JP2005519161A5 - - Google Patents

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Publication number
JP2005519161A5
JP2005519161A5 JP2003573065A JP2003573065A JP2005519161A5 JP 2005519161 A5 JP2005519161 A5 JP 2005519161A5 JP 2003573065 A JP2003573065 A JP 2003573065A JP 2003573065 A JP2003573065 A JP 2003573065A JP 2005519161 A5 JP2005519161 A5 JP 2005519161A5
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Japan
Prior art keywords
foam
weight
resin composition
amount sufficient
present
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Pending
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JP2003573065A
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Japanese (ja)
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JP2005519161A (en
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Priority claimed from PCT/US2003/000953 external-priority patent/WO2003074603A1/en
Publication of JP2005519161A publication Critical patent/JP2005519161A/en
Publication of JP2005519161A5 publication Critical patent/JP2005519161A5/ja
Pending legal-status Critical Current

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Claims (12)

(a)組成物の重量に基づき少なくとも50重量%のプロピレン部分含有量を有するポリマー樹脂組成物;
(b)成分(a)、(c)、(d)及び(e)のみを含むプロピレンポリマー発泡体の熱伝導率よりも少なくとも0.0005ワット/メーター−ケルビン低い熱伝導率を有する発泡体を生成するのに充分な量の、カーボンブラック、活性化カーボンブラック、グラファイト及びそれらの混合物からなる群から選ばれた赤外線遮断材料;
(c)DIN 4102燃焼性評価B2を発泡体に与えるのに充分な量で存在する、少なくとも1種の臭素化合物;
(d)フェノール系酸化防止剤;並びに
(e)臭素化合物とは実質的に反応せず、発泡体に、(1)少なくとも25日間の期間でかつ(2)成分(a)、(b)、(c)及び(d)のみを含む発泡体の耐熱老化性よりも3日長い、温度150℃における耐熱老化性を与えるのに充分な量で存在する、ヒンダードアミン光安定剤、N−アルコキシアミン安定剤、N−ヒドロキシルアミン安定剤及びチオ相乗剤から選ばれた少なくとも1種の安定剤から実質的になるプロピレンポリマー発泡体。
(A) a polymer resin composition having a propylene moiety content of at least 50% by weight based on the weight of the composition;
(B) a foam having a thermal conductivity of at least 0.0005 Watts / meter-Kelvin lower than the thermal conductivity of a propylene polymer foam comprising only components (a), (c), (d) and (e). An infrared shielding material selected from the group consisting of carbon black, activated carbon black, graphite and mixtures thereof in an amount sufficient to produce;
(C) at least one bromine compound present in an amount sufficient to provide DIN 4102 flammability rating B2 to the foam;
(D) a phenolic antioxidant; and (e) substantially non-reactive with the bromine compound and in the foam (1) for a period of at least 25 days and (2) components (a), (b), A hindered amine light stabilizer, N-alkoxyamine stable, present in an amount sufficient to provide heat aging resistance at a temperature of 150 ° C., 3 days longer than the heat aging resistance of the foam containing only (c) and (d) A propylene polymer foam consisting essentially of at least one stabilizer selected from an agent, an N-hydroxylamine stabilizer and a thiosynergist.
前記発泡体が成分(b)の潜在的悪影響を相殺するのに充分な量の(f)充填剤表面不活性化剤を更に含んでなり、前記充填剤不活性化剤がエポキシ樹脂又はエポキシ化合物である請求項1に記載の発泡体。   The foam further comprises (f) a filler surface deactivator in an amount sufficient to offset the potential adverse effects of component (b), wherein the filler deactivator is an epoxy resin or an epoxy compound. The foam according to claim 1. 前記臭素化合物がデカブロモジフェニルエタン、テトラブロモフタル酸ジ−2−エチルヘキシルエステル、オクタブロモジフェニルオキシド、ビス(トリブロモフェノキシ)エタン、トリス(トリボロモネオペンチル)ホスフェート、臭素化トリメチルフェニルインダン及び臭素化エポキシ樹脂からなる群から選ばれた芳香族臭素化合物であって、ポリマー樹脂組成物の重量に基づき、少なくとも0.2重量%の臭素含量を生じるのに充分な量で存在する請求項1又は2に記載の発泡体。   The bromine compound is decabromodiphenylethane, tetrabromophthalic acid di-2-ethylhexyl ester, octabromodiphenyl oxide, bis (tribromophenoxy) ethane, tris (triboromoneopentyl) phosphate, brominated trimethylphenylindane and brominated 3. An aromatic bromine compound selected from the group consisting of epoxy resins, present in an amount sufficient to produce a bromine content of at least 0.2% by weight, based on the weight of the polymer resin composition. The foam described in 1. 24kg/m3未満の密度を有する請求項1に記載の発泡体。 The foam of claim 1 having a density of less than 24 kg / m 3 . 0.1〜1.5mmの範囲内の気泡サイズを有する請求項1又は2に記載の発泡体。   The foam according to claim 1 or 2, which has a cell size in the range of 0.1 to 1.5 mm. 前記発泡体が融合ストランド構造を有する厚板であり、前記厚板が10〜100mmの範囲内の厚さを有する請求項1又は2に記載の発泡体。   The foam according to claim 1 or 2, wherein the foam is a plank having a fused strand structure, and the plank has a thickness in the range of 10 to 100 mm. 前記赤外線遮断材料がサーマルブラック、ファーネスブラック、アセチレンブラック及びチャンネルブラックからなる群から選ばれた低ストラクチャーのカーボンブラックであり、前記カーボンブラックが10〜400nmの範囲内の平均粒径を有し且つ、ポリマー樹脂組成物の重量に基づき、少なくとも2重量%の量で存在する請求項1又は2に記載の発泡体。   The infrared blocking material is a low structure carbon black selected from the group consisting of thermal black, furnace black, acetylene black and channel black, the carbon black having an average particle size in the range of 10 to 400 nm; and The foam of claim 1 or 2 present in an amount of at least 2% by weight, based on the weight of the polymer resin composition. 0.045ワット/メーター−ケルビン以下の熱伝導率を有する請求項1又は2に記載の発泡体。   The foam according to claim 1 or 2, having a thermal conductivity of 0.045 Watt / meter-Kelvin or less. 前記赤外線遮断材料がグラファイトであり、前記グラファイトが1〜200μmの平均粒径を有し且つ、ポリマー樹脂組成物重量に基づき、0.1〜10重量%の範囲内の量で存在する請求項1又は2に記載の発泡体。   2. The infrared blocking material is graphite, the graphite has an average particle size of 1 to 200 [mu] m and is present in an amount in the range of 0.1 to 10% by weight based on the weight of the polymer resin composition. Or the foam as described in 2. 前記フェノール系酸化防止剤が、ポリマー樹脂組成物の重量に基づき、少なくとも0.3重量%の量で存在する請求項1又は2に記載の発泡体。   The foam according to claim 1 or 2, wherein the phenolic antioxidant is present in an amount of at least 0.3% by weight, based on the weight of the polymer resin composition. 枠組壁工法の壁間柱間の断熱材として、たる木若しくは天井野縁間の断熱材として、又は断熱コンクリート壁パネル内の又はレンガ及びコンクリートブロック壁若しくは現場打ちコンクリート壁の内腔内の断熱成分として使用するのに適した断熱構造であって、請求項1又は2に記載の発泡体を含んでなる断熱構造体。   Used as insulation between inter-column pillars in framed wall construction, as insulation between rafters or ceiling edges, or as a thermal insulation component in insulated concrete wall panels or in the lumens of brick and concrete block walls or cast-in-place concrete walls A heat insulating structure suitable for the heat insulation structure, comprising the foam according to claim 1. 隣接する建物壁間柱間の間隙、隣接するたる木間の間隙、隣接する天井野縁間の間隙、断熱コンクリート壁パネルの内側及び外側パネル部分の間の間隙、レンガ及びコンクリートブロック壁の内部キャビティ又は現場打ちコンクリート壁の内部キャビティから選ばれた建物又は構造の空隙並びに請求項1又は2に記載された発泡体を含んでなる断熱組合せ体。   Gaps between adjacent building wall columns, gaps between adjacent trees, gaps between adjacent ceiling edges, gaps between the inner and outer panel parts of insulated concrete wall panels, internal cavities or sites in brick and concrete block walls A heat insulating combination comprising a void of a building or structure selected from an internal cavity of a cast concrete wall and a foam according to claim 1 or 2.
JP2003573065A 2002-03-01 2003-01-13 Dimensionally stable propylene polymer foam with improved heat aging Pending JP2005519161A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US36078202P 2002-03-01 2002-03-01
PCT/US2003/000953 WO2003074603A1 (en) 2002-03-01 2003-01-13 Dimensionally-stable propylene polymer foam with improved thermal aging.

Publications (2)

Publication Number Publication Date
JP2005519161A JP2005519161A (en) 2005-06-30
JP2005519161A5 true JP2005519161A5 (en) 2006-03-02

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JP2003573065A Pending JP2005519161A (en) 2002-03-01 2003-01-13 Dimensionally stable propylene polymer foam with improved heat aging

Country Status (9)

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US (1) US20050004285A1 (en)
EP (1) EP1483323A1 (en)
JP (1) JP2005519161A (en)
CN (1) CN1277874C (en)
AU (1) AU2003205122A1 (en)
CA (1) CA2477884A1 (en)
RU (1) RU2004129306A (en)
TW (1) TW200303891A (en)
WO (1) WO2003074603A1 (en)

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