JP2005294369A - Electric wave absorber, manufacturing method of laminated structure thereof, and laminated structure - Google Patents
Electric wave absorber, manufacturing method of laminated structure thereof, and laminated structure Download PDFInfo
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- JP2005294369A JP2005294369A JP2004104216A JP2004104216A JP2005294369A JP 2005294369 A JP2005294369 A JP 2005294369A JP 2004104216 A JP2004104216 A JP 2004104216A JP 2004104216 A JP2004104216 A JP 2004104216A JP 2005294369 A JP2005294369 A JP 2005294369A
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電波、および電磁波を吸収する吸収体の多数を重合した、フィルムないしシート状の構造体を迅速かつ精度よく能率的に製造できるようにした新規な電波吸収体・電磁波吸収体の積層体の製造法およびその積層構造体に関する。 A novel method of manufacturing a laminate of a radio wave absorber and an electromagnetic wave absorber that can quickly and accurately produce a film or sheet-like structure obtained by polymerizing a large number of absorbers that absorb radio waves and electromagnetic waves. And a laminated structure thereof.
一般に、建物等による電波の乱反射を防止、無線環境を良好に保つため、内装、天井,屋根,壁、或は床材などに電波吸収体が広く用いられている。 In general, radio wave absorbers are widely used for interiors, ceilings, roofs, walls, floors, and the like in order to prevent irregular reflection of radio waves from buildings and the like and to maintain a favorable wireless environment.
そして、之等の電波吸収体には、例えば金属で被覆されると共に、該金属が酸化処理又は磁化処理された第1の繊維と、金属で被覆されていない絶縁性の第2の繊維との不織布で構成されているもの(下記、特許文献1参照。)や、表面に絶縁膜を有する扁平状軟磁性金属粉が、その厚さ方向に積層されることで所定の厚さに形成された軟磁性層と、前記軟磁性層の表面を覆う電気絶縁層と、を備えることを特徴とする電磁波吸収シート(下記、特許文献2参照。)などが知られている。
And the radio wave absorbers such as these are composed of, for example, a first fiber coated with a metal and oxidized or magnetized, and an insulating second fiber not coated with the metal. What was comprised with the nonwoven fabric (refer below, patent document 1) and the flat soft magnetic metal powder which has an insulating film on the surface were formed in the predetermined thickness by being laminated | stacked in the thickness direction. 2. Description of the Related Art An electromagnetic wave absorbing sheet (see
また、電波、電磁波を吸収するフェライトとか金属をゴムなどに配合したシート状の吸収体も知られている。
之等の従来技術では、薄層の電波、電磁波吸収体が得られても、いずれも単体であり、所望の最終積層製品としての電波吸収体を得るためには、接着剤を用いた塗布手段で行うか、或は吸収体がゴムを用いている場合は未架橋の素材を熱によって加硫し重合する層間を融着させるなどによって行っていた。 In these conventional techniques, even if a thin-layer radio wave and electromagnetic wave absorber is obtained, both are single bodies, and in order to obtain a radio wave absorber as a desired final laminated product, a coating means using an adhesive is used. Or when the absorber uses rubber, the uncrosslinked material is vulcanized by heat and the layers to be polymerized are fused.
そのため、厚さ精度を保持するのが難しく、作業時間が長くなって非能率となり、連続作業も困難で、コスト高となり効率も悪く、安価に量産できないという欠点があった。 Therefore, it is difficult to maintain the thickness accuracy, the work time becomes long and inefficient, the continuous work is difficult, the cost is high, the efficiency is inferior, and the mass production is not possible at a low cost.
この発明は、叙上の点に着目して成されたものであって、積層する多数の電波、電磁波の吸収素材間に多段に介装される一定厚さの接着中間膜を用いて、加熱、或は加圧または加熱,加圧手段により一体接着できるようにした、電波吸収体・電磁波吸収体の積層構造体の製造法およびその積層構造体を提供することを目的とする。 The present invention has been made paying attention to the above points, and uses a fixed thickness adhesive intermediate film interposed between a large number of laminated radio wave and electromagnetic wave absorbing materials in a heating manner. Alternatively, an object of the present invention is to provide a method of manufacturing a laminated structure of a radio wave absorber and an electromagnetic wave absorber that can be integrally bonded by pressing, heating, or pressing means, and a laminated structure thereof.
この発明は、以下の構成により解決できる。 The present invention can be solved by the following configuration.
(1)電波、電磁波の吸収剤を配合して得られる薄層の電波吸収素材を多数重合し、之等電波吸収素材の隣り合う積層間に均一な厚さを有する中間接着膜を介装させ、かつ所望の接合手段により一体化接着するようにして成ることを特徴とする電波吸収体・電磁波吸収体の積層構造体の製造法。 (1) A large number of thin-layer radio wave absorbing materials obtained by blending radio wave and electromagnetic wave absorbers are polymerized, and an intermediate adhesive film having a uniform thickness is interposed between adjacent layers of radio wave absorbing materials. And a method for producing a laminated structure of a radio wave absorber and an electromagnetic wave absorber, characterized by being integrally bonded by a desired joining means.
(2)電波、電磁波の吸収剤を配合して得られる薄層の電波吸収素材を多数重合し、之等電波吸収素材の隣り合う積層間に均一な厚さを有する中間接着膜を介装させ、さらにいずれか一方の面に、電波・電磁波反射性のある金属を基盤として配し、かつ所望の接合手段により一体化接着するようにして成ることを特徴とする電波吸収体・電磁波吸収体の積層構造体の製造法。 (2) A large number of thin-layer radio wave absorption materials obtained by blending radio wave and electromagnetic wave absorbers are polymerized, and an intermediate adhesive film having a uniform thickness is interposed between adjacent layers of radio wave absorption materials. Further, a radio wave absorber / electromagnetic wave absorber characterized in that a metal having radio wave / electromagnetic wave reflectivity is arranged on either side as a base and is integrally bonded by a desired joining means. Manufacturing method of laminated structure.
(3)中間接着膜は、ホットメルトシートであることを特徴とする前項(1)または(2)記載の電波吸収体・電磁波吸収体の積層構造体の製造法。 (3) The method for producing a laminated structure of a radio wave absorber / electromagnetic wave absorber according to the above (1) or (2), wherein the intermediate adhesive film is a hot melt sheet.
(4)ホットメルトシートの組成物は、エチレン酢酸ビニル共重合体,ケン化エチレン酢酸ビニル重合体,ポリウレタン,ポリアミド,ポリイミド,ポリエステル,アタクチックポリプロピレンのいずれか1以上の化学組成物から成ることを特徴とする前項(3)記載の電波吸収体・電磁波吸収体の積層構造体の製造法。 (4) The composition of the hot melt sheet is composed of one or more chemical compositions of ethylene vinyl acetate copolymer, saponified ethylene vinyl acetate polymer, polyurethane, polyamide, polyimide, polyester, and atactic polypropylene. A method for producing a laminated structure of a radio wave absorber / electromagnetic wave absorber as described in (3) above.
(5)前項(1)または(2)で製造されることを特徴とする電波吸収体・電磁波吸収体の積層構造体。 (5) A laminated structure of a radio wave absorber and an electromagnetic wave absorber, which is produced in the above item (1) or (2).
この発明によれば、多数の電波吸収素材を一体的に接着する際、一定の保形された中間接着膜を用いているので、各電波吸収素材の中間に介在させる作業は機械的にしかも能率的に行うことができ、液状接着剤に比し、垂直面、下向き角を形成しても容易に貼り合わせができ、特にメルトフローレートが低いため、合わせエッジ部からの中間接着膜の滲み出しが殆ど生ぜず、均一な厚み合わせができる。 According to the present invention, when a large number of radio wave absorbing materials are bonded together, a certain shape-retained intermediate adhesive film is used. Therefore, the work interposed between the radio wave absorbing materials is mechanically and efficiently performed. Compared to liquid adhesives, it can be bonded easily even if it has a vertical surface and downward angle, and the melt flow rate is particularly low, so that the intermediate adhesive film oozes out from the mating edge. Almost no occurrence and uniform thickness matching is possible.
さらに合わせ中間接着膜は、ホットメルト型ポリマーに基づく場合、テープ状、或はフィルム状等好みの状態で実施できると共に、この合わせ中間接着膜を用いることにより、ブロッキングがなく、取扱いが容易で、しかも単独操作および連続作業が可能となるなどの多くの効果を有する。 Furthermore, when the laminated intermediate adhesive film is based on a hot-melt type polymer, it can be carried out in a desired state such as a tape or a film, and by using this laminated intermediate adhesive film, there is no blocking, and handling is easy. Moreover, it has many effects such as single operation and continuous work.
さらにこの発明によれば、電波反射する電波吸収素材が多段多層に配設してあるので、積層構造体への入射する電波は侵入度合に応じて漸次吸収されて減衰して強力な電磁波の侵入を防止できると共に、基盤を設けた場合は逆方向への反射効果も生じてきわめて電波・電磁波の吸収を高められる効果がある。 Furthermore, according to the present invention, since the radio wave absorbing material that reflects radio waves is arranged in multiple layers, the radio waves incident on the laminated structure are gradually absorbed and attenuated according to the degree of penetration, and strong electromagnetic waves penetrate. In addition, when a base is provided, a reflection effect in the reverse direction is also produced, and there is an effect that the absorption of radio waves and electromagnetic waves can be greatly enhanced.
以下に、本発明の実施例を説明する。 Examples of the present invention will be described below.
図1の断面説明図を参照し乍ら、本発明の実施例を説明する。 The embodiment of the present invention will be described with reference to the cross-sectional explanatory view of FIG.
図示は積層構造体を拡大して示したもので、1,1、2,2は、多段に重合させた電波および電磁波を吸収する化学物質を配合して予めフィルム状に成形した二種類の薄層の電波吸収素材、3は最下層の基盤に相当する金属材料を示す。すなわち、上層の2枚の電波吸収素材1,1は厚さが0.30mm、下層の電波吸収素材2,2は厚さが0.60mm、基盤3の厚さは2mmのものを示し、之等電波吸収素材1,1、2,2および基盤3との間に20〜250μの厚さの中間接着膜4を介在させることができる。
The illustration shows an enlarged view of the laminated structure. 1, 1, 2 and 2 are two types of thin films that are pre-formed into a film shape by compounding chemical substances that absorb radio waves and electromagnetic waves polymerized in multiple stages. An electromagnetic
斯くして中間接着膜4を電波吸収素材1,1、2,2および基盤3内に介装した積層構造素材を加熱,加圧装置付きの製造設備内に配設し、まず、常温で約2分間減圧(30トール以下)に保持し、系外の空気を除去すると共に一定の圧力をかける。
Thus, the laminated structure material in which the intermediate
つぎに減圧のまま加熱し、積層構造素材の温度を90〜150℃に保持し、1〜10分間加熱し、中間接着膜4を溶融し、調合した電波吸収素材1,1、2,2および基盤3を一体的に固着させることができる。
Next, heating is performed under reduced pressure, the temperature of the laminated structure material is maintained at 90 to 150 ° C., heating is performed for 1 to 10 minutes, the intermediate
ところで、電波吸収素材は、前述の構成や数に限るものでなく、ゴム,プラスチックポリマーなど好みの高分子材料を用いることができ、これに電波・電磁波を吸収、反射できるフェライト,鉄などの金属粉を配合したものを自由に選択使用できる。 By the way, the radio wave absorbing material is not limited to the above-described configuration and number, and any polymer material such as rubber or plastic polymer can be used, and metals such as ferrite and iron that can absorb and reflect radio waves and electromagnetic waves can be used. You can freely select and use the powder.
以上は、シート状に形成する場合の一例を示したが、長尺の場合は、ロール状に巻装したそれぞれの電波吸収素材や、中間接着膜および基盤より連続的に加熱,加圧装置へ供給して同様に実施できる。 The above shows an example of forming a sheet, but in the case of a long sheet, it is continuously heated and pressurized from the respective radio wave absorbing materials wound in a roll, the intermediate adhesive film, and the substrate. The same can be carried out.
また、中間接着膜を構成する組成物としては、例えばホットメルト接着剤の石油系ワックスと低分子量ポリスチレン,アタクチックポリプロピレン,ロジン,ペンテン樹脂等の石油系粘着材を組み合わせたものなどが用いられるが、具体的には、例えば以下のホットメルト型のプラスチックポリマーが考えられる。そして厚さを変化させることにより、自由に強度を調整できる。 In addition, as the composition constituting the intermediate adhesive film, for example, a combination of a petroleum wax as a hot melt adhesive and a petroleum adhesive such as low molecular weight polystyrene, atactic polypropylene, rosin, and pentene resin is used. Specifically, for example, the following hot-melt type plastic polymers can be considered. The strength can be freely adjusted by changing the thickness.
ところで、図1に示す中間接着膜4の種類と厚さ、温度、圧力、時間による厚さ精度と接着強度をそれぞれ表1と表2に示す。
By the way, Table 1 and Table 2 show the thickness accuracy and adhesive strength depending on the type, thickness, temperature, pressure, and time of the intermediate
この発明によれば、中間接着膜を用いて能率の高い積層接着を行っているので、薄層の電波吸収体を多数重合して反射、吸収性のきわめて高い電波吸収体、電磁波吸収体の積層構造体を量産性と高精度に安価に提供できる。 According to the present invention, since highly efficient laminating adhesion is performed using an intermediate adhesive film, a large number of thin wave absorbers are polymerized to reflect and absorb extremely highly absorbing radio wave absorbers and electromagnetic wave absorbers. A structure can be provided at low cost with high productivity and high accuracy.
1,1、2,2 電波吸収素材
3 基盤
4 中間接着膜
1, 1, 2, 2 Radio
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Cited By (1)
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JPWO2017169672A1 (en) * | 2016-03-30 | 2019-02-07 | 株式会社巴川製紙所 | Radio wave absorbing adhesive sheet |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08204379A (en) * | 1995-01-24 | 1996-08-09 | Mitsubishi Cable Ind Ltd | Radio wave absorber |
JP2000101283A (en) * | 1998-09-18 | 2000-04-07 | Sony Corp | Electromagnetic wave absorbing body and manufacture thereof |
JP2002084089A (en) * | 2000-06-19 | 2002-03-22 | Dainippon Printing Co Ltd | Radio wave absorber |
JP2002190692A (en) * | 2000-12-22 | 2002-07-05 | Tomoegawa Paper Co Ltd | Electromagnetic wave shield sheet and electromagnetic wave shield product using the sheet, and method for manufacturing the same |
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- 2004-03-31 JP JP2004104216A patent/JP4545472B2/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH08204379A (en) * | 1995-01-24 | 1996-08-09 | Mitsubishi Cable Ind Ltd | Radio wave absorber |
JP2000101283A (en) * | 1998-09-18 | 2000-04-07 | Sony Corp | Electromagnetic wave absorbing body and manufacture thereof |
JP2002084089A (en) * | 2000-06-19 | 2002-03-22 | Dainippon Printing Co Ltd | Radio wave absorber |
JP2002190692A (en) * | 2000-12-22 | 2002-07-05 | Tomoegawa Paper Co Ltd | Electromagnetic wave shield sheet and electromagnetic wave shield product using the sheet, and method for manufacturing the same |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPWO2017169672A1 (en) * | 2016-03-30 | 2019-02-07 | 株式会社巴川製紙所 | Radio wave absorbing adhesive sheet |
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