JP2005321371A - Sheet for measuring ultraviolet ray transmission amount, device for measuring ultraviolet ray transmission amount, and method for measuring ultraviolet ray transmission using the sheet - Google Patents

Sheet for measuring ultraviolet ray transmission amount, device for measuring ultraviolet ray transmission amount, and method for measuring ultraviolet ray transmission using the sheet Download PDF

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JP2005321371A
JP2005321371A JP2004279123A JP2004279123A JP2005321371A JP 2005321371 A JP2005321371 A JP 2005321371A JP 2004279123 A JP2004279123 A JP 2004279123A JP 2004279123 A JP2004279123 A JP 2004279123A JP 2005321371 A JP2005321371 A JP 2005321371A
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ultraviolet ray
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JP4424667B2 (en
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Sadao Yamamoto
貞夫 山本
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a sheet body for simply measuring and evaluating ultraviolet ray transmission of various cloth-like specimens, and to provide a method for measuring and evaluating ultraviolet ray transmission using the sheet body. <P>SOLUTION: In the sheet 1 for measuring an ultraviolet ray transmission amount, a sheet-like base substance is dyed by a dye in which light resistance is blue scale one class or less regulated in JIS L 0842 after 20 hours of light irradiation of an ultraviolet ray carbon arc lamp. The dye is preferably C.I. mordant green 17, and the sheet-like base substance is dyed without mordanting. Nylon textiles, cation cotton fabrics, hemp textiles, rayon fabrics, leather, wool yarn textiles, silk textiles, paper and the like are mentioned as the sheet-like base substance. In the device for measuring the ultraviolet ray transmission amount, the sheet 1 for measuring the ultraviolet ray transmission amount is stored in an envelope body 2 comprising an ultraviolet ray transmissive material, and at least one ultraviolet ray irradiation open hole 3 is provided in one face of the envelope body 2. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、評価対象物である被試験体(一般には布)の紫外線透過性を測定するのに使用されるシート体(紫外線透過量測定用シート)、当該シートが紫外線非透過性の材質よりなる封筒体の中に収容された紫外線透過量測定装置、並びに当該シートを用いた紫外線透過性の測定方法に関するものである。   The present invention relates to a sheet body (sheet for measuring the amount of UV transmission) used for measuring the UV transmittance of an object to be tested (generally a cloth) that is an evaluation object, and the sheet is made of a material that is not UV transparent. The present invention relates to an ultraviolet ray transmission amount measuring apparatus accommodated in an envelope body and an ultraviolet ray transmission measuring method using the sheet.

これまでに、紫外線の量を測定する装置や方法が数多く提案されてきており、紫外線を受けることにより発色したり退色したりする材料も種々知られている。しかしながら、これまでに知られている紫外線照射によって色調が変化する色素は、直接紫外線を受けて変色を起こすのに適したものであるために、布帛状の試験体の表面側から裏面側へ透過する紫外線量を測定するのには不適であった。
透過する紫外線の量を測定する装置としては、例えば下記の特許文献1〜3に記載されているものが挙げられるが、これら特許文献1〜3に記載される装置はいずれも受光部で紫外線の照度を機械的に測定するために装置が高価であり、又、簡単に測定が行えるものではなかった。
特開平5−248944号公報 特開平5−248945号公報 特開2002−296180号公報
Many devices and methods for measuring the amount of ultraviolet rays have been proposed so far, and various materials that develop or fade when exposed to ultraviolet rays are also known. However, known dyes that change color tone by irradiation with ultraviolet rays are suitable for direct discoloration by direct exposure to ultraviolet rays, so that they are transmitted from the front side to the back side of a fabric-like specimen. It was unsuitable for measuring the amount of ultraviolet rays.
Examples of the device for measuring the amount of transmitted ultraviolet light include those described in Patent Documents 1 to 3 below, and all of the devices described in Patent Documents 1 to 3 are ultraviolet rays in the light receiving unit. The apparatus is expensive for mechanically measuring the illuminance, and it cannot be easily measured.
JP-A-5-248944 JP-A-5-248945 JP 2002-296180 A

本発明は、上述の問題点を解決し、布帛状の被試験体の紫外線透過性を簡単に測定・評価可能なシート体を提供することを課題とする。また、本発明は、このようなシート体を用いることによって各種の布帛状被試験体の紫外線透過性を簡単に評価することが可能な装置及び方法を提供することを課題とするものである。   An object of the present invention is to solve the above-mentioned problems and to provide a sheet body that can easily measure and evaluate the ultraviolet transmittance of a fabric-like object to be tested. Moreover, this invention makes it a subject to provide the apparatus and method which can evaluate the ultraviolet-ray transmittance of various fabric-like test objects easily by using such a sheet | seat body.

上記課題を解決するための本発明の紫外線透過量測定用シートは、被試験体の紫外線透過性を測定するのに使用されるシート体で、当該シート体を構成するシート状基材が、紫外線カーボンアーク灯光照射20時間後における耐光性がJIS L 0842に規定されるブルースケール1級以下である染料を用いて染色されていることを特徴とする。
又、本発明は、上記の特徴を有した紫外線透過量測定用シートにおいて、前記染料がC.I.モーダントレッド7、C.I.モーダントバイオレット1、C.I.モーダントブルー1、C.I.モーダントブルー17、C.I.モーダントブラック1、C.I.モーダントブラック9、C.I.モーダントブラック11、C.I.モーダントブルー29、C.I.モーダントブルー3、C.I.モーダントグリーン17、C.I.モーダントグリーン28から成るグループより選ばれたものであり、当該染料が、媒染を行なうことなく前記シート状基材に染着されていることを特徴とするものである。
更に本発明は、上記の特徴を有した紫外線透過量測定用シートにおいて、前記シート状基材が、ナイロン織物、カチオン化綿織物、麻織物、レーヨン織物、皮革、ウール織物、シルク織物および紙から成るグループより選ばれたものであることを特徴とするものでもある。
In order to solve the above problems, the ultraviolet ray transmission amount measuring sheet of the present invention is a sheet body used for measuring the ultraviolet transmittance of a test object, and the sheet-like base material constituting the sheet body is an ultraviolet ray. It is characterized by being dyed with a dye whose light resistance after 20 hours of irradiation with a carbon arc lamp is a blue scale grade 1 or less as defined in JIS L 0842.
The present invention also relates to the ultraviolet ray transmission amount measuring sheet having the above characteristics, wherein the dye is C.I. I. Modern Tread 7, C.I. I. Modern Violet 1, C.I. I. Modern Blue 1, C.I. I. Modern Blue 17, C.I. I. Modern Black 1, C.I. I. Modern Black 9, C.I. I. Modern Black 11, C.I. I. Modern Blue 29, C.I. I. Modern Blue 3, C.I. I. Modern Green 17, C.I. I. It is selected from the group consisting of modern green 28, and is characterized in that the dye is dyed on the sheet-like substrate without mordanting.
Furthermore, the present invention is the ultraviolet ray transmission amount measuring sheet having the above characteristics, wherein the sheet-like base material is made of nylon fabric, cationized cotton fabric, hemp fabric, rayon fabric, leather, wool fabric, silk fabric and paper. It is also characterized by being selected from a group.

又、本発明は、上述の紫外線透過量測定用シートが、紫外線非透過性の材質よりなる封筒体の中に収容されており、当該封筒体に一方の面に、少なくとも1つの紫外線照射用開孔が設けられていることを特徴とする紫外線透過量測定装置でもある。
又、本発明は、上記の特徴を有した紫外線透過量測定装置において、前記紫外線透過量測定用シートの表面に、透明性を有する材質より成るシート体(透明性シート体)が積層された構造であることを特徴とするものでもある。
Further, according to the present invention, the above-mentioned ultraviolet ray transmission amount measuring sheet is accommodated in an envelope made of a non-ultraviolet material, and at least one ultraviolet irradiation opening is provided on one surface of the envelope. It is also an ultraviolet ray transmission amount measuring device characterized by being provided with holes.
Further, according to the present invention, in the ultraviolet transmission measuring apparatus having the above-described features, a structure in which a sheet body (transparent sheet body) made of a transparent material is laminated on the surface of the ultraviolet transmission measurement sheet. It is also characterized by being.

更に本発明は、紫外線透過量を測定することが可能な紫外線透過量測定用シートを用いて、被試験体の紫外線透過性を測定する方法で、当該方法が、下記の工程A〜C:
工程A:前記請求項1〜3のいずれか1項に記載の紫外線透過量測定用シートを準備する工程、
工程B:前記紫外線透過量測定用シートの表面に被試験体を密接させて積層し、前記被試験体の表面に紫外線照射部と紫外線非照射部が形成される状態で紫外線を照射する工程、及び、
工程C:前記工程Bにて紫外線照射された後の紫外線透過量測定用シートにおける紫外線照射部と紫外線非照射部との色差から、前記被試験体の紫外線透過性を評価する工程
を含むことを特徴とするものでもある。
又、本発明は、上記の特徴を有した紫外線透過量測定方法における工程Bにおいて、前記紫外線透過量測定用シートの表面に、透明性を有する材質より成るシート体を積層させてから前記被試験体を積層することを特徴とするものでもある。
Furthermore, the present invention is a method for measuring the ultraviolet transmittance of a test object using an ultraviolet transmittance measuring sheet capable of measuring the ultraviolet transmittance, and the method comprises the following steps A to C:
Step A: a step of preparing the ultraviolet ray transmission amount measuring sheet according to any one of claims 1 to 3,
Process B: A process of irradiating ultraviolet rays in a state where an ultraviolet irradiation part and an ultraviolet non-irradiation part are formed on the surface of the test object, by laminating the test object in close contact with the surface of the ultraviolet ray transmission amount measurement sheet, as well as,
Step C: including a step of evaluating the ultraviolet transmittance of the DUT from the color difference between the ultraviolet ray irradiation portion and the ultraviolet ray non-irradiation portion in the ultraviolet ray transmission amount measurement sheet after being irradiated with the ultraviolet ray in the step B. It is also a feature.
Further, the present invention provides the test object after laminating a sheet body made of a transparent material on the surface of the ultraviolet ray transmission amount measuring sheet in the step B in the ultraviolet ray transmission amount measuring method having the above characteristics. It is also characterized by laminating bodies.

本発明の紫外線透過量測定用シートは、布帛状の被試験体の紫外線透過性を簡単に測定評価するのに好適である。また、このようなシート体を用いた本発明の方法により、高価な測定機器を用いなくても、各種の布帛状被試験体の紫外線透過性を簡単に評価することができる。更に、上記紫外線透過量測定用シートの表面に、ポリエチレンフィルムやガラス板などの透明性を有するシート体を積層することによって、このようなシート体を積層しない場合に比べて紫外線透過量の測定感度を高めることができ、短時間での紫外線透過量の評価・測定に適したものとなる。   The sheet for measuring the amount of transmitted UV light of the present invention is suitable for simply measuring and evaluating the UV transmittance of a cloth-like object to be tested. Further, by the method of the present invention using such a sheet body, it is possible to easily evaluate the ultraviolet transmittance of various fabric-like test bodies without using an expensive measuring instrument. Further, by laminating a transparent sheet body such as a polyethylene film or a glass plate on the surface of the sheet for measuring the amount of transmitted ultraviolet light, the sensitivity of measuring the amount of transmitted ultraviolet light compared to the case where such a sheet body is not laminated. This makes it suitable for evaluating and measuring the amount of ultraviolet light transmitted in a short time.

まず、本発明の紫外線透過量測定用シートに使用される染料について説明する。本発明において使用される染料は、紫外線カーボンアーク灯光照射20時間後における耐光性がJIS L 0842に規定されるブルースケール1級以下であるものであり、このような染料としては、酸性媒染染料の中で構造中に−N=N−(アゾ基)を有するものが使用でき、代表的にはC.I.モーダントレッド7、C.I.モーダントバイオレット1、C.I.モーダントブルー1、C.I.モーダントブルー17、C.I.モーダントブラック1、C.I.モーダントブラック9、C.I.モーダントブラック11、C.I.モーダントブルー29、C.I.モーダントブルー3、C.I.モーダントグリーン17、C.I.モーダントグリーン28が挙げられ、特にC.I.モーダントグリーン17が好ましいが、トリフェノールメタン等も使用できる。尚、本発明に最も適したC.I.モーダントグリーン17は、モルダントグリーンF(三井東圧化学製)、サンクロミングリーンLG conc.(住化ケムテックス製)、モルダントグリーン501(山田化学製)として市販されているものが利用でき、その特性を応用して種々の紫外線測定が簡単に安価でできる。   First, the dye used for the ultraviolet ray transmission amount measuring sheet of the present invention will be described. The dye used in the present invention has a light resistance after 20 hours of irradiation with an ultraviolet carbon arc lamp, which is a blue scale grade 1 or less as defined in JIS L 0842. Such dyes include acid mordant dyes. Among them, those having —N═N— (azo group) in the structure can be used. I. Modern Tread 7, C.I. I. Modern Violet 1, C.I. I. Modern Blue 1, C.I. I. Modern Blue 17, C.I. I. Modern Black 1, C.I. I. Modern Black 9, C.I. I. Modern Black 11, C.I. I. Modern Blue 29, C.I. I. Modern Blue 3, C.I. I. Modern Green 17, C.I. I. Modern green 28, and C.I. I. Modern green 17 is preferred, but triphenolmethane or the like can also be used. C. most suitable for the present invention. I. Modern Green 17 is Mordant Green F (Mitsui Toatsu Chemicals), Sanchromin Green LG conc. (Made by Sumika Chemtex Co., Ltd.) and Mordant Green 501 (manufactured by Yamada Chemical Co., Ltd.) can be used, and various UV measurements can be performed easily and inexpensively by applying the characteristics.

そして、本発明では、上記のような酸性媒染染料を媒染せずに、金属と反応させることなくシート状基材に染着させる。本発明では、このようにして媒染処理を行わないこと(未媒染)によって、紫外線照射に対しての適度な変色性が得られ、また、同じ染料を使用した場合であってもシート状基材の材質を選択することにより、短時間紫外線照射測定用シートとすることも、長時間紫外線照射測定用シートとすることもできる。即ち、短時間紫外線照射測定用として適したシート状基材としては、ナイロン織物(6‐ナイロン織物、6,6‐ナイロン織物)、カチオン化綿織物、麻織物、レーヨン織物、皮革等が挙げられ、一般的なキセノンフェードメータ(紫外線耐光試験機、スガ試験機製)での紫外線照射時間10分〜180分で段階的に変色する。この中で、短時間紫外線照射用として最も適したシート状基材はナイロン織物である。一方、長時間紫外線照射測定用として適したシート状基材としては、ウール織物、シルク織物、紙等が挙げられ、同じ染料を媒染することなく使用した場合であっても、上記フェードメータでの紫外線照射時間が180分〜900分で段階的に変色するものとなる。   And in this invention, the above-mentioned acidic mordant dye is dyed to a sheet-like base material, without making it react with a metal, without mordanting. In the present invention, by not performing the mordanting treatment (unmordanting) in this way, an appropriate discoloration for ultraviolet irradiation can be obtained, and even when the same dye is used, a sheet-like substrate By selecting the material, it can be used as a short-time ultraviolet irradiation measurement sheet or a long-time ultraviolet irradiation measurement sheet. That is, examples of the sheet-like base material suitable for short-time ultraviolet irradiation measurement include nylon fabric (6-nylon fabric, 6,6-nylon fabric), cationized cotton fabric, hemp fabric, rayon fabric, leather, etc. The color changes gradually in the ultraviolet irradiation time of 10 minutes to 180 minutes in a general xenon fade meter (ultraviolet light resistance tester, manufactured by Suga Test Instruments). Among these, the most suitable sheet-like substrate for short-time ultraviolet irradiation is a nylon fabric. On the other hand, examples of the sheet-like base material suitable for long-time ultraviolet irradiation measurement include wool woven fabric, silk woven fabric, paper, etc., even when the same dye is used without mordanting, The ultraviolet irradiation time changes in steps from 180 minutes to 900 minutes.

このようなシート状基材に前記染料を染着させて得られた本発明の紫外線透過量測定用シートは、布帛状の被試験体、例えば布地の衣料、カーテン等を透過する紫外線の量を短時間に測定でき、ガラス、合成樹脂(フィルム、波板)の紫外線透過量測定も同様に可能である。又、本発明の紫外線透過量測定用シートを用いて、各種物体からの紫外線反射量を測定することも可能であり、例えば壁や道路、雪、雲等の紫外線の反射測定にも応用でき、植物の葉や花の紫外線透過性の測定も可能である。   The sheet for measuring the amount of ultraviolet light transmission of the present invention obtained by dyeing the dye on such a sheet-like base material has the amount of ultraviolet light transmitted through a cloth-like object to be tested, for example, clothing, curtains, etc. It can be measured in a short time, and the ultraviolet ray transmission amount of glass and synthetic resin (film, corrugated sheet) can be measured in the same manner. Moreover, it is also possible to measure the amount of reflected ultraviolet light from various objects using the sheet for measuring the amount of transmitted ultraviolet light of the present invention, and can be applied to the reflection measurement of ultraviolet light such as walls, roads, snow, clouds, etc. It is also possible to measure the UV transmittance of plant leaves and flowers.

次に、本発明の紫外線透過量測定装置について説明する。本発明の紫外線透過量測定装置は、前述の紫外線透過量測定用シートが、紫外線非透過性の材質よりなる封筒体の中に収容された形態を有するものであり、当該封筒体に一方の面には、前記シートの表面に紫外線照射部と紫外線非照射部が形成されるように、少なくとも1つの紫外線照射用開孔が設けられている。図1は、本発明の紫外線透過量測定装置の一例を示す外観図で、(a)は、紫外線照射用開孔3が設けられた面を見た時の図であり、(b)は、その反対側の面を見た時の図である。   Next, the ultraviolet transmission measuring device of the present invention will be described. The ultraviolet ray transmission amount measuring apparatus of the present invention has a configuration in which the above-described ultraviolet ray transmission amount measurement sheet is housed in an envelope made of an ultraviolet non-transparent material, and the envelope body has one surface. Is provided with at least one ultraviolet irradiation hole so that an ultraviolet irradiation part and an ultraviolet non-irradiation part are formed on the surface of the sheet. FIG. 1 is an external view showing an example of the ultraviolet ray transmission amount measuring apparatus of the present invention, (a) is a view when a surface provided with an ultraviolet irradiation aperture 3 is viewed, and (b), It is a figure when the surface on the opposite side is seen.

図1(a)及び(b)に示されるように、本発明の紫外線透過量測定装置にあっては、前述の染料を用いて染着された紫外線透過量測定用シート1が、紫外線非透過性の材質よりなる封筒体2の中に収容されており、この際、この封筒体2に一方の面には、シート1の表面に紫外線照射部と紫外線非照射部が形成されるように、少なくとも1つの紫外線照射用開孔3が設けられている。図1には、円形の紫外線照射用開孔3が1つ設けられているものが例示されているが、開孔3の数や形状はこれに限定されるものではなく、紫外線照射部と紫外線非照射部の間の色差が判別できれば良い。又、封筒体2を構成する材質についても、紫外線透過量測定用シート1の表面に紫外線照射部と紫外線非照射部が形成されるように、紫外線を通さず、簡単に装着できるものであれば良く、例えば紙、布、フィルム、合成樹脂、皮、金属等などが挙げられる。尚、図1に例示した紫外線透過量測定装置における封筒体2は紙製であり、紫外線透過量測定用シート1を横方向から挿脱できるように糊付け部4が設けられいる。
図2(a)は、図1に例示した本発明の紫外線透過量測定装置の紫外線透過量測定用シート1を横方向(図面の右側方向)へ引き抜いた後の封筒体2の外観を示す図であり、(b)は、引き抜かれた紫外線透過量測定用シート1の外観を示す図である。
As shown in FIGS. 1 (a) and 1 (b), in the ultraviolet ray transmission amount measuring apparatus of the present invention, the ultraviolet ray transmission amount measuring sheet 1 dyed with the above-described dye is not ultraviolet-transmissive. In this case, the envelope body 2 is housed in an envelope 2 on one surface, so that an ultraviolet irradiation portion and an ultraviolet non-irradiation portion are formed on the surface of the sheet 1. At least one ultraviolet irradiation aperture 3 is provided. FIG. 1 illustrates an example in which one circular ultraviolet irradiation aperture 3 is provided, but the number and shape of the apertures 3 are not limited to this, and the ultraviolet irradiation unit and the ultraviolet rays are not limited thereto. It suffices if the color difference between the non-irradiated parts can be discriminated. Also, the material constituting the envelope 2 may be any material that does not transmit ultraviolet light and can be easily mounted so that an ultraviolet irradiation part and an ultraviolet non-irradiation part are formed on the surface of the ultraviolet ray transmission measuring sheet 1. For example, paper, cloth, film, synthetic resin, leather, metal and the like can be mentioned. The envelope 2 in the ultraviolet transmission measuring device illustrated in FIG. 1 is made of paper, and a gluing portion 4 is provided so that the ultraviolet transmission measuring sheet 1 can be inserted and removed from the lateral direction.
FIG. 2A is a view showing the outer appearance of the envelope 2 after the ultraviolet transmission measurement sheet 1 of the ultraviolet transmission measurement apparatus of the present invention illustrated in FIG. 1 is pulled out in the lateral direction (right side in the drawing). (B) is a figure which shows the external appearance of the sheet | seat 1 for ultraviolet-ray transmission amount measurement withdrawn.

本発明の紫外線透過量測定装置の好ましい一例は、小型封筒の表に紫外線照射用開孔が設けられた黒色の測定器で、測定目的により封筒及び開孔の大きさは自由にできるが、スタンダード品としては10cm×6.5cmの黒色紙製封筒の表面に内径2cm程度の穴を設け、この封筒の中に10cm×3.5cmの大きさのセンサー台紙(前述の染料を用いて例えば紙を染色したもの)を挿入したものが挙げられる(図1及び図2参照)。このような装置を使用する際には、測定時にセンサー面が封筒の表面側を向くようにして使用し、測定終了時にセンサー台紙を引き抜いてセンサー面が裏面側を向くようにして封筒内に挿入し、紫外線が照射されないようにするが、本発明の紫外線量測定器は、このような形態のものに限定されるものではない。   A preferable example of the ultraviolet ray transmission amount measuring apparatus of the present invention is a black measuring instrument in which an opening for ultraviolet irradiation is provided on the surface of a small envelope, and the size of the envelope and the opening can be freely set depending on the measurement purpose. As a product, a hole with an inner diameter of about 2 cm is provided on the surface of a 10 cm × 6.5 cm black paper envelope, and a 10 cm × 3.5 cm sensor mount (for example, paper using the above-mentioned dye is placed in the envelope. (Stained) is inserted (see FIGS. 1 and 2). When using such a device, use it with the sensor side facing the envelope side at the time of measurement, and pull out the sensor mount at the end of measurement and insert it into the envelope with the sensor side facing the back side. However, although ultraviolet rays are not irradiated, the ultraviolet ray amount measuring device of the present invention is not limited to such a configuration.

尚、本発明の紫外線透過量測定装置は、測定シートの紫外線測定感度を高めるために、紫外線透過量測定用シートの表面側に、透明性を有する材質より成るシート体が積層され構造であっても良く、図3(a)(b)には、本発明の紫外線透過量測定装置の一例として、封筒体2の開口3側に透明性シート体5が位置するようにして、紫外線透過量測定用シート1と透明性シート体5が積層された状態で封筒体2の中に入れられた構造を有するもの((a)が正面図、(b)は右側側方から見た時の層構成を示す概略図)を例示したが、このような形態に限定されるものではなく、図1に記載される測定装置が透明性を有する材質よりなる袋体内に入れられた構造であっても良い。
本発明において、測定シートの紫外線測定感度を高めるのに適した透明シート体としては、例えば市販の無色のポリエチレンフィルム、ナイロンフィルム、セロハンフィルム、ポリ塩化ビニリデンフィルム等が挙げられ、ガラス板を使用することも可能である。
本発明では、(被試験布帛/紫外線透過量測定用シート)積層物の被試験布帛側から紫外線を照射した場合よりも、(被試験布帛/透明性シート体/紫外線透過量測定用シート)積層物の被試験布帛側から紫外線を照射した場合の方が、紫外線透過量測定用シートの変色度合いが大きくなり、これによって、短時間で感度良く被試験布帛の紫外線透過性を測定・評価することができる。
The ultraviolet ray transmission amount measuring device of the present invention has a structure in which a sheet body made of a transparent material is laminated on the surface side of the ultraviolet ray transmission amount measurement sheet in order to increase the ultraviolet ray measurement sensitivity of the measurement sheet. 3 (a) and 3 (b), as an example of the ultraviolet ray transmission amount measuring apparatus of the present invention, the ultraviolet ray transmission amount measurement is performed so that the transparent sheet body 5 is positioned on the opening 3 side of the envelope body 2. Having a structure in which the sheet 1 and the transparent sheet 5 are put in the envelope body 2 in a laminated state ((a) is a front view, (b) is a layer structure when viewed from the right side) However, the present invention is not limited to such a form, and the measurement device described in FIG. 1 may have a structure in a bag made of a transparent material. .
In the present invention, examples of the transparent sheet suitable for increasing the UV measurement sensitivity of the measurement sheet include a commercially available colorless polyethylene film, nylon film, cellophane film, polyvinylidene chloride film, and the like, and a glass plate is used. It is also possible.
In the present invention, (test fabric / transparent sheet body / ultraviolet transmission amount measurement sheet) laminate rather than the case where (UV) / UV transmission amount measurement sheet is irradiated with ultraviolet rays from the fabric under test side. When the ultraviolet ray is irradiated from the fabric side to be tested, the degree of discoloration of the ultraviolet ray transmission amount measuring sheet is increased, and thus the ultraviolet ray permeability of the fabric to be tested is measured and evaluated with high sensitivity in a short time. Can do.

前述の紫外線透過量測定用シート及び紫外線透過量測定装置を用いて被試験体の紫外線透過性を測定する本発明の方法は下記の工程A〜Cを含み、第1の工程Aにおいては、前述の紫外線透過量測定用シートを準備する。例えば、短時間紫外線照射用のシートを製造するには、前述の、紫外線カーボンアーク灯光照射20時間後における耐光性がJIS L 0842に規定されるブルースケール1級以下である酸性媒染染料(例えばC.I.モーダントグリーン17)と、硫酸アンモニウム及び界面活性剤を含む染色浴中にナイロンタフタを常温にて浸漬し、その後、徐々に昇温を行い、一定時間この温度を保持し、その後、常温まで冷却し、水洗、乾燥させる。この際、媒染は行わず、染色浴中の染料濃度は、紫外線の影響性を重視し、極淡色となるように、0.05〜0.2%owf、好ましくは0.1%owf前後であることが好ましい。   The method of the present invention for measuring the ultraviolet transmittance of a test object using the above-described ultraviolet ray transmission amount measuring sheet and ultraviolet ray transmission amount measuring apparatus includes the following steps A to C. A sheet for measuring the amount of transmitted UV light is prepared. For example, in order to produce a sheet for ultraviolet irradiation for a short time, the above-mentioned acidic mordant dye (for example, C I. Modern Green 17) and nylon taffeta are immersed in a dyeing bath containing ammonium sulfate and a surfactant at room temperature, and then gradually heated to maintain this temperature for a certain period of time. Allow to cool, wash with water and dry. At this time, mordanting is not carried out, and the dye concentration in the dyeing bath is 0.05 to 0.2% owf, preferably around 0.1% owf, so that the influence of ultraviolet rays is emphasized and an extremely light color is obtained. Preferably there is.

そして、第2の工程Bにおいては、前記工程Aで得られた紫外線透過量測定用シートの表面に、紫外線透過量を測定する対象物である被試験体を密接させた状態で積層し、この被試験体の表面に、フェードメータなどを用いて、紫外線照射部と紫外線非照射部が形成されるようにして紫外線を照射する。このときの紫外線照射時間は、被試験体の紫外線透過性と、紫外線透過量測定用シートの紫外線感度によって適宜選択されることになる。本発明では、この工程Bにおいて、紫外線透過量測定用シートと被試験体との間に、前述の透明性を有する材質より成るシート体を密着させた状態で積層させることが好ましく、このような積層状態で、紫外線照射部と紫外線非照射部が形成されるようにして紫外線を照射することにより、透明性シート体を積層しない場合よりも短時間にて、被試験布帛の紫外線透過性を測定・評価することが可能になる。   In the second step B, the surface of the ultraviolet ray transmission amount measurement sheet obtained in the step A is laminated in a state in which a test object that is an object for measuring the ultraviolet ray transmission amount is in close contact, The surface of the test object is irradiated with ultraviolet rays using a fade meter or the like so that an ultraviolet irradiation portion and an ultraviolet non-irradiation portion are formed. The ultraviolet irradiation time at this time is appropriately selected depending on the ultraviolet transmittance of the test object and the ultraviolet sensitivity of the ultraviolet ray transmission amount measuring sheet. In the present invention, in this step B, it is preferable to laminate the sheet body made of the above-described transparent material between the ultraviolet ray transmission amount measuring sheet and the test object, By irradiating ultraviolet rays so that an ultraviolet irradiation part and an ultraviolet non-irradiation part are formed in the laminated state, the ultraviolet transmittance of the test fabric is measured in a shorter time than when the transparent sheet is not laminated.・ It becomes possible to evaluate.

最後に第3の工程Cにおいては、前記工程Bにて紫外線照射された後の紫外線透過量測定用シートにおける紫外線照射部と紫外線非照射部との色差から、被試験体の紫外線透過性を評価する。この際、紫外線照射部と紫外線非照射部との色差は、目視により評価されても良いし、色測定器により機器的に評価されても良い。
以下、本発明の実施例を示すが、本発明はこれらに限定されるものではない。
Finally, in the third step C, the ultraviolet transmittance of the DUT is evaluated from the color difference between the ultraviolet ray irradiated portion and the ultraviolet ray non-irradiated portion in the ultraviolet ray transmission amount measurement sheet after the ultraviolet ray irradiation in the step B. To do. At this time, the color difference between the ultraviolet irradiation part and the ultraviolet non-irradiation part may be evaluated by visual observation, or may be evaluated by an instrument using a color measuring device.
Examples of the present invention will be described below, but the present invention is not limited thereto.

実施例I:透明性シート体を積層しない場合の本発明の紫外線透過量測定用シートによる各種試験布帛の紫外線透過性評価実験
〔本発明の紫外線透過量測定用シートの作製方法〕
シート状基材としてナイロンタフタ(ユニチカ製)を準備し、酸性媒染染料であるSunchromine Green LG(住化ケムテックス製)0.1%owf、硫酸アンモニウム2%owf、ノニオン系界面活性剤(ノイゲンHC、第一工業製薬製)1%owfなる組成を有した染色浴中に前記ナイロンタフタを20〜30℃の温度範囲にて浸漬して徐々に98℃まで昇温し、この温度を30分間保持した後、常温まで冷却し、水洗した後、乾燥させて、本発明の紫外線透過量測定用シートを得た。
Example I: Experiments for evaluating ultraviolet transmittance of various test fabrics using the sheet for measuring the amount of UV transmission of the present invention when the transparent sheet is not laminated [Method for producing sheet for measuring the amount of UV transmission of the present invention]
Nylon taffeta (manufactured by Unitika) was prepared as a sheet-like substrate, and an acid mordant dye, Sunchromine Green LG (manufactured by Sumika Chemtex) 0.1% owf, ammonium sulfate 2% owf, a nonionic surfactant (Neugen HC, No. 1) After the nylon taffeta is immersed in a temperature range of 20-30 ° C. in a dyeing bath having a composition of 1% owf, the temperature is gradually raised to 98 ° C., and this temperature is maintained for 30 minutes. After cooling to room temperature, washing with water and drying, the ultraviolet ray transmission measuring sheet of the present invention was obtained.

〔被試験布帛の作製方法〕
被試験布帛を製造するための染色液として、Chrome Yellow RCN(山田化学製)0.1%owf、Chrome Red GN−N(山田化学製)0.02%owf、Sunchromine Green LG(住化ケムテックス製)0.015%owfなる組成を有したものを調製し、この染色液中に、以下の表1に記載される素材の布帛をそれぞれ浸漬させ、媒染を行なわずに(実施例1〜3及び6)/又は媒染を行って(実施例4及び5)取り出し、水洗、乾燥させ、各被試験布帛を得た。
[Method for Fabricating Test Fabric]
As a dyeing solution for producing a fabric to be tested, Chrome Yellow RCN (manufactured by Yamada Chemical) 0.1% owf, Chrome Red GN-N (manufactured by Yamada Chemical) 0.02% owf, Sunchromine Green LG (manufactured by Sumika Chemtex) ) A composition having a composition of 0.015% owf was prepared, and the fabrics of the materials described in Table 1 below were immersed in this dyeing solution without performing mordanting (Examples 1 to 3 and 6) / Mordant (Examples 4 and 5) was taken out, washed with water and dried to obtain each fabric to be tested.

〔紫外線照射試験方法〕
前記により得た紫外線透過量測定用シートの表面に、前記の被試験布帛を2枚重ねにして積層し、紫外線照射部と紫外線非照射部が形成されるようにしてフェードメータ(スガ試験機製)を用いて被試験布帛側から120時間紫外線を照射した。
そして、紫外線照射後における2枚の被試験布帛のうちの下側に位置する布帛と、紫外線透過量測定用シートの、紫外線照射部と紫外線非照射部との色の違い(退色度合い)を目視にて評価した。尚、評価は、著しく退色の程度の大きいものを評価「1」とし、ほとんど変色のないものを「5」とし、この間の変色の程度を退色の大きいものから順に「2」、「3」、「4」として、全体で5つの区分に分類した。
この結果を以下の表1に示す。
[Ultraviolet irradiation test method]
A fade meter (manufactured by Suga Test Instruments Co., Ltd.) was formed by laminating two layers of the fabric to be tested on the surface of the ultraviolet ray transmission amount measurement sheet obtained as described above, and forming an ultraviolet irradiation part and an ultraviolet non-irradiation part. Was irradiated with ultraviolet rays for 120 hours from the fabric side to be tested.
Then, the difference in color (degree of fading) between the UV-irradiated part and the UV-irradiated part of the UV-transmitted sheet on the lower side of the two fabrics to be tested after UV irradiation and the UV non-irradiated part is visually observed. Evaluated. In the evaluation, an evaluation of “1” is given when the degree of fading is remarkably large, “5” is given when there is almost no discoloration, and “2”, “3”, As "4", it was classified into five categories as a whole.
The results are shown in Table 1 below.

Figure 2005321371
Figure 2005321371

上記表1の結果から、本発明の紫外線透過量測定用シートは、紫外線透過性の異なる各種布帛の紫外線透過性能を評価するのに適しており、紫外線透過性の程度に応じて敏感に色変化を起こすことが確認された。
又、シート状基材としてウール織物を用い、前述の紫外線透過量測定用シートの作製方法に従って本発明の紫外線透過量測定用シートを作製し、これを用いてフェードメータで720分間、紫外線照射を行ったところ、上記表1と同じ順序で紫外線透過量測定用シートの退色(変色)が生じ、退色の程度を比較することによって、被試験体(各種布帛)の紫外線透過性を簡単に測定・評価することが可能であった。
From the results of Table 1 above, the sheet for measuring the amount of UV transmission of the present invention is suitable for evaluating the UV transmission performance of various fabrics having different UV transmission, and the color changes sensitively depending on the degree of UV transmission. It was confirmed that
In addition, using a wool fabric as a sheet-like base material, the ultraviolet ray transmission amount measuring sheet of the present invention is prepared according to the above-described method for producing the ultraviolet ray transmission amount measuring sheet, and using this, the ultraviolet ray is irradiated with a fade meter for 720 minutes. As a result, fading (discoloration) of the ultraviolet ray transmission amount measuring sheet occurred in the same order as in Table 1 above, and by comparing the degree of fading, the ultraviolet transmittance of the test specimen (various fabrics) was easily measured. It was possible to evaluate.

実施例II:透明性シート体を積層した場合と積層しない場合の、本発明の紫外線透過量測定用シートによるナイロン染色織物の紫外線透過性比較実験
Sunchromine Green LG(住化ケムテックス製)1gを50〜60℃の温水約100ccに溶解させ、得られた液に水(水道水)を添加して全体を700ccとし、得られた染色液に市販の画用紙を約30秒間浸漬させた後、取り出し、紫外線の当たらない場所で常温にて乾燥させ、本発明の紫外線透過量測定用シートを作製した。又、被試験布帛については、実施例3におけるナイロン織物被試験布帛を使用し、透明シート体としては、市販の無色ポリエチレンフィルム(厚さ:40μm)を準備した。
上記の被試験布帛/透明性シート体/紫外線透過量測定用シートの積層構造を有した本発明の紫外線透過量測定装置と、上記の被試験布帛/紫外線透過量測定用シートの積層構造を有した測定装置を作製し、10〜150分間の日光照射による測定用シートの変色度合いを上記実施例Iと同様の評価基準にて評価した。その結果を以下の表2に示す。
Example II: Comparison of UV transmittance of nylon-dyed fabric with UV-transmitting sheet according to the present invention when transparent sheets were laminated and 50 g of Sunchromine Green LG (manufactured by Sumika Chemtex) Dissolve in about 100 cc of hot water at 60 ° C., add water (tap water) to the resulting solution to make 700 cc as a whole, immerse a commercially available drawing paper in the obtained dyeing solution for about 30 seconds, take out, and remove ultraviolet rays. Was dried at room temperature in a place not exposed to UV light, and the ultraviolet ray transmission amount measuring sheet of the present invention was produced. Moreover, about the fabric to be tested, the nylon fabric fabric to be tested in Example 3 was used, and a commercially available colorless polyethylene film (thickness: 40 μm) was prepared as the transparent sheet.
It has the laminated structure of the above-mentioned fabric to be tested / transparent sheet / ultraviolet ray transmission amount measuring sheet of the present invention having the laminated structure of the present invention and the above-mentioned fabric to be tested / ultraviolet ray transmission amount measuring sheet. The measurement device was prepared, and the degree of discoloration of the measurement sheet by sunlight irradiation for 10 to 150 minutes was evaluated according to the same evaluation criteria as in Example I above. The results are shown in Table 2 below.

Figure 2005321371
Figure 2005321371

上記表2の結果から、紫外線透過量測定用シートの上面に透明性シート体(無色ポリエチレンフィルム)を積層した構造の本発明の紫外線透過量測定装置は、透明性シート体が積層されていない測定装置よりも紫外線照射による測定用シートの変色度合いが大きく、上記実施例IIで使用したナイロン染色織物だけでなく、紫外線を透過しにくい各種織物(例えばコバルト媒染シルク織物、コバルト媒染ナイロン織物、ウール織物など)の紫外線透過性を短時間にて高感度で測定・評価するのに適していることが確認された。   From the results of Table 2 above, the ultraviolet transmission measuring device of the present invention having a structure in which a transparent sheet (colorless polyethylene film) is laminated on the upper surface of the ultraviolet transmission measurement sheet is a measurement in which the transparent sheet is not laminated. The degree of discoloration of the measurement sheet due to ultraviolet irradiation is larger than that of the apparatus, and not only the nylon-dyed fabric used in Example II above, but also various fabrics that are difficult to transmit ultraviolet rays (for example, cobalt mordanted silk fabric, cobalt mordanted nylon fabric, wool fabric) It has been confirmed that it is suitable for measuring and evaluating the ultraviolet transmittance of a high-sensitivity in a short time with high sensitivity.

本発明の紫外線透過量測定装置の一例を示す外観図で、(a)は、紫外線照射用開孔3が設けられた面を見た時の図であり、(b)は、その反対側の面を見た時の図である。BRIEF DESCRIPTION OF THE DRAWINGS It is an external view which shows an example of the ultraviolet-ray transmission amount measuring apparatus of this invention, (a) is a figure when seeing the surface in which the opening 3 for ultraviolet irradiation was provided, (b) is the other side. It is a figure when the surface is seen. (a)は、図1に例示した本発明の紫外線透過量測定装置の紫外線透過量測定用シート1を横方向(図面の右側方向)へ引き抜いた後の封筒体2の外観を示す図であり、(b)は、引き抜かれた紫外線透過量測定用シート1の外観を示す図である。(A) is a figure which shows the external appearance of the envelope body 2 after drawing out the ultraviolet-ray-transmission-measuring sheet | seat 1 of the ultraviolet-transmission measuring device of this invention illustrated in FIG. 1 to the horizontal direction (right side of drawing). (B) is a figure which shows the external appearance of the sheet | seat 1 for ultraviolet-ray transmission amount measurement withdrawn. 紫外線透過量測定用シート1の表面側に、透明性を有する材質より成るシート体5が積層された状態で封筒体2の中に入れられた構造の本発明の紫外線透過量測定装置の一例を示す図であり、(a)が正面図で、(b)は側方から見た時の概略図である。An example of the ultraviolet ray transmission amount measuring apparatus of the present invention having a structure in which a sheet body 5 made of a transparent material is laminated on the surface side of the ultraviolet ray transmission amount measuring sheet 1 and placed in the envelope body 2. It is a figure shown, (a) is a front view, (b) is the schematic when it sees from a side.

符号の説明Explanation of symbols

1 紫外線透過量測定用シート(紫外線透過センサー)
2 封筒体
3 紫外線照射用開孔
4 糊付け部
5 透明性シート体(透明カバーフィルム)
1 UV transmission sheet (UV transmission sensor)
2 Envelope body 3 Opening for ultraviolet irradiation 4 Gluing part 5 Transparent sheet body (transparent cover film)

Claims (7)

被試験体の紫外線透過性を測定するのに使用されるシート体であって、当該シート体を構成するシート状基材が、紫外線カーボンアーク灯光照射20時間後における耐光性がJIS L 0842に規定されるブルースケール1級以下である染料を用いて染色されていることを特徴とする紫外線透過量測定用シート。 A sheet body used to measure the ultraviolet transmittance of a test object, and the sheet-like substrate constituting the sheet body has a light resistance after 20 hours of irradiation with an ultraviolet carbon arc lamp as defined in JIS L 0842. The ultraviolet ray transmission amount measuring sheet is characterized by being dyed with a dye having a blue scale grade 1 or less. 前記染料がC.I.モーダントレッド7、C.I.モーダントバイオレット1、C.I.モーダントブルー1、C.I.モーダントブルー17、C.I.モーダントブラック1、C.I.モーダントブラック9、C.I.モーダントブラック11、C.I.モーダントブルー29、C.I.モーダントブルー3、C.I.モーダントグリーン17、C.I.モーダントグリーン28から成るグループより選ばれたものであり、当該染料が、媒染を行なうことなく前記シート状基材に染着されていることを特徴とする請求項1記載の紫外線透過量測定用シート。 The dye is C.I. I. Modern Tread 7, C.I. I. Modern Violet 1, C.I. I. Modern Blue 1, C.I. I. Modern Blue 17, C.I. I. Modern Black 1, C.I. I. Modern Black 9, C.I. I. Modern Black 11, C.I. I. Modern Blue 29, C.I. I. Modern Blue 3, C.I. I. Modern Green 17, C.I. I. 2. The ultraviolet ray transmission amount measurement according to claim 1, wherein the dye is selected from the group consisting of modern green 28, and the dye is dyed on the sheet-like substrate without mordanting. Sheet. 前記シート状基材が、ナイロン織物、カチオン化綿織物、麻織物、レーヨン織物、皮革、ウール織物、シルク織物および紙から成るグループより選ばれたものであることを特徴とする請求項1又は2記載の紫外線透過量測定用シート。 3. The sheet-like substrate is selected from the group consisting of nylon fabric, cationized cotton fabric, hemp fabric, rayon fabric, leather, wool fabric, silk fabric and paper. Sheet for measuring the amount of UV transmission. 前記請求項1〜3のいずれか1項に記載の紫外線透過量測定用シートが、紫外線非透過性の材質よりなる封筒体の中に収容されており、当該封筒体に一方の面に、少なくとも1つの紫外線照射用開孔が設けられていることを特徴とする紫外線透過量測定装置。 The ultraviolet ray transmission amount measuring sheet according to any one of claims 1 to 3 is accommodated in an envelope made of an ultraviolet non-transparent material, and at least on one surface of the envelope body An ultraviolet ray transmission amount measuring apparatus, wherein one ultraviolet ray irradiation aperture is provided. 前記紫外線透過量測定用シートの表面側に、透明性を有する材質より成るシート体が積層された構造であることを特徴とする請求項4記載の紫外線透過量測定装置。 5. The ultraviolet ray transmission amount measuring apparatus according to claim 4, wherein a sheet body made of a transparent material is laminated on the surface side of the ultraviolet ray transmission amount measuring sheet. 紫外線透過量を測定することが可能な紫外線透過量測定用シートを用いて、被試験体の紫外線透過性を測定する方法であって、当該方法が、以下の工程A〜C:
工程A:前記請求項1〜3のいずれか1項に記載の紫外線透過量測定用シートを準備する工程、
工程B:前記紫外線透過量測定用シートの表面に被試験体を密接させて積層し、前記被試験体の表面に紫外線照射部と紫外線非照射部が形成される状態で紫外線を照射する工程、及び、
工程C:前記工程Bにて紫外線照射された後の紫外線透過量測定用シートにおける紫外線照射部と紫外線非照射部との色差から、前記被試験体の紫外線透過性を評価する工程
を含むことを特徴とする紫外線透過性の測定方法。
A method for measuring the ultraviolet transmittance of a test object using an ultraviolet ray transmission amount measuring sheet capable of measuring an ultraviolet ray transmission amount, which method comprises the following steps A to C:
Step A: a step of preparing the ultraviolet ray transmission amount measuring sheet according to any one of claims 1 to 3,
Process B: A process of irradiating ultraviolet rays in a state where an ultraviolet irradiation part and an ultraviolet non-irradiation part are formed on the surface of the test object, by laminating the test object in close contact with the surface of the ultraviolet ray transmission amount measurement sheet, as well as,
Step C: including a step of evaluating the ultraviolet transmittance of the DUT from the color difference between the ultraviolet ray irradiation portion and the ultraviolet ray non-irradiation portion in the ultraviolet ray transmission amount measurement sheet after being irradiated with the ultraviolet ray in the step B. A method for measuring ultraviolet light transmittance.
前記工程Bにおいて、前記紫外線透過量測定用シートの表面に、透明性を有する材質より成るシート体を積層させてから前記被試験体を積層することを特徴とする請求項6記載の紫外線透過性の測定方法。 7. The ultraviolet ray transmitting property according to claim 6, wherein in the step B, a sheet body made of a transparent material is laminated on the surface of the ultraviolet ray transmission amount measuring sheet, and then the test object is laminated. Measuring method.
JP2004279123A 2004-04-09 2004-09-27 Ultraviolet transmission amount measurement sheet, ultraviolet transmission amount measurement device, and ultraviolet transmission measurement method using the sheet Expired - Fee Related JP4424667B2 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007327899A (en) * 2006-06-09 2007-12-20 Nippon Telegr & Teleph Corp <Ntt> Ultraviolet detecting element, and apparatus and method for measuring ultraviolet ray
WO2014002591A1 (en) * 2012-06-27 2014-01-03 シャープ株式会社 Ultraviolet detection device and electronic apparatus
JP2015117948A (en) * 2013-12-16 2015-06-25 東海光学株式会社 Lens evaluation method
CN112697682A (en) * 2020-11-27 2021-04-23 中杭监测技术研究院有限公司 Method for detecting color fastness to light of furniture based on machine vision

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007327899A (en) * 2006-06-09 2007-12-20 Nippon Telegr & Teleph Corp <Ntt> Ultraviolet detecting element, and apparatus and method for measuring ultraviolet ray
WO2014002591A1 (en) * 2012-06-27 2014-01-03 シャープ株式会社 Ultraviolet detection device and electronic apparatus
JP2015117948A (en) * 2013-12-16 2015-06-25 東海光学株式会社 Lens evaluation method
CN112697682A (en) * 2020-11-27 2021-04-23 中杭监测技术研究院有限公司 Method for detecting color fastness to light of furniture based on machine vision
CN112697682B (en) * 2020-11-27 2022-06-10 中杭监测技术研究院有限公司 Method for detecting color fastness to light of furniture based on machine vision

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