JP2006007223A - Dipped type membrane cartridge - Google Patents

Dipped type membrane cartridge Download PDF

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Publication number
JP2006007223A
JP2006007223A JP2005276958A JP2005276958A JP2006007223A JP 2006007223 A JP2006007223 A JP 2006007223A JP 2005276958 A JP2005276958 A JP 2005276958A JP 2005276958 A JP2005276958 A JP 2005276958A JP 2006007223 A JP2006007223 A JP 2006007223A
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membrane
filter plate
filtration membrane
filtration
filter
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Masaaki Nagano
昌章 永野
Yasunobu Okajima
康信 岡島
Yutaka Yamada
山田  豊
Seiji Izumi
清司 和泉
Tatsuya Uejima
達也 上島
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Kubota Corp
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Kubota Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a dipped type membrane cartridge with enhanced durability against aeration. <P>SOLUTION: This dipped type membrane cartridge has a resin filter plate 41 and a filter membrane 44 disposed by covering a surface of the filter plate 41 and a fixed part formed by welding the filter membrane 44 to a welding margin formed along the filter plate 41. The filter membrane 44 is formed by forming an organic membrane 44b on front and rear sides of a nonwoven fabric membrane support material 44a, and a welding layer F is formed so as to reach the front layer of the welding face side of the membrane support 44a at the fixed part. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、浸漬型膜カートリッジに関し、生活排水処理や産業排水処理等において使用する固液分離装置に搭載する膜カートリッジの技術に係るものである。   The present invention relates to a submerged membrane cartridge and relates to the technology of a membrane cartridge mounted on a solid-liquid separation device used in domestic wastewater treatment, industrial wastewater treatment, or the like.

従来の固液分離装置としては、例えば図15に示すような浸漬型膜分離装置がある。図15において、膜分離装置21は、複数枚の平板状膜カートリッジ22と、その下方より膜面洗浄気体を噴出する散気装置23とをケース24の内部に配置したものである。ケース24は膜ケース25と散気ケース26とに分割形成し、散気装置23より噴出する膜面洗浄気体の全量が膜ケース25内に入り込むように形成している。   As a conventional solid-liquid separator, for example, there is a submerged membrane separator as shown in FIG. In FIG. 15, the membrane separation device 21 is configured by arranging a plurality of flat plate membrane cartridges 22 and an air diffuser 23 for jetting membrane surface cleaning gas from below the case 24. The case 24 is divided into a membrane case 25 and an air diffuser case 26, and is formed so that the entire amount of the film surface cleaning gas ejected from the air diffuser 23 enters the film case 25.

膜カートリッジ22は、ABS樹脂製のろ板22Aの両表面にろ過膜22Bを配置し、ろ過膜22Bをその周縁部の止水部Sにおいてろ板22Aに超音波溶着(溶接)によって融着したものである。ろ板22Aとろ過膜22Bとの間、およびろ板22Aの内部には透過液流路を形成し、透過液流路に連通する透過液取出口22Cをろ板22Aの上端縁に形成している。   The membrane cartridge 22 has filtration membranes 22B disposed on both surfaces of a filter plate 22A made of ABS resin, and the filtration membrane 22B is fused to the filter plate 22A by ultrasonic welding (welding) at the water stop portion S at the peripheral edge thereof. Is. A permeate channel is formed between the filter plate 22A and the filter membrane 22B and inside the filter plate 22A, and a permeate outlet 22C communicating with the permeate channel is formed at the upper edge of the filter plate 22A. Yes.

各膜カートリッジ22は、透過液取出口22Cに接続したチューブ27を介して集水管28に連通しており、膜透過液を導出する透過液導出管29を集水管28に接続している。   Each membrane cartridge 22 communicates with a water collection pipe 28 via a tube 27 connected to the permeate outlet 22C, and a permeate discharge pipe 29 for leading the membrane permeate is connected to the water collection pipe 28.

膜分離装置21を活性汚泥処理施設において使用する場合には、曝気槽内部の活性汚泥混合液中に膜分離装置21を浸漬し、散気装置23より曝気空気を噴出させる状態において、原水中の有機物や窒素を活性汚泥により処理している。   When the membrane separation device 21 is used in an activated sludge treatment facility, the membrane separation device 21 is immersed in the activated sludge mixed solution inside the aeration tank, and aeration air is ejected from the aeration device 23 in the raw water. Organic matter and nitrogen are treated with activated sludge.

活性汚泥混合液は、槽内での水頭を駆動圧として膜カートリッジ22により重力ろ過し(透過液導出管29に吸引ポンプを介装することで吸引ろ過も可能である)、膜カートリッジ22の膜面を透過した透過液を処理水として透過液導出管29を通じて槽外へ導出する。   The activated sludge mixed liquid is gravity filtered by the membrane cartridge 22 with the water head in the tank as the driving pressure (the suction filtration is also possible by inserting a suction pump in the permeate outlet pipe 29), and the membrane of the membrane cartridge 22 The permeated liquid that has passed through the surface is led out of the tank through the permeated liquid outlet pipe 29 as treated water.

このとき、散気装置23より噴出する曝気空気の気泡およびそれにより生起される上昇流が、相互に隣接する膜カートリッジ22の間の狭い流路(5〜10mmの幅)を流れることによって、膜カートリッジ22の膜面を洗浄し、分離機能の低下を抑制して膜分離装置21が機能不全に至ることを防止している。   At this time, the bubbles of the aerated air ejected from the diffuser 23 and the upward flow generated thereby flow through the narrow flow path (width of 5 to 10 mm) between the membrane cartridges 22 adjacent to each other. The membrane surface of the cartridge 22 is washed to suppress a decrease in separation function, thereby preventing the membrane separation device 21 from malfunctioning.

このように、膜分離装置21の使用時において、膜カートリッジ22は曝気空気による上昇流に曝されるので、止水部Sに囲まれた領域およびろ過膜22Bの周縁部が振動し、疲労によって止水部Sでろ過膜22Bが破断する恐れがある。
このために、図16に示すように、ろ過膜22Bの周縁部に沿って断続的に形成する周縁固定部Bにおいて、ろ過膜22Bをろ板22Aに補助的に固定するものがある。
特開平7−24270号公報
As described above, when the membrane separation device 21 is used, the membrane cartridge 22 is exposed to the upward flow caused by the aeration air, so that the region surrounded by the water-stopping portion S and the peripheral portion of the filtration membrane 22B vibrate, resulting in fatigue. There is a possibility that the filtration membrane 22B breaks at the water stop portion S.
For this reason, as shown in FIG. 16, in the peripheral fixing part B formed intermittently along the peripheral part of the filtration membrane 22B, there is one that auxiliaryly fixes the filtration membrane 22B to the filter plate 22A.
Japanese Patent Laid-Open No. 7-24270

超音波溶着(溶接)法の一例としては、ロータリ溶着(溶接)法がある。これは図17に示すように、ろ板22Aの表面を覆ってろ過膜22Bを配置し、ロータリホーン31によってろ過膜22Bをろ板22Aに押圧しながらロータリホーン31を回転させ、ロータリホーン31から出力する超音波によってろ過膜22Bおよびろ板22Aを融着して止水部Sおよび補助固定部Bを形成するものである。   An example of the ultrasonic welding (welding) method is a rotary welding (welding) method. As shown in FIG. 17, the filter membrane 22B is disposed so as to cover the surface of the filter plate 22A, and the rotary horn 31 is rotated while pressing the filter membrane 22B against the filter plate 22A by the rotary horn 31. The filter membrane 22B and the filter plate 22A are fused by the output ultrasonic wave to form the water stop portion S and the auxiliary fixing portion B.

しかし、ロータリ溶着(溶接)法では、図18に示すように、止水部Sにおいてろ板22Aが溶けて溝状に窪み、ろ過膜22Bがろ板22Aに食い込む状態に融着されるために、溶着(溶接)時にろ過膜22Bが痛み、疲労破壊が起こり易くなる。   However, in the rotary welding (welding) method, as shown in FIG. 18, the filter plate 22A melts in the water-stopping portion S and is recessed into a groove shape, and the filtration membrane 22B is fused in a state of biting into the filter plate 22A. The filtration membrane 22B is painful during welding (welding), and fatigue failure tends to occur.

超音波溶着(溶接)法の他の例としてはアップダウン法がある。これは図19〜図21に示すように、予めろ板22Aの表面に、止水部Sを形成するための線状の溶融代32および帯状の補助溶融代33を表面から突出して形成しておき、溶融代32および補助溶融代33を覆ってろ過膜22Bを配置し、アップダウンホーン34をろ過膜22Bの上から溶融代32および補助溶融代33に押圧するものである。   Another example of the ultrasonic welding (welding) method is an up-down method. As shown in FIGS. 19 to 21, a linear melting allowance 32 and a belt-like auxiliary melting allowance 33 for forming the water stop portion S are previously formed on the surface of the filter plate 22A so as to protrude from the surface. In addition, the filtration membrane 22B is disposed so as to cover the melting allowance 32 and the auxiliary melting allowance 33, and the up / down horn 34 is pressed onto the melting allowance 32 and the auxiliary melting allowance 33 from above the filtration membrane 22B.

アップダウンホーン34は、ろ過膜22Bに相対する下面に模様部(ローレット)34aを有し、模様部34aは高さ0.3mmの正四角錐を0.6mmのピッチで配した形状を有している。   The up / down horn 34 has a pattern portion (knurl) 34a on the lower surface facing the filtration membrane 22B, and the pattern portion 34a has a shape in which regular square pyramids having a height of 0.3 mm are arranged at a pitch of 0.6 mm. Yes.

このアップダウンホーン34から出力する超音波振動により、ろ過膜22Bを溶融代32および補助溶融代33においてろ板22Aに融着して直線状の止水部Sおよび補助固定部Bを形成するものである。   By the ultrasonic vibration output from the up / down horn 34, the filtration membrane 22B is fused to the filter plate 22A at the melting allowance 32 and the auxiliary melting allowance 33 to form the linear water stop portion S and the auxiliary fixing portion B. It is.

ところで、ろ過膜22Bは基材をなす不織布の表裏に有機材によって膜を形成したものであり、不織布によって機械的強度を確保している。このため、上記した手法においては、アップダウンホーン34の模様部34aに対応する部位においてろ過膜22Bが局所的に押圧され、その部位において過剰なエネルギーの集中によって不織布の繊維が破断されやすく、機械的強度が損なわれることになる。   By the way, the filtration membrane 22B is formed by forming a membrane with an organic material on the front and back of the nonwoven fabric forming the base material, and the mechanical strength is ensured by the nonwoven fabric. For this reason, in the above-described method, the filtration membrane 22B is locally pressed at the site corresponding to the pattern portion 34a of the up / down horn 34, and the nonwoven fabric fibers are easily broken due to excessive energy concentration at the site. The mechanical strength is impaired.

本発明は上記した課題を解決するものであり、曝気に対する耐久性を高めた浸漬型膜カートリッジを提供することを目的とする。   The present invention solves the above-described problems, and an object of the present invention is to provide an immersion type membrane cartridge with improved durability against aeration.

上記課題を解決するために、本発明の浸漬型膜カートリッジは、樹脂製のろ板とろ板の表面を覆って配置したろ過膜とを有し、ろ板に沿って成形した溶融代においてろ過膜を融着してなる固定部を形成し、ろ過膜が不織布からなる膜支持材の表裏に有機質の膜を形成してなり、前記固定部において膜支持材の溶着面側の表層に達する融着層を形成したことを特徴とする。   In order to solve the above-mentioned problems, the immersion membrane cartridge of the present invention has a filter plate made of resin and a filter membrane arranged so as to cover the surface of the filter plate, and in the melting allowance formed along the filter plate, the filter membrane A fusion part is formed by forming an organic film on the front and back of the membrane support material made of nonwoven fabric, and the fusion membrane reaches the surface layer on the welding surface side of the membrane support material. A layer is formed.

上記した構成において、浸漬型膜カートリッジは反応槽に浸漬し、下方より曝気する状態で使用する。この状態で、曝気に由来する気液固混相の上向流が膜面に沿って流れるので、浸漬型膜カートリッジに気液固混相流に由来する振動が作用する。また、反応槽における浸漬型膜カートリッジの使用環境は、反応槽の形状、反応槽に貯留する被処理液の性状、季節的な変動要因等によって変化し、使用環境の変化によって浸漬型膜カートリッジには不測の外力が作用することがある。   In the above-described configuration, the immersion type membrane cartridge is used in a state where it is immersed in a reaction vessel and aerated from below. In this state, since the upward flow of the gas-liquid / solid mixed phase derived from aeration flows along the film surface, the vibration derived from the gas / liquid / solid mixed phase flow acts on the submerged membrane cartridge. In addition, the usage environment of the immersion membrane cartridge in the reaction tank changes depending on the shape of the reaction tank, the properties of the liquid to be treated stored in the reaction tank, seasonal fluctuation factors, etc. Unexpected external force may be applied.

本発明においては、固定部において膜支持材の溶着面側の表層に達する融着層を形成することにより、不測の外力および振動疲労によりろ過膜が固定部で剥離する場合にあっても、ろ過膜は膜支持材の破断を伴うことなく固定部から剥離するので、その修復を容易に行うことができ、膜カートリッジの延命化が図れる。   In the present invention, by forming a fusion layer that reaches the surface layer on the welding surface side of the membrane support material in the fixing part, even when the filtration membrane peels off at the fixing part due to unexpected external force and vibration fatigue, Since the membrane is peeled off from the fixing portion without causing breakage of the membrane support material, the membrane can be easily repaired and the life of the membrane cartridge can be extended.

しかし、固定部においてろ過膜の膜支持材に深く達する融着層を形成してろ過膜がろ板から剥離しないように強く融着する場合には、融着部位に必要以上の熱エネルギーが発生し、ろ過膜の膜支持材を劣化させることになり、膜カートリッジとしての寿命を低下させ、ろ過膜が固定部において破断する。また、固定部においてろ過膜の膜支持材に浅く達する融着層を形成した場合には、ろ過膜が膜支持材において剥離し、修復することができない。   However, if a fusion layer is formed that reaches the membrane support material of the filtration membrane deeply at the fixed part and the filtration membrane is strongly fused so that it does not peel from the filter plate, more heat energy than necessary is generated at the fusion site. As a result, the membrane support material of the filtration membrane is deteriorated, the life of the membrane cartridge is reduced, and the filtration membrane is broken at the fixed portion. Moreover, when the fusion | melting layer which reaches | attains the membrane support material of a filtration membrane shallowly in a fixed part is formed, a filtration membrane peels in a membrane support material and cannot be repaired.

また、本発明の浸漬型膜カートリッジは、溶融代が、ろ板の表面から突出して、かつろ板の周縁部に沿って成形してなることを特徴とする。
また、本発明の浸漬型膜カートリッジは、固定部が、ろ過膜を全周にわたってろ板に融着してなることを特徴とする。
The immersion membrane cartridge of the present invention is characterized in that the melting allowance projects from the surface of the filter plate and is molded along the peripheral edge of the filter plate.
Moreover, the immersion type membrane cartridge of the present invention is characterized in that the fixing part is formed by fusing the filtration membrane to the filter plate over the entire circumference.

また、本発明の浸漬型膜カートリッジは、固定部が、ろ板の表面から突出し、かつろ板の周縁部に沿って多重に成形した複数の溶融代においてろ過膜を融着してなることを特徴とする。   In the immersion type membrane cartridge of the present invention, the fixed part protrudes from the surface of the filter plate, and the filter membrane is fused at a plurality of melting allowances formed in a multiple manner along the peripheral edge of the filter plate. Features.

また、本発明の浸漬型膜カートリッジは、固定部が、内側の溶融代でろ過膜を緊張状態に保持する内側固定部を形成し、中央の溶融代でろ過膜の全周にわたって止水機能を確保する止水部を形成し、外側の溶融代でろ過膜の周縁をろ板に固定する外側固定部を形成することを特徴とする。   Further, in the immersion type membrane cartridge of the present invention, the fixing portion forms an inner fixing portion that holds the filtration membrane in a tension state at the inner melting allowance, and has a water stop function over the entire circumference of the filtration membrane at the central melting allowance. A water stop portion to be secured is formed, and an outer fixing portion for fixing the periphery of the filtration membrane to the filter plate is formed by an outer melting allowance.

この構成により、通常の使用状態においてろ過膜に作用する外力に対して、ろ過膜を緊張状態に保持する内側固定部、およびろ過膜の周縁をろ板に固定する外側固定部は十分な強度を有しており、外力を内側固定部と外側固定部とで受け止めることによって外力は止水部に及ばず、止水部の損傷を防止できる。   With this configuration, the inner fixing part that holds the filtration membrane in a tension state and the outer fixing part that fixes the periphery of the filtration membrane to the filter plate have sufficient strength against the external force that acts on the filtration membrane in normal use. The external force is received by the inner fixing portion and the outer fixing portion so that the external force does not reach the water stopping portion, and damage to the water stopping portion can be prevented.

このように、内側固定部および外側固定部が外力に対する防護体をなすことにより、振動疲労および不測の外力によってろ過膜が内側固定部または外側固定部で剥離する場合であっても、止水部が同時に剥離することがなく、浸漬型膜カートリッジのろ過能が不測の事態において損なわれることを防止でき、浸漬型膜カートリッジの曝気に対する耐久性が高まる。   In this way, the inner fixing portion and the outer fixing portion protect the external force, so that even if the filtration membrane is peeled off by the inner fixing portion or the outer fixing portion due to vibration fatigue and unexpected external force, the water stopping portion Are not peeled off at the same time, and the filtration performance of the submerged membrane cartridge can be prevented from being damaged in an unexpected situation, and the durability of the submerged membrane cartridge against aeration is increased.

また、内側固定部または外側固定部に剥離が発生した時点で、内側固定部または外側固定部を補修してその防護体としての機能を回復して止水部の剥離を未然に防止し、浸漬型膜カートリッジの延命を図ることができる。   In addition, when peeling occurs at the inner fixing part or the outer fixing part, the inner fixing part or the outer fixing part is repaired to recover its function as a protective body and prevent the water-stopping part from peeling off, The life of the mold membrane cartridge can be extended.

以上のように本発明によれば、固定部においてろ過膜の膜支持材の表層に達する融着層を形成することにより、振動疲労および不測の外力によってろ過膜が固定部で剥離する場合にあっても、ろ過膜は膜支持材の破断を伴うことなく固定部から剥離するので、その修復を容易に行うことができる。内側固定部または外側固定部に剥離が発生した時点で、内側固定部または外側固定部を補修してその防護体としての機能を回復して止水部の剥離を未然に防止し、浸漬型膜カートリッジの延命を図ることができる。内側固定部、止水部、外側固定部においてろ過膜を全周にわたってろ板に融着することにより、止水機能を多重に確保することができる。   As described above, according to the present invention, when the fusion membrane reaching the surface layer of the membrane support material of the filtration membrane is formed in the fixed portion, the filtration membrane peels off at the fixed portion due to vibration fatigue and unexpected external force. However, since the filtration membrane peels off from the fixed portion without causing breakage of the membrane support material, it can be easily repaired. When peeling occurs on the inner fixing part or outer fixing part, the inner fixing part or outer fixing part is repaired to restore its protective function and prevent the water-stopping part from peeling off. The life of the cartridge can be extended. By fusing the filtration membrane to the filter plate over the entire circumference in the inner fixing part, the water stopping part, and the outer fixing part, multiple water stopping functions can be ensured.

以下、本発明の実施の形態を図面に基づいて説明する。本実施の形態における浸漬型膜カートリッジは浸漬型膜分離装置に使用するものであり、浸漬型膜分離装置の基本的な構造は、先に図15において説明したものと同様であるので、同様の部材には同一番号を付して説明を省略する。   Hereinafter, embodiments of the present invention will be described with reference to the drawings. The submerged membrane cartridge in the present embodiment is used for the submerged membrane separator, and the basic structure of the submerged membrane separator is the same as that described above with reference to FIG. The same reference numerals are given to the members and the description is omitted.

以下に、本実施の形態における浸漬型膜カートリッジの製造方法を図1〜図4を参照して説明する。
図2に示すように、浸漬型膜カートリッジ40のろ板41はABS樹脂からなり、例えば横490mm×縦1000mm×厚さ6mmの形状を有しており、内側に位置する線状溶融代42aと中央に位置する線状溶融代42bと外側に位置する所定幅の網目状溶融代43とをろ板41の表裏面から突出して、かつろ板41の周縁部に沿った全周にわたって一体に成形している。
Below, the manufacturing method of the immersion type membrane cartridge in this Embodiment is demonstrated with reference to FIGS.
As shown in FIG. 2, the filter plate 41 of the submerged membrane cartridge 40 is made of ABS resin, and has a shape of, for example, 490 mm in width, 1000 mm in length, and 6 mm in thickness. A linear melt allowance 42b located at the center and a mesh-like melt allowance 43 of a predetermined width located outside are projected from the front and back surfaces of the filter plate 41 and formed integrally over the entire periphery along the peripheral edge of the filter plate 41. is doing.

線状溶融代42a、42bはその高さが0.4〜0.6mmである。網目状溶融代43はろ過膜44の周縁に対応する位置にあり、線状溶融代42a、42bより0.1mm程度低い形状を有しており、3つの折線状の軌跡43a、43b、43cを重ねた形状である。   The linear melting allowances 42a and 42b have a height of 0.4 to 0.6 mm. The mesh melting allowance 43 is located at a position corresponding to the periphery of the filtration membrane 44, has a shape that is lower by about 0.1 mm than the linear melting allowances 42a, 42b, and has three broken line trajectories 43a, 43b, 43c. It is a stacked shape.

図3に示すように、ろ板41の表裏両面に線状溶融代42a、42bおよび網目状溶融代43を覆ってろ過膜44を配置する。ろ過膜44は不織布からなる膜支持材44aの表裏に有機質の膜44bを形成したものである。   As shown in FIG. 3, filtration membranes 44 are arranged on both front and back surfaces of the filter plate 41 so as to cover the linear melting allowances 42 a and 42 b and the mesh melting allowance 43. The filtration membrane 44 is obtained by forming an organic membrane 44b on the front and back of a membrane support material 44a made of a nonwoven fabric.

図4に示すように、ろ過膜44を伴ったろ板41を治具45の上に配置し、ろ過膜44を介してろ板41の下面の網目状溶融代43を治具45で支持する。この状態で、ろ板41の上面に配置したろ過膜44の上からアップダウンホーン46を線状溶融代42a、42bおよび網目状溶融代43に押圧する。   As shown in FIG. 4, the filter plate 41 with the filtration membrane 44 is disposed on the jig 45, and the mesh melting allowance 43 on the lower surface of the filter plate 41 is supported by the jig 45 through the filtration membrane 44. In this state, the up / down horn 46 is pressed against the linear melting allowances 42 a and 42 b and the mesh melting allowance 43 from above the filter membrane 44 disposed on the upper surface of the filter plate 41.

アップダウンホーン46は超音波振動するもので、ろ過膜44に対向する下面が平坦面をなしている。
アップダウンホーン46から超音波を出力してろ過膜44を線状溶融代42a、42bおよび網目状溶融代43において融着する。このとき、網目状溶融代43が線状溶融代42a、42bよりも低いので、ろ板41の上面側においては、ろ過膜44がアップダウンホーン46と線状溶融代42a、42bとに挟持されて、網目状溶融代43と接触しない。このため、線状溶融代42a、42bにおいてはろ過膜44とろ板41の融着が起こり、十分強度の溶着(溶接)を施すとともに、網目状溶融代43においては高さ寸法の誤差に起因する高い部位でのみ融着が起こる。一方、ろ板41の下面側においては、ろ過膜44が治具45と網目状溶融代43とに挟持されているので、網目状溶融代43においてのみろ過膜44とろ板41の融着が起こり、十分な強度の溶着(溶接)を施すことができる。この融着の完了後に、ろ過膜44を伴ったろ板41を反転させて治具45の上に再度配置し、同様の手順で再度融着を行う。
The up / down horn 46 vibrates ultrasonically, and the lower surface facing the filtration membrane 44 is a flat surface.
An ultrasonic wave is output from the up / down horn 46 and the filtration membrane 44 is fused at the linear melting allowances 42 a and 42 b and the mesh melting allowance 43. At this time, since the mesh melting allowance 43 is lower than the linear melting allowances 42a and 42b, the filtration membrane 44 is sandwiched between the up / down horn 46 and the linear melting allowances 42a and 42b on the upper surface side of the filter plate 41. Thus, it does not come into contact with the mesh melting allowance 43. Therefore, the filtration membrane 44 and the filter plate 41 are fused in the linear melting allowances 42a and 42b, and a sufficiently strong weld (welding) is performed. In the mesh melting allowance 43, an error in the height dimension is caused. Fusion occurs only at high sites. On the other hand, since the filtration membrane 44 is sandwiched between the jig 45 and the mesh melting allowance 43 on the lower surface side of the filter plate 41, the filtration membrane 44 and the filter plate 41 are fused only at the mesh melting allowance 43. It is possible to perform welding (welding) with sufficient strength. After completion of this fusion, the filter plate 41 with the filtration membrane 44 is reversed and placed again on the jig 45, and the fusion is performed again in the same procedure.

この融着操作においては、図12に示すように、内側固定部A、止水部S、外側固定部Cに膜支持材44aの溶着面側の表層に達する融着層Fを形成する。このため、アップダウンホーン46の押圧力(0.2〜0.6MPa)、振幅(30〜60μm)、発振時間(0.1〜0.5秒)を設定する。   In this fusion operation, as shown in FIG. 12, a fusion layer F reaching the surface layer on the welding surface side of the membrane support material 44a is formed in the inner fixing portion A, the water stop portion S, and the outer fixing portion C. For this reason, the pressing force (0.2 to 0.6 MPa), amplitude (30 to 60 μm), and oscillation time (0.1 to 0.5 seconds) of the up / down horn 46 are set.

このように、平坦面のアップダウンホーン46を使用し、ろ板41の表面から突出した線状溶融代42a、42bと網目状溶融代43でろ過膜44を融着して内側固定部A、止水部S、外側固定部Cを形成することにより、過剰なエネルギーの集中によってろ過膜44が劣化することを防止できるとともに、従来のようなローレット傷の発生を防止できる。   In this way, using the flat up / down horn 46, the inner fixed portion A is obtained by fusing the filtration membrane 44 with the linear melting allowances 42 a and 42 b and the mesh melting allowance 43 protruding from the surface of the filter plate 41. By forming the water stop portion S and the outer fixing portion C, it is possible to prevent the filtration membrane 44 from being deteriorated due to excessive energy concentration, and to prevent the occurrence of knurled scratches as in the conventional case.

ところで、幅の広い網目状溶融代43は高さが不揃いとなり易く、線状溶融代42a、42bと網目状溶融代43を同時にアップダウンホーン46の平坦面で押圧すると、網目状溶融代43における外側固定部Cの融着層Fが不足して不連続となるか、線状溶融代42a、42bにおける内側固定部Aおよび止水部Sの融着層Fが過剰となり、内側固定部A、止水部S、外側固定部Cに同時に適切な融着層Fを形成することが困難である。   By the way, the wide network melting allowance 43 tends to be uneven in height, and when the linear melting allowances 42a and 42b and the mesh melting allowance 43 are simultaneously pressed by the flat surface of the up / down horn 46, the mesh melting allowance 43 The fusion layer F of the outer fixing part C becomes insufficient and becomes discontinuous, or the inner fixing part A and the fusion layer F of the water stop part S in the linear fusion allowances 42a and 42b become excessive, and the inner fixing part A, It is difficult to simultaneously form an appropriate fusion layer F on the water stop portion S and the outer fixing portion C.

しかし、線状溶融代42a、42bと網目状溶融代43の高さを違え、ろ板41の表裏において別途に融着操作することによって、各溶融代の特性に応じた溶融操作を行って内側固定部A、止水部S、外側固定部Cに適切な融着層Fを形成することができる。   However, the heights of the linear melting allowances 42a and 42b and the mesh melting allowance 43 are different from each other, and by separately fusing on the front and back of the filter plate 41, the melting operation according to the characteristics of each melting allowance is performed. An appropriate fusion layer F can be formed on the fixing portion A, the water stopping portion S, and the outer fixing portion C.

上述の融着操作により、図1に示すように、内側の線状溶融代42aにおいて直線状の内側固定部Aが形成され、中央の線状溶融代42bにおいて止水部Sが形成されるとともに、融着後の内側固定部Aおよび止水部Sに囲まれたろ過膜44の有効ろ過領域が緊張状態に保持される。   As shown in FIG. 1, a linear inner fixing portion A is formed in the inner linear melting allowance 42 a and a water stop portion S is formed in the central linear melting allowance 42 b by the above-described fusion operation. The effective filtration region of the filtration membrane 44 surrounded by the inner fixing part A and the water stop part S after the fusion is kept in a tension state.

網目状溶融代43に形成する外側固定部Cは、ろ過膜44の周縁をろ板41に断続的に固定する。内側固定部A、止水部S、外側固定部Cは、その軌跡がろ過膜44の全周にわたって連続する形状となり、ろ過膜44を全周にわたってろ板41に融着し、止水機能を発揮する。特に外側固定部Cは3つの軌跡43a、43b、43cによって、多重にシールされる。尚、外側固定部Cは必ずしも止水機能を有する必要はなく、その軌跡を不連続なものに形成することも可能である。   The outer fixing portion C formed in the mesh melting allowance 43 intermittently fixes the periphery of the filtration membrane 44 to the filter plate 41. The inner fixing portion A, the water stopping portion S, and the outer fixing portion C have a shape in which the trajectory is continuous over the entire circumference of the filtration membrane 44, and the filtration membrane 44 is fused to the filter plate 41 over the entire circumference, thereby providing a water stopping function. Demonstrate. In particular, the outer fixing portion C is sealed in multiples by three trajectories 43a, 43b, 43c. In addition, the outer side fixing | fixed part C does not necessarily need to have a water stop function, and it is also possible to form the locus | trajectory in a discontinuous thing.

以下、上記した構成における作用を説明する。平膜状膜カートリッジ40は、膜分離装置21のケース24に装着して曝気槽内に浸漬し、下方より曝気する状態で使用する。この使用状態で、曝気に由来する気液固混相の上向流が膜面に沿って流れるので、浸漬型膜カートリッジ40には気液固混相流に由来する振動が作用する。特にろ過停止時の曝気によって高い負荷が浸漬型膜カートリッジ40に作用し、この負荷による繰返し応力は内側固定部Aにおけるろ過膜44とろ板41との融着部の境界付近に集中する。   Hereinafter, the operation of the above-described configuration will be described. The flat membrane-like membrane cartridge 40 is mounted on the case 24 of the membrane separation device 21, immersed in an aeration tank, and used in a state of aeration from below. In this state of use, the upward flow of the gas-liquid solid mixed phase derived from aeration flows along the film surface, so that vibrations derived from the gas liquid solid mixed phase flow act on the submerged membrane cartridge 40. In particular, a high load acts on the submerged membrane cartridge 40 due to aeration when the filtration is stopped, and the repeated stress due to this load is concentrated in the vicinity of the boundary between the filtration membrane 44 and the filter plate 41 in the inner fixing portion A.

また、曝気槽における浸漬型膜カートリッジ40の使用環境は、曝気槽の形状、曝気槽に貯留する被処理液の性状、季節的な変動要因等によって変化し、使用環境の変化によって浸漬型膜カートリッジ40には不測の外力が作用することがある。   The use environment of the submerged membrane cartridge 40 in the aeration tank changes depending on the shape of the aeration tank, the properties of the liquid to be treated stored in the aeration tank, seasonal fluctuation factors, and the like. An unexpected external force may act on 40.

通常の使用状態においてろ過膜44に作用する外力に対して、ろ過膜44を緊張状態に保持する内側固定部A、およびろ過膜44の周縁をろ板41に固定する外側固定部Cは十分な強度を有しており、外力を内側固定部Aと外側固定部Cとで受け止めることによって外力は止水部Sに及ばず、止水部Sの損傷を防止できる。   The inner fixing portion A that holds the filtration membrane 44 in a tensioned state and the outer fixing portion C that fixes the periphery of the filtration membrane 44 to the filter plate 41 are sufficient with respect to an external force that acts on the filtration membrane 44 in a normal use state. By having the strength and receiving the external force at the inner fixing portion A and the outer fixing portion C, the external force does not reach the water stopping portion S, and the water stopping portion S can be prevented from being damaged.

このように、内側固定部Aおよび外側固定部Cが外力に対する防護体をなすことにより、振動疲労および不測の外力によってろ過膜44が内側固定部Aまたは外側固定部Cで剥離する場合であっても、止水部Sが同時に剥離することがなく、浸漬型膜カートリッジ40のろ過能が不測の事態において損なわれることを防止でき、浸漬型膜カートリッジ40の曝気に対する耐久性が高まる。   As described above, when the inner fixing portion A and the outer fixing portion C form a protective body against external force, the filtration membrane 44 is peeled off by the inner fixing portion A or the outer fixing portion C due to vibration fatigue and unexpected external force. However, the water stop portion S does not peel off at the same time, and the filtration ability of the submerged membrane cartridge 40 can be prevented from being damaged in an unexpected situation, and the durability of the submerged membrane cartridge 40 against aeration is increased.

内側固定部Aまたは外側固定部Cに剥離が発生した時点で、内側固定部Aまたは外側固定部Cを補修してその防護体としての機能を回復して止水部Sの剥離を未然に防止し、浸漬型膜カートリッジ40の延命を図ることができる。   When peeling occurs in the inner fixing part A or the outer fixing part C, the inner fixing part A or the outer fixing part C is repaired to recover its function as a protective body and prevent the water-stopping part S from peeling off. In addition, the life of the submerged membrane cartridge 40 can be extended.

外側固定部Cが網目状をなすことにより、ろ過膜44の周縁が所定幅を有する外側固定部Cにおいて溶着(溶接)されるので、ろ過膜44とろ板41の寸法誤差を外側固定部Cにおいて吸収することができる。   Since the outer fixed portion C has a mesh shape, the peripheral edge of the filtration membrane 44 is welded (welded) at the outer fixed portion C having a predetermined width. Therefore, a dimensional error between the filtration membrane 44 and the filter plate 41 is caused at the outer fixed portion C. Can be absorbed.

浸漬型膜カートリッジ40は、内側固定部A、止水部S、外側固定部Cが止水機能を発揮するので、止水機能を多重に確保することができる。
融着によって内側固定部A、止水部S、外側固定部Cにおいてろ過膜44の膜支持材44aの表層に達する融着層Fを形成することにより、振動疲労および不測の外力によってろ過膜44が内側固定部Aおよび外側固定部Cで剥離する場合にあっても、ろ過膜44は止水部Sにおいて破断する前に、膜支持材44aの破断を伴うことなく、内側固定部Aまたは外側固定部Cから剥離して膜としての機能を維持する。このため、点検時等に剥離した内側固定部Aまたは外側固定部Cを補修することで、膜カートリッジ40の延命化が図れる。
In the submerged membrane cartridge 40, the inner fixing part A, the water stopping part S, and the outer fixing part C exhibit a water stopping function, so that it is possible to ensure multiple water stopping functions.
By forming the fusion layer F reaching the surface layer of the membrane support material 44a of the filtration membrane 44 in the inner fixing portion A, the water stopping portion S, and the outer fixing portion C by fusion, the filtration membrane 44 is caused by vibration fatigue and unexpected external force. Even when the membrane is peeled off at the inner fixing portion A and the outer fixing portion C, the filtration membrane 44 does not break at the water stopping portion S, and the inner fixing portion A or the outer side does not break without breaking the membrane support material 44a. It peels from the fixing part C and maintains its function as a film. For this reason, it is possible to extend the life of the membrane cartridge 40 by repairing the inner fixing portion A or the outer fixing portion C that has been peeled off during inspection or the like.

この溶着(溶接)強度についての剥離試験を以下に説明する。図5に示すように、この剥離試験は、ろ板41に融着したろ過膜44(所定幅に切断した試験片)をろ板41に対して垂直に引っ張って行うものである。   A peel test for the welding (welding) strength will be described below. As shown in FIG. 5, this peel test is performed by pulling a filtration membrane 44 (test piece cut to a predetermined width) fused to the filter plate 41 perpendicularly to the filter plate 41.

図6に示すように、融着によって内側固定部A、止水部S、外側固定部Cにおいてろ過膜44の膜支持材44aに深く達する融着層Fを形成した場合には、図7に示すように、ろ過膜44が内側固定部Aにおいて破断する。この場合には、図8に示す引張り強さと引張り時間の関係図において明らかなように、強度のピークは高いが急激に破断に至る。   As shown in FIG. 6, when the fusion layer F that reaches the membrane support material 44 a of the filtration membrane 44 is formed in the inner fixing part A, the water stopping part S, and the outer fixing part C by fusion, As shown, the filtration membrane 44 breaks at the inner fixed portion A. In this case, as clearly shown in the relationship diagram between the tensile strength and the tensile time shown in FIG. 8, the peak of strength is high, but it suddenly breaks.

このように、ろ過膜44がろ板41から剥離しないように強く融着すると、融着部位に必要以上の熱エネルギーが発生し、ろ過膜44の膜支持材44aを劣化させることになり、膜カートリッジ22としての寿命を低下させる結果を招く。   In this way, if the filtration membrane 44 is strongly fused so as not to peel from the filter plate 41, thermal energy more than necessary is generated at the fusion site, and the membrane support material 44a of the filtration membrane 44 is deteriorated. As a result, the life of the cartridge 22 is reduced.

図9に示すように、融着によって内側固定部A、止水部S、外側固定部Cにおいてろ過膜44の膜支持材44aに浅く達する融着層Fを形成した場合には、図10に示すように、ろ過膜44が膜支持材44aにおいて剥離する。この場合には、図11に示す引張り強さと引張り時間の関係図において明らかなように、強度のピークは強く融着したものに比べて低く、内側固定部Aが破損した後において止水部Sおよび外側固定部Cが連続して破損し、膜支持材44aにおいて剥離するので、修復することができない。   As shown in FIG. 9, when the fusion layer F that reaches the membrane support material 44a of the filtration membrane 44 shallowly is formed in the inner fixing part A, the water stop part S, and the outer fixing part C by fusion, As shown, the filtration membrane 44 peels off at the membrane support material 44a. In this case, as is clear from the relationship between the tensile strength and the pulling time shown in FIG. 11, the strength peak is lower than that of the strongly fused portion, and the water stopping portion S after the inner fixing portion A is broken. Since the outer fixing portion C is continuously damaged and peels off at the membrane support material 44a, it cannot be repaired.

図12に示すように、融着によって内側固定部A、止水部S、外側固定部Cにおいてろ過膜44の膜支持材44aの溶着面側の表層に達する融着層Fを形成した場合には、図13に示すように、ろ過膜44が膜支持材44aの溶着面側の表層において剥離する。この場合には、図14に示す引張り強さと引張り時間の関係図において明らかなように、強度のピークは強く融着したものに比べて低いが、内側固定部Aが剥離した後においても止水部Sで所定の融着強度が維持されるので、浸漬型膜カートリッジ40としての寿命が長くなる。   As shown in FIG. 12, when the fusion layer F that reaches the surface layer on the welding surface side of the membrane support material 44a of the filtration membrane 44 is formed in the inner fixing portion A, the water stopping portion S, and the outer fixing portion C by fusion. As shown in FIG. 13, the filtration membrane 44 peels off at the surface layer on the welding surface side of the membrane support material 44a. In this case, as clearly shown in the relationship diagram between the tensile strength and the pulling time shown in FIG. 14, the peak of strength is lower than that of the strongly fused portion, but the water stoppage even after the inner fixing portion A peels off. Since the predetermined fusion strength is maintained in the portion S, the life of the immersion membrane cartridge 40 is extended.

以上のように本発明によれば、通常の使用状態においてろ過膜に作用する外力に対して、ろ過膜を緊張状態に保持する内側固定部、およびろ過膜の周縁をろ板に固定する外側固定部が防護体をなすことによって外力が止水部に及ばず、止水部の損傷を防止できる。振動疲労および不測の外力によってろ過膜が内側固定部および外側固定部で剥離する場合であっても、止水部が同時に剥離することがなく、浸漬型膜カートリッジの曝気に対する耐久性を高めることができる。内側固定部または外側固定部に剥離が発生した時点で、内側固定部または外側固定部を補修してその防護体としての機能を回復して止水部の剥離を未然に防止し、浸漬型膜カートリッジの延命を図ることができる。外側固定部が網目状をなすことにより、ろ過膜とろ板の寸法誤差を外側固定部において吸収することができる。内側固定部、止水部、外側固定部においてろ過膜を全周にわたってろ板に融着することにより、止水機能を多重に確保することができる。内側固定部、止水部、外側固定部においてろ過膜の膜支持材の表層に達する融着層を形成することにより、ろ過膜は膜支持材の破断を伴うことなく内側固定部および外側固定部から剥離するので、その修復を容易に行うことができる。   As described above, according to the present invention, with respect to the external force acting on the filtration membrane in a normal use state, the inner fixing portion that holds the filtration membrane in a tensioned state, and the outer fixing that fixes the periphery of the filtration membrane to the filter plate When the part forms a protective body, external force does not reach the water stop part, and damage to the water stop part can be prevented. Even if the filtration membrane peels off at the inner and outer fixed parts due to vibration fatigue and unforeseen external forces, the water stop part does not peel off at the same time, and the durability of the submerged membrane cartridge against aeration can be improved. it can. When peeling occurs on the inner fixing part or outer fixing part, the inner fixing part or outer fixing part is repaired to restore its protective function and prevent the water-stopping part from peeling off. The life of the cartridge can be extended. By forming the outer fixing portion in a mesh shape, a dimensional error between the filtration membrane and the filter plate can be absorbed in the outer fixing portion. By fusing the filtration membrane to the filter plate over the entire circumference in the inner fixing part, the water stopping part, and the outer fixing part, multiple water stopping functions can be ensured. By forming a fusion layer that reaches the surface layer of the membrane support material of the filtration membrane at the inner fixed portion, the water stop portion, and the outer fixed portion, the filtration membrane can be connected to the inner fixed portion and the outer fixed portion without breaking the membrane support material. Since it peels off, it can be easily repaired.

本発明の実施の形態における膜カートリッジを示す模式図である。It is a schematic diagram which shows the film | membrane cartridge in embodiment of this invention. 同実施の形態におけるろ板を示す模式図である。It is a schematic diagram which shows the filter plate in the same embodiment. 同実施の形態における膜カートリッジの製造手順を示す模式図である。It is a schematic diagram which shows the manufacture procedure of the film | membrane cartridge in the same embodiment. 同実施の形態における膜カートリッジの製造方法を示す模式図である。It is a schematic diagram which shows the manufacturing method of the film | membrane cartridge in the embodiment. 溶着強度の試験方法を示す模式図である。It is a schematic diagram which shows the test method of welding strength. ろ過膜の強い溶着状態を示す模式図である。It is a schematic diagram which shows the strong welding state of a filtration membrane. 強い溶着状態におけるろ過膜の破断形態を示す模式図である。It is a schematic diagram which shows the fracture | rupture form of the filtration membrane in a strong welding state. 強い溶着状態における引張り強さと引張り時間の相関図である。It is a correlation diagram of tensile strength and tension time in a strong welding state. ろ過膜の少し強い溶着状態を示す模式図である。It is a schematic diagram which shows the slightly strong welding state of a filtration membrane. 少し強い溶着状態におけるろ過膜の剥離形態を示す模式図である。It is a schematic diagram which shows the peeling form of the filtration membrane in a slightly strong welding state. 少し強い溶着状態における引張り強さと引張り時間の相関図である。It is a correlation diagram of the tensile strength and the tension time in a slightly strong welding state. ろ過膜の理想的な溶着状態を示す模式図である。It is a schematic diagram which shows the ideal welding state of a filtration membrane. 理想的な溶着状態におけるろ過膜の剥離形態を示す模式図である。It is a schematic diagram which shows the peeling form of the filtration membrane in an ideal welding state. 理想的な溶着状態における引張り強さと引張り時間の相関図である。FIG. 5 is a correlation diagram between tensile strength and tension time in an ideal welding state. 従来の膜分離装置を示す斜視図である。It is a perspective view which shows the conventional membrane separator. 従来の膜カートリッジを示す模式図である。It is a schematic diagram which shows the conventional membrane cartridge. 従来の膜カートリッジの製造方法を示す模式図である。It is a schematic diagram which shows the manufacturing method of the conventional film | membrane cartridge. 従来の膜カートリッジの断面図である。It is sectional drawing of the conventional film | membrane cartridge. 従来の膜カートリッジの製造方法を示す模式図である。It is a schematic diagram which shows the manufacturing method of the conventional film | membrane cartridge. 従来のアップダウンホーンを示す模式図である。It is a schematic diagram which shows the conventional up-down horn. 従来の膜カートリッジを示す模式図である。It is a schematic diagram which shows the conventional membrane cartridge.

符号の説明Explanation of symbols

21 膜分離装置
23 散気装置
24 ケース
25 膜ケース
26 散気ケース
27 チューブ
28 集水管
29 透過液導出管
40 浸漬型膜カートリッジ
41 ろ板
42a 線状溶融代
42b 線状溶融代
43 網目状溶融代
44 ろ過膜
44a 膜支持材
44b 膜
45 治具
46 アップダウンホーン
A 内側固定部
S 止水部
B 外側固定部
F 融着層
DESCRIPTION OF SYMBOLS 21 Membrane separator 23 Air diffuser 24 Case 25 Membrane case 26 Air diffuser case 27 Tube 28 Water collecting pipe 29 Permeate outlet pipe 40 Immersion type membrane cartridge 41 Filter plate 42a Linear melting allowance 42b Linear melting allowance 43 Network melting allowance 44 Filtration Membrane 44a Membrane Support Material 44b Membrane 45 Jig 46 Up / Down Horn A Inner Fixed Portion S Water Stopping Portion B Outer Fixed Portion F Fused Layer

Claims (5)

樹脂製のろ板とろ板の表面を覆って配置したろ過膜とを有し、ろ板に沿って成形した溶融代においてろ過膜を融着してなる固定部を形成し、ろ過膜が不織布からなる膜支持材の表裏に有機質の膜を形成してなり、前記固定部において膜支持材の溶着面側の表層に達する融着層を形成したことを特徴とする浸漬型膜カートリッジ。 It has a filter plate made of resin and a filter membrane arranged so as to cover the surface of the filter plate, and forms a fixed part formed by fusing the filter membrane in the melting allowance formed along the filter plate, and the filter membrane is made of nonwoven fabric. An immersion type membrane cartridge, wherein an organic film is formed on the front and back of the membrane support material to be formed, and a fusion layer reaching the surface layer on the welding surface side of the membrane support material is formed in the fixing portion. 溶融代が、ろ板の表面から突出して、かつろ板の周縁部に沿って成形してなることを特徴とする請求項1に記載の浸漬型膜カートリッジ。 The immersion membrane cartridge according to claim 1, wherein the melting allowance projects from the surface of the filter plate and is molded along the peripheral edge of the filter plate. 固定部が、ろ過膜を全周にわたってろ板に融着してなることを特徴とする請求項1又は2に記載の浸漬型膜カートリッジ。 The submerged membrane cartridge according to claim 1 or 2, wherein the fixing part is formed by fusing the filtration membrane to the filter plate over the entire circumference. 固定部が、ろ板の表面から突出し、かつろ板の周縁部に沿って多重に成形した複数の溶融代においてろ過膜を融着してなることを特徴とする請求項1又は3に記載の浸漬型膜カートリッジ。 The fixed part protrudes from the surface of the filter plate and is formed by fusing the filtration membrane at a plurality of melting allowances formed in a multiple manner along the peripheral edge of the filter plate. Immersion type membrane cartridge. 固定部が、内側の溶融代でろ過膜を緊張状態に保持する内側固定部を形成し、中央の溶融代でろ過膜の全周にわたって止水機能を確保する止水部を形成し、外側の溶融代でろ過膜の周縁をろ板に固定する外側固定部を形成することを特徴とする請求項4に記載の浸漬型膜カートリッジ。 The fixing part forms an inner fixing part that holds the filtration membrane in a tension state at the inner melting allowance, and forms a water stopping part that secures a water stopping function over the entire circumference of the filtration membrane at the central melting allowance. The submerged membrane cartridge according to claim 4, wherein an outer fixing portion for fixing the periphery of the filtration membrane to the filter plate is formed by a melting allowance.
JP2005276958A 2005-09-26 2005-09-26 Dipped type membrane cartridge Pending JP2006007223A (en)

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Cited By (3)

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Publication number Priority date Publication date Assignee Title
WO2019111699A1 (en) * 2017-12-04 2019-06-13 株式会社クボタ Flat membrane element and method for producing same
CN112892229A (en) * 2021-01-27 2021-06-04 广州中国科学院先进技术研究所 Virus composite filtering membrane and preparation method thereof
CN114514064A (en) * 2019-09-26 2022-05-17 东洋纺株式会社 Immersion type flat membrane element and method for manufacturing same

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019111699A1 (en) * 2017-12-04 2019-06-13 株式会社クボタ Flat membrane element and method for producing same
CN111278541A (en) * 2017-12-04 2020-06-12 株式会社久保田 Flat membrane element and method for the production thereof
KR20200090780A (en) * 2017-12-04 2020-07-29 가부시끼 가이샤 구보다 Flat membrane element and method for manufacturing same
CN111278541B (en) * 2017-12-04 2022-04-05 株式会社久保田 Flat membrane element and method for the production thereof
KR102505554B1 (en) * 2017-12-04 2023-03-03 가부시끼 가이샤 구보다 Flat membrane element and manufacturing method thereof
CN114514064A (en) * 2019-09-26 2022-05-17 东洋纺株式会社 Immersion type flat membrane element and method for manufacturing same
CN114514064B (en) * 2019-09-26 2023-09-05 东洋纺Mc 株式会社 Impregnated flat membrane element and method for manufacturing same
CN112892229A (en) * 2021-01-27 2021-06-04 广州中国科学院先进技术研究所 Virus composite filtering membrane and preparation method thereof

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