preferably an alkyl group or a hydrogen atom, and more preferably. Is a hydrogen atom) alone or in combination thereof, more preferably an alkylene group having 1 to 12 carbon atoms, an arylene group having 6 to 12 carbon atoms, -C (= O)-, -O —, —S—, —S (═O) —, —S (═O) ₂ — or —NR ^A100 — is a group obtained alone or in combination. More preferably, Z is an alkylene group having 1 to 8 carbon atoms, —C (═O) —, —O—, —S—, —S (═O) —, —S (═O) ₂ — or —NR. ^A100 - a a group obtained singly or in their combination, for _{example, - (CH 2) 2 S} -, - (CH 2) 2 NH -, - (CH 2) 3 NH -, - (CH 2) 2 C (= O) NH -, - (CH 2) 2 SCH 2 -, - (CH 2) 2 NHCH 2 -, - (CH 2) 3 NHCH 2 -, and the like.

In the general formula (4), X ⁺ represents a cationic substituent, and X ⁺ is preferably an organic cationic substituent, and more preferably a nitrogen or phosphorus cationic group. More preferred is a pyridinium cation or an ammonium cation, and more preferred is a trialkylammonium cation represented by the following general formula (4-1).

Formula (4-1)

In the general formula (4-1), R ^A13 , R ^A14 and R ^A15 each represent a substituted or unsubstituted alkyl group. Examples of the substituent include the substituent T described in paragraph numbers 0173 to 0176 of JP-A No. 2003-270754, and a preferable range thereof is also synonymous with these.
R ^A13 , R ^A14 and R ^A15 may combine with each other to form a ring, if possible. R ^A13 , R ^A14 and R ^A15 are preferably an alkyl group having 1 to 12 carbon atoms, more preferably an alkyl group having 1 to 6 carbon atoms, and still more preferably a methyl group, an ethyl group or a methyl carboxyl group. And particularly preferably a methyl group.

In the general formula (4-1), Y ⁻ represents a counter anion and may be an inorganic anion or an organic anion. Further, when the charge becomes 0 in the molecule, Y ⁻ may not be present. Preferred examples of the inorganic anion include iodo ion, bromine ion and chlorine ion, and preferred examples of the organic anion include p-toluenesulfonate ion and benzenesulfonate ion. Y ^- is more preferably iodo ion, p-toluenesulfonic acid ion or benzenesulfonic acid ion, and still more preferably p-toluenesulfonic acid.

In the general formula (4), m ^A represents 0 or 1, and preferably 0.

  Among the compounds represented by the general formula (4), compounds represented by the following general formula (4-2) are preferable.

Formula (4-2)

In General Formula (4-2), R ^A11 and R ^A12 each represent a substituted or unsubstituted alkyl group, and at least one of R ^A11 and R ^A12 represents an alkyl group substituted with a fluorine atom, and R ^A11 And the total number of carbon atoms of R ^A12 is 19 or less. L ^A2 and L ^A3 each independently represent —O—, —S—, or —NR ¹⁰⁰ —, R ¹⁰⁰ represents a hydrogen atom or a substituent, and L ^A1 represents a single bond or a divalent linking group. L ^A1 and Y ⁻ have the same meanings as those in the general formula (4), and preferred ranges thereof are also the same. R ^A13 , R ^A14 and R ^A15 have the same ^{meanings as} those in the general formula (2-1), and preferred ranges are also the same.

In the general formula (4-2), L ^A2 and L ^A3 are each —O—, —S— or —NR ¹⁰⁰ — (R ¹⁰⁰ represents a hydrogen atom or a substituent, and the substituent is a substituent described later. Those listed as T can be applied, and R ¹⁰⁰ is preferably an alkyl group, the aforementioned Rf, or a hydrogen atom, and more preferably a hydrogen atom. L ^A2 and L ^A3 are more preferably —O— or —NH—, and still more preferably —O—.

In the general formula (4-2), R ^A11 and R ^A12 have the same ^{meanings as} R ^A1 and R ^A2 in the general formula (4), respectively, and preferred ranges thereof are also the same. However, the total number of carbon atoms of R ^A11 and R ^A12 is 19 or less.

  Among the compounds represented by the general formula (4), a compound represented by the following general formula (4-3) is more preferable.

Formula (4-3)

In the general formula (4-3), R ^A13 , R ^A14 , R ^A15 , L ^A1 and Y ⁻ have the same meanings as those in the general formula (4) and the general formula (4-1), respectively, and a preferable range. Is the same. A and B each independently represent a fluorine atom or a hydrogen atom. A and B both preferably represent a fluorine atom or a hydrogen atom, and preferably both represent a fluorine atom. In the general formula (4-3), n ^A1 represents an integer of 1 to 6, and n ^A2 represents an integer of 3 to 8.

  Among the compounds represented by the general formula (4), a compound represented by the following general formula (4-4) is more preferable.

Formula (4-4)

In the general formula (4-4), n ^A1 represents any integer of 1 to 6, n ^A2 represents any integer of 3 to 8, but 2 (n ^A1 + n ^A2 ) is 19 or less. . R ^A13 , R ^A14 , R ^A15 , L ^A1 and Y ⁻ have the same meanings as those in formula (4) and formula (4-1), respectively, and preferred ranges thereof are also the same.

n ^A1 represents an integer of 1 to 6, preferably an integer of 1 to 3, more preferably 2 or 3, and most preferably 2. n ^A2 represents an integer of 3 to 8, more preferably 3 to 6, and still more preferably 4 to 6. As a preferable combination of n ^A1 and n ^A2 , n ^A1 is preferably 2 or 3, and n ^A2 is preferably 4 or 6.

  Preferable examples of the compound represented by the general formula (4) include those described in paragraph numbers 0077 to 0090 of JP-A-2003-270754. Among these, FS-113, 114, 115, 116, 119, and 120) are preferable.

（一般式（５）中、Ｒ^B3、Ｒ^B4およびＲ^B5はそれぞれ水素原子または置換基を表す。ＡおよびＢはそれぞれフッ素原子または水素原子を表す。ｎ^B3およびｎ^B4はそれぞれ４〜８の整数を表す。Ｌ^B1およびＬ^B2はそれぞれ、置換もしくは無置換のアルキレン基、置換もしくは無置換のアルキレンオキシ基またはこれらを組み合わせてできる２価の連結基を表す。ｍ^Bは０または１を表す。Ｍはカチオンを表す。） General formula (5)

(In the general formula (5), R ^B3 , R ^B4 and R ^B5 each represent a hydrogen atom or a substituent. A and B each represent a fluorine atom or a hydrogen atom. N ^B3 and n ^B4 each represent 4-8. L ^B1 and L ^B2 each represent a substituted or unsubstituted alkylene group, a substituted or unsubstituted alkyleneoxy group, or a divalent linking group formed by a combination thereof, m ^B represents 0 or 1 M represents a cation.)

In the general formula (5), R ^B3 , R ^B4 and R ^B5 each represent a hydrogen atom or a substituent. Examples of the substituent include substituent T described in paragraph numbers 0173 to 0176 of JP-A No. 2003-270754, and a preferable range thereof is also synonymous with these.
R ^B3 , R ^B4 and R ^B5 are preferably an alkyl group or a hydrogen atom, more preferably an alkyl group having 1 to 12 carbon atoms or a hydrogen atom, still more preferably a methyl group or a hydrogen atom, Preferably it is a hydrogen atom.

  In the general formula (5), A and B each represents a fluorine atom or a hydrogen atom. A and B are preferably both fluorine atoms or both hydrogen atoms, more preferably both fluorine atoms.

In the general formula (5), n ^B3 and n ^B4 each represent an integer of 4 to 8. Preferably as n ^B3 and n ^B4 in integer of 4-6, and a n ^B3 = n ^B4, more preferably an integer of 4 or 6, and an n ^B3 = n ^B4, more preferably n ^B3 = n ^B4 = 4.

In the general formula (5), m ^B represents 0 or 1, both of which are similarly preferred.

In the general formula (5), L ^B1 and L ^B2 each independently represent a substituted or unsubstituted alkylene group, a substituted or unsubstituted alkyleneoxy group, or a divalent group formed by combining these. Examples of the substituent include the substituent T described in paragraphs 0173 to 0176 of JP-A No. 2003-270754, and a preferable range thereof is also synonymous with these.
L ^B1 and L ^B2 each preferably have 4 or less carbon atoms, and are preferably unsubstituted alkylene.

  M represents a cation and has the same meaning as M in the general formula (1). M is preferably lithium ion, sodium ion, potassium ion or ammonium ion, and more preferably lithium ion, sodium ion or potassium ion. More preferred is sodium ion.

  Among the compounds represented by the general formula (5), the compounds represented by the following general formula (5-1) are preferable.

General formula (5-1)

In the general formula (5-1), R ^B3 , R ^B4 , R ^B5 , n ^B3 , n ^B4 , m ^B , A, B and M have the same meaning as those in the general formula (5) and are preferable. The range is the same. n ^B1 and n ^B2 each independently represent an integer of 1 to 6.

In the general formula (5-1), n ^B1 and n ^B2 each independently represents an integer of 1 to 6. n ^B1 and n ^B2 in integer of 1 to 6, and is preferably an n ^B1 = n ^B2, 2 or 3, and more preferably from ^{n B1 = n B2, n B1} = n B2 = 2 More preferably.

  Among the compounds represented by the general formula (5), a compound represented by the following general formula (5-2) is more preferable.

General formula (5-2)

In the general formula (5-2), n ^B3 , n ^B4 , m ^B and M have the same meanings as those in the general formula (5), and preferred ranges are also the same. In the general formula (5-2), n ^B1 and n ^B2 have the same meanings as those in the general formula (5-1), and preferred ranges are also the same.

  The compound represented by the general formula (5) is more preferably a compound represented by the following general formula (5-3).

Formula (5-3)

In the general formula (5-3), n ^B5 represents 2 or 3, and n ^B6 represents any integer of 4 to 6. m ^B represents 0 or 1, both of which are likewise preferred. M has the same meaning as M in the general formula (5), and the preferred range is also the same.

  Preferred examples of the compound represented by the general formula (5) include compounds described in paragraph numbers 0115 to 0119 of JP-A-2003-270754. Among these, (FS-201, 202, 204, 207, 219, 220, 222, 223) is preferable.

In a silver halide photographic light-sensitive material having a support and at least one photosensitive silver halide emulsion layer and at least one non-photosensitive hydrophilic colloid layer provided on the same surface of the support, On the side of the support on which the photosensitive silver halide emulsion layer is provided, at least one compound represented by the general formula (1), and the general formula (2) and the general formula (3) are used. It contains at least one kind of compound, a fluorosurfactant, and a solid disperse dye. Particularly preferably, the photosensitive silver halide emulsion layer and / or the non-photosensitive hydrophilic colloid layer has at least one compound represented by the general formula (1), the general formula (2) and the general formula (3). It is preferable that at least one of the compounds represented by formula (II) and a fluorosurfactant are included.
As a preferred embodiment of the silver halide photographic light-sensitive material of the present invention, the outermost layer has a non-photosensitive hydrophilic colloid layer, and the outermost layer is a compound represented by the above general formulas (1) to (3), The aspect containing a fluorine-type surfactant is mentioned.
The outermost layer can be formed by coating an aqueous coating composition containing the compounds represented by the above general formulas (1) to (3) and a fluorosurfactant above the support. Here, the compounds represented by the general formulas (1) to (3) and the fluorosurfactant may be used alone or in combination of two or more. Also good. Moreover, you may use another surfactant with those components. Examples of the surfactant that can be used in combination include other anionic, cationic, and other nonionic surfactants. The surfactant used in combination may be a polymer surfactant. As the surfactant used in combination, other anionic or other nonionic surfactants are more preferable. Examples of surfactants that can be used in combination include JP-A-62-215272 (pages 649-706), Research Disclosure (RD) Item 17643, pages 26-27 (December 1978), pages 18716, 650 ( (November 1979), 307105, pages 875-876 (November 1989), and the like.

As other components that may be contained in the aqueous coating composition, for example, those described in paragraph numbers 0178 to 0179 of JP-A No. 2003-270754 can be employed.
There is no restriction | limiting in particular about the density | concentration of the compound represented by the said general formula (1)-(3) in the said aqueous coating composition, and a fluorine-type surfactant, The structure of the compound to be used, its use, In an aqueous composition The amount of use can be arbitrarily determined according to the type and amount of the material included, the configuration of the medium, and the like.
Preferably to support a compound represented by the general formula (1) is 1 to 100 mg / m ^2, more preferably from 5 to 30 mg / m ^2. Formula (2) and / or the compound represented by (3) are in total, preferably 1 to 100 mg / m ^2, more preferably 1 to 30 mg / m ^2. The total amount of the compounds represented by the general formula (4) and / or (5) is preferably 0.1 to 20 g / m ² , more preferably 0.2 to 5 mg / m ² .

  The silver halide photographic light-sensitive material of the present invention can be produced by coating one or more of the aqueous coating compositions above a support. The coating method of the coating composition is not particularly limited, and may be any of a slide bead coating method, a slide curtain coating method, an extrusion curtain coating method, and an extrusion bead coating method. Among these, the slide bead coating method is preferable.

Hereinafter, various materials and apparatuses used in the silver halide photographic light-sensitive material of the present invention may be those described in paragraph numbers 0182 to 0215 of JP-A-2003-270754, for example. Specifically, the emulsions described in paragraph numbers 0182 to 0211 of JP-A No. 2003-270754 can be employed. In particular, the silver halide grains used in the present invention may be chemically sensitized, for example, according to the description in paragraphs 0197 to 0202 of JP-A No. 2003-270754.

  Regarding emulsions and layer alignment techniques that can be used for photographic light-sensitive materials using the emulsions, silver halide emulsions, functional couplers such as dye-forming couplers and DIR couplers, various additives, and development processing EP 0565096A1 (published on Oct. 13, 1993) and the patents cited therein.

  The present invention will be described more specifically with reference to the following examples. The materials, amounts used, ratios, processing details, processing procedures, and the like shown in the following examples can be changed as appropriate without departing from the spirit of the present invention. Therefore, the scope of the present invention is not limited to the specific examples shown below.

Example 1
In Example 1 described in paragraph Nos. 0133 to 0150 of JP-A-7-225447, the same procedure was carried out except that the surfactant and the emulsion were changed as follows.

  That is, in paragraph No. 0141 of JP-A-7-225447, sodium dodecylbenzenesulfonate, which is a surfactant for the protective layer, is used as the compound corresponding to the general formula (1), and compound-8 is used as the general formula (2). ) Or (3), the compound-9 was replaced with the following fluorosurfactant. Specifically, it is as shown in Table 1.

Emulsion 2 parts and 3 parts were added to 1 part of Table 1 kept at 64 ° C. over 20 minutes while controlling to pAg 8.3 while stirring, and then 4 parts and 5 parts of Table 1 were added. The mixture was added for 30 minutes while controlling to a pAg of 7.6, and finally a monodispersed cubic silver iodobromide emulsion having an average grain size of 0.3 μm and an average iodine content of 1 mol% was obtained (variation coefficient: 8%). . Thereafter, the mixture was washed with water by the flocculation method using the following compound, gelatin was added, pH was adjusted to 6.8, and pAg was adjusted to 9.5. Thereafter, 2.8 mg of sodium thiosulfate per 1 mol of silver, chloride Then, 4.6 mg of gold acid, 36 mg of potassium thiocyanate, and 10.2 mg of sodium benzenethiosulfonate were added, and chemical sensitization was performed at 65 ° C. so as to obtain an optimum sensitivity. Further, 500 mg of 2-methyl-4-hydroxy-1,3,3a, 7-tetrazaindene as a stabilizer and 100 mg of phenoxyethanol as a preservative were added to obtain silver iodobromide cubic emulsion A.

本発明界面活性剤（４）（本発明（４））下記化合物

比較界面活性剤（１）（比較（１））C₈H₁₇-ph-(OCH₂CH₂)n-SO₃Na ｎ＝２〜４
比較界面活性剤（２）（比較（２））CH₃-ph-O(CH₂CH₂O)₂₀-H Surfactants present invention surfactant (1) (invention _{(1)) C 10 H 21} -O- (CH 2 CH 2 O) n- (CH 2) 4 -SO 3 Na n: Average 2
The surfactant (2) of the present invention (the present invention (2)) C ₁₂ H ₂₅ O— (CH ₂ CH (OH) CH ₂ O) ₁₀ —H
The surfactant (3) of the present invention (the present invention (3)) The following compounds

The surfactant (4) of the present invention (the present invention (4)) the following compound

Comparative Surfactant (1) (Comparison _{(1)) C 8 H 17} -ph- (OCH 2 CH 2) n-SO 3 Na n = 2~4
Comparative surfactant (2) (Comparison (2)) CH ₃ -ph-O (CH ₂ CH ₂ O) ₂₀ -H

  The results are shown in Table 2. Here, the evaluation (repel) is shown by a five-step evaluation, with 5 being best and 4 or more being within the practical range. Further, “-” in Table 2 indicates that the compound is not added.

As shown in Table 2, by adopting the compounds corresponding to the general formulas (1) to (3) and the fluorosurfactant of the present invention (No. 5 and 6), repelling was a preferable result.
On the other hand, when no fluorosurfactant is used (No. 3) or when the compounds represented by the general formulas (2) and (3) are not used (No. 4), the evaluation of repelling is practical. It became low out of range.

Example 2
In Example 1 described in paragraph Nos. 0170 to 0193 of JP-A-7-168324, the surfactant was changed to the surfactant of the present invention. That is, the protective upper layer N-perfluorooctanesulfonyl-N-propylglycine potassium described in paragraph No. 0174 of JP-A-7-168324 is used as the surfactant (3) of the present invention and the dodecylbenzene. The experiment was conducted by replacing the sulfonic acid with the surfactant (1) of the present invention so as to have the same amount, and further adding 20 mg / m ^{2 of the} surfactant (2) of the present invention. As a result, the same result as in Example 1 (repel was 5) was obtained.

Example 3
In Example 1 described in paragraph Nos. 0016 to 0031 of JP-A-7-219096, compound F-13 of the surface protective layer described in paragraph Nos. 0025 and 0026 of the publication is used as the surfactant (1) of the present invention. In addition, F-14 described in the paragraph numbers 0025 and 0026 was changed to FS-113 (paragraph number 0079) of JP-A-2003-270754, and the amount was 5 mg / m ² . Further, 20 mg / m ^{2 of the} surfactant (2) of the present invention was added. Further, a dye layer containing the solid disperse dye of Example 1 was provided between the emulsion layer and the support. As a result, the same result as in Example 1 (repel was 5) was obtained.

Example 4
In Example 1 of page 13 upper right 14th line-page 15 lower left 16th line of Unexamined-Japanese-Patent No. 4-161949, the thing of the 2nd one from the bottom among the uppermost layer surfactant described in the 14th page upper left of the same gazette The surfactant (1) of the present invention (13) was changed to 13 mg / m ² , the first from the bottom was changed to the present invention (2), and 100 mg / m ² fluorine surfactant was changed to 0.8 mg / m ² of the present invention (3). change in m ^2, and more, provided dyed layer comprising a solid disperse dye of example 1 between the emulsion layer and the support. As a result, the same result as in Example 1 (repel was 5) was obtained.

Example 5
In Example 1 described in paragraph Nos. 0076 to 0085 of JP-A-5-165137, two surfactants of the protective layer described in Table 1 of paragraph No. 0080 of the publication are used as the surfactant of the present invention ( 1) 60 mg / m ² and (3) 7 mg / m ² , and 20 mg / m ^{2 of the} surfactant (2) was further added to prepare a photosensitive material. Further, a dye layer containing the solid disperse dye of Example 1 was provided between the emulsion layer and the support. As a result, the same result as in Example 1 (repel was 5) was obtained.

As described above, in the silver halide photographic light-sensitive material, the compound represented by the general formula (1), at least one compound represented by the general formulas (2) and (3), and a fluorine-based surfactant are employed. It was found that the repellency was improved.
Therefore, it can be preferably used for a silver halide photographic light-sensitive material using a solid disperse dye.

Claims (2)

A support, and at least one photosensitive silver halide emulsion layer and at least one non-photosensitive hydrophilic colloid layer provided on the same surface of the support, and the support On the side of the surface on which the photosensitive silver halide emulsion layer and the non-photosensitive hydrophilic colloid layer are provided, at least one compound represented by the following general formula (1), and the following general formula: A silver halide photographic light-sensitive material comprising at least one compound represented by formula (2) and general formula (3) and a fluorosurfactant.
General formula (1)

(In the general formula (1), R ¹ represents an alkyl group or alkenyl group having 6 to 25 carbon atoms, m ¹ represents any integer of 2 to 4, and n ¹ represents any integer of 0 to 30. A represents 0 or 1. Z ¹ represents OSO ₃ M or SO ₃ M, and M represents a cation.)
General formula (2)

(In the general formula (2), R ² Represents an aliphatic group having 1 to 40 carbon atoms, A ² represents an arylene group, X ² represents a divalent linking group, G represents

Y ² represents a hydrogen atom, — (CH ₂ CH ₂ O) _i —H (i represents an integer of 1 to 500) or an anionic group, t2 represents 0 or 1, m2 represents 1 to Represents an integer of 50. )
General formula (3)

(In the general formula (3), R ³ Represents an aliphatic group having 1 to 40 carbon atoms, A ³ represents an arylene group, X ³ Represents an oxygen atom or a group represented by — (OCH ₂ CH ₂ ) _j —O— (j represents an integer of 1 to 500);

Y ³ Represents a hydrogen atom, — (CH ₂ CH ₂ O) _i —H (i represents an integer of 1 to 500) or an anionic group. t3 represents 0 or 1, and m3 represents an integer of 1 to 50. ) The silver halide photographic light-sensitive material according to claim 1, wherein the fluorine-based surfactant is a compound represented by the following general formula (4) and / or (5).
General formula (4)

(In General Formula (4), R ^A1 and R ^A2 each represent a substituted or unsubstituted alkyl group, and at least one of R ^A1 and R ^A2 represents an alkyl group substituted with a fluorine atom. R ^A3 , R ^A4 and R ^A5 each represent a hydrogen atom or a substituent, L ^A1, L ^A2 and L ^A3 represents a single bond or a divalent linking group, respectively, X ⁺ represents a cationic substituent .Y ^- Represents a counter anion, but Y ⁻ may not be present when the charge in the molecule is 0. m ^A is 0 or 1.)
General formula (5)

(In the general formula (5), R ^B3 , R ^B4 and R ^B5 each represent a hydrogen atom or a substituent. A and B each represent a fluorine atom or a hydrogen atom. N ^B3 and n ^B4 each represent 4-8. L ^B1 and L ^B2 each represent a substituted or unsubstituted alkylene group, a substituted or unsubstituted alkyleneoxy group, or a divalent linking group formed by a combination thereof, m ^B represents 0 or 1 M represents a cation.)