JP2005286178A5 - - Google Patents

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JP2005286178A5
JP2005286178A5 JP2004099461A JP2004099461A JP2005286178A5 JP 2005286178 A5 JP2005286178 A5 JP 2005286178A5 JP 2004099461 A JP2004099461 A JP 2004099461A JP 2004099461 A JP2004099461 A JP 2004099461A JP 2005286178 A5 JP2005286178 A5 JP 2005286178A5
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powder
double layer
calcined
electric double
layer capacitor
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JP4095043B2 (en
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ニードルコークスグリーンパウダーを、不活性雰囲気下600〜900℃で2〜4時間焼成し、焼成した粉末を、重量比で1.8〜2.2倍量の水酸化アルカリ粉末と混合し、粉末混合物を、不活性雰囲気下650〜850℃で2〜4時間焼成し、焼成した粉末混合物を洗浄して水酸化アルカリを除去し乾燥させて、細孔径0.8nm以下の細孔容積が0.01〜0.1ml/gである炭素粉末を得る工程;及び
該炭素粉末を成形する工程;
を包含する方法によって得られる、電気二重層キャパシタ用炭素質電極。
Needle coke green powder is calcined at 600 to 900 ° C. for 2 to 4 hours under an inert atmosphere, and the calcined powder is mixed with 1.8 to 2.2 times the amount of alkali hydroxide powder in weight ratio to obtain a powder mixture Is calcined at 650 to 850 ° C. for 2 to 4 hours under an inert atmosphere, and the calcined powder mixture is washed to remove alkali hydroxide and dried to obtain a pore volume of 0.1 nm or less in pore diameter of 0.01 nm or less. Obtaining carbon powder that is ˜0.1 ml / g; and shaping the carbon powder;
A carbonaceous electrode for an electric double layer capacitor obtained by a method comprising:
前記ニードルコークスグリーンパウダーが、石炭系ニードルコークスグリーンパウダーである請求項1記載の電気二重層キャパシタ用炭素質電極。   The carbonaceous electrode for an electric double layer capacitor according to claim 1, wherein the needle coke green powder is a coal-based needle coke green powder. 前記電気二重層キャパシタが、溶質を有機溶媒に溶解させた有機電解液中に炭素質電極が浸されてなる構造のものである、請求項1又は2記載の電気二重層キャパシタ用炭素質電極 The electric double layer capacitor is of a structure in which soaked carbonaceous electrode solutes in the organic photoelectric Kaieki dissolved in an organic solvent, carbonaceous electrode according to claim 1 or 2, wherein the electric double layer capacitor . 前記有機電解液の溶質が、式
Figure 2005286178
[式中、Rはそれぞれ独立して炭素数1〜10のアルキル基、又は一緒に連結した炭素数3〜8のアルキレン基であり、Xは対アニオンである。]
で表されるピロリジニウム化合物塩である請求項3記載の電気二重層キャパシタ用炭素質電極
The solute of the organic electrolyte is a formula
Figure 2005286178
[Wherein, each R is independently an alkyl group having 1 to 10 carbon atoms, or an alkylene group having 3 to 8 carbon atoms linked together, and X is a counter anion. ]
The carbonaceous electrode for electric double layer capacitors according to claim 3, which is a pyrrolidinium compound salt represented by the formula:
前記ピロリジニウム化合物塩がスピロビピロリジニウム塩である請求項4記載の電気二重層キャパシタ用炭素質電極The carbonaceous electrode for an electric double layer capacitor according to claim 4, wherein the pyrrolidinium compound salt is a spirobipyrrolidinium salt. 前記ピロリジニウム化合物塩の対アニオンが4フッ化ホウ酸アニオン、一部をほうフッ化アルキル基により置換したほう酸アニオン、6フッ化リン酸アニオン、過塩素酸、又はヨウ素である請求項4又は5記載の電気二重層キャパシタ用炭素質電極The counter anion of the pyrrolidinium compound salt is a tetrafluoroborate anion, a borate anion partially substituted with a borofluoride alkyl group, a hexafluorophosphate anion, perchloric acid, or iodine. Carbonaceous electrode for electric double layer capacitor. ニードルコークスグリーンパウダーを、不活性雰囲気下600〜900℃で2〜4時間焼成し、焼成した粉末を、重量比で1.8〜2.2倍量の水酸化アルカリ粉末と混合し、粉末混合物を、不活性雰囲気下650〜850℃で2〜4時間焼成し、焼成した粉末混合物を洗浄して水酸化アルカリを除去し乾燥させて、細孔径0.8nm以下の細孔容積が0.01〜0.1ml/gである炭素粉末を得る工程;及び
該炭素粉末を成形する工程;
を包含する電気二重層キャパシタ用炭素質電極の製造方法。
Needle coke green powder is calcined at 600 to 900 ° C. for 2 to 4 hours under an inert atmosphere, and the calcined powder is mixed with 1.8 to 2.2 times the amount of alkali hydroxide powder in weight ratio to obtain a powder mixture Is calcined at 650 to 850 ° C. for 2 to 4 hours under an inert atmosphere, and the calcined powder mixture is washed to remove alkali hydroxide and dried to obtain a pore volume of 0.1 nm or less in pore diameter of 0.01 nm or less. Obtaining carbon powder that is ˜0.1 ml / g; and shaping the carbon powder;
Of producing a carbonaceous electrode for an electric double layer capacitor.
JP2004099461A 2004-03-30 2004-03-30 Carbonaceous electrode for electric double layer capacitor and manufacturing method thereof Expired - Fee Related JP4095043B2 (en)

Priority Applications (1)

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JP2004099461A JP4095043B2 (en) 2004-03-30 2004-03-30 Carbonaceous electrode for electric double layer capacitor and manufacturing method thereof

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JP2004099461A JP4095043B2 (en) 2004-03-30 2004-03-30 Carbonaceous electrode for electric double layer capacitor and manufacturing method thereof

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JP2005286178A JP2005286178A (en) 2005-10-13
JP2005286178A5 true JP2005286178A5 (en) 2007-07-26
JP4095043B2 JP4095043B2 (en) 2008-06-04

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4502380B2 (en) * 2004-08-03 2010-07-14 日本カーリット株式会社 Electrolytic solution for electric double layer capacitor and electric double layer capacitor
JP2006269494A (en) * 2005-03-22 2006-10-05 Nippon Steel Chem Co Ltd Carbonaceous material for polarized electrode for electric double-layer capacitor, and manufacturing method of polarized electrode
JP4929182B2 (en) 2005-11-04 2012-05-09 ステラケミファ株式会社 Electricity storage element
JP2008166544A (en) * 2006-12-28 2008-07-17 Power System:Kk Non-porous carbon having adjusted ignition loss and electric double-layer capacitor
JP2007258746A (en) * 2007-06-05 2007-10-04 Power System:Kk Organic electrolytic solution for electric double-layer capacitor, and the electric double-layer capacitor
JP5930260B2 (en) * 2010-11-08 2016-06-08 学校法人 関西大学 Electrochemical capacitor and method for producing electrochemical capacitor

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