JP2005298979A - Method for transferring image by using a transfer sheet - Google Patents

Method for transferring image by using a transfer sheet Download PDF

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JP2005298979A
JP2005298979A JP2004111941A JP2004111941A JP2005298979A JP 2005298979 A JP2005298979 A JP 2005298979A JP 2004111941 A JP2004111941 A JP 2004111941A JP 2004111941 A JP2004111941 A JP 2004111941A JP 2005298979 A JP2005298979 A JP 2005298979A
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transfer
image
transfer layer
layer
transferred
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Hideo Nakanishi
秀生 中西
Shinya Ishigaki
慎也 石垣
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Daicel Corp
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Daicel Chemical Industries Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for transferring an image recorded on a transfer sheet surely on a material to be transferred, without damaging the color density of the image recorded on a colored transfer layer of the transfer sheet, and without forming disorder such as the peeling or cracking of the transfer layer transferred on the material to be transferred. <P>SOLUTION: This method for transferring the image is constituted by recording the image on the transfer layer by using a transfer sheet constituted of a substrate and the transfer layer capable of being released from the substrate, having heat-adhesion property and being colored, and then in a state of overlapping the surface side of the transfer layer, on which the image of the transfer layer is not recorded, on the material to be transferred, heating/compressing from the surface side of the material to be transferred which is not adhered with the transfer layer. Then, by heating/compressing from the surface side of the material to be transferred not adhered with the transfer layer, the transfer layer is strongly transferred, and it is possible to transfer the image together with the transfer layer on the material to be transferred without damaging the color density of the image recorded on the transfer layer together with the transfer layer. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、転写時において、画像の色濃度を損なわずに被転写体に画像を形成することができる転写シートの画像転写方法に関する。   The present invention relates to an image transfer method for a transfer sheet, which can form an image on a transfer medium without losing the color density of the image during transfer.

Tシャツなどの布地や、陶器、プラスチック製品などの表面へマーク・ロゴや画像を形成する方法として、転写シート、すなわち基材上に熱溶融性樹脂で構成された剥離可能な転写層が形成されたシートを用いる方法が汎用されている。この方法は、転写シートの転写層に画像を記録した後、その転写層を基材から加熱によって溶融剥離させて布帛などの被転写体に熱転写することにより、被転写体に画像を形成する方法である。特に、転写シートを用いた画像形成方法は、電子写真方式の記録方式やインクジェット記録方式などのカラー複写機やカラープリンターにより、画像のフルカラー化が容易であり、また直接プリンターで印刷できない各種メディアに対しても画像形成が可能になるため、このような転写シートを利用した様々なメディアへの画像形成が注目されている。転写シートを用いた画像形成では、被転写体の種類によらず鮮明な画像が形成できる必要があり、例えば、濃色の被転写体であっても鮮明な画像が形成できることが要求される。   As a method of forming marks, logos and images on the surface of T-shirts and other fabrics, ceramics, plastic products, etc., a transfer sheet, that is, a peelable transfer layer made of a heat-melting resin, is formed on the substrate. A method using a sheet is widely used. In this method, after an image is recorded on a transfer layer of a transfer sheet, the transfer layer is melt-peeled by heating from a base material and thermally transferred to a transfer material such as a cloth, thereby forming an image on the transfer material. It is. In particular, the image forming method using a transfer sheet is easy to make full-color images with color copying machines and color printers such as an electrophotographic recording method and an ink jet recording method. On the other hand, since image formation becomes possible, image formation on various media using such a transfer sheet has attracted attention. In image formation using a transfer sheet, it is necessary to form a clear image regardless of the type of transfer target. For example, it is required that a clear image can be formed even with a dark transfer target.

転写シートを用いて被転写体に形成された画像の鮮明度や色合いは、被転写体の色に影響を受ける。特に、被転写体が黒色などの濃色の場合には、その影響が大きい。このため、被転写体の色を隠蔽する性能を有する転写シートを使用して被転写体に画像を形成する方法が提案されている。   The sharpness and color tone of the image formed on the transfer medium using the transfer sheet are affected by the color of the transfer medium. In particular, when the transfer target is a dark color such as black, the influence is large. For this reason, a method has been proposed in which an image is formed on a transfer medium using a transfer sheet having a performance of hiding the color of the transfer object.

例えば、特開2002−248875号公報(特許文献1)には、基材と、この基材に対して剥離可能な転写層とで構成された転写シートであって、転写層が接着層と受像層とで構成されており、接着層及び受像層のうち少なくとも一方の層に白色隠蔽剤が含まれている正画像型の転写シートを用いて、この転写シートの受像層に画像を記録した後、基材を接着層から剥離し、接着層の剥離面と被転写体とを接触させて、受像層をアイロンなどの加熱摺動部材で加圧及び加温して、記録画像を熱転写する方法が開示されている。   For example, Japanese Patent Application Laid-Open No. 2002-248875 (Patent Document 1) discloses a transfer sheet composed of a base material and a transfer layer that can be peeled off from the base material. After recording an image on the image receiving layer of this transfer sheet using a positive image type transfer sheet comprising a white hiding agent in at least one of the adhesive layer and the image receiving layer. A method of thermally transferring a recorded image by peeling a base material from an adhesive layer, bringing the release surface of the adhesive layer into contact with a transfer target, and pressurizing and heating the image receiving layer with a heating sliding member such as an iron. Is disclosed.

特許文献1記載の方法では、被転写体の色の影響を受けずに画像形成ができる。しかし、転写シートを使って布帛などの被転写体に画像を良好に形成するためには、転写シートに適度な加熱温度と圧力を加えながら、転写層を軟化・溶融させて、被転写体に対して十分に転写層を接着させる必要があるため、この方法では、加熱・加圧によって転写層が軟化・溶融し、記録した画像が転写層(特に、受像層に白色隠蔽剤を含む転写層)に沈み込んでしまい、転写層とともに被転写体に転写された画像の色濃度が損なわれる問題がある。また、画像の色濃度を損なわないように、加熱・加圧の条件を弱めに行った場合には、色濃度が損なわれる程度は軽減するが、被転写体に対する転写層の接着状態が弱くなるため、この方法では、転写時及び転写後において、転写画像の剥離やひび割れ(洗濯後のひび割れなど)などが生じるおそれがあり、布地などの被転写体に対して確実に画像を転写することは困難である。   In the method described in Patent Document 1, an image can be formed without being affected by the color of the transfer target. However, in order to satisfactorily form an image on a transfer medium such as a fabric using a transfer sheet, the transfer layer is softened and melted while applying an appropriate heating temperature and pressure to the transfer sheet, and the transfer sheet is formed. In this method, since the transfer layer needs to be sufficiently adhered to the transfer layer, the transfer layer is softened and melted by heating and pressurizing, and the recorded image is transferred to the transfer layer (particularly, the transfer layer containing a white hiding agent in the image receiving layer). ) And the color density of the image transferred to the transfer medium together with the transfer layer is impaired. In addition, when the heating and pressurizing conditions are weakened so as not to impair the color density of the image, the degree to which the color density is impaired is reduced, but the adhesion state of the transfer layer to the transfer target is weakened. Therefore, in this method, there is a risk that the transferred image may be peeled off or cracked (crack after washing, etc.) during and after transfer, and the image can be reliably transferred to the transfer target such as cloth. Have difficulty.

特開2002−248875号公報(請求項14、段落番号[0113])JP 2002-248875 A (claim 14, paragraph number [0113])

従って、本発明の目的は、色濃度を損なわずに、転写シートに記録された画像を確実に被転写体に転写する方法を提供することにある。   Accordingly, an object of the present invention is to provide a method for reliably transferring an image recorded on a transfer sheet to a transfer medium without impairing color density.

本発明の他の目的は、長期に亘って使用しても被転写体に転写した画像の剥離やひび割れなどの障害を生じないように、転写シートに記録された画像を被転写体に転写する方法を提供することにある。   Another object of the present invention is to transfer an image recorded on a transfer sheet to a transferred material so that the image transferred to the transferred material is not peeled off or cracked even when used for a long time. It is to provide a method.

本発明者らは、前記課題を達成するため鋭意検討した結果、転写シートの転写時に被転写体側から加熱することにより、転写時および転写後において画像の色濃度が損なわれることなく、画像を布地などの被転写体に形成できることを見いだし、本発明を完成した。   As a result of intensive investigations to achieve the above-mentioned problems, the inventors of the present invention heated the transfer sheet from the transfer target side during transfer of the transfer sheet, thereby preventing the image color density from being impaired during transfer and after transfer. Thus, the present invention has been completed.

すなわち、本発明の画像転写方法は、基材とこの基材に対して剥離可能でかつ着色されている転写層とで構成されており、前記転写層が受像可能でありかつ熱接着性を有する転写シートを用いてその転写層の一方の面側に画像を記録した後、転写層とともに画像(マーク・ロゴや文字を含む)を被転写体に転写する方法であって、転写層から基材を剥離した後、前記転写層の画像を記録していない面側を被転写体に接触させ、次いで転写層と被転写体とを密着させた状態で被転写体側から加熱して、前記転写層を被転写体に熱接着させて画像を被転写体に転写する方法であってもよい。   That is, the image transfer method of the present invention comprises a substrate and a transfer layer that is peelable and colored with respect to the substrate, and the transfer layer can receive an image and has thermal adhesiveness. A method of recording an image on one side of a transfer layer using a transfer sheet, and then transferring the image (including marks, logos and characters) together with the transfer layer to a transfer medium, from the transfer layer to the substrate The surface of the transfer layer on which the image is not recorded is brought into contact with the transfer target, and then the transfer layer is heated from the transfer target side in a state where the transfer layer and the transfer target are in close contact with each other. Alternatively, the image may be transferred to the transfer body by thermally bonding the image to the transfer body.

前記転写層に画像を記録する方法は、インクジェット記録方式(ノズルから転写層に向けてインク小滴を飛翔させるインクジェット方式など)、熱溶融転写記録方式、昇華型熱転写記録方式、電子写真記録方式(カラー複写機やカラーレーザーブリンターなど)の記録方式を用いて画像を記録する方法であってもよい。   A method for recording an image on the transfer layer includes an ink jet recording method (such as an ink jet method in which ink droplets are ejected from a nozzle toward the transfer layer), a hot melt transfer recording method, a sublimation thermal transfer recording method, an electrophotographic recording method ( A method of recording an image using a recording method of a color copying machine or a color laser printer) may be used.

また前記被転写体側からの加熱方法は、被転写体の転写層と密着していない面側から加熱体を接触させて加熱する方法、例えば、熱転写可能な温度(例えば80〜200℃)に調節された加熱体を被転写体の転写層と密着していない面側から適度な圧力(980〜98000Pa程度)で押し当てながら加熱する方法などであってもよい。また加熱時には、必要に応じて転写層の画像を記録した面側に離型紙の離型処理面を接触させた状態で加熱し、加熱後に前記離型紙を剥離して画像を転写する方法であってもよい。   Further, the heating method from the transferred body side is adjusted to a method in which the heated body is heated from the surface side not in close contact with the transfer layer of the transferred body, for example, a temperature at which heat transfer is possible (for example, 80 to 200 ° C.). For example, a method may be used in which the heated body is heated while being pressed with an appropriate pressure (about 980 to 98000 Pa) from the side of the transfer target that is not in close contact with the transfer layer. In addition, during heating, if necessary, heating is performed with the release processing surface of the release paper in contact with the surface on which the image of the transfer layer is recorded, and the image is transferred by peeling the release paper after heating. May be.

前記転写シートは、基材と、この基材に対して剥離可能な転写層とで構成されており、前記転写層はその一部分または全部が着色(例えば、白色に着色)されていてもよく、また前記転写層は画像が記録可能な受像層と熱接着性を有する接着層とで構成されていてもよく、前記受像層が着色されていてもよい。   The transfer sheet is composed of a base material and a transfer layer that can be peeled from the base material, and the transfer layer may be partially or entirely colored (for example, colored white), The transfer layer may be composed of an image receiving layer capable of recording an image and an adhesive layer having thermal adhesiveness, and the image receiving layer may be colored.

本発明の画像転写方法は、着色された転写層で構成された転写シートを用いて、転写層の一方の面側に記録された画像を被転写体に転写する方法であって、前記転写層の他方の面側を被転写体に接触させて被転写体の転写位置に仮止めした後、転写層と被転写体を密着させた状態で被転写体側から加熱して、転写層を被転写体に熱接着させて画像を被転写体に転写する方法であってもよい。   The image transfer method of the present invention is a method for transferring an image recorded on one side of a transfer layer to a transfer medium using a transfer sheet composed of a colored transfer layer, the transfer layer The other surface side of the substrate is brought into contact with the transfer body and temporarily fixed at the transfer position of the transfer body, and then the transfer layer is heated from the transfer body side while the transfer layer and the transfer body are in close contact with each other to transfer the transfer layer. A method may be used in which an image is transferred to a transfer target body by heat bonding to the body.

前記仮止め方法は、転写層の熱接着性を利用して、転写層に熱接着性が生じる程度の比較的低い温度で加熱して熱接着する方法であってもよい。転写層を熱接着により仮止めするときは、転写層と被転写体とを加熱圧着してもよい。   The temporary fixing method may be a method in which heat bonding is performed by heating at a relatively low temperature to the extent that thermal adhesion occurs in the transfer layer, using the heat bonding property of the transfer layer. When the transfer layer is temporarily fixed by thermal bonding, the transfer layer and the transfer target may be thermocompression bonded.

本発明は、着色された転写層で構成された転写シートを用いて、転写層の一方の面側に記録された画像を被転写体に転写する方法であって、前記転写層の他方の面側を被転写体に接触させた後、転写層と被転写層を密着させた状態で被転写体側から加熱し、転写層の画像を記録した面側の温度及び/またはその温度変化を測定し、測定した温度及び/またはその温度変化に応じて被転写体側からの加熱温度を調節して、転写層を被転写体に熱接着させて画像を被転写体に転写する方法であってもよい。   The present invention relates to a method for transferring an image recorded on one side of a transfer layer to a transfer medium using a transfer sheet composed of a colored transfer layer, the other side of the transfer layer. After the side is brought into contact with the transfer target, the transfer layer and the transfer target layer are heated so that the transfer layer and the transfer target layer are in close contact with each other. Alternatively, a method may be used in which the temperature is measured and / or the heating temperature from the transfer target is adjusted according to the temperature change, and the transfer layer is thermally bonded to the transfer target to transfer the image to the transfer target. .

前記加熱温度を測定する方法は、例えば接触式や非接触式の通常用いられている温度測定方法を用いてもよい。   As the method for measuring the heating temperature, for example, a contact-type or non-contact type temperature measurement method that is usually used may be used.

本発明の転写シートの画像転写方法では、被転写体側から加熱して熱転写するので、色濃度を損なうことなく画像を被転写体に転写できる。また、本発明の転写シートの画像転写方法では、転写前に転写層を被転写体の転写位置に仮止めするので、転写位置がずれることなく画像を被転写体に転写できる。さらに、本発明の転写シートの画像転写方法では、転写層の画像を記録した面側の温度によって転写時の加熱を調整するので、適切な温度条件で画像が転写でき、長期に亘って使用しても、被転写体に形成した画像の剥離やひび割れなどの障害を生じることなく、安定した画像を転写可能である。   In the image transfer method of the transfer sheet of the present invention, heat transfer is performed by heating from the transfer target side, so that the image can be transferred to the transfer target without impairing the color density. Further, in the image transfer method of the transfer sheet of the present invention, the transfer layer is temporarily fixed at the transfer position of the transfer target before transfer, so that the image can be transferred to the transfer target without shifting the transfer position. Furthermore, in the image transfer method of the transfer sheet of the present invention, the heating during transfer is adjusted by the temperature of the surface on which the image of the transfer layer is recorded, so that the image can be transferred under an appropriate temperature condition and used for a long time. However, a stable image can be transferred without causing problems such as peeling or cracking of the image formed on the transfer target.

[画像転写方法]
本発明の画像転写方法は、基材とこの基材に対して剥離可能でかつ着色されている転写層とで構成されており、前記転写層が受像可能でありかつ熱接着性を有する転写シートを用いて転写層の一方の面側に画像を記録した後、転写層とともに前記画像を被転写体に転写する方法であって、転写層から基材を剥離して前記転写層の画像を記録していない面側を被転写体に接触させ、次いで転写層と被転写体とを密着させた状態で被転写体側から加熱して、前記転写層を被転写体に熱接着させて画像を被転写体に転写する方法である。前記転写層は、その一部又は全部が着色されていてもよい。前記転写シートは、基材と、基材に対して剥離可能な転写層で構成されていてもよく、転写層を被転写体に接触させる前に、転写シートから基材を剥離した後、転写層の基材を剥離した側の面と被転写体を接触させて、上記転写方法により画像を被転写体に転写する方法であってもよい。
[Image transfer method]
The image transfer method of the present invention comprises a base material and a transfer layer that is peelable and colored with respect to the base material. The transfer sheet is capable of receiving an image and has thermal adhesiveness. After recording an image on one side of the transfer layer using a transfer layer, the image is transferred to the transfer target body together with the transfer layer, and the image of the transfer layer is recorded by peeling the substrate from the transfer layer. The uncoated surface side is brought into contact with the transfer target, and then the transfer layer and the transfer target are in close contact with each other and heated from the transfer target side to thermally bond the transfer layer to the transfer target and cover the image. This is a method of transferring to a transfer body. A part or all of the transfer layer may be colored. The transfer sheet may be composed of a base material and a transfer layer that can be peeled off from the base material. Before the transfer layer is brought into contact with the transfer target, the base material is peeled off from the transfer sheet, and then transferred. A method may be used in which the surface of the layer from which the substrate is peeled is brought into contact with the transfer target, and the image is transferred to the transfer target by the transfer method described above.

本発明の画像転写方法は、基材とこの基材に対して剥離可能でかつ着色されている転写層とで構成されており、前記転写層が受像可能でありかつ熱接着性を有する転写シートを用いて、前記記録方法などにより転写層の一方の面側に記録された画像を転写層とともに被転写体に転写する方法であって、前記転写層の他方の面側を被転写体に接触させて転写層を被転写体の転写位置に仮止めした後、転写層と被転写体を密着させた状態で被転写体側から加熱して、転写層と被転写層とを熱接着して、画像を被転写体に転写する方法であってもよい。   The image transfer method of the present invention comprises a base material and a transfer layer that is peelable and colored with respect to the base material. The transfer sheet is capable of receiving an image and has thermal adhesiveness. And transferring the image recorded on one side of the transfer layer together with the transfer layer to the transfer body using the recording method or the like, wherein the other side of the transfer layer is in contact with the transfer body After temporarily fixing the transfer layer to the transfer position of the transfer target, heat the transfer layer and the transfer target in a state where the transfer layer and the transfer target are in close contact, and thermally bond the transfer layer and the transfer target layer. A method of transferring an image to a transfer target may be used.

また本発明の画像転写方法は、一部又は全部が着色された転写層で構成された転写シートを用いて、転写層の一方の面側に記録された画像を被転写体に転写する方法であって、前記転写層の他方の面側を被転写体に接触させ、次いで転写層の画像を記録した面側の温度を測定しながら、転写層と被転写層を密着させた状態で被転写体側から加熱し、前記温度の測定値及び/またはその変化によって前記加熱を調節して、転写層と被転写層とを熱接着する工程で構成されている画像を被転写体に転写する方法であってもよい。   The image transfer method of the present invention is a method of transferring an image recorded on one surface side of a transfer layer to a transfer medium using a transfer sheet composed of a transfer layer partially or entirely colored. The transfer layer is in contact with the transfer layer while the other surface side of the transfer layer is brought into contact with the transfer target, and then the temperature of the transfer layer on which the image is recorded is measured. A method of transferring an image formed by a process of heating from the body side and adjusting the heating according to the measured value of the temperature and / or a change thereof to thermally bond the transfer layer and the transfer layer to the transfer target. There may be.

(画像記録方法)
本発明の画像転写方法に用いられる転写層への画像記録の方法としては、例えば油性、水性又はインキペンなどのよって筆記具によって、転写前の転写層に画像(マーク・ロゴや文字含む)を記録する方法の他、インクジェット記録方式(ノズルからシートに向けてインク小滴を飛翔させるインクジェット方式など)、熱溶融転写方式、昇華型熱転写方式、電子写真方式(例えば、カラー複写機やカラーレーザープリンターなどのトナー画像を記録する方式)などが例示できる。
(Image recording method)
As a method for recording an image on the transfer layer used in the image transfer method of the present invention, an image (including marks, logos, and characters) is recorded on the transfer layer before transfer with a writing instrument such as oil-based, water-based, or ink pen. In addition to methods, inkjet recording methods (such as inkjet methods that eject ink droplets from nozzles to sheets), thermal melt transfer methods, sublimation thermal transfer methods, and electrophotographic methods (for example, color copiers and color laser printers) Examples thereof include a method for recording a toner image.

(加熱方法)
前記被転写体側から加熱する方法は、転写時に転写層の画像が記録された面側から加熱する方法以外の加熱方法であればよく、特に限定されないが、例えば転写層と被転写体を接触させた後に被転写体の転写層と密着していない面側から熱転写可能な温度で加熱する方法であってもよく、転写層と被転写体とを密着させた状態で被転写体自体を加熱する方法であってもよく、また予め加熱した被転写体を転写層に密着させることにより加熱する方法であってもよい。
(Heating method)
The method of heating from the transferred material side is not particularly limited as long as it is a heating method other than the method of heating from the surface side on which the image of the transfer layer is recorded at the time of transfer. For example, the transfer layer and the transferred material are brought into contact with each other. After that, heating may be performed at a temperature at which heat transfer can be performed from the side of the transfer target that is not in close contact with the transfer layer. It may be a method, or may be a method in which a previously heated object to be transferred is heated by bringing it into close contact with the transfer layer.

前記の転写層と被転写体を接触させた後に被転写体の転写層と密着していない面側に大して加熱する方法としては、熱転写可能な温度、例えば80〜200℃、好ましくは100〜180℃、さらに好ましくは110〜150℃の温度に調節された加熱体を、被転写体の転写層と密着していない面側に接触させ、適度な圧力、例えば980〜98000Pa程度、好ましくは5000〜80000Pa、さらに好ましくは10000〜60000Paの圧力で、被転写体に押し当てながら加熱する方法であってもよい。前記加熱体としては、ヒートプレス装置の熱板、業務用や家庭用のアイロンなどが例示できる。前記加熱体による加熱時間は、熱転写可能な時間であれば特に限定されず、また加熱時の温度や圧力にもよるが、通常、加熱体を被転写体に接触させてから起算して、例えば、3秒以上(3〜120秒)、好ましくは5秒〜60秒程度であってもよい。   As a method of heating the transfer layer and the transfer target after contact with the transfer layer, the surface of the transfer target that is not in close contact with the transfer layer is heated to a temperature at which heat transfer is possible, for example, 80 to 200 ° C., preferably 100 to 180. A heating body adjusted to a temperature of 100 ° C., more preferably 110 to 150 ° C., is brought into contact with the surface of the transfer target that is not in close contact with the transfer layer, and an appropriate pressure, for example, about 980 to 98000 Pa, preferably 5000 to It may be a method of heating while pressing against the transfer body at a pressure of 80000 Pa, more preferably 10000 to 60000 Pa. Examples of the heating body include a hot plate of a heat press device, and a business or household iron. The heating time by the heating body is not particularly limited as long as it can be thermally transferred, and depends on the temperature and pressure at the time of heating, but is usually calculated after bringing the heating body into contact with the transferred body, for example, It may be 3 seconds or longer (3 to 120 seconds), preferably about 5 seconds to 60 seconds.

(仮止め方法)
前記仮止め方法は、熱転写工程において、転写層を被転写体の転写したい位置(転写位置)に固定されておればよく、機械的な手段も用いた固定方法、接着・粘着手段を用いた固定方法、転写層の熱接着性を利用した固定方法などの方法であってもよい。前記機械的な手段も用いた固定方法としては、例えば転写層を被転写体の転写位置に重ねた状態でそれらをクリップや止めピンなどを用いて、転写層を被転写体の転写位置に固定する方法が例示できる。前記接着・粘着手段を用いた固定方法としては、例えば転写層を被転写体の転写位置に重ねた状態で粘着テープや接着剤などを用いて転写層を被転写体の転写位置に固定方法が例示できる。また前記転写層の熱接着性を利用して固定する方法として、例えば転写層を、熱接着性が発現する程度の比較的低い温度で加熱して、被転写体に仮接着する固定方法が例示できる。前記熱接着性を利用して仮接着する方法としては、転写層を熱接着可能な温度、例えば60〜180℃、好ましくは80〜160℃、さらに好ましくは100〜150℃の温度に調節された加熱体を、被転写体の転写層と密着していない面側に接触させ、適度な圧力、例えば980〜98000Pa程度、好ましくは5000〜80000Pa、さらに好ましくは10000〜60000Paの圧力で、被転写体に押し当てながら仮接着する方法であってもよい。前記加熱体としては、ヒートプレス装置の熱板、業務用や家庭用のアイロンなどが例示できる。前記加熱体による加熱時間は、熱転写可能な時間であれば特に限定されず、また加熱時の温度や圧力にもよるが、通常、加熱体を被転写体に接触させてから起算して、例えば、1秒以上(1〜60秒)、好ましくは3秒〜30秒程度であってもよい。これらの仮止め方法のうち、転写シート以外の部材を部分的に介在させることによる転写時の部分的な加熱不良や仮止め部材による転写後の画像損傷や転写部位の風合い不良が生じるおそれがない、転写層の熱接着性を利用した仮止め方法が好ましい。
(Temporary fixing method)
In the thermal transfer process, the temporary fixing method may be as long as the transfer layer is fixed at a position (transfer position) where the transfer target is desired to be transferred, a fixing method using mechanical means, or fixing using an adhesive / adhesive means. It may be a method such as a method or a fixing method utilizing the thermal adhesiveness of the transfer layer. As a fixing method using the mechanical means, for example, with the transfer layer superimposed on the transfer position of the transfer target, the transfer layer is fixed to the transfer position of the transfer target using a clip or a stop pin. The method of doing can be illustrated. As the fixing method using the adhesive / adhesive means, for example, there is a method of fixing the transfer layer to the transfer position of the transfer object using an adhesive tape or an adhesive in a state where the transfer layer is superimposed on the transfer position of the transfer object. It can be illustrated. Further, as a method for fixing using the thermal adhesiveness of the transfer layer, for example, a fixing method in which the transfer layer is heated at a relatively low temperature to the extent that thermal adhesiveness is exhibited and temporarily bonded to the transfer target is exemplified. it can. As a method of temporary bonding using the thermal adhesiveness, the temperature at which the transfer layer can be thermally bonded, for example, 60 to 180 ° C., preferably 80 to 160 ° C., more preferably 100 to 150 ° C. was adjusted. The heated body is brought into contact with the surface of the transfer target that is not in close contact with the transfer layer, and the transfer target is subjected to an appropriate pressure, for example, about 980 to 98000 Pa, preferably 5000 to 80000 Pa, more preferably 10,000 to 60000 Pa. It may be a method of temporarily adhering while pressing. Examples of the heating body include a hot plate of a heat press device, and a business or household iron. The heating time by the heating body is not particularly limited as long as it can be thermally transferred, and depends on the temperature and pressure at the time of heating, but is usually calculated after bringing the heating body into contact with the transferred body, for example, It may be 1 second or longer (1 to 60 seconds), preferably about 3 seconds to 30 seconds. Among these temporary fixing methods, there is no risk of partial heating failure during transfer due to partial interposition of members other than the transfer sheet, image damage after transfer due to the temporary fixing member, and poor texture of the transfer site. A temporary fixing method using the thermal adhesiveness of the transfer layer is preferred.

(温度測定方法)
前記温度を測定する方法は、転写層の画像を記録した表面の温度を測定できる測定方法であれば、特に限定されず、例えば接触式(例えば、熱電対方式など)及び非接触式(例えば、放射型温度計方式など)の通常用いられている温度測定方法が例示でき、これらの測定方法は、転写の態様に応じて適宜選択してもよい。温度の測定位置は、転写層の全面を測定するのが好ましいが、適当な間隔を設けて、スポットで測定してもよい。転写時に加熱体と転写層との間に、離型性シート状基材(例えば、離型処理紙など)を介在させる場合は、その離型性シート状基材の表面温度を測定することで代替してもよい。また、温度測定では、温度とその温度変化を測定し、その測定値(温度および/又はその温度変化の値)に応じて、転写時の加熱を調整してもよい。加熱を調整する方法としては、例えば加熱源として電気回路で加熱調整する加熱装置を用いて熱転写する場合、測定温度および/又はその測定温度の変化の値を電気信号として前記加熱装置の電気回路に送信し、前記電気信号を受診した電気回路は、その電気信号に応じて加熱装置の加熱状態を高低させて調整する加熱方法が例示できる。このように、転写層の画像を記録した面側の温度および/又はその温度変化に応じて、転写時の加熱温度を調整しながら転写できるので、色濃度を損なわない、より良好な画像を被転写体に転写することができる。
(Temperature measurement method)
The method for measuring the temperature is not particularly limited as long as it can measure the temperature of the surface on which the image of the transfer layer is recorded. For example, a contact type (for example, thermocouple method) and a non-contact type (for example, Examples of the temperature measuring method that is usually used (radiation type thermometer method, etc.) can be exemplified, and these measuring methods may be appropriately selected according to the mode of transfer. The temperature measurement position is preferably measured over the entire surface of the transfer layer, but may be measured with a spot at an appropriate interval. When a releasable sheet-like substrate (for example, release treated paper) is interposed between the heating body and the transfer layer during transfer, the surface temperature of the releasable sheet-like substrate is measured. It may be replaced. In the temperature measurement, the temperature and its temperature change may be measured, and the heating during transfer may be adjusted according to the measured value (temperature and / or value of the temperature change). As a method for adjusting the heating, for example, when thermal transfer is performed using a heating device that adjusts the heating with an electric circuit as a heating source, the measured temperature and / or the value of the change in the measured temperature is used as an electric signal in the electric circuit of the heating device. The electric circuit which transmitted and received the said electrical signal can illustrate the heating method which raises and lowers the heating state of a heating apparatus according to the electrical signal. In this way, transfer can be performed while adjusting the heating temperature at the time of transfer according to the temperature of the surface on which the image of the transfer layer is recorded and / or the temperature change thereof, so that a better image that does not impair the color density is covered. It can be transferred to a transfer body.

以下に、本発明に用いられる転写シート及び画像記録方法を例示する。   The transfer sheet and image recording method used in the present invention are exemplified below.

[転写シート]
本発明に用いられる転写シートは、画像記録可能で、熱接着性を有する転写層で構成されており、前記転写層の一部又は全部が着色されている転写シートが用いられる。前記転写層は、画像記録可能な受像層、着色剤(例えば、白色顔料など)とバインダー樹脂を含む着色層、熱接着性を有する接着層で構成されていてもよく、またこれらの層の機能を併合する層で構成されていてもよい。また、前記転写シートは、基材と、基材に対して剥離可能な転写層で構成されていてもよい。
[Transfer sheet]
The transfer sheet used in the present invention is composed of a transfer layer capable of recording an image and having thermal adhesiveness, and a transfer sheet in which a part or all of the transfer layer is colored is used. The transfer layer may be composed of an image-receiving layer capable of recording an image, a colored layer containing a colorant (for example, a white pigment) and a binder resin, and an adhesive layer having thermal adhesion, and functions of these layers. May be composed of layers merging each other. Moreover, the said transfer sheet may be comprised by the transfer layer which can peel with respect to a base material and a base material.

(基材)
基材は、例えば、紙類、布(織布や不織布等)、化学繊維紙、合成紙、プラスチックフィルムなどが挙げられ、通常、離型性基材、例えば、離型処理紙(離型紙)、離型処理していてもよい合成紙、化学繊維紙、プラスチックフィルムなどが用いられている。
(Base material)
Examples of the base material include paper, cloth (woven fabric, non-woven fabric, etc.), chemical fiber paper, synthetic paper, plastic film, and the like, and usually a releasable base material such as release treated paper (release paper). Synthetic paper, chemical fiber paper, plastic film, etc., which may be subjected to release treatment, are used.

(転写層)
転写層は、通常、ホットメルト接着性樹脂を含んでいる。ホットメルト接着性樹脂の形状は、限定されないが、粒子状であってもよい。転写層に含まれるホットメルト接着性樹脂(接着性粒子を含む)としては、ポリアミド系樹脂、熱可塑性ポリウレタン系樹脂、ポリエステル系樹脂、オレフィン系樹脂などが例示でき、これらのうち単独で又は2種以上を組み合わせてもよい。ホットメルト接着性樹脂の融点または軟化点は、特に限定されないが、40〜200℃、好ましくは60〜150℃程度である。
(Transfer layer)
The transfer layer usually contains a hot melt adhesive resin. The shape of the hot melt adhesive resin is not limited, but may be particulate. Examples of the hot melt adhesive resin (including adhesive particles) contained in the transfer layer include polyamide resins, thermoplastic polyurethane resins, polyester resins, olefin resins, and the like. The above may be combined. The melting point or softening point of the hot-melt adhesive resin is not particularly limited, but is about 40 to 200 ° C, preferably about 60 to 150 ° C.

前記転写層は、その一部又は全部が着色されており、例えば着色剤(例えば、白色顔料など)とバインダー樹脂を含み、転写層の白色度を高めたり、被転写体の色を隠蔽する性能を有していてもよい。   The transfer layer is partly or entirely colored, and includes, for example, a colorant (for example, a white pigment) and a binder resin, and increases the whiteness of the transfer layer or conceals the color of the transfer target. You may have.

前記転写層は、前記ホットメルト接着性樹脂(前記接着性粒子を含む)の他、成膜性樹脂成分(親水性高分子、ウレタン系樹脂、熱硬化性又は架橋性樹脂など)や、染料定着剤[カチオン性化合物(低分子染料固着剤)、高分子染料固着剤など]などで構成されている場合が多い。   In addition to the hot-melt adhesive resin (including the adhesive particles), the transfer layer includes a film-forming resin component (such as a hydrophilic polymer, a urethane-based resin, a thermosetting or cross-linkable resin), and a dye fixing. It is often composed of an agent [cationic compound (low molecular dye fixing agent), high molecular dye fixing agent, etc.].

また、転写層は、必要に応じて、各種添加剤(安定化剤(酸化防止剤、紫外線吸収剤、熱安定化剤など)、染料、顔料、帯電防止剤、難燃剤、滑剤、アンチブロッキング剤、充填剤、着色剤、消泡剤、塗布性改良剤、増粘剤など)を含んでいてもよい。   In addition, the transfer layer may contain various additives (stabilizers (antioxidants, ultraviolet absorbers, heat stabilizers, etc.), dyes, pigments, antistatic agents, flame retardants, lubricants, antiblocking agents as necessary. , Fillers, colorants, antifoaming agents, applicability improvers, thickeners, etc.).

転写層の厚みは、例えば、10〜300μm、好ましくは20〜250μm、さらに好ましくは30〜200μm程度である。   The thickness of the transfer layer is, for example, about 10 to 300 μm, preferably about 20 to 250 μm, and more preferably about 30 to 200 μm.

[被転写体]
被転写体としては、繊維、紙、木材、プラスチック、セラミックス、金属などの種々の材料で形成された二次元又は三次元構造物が例示できる。本発明では、布(例えば、Tシャツなど)、プラスチックフィルム・シートや紙(特に布)を被転写体として好適に利用できる。
[Transfer]
Examples of the transfer target include two-dimensional or three-dimensional structures formed of various materials such as fiber, paper, wood, plastic, ceramics, and metal. In the present invention, a cloth (for example, a T-shirt), a plastic film sheet, or paper (particularly a cloth) can be suitably used as the transfer target.

本発明の画像転写方法は、電子写真方式などにより画像を記録できる転写シートを用いて、布地などの被転写体に画像を転写する方法として有効に利用できる。   The image transfer method of the present invention can be effectively used as a method of transferring an image to a transfer medium such as a fabric using a transfer sheet capable of recording an image by an electrophotographic method or the like.

以下に、実施例に基づいて本発明をより詳細に説明するが、本発明はこれらの実施例によって限定されるものではない。なお、文中、特に断わりのない限り、「部」とは「重量部」を意味する。また、実施例及び比較例で用いた転写シート、被転写体及び読取用原稿は次の通りである。さらに、実施例及び比較例の画像転写方法によって転写シートの転写層(受像層と接着層とで構成された層)とともに被転写体に転写された画像の各種特性の評価法は次の通りである。   Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited to these examples. In the text, “parts” means “parts by weight” unless otherwise specified. In addition, the transfer sheet, the transfer target, and the reading document used in Examples and Comparative Examples are as follows. Furthermore, evaluation methods for various characteristics of images transferred to a transfer medium together with a transfer layer (a layer composed of an image receiving layer and an adhesive layer) of a transfer sheet by the image transfer methods of Examples and Comparative Examples are as follows. is there.

[転写シート]
転写シートは、基材と、白色の転写層とで構成された転写層を用いた。前記転写層は受像層と接着層とで構成されており、転写シートの基材、接着層及び受像層の内容は次の通りである。
[Transfer sheet]
As the transfer sheet, a transfer layer composed of a base material and a white transfer layer was used. The transfer layer is composed of an image receiving layer and an adhesive layer. The contents of the substrate, the adhesive layer and the image receiving layer of the transfer sheet are as follows.

(基材)
基材:離型処理した紙(リンテック(株)製、SGP85OKT−T、坪量:100g/m2、厚み:90μm)
(Base material)
Substrate: Release-treated paper (manufactured by Lintec Corporation, SGP85OKT-T, basis weight: 100 g / m 2 , thickness: 90 μm)

(接着層)
前記基材の離型処理面側に、ポリエステル系ウレタン樹脂溶液A[大日精化工業(株)製、レザミンUD1305、溶剤:ジメチルホルムアミド/メチルエチルケトン=40/60(重量比)、固形分50重量%、軟化温度95℃]80部とポリエステル系ウレタン樹脂溶液B[大日精化工業(株)製、レザミンME3119LP、溶剤:ジメチルホルムアミド/メチルエチルケトン=35/65(重量比)、固形分50重量%、軟化温度95℃]20部とを混合した樹脂溶液にジメチルホルムアミドを添加して固形分を35重量%に調整した塗布液を乾燥塗布量35g/m2となるように塗布・乾燥して接着層を形成した。
(Adhesive layer)
Polyester urethane resin solution A [manufactured by Dainichi Seika Kogyo Co., Ltd., Resamine UD1305, solvent: dimethylformamide / methyl ethyl ketone = 40/60 (weight ratio), solid content 50 wt% , 80 parts of softening temperature and polyester urethane resin solution B [manufactured by Dainichi Seika Kogyo Co., Ltd., Resamine ME3119LP, solvent: dimethylformamide / methyl ethyl ketone = 35/65 (weight ratio), solid content 50% by weight, softening Apply a coating solution prepared by adding dimethylformamide to a resin solution mixed with 20 parts at a temperature of 95 ° C. to adjust the solid content to 35% by weight and dry the coating solution to a dry coating amount of 35 g / m 2. Formed.

(受像層)
前記接着層の上に、酸化チタン含有カーボネート系ウレタン樹脂溶液A[大日精化工業(株)製、セイカセブンBS012(S)ホワイト、ウレタン系樹脂/酸化チタン=9/1(重量比)、溶剤:ジメチルホルムアミド、固形分55重量%]65部とポリエステル系ウレタン樹脂溶液A[大日精化工業(株)製、レザミンUD1305、溶剤:ジメチルホルムアミド/メチルエチルケトン=40/60(重量比)、固形分50重量%、軟化温度95℃]35部とを混合した樹脂溶液にジメチルホルムアミドを添加して固形分を30重量%に調整した塗布液を乾燥塗布量40g/m2となるように塗布・乾燥して受像層を形成した。
(Image receiving layer)
On the adhesive layer, a titanium oxide-containing carbonate-based urethane resin solution A [manufactured by Dainichi Seika Kogyo Co., Ltd., Seika Seven BS012 (S) white, urethane-based resin / titanium oxide = 9/1 (weight ratio), solvent : 65 parts by weight of dimethylformamide, solid content 55% and polyester urethane resin solution A [manufactured by Dainichi Seika Kogyo Co., Ltd., Resamine UD1305, solvent: dimethylformamide / methyl ethyl ketone = 40/60 (weight ratio), solid content 50 A coating solution prepared by adding dimethylformamide to a resin solution mixed with 35 parts by weight and a softening temperature of 95 ° C. was adjusted to a solid content of 30% by weight, and applied and dried to a dry coating amount of 40 g / m 2. Thus, an image receiving layer was formed.

[読取用原稿]
インクジェットプリンター(キヤノン(株)製、PIXUS990i)を用いて、印刷用紙(キヤノン(株)製、キヤノン光沢紙GP−401)にシアン(C)、マゼンタ(M)、イエロー(Y)、ブラック(B)インクの各色ベタ画像を印刷し、読取用原稿を作成した。
[Scanning Document]
Using an inkjet printer (Canon, PIXUS990i), printing paper (Canon, Canon Glossy Paper GP-401) is printed on cyan (C), magenta (M), yellow (Y), black (B ) A solid image of each color of ink was printed to prepare a reading document.

[被転写体]
被転写体は、黒色Tシャツ(新井清太郎商店(株)製、J6650)を用いた。
[Transfer]
A black T-shirt (manufactured by Arai Seitaro Co., Ltd., J6650) was used as the transfer target.

[色濃度]
読取用原稿の各色ベタ画像において色濃度の測定位置を任意に3点定めて、それらの測定位置の色濃度を反射色濃度計(サカタインクス(株)製、ダレタマクベス反射色濃度計RD−19)で測定し、各色の平均値を算出した。また実施例及び比較例の画像転写方法によって転写層とともに被転写体に転写された各色ベタ画像について、読取用原稿の前記測定位置に対応する位置で色濃度を測定し、各色の平均値を算出した。前記読取用原稿の各色ベタ画像の色濃度の平均値は、それぞれシアン(C)が1.1、マゼンタ(M)が1.1、イエロー(Y)が1.1、ブラックが1.4であった。
[Color density]
Three measurement positions of color density are arbitrarily determined in each color solid image of the reading document, and the color density of these measurement positions is determined by a reflection color densitometer (Dareta Macbeth reflection color densitometer RD-19, manufactured by Sakata Inx Corporation). The average value of each color was calculated. Further, for each color solid image transferred to the transfer medium together with the transfer layer by the image transfer method of the example and the comparative example, the color density is measured at a position corresponding to the measurement position of the reading document, and the average value of each color is calculated. did. The average value of the color density of each color solid image of the reading document is 1.1 for cyan (C), 1.1 for magenta (M), 1.1 for yellow (Y), and 1.4 for black. there were.

[耐洗濯性]
実施例及び比較例の画像転写方法によって転写層とともに各色ベタ画像を被転写体に転写後、家庭用洗濯機(三洋電機(株)製、)を用いて、温度30℃の温水15リットルに市販の洗剤を1g/リットルの濃度で添加し、洗い15分、濯ぎ20分、脱水5分のサイクルを5サイクル行って前記被転写体を洗濯し、その後自然乾燥した。乾燥した被転写体に転写されている転写層を目視で観察し、下記の基準で洗濯耐久性を評価した。
[Washing resistance]
After transferring each color solid image together with the transfer layer to the transfer target material by the image transfer method of Examples and Comparative Examples, using a household washing machine (manufactured by Sanyo Electric Co., Ltd.), commercially available in 15 liters of hot water at a temperature of 30 ° C. Was added at a concentration of 1 g / liter, and the transfer material was washed by washing in 15 cycles of washing, 20 minutes of rinsing and 5 minutes of dehydration, and then air-dried. The transfer layer transferred to the dried transfer material was visually observed, and the washing durability was evaluated according to the following criteria.

○:転写層に割れや剥離がない。
×:転写層に割れや剥離がある。
○: There is no crack or peeling in the transfer layer.
X: There exists a crack and peeling in a transfer layer.

実施例1
カラーレーザー複写機(キヤノン(株)製、カラーレーザーコピアCLC1130、厚紙モード:157g/m2)を用いて、読取用原稿のベタ画像のトナー画像を転写シートの受像層側面に記録した。その後転写シートから基材を剥離し、転写層の接着層側面を被転写体の表面に所定の位置で重ね合わせ、さらに転写シートの受像層側面(トナー画像が記録された面側)に剥離紙(リンテック(株)製、KA7W白(V10)、シリコン系離型処理、坪量:60g/m2、厚み:50μm)の離型処理面側を重ね合わせた状態で、その剥離紙の転写シートが接触していない面側からヒートプレス機(奥野電気産業(株)製、AF−43T、設定温度:120℃、加圧条件:加圧目盛設定1(4.9kPa))を用いて1秒間加熱圧着して熱接着することにより転写層を被転写体に仮止めした。その後さらに被転写体の熱接着していない面側からヒートプレス機(奥野電気産業(株)製、AF−43T、設定温度:120℃、加圧条件:加圧目盛設定5(39kPa))を用いて10秒間加熱圧着して転写層とともにトナー画像を被転写体に転写した。被転写体の熱接着していない面側から加熱圧着した時の転写層の受像層側面の表面温度を熱伝対温度計(K型)で測定したところ、その表面温度は110℃を超えていなかった。転写されたトナー画像の色濃度の平均値は、それぞれシアン(C)が1.1、マゼンタ(M)が1.1、イエロー(Y)が1.1、ブラックが1.3であり、読取用原稿のベタ画像の色濃度とほぼ同等であった。また転写後の耐洗濯性の評価結果は「○」であった。
Example 1
Using a color laser copying machine (manufactured by Canon Inc., color laser copier CLC 1130, thick paper mode: 157 g / m 2 ), a solid toner image of the reading document was recorded on the side of the image receiving layer of the transfer sheet. After that, the base material is peeled off from the transfer sheet, the adhesive layer side surface of the transfer layer is superposed on the surface of the transfer object at a predetermined position, and the release paper is placed on the image receiving layer side surface (side on which the toner image is recorded) of the transfer sheet. A transfer sheet of the release paper in a state in which the release treatment side of KA7W White (V10), manufactured by Lintec Corporation, silicon mold release treatment, basis weight: 60 g / m 2 , thickness: 50 μm is overlaid. For 1 second using a heat press machine (Okuno Electric Industry Co., Ltd., AF-43T, set temperature: 120 ° C., pressurization condition: pressurization scale setting 1 (4.9 kPa)) The transfer layer was temporarily fixed to the transfer body by thermocompression bonding and heat bonding. Thereafter, a heat press machine (manufactured by Okuno Electric Industry Co., Ltd., AF-43T, set temperature: 120 ° C., pressurization condition: pressurization scale setting 5 (39 kPa)) is further applied from the non-thermally bonded surface side of the transfer object. The toner image was transferred onto the transfer medium together with the transfer layer by thermocompression bonding for 10 seconds. When the surface temperature of the image-receiving layer side surface of the transfer layer was measured with a thermocouple thermometer (K type) when heat-pressed from the non-thermally bonded surface side of the transfer object, the surface temperature exceeded 110 ° C. There wasn't. The average color density of the transferred toner image is 1.1 for cyan (C), 1.1 for magenta (M), 1.1 for yellow (Y), and 1.3 for black. The color density of the solid image of the original was almost the same. Moreover, the evaluation result of the washing resistance after the transfer was “◯”.

比較例1
実施例1と同様にして転写シートの受像層側面にトナー画像を記録した。その後転写シートから基材を剥離し、転写層の接着層側面を被転写体の表面に所定の位置で重ね合わせ、さらに転写シートの受像層側面(トナー画像が記録された面側)に剥離紙(リンテック(株)製、KA7W白(V10)、シリコン系離型処理、坪量:60g/m2、厚み:50μm)の離型処理面側を重ね合わせた状態で、その剥離紙の転写シートが接触していない面側からヒートプレス機(奥野電気産業(株)製、AF−43T、設定温度:100℃、加圧条件:加圧目盛設定1(4.9kPa))を用いて10秒間加熱圧着して転写層とともにトナー画像を被転写体に転写した。転写されたトナー画像の色濃度の平均値は、それぞれシアン(C)が1.1、マゼンタ(M)が1.1、イエロー(Y)が1.1、ブラックが1.4であり、読取用原稿のベタ画像の色濃度と同等であったが、転写後の耐洗濯性の評価結果は「×」であった。
Comparative Example 1
In the same manner as in Example 1, a toner image was recorded on the side of the image receiving layer of the transfer sheet. After that, the base material is peeled off from the transfer sheet, the adhesive layer side surface of the transfer layer is superposed on the surface of the transfer object at a predetermined position, and the release paper is placed on the image receiving layer side surface (side on which the toner image is recorded) of the transfer sheet. A transfer sheet of the release paper in a state in which the release treatment side of KA7W White (V10), manufactured by Lintec Corporation, silicon mold release treatment, basis weight: 60 g / m 2 , thickness: 50 μm is overlaid. 10 seconds using a heat press machine (Okuno Electric Industry Co., Ltd., AF-43T, set temperature: 100 ° C., pressurization condition: pressurization scale setting 1 (4.9 kPa)) from the surface side where no contact is made The toner image was transferred onto a transfer medium together with the transfer layer by thermocompression bonding. The average color density of the transferred toner image is 1.1 for cyan (C), 1.1 for magenta (M), 1.1 for yellow (Y), and 1.4 for black. The color density was the same as that of the solid image of the original, but the evaluation result of the washing resistance after the transfer was “x”.

比較例2
実施例1と同様にして転写シートの受像層側面にトナー画像を記録した。その後転写シートから基材を剥離し、転写層の接着層側面を被転写体の表面に所定の位置で重ね合わせ、さらに転写シートの受像層側面(トナー画像が記録された面側)に剥離紙(リンテック(株)製、KA7W白(V10)、シリコン系離型処理、坪量:60g/m2、厚み:50μm)の離型処理面側を重ね合わせた状態で、その剥離紙の転写シートが接触していない面側からヒートプレス機(奥野電気産業(株)製、AF−43T、設定温度:120℃、加圧条件:加圧目盛設定5(39kPa))を用いて10秒間加熱圧着して転写層とともにトナー画像を被転写体に転写した。転写されたトナー画像の色濃度の平均値は、それぞれシアン(C)が0.9、マゼンタ(M)が0.8、イエロー(Y)が0.9、ブラックが1.2であり、読取用原稿のベタ画像の色濃度に比べて、色濃度は低下した。また転写後の耐洗濯性の評価結果は「○」であった。
Comparative Example 2
In the same manner as in Example 1, a toner image was recorded on the side of the image receiving layer of the transfer sheet. After that, the base material is peeled off from the transfer sheet, the adhesive layer side surface of the transfer layer is superposed on the surface of the transfer object at a predetermined position, and the release paper is placed on the image receiving layer side surface (side on which the toner image is recorded) of the transfer sheet. A transfer sheet of the release paper in a state in which the release treatment side of KA7W White (V10), manufactured by Lintec Corporation, silicon mold release treatment, basis weight: 60 g / m 2 , thickness: 50 μm is overlaid. From the surface side where no contact is made using a heat press machine (Okuno Electric Industry Co., Ltd., AF-43T, set temperature: 120 ° C., pressurization condition: pressurization scale setting 5 (39 kPa)) for 10 seconds. Then, the toner image was transferred onto the transfer material together with the transfer layer. The average values of the color densities of the transferred toner images are 0.9 for cyan (C), 0.8 for magenta (M), 0.9 for yellow (Y), and 1.2 for black. The color density was lower than that of the solid image of the original. Moreover, the evaluation result of the washing resistance after the transfer was “◯”.

これらのことからも明らかなように、比較例の画像転写方法に比べて、実施例の画像転写方法は、転写後の画像の色濃度を損なうことなく、確実に転写層とともに画像を被転写体に転写することができる。
As is clear from these facts, compared to the image transfer method of the comparative example, the image transfer method of the embodiment reliably transfers the image together with the transfer layer without impairing the color density of the image after transfer. Can be transferred to.

Claims (3)

基材とこの基材に対して剥離可能でかつ着色されている転写層とで構成されており、前記転写層が受像可能でありかつ熱接着性を有する転写シートを用いてその転写層の一方の面側に画像を記録した後、転写層とともに前記画像を被転写体に転写する方法であって、転写層から基材を剥離した後、前記転写層の画像を記録していない面側を被転写体に接触させ、次いで転写層と被転写体とを密着させた状態で被転写体側から加熱して、前記転写層を被転写体に熱接着させて画像を被転写体に転写する方法。   The transfer layer is composed of a base material and a transfer layer that is peelable and colored with respect to the base material. After the image is recorded on the surface side of the substrate, the image is transferred together with the transfer layer to the transfer body, and after the substrate is peeled from the transfer layer, the surface side of the transfer layer on which the image is not recorded is A method of transferring an image to a transfer body by bringing the transfer layer into contact with the transfer body, then heating the transfer layer and the transfer body in close contact with each other, and heating the transfer layer to the transfer body. . 転写層の画像が記録されていない面側を被転写体に接触させ、転写層を被転写体に仮止めした後、前記被転写体側から加熱して、前記転写層を被転写体に熱接着させて被転写体に画像を転写する請求項1記載の方法。   The surface of the transfer layer on which the image is not recorded is brought into contact with the transfer target, the transfer layer is temporarily fixed to the transfer target, and then heated from the transfer target side to thermally bond the transfer layer to the transfer target. The method according to claim 1, wherein the image is transferred to a transfer medium. 転写層の画像を記録した面側の温度及び/またはその温度変化に応じて被転写体側からの加熱温度を調節することを特徴とする請求項1記載の方法。
2. The method according to claim 1, wherein the temperature on the surface side on which the image of the transfer layer is recorded and / or the heating temperature from the transferred material side is adjusted according to the temperature change.
JP2004111941A 2004-04-06 2004-04-06 Method for transferring image by using a transfer sheet Pending JP2005298979A (en)

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