JP2005533901A5 - - Google Patents
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- Publication number
- JP2005533901A5 JP2005533901A5 JP2004524384A JP2004524384A JP2005533901A5 JP 2005533901 A5 JP2005533901 A5 JP 2005533901A5 JP 2004524384 A JP2004524384 A JP 2004524384A JP 2004524384 A JP2004524384 A JP 2004524384A JP 2005533901 A5 JP2005533901 A5 JP 2005533901A5
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- enzymatically
- polymerization reaction
- catalyzed
- controlled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000006116 polymerization reaction Methods 0.000 claims description 35
- 238000006243 chemical reaction Methods 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 14
- 238000007334 copolymerization reaction Methods 0.000 claims description 13
- 239000003999 initiator Substances 0.000 claims description 9
- 238000010526 radical polymerization reaction Methods 0.000 claims description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000006068 polycondensation reaction Methods 0.000 claims description 5
- 229920001400 block copolymer Polymers 0.000 claims description 4
- 238000012705 nitroxide-mediated radical polymerization Methods 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 238000012690 ionic polymerization Methods 0.000 claims description 3
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 claims description 2
- 230000002255 enzymatic effect Effects 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims 1
- 238000006911 enzymatic reaction Methods 0.000 claims 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 4
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 3
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000012712 reversible addition−fragmentation chain-transfer polymerization Methods 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000013033 iniferter Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02102059 | 2002-07-25 | ||
| PCT/NL2003/000515 WO2004011515A2 (en) | 2002-07-25 | 2003-07-14 | Process for the preparation of a block copolymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005533901A JP2005533901A (ja) | 2005-11-10 |
| JP2005533901A5 true JP2005533901A5 (enExample) | 2006-08-31 |
Family
ID=30775866
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004524384A Pending JP2005533901A (ja) | 2002-07-25 | 2003-07-14 | ブロック共重合体の製造方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20060100390A1 (enExample) |
| EP (1) | EP1539847B1 (enExample) |
| JP (1) | JP2005533901A (enExample) |
| CN (1) | CN100447171C (enExample) |
| AT (1) | ATE365754T1 (enExample) |
| AU (1) | AU2003253507A1 (enExample) |
| CA (1) | CA2493771A1 (enExample) |
| DE (1) | DE60314644T2 (enExample) |
| DK (1) | DK1539847T3 (enExample) |
| ES (1) | ES2289338T3 (enExample) |
| WO (1) | WO2004011515A2 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005026135A1 (de) * | 2005-06-06 | 2006-12-07 | Basf Ag | Verfahren zur Herstellung einer wässrigen Polymerdispersion |
| US7662883B2 (en) * | 2006-12-28 | 2010-02-16 | The Goodyear Tire & Rubber Company | Rubbery block polymers containing polylactone and rubber compounds including the same |
| US7666973B2 (en) * | 2007-07-30 | 2010-02-23 | Tyco Healthcare Group Lp | Carbonate copolymers |
| EP2151457A1 (en) * | 2008-07-28 | 2010-02-10 | Total Petrochemicals France | Process to make a diblock copolymer having a monovinylaromatic polymer block |
| US8119763B2 (en) * | 2008-09-29 | 2012-02-21 | Xerox Corporation | Production of polyesters in a continuous packed-bed reactor using immobilized enzyme catalysts |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4981696A (en) * | 1986-12-22 | 1991-01-01 | E. I. Du Pont De Nemours And Company | Polylactide compositions |
| US5439985A (en) * | 1993-07-28 | 1995-08-08 | University Of Massachusetts Lowell | Biodegradable and hydrodegradable diblock copolymers composed of poly(.beta. |
| US6114458A (en) * | 1998-09-23 | 2000-09-05 | International Business Machines Corporation | Highly branched radial block copolymers |
-
2003
- 2003-07-14 US US10/522,168 patent/US20060100390A1/en not_active Abandoned
- 2003-07-14 CN CNB038178575A patent/CN100447171C/zh not_active Expired - Fee Related
- 2003-07-14 ES ES03771490T patent/ES2289338T3/es not_active Expired - Lifetime
- 2003-07-14 AT AT03771490T patent/ATE365754T1/de not_active IP Right Cessation
- 2003-07-14 AU AU2003253507A patent/AU2003253507A1/en not_active Abandoned
- 2003-07-14 WO PCT/NL2003/000515 patent/WO2004011515A2/en not_active Ceased
- 2003-07-14 EP EP03771490A patent/EP1539847B1/en not_active Expired - Lifetime
- 2003-07-14 JP JP2004524384A patent/JP2005533901A/ja active Pending
- 2003-07-14 DE DE60314644T patent/DE60314644T2/de not_active Expired - Fee Related
- 2003-07-14 CA CA002493771A patent/CA2493771A1/en not_active Abandoned
- 2003-07-14 DK DK03771490T patent/DK1539847T3/da active
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