JP2006007727A - Manufacturing method of extrusion-molded article of wooden flour resin - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a manufacturing method of an extrusion-molded article of a wooden flour resin capable of manufacturing the extrusion-molded article of the wooden flour resin showing high dimensional accuracy and high productivity even using an olefin-based resin as a material in the case of manufacturing the extrusion-molded article of the wooden flour resin having high tenacity and high stiffness and showing improved caster resistance. <P>SOLUTION: A mixture composition 3 is composed of 15 to 45wt% of the olefin-base resin, 50 to 80wt% of the wooden flour having an average diameter of 20 to 80 mesh, a compatibilizer making the wooden flour 2 and the olefin-base resin 1 tightly contact each other, and an additive having an effect of increasing melt tension, and 0.1 to 1.0wt% of a foaming agent is compounded in the mixture composition 3. An intermediate molded article 5 is molded by extrusion-molding the mixture compound 3 containing the foaming agent. Then the intermediate molded article 5 is subjected to sizing fabrication to produce the extrusion-molded article 6 of the wooden flour resin. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a method for producing a wood powder resin extruded product obtained by extrusion molding a mixed composition of wood powder and an olefin resin.

  A wood powder resin molded product obtained by molding a mixed composition of wood powder and resin can exhibit a wood texture on the appearance and has excellent resistance to fading and corrosion, that is, has the advantages of wood and resin. In addition, pulverized construction waste materials can be used for wood flour, and there are environmental considerations. In recent years, not only interior materials but also exterior materials have been widely used, and research and inventions have been actively conducted. ing. As a production method for obtaining this wood powder resin molded product, for example, extrusion molding that is easy to operate and excellent in productivity is often employed. As a manufacturing method of the wood powder resin extruded product 6, as shown in FIG. 4A, the mixed composition 3 of the wood powder 2 and the resin is extruded by the extruder 7 and is discharged from the extruder 7. The intermediate molded product 5 is taken up by the take-up machine 12, and the intermediate molded product 5 is sized by the sizing device 8 and molded to obtain a wood powder resin extruded product 6 of a predetermined shape.

  In general, there are various types of wood powder resin extruded products 6 depending on the application, and for example, it is obtained by not adding a foaming agent to the mixed composition 3 of wood powder 2 and resin. Foaming agent blended in wood powder resin extruded product 6 with high strength and high hardness and improved caster resistance and mixed composition 3 of wood powder 2 and resin to reduce the weight and nail There is a wood resin foam extrusion 6a that is easy to drive.

  By the way, although various resin is conventionally used for resin which comprises the mixed composition 3, the case where the olefin resin 1 is used is known, for example (for example, refer patent document 1). This Patent Document 1 is intended to obtain a wood resin foam extrusion molded article 6a which is efficiently light and excellent in workability by efficiently including bubbles 4 due to foaming of a foaming agent. Specifically, in Patent Document 1, wood powder 2 having a particle size of 150 μm or less is used for wood powder 2 that is a constituent of mixed composition 3 together with olefin resin 1, and 1.0 to 10 wt% is used for mixed composition 3. As shown in FIG. 4B, the mixture composition 3 containing the foaming agent is subjected to extrusion molding with an extrusion mold 7a to obtain an intermediate molded product 5, and this intermediate molded product. 5 is sized with a sizing die 8a to obtain a wood powder resin foam extrusion 6a obtained by foaming a foaming agent. That is, in this patent document 1, by mixing 1.0 to 10% by weight of a foaming agent and wood powder 2 having a powder diameter of 150 μm or less into the mixed composition 3, as shown in FIG. The foamed foam 4 is obtained by confining the foamed bubbles 4 inside the intermediate molded product 5 and efficiently incorporating the bubbles 4 therein. FIG. 4C shows the state of the mixed composition and each molded product corresponding to FIG. As described above, in Patent Document 1, the final product is a wood powder resin foam extruded product 6a in which bubbles 4 due to foaming of a foaming agent are contained, and has high strength and high hardness and is caster resistant. It is not possible to obtain the wood powder resin extruded product 6 having improved properties.

In addition, when trying to manufacture a wood powder resin extruded product 6 having high strength and high hardness and improved caster resistance using the olefin resin 1, the sizing mold 8a of the olefin resin 1 is used. Therefore, the stability of the dimensional accuracy of the obtained wood powder resin extruded product 6 cannot be ensured, and the productivity cannot be increased. That is, at present, when the wood powder resin extruded product 6 having high strength and high hardness and improved caster resistance is manufactured using the olefin resin 1, the resulting wood powder resin extrusion is obtained. The molded product 6 cannot be provided with high dimensional accuracy.
JP 2001-192489 A

The present invention has been invented in view of the above-described conventional problems, and is used as a material for producing an extruded product of wood powder resin having high strength and high hardness and improved caster resistance. It is an object of the present invention to provide a method for producing a wood powder resin extruded product that enables production of a wood powder resin extruded product with high dimensional accuracy and high productivity even when used in the above.

  In order to solve the above-mentioned problems, a method for producing an extruded product of wood flour resin according to claim 1 of the present invention comprises 50 to 45% by weight of olefin resin 1 and 50 to 40 wood flour 2 having an average particle size of 20 to 80 mesh. 80% by weight, 0.1 to 1.0% of the foaming agent in the mixed composition 3 in which the compatibilizer for adhering the wood powder 2 and the olefinic resin 1 and the additive having the effect of improving the melt tension are mixed. The intermediate composition 5 is formed by extruding the mixed composition 3 containing the foaming agent and the foaming agent composition, and then sizing the intermediate composition 5 to form the wood resin extruded product 6. It is characterized by having obtained.

  According to this, since wood powder 2 having an average particle diameter of 20 to 80 mesh was used for wood powder 2 constituting mixed composition 3 together with olefin resin 1, the mixture composition 3 had a space between wood powder 2. In this state, a relatively large gap S can be formed, and 0.1 to 1.0% by weight of a foaming agent is blended with the mixed composition 3, whereby the mixed composition 3 containing the foaming agent is blended. In the intermediate molded product 5 subjected to extrusion molding, an appropriate cushioning property can be provided by foaming of the foaming agent. However, when the intermediate molded product 5 is introduced into the sizing mold 8a, this intermediate molded product 5 is provided. Because of the above-mentioned cushioning properties, the wood powder resin extruded product 6 having high dimensional accuracy can be obtained because it is adapted to be intimately adhered to the inner surface of the sizing die 8a, and at the same time, this sizing can be obtained. To the mold 8a Due to the pressure applied to the intermediate molded product 5 when the inter-molded product 5 is introduced, the bubbles 4 due to foaming of the foaming agent are released from between the wood powder 2 in which a relatively large gap S is formed to the outside of the intermediate molded product 5 As a result, it is possible to obtain a wood powder resin extruded product 6 having high strength, high hardness and improved caster resistance, which hardly leaves bubbles 4 in the end. Thus, even if it uses the olefin resin 1 as a material, it is possible to obtain a wood powder resin extruded product 6 with high dimensional accuracy, high strength and high hardness, and improved caster resistance. It can be done.

  In addition, the method for producing an extruded product of wood powder resin according to claim 2 is characterized in that, in claim 1, the shape of the intermediate molded product 5 is a hollow shape. According to this, since the surface area of the intermediate molded product 5 can be increased, the bubbles 4 can be easily released by the foaming agent, and the wood powder resin extruded product 6 in which the remaining bubbles 4 are further eliminated can be obtained. is there.

  Even if the present invention uses an olefin resin as a material, a wood powder resin extruded product having high strength and high hardness and improved caster resistance can be obtained with high dimensional accuracy and high productivity. It has the effect that it can be obtained.

  An example of an embodiment of the present invention is a manufacturing method for obtaining a wood powder resin extruded product 6 having high dimensional accuracy, high strength and high hardness, and improved caster resistance under high productivity. The wood powder resin extruded product 6 is characterized in that an appropriate amount of a foaming agent that functions only during the production process is blended, and that wood powder 2 having a defined average particle size is used. This will be described below.

  The main material of the wood powder resin extruded product 6 of this example is composed of 50 to 80% by weight of wood powder 2 and 15 to 45% by weight of olefin resin 1. Here, the blending ratio of each component is based on the total amount of the mixed composition 3 containing the foaming agent described later. As the olefin resin 1, specifically, polypropylene, polyethylene, or a mixture thereof is generally used, but is not particularly limited. The wood powder 2 is made of wood as a starting material, such as virgin chips obtained by crushing unused wood, MDF powder obtained by crushing waste MDF, and particle powder obtained by crushing waste particle board. However, as the wood flour 2 of this example, one having an average particle diameter of 20 to 80 mesh (particle diameter of 850 to 190 μm) is used. In addition, in the mixing ratio of the wood powder 2 and the olefin resin 1, when the wood powder 2 is too much compared to the olefin resin 1, the surface of the mixed composition 3 is dry and the intermediate molding is performed. If the surface of the product 5 is rough and good surface smoothness of the wood powder resin extruded product 6 cannot be obtained, and if the wood powder 2 is too small compared to the olefin resin 1, the intermediate molded product 5 after the extrusion molding is retained. There is a situation that the shape becomes difficult, and the above-described mixing ratio is suitable for ensuring good productivity and finishing of the wood powder resin extruded product 6.

  The 50 to 80 wt% wood powder 2 and 15 to 45 wt% olefin resin 1 are melt kneaded using a kneader to obtain a mixed composition 3. A compatibilizer for bringing the powder 2 and the olefin resin 1 into close contact with each other and an additive for improving the melt tension are blended simultaneously. Here, as a compatibilizing agent, for example, an agent obtained by modifying a generally widespread polypropylene with maleic acid is used, and as an additive for improving melt tension, natural rubber or ethylene propylene rubber (EPDM) is used. Or a rubber system such as ethylene vinyl acetate copolymer, or a thickener system such as polymer acrylic or acrylic modified polytetrafluoroethylene. In the mixed composition 3 obtained in this way, the wood powder 2 to be formed has an average particle size of 20 to 80 mesh, so that the wood powder 2 is between the wood powders 2 as shown in FIG. Is a state in which a relatively large gap S is generated.

  As shown in FIG. 1 (a), the mixed composition 3 is subjected to extrusion molding by an extruder 7, and this mixed composition 3 is introduced immediately before the mixed composition 3 is introduced into the extruder 7. Is blended with a foaming agent. As the foaming agent, an organic foaming agent used for ordinary resin extrusion molding, for example, an azo compound or a sulfonyl hydrazide compound is used, and its blending amount is 0.1 to 1.0% by weight. Is done.

  The intermediate molded product 5 obtained by extruding the mixed composition 3 containing the foaming agent is taken out from the die of the extruder 7 and taken up by a take-up machine 12 disposed at the end of the manufacturing process. In the intermediate molded product 5, a sufficiently small amount of foaming agent is foamed compared to the wood powder 2 and the olefin-based resin 1, so that the intermediate molded product 5 expands somewhat more than the cross-sectional shape of the extrusion mold 7 a and is moderate. Cushioning is provided. The intermediate molded product 5 in a state where the foaming agent is foamed is then subjected to sizing for forming into a predetermined shape. The sizing device 8 for sizing the intermediate molded product 5 has a sizing die 8a having substantially the same shape as the cross-sectional shape of the extrusion molding die 7a as shown in FIG. ), A cooling portion 8b for accommodating a cooling medium such as water is disposed around the sizing die 8a. That is, in this example, the intermediate molded product 5 is sized together with cooling.

  Here, when the intermediate molded product 5 is introduced into the sizing mold 8a, the intermediate molded product 5 spreads all over the inside of the sizing mold 8a due to the cushioning property provided in the intermediate molded product 5 by foaming of the foaming agent. That is, the intermediate molded product 5 is adapted to the sizing mold 8a, and the wood powder resin extruded product 6 with high dimensional accuracy can be obtained. In the take-up machine 12 arranged at the end of the process of this example, the surface decorative sheet 13 is pressure-bonded to the wood powder resin extruded product 6 using the roller 12a provided in the take-up machine 12 as shown in FIG. The wood powder resin extruded product 6 is finished.

  By the way, if the bubbles 4 formed by foaming the foaming agent in the intermediate molded product 5 remain in the wood powder resin extruded product 6 as they are, a so-called wood powder resin foam extruded product 6a is obtained, which has a high strength. Moreover, it is not possible to obtain a wood powder resin extruded product 6 having high hardness and improved caster resistance. However, in this example, in order to obtain the wood powder resin extruded product 6 having high strength and high hardness and improved caster resistance, the removal of the bubbles 4 by foaming of the foaming agent particularly adds any manufacturing process. It is planned soon. In other words, in this example, wood powder 2 having an average particle diameter of 20 to 80 mesh (particle diameter of 850 to 190 μm) is used, so a large gap S is formed between wood powder 2 contained in intermediate molded product 5. It has been made possible. In other words, when the intermediate molded product 5 is introduced into the sizing mold 8a by pressurization to the intermediate molded product 5, the bubbles 4 caused by foaming of the foaming agent existing in the intermediate molded product 5 are formed in the gaps between the wood powders 2. It is discharged to the outside of the intermediate molded product 5 through S (see the dotted arrow in FIG. 1 (c)). Finally, it has a high strength and a high hardness that hardly causes bubbles 4 to remain. The wood powder resin extruded product 6 with improved castability can be obtained.

  Furthermore, in this example, as shown in FIG. 1B, the intermediate molded product 5 after extrusion is provided with a hollow portion 9. That is, the surface area of the intermediate molded product 5 is increased by the hollow portion 9, and it is easy for the bubbles 4 to be released from the intermediate molded product 5 by foaming of the foaming agent. Further reduction of the residual bubbles 4 in the resin extrusion 6 is achieved.

  Further, the intermediate molded product after the pressure in the extrusion mold 7a (internal pressure) and the extrusion molding are applied when the mixed composition 3 containing the foaming agent is extruded and exits the extrusion mold 7a. It is also preferable in order to suppress the degree of foaming to make the pressure difference with respect to the pressure applied to 5 (external pressure) as small as possible. Further, for example, as shown in FIG. 2, the length of the die of the extruder 7 (die land 7b) is formed long, and the foaming agent is foamed in a state where the intermediate molded product 5 is positioned inside the die. However, according to this, foaming of the foaming agent can be performed while maintaining the shape of the intermediate molded product 5, which can contribute to improving the dimensional accuracy of the wood powder resin extruded product 6. In order to stabilize foaming of the foaming agent and improve the surface smoothness of the wood powder resin extruded product 6, it is also preferable to provide a vent in the extruder 7. Moreover, in order to raise the surface smoothness and production speed of the wood-powder resin extrusion molded article 6, and to improve productivity, it is also preferable to mix | blend a lubricant. Moreover, it is preferable to replace a part of the wood powder 2 with another filler (for example, an inorganic filler such as mica or wollastonite), to color the pigment with a pigment, or to not attach the surface decorative sheet 13, According to this, various external appearances can be obtained in the wood powder resin extruded product 6.

  In the wood powder resin extruded product 6 obtained as described above, which has good dimensional accuracy, high productivity, high strength and high hardness, and has caster resistance, the floor, the wall, and the artificial member It can be used not only for building interior materials such as counters and doors, but also for building exterior materials such as siding, fence components, and wood decks.

Next, the present invention will be specifically described with reference to examples.
[Example 1]
As the olefin resin 1, polypropylene having an MFR (melt flow rate) value of 40 to 50 g / 10 min is used. As the wood powder 2, virgin wood powder 2 having an average particle size of 45 mesh is used. As the compatibilizing agent, maleic acid-modified polypropylene is used. As the additive for improving the melt tension, acrylic-modified polytetrafluoroethylene was used, and azodicarbonamide was used as the foaming agent. Then, 30 wt% of the olefin resin 1, 65 wt% of the wood flour 2, 3 wt% of the compatibilizer and 1.5 wt% of the additive were kneaded with a kneader to obtain a mixed composition 3. Obtained. In addition, 0.5% by weight of a foaming agent was added to the mixed composition 3 immediately before being introduced into the extruder 7. As the extruder 7, a conical twin screw extruder was used. Extrusion molding performed by the extrusion molding machine 7 was performed at a temperature of the extrusion mold 7a of 190 to 210 ° C. and a pressure of the extrusion mold 7a of 15 MPa. The mixed composition 3 containing the foaming agent was subjected to extrusion molding to form an intermediate molded product 5. The intermediate molded product 5 was sized and molded to obtain a wood powder resin extruded product 6. In addition, as the shape of the intermediate molded product 5 and the wood powder resin extrusion molded product 6, as shown in FIG. 3A, a long solid plate material 10 having a vertical width of 30 mm and a horizontal width of 150 mm is rectangular.
[Example 2]
A wood powder resin extruded product 6 was produced basically in the same manner as in [Example 1] above. In addition, as the shape of the intermediate molded product 5 formed by subjecting the mixed composition 3 containing the foaming agent to extrusion molding and the wood powder resin extruded product 6 formed by sizing the intermediate molded product 5, FIG. As shown in b), a long hollow plate 11 having a rectangular shape with a vertical width of 30 mm and a horizontal width of 150 mm and having a hollow portion 9 formed inside to leave a thickness of 3 mm from each of the upper, lower, left and right outer surfaces. . That is, Example 1 is manufactured by making the shapes of the intermediate molded product 5 and the wood powder resin extruded product 6 different.
[Comparative Example 1]
After obtaining the same mixed composition 3 as in the above [Example 1], the mixed composition 3 was subjected to extrusion molding and sizing in the same manner as in the above [Example 1] without blending the foaming agent. A powder resin extruded product 6 was obtained.
[Comparative Example 2]
After obtaining the same mixed composition 3 as in the above [Example 1], 2% by weight of a foaming agent was added to the mixed composition 3, and the above-mentioned [Example 1] was added to the mixed composition 3 containing this foaming agent. ] Extrusion molding and sizing were performed in the same manner as in the above to obtain a wood powder resin extruded product 6.
[Comparative Example 3]
Wood powder 2 having an average particle diameter of 90 to 110 mesh is kneaded with the same olefin resin 1 and various additives as in [Example 1] to obtain a mixed composition 3. In the same manner, a foaming agent was blended, and extrusion molding and sizing were performed in this order to obtain a wood powder resin extruded product 6.

  Table 1 below summarizes various evaluations relating to each of the wood powder resin extrusion-molded articles 6 of the above Examples and Comparative Examples.

  According to this table, in each example, the dimensional error of the wood powder resin extruded product 6 is also suppressed satisfactorily, and the pulling-out speed of the drawing machine has been confirmed to be stable production for 10 minutes or more. The stable take-up speed is relatively fast and good productivity is obtained, and as shown in FIG. 1 (b), although some bubbles 4 remain in the wood powder resin extruded product 6, it is obtained. Further, it was found that the specific gravity of each wood powder resin extruded product 6 can be made substantially equal to that of the wood powder resin extruded product 6 of Comparative Example 1 without a foaming agent, and the appearance evaluation and caster resistance performance are also good.

  Specifically, when each example and Comparative Example 1 are compared, it can be seen that the dimensional accuracy of the wood powder resin extruded product 6 varies depending on the presence or absence of the blending of the foaming agent. That is, unless a foaming agent is blended in the mixed composition 3, good molding cannot be performed by sizing, and the wood powder resin extruded product 6 with high dimensional accuracy cannot be obtained. Furthermore, in the wood powder resin extruded product 6 of Comparative Example 1, sink marks and dents were generated on the outer surface, and a good appearance could not be provided.

  Moreover, when each Example and the comparative example 2 are compared, it turns out that the specific gravity of the stable drawing speed | rate and the wood powder resin extrusion molded product 6 changes with the difference in the compounding quantity of a foaming agent. The reduction in specific gravity of the wood powder resin extruded product 6 indicates that bubbles 4 remain inside the wood powder resin extruded product 6. In other words, the final molded product of Comparative Example 2 has a lighter specific gravity than Comparative Example 1 in which no foaming agent is blended. Therefore, a large amount of bubbles 4 remain due to foaming of the foaming agent, and the caster performance is also good. It becomes the wood powder resin foam extrusion molding 6a which does not carry out. In addition, if the foaming agent is added too much to the mixed composition 3 as in Comparative Example 2, the intermediate molded product 5 expands due to foaming of the foaming agent, and the melt tension decreases, so that the intermediate molded product 5 is within the sizing. It is easy to tear, and as a result, the production speed cannot be increased. Furthermore, in the wood-resin extruded product 6 of Comparative Example 2, the bubbles 4 appeared on the outer surface, the outer surface was rough, and a good appearance could not be provided.

  Moreover, when each Example and Comparative Example 3 are compared, due to the difference in the average particle diameter of the wood powder 2 to be used, the specific gravity of the wood powder resin extruded product 6, that is, the foaming agent remaining in the wood powder resin extruded product 6 It can be seen that the amount of bubbles 4 varies. That is, when wood powder 2 having a small average particle diameter is used, bubbles 4 due to foaming of the foaming agent are difficult to escape from intermediate molded product 5 as in Comparative Example 3, and when wood powder 2 having a large average particle diameter is used, each of the examples. Thus, it can be seen that the bubbles 4 due to foaming of the foaming agent are easily removed from the intermediate molded product 5. Comparative Example 3 in which the bubbles 4 are difficult to escape from the intermediate molded product 5 is the wood powder resin foam extrusion molded product 6a as the final molded product as in Comparative Example 2, and even when compared with each Example, Both productivity and appearance are inferior.

  Moreover, when Example 1 and Example 2 are compared, it turns out that the dimensional error of the wood powder resin extrusion molded product 6 changes with the difference in the shape of the wood powder resin extrusion molded product 6 to form. That is, when the hollow portion 9 is provided in the wood powder resin extruded product 6 to increase the surface area, the bubbles 4 are released from the intermediate molded product 5 also from the hollow portion 9, and the dimensional accuracy is improved. It is.

It is explanatory drawing explaining the example of embodiment of this invention, (a) is explanatory drawing explaining the flow of a manufacturing process, (b) is a longitudinal cross-sectional view in each part of a manufacturing process, (c) These are the enlarged views of the molded product in each part of a manufacturing process. It is explanatory drawing explaining the flow of the manufacturing process of the other example same as the above. (A) (b) is a longitudinal cross-sectional view of an intermediate molded product. It is explanatory drawing explaining the example of background art, (a) is explanatory drawing explaining the flow of a manufacturing process, (b) is a longitudinal cross-sectional view in each part of a manufacturing process, (c) is a manufacturing process. It is an enlarged view of the molded product in each part.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Olefin resin 2 Wood powder 3 Mixture composition 4 Bubble 5 Intermediate molding 6 Wood powder resin extrusion molding 7 Extruder 7a Extrusion mold 7b Dieland 8 Sizing device 8a Sizing mold 8b Cooling part 9 Hollow part S Crevice

Claims (2)

  15 to 45% by weight of olefin-based resin, 50 to 80% by weight of wood flour having an average particle size of 20 to 80 mesh, a compatibilizing agent for closely adhering the wood flour and olefin-based resin, and having an effect of improving melt tension A foaming agent is blended in an amount of 0.1 to 1.0% by weight to the mixed composition containing the additive, and the intermediate composition is formed by extruding the mixed composition containing the foaming agent. A method for producing a wood powder resin extruded product, wherein the wood powder resin extruded product is obtained by sizing and molding.   The method for producing an extruded product of wood flour resin according to claim 1, wherein the intermediate molded product has a hollow shape.

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