JP2005283627A - Coating liquid for image recording layer, image recording material and its manufacturing method and image forming method - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an image recording material used for an ink jet recording material, a thermosensitive recording material, a thermal developing material, an electrophotographic material and a silver halide photographic material. <P>SOLUTION: Regarding the image recording layer coating liquid containing water-dispersion emulsion, aggregation inhibitor having a part which can perform a specific interaction with a surface functional group in a resin particle in the water-dispersion emulsion, and water soluble polymer compound, the viscosity A(Pa s) of the coating liquid at 25°C before the addition of the water soluble polymer compound to mixed liquid after the addition of the aggregation inhibitor by the solid content of ≥0.5 mass% into the water-dispersion emulsion and the viscosity B(Pa s) of the coating liquid at 25°C after the addition of the water-dispersion polymer compound by the solid content of 1.0 mass% to the mixed liquid satisfy the following expression; viscosity ratio (B/A)≤40. The image recording material is constituted of a supporting body and the image recording layer coating liquid applied on the supporting body. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention provides high-quality images, and is used in ink jet recording materials, heat sensitive recording materials, heat developing materials, electrophotographic materials, and silver halide photographic materials. The present invention relates to an image recording layer coating solution suitable for electrophotography, an image recording material, a manufacturing method thereof, and an image forming method.

Conventionally, in order to apply a water-dispersible emulsion on a support in an image recording material such as an electrophotographic image-receiving sheet, it is necessary to add a water-soluble polymer compound to the coating liquid to increase the liquid viscosity. However, when a water-soluble polymer compound is added to a water-dispersible emulsion, the emulsion aggregates and the like has a problem in stability. Further, when aggregation occurs, the surface shape after coating and drying is not good, and therefore, the coating film itself becomes brittle, cracks are generated, and the commercial value is lowered.
As a technique for solving the above-mentioned problems, for example, an aqueous binder resin selected from a polyethylene-vinyl acetate emulsion, a urethane emulsion, and a styrene-butadiene emulsion, and an anti-chipping agent comprising an inorganic cushioning agent, An aqueous chipping resistant coating composition containing at least a viscosity modifier has been proposed (see Patent Document 1).
However, in this case, the water-resistant chipping-resistant coating composition of Patent Document 1 is not used for image recording materials, particularly electrophotographic applications, and does not disclose or suggest an additive for suppressing aggregation. Currently, development is desired.

JP-A-5-214269

  This invention is made | formed in view of this present condition, and makes it a subject to solve the said various problems in the past and to achieve the following objectives. That is, the present invention provides a high-quality image, and is used in at least one of an ink jet recording material, a thermal recording material, a heat developing material, an electrophotographic material, and a silver halide photographic material. An object of the present invention is to provide a coating solution for an image recording layer, an image recording material, a method for producing the same, and an image forming method, which can prevent the coating layer from falling off and cracks are generated.

Means for solving the problems are as follows. That is,
<1> A coating solution for an image recording layer comprising a water-dispersible emulsion, an aggregation inhibitor having a site capable of interacting with a surface functional group in the resin particles in the water-dispersible emulsion, and a water-soluble polymer compound. The viscosity at 25 ° C. of the coating solution before adding the water-soluble polymer compound to the mixed solution obtained by adding 0.5% by mass or more of the aggregation inhibitor to the water-dispersible emulsion. A (Pa · s) and the viscosity B (Pa · s) at 25 ° C. of a coating solution obtained by adding 1.0% by mass of the water-soluble polymer compound to the mixed solution as a solid content are represented by the following formula: A coating liquid for an image recording layer, wherein the viscosity ratio (B / A) ≦ 40 is satisfied.
<2> The image recording layer coating solution according to <1>, wherein the surface functional group of the resin particles in the water-dispersible emulsion is an amine salt of a carboxylic acid.
<3> The coating liquid for an image recording layer according to any one of <1> to <2>, wherein the water-dispersible emulsion is a water-dispersible polyester emulsion.
<4> The coating solution for an image recording layer according to any one of <1> to <3>, wherein the aggregation inhibitor is at least one selected from a surfactant and an inclusion compound.
<5> The image recording layer coating solution according to <4>, wherein the surfactant comprises a sulfoalkyl succinate dialkyl salt.
<6> The image recording layer coating solution according to <4>, wherein the clathrate compound is crown ether.
<7> The coating liquid for an image recording layer according to <6>, wherein the crown ether is represented by the following formula: x-crown-y-ether, x is 13 or more, and y is 5 or more. .
<8> The line width of ¹ H-NMR representing the mobility of CH ₂ in a mixed liquid obtained by adding crown ether as an aggregation inhibitor in a water-dispersible emulsion is 4 Hz or more, and a line of ¹³ C-NMR The coating solution for an image recording layer according to any one of <6> to <7>, wherein the width is 7 Hz or more.
<9> The coating solution for an image recording layer according to any one of <1> to <8>, wherein the water-soluble polymer compound is polyethylene oxide having a weight average molecular weight (Mw) of 400,000 or less.
<10> An image comprising at least a support and an image recording layer obtained by coating the support on the image recording layer coating solution according to any one of <1> to <9>. Recording material.
<11> The image recording material according to <10>, wherein the image recording material is at least one selected from an ink jet recording material, a heat sensitive recording material, a heat developing material, an electrophotographic material, and a silver halide photographic material. It is an image recording material.
<12> The image recording material according to <11>, wherein the image recording material is an electrophotographic image-receiving sheet having a support and at least one toner image-receiving layer on the support.
<13> A method for producing an image recording material having a support and at least one image recording layer on at least one surface of the support, wherein the resin in the water-dispersible emulsion is contained in the water-dispersible emulsion. An image recording layer coating solution preparation step of adding a water-soluble polymer compound to prepare an image recording layer coating solution after adding an aggregation inhibitor having a site capable of interacting with a surface functional group in the particles; An image recording layer forming step of forming an image recording layer by applying an image recording layer coating liquid on the support.
<14> The method for producing an image recording material according to <13>, wherein the aggregation inhibitor is at least one selected from a surfactant and an inclusion compound.
<15> A belt fixing type smoothing process comprising: a toner image forming step of forming a toner image on the electrophotographic image-receiving sheet according to <12>; a heating and pressing member; a belt member; and a cooling device. And a fixing and smoothing step of heating and pressurizing using a processing processor, cooling and peeling off, and an image forming method.
<16> The image forming method according to <15>, wherein the belt member has a fluorocarbonsiloxane rubber layer formed on a belt support.
<17> The image forming method according to <15>, wherein the belt member has a silicone rubber layer formed on a belt support and a fluorocarbonsiloxane rubber layer formed on a surface of the silicone rubber layer.
<18> The image forming method according to any one of <16> to <17>, wherein the fluorocarbon siloxane rubber in the fluorocarbon siloxane rubber layer has at least one of a perfluoroalkyl ether group and a perfluoroalkyl group in a main chain. is there.

  The image recording layer coating liquid of the present invention contains a water-dispersible emulsion, an aggregation inhibitor having a site capable of interacting with a surface functional group in the resin particles in the water-dispersible emulsion, and a water-soluble polymer compound. A coating liquid for an image recording layer, which is a coating liquid before adding the water-soluble polymer compound to a mixed liquid in which the aggregation inhibitor is added in an amount of 0.5% by mass or more in solid content in the water-dispersible emulsion. The viscosity A (Pa · s) at 25 ° C. of the liquid and the viscosity B (Pa · s) at 25 ° C. of the coating liquid obtained by adding 1.0% by mass of the water-soluble polymer compound as a solid content to the mixed liquid ) Satisfies the following formula, viscosity ratio (B / A) ≦ 40. In the image recording layer coating solution of the present invention, a water-soluble polymer compound is added to provide a coating layer that is excellent in coating property, has no aggregation, has excellent coating solution stability, and has good surface properties. Can be formed.

  The image recording material of the present invention has at least an image recording layer formed by coating a support and the image recording layer coating liquid of the present invention on the support. As a result, it is possible to prevent the coating layer (image recording layer) from falling off and cracking, and to provide ink jet recording materials, heat sensitive recording materials, heat developing materials, electrophotographic materials, and silver halide photographic materials. In particular, it is suitable for electrophotography.

  The method for producing an image recording material of the present invention includes an image recording layer coating liquid preparing step and an image recording layer forming step. In the image recording layer coating liquid preparation step, first, an aggregation inhibitor is added to the water-dispersible emulsion to interact with surface functional groups (for example, amine salts of carboxylic acids) in the resin particles in the water-dispersible emulsion. By making it act, a water-soluble polymer compound is added in a state where aggregation of resin particles in the water-dispersible emulsion is prevented. As a result, a coating solution for an image recording layer having no aggregation and having an appropriate viscosity and excellent coating suitability can be prepared. In the image recording layer forming step, by applying the image recording layer coating liquid onto the support, it is possible to form an image recording layer having good surface properties and free from dropping and cracking.

  According to the present invention, conventional problems can be solved, and high-quality images can be obtained. At least one of an inkjet recording material, a thermal recording material, a heat developing material, an electrophotographic material, and a silver halide photographic material. In particular, it is possible to prevent the coating layer from dropping and cracking from occurring, and an image recording material suitable for electrophotography can be provided.

(Coating solution for image recording layer)
The coating solution for an image recording layer of the present invention contains a water-dispersible emulsion, an aggregation inhibitor, and a water-soluble polymer compound, and further contains other components as necessary.

In the coating solution for an image recording layer of the present invention, as apparent from the results of FIGS. 1 and 2 of Examples described later, the aggregation inhibitor is added in an amount of 0.5% by mass in the water-dispersible emulsion. 1. Viscosity A (Pa · s) at 25 ° C. of the coating solution before adding the water-soluble polymer compound to the mixed solution added above, and 1. It is necessary that the viscosity B (Pa · s) at 25 ° C. of the coating liquid added with 0% by mass satisfies the following formula, viscosity ratio (B / A) ≦ 40, and 3 to 15 is more preferable.
When the viscosity ratio (B / A) exceeds 40, the coating solution is agglomerated, the stability is lowered, the properties of the coated surface after coating and drying are deteriorated, and the coating layer May become brittle and may crack.
Here, the viscosity of the coating solution can be measured using, for example, a rheometer.

Further, in the image recording layer coating liquid of the present invention, as is apparent from the results of FIGS. 3 and 4 of Examples described later, a mixture in which crown ether as an aggregation inhibitor is added to the water-dispersible emulsion. It is preferable that the mobility of CH _{2 in} the liquid is low in that the aggregation of the coating liquid can be prevented. For evaluation of the mobility of CH ₂ , the line width of ¹ H-NMR is preferably 4 Hz or more, and more preferably 10 Hz or more. Further, the line width of ¹³ C-NMR is preferably 7 Hz or more, and more preferably 10 Hz or more.
Here, for the mobility of CH ₂ , an aqueous solution in which 0.02 g of crown ether was added to a water-dispersible emulsion was prepared. This solution was transferred to the outer tube of a double tube NMR probe, and D ₂ O added with acetonitrile (CH ₃ CN) as an internal standard substance was injected into the inner tube. Using NMR, it can be evaluated by measuring the CH ₂ peak line width of a crown ether near δ 70 by ¹ H-NMR and δ 3.5 by ¹³ C-NMR.

-Water-dispersible emulsion-
The water-dispersible emulsion is not particularly limited as long as the surface functional groups in the resin particles in the water-dispersible emulsion interact with the aggregation inhibitor, and can be appropriately selected depending on the purpose. For example, water dispersible polyurethane emulsion, water dispersible polyester emulsion, chloroprene emulsion, styrene-butadiene emulsion, nitrile-butadiene emulsion, butadiene emulsion, vinyl chloride emulsion, vinylpyridine-styrene-butadiene emulsion, polybutene Emulsion, polyethylene emulsion, vinyl acetate emulsion, ethylene-vinyl acetate emulsion, vinylidene chloride emulsion, methyl methacrylate-butadiene emulsion, etc. It is. Among these, a water-dispersible polyester emulsion is more preferable because it is thermoplastic and has high emulsion stability.

  Commercially available products can be used as the water-dispersible polyester emulsion, for example, Elitel UE3500, UE3210, XA-8153, KZA-1449, KZA-A464S manufactured by Unitika; Byron 290, Byron 200, Byron 280 manufactured by Toyobo. Byron 300, Byron 103, Byron GK-140, Byron GK-130; Kao's Tufton NE-382, Tufton U-5, ATR-2009, ATR-2010; Nippon Synthetic Chemical's Polyester TP-220, R -188, HP-320, and the like.

Examples of the surface functional group in the resin particles in the water-dispersible emulsion include a sulfonyl group, a carboxyl group, an amide group, an amine salt of a carboxylic acid, and the like. Among these, an amine salt of a carboxylic acid is particularly preferable. .
The content of the water-dispersible emulsion in the image recording layer coating solution is preferably 10 to 90% by mass, and more preferably 10 to 70% by mass.

-Surfactant-
The surfactant is not particularly limited, and may be any of an anionic surfactant, a cationic surfactant, a nonionic surfactant, and an amphoteric surfactant, and is appropriately selected and used depending on the purpose. be able to.
Examples of the anionic surfactant include soap bases, fatty acid soaps such as sodium laurate; higher alkyl sulfates such as sodium lauryl sulfate; polyoxyethylene (hereinafter sometimes referred to as POE) lauryl ether sulfate tri Alkyl ether sulfates such as ethanolamine; N-acyl sarcosine salts such as sodium lauroyl sarcosine; palm oil fatty acid methyl taurine sodium; phosphate ester salts such as POE stearyl ether phosphate; sodium di-2-ethylhexylsulfosuccinate Dialkyl salts of sulfosuccinic acid such as alkylbenzene sulfonates such as sodium dodecylbenzene sulfonate; N-acyl glutamates such as disodium N-stearoyl glutamate; Higher fatty acid ester sulfates such as sodium serine sulfate; POE alkyl ether carboxylates; POE alkyl allyl ether carboxylates; α-olefin sulfonates; higher fatty acid ester sulfonates; secondary alcohol sulfates; Alkylolamide sulfate; sodium lauroyl monoethanolamide succinate, N-palmitoyl aspartate ditriethanolamine, sodium caseinate and the like.

  Examples of the cationic surfactant include alkyl trimethyl ammonium salts such as stearyl trimethyl ammonium chloride; dialkyl dimethyl ammonium salts such as distearyl dimethyl ammonium chloride; alkyl pyridinium salts such as cetyl pyridium chloride; alkyl quaternary ammonium salts; Examples thereof include dimethylbenzylammonium salt; alkylisoquinolinium salt; dialkyl morpholinium salt; POE alkylamine, alkylamine salt, polyamine fatty acid derivative, amyl alcohol fatty acid derivative, benzalkonium chloride, benzethonium chloride and the like.

  Examples of the nonionic surfactant include sorbitan fatty acid esters such as sorbitan monoisostearate and sorbitan sesquioleate; glycerin polyglycerol fatty acids such as glyceryl monostearate; propylene glycol fatty acid esters such as propylene glycol monostearate; Examples include hardened castor oil derivatives and glycerin alkyl ethers.

  Examples of the amphoteric surfactant include imidazoline-based amphoteric surfactants such as 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium; and betaine-based amphoteric surfactants such as lauryldimethylaminoacetic acid betaine. Surfactant etc. are mentioned.

Among these, a dialkyl salt of sulfosuccinic acid is preferable because it is easy to adjust the solubility in water and the surface tension of the coating solution.
Examples of the dialkyl salt of sulfosuccinate include dioctyl sodium sulfosuccinate, diethylhexyl sodium sulfosuccinate, and the like.

The addition amount of the surfactant is preferably 0.5% by mass or more, and more preferably 0.7 to 1.0% by mass in terms of solid content.
When the addition amount is less than 0.5% by mass, aggregation may occur and the coated surface may be deteriorated.

-Inclusion compound-
The inclusion compound is not particularly limited as long as it has molecular recognition ability (host-guest binding ability), and can be appropriately selected according to the purpose. For example, a compound having a cylindrical (one-dimensional) cavity, Preferred examples include those having a layered (two-dimensional) cavity and those having a cage (three-dimensional) cavity.

  Examples of the inclusion compound having a cylindrical (one-dimensional) cavity include urea, thiourea, deoxycholic acid, dinitrodiphenyl, dioxytriphenylmethane, triphenylmethane, methylnaphthalene, spirochroman, PHTP (perhydro Triphenylene), cellulose, amylose, cyclodextrin (however, in the solution, the cavity is in a cage shape).

  The cyclodextrin is a cyclic dextrin produced by the degradation of starch with amylase, and three types of α-cyclodextrin, β-cyclodextrin, and γ-cyclodextrin are known. Examples of the cyclodextrin include cyclodextrin derivatives in which some of these hydroxyl groups are changed to other functional groups such as alkyl groups, allyl groups, alkoxy groups, amide groups, and sulfonic acid groups.

  Examples of the layered (two-dimensional) inclusion compound include clay minerals, graphite, smectite, montmorillonite, and zeolite.

  Examples of the cage-like (three-dimensional) inclusion compound include hydroquinone, gaseous hydrate, tri-o-thymotide, oxyflavan, dicyanoammine nickel, cryptand, calixarene, and crown compound.

  The calixarene is a cyclic oligomer in which a phenol unit synthesized from phenol and formaldehyde under appropriate conditions is bonded with a methylene group, and 4 to 8 nuclei are known.

The crown compound includes not only a crown ether having oxygen as an electron-donating donor atom but also a macrocyclic compound having a donor atom such as nitrogen or sulfur as a constituent atom of the ring structure as an analog thereof, and also includes a cryptand. A bicyclic crown compound composed of two or more representative rings is also included.
Among the above clathrate compounds, in particular, crown ether is preferable from the viewpoints of price, availability, and ease of synthesis.
The crown ether is represented by the following formula, x-crown-y-ether. However, those in which x is 13 or more and y is 5 or more are preferable, and 15-crown-O-5-ether, 18-crown-O-6-ether, and the like are preferable.
Specifically, cyclohexyl-12-crown-4, dibenzo-14-crown-4, t-butylbenzo-15-crown-5, dibenzo-18-crown-6, dicyclohexyl-18-crown-6, 18-crown -6, tribenzo-18-crown-6, tetrabenzo-24-crown-8, dibenzo-26-crown-6 and the like.

Examples of the capture target that can be captured by the crown compound include various metal ions such as alkali metals such as Li, Na and K, alkaline earth metals such as Mg and Ca, NH ⁴⁺ , alkylammonium ions, and guanidinium. Ions, aromatic diazonium ions, and the like, and the crown compound forms a complex with them. In addition to these, capture objects that can be captured by the crown compound include C—H (acetonitrile, malonnitrile, adiponitrile, etc.), NH (aniline, aminobenzoic acid, amide) having relatively high acidity. , Sulfamide derivatives, etc.), polar organic compounds having an O—H (phenol, acetic acid derivative, etc.) unit, etc., and the crown compound forms a complex with them.

The addition amount of the clathrate compound is preferably 0.5% by mass or more, more preferably 1 to 5% by mass in terms of solid content.
When the addition amount is less than 0.5% by mass, aggregation may occur and the coated surface may be deteriorated.

-Water-soluble polymer compounds-
The water-soluble polymer compound is not particularly limited as long as the weight average molecular weight (Mw) is 400,000 or less, and can be appropriately selected according to the purpose. For example, polyvinyl alcohol, carboxy-modified polyvinyl alcohol, carboxy Examples include methyl cellulose, hydroxyethyl cellulose, cellulose sulfate, polyethylene oxide, gelatin, cationized starch, casein, sodium polyacrylate, sodium styrene-maleic anhydride copolymer, sodium polystyrene sulfonate, etc. Polyethylene oxide is preferable because the viscosity of the liquid can be easily adjusted.

  The water-soluble polymer compound has a weight average molecular weight (Mw) of 400,000 or less, preferably 100,000 to 400,000. When the weight average molecular weight (Mw) of the water-soluble polymer compound exceeds 400,000, aggregation tends to occur and the surface state after coating may be poor.

  The mass ratio of the water-dispersible emulsion to the water-soluble polymer compound (water-dispersible emulsion: water-soluble polymer compound) is preferably 1: 0.01 to 1, and more preferably 1: 0.1 to 1.

In addition to the water-dispersible emulsion, the aggregation inhibitor, and the water-soluble polymer compound, the coating liquid for an image recording layer of the present invention includes other components such as water, a pigment, a release agent, a stabilizer, Various additives such as an antioxidant can be blended.
The coating solution for an image recording layer of the present invention has an appropriate viscosity, has no aggregation, is stable, has excellent coating properties, is coated on a support, and is dried and cracked or dropped on the image recording layer. Therefore, it can be suitably used for image recording materials such as ink jet recording materials, heat-sensitive recording materials, heat developing materials, electrophotographic materials, and silver halide photographic materials.

(Image recording material)
The image recording material of the present invention has at least an image recording layer obtained by coating the coating solution for an image recording layer of the present invention on a support, such as an electrophotographic image receiving sheet, a melt thermal transfer recording sheet, and a sublimation thermal transfer. Any one selected from a recording sheet, a heat-sensitive recording material, a silver halide photographic material, and an inkjet recording material can be used, and among these, an electrophotographic image-receiving sheet is preferred.
Hereinafter, the electrophotographic image receiving sheet will be specifically described.

<Electrophotographic image-receiving sheet>
The electrophotographic image-receiving sheet has a support and at least one toner image-receiving layer on at least one surface of the support, a polymer layer, and other layers appropriately selected as necessary, for example, a surface protective layer, It has a cushion layer, a charge control (prevention) layer, a reflection layer, a tint preparation layer, a storage stability improving layer, an adhesion prevention layer, an anti-curl layer, a smoothing layer and the like. Each of these layers may have a single layer structure or a laminated structure.

[Support]
Examples of the support include base paper, synthetic paper, synthetic resin sheet, coated paper, and laminated paper. These supports may have a single layer structure or a laminated structure of two or more layers. Among these, a laminated paper in which a polyolefin resin layer is coated on one side or both sides of a base paper is preferable because it is excellent in smooth glossiness and stretchability.

-Base paper-
The base paper is not particularly limited and may be appropriately selected depending on the intended purpose. Specifically, it is a high-quality paper, for example, “Photographic Engineering Basics—Silver Salt Photography” edited by the Japan Photography Society, Ltd. The paper etc. of a corona company publication (Showa 54) (223)-(240) page are mentioned as a suitable thing.

  In order to impart a desired centerline average roughness to the surface of the base paper, for example, as described in JP-A-58-68037, a fiber length distribution (for example, a 24 mesh screen residue, It is preferable to use pulp fibers having a total of 42 mesh screen residue, for example, 20 to 45% by mass and 24 mesh screen residue of 5% by mass or less. Further, the center line average roughness can be appropriately adjusted by applying heat and pressure to the surface with a machine calendar, a super calendar, or the like.

  The base paper is not particularly limited and can be appropriately selected according to the purpose. For example, natural pulp such as softwood and hardwood, synthetic pulp made of synthetic resin such as polyethylene and polypropylene, or natural pulp and synthetic pulp A mixture etc. are mentioned.

The pulp as the raw material of the base paper is preferably hardwood bleached kraft pulp (LBKP) from the viewpoint of improving the surface smoothness, rigidity and dimensional stability (curlability) of the base paper to a balanced and sufficient level. However, it is also possible to use softwood bleached kraft pulp (NBKP), hardwood sulfite pulp (LBSP), and the like.
For example, a beater or a refiner can be used to beat the pulp.
The Canadian standard freeness of the pulp can control the shrinkage of the paper in the paper making process, so 200-440 ml C.I. S. F. Is more preferred, 250-380 ml C.I. S. F. Is more preferable.
In the pulp slurry obtained after beating the pulp (hereinafter sometimes referred to as “pulp stock”), various additives such as a filler, a dry paper strength enhancer, a sizing agent, A wet paper strength enhancer, a fixing agent, a pH adjuster, and other chemicals are added.

Examples of the filler include calcium carbonate, clay, kaolin, white clay, talc, titanium oxide, diatomaceous earth, barium sulfate, aluminum hydroxide, and magnesium hydroxide.
Examples of the dry paper strength enhancer include cationized starch, cationized polyacrylamide, anionized polyacrylamide, amphoteric polyacrylamide, and carboxy-modified polyvinyl alcohol.
Examples of the sizing agent include fatty acid salts, rosin derivatives such as rosin and maleated rosin, paraffin wax, alkyl ketene dimer, alkenyl succinic anhydride (ASA), compounds containing higher fatty acids such as epoxidized fatty acid amide, etc. Is mentioned.
Examples of the wet paper strength enhancer include polyamine polyamide epichlorohydrin, melamine resin, urea resin, and epoxidized polyamide resin.
Examples of the fixing agent include polyvalent metal salts such as aluminum sulfate and aluminum chloride, and cationic polymers such as cationized starch.
Examples of the pH adjuster include caustic soda and sodium carbonate.
As said other chemical | medical agent, an antifoamer, dye, a slime control agent, a fluorescent whitening agent, etc. are mentioned, for example.
Furthermore, a softening agent etc. can also be added as needed. As the softening agent, for example, those described in New Handbook for Paper Processing (Edited by Paper Medicine Time), pages 554 to 555 (issued in 1980) can be used.

The treatment liquid used for the surface sizing treatment is not particularly limited and may be appropriately selected depending on the intended purpose. For example, a water-soluble polymer compound, a water-resistant substance, a pigment, and the like may be contained. Good.
Examples of the water-soluble polymer compound include cationized starch, polyvinyl alcohol, carboxy-modified polyvinyl alcohol, carboxymethyl cellulose, hydroxyethyl cellulose, cellulose sulfate, gelatin, casein, sodium polyacrylate, styrene-maleic anhydride copolymer sodium. Salt, sodium polystyrene sulfonate, and the like.
Examples of the water-resistant substance include latex / emulsions such as styrene-butadiene copolymer, ethylene-vinyl acetate copolymer, polyethylene, vinylidene chloride copolymer, and polyamide polyamine epichlorohydrin.
Examples of the pigment include calcium carbonate, clay, kaolin, talc, barium sulfate, and titanium oxide.

  The base paper has a longitudinal Young's modulus (Ea) and a transverse Young's modulus (Eb) ratio (Ea / Eb) of 1.5 to 2.0 in terms of improving rigidity and dimensional stability (curling property). The range of is preferable. In the range where the Ea / Eb value is less than 1.5 and exceeds 2.0, the rigidity and curl of the base paper are likely to be deteriorated, which may hinder the runnability during conveyance.

In general, it is known that the “strain” of paper differs based on the difference in the mode of beating, and after the beating, the elasticity (rate) of the paper made by papermaking represents the degree of “strain” of the paper. Can be used as an additional factor. In particular, the relationship between the dynamic elastic modulus indicating the physical properties of the viscoelastic body of paper and the density is used. By measuring the velocity of sound propagating through the paper using an ultrasonic vibration element, the elastic modulus of the paper can be obtained from the following mathematical formula.
E = ρc ² (1-n ² )
In the above formula, E means dynamic elastic modulus. ρ means density. c means the speed of sound in the paper. n means Poisson's ratio.

In the case of normal paper, since n = about 0.2, even if it is calculated by the following formula, it can be calculated without much difference.
E = ρc ²
That is, if the density and sound speed of paper can be measured, the elastic modulus can be easily obtained. In the above formula, when measuring the speed of sound, various known devices such as Sonic Tester SST-110 (manufactured by Nomura Corporation) can be used.

There is no restriction | limiting in particular in the thickness of the said base paper, According to the objective, it can select suitably, For example, 50-300 micrometers is preferable and 100-250 micrometers is more preferable.
The basis weight of the raw paper is not particularly limited and may be appropriately selected depending on the purpose, for example, preferably ^{50~250g / m 2, 100~200g / m} 2 is more preferable.

-Synthetic paper-
The synthetic paper is paper mainly composed of polymer fibers other than cellulose. Examples of the polymer fiber include polyolefin fibers such as polyethylene and polypropylene.

-Synthetic resin sheet (film)-
Examples of the synthetic resin sheet (film) include those obtained by forming a synthetic resin into a sheet shape, such as polypropylene, stretched polyethylene, stretched polypropylene, polyester film, stretched polyester, nylon film, stretched white film, Examples thereof include a white film containing a white pigment.

-Coated paper-
The coated paper is a paper obtained by coating various sheets of resin, rubber latex, or polymer material on one side or both sides of a sheet such as a base paper, and the coating amount varies depending on the application. Examples of the coated paper include art paper, cast coated paper, Yankee paper, and the like.

  As the resin applied to the surface of the base paper or the like, it is preferable to use a thermoplastic resin. Examples of the thermoplastic resin include the thermoplastic resins shown in the following (i) to (viii).

(I) Polyolefin resins such as polyethylene resins and polypropylene resins, copolymer resins of olefins such as ethylene and propylene and other vinyl monomers, acrylic resins, and the like.
(Ii) A thermoplastic resin having an ester bond. For example, a dicarboxylic acid component (these dicarboxylic acid components may be substituted with a sulfonic acid group, a carboxyl group, etc.) and an alcohol component (these alcohol components may be substituted with a hydroxyl group, etc.) Polyester resin, polymethyl methacrylate, polybutyl methacrylate, polymethyl acrylate, polybutyl acrylate and other polyacrylic acid ester resins or polymethacrylic acid ester resins, polycarbonate resins, polyvinyl acetate resins, styrene acrylate resins, styrene -Methacrylic acid ester copolymer resin, vinyl toluene acrylate resin, etc. are mentioned.
Specific examples include those described in JP-A Nos. 59-101395, 63-7971, 63-7972, 63-7973, and 60-294862. it can.
Commercially available products include Byron 290, Byron 200, Byron 280, Byron 300, Byron 103, Byron GK-140, Byron GK-130 manufactured by Toyobo; Kao-made Tufton NE-382, Tufton U-5, ATR- 2009, ATR-2010; Unitika's Elitel UE3500, UE3210, XA-8153, KZA-7049, KZA-1449; Nippon Synthetic Chemical Polyester TP-220, R-188; And various thermoplastic resins.

(Iii) A polyurethane resin etc. are mentioned.
(Iv) Polyamide resin, urea resin, etc. are mentioned.
(V) Polysulfone resin and the like.
(Vi) Polyvinyl chloride resin, polyvinylidene chloride resin, vinyl chloride-vinyl acetate copolymer resin, vinyl chloride-vinyl propionate copolymer resin, and the like.
(Vii) Cellulose resins such as polyol resins, ethyl cellulose resins, and cellulose acetate resins, such as polyvinyl butyral.
(Viii) Polycaprolactone resin, styrene-maleic anhydride resin, polyacrylonitrile resin, polyether resin, epoxy resin, phenol resin and the like.
In addition, a thermoplastic resin may be used individually by 1 type, and may use 2 or more types together.

  The thermoplastic resin may contain a fluorescent whitening agent, a conductive agent, a filler, a pigment or a dye such as titanium oxide, ultramarine blue, or carbon black as required.

-Laminated paper-
The laminated paper is a paper obtained by laminating a polymer sheet or film made of various resins and rubbers on a sheet such as a base paper. Examples of the laminate material include polyolefin, polyvinyl chloride, polyethylene terephthalate, polystyrene, polymethacrylate, polycarbonate, polyimide, triacetyl cellulose, and the like. These may be used individually by 1 type and may use 2 or more types together.

  In general, the polyolefin is often formed using low-density polyethylene. However, in order to improve the heat resistance of the support, polypropylene, a blend of polypropylene and polyethylene, high-density polyethylene, high-density polyethylene and low-density polyethylene are used. It is preferable to use a blend or the like. In particular, it is most preferable to use a blend of high-density polyethylene and low-density polyethylene from the viewpoint of cost, suitability for lamination, and the like.

The blend ratio (mass ratio) of the high-density polyethylene and the low-density polyethylene is preferably 1/9 to 9/1, more preferably 2/8 to 8/2, and still more preferably 3/7 to 7/3. .
When forming a thermoplastic resin layer on both surfaces of the support, the back surface of the support is preferably formed using, for example, high-density polyethylene or a blend of high-density polyethylene and low-density polyethylene.
There is no restriction | limiting in particular as said polyethylene, Although it can select suitably according to the objective, For both high-density polyethylene and low-density polyethylene, melt index is preferable 1.0-40 g / 10min.
In addition, you may perform the process which gives white reflectivity to the said sheet | seat or film. Examples of such a treatment method include a method of blending a pigment such as titanium oxide in these sheets or films.

  There is no restriction | limiting in particular as thickness of the said support body, According to the objective, it can select suitably, For example, 25-300 micrometers is preferable, 50-260 micrometers is more preferable, 75-220 micrometers is still more preferable. The rigidity of the support is not particularly limited and can be used according to the purpose. The support for a photographic image receiving sheet for electrophotography is close to a support for color silver halide photography. Those are preferred.

<Polymer layer>
The polymer layer is provided between the support and a toner image receiving layer formed on the support.
The thickness of the polymer layer is preferably 2 μm or more, and more preferably 3 to 10 μm.
The polymer layer preferably contains a water-soluble polymer or a water-dispersible polymer as a main component, and among these, more preferably contains a rubber-based polymer as a main component.
For example, the composition, bond structure, molecular structure, molecular weight, molecular weight distribution, form and the like of the water-soluble polymer are not particularly limited as long as they are water-soluble. In order to make the polymer water-soluble, for example, the polymer needs to have a water-solubilizing group. Examples of the water-solubilizing group include, for example, a hydroxyl group, a carboxylic acid group, an amino group, an amide group. And ether groups.

  Examples of the water-soluble polymer include Research Disclosure No. 17,643, page 26, No. 18,716, page 651, No. 307,105, pages 873-874, and JP-A No. 64-13,546. (Page 71) to page (75). Specifically, examples of the water-soluble polymer include vinyl pyrrolidone-vinyl acetate copolymer, styrene-vinyl pyrrolidone copolymer, styrene-maleic anhydride copolymer, water-soluble polyester, water-soluble polyurethane, water-soluble nylon. Water-soluble epoxy resin, polyvinyl alcohol (PVA), etc. can be used.

  The water-dispersible polymer is appropriately selected from acrylic resin emulsion, polyvinyl acetate emulsion, SBR (styrene / butadiene / rubber) emulsion, polyester resin emulsion, polystyrene resin emulsion, urethane resin emulsion, etc. You can also. In the case of gelatin, it can be selected from so-called demineralized gelatin with a reduced content of lime-processed gelatin, acid-processed gelatin, calcium and the like, depending on the purpose.

[Toner image receiving layer]
The toner image receiving layer is a toner image receiving layer for receiving color or black toner and forming an image. The toner image receiving layer has a function of receiving toner for forming an image from a developing drum or an intermediate transfer body by (static) electricity, pressure, etc. in a transfer process, and fixing it by heat, pressure, etc. in a fixing process. Have
The toner image receiving layer is formed by applying the image recording layer coating solution. Therefore, the toner image-receiving layer contains a water-dispersible emulsion, an aggregation inhibitor, and a water-soluble polymer compound, and further contains other components as necessary. The water-dispersible emulsion, the aggregation inhibitor, and the water-soluble polymer compound are the same as those described above.

  Examples of other components include thermoplastic resins other than water-dispersible emulsions, and colorants such as pigments and dyes, in which the whiteness of the toner image-receiving layer can be adjusted. It is done. Various additives added for the purpose of improving the thermodynamic properties of the toner image-receiving layer, such as plasticizers, mold release agents or slip agents, matting agents, fillers, crosslinking agents, charge control agents, emulsions, dispersions Thing etc. are mentioned.

  Examples of the thermoplastic resin other than the water dispersible emulsion include (i) polyurethane resin, (ii) polyamide resin, (iii) polysulfone resin, (iv) polyvinyl chloride resin, etc. (v) polyvinyl butyral. (Vi) polycaprolactone resin, (vii) polyolefin resin and the like.

Examples of the (iv) polyvinyl chloride resin include polyvinylidene chloride resin, vinyl chloride-vinyl acetate copolymer resin, vinyl chloride-vinyl propionate copolymer resin, and the like.
Examples of the (v) polyvinyl butyral include cellulose resins such as polyol resin, ethyl cellulose resin, and cellulose acetate resin. Examples of commercially available products include those manufactured by Denki Kagaku Kogyo Co., Ltd. and Sekisui Chemical Co., Ltd. The polyvinyl butyral has a polyvinyl butyral content of 70% by mass or more, an average polymerization degree of 500 or more is preferable, and an average polymerization degree of 1000 or more is more preferable. Examples of commercially available products include Denka Butyral 3000-1, 4000-2, 5000A, 6000C manufactured by Denki Kagaku Kogyo Co., Ltd .; S-REC BL-1, BL-2, BL-3, BL-S, BX manufactured by Sekisui Chemical Co., Ltd. -L, BM-1, BM-2, BM-5, BM-S, BH-3, BX-1, BX-7, and the like.
Examples of the (vi) polycaprolactone resin include styrene-maleic anhydride resin, polyacrylonitrile resin, polyether resin, epoxy resin, phenol resin, and the like.
Examples of the (vii) polyolefin resin include polyethylene resins, polypropylene resins, copolymer resins of olefins such as ethylene and propylene and other vinyl monomers, acrylic resins, and the like.

  The said thermoplastic resin may be used individually by 1 type, may be 2 or more types, In addition to these, these mixtures, these copolymers, etc. can also be used.

Examples of the colorant include fluorescent brighteners, white pigments, colored pigments, dyes, and the like.
The fluorescent whitening agent is a compound that absorbs in the near ultraviolet region and emits fluorescence at 400 to 500 nm, and various known fluorescent whitening agents can be used without particular limitation. Examples of the optical brightener include K.I. Preferable examples include the compounds described in “The Chemistry of Synthetic Dies” edited by Veen Rataraman, Vol. Specific examples include stilbene compounds, coumarin compounds, biphenyl compounds, benzoxazoline compounds, naphthalimide compounds, pyrazoline compounds, carbostyril compounds, and the like. As a commercial item of the said fluorescent whitening agent, Sumitomo Chemical white fur fur PSN, PHR, HCS, PCS, B; UVITEX-OB made from Ciba-Geigy etc. are mentioned, for example.

As said white pigment, inorganic pigments, such as a titanium oxide and a calcium carbonate, can be used, for example.
Examples of the colored pigment include various pigments or azo pigments described in JP-A-63-44653 (for example, azo lake; carmine 6B, red 2B, insoluble azo; monoazo yellow, disazo yellow, pyrazolo orange, vulcan orange, Condensed azo series; chromophyl yellow, chromophthal red), polycyclic pigments (eg, phthalocyanine series; copper phthalocyanine blue, copper phthalocyanine green, dioxazine series; dioxazine violet, isoindolinone series; isoindolinone yellow, slen series Perylene, perinone, flavantron, thioindigo, lake pigment (eg, malachite green, rhodamine B, rhodamine G, Victoria blue B), or inorganic pigment (eg, oxide, titanium dioxide, bengara, sulfate; precipitation sulfur Barium, carbonate; precipitated calcium carbonate, succinate; hydrous succinate, anhydrous succinate, metal powder; aluminum powder, bronze powder, zinc dust, carbon black, yellow lead, bitumen, etc.) .
These may be used alone or in combination of two or more. Among these, titanium oxide is particularly preferable as the pigment.

  There is no restriction | limiting in particular as a shape of the said pigment, According to the objective, it can select suitably, It is preferable that it is a hollow particle shape at the point which is excellent in the heat conductivity at the time of image fixing (low thermal conductivity).

As the dye, various dyes such as oil-soluble dyes and water-insoluble dyes can be used.
Examples of the oil-soluble dye include anthraquinone compounds and azo compounds.
Examples of the water-insoluble dye include C.I. I. Vat violet 1, C.I. I. Vat violet 2, C.I. I. Vat violet 9, C.I. I. Vat violet 13, C.I. I. Vat violet 21, C.I. I. Vat Blue 1, C.I. I. Vat Blue 3, C.I. I. Vat Blue 4, C.I. I. Vat Blue 6, C.I. I. Vat Blue 14, C.I. I. Vat Blue 20, C.I. I. Vat dyes such as Vat Blue 35; I. Dispers Violet 1, C.I. I. Disperse Violet 4, C.I. I. Disperse Violet 10, C.I. I. Disperse Blue 3, C.I. I. Disperse Blue 7, C.I. I. Disperse dyes such as Disperse Blue 58; I. Solvent Violet 13, C.I. I. Solvent Violet 14, C.I. I. Solvent Violet 21, C.I. I. Solvent Violet 27, C.I. I. Solvent Blue 11, C.I. I. Solvent Blue 12, C.I. I. Solvent Blue 25, C.I. I. Solvent Blue 55, and the like.
A colored coupler used in silver salt photography can also be preferably used.

Of the colorant, the content in the toner image-receiving layer (surface) is preferably ^{0.1~8g / m 2, 0.5~5g / m} 2 is more preferable.
When the content of the colorant is less than 0.1 g / m ² , the light transmittance in the toner image-receiving layer may be increased. When the content exceeds 8 g / m ² , handling such as cracking and adhesion resistance is performed. May decrease.

The release agent is blended in the toner image receiving layer in order to prevent the toner image receiving layer from being offset. The release agent is heated and melted at the fixing temperature, and is deposited on the surface of the toner image receiving layer and unevenly distributed on the surface of the toner image receiving layer. Further, there is no particular limitation as long as it forms a release agent material layer on the surface of the toner image receiving layer by cooling and solidification, and it can be appropriately selected according to the purpose.
Examples of the release agent include at least one selected from a silicone compound, a fluorine compound, a wax, and a matting agent. Among these, at least one selected from silicone oil, polyethylene wax, carnauba wax, silicone particles, and polyethylene wax particles is particularly preferable.

  As the mold release agent, for example, compounds described in Sachishobo "Revised Wax Properties and Applications", a silicone handbook published by Nikkan Kogyo Shimbun, Ltd. can be used. JP-B-59-38581, JP-B-4-32380, Patent Nos. 2838498, 2949558, JP-A-50-117433, 52-52640, 57-148755, 61-62056. 61-62057, 61-118760, JP-A-2-42451, 3-41465, 4-212175, 4-214570, 4-263267, 5-34966, 5-119514, 6-59502, 6-161150, 6-175396, 6-219040, 6-230600, 6-295093, 7-36210, 7 -43940, 7-56387, 7-56390, 7-64335, 7-199682, 7-223362 7-287413, 8-184992, 8-227180, 8-248671, 8-248799, 8-248801, 8-278663, 9-152939, 9 -160278, 9-185181, 9-319139, 9-319143, 10-20549, 10-48889, 10-198069, 10-207116, 11-2917 No. 11-44969, No. 11-65156, No. 11-73049, No. 11-194542, and the silicone compounds, fluorine compounds, and waxes used in the toners are also preferably used. . A plurality of these compounds can be used in combination.

  Examples of the silicone compounds include unmodified silicone oils as silicone oils (specifically, dimethylsiloxane oil, methyl hydrogen silicone oil, phenylmethyl silicone oil, commercially available products KF-96, KF-96L manufactured by Shin-Etsu Chemical Co., Ltd.) KF-96H, KF-99, KF-50, KF-54, KF-56, KF-965, KF-968, KF-994, KF-995, HIVAC F-4, F-5; Toray Dow Corning SH200 made of silicone, SH203, SH490, SH510, SH550, SH710, SH704, SH705, SH7028A, SH7036, SM7060, SM7001, SM7706, SH7036, SH8710, SH1107, SH8627; Toshiba TSF4 0, TSF401, TSF404, TSF405, TSF431, TSF433, TSF434, TSF437, TSF450 series, TSF451 series, TSF456, TSF458 series, TSF483, TSF484, TSF4045, TSF4300, TSF4600, YF33 series, YF-3057, YF-3800 3802, YF-3804, YF-3807, YF-3897, XF-3905, XS69-A1753, TEX100, TEX101, TEX102, TEX103, TEX104, TSW831, etc., amino-modified silicone oil (KF manufactured by Shin-Etsu Chemical Co., Ltd. as a commercial product) -857, KF-858, KF-859, KF-861, KF-864, KF-880, Toray Dow Corning Siri SF8417, SM8709 manufactured by Corn, TSF4700, TSF4701, TSF4702, TSF4702, TSF4704, TSF4705, TSF4706, TEX150, TEX151, TEX154, etc. Toshiba silicone TSF4770, XF42-A9248, etc.), carbinol modified silicone oil (commercially available Toshiba Silicone XF42-B0970 etc.), vinyl modified silicone oil (commercially available Toshiba Silicone XF40-A1987 etc.), epoxy modified silicone oil (Toray Dow Corning Silicone SF8411, SF8413; Toshiba Silicone TS 3965, TSF4730, TSF4732, XF42-A4439, XF42-A4438, XF42-A5041, XC96-A4462, XC96-A4463, XC96-A4464, TEX170, etc., polyether-modified silicone oil (KF-351 manufactured by Shin-Etsu Chemical Co., Ltd. as a commercial product) (A), KF-352 (A), KF-353 (A), KF-354 (A), KF-355 (A), KF-615 (A), KF-618, KF-945 (A); Toray Dow Corning Silicone SH3746, SH3771, SF8421, SF8419, SH8419, SH8410; Toshiba Silicone TSF4440, TSF4441, TSF4445, TSF4446, TSF4450, TSF4452, TSF4453, TSF44 0), silanol-modified silicone oil, methacryl-modified silicone oil, mercapto-modified silicone oil, alcohol-modified silicone oil (commercially available products include Toray Dow Corning Silicone SF8427, SF8428, Toshiba Silicone TSF4750, TSF4751, XF42-B0970, etc.) , Alkyl-modified silicone oils (Toray Dow Corning Silicone SF8416, Toshiba Silicone TSF410, TSF411, TSF4420, TSF4421, TSF4422, TSF4450, XF42-334, XF42-A3160, XF42-A3161, etc.), fluorine-modified silicone Oil (commercially available Toray Dow Corning Silicone FS1265, Toshiba Silicone FQF5 01, etc.), silicone rubber and silicone fine particles (commercially available products are SH851U, SH745U, SH55UA, SE4705U, SH502UA & B, SRX539U, SE6770U-P, DY38-038, DY38-047, Trefill F-201, F manufactured by Toray Dow Corning Silicone) -202, F-250, R-900, R-902A, E-500, E-600, E-601, E-506, BY29-119; Toshiba Silicone Tospearl 105, 120, 130, 145, 240, 3120 Etc.), silicone-modified resin (specifically, olefin resin, polyester resin, vinyl resin, polyamide resin, cellulose resin, phenoxy resin, vinyl chloride-vinyl acetate resin, urethane resin, acrylic resin, styrene-acrylic resin) As a commercially available product such as a compound obtained by modifying these copolymer resins with silicone, etc., Daiichi Seika's Dialomer SP203V, SP712, SP2105, SP3023; Nippon Oil & Fats Modiper FS700, FS710, FS720, FS730, FS770; -270, US-350, US-352, US-380, US-413, US-450, Reseda GP-705, GS-30, GF-150, GF-300; Toray Dow Corning Silicone SH997, SR2114 , SH2104, SR2115, SR2202, DCI-2577, SR2317, SE4001U, SRX625B, SRX643, SRX439U, SRX488U, SH804, SH840, SR2107, SR2115; Toshiba Silicon YR3370, TSR1122, TSR102, TSR108, TSR116, TSR117, TSR125A, TSR127B, TSR144, TSR180, TSR187, YR47, YR3187, YR3224, YR3232, YR3270, YR3286, YR3340, YR1365, TE1X Reactive silicone compounds (specifically, there are addition reaction type, peroxide curable type, ultraviolet curable type, commercially available TSR1500, TSR1510, TSR1511, TSR1515, TSR1520, YR3286, YR3340, PSA6574, TPR6500, manufactured by Toshiba Silicone) TPR6501, TPR6600, TPR6702, TPR6604, TPR6700, TPR6701, TPR6705, TPR6707, TPR6708, TPR6710, TPR6712, TPR6721, TPR6722, UV9300, UV9315, UV9425, UV9430, XS56-A2775, XS56-A2982, XS56-A3075, XS56-A3969, XS56-S5680 B1794, SL6100, SM3000, SM3030, SM3200, YSR3022, and the like.

  Examples of the fluorine compound include fluorine oil (Daikin Industries # 1, # 3, # 10, # 20, # 50, # 100, Unidyne TG-440, TG-452, TG-490, TG as commercially available products). -560, TG-561, TG-590, TG-652, TG-670U, TG-991, TG-999, TG-3010, TG-3020, TG-3510; TF-100, MF-110 manufactured by Tochem Products , MF-120, MF-130, MF-160, MF-160E; Asahi Glass Surflon S-111, S-112, S-113, S-121, S-131, S-132, S-141, S- 145; Mitsui Fluorochemicals FC-430, FC-431, etc.), fluoro rubber (Toray Dow Corning Silicone L as a commercial product) 63U, etc.), fluorine-modified resin (Nippon Yushi Modiper F200, F220, F600, F2020, F3035; Dainichi Seika's Dialomers FF203, FF204; Asahi Glass Surflon S-381, S-383, S-393, SC -101, SC-105, KH-40, SA-100; manufactured by Tochem Products EF-351, EF-352, EF-801, EF-802, EF-601, TFE, TFEA, TFEMA, PDFOH; manufactured by Sumitomo 3M THV-200P, etc.), fluorine sulfonic acid compounds (commercially available products from Tochem Products such as EF-101, EF-102, EF-103, EF-104, EF-105, EF-112, EF-121, EF-122A, EF-122B, EF-122C, EF-123A, EF-12 B, EF-125M, EF-132, EF-135M, EF-305, FBSA, KFBS, LFBS, etc.), fluorosulfonic acid, fluoric acid compound or a salt thereof (specifically, anhydrous hydrofluoric acid, dilute hydrofluoric acid, borofluoride) Acid, zinc borofluoride, nickel borofluoride, tin borofluoride, lead borofluoride, copper borofluoride, silicofluoric acid, potassium fluorotitanate, perfluorocaprylic acid, ammonium perfluorooctanoate), inorganic fluoride (specific Includes aluminum fluoride, potassium silicofluoride, potassium fluoride zirconate, zinc fluoride tetrahydrate, calcium fluoride, lithium fluoride, barium fluoride, tin fluoride, potassium fluoride, potassium acid fluoride, Magnesium fluoride, fluorinated titanate, fluorinated zirconate, ammonium hexafluorophosphate, hexafluoride And potassium phosphate).

  Examples of the wax include synthetic hydrocarbons, modified waxes, hydrogenated waxes, natural waxes, and the like.

  Examples of the synthetic hydrocarbon include polyethylene wax (as commercial products, Polylon A, 393, H-481, manufactured by Chukyo Yushi Co., Ltd., Sanyo Kasei Sun Wax E-310, E-330, E-250P, LEL-250, LEL- 800, LEL-400P, etc.), polypropylene wax (commercially available Sanyo Chemical Co., Ltd. Biscol 330-P, 550-P, 660-P), Fischer-Tropsch wax (commercially available products such as Nippon Seiki FT100, FT-0070, etc.) , Acid amide compounds or acid imide compounds (specifically, stearamide, phthalimide anhydride, etc., commercially available products such as Chukyo Oil & Fats Cellosol 920, B-495, High Micron G-270, G-110, Hydrin D- 757) and the like.

  Examples of the modified wax include amine-modified polypropylene (QN-7700 manufactured by Sanyo Chemical Co., Ltd. as a commercial product), acrylic acid-modified, fluorine-modified, olefin-modified wax, and urethane type wax (NPS-6010 manufactured by Nippon Seiki Co., Ltd. as a commercial product). -5090), alcohol type wax (NPS-9210, NPS-9215, OX-1949, XO-020T, etc., manufactured by Nippon Seiki) and the like.

  Examples of the hydrogenated wax include hardened castor oil (as a commercially available product, castor wax from Ito Oil Co., Ltd.), castor oil derivatives (dehydrated castor oil DCO, DCO Z-1, DCO Z-3, castor from Ito Oil as commercial products). Oil fatty acid CO-FA, ricinoleic acid, dehydrated castor oil fatty acid DCO-FA, dehydrated castor oil fatty acid epoxy ester D-4 ester, castor oil-based urethane acrylate CA-10, CA-20, CA-30, castor oil derivative MINERASOL S -74, S-80, S-203, S-42X, S-321, Special castor oil-based condensed fatty acid MINERASOL RC-2, RC-17, RC-55, RC-335, Special castor oil-based condensed fatty acid ester MINERASOL LB-601, LB-603, LB-604, LB-702, L B-703, # 11, L-164, etc.), stearic acid (12-hydroxystearic acid made by Ito Oil as a commercial product), lauric acid, myristic acid, palmitic acid, behenic acid, sebacic acid (as commercial products) Sebacic acid from Ito Oil), undecylenic acid (such as undecylenic acid from Ito Oil as a commercial product), heptylic acid (such as heptyl acid from Ito Oil as a commercial product), maleic acid, highly maleated oil (as a commercial product) HIMALIN DC-15, LN-10, 00-15, DF-20, SF-20, etc., manufactured by Ito Oil Co., Ltd., blown oil (commercially available, Celbonol # 10, # 30, # 60, R-40 manufactured by Ito Oil Co., Ltd.) , S-7, etc.), cyclopentadiene oil (CP oil, CP oil-S, etc. made by Ito Oil Co., Ltd. as commercial products) and the like.

  The natural wax is preferably at least one selected from plant waxes, animal waxes, mineral waxes and petroleum waxes, and more preferably plant waxes. As the natural wax, a water-dispersed wax is particularly preferable from the viewpoint of compatibility when a water-based thermoplastic resin is used as the thermoplastic resin of the toner image-receiving layer.

Examples of the plant wax include carnauba wax (Nippon Seiki EMUSTAR-0413, Chukyo Yushi Cellosol 524, etc. as commercial products), castor oil (commercially available Ito Oil refined castor oil, etc.), rapeseed oil, large Examples include bean oil, wax, cotton wax, rice wax, sugarcane wax, candelilla wax, Japan wax, jojoba oil, and the like. Among these, in particular, it has an excellent offset resistance, adhesion resistance, paper permeability, glossiness, is resistant to cracking, and can provide an electrophotographic image-receiving sheet capable of forming a high-quality image. Is particularly preferably a carnauba wax having a temperature of 70 to 95 ° C.
Examples of the animal wax include beeswax, lanolin, spermaceti, stew wax (whale oil), and wool wax.

  Examples of the mineral wax include, for example, montan wax, montan ester wax, ozokerite, ceresin, and fatty acid ester (commercially available products are Nippon Sanka's Sansosizer DOA, AN-800, DINA, DIDA, DOZ, DOS, TOTM, TITM. , E-PS, nE-PS, E-PO, E-4030, E-6000, E-2000H, E-9000H, TCP, C-1100, etc.). Among these, in particular, it has an excellent offset resistance, adhesion resistance, paper permeability, glossiness, is resistant to cracking, and can provide an electrophotographic image-receiving sheet capable of forming a high-quality image. Is particularly preferably a montan wax having a temperature of 70 to 95 ° C.

  Examples of the petroleum wax include paraffin wax (paraffin wax 155, 150, 140, 135, 130, 125, 120, 115, HNP-3, HNP-5, HNP-9, HNP- 10, HNP-11, HNP-12, HNP-14G, SP-0160, SP-0145, SP-1040, SP-1035, SP-3040, SP-3035, NPS-8070, NPS-L-70, OX- 2151, OX-2251, EMUSTAR-0384, EMUSTAR-0136, Chukyo Oil & Fats Cellosol 686, 428, 651-A, A, H-803, B-460, E-172, 866, K-133, Hydrin D-337 E-139, 125 ° paraffin, 125 ° FD, 130 ° Fins, 135 ° paraffin, 135 ° H, 140 ° paraffin, 140 ° N, 145 ° paraffin, paraffin wax M, etc., microcrystalline wax (commercially available from Nihon Seiki Hi-Mic-2095, Hi-Mic-3090) , Hi-Mic-1080, Hi-Mic-1070, Hi-Mic-2065, Hi-Mic-1045, Hi-Mic-2045, EMUSTAR-0001, EMUSTAR-042X, Chukyo Oil & Fats Cellosol 967, M, Nisseki Mitsubishi Petroleum (manufactured by Nippon Seiki OX-1749, OX-0450, OX-0650B, OX-0153, OX-261BN, OX-0551, OX-0550, OX) -0750B, JP- 500, JP-056R, such as JP-011P), and the like.

The content in the toner image-receiving layer (surface) of the natural wax is preferably ^{0.1~4g / m 2, 0.2~2g / m} 2 is more preferable. When the content is less than 0.1 g / m ² , offset resistance and adhesion resistance may be particularly insufficient. When the content exceeds 4 g / m ² , the amount of wax is excessive and formed. The image quality may be inferior.

  The melting point (° C.) of the natural wax is preferably 70 to 95 ° C., more preferably 75 to 90 ° C., particularly in terms of offset resistance and paper passing properties.

  Examples of the matting agent include various known ones. Solid particles used as the matting agent can be classified into inorganic particles and organic particles. Specific examples of the material for the inorganic matting agent include oxides (for example, silicon dioxide, titanium oxide, magnesium oxide, aluminum oxide), alkaline earth metal salts (for example, barium sulfate, calcium carbonate, magnesium sulfate), halogens Examples include silver halide (eg, silver chloride, silver bromide) and glass.

  Examples of the inorganic matting agent include West German Patent 2529321, British Patent 760775, 1260772, U.S. Patent 1201905, 2192241, 3030562, 3030649, 3257206, 3322555, and 3353958. No. 3,370,951, No. 3,411,907, No. 3,437,484, No. 3523022, No. 3,615,554, No. 3,635,714, No. 3769020, No. 40212245, and No. 4029504.

The material of the organic matting agent includes starch, cellulose ester (for example, cellulose acetate propionate), cellulose ether (for example, ethyl cellulose) and synthetic resin. The synthetic resin is preferably water-insoluble or poorly water-soluble. Examples of the water-insoluble or poorly water-soluble synthetic resin include poly (meth) acrylic acid esters (for example, polyalkyl (meth) acrylate, polyalkoxyalkyl (meth) acrylate, polyglycidyl (meth) acrylate), poly (meth) acrylate. ) Acrylamide, polyvinyl ester (eg, polyvinyl acetate), polyacrylonitrile, polyolefin (eg, polyethylene), polystyrene, benzoguanamine resin, formaldehyde condensation polymer, epoxy resin, polyamide, polycarbonate, phenol resin, polyvinyl carbazole, polyvinylidene chloride, etc. Is mentioned.
You may use the copolymer which combined the monomer used for the above polymer.

In the case of the copolymer, a small amount of hydrophilic repeating units may be contained. Examples of the monomer that forms the hydrophilic repeating unit include acrylic acid, methacrylic acid, α, β-unsaturated dicarboxylic acid, hydroxyalkyl (meth) acrylate, sulfoalkyl (meth) acrylate, and styrene sulfonic acid.
Examples of the organic matting agent include British Patent No. 1055713, U.S. Pat. Nos. 1,939,213, 2221873, 2268661, 2322037, 2376005, 2391181, 2701245, 2992101, and 3079257. Nos. 3,262,782, 3,443,946, 3,516,832, 3,539,344, 3,591,379, 3,754,924, 3,767,448, JP-A-49-106821, JP-A-57-14835 Are described in the above.
Two or more kinds of solid particles may be used in combination. The average particle size of the solid particles is, for example, preferably 1 to 100 μm, and more preferably 4 to 30 μm. The amount of the solid particles is preferably ^{0.01~0.5g / m 2, 0.02~0.3g / m} 2 is more preferable.

  As the release agent added to the toner image-receiving layer of the present invention, these derivatives, oxides, purified products, and mixtures can also be used. Moreover, these may have a reactive substituent.

The melting point (° C.) of the release agent is particularly preferably 70 to 95 ° C., and more preferably 75 to 90 ° C. in terms of offset resistance and paper passing properties.
The release agent is preferably a water-dispersed release agent, particularly in terms of compatibility when an aqueous thermoplastic resin is used as the thermoplastic resin of the toner image receiving layer.

  The content of the release agent in the toner image-receiving layer is preferably 1 to 20% by mass, more preferably 1 to 8.0% by mass, and still more preferably 1 to 5.0% by mass.

As the plasticizer, known plasticizers for resins can be used without particular limitation. The plasticizer has a function of adjusting the flow or softening of the toner image-receiving layer by either heat or pressure when fixing the toner.
The plasticizers include “Chemical Handbook” (edited by the Chemical Society of Japan, Maruzen), “Plasticizers—Theory and Applications” (Kouichi Murai, edited by Koshobo), “Research on plasticizers”, “Research on plasticizers” "Lower" (edited by Polymer Chemistry Association), "Handbook Rubber and Plastic Compounded Chemicals" (edited by Rubber Digest Co., Ltd.), etc.

  Examples of the plasticizer include phthalic acid esters, phosphoric acid esters, fatty acid esters, abietic acid esters, adipic acid esters, sebacic acid esters, azelaic acid esters, benzoic acid esters, butyric acid esters. Epoxidized fatty acid esters, glycolic acid esters, propionic acid esters, trimellitic acid esters, citric acid esters, sulfonic acid esters, carboxylic acid esters, succinic acid esters, maleic acid esters, fumaric acid Esters, phthalic acid esters, stearic acid esters, etc .; amides (for example, fatty acid amides, sulfoamides, etc.), ethers, alcohols, lactones, polyethyleneoxys, etc. -83154, 59-178451 59-178453, 59-178454, 59-178455, 59-178457, 62-174754, 62-245253, 61-209444, 61-200538, 62 No.-8145, No. 62-9348, No. 62-30247, No. 62-136646, No. 62-174754, No. 62-245253, No. 61-209444, No. 61-200538, No. 62-8145 Nos. 62-9348, 62-30247, 62-136646, JP-A-2-235694, etc.). In addition, the said plasticizer can be mixed and used for resin.

  A relatively low molecular weight polymer can be used as the plasticizer. In this case, the molecular weight of the plasticizer is preferably lower than the molecular weight of the binder resin to be plasticized. The molecular weight is preferably 15000 or less, and more preferably 5000 or less. In the case of a polymer plasticizer, the polymer is preferably the same type as the binder resin to be plasticized. For example, a low molecular weight polyester is preferable for plasticizing a polyester resin. Furthermore, oligomers can also be used as plasticizers. In addition to the above compounds, commercially available products include, for example, Adeka Sizer PN-170, PN-1430 manufactured by Asahi Denka Kogyo; P. HALL products PARAPLEX-G-25, G-30, G-40; Rika Hercules products Ester gum 8L-JA, Ester R-95, Pentaline 4851, FK115, 4820, 830, Louisol 28-JA, Picolastic A75, Pico Tex LC, Crystallex 3085, etc. are mentioned.

The plasticizer relieves stress and strain (physical strain such as elastic force and viscosity, strain due to mass balance of molecules, binder main chain, pendant, etc.) generated when toner particles are embedded in the toner image receiving layer. Can be used arbitrarily to
The plasticizer may be in a micro-dispersed state in the toner image-receiving layer, may be in a phase-separated microscopically in a sea-island shape, or may be in a sufficiently mixed and dissolved state with other components such as a binder.
The content of the plasticizer in the toner image-receiving layer is preferably 0.001 to 90% by mass, more preferably 0.1 to 60% by mass, and still more preferably 1 to 40% by mass.
The plasticizer adjusts smoothness (improves transportability due to reduced frictional force), improves fixing unit offset (detachment of toner and layers from the fixing unit), adjusts curl balance, and adjusts charging (toner electrostatic image It may be used for the purpose of forming).

As said filler, an organic or inorganic filler is mentioned, A well-known thing can be used as a reinforcing agent for binder resin, a filler, and a reinforcing material. The filler should be selected with reference to "Handbook Rubber / Plastic Compounding Chemicals" (edited by Rubber Digest Co., Ltd.), "New Edition Plastic Compounding Agent Fundamentals and Applications" (Taiseisha), "Filler Handbook" (Taiseisha), etc. Can do.
As the filler, an inorganic filler (or inorganic pigment) can be suitably used. Examples of the inorganic filler (inorganic pigment) include silica, alumina, titanium dioxide, zinc oxide, zirconium oxide, mica-like iron oxide, white lead, lead oxide, cobalt oxide, strontium chromate, molybdenum-based pigment, smectite, magnesium oxide. , Calcium oxide, calcium carbonate, mullite, and the like. Among these, silica and alumina are preferable. These may be used alone or in combination of two or more. Moreover, as said filler, a thing with a small particle size is preferable. If the particle size is large, the surface of the toner image-receiving layer tends to be roughened.

The silica includes spherical silica and amorphous silica. The silica can be synthesized by a dry method, a wet method, or an airgel method. The surface of the hydrophobic silica particles may be surface-treated with a trimethylsilyl group or silicone. As silica, colloidal silica is preferable. The average particle size of the silica is preferably 4 to 120 nm, and more preferably 4 to 90 nm.
The silica is preferably porous. The average pore diameter of the porous silica is preferably 50 to 500 nm. Moreover, the average pore volume per mass of the porous silica is preferably, for example, 0.5 to 3 ml / g.

  The alumina includes anhydrous alumina and alumina hydrate. As the crystal form of anhydrous alumina, α, β, γ, δ, ζ, η, θ, κ, ρ, or χ can be used. Alumina hydrate is preferred over anhydrous alumina. As the alumina hydrate, a monohydrate or a trihydrate can be used. Alumina monohydrate includes pseudoboehmite, boehmite and diaspore. Alumina trihydrate includes dibsite and bayerite. As an average particle diameter of an alumina, 4-300 nm is preferable and 4-200 nm is more preferable. Alumina is preferably porous. The average pore diameter of the porous alumina is preferably 50 to 500 nm. The average pore volume per mass of the porous alumina is preferably 0.3 to 3 ml / g.

The alumina hydrate can be synthesized by a sol-gel method in which ammonia is added to an aluminum salt solution to precipitate, or a method in which an alkali aluminate is hydrolyzed. Anhydrous alumina can be obtained by dehydrating alumina hydrate by heating.
The amount of the filler added is preferably 5 to 2000 parts by mass with respect to 100 parts by mass of the dry mass of the binder of the toner image receiving layer.

  The cross-linking agent can be added to adjust the storage stability, thermoplasticity, etc. of the toner image-receiving layer. As the cross-linking agent, a compound having two or more known reactive groups in the molecule as epoxy groups, isocyanate groups, aldehyde groups, active halogen groups, active methylene groups, acetylene groups and the like as reactive groups is used.

As the crosslinking agent, a compound having two or more groups capable of forming a bond by a hydrogen bond, an ionic bond, a coordination bond, or the like can also be used.
Examples of the crosslinking agent include resin coupling agents, curing agents, polymerization agents, polymerization accelerators, coagulants, film-forming agents, film-forming aids, and the like. Examples of the coupling agent include chlorosilanes, vinyl silanes, epoxy silanes, aminosilanes, alkoxyaluminum chelates, titanate coupling agents, etc., and “Handbook Rubber / Plastic Compounding Chemicals” (edited by Rubber Digest Co., Ltd.). ) Etc. can be used.

  The charge control agent is contained in order to adjust toner transfer, adhesion, and the like in the toner image receiving layer and to prevent charge adhesion of the toner image receiving layer. As the charge control agent, conventionally known various charge control agents can be used. Examples of the charge control agent include cationic surfactants, anionic surfactants, amphoteric surfactants, surfactants such as nonionic surfactants, polymer electrolytes, conductive metal oxides, and the like. Can be used. For example, quaternary ammonium salts, polyamine derivatives, cation-modified polymethyl methacrylate, cationic antistatic agents such as cation-modified polystyrene, anionic antistatic agents such as alkyl phosphates and anionic polymers, nonionics such as fatty acid esters and polyethylene oxide Examples thereof include, but are not limited to, antistatic agents.

When the toner has a negative charge, for example, a cation or nonion is preferable as the charge control agent to be blended in the toner image receiving layer.
Examples of the conductive metal oxide include ZnO, TiO ₂ , SnO ₂ , Al ₂ O ₃ , In ₂ O ₃ , SiO ₂ , MgO, BaO, and MoO ₃ . These conductive metal oxides may be used alone or in combination with these composite oxides. The conductive metal oxide may further contain a different element. For example, Al, In, etc. with respect to ZnO, Nb, Ta, etc. with respect to TiO ₂ , and Sb with respect to SnO ₂ . , Nb, halogen elements and the like can be contained (doping).

  The material that can be used for the toner image-receiving layer may contain various additives for improving the stability of the output image or for improving the stability of the toner image-receiving layer itself. Examples of the additive include various known antioxidants, antioxidants, deterioration inhibitors, ozone deterioration inhibitors, ultraviolet absorbers, metal complexes, light stabilizers, preservatives, fungicides, and the like.

  Examples of the antioxidant include a chroman compound, a coumaran compound, a phenol compound (eg, hindered phenol), a hydroquinone derivative, a hindered amine derivative, and a spiroindane compound. The antioxidant is described in JP-A No. 61-159644.

  Examples of the antiaging agent include those described in “Handbook Rubber / Plastic Compounding Chemicals Revised 2nd Edition” (1993, Rubber Digest Co.) p76-121.

  Examples of the ultraviolet absorber include a benzotriazole compound (described in US Pat. No. 3,533,794), a 4-thiazolidone compound (described in US Pat. No. 3,352,681), a benzophenone compound (described in Japanese Patent Laid-Open No. Sho 46-2784), Examples thereof include ultraviolet absorbing polymers (described in JP-A-62-260152).

  Examples of the metal complex include U.S. Pat. Nos. 4,241,155, 4,425,018, and 4,254,195, JP-A-61-88256, JP-A-62-174741, JP-A-63-199248, and JP-A-1-75568. No. 1-74272.

  As described above, known photographic additives can be added to the material that can be used for the toner image-receiving layer. Examples of the photographic additive include, for example, Research Disclosure Magazine (hereinafter abbreviated as RD) No. 17643 (December 1978), 18716 (November 1979), and 307105 (November 1989), and the corresponding parts are summarized below.

Type of additive RD17643 RD18716 RD307105
1. Brightener 24 pages 648 right column 868 pages 2. Stabilizer Pages 24-25 Page 649 Right column 868-870 Light Absorber Page 25-26 Page 649 Right Column 873 (Ultraviolet Absorber)
4). Dye image stabilizer page 25 page 650 right column page 872 5. Hardener 26 pages 651 left column 874-875 6. Binder page 26 page 651 left column pages 873-874 Plasticizer, lubricant page 27 page 650 right column page 876 8. Coating aid 26-27 pages 650, right column 875-876 (surfactant)
9. Antistatic agent page 27 page 650 right column pages 876-877
Ten. Matting agent 878-879 pages

[Physical properties of toner image-receiving layer]
The thickness of the toner image receiving layer is preferably 1 to 50 μm, and more preferably 5 to 15 μm, for example.
The toner image-receiving layer has a 180 degree peel strength at a fixing temperature with the fixing member of preferably 0.1 N / 25 mm or less, and more preferably 0.041 N / 25 mm or less.
Here, the 180-degree peel strength can be measured according to the method described in JIS K6887 using the surface material of the fixing member.
The toner image receiving layer preferably has high whiteness. The whiteness is preferably 85% or more as measured by the method defined in JIS P8123. Further, it is preferable that the spectral reflectance is 85% or more in the wavelength region of 440 nm to 640 nm and the difference between the maximum spectral reflectance and the minimum spectral reflectance in the same wavelength region is within 5%. Furthermore, it is more preferable that the spectral reflectance is 85% or more in the wavelength region of 400 nm to 700 nm, and the difference between the maximum spectral reflectance and the minimum spectral reflectance in the same wavelength region is within 5%.
Further, as the whiteness, specifically, in the CIE 1976 (L ^* a ^* b ^* ) color space, the L ^* value is preferably 80 or more, more preferably 85 or more, and still more preferably 90 or more. Further, the white color is preferably as neutral as possible. As the white color, in the L ^* a ^* b ^* space, the value of (a ^* ) ² + (b ^* ) ² is preferably 50 or less, more preferably 18 or less, and still more preferably 5 or less.

The toner image receiving layer preferably has a high glossiness. As the glossiness, the 45 ° glossiness is preferably 60 or more, more preferably 75 or more, and still more preferably 90 or more in the entire region from white without toner to black having the maximum density.
However, the glossiness is preferably 110 or less. When the glossiness exceeds 110, it becomes like metallic luster, which is not preferable for image quality.
The glossiness can be measured based on JIS Z8741.

The toner image-receiving layer preferably has physical properties of one of the following items, more preferably a plurality of items, and most preferably all physical properties.
(1) Tm (melting temperature) of the toner image-receiving layer is preferably 30 ° C. or higher, and more preferably Tm + 20 ° C. or lower of the toner.
(2) The temperature at which the viscosity of the toner image-receiving layer becomes 1 × 10 ⁵ cp is preferably 40 ° C. or higher, and more preferably lower than that of the toner.
(3) The storage elastic modulus (G ′) at the fixing temperature of the toner image receiving layer is preferably 1 × 10 ² to 1 × 10 ⁵ Pa. The loss elastic modulus (G ″) is preferably 1 × 10 ² to 1 × 10 ⁵ Pa.
(4) The loss tangent (G ″ / G ′), which is the ratio of the loss elastic modulus (G ″) at the fixing temperature of the toner image receiving layer and the storage elastic modulus (G ′), is preferably from 0.01 to 10.
(5) The storage elastic modulus (G ′) at the fixing temperature of the toner image-receiving layer is preferably −50 to +2500 with respect to the loss elastic modulus (G ″) at the fixing temperature of the toner.
(6) The inclination angle of the molten toner on the toner image-receiving layer is preferably 50 degrees or less, and more preferably 40 degrees or less.
The toner image-receiving layer satisfies the physical properties disclosed in Japanese Patent No. 2788358, Japanese Patent Application Laid-Open Nos. 7-248637, 8-305067, and 10-239889. preferable.

The toner image-receiving layer preferably has a surface electrical resistance in the range of 1 × 10 ⁶ to 1 × 10 ¹⁵ Ω / cm ² (under conditions of 25 ° C. and 65% RH).
If the surface electrical resistance is less than 1 × 10 ⁶ Ω / cm ² , the amount of toner when the toner is transferred to the toner image-receiving layer is not sufficient, and the density of the resulting toner image tends to be low. If it exceeds 1 × 10 ¹⁵ Ω / cm ² , an excessive charge is generated at the time of transfer, the toner is not sufficiently transferred, the image density is low, and the image receiving sheet for electrophotography is charged with static electricity. Dust may be easily attached. Misfeeds, double feeds, discharge marks, toner transfer missing, etc. may occur during copying.

The surface electrical resistance of the surface opposite to the toner image-receiving layer with respect to the support is preferably 5 × 10 ^{8 to} 3.2 × 10 ¹⁰ Ω / cm ² and 1 × 10 ⁹ to 1 × 10 ^10. More preferable is Ω / cm ² .
Here, the surface electrical resistance is measured in accordance with JIS K6911. The sample is conditioned for 8 hours or more in an environment of temperature 20 ° C. and humidity 65%, and R8340 manufactured by Advantest Corporation is used in the same environment. In addition, the measurement can be performed after 1 minute has passed since energization under the condition of an applied voltage of 100V.

  Examples of the other layers include a surface protective layer, a back layer, an adhesion improving layer, an undercoat layer, a cushion layer, a charge control (preventing) layer, a reflective layer, a tint adjusting layer, a storage stability improving layer, an adhesion preventing layer, Examples thereof include an anti-curl layer and a smoothing layer. These layers may be composed of a single layer or may be composed of two or more layers.

  The surface protective layer is used for the purpose of protecting the surface of the electrophotographic image-receiving sheet, improving storage stability, improving handleability, imparting writing properties, improving instrument passage properties, imparting anti-offset properties, and the like. It can be provided on the surface of the image receiving layer. The surface protective layer may be a single layer or may be composed of two or more layers. In the surface protective layer, various thermoplastic resins, thermosetting resins, and the like can be used as a binder, and it is preferable to use the same type of resin as the toner image receiving layer. However, thermodynamic characteristics, electrostatic characteristics, and the like do not need to be the same as those of the toner image-receiving layer, and can be optimized.

The surface protective layer may contain the various additives described above that can be used for the toner image-receiving layer. In particular, the surface protective layer may be blended with other additives such as a matting agent in addition to the release agent used in the present invention. In addition, as said mat agent, various well-known things are mentioned.
The outermost surface layer in the electrophotographic image-receiving sheet (for example, the surface protective layer when a surface protective layer is formed) preferably has good compatibility with the toner from the viewpoint of fixability. Specifically, the contact angle with the melted toner is preferably, for example, 0 to 40 degrees.

In the electrophotographic image-receiving sheet, the back layer is provided on the opposite side of the toner image-receiving layer with respect to the support for the purpose of imparting backside output suitability, improving backside output image quality, improving curl balance, and improving device passability. It is preferred that
Although there is no restriction | limiting in particular as a color of the said back layer, When the said electrophotographic image receiving sheet is a double-sided output type image receiving paper which forms an image also in a back surface, it is preferable that a back layer is also white. The whiteness and the spectral reflectance are preferably 85% or more like the surface.
Further, the back layer may have the same structure as that of the toner image receiving layer for improving the duplex output suitability. Various additives described above can be used for the back layer. As such an additive, it is particularly preferable to add a matting agent, a charge adjusting agent, or the like. The back layer may have a single layer configuration or a stacked configuration of two or more layers.
Further, in order to prevent offset at the time of fixing, when a releasable oil is used for the fixing roller or the like, the back layer may be oil absorbing.

  The adhesion improving layer is preferably formed for the purpose of improving the adhesion between the support and the toner image receiving layer in the electrophotographic image receiving paper. The above-mentioned various additives can be blended in the adhesion improving layer, and it is particularly preferable to blend a crosslinking agent. The electrophotographic image-receiving sheet is preferably further provided with a cushion layer or the like between the adhesion improving layer and the toner image-receiving layer in order to improve toner acceptability.

〔toner〕
The electrophotographic image-receiving sheet is used by allowing a toner image-receiving layer to receive toner during printing or copying.
The toner contains at least a binder resin and a colorant, and if necessary, a release agent and other components.

-Toner binder resin-
Examples of the binder resin include styrenes such as styrene and parachlorostyrene; vinyl esters such as vinyl naphthalene, vinyl chloride, vinyl bromide, vinyl fluoride, vinyl acetate, vinyl propionate, vinyl benzoate, and vinyl butyrate; Methyl acrylate, ethyl acrylate, n-butyl acrylate, isobutyl acrylate, dodecyl acrylate, n-octyl acrylate, 2-chloroethyl acrylate, phenyl acrylate, methyl α-chloroacrylate, methyl methacrylate, methacryl Methylene aliphatic carboxylic acid esters such as ethyl acetate and butyl methacrylate; Vinyl nitriles such as acrylonitrile, methacrylonitrile, and acrylamide; Vinyl ethers such as vinyl methyl ether, vinyl ethyl ether, and vinyl isobutyl ether Tells; N-vinyl compounds such as N-vinyl pyrrole, N-vinyl carbazole, N-vinyl indole, N-vinyl pyrrolidone; single weight of vinyl monomers such as vinyl carboxylic acids such as methacrylic acid, acrylic acid and cinnamic acid Copolymers, copolymers thereof, and various polyesters can be used, and various waxes can be used in combination.
Among these resins, it is preferable to use a resin of the same system as that used for the toner image receiving layer.

-Toner Colorant-
As the colorant, those usually used in toners can be used without limitation. For example, carbon black, chrome yellow, hansa yellow, benzidine yellow, sren yellow, quinoline yellow, permanent orange GTR, pyrazolone. Orange, Vulcan Orange, Watch Young Red, Permanent Red, Brilliantamine 3B, Brilliantamine 6B, Daypon Oil Red, Pyrazolone Red, Risor Red, Rhodamine B Lake, Lake Red C, Rose Bengal, Aniline Blue, Ultramarine Blue, Calco Examples include various pigments such as oil blue, methylene blue chloride, phthalocyanine blue, phthalocyanine green, and malachite green oxalelate. Acridine, xanthene, azo, benzoquinone, azine, anthraquinone, thioindico, dioxazine, thiazine, azomethine, indico, thioindico, phthalocyanine, aniline black, polymethine, triphenyl Examples include various dyes such as methane, diphenylmethane, thiazine, thiazole, and xanthene. These colorants may be used alone or in combination of two or more.
The content of the colorant is preferably in the range of 2 to 8% by mass. If the content of the colorant is 2% by mass or more, the coloring power is not weakened. On the other hand, if it is 8% by mass or less, the transparency is not impaired, which is preferable.

-Toner release agent-
As the mold release agent, all known waxes can be used in principle, but polar waxes containing nitrogen such as relatively low molecular weight high crystalline polyethylene wax, Fischer-Tropsch wax, amide wax, urethane compound, etc. Etc. are particularly effective. The polyethylene wax preferably has a molecular weight of 1000 or less, more preferably 300 to 1000.

  The compound having a urethane bond is suitable because even if it has a low molecular weight, the solid state can be maintained and the melting point can be set high for the molecular weight due to the strength of cohesive force due to the polar group. The molecular weight is preferably from 300 to 1,000. Examples of the raw materials include combinations of diisocyanate compounds and monoalcohols, combinations of monoisocyanic acid and monoalcohols, combinations of dialcohols and monoisocyanic acid, combinations of trialcohols and monoisocyanic acid, Various combinations such as a combination of an isocyanate compound and a monoalcohol can be selected. However, in order not to increase the molecular weight, it is preferable to combine a compound having a polyfunctional group and a monofunctional group. In addition, it is important to have an equivalent functional group amount.

Specific examples of the raw material compound include monoisocyanate compounds such as dodecyl isocyanate, phenyl isocyanate and derivatives thereof, naphthyl isocyanate, hexyl isocyanate, benzyl isocyanate, butyl isocyanate, and allyl isocyanate. It is done.
Examples of the diisocyanate compound include tolylene diisocyanate, 4,4′diphenylmethane diisocyanate, toluene diisocyanate, 1,3-phenylene diisocyanate, hexamethylene diisocyanate, 4-methyl-m-phenylene diisocyanate, and isophorone diisocyanate. Can be mentioned.
As the monoalcohol, it is possible to use very common alcohols such as methanol, ethanol, propanol, butanol, pentanol, hexanol, and heptanol.
Among the raw material compounds, as the dialcohols, a number of glycols such as ethylene glycol, diethylene glycol, triethylene glycol, trimethylene glycol; as the trialcohols, trimethylolpropane, triethylolpropane, trimethanolethane, etc. can be used. However, it is not necessarily limited to this range.

These urethane compounds can be mixed with a resin and a colorant at the time of kneading and used as a kneaded and pulverized toner as in a normal release agent. Also, when used in the emulsion polymerization aggregation melting toner described above, it is dispersed in water together with a polymer electrolyte such as an ionic surfactant, a polymer acid or a polymer base, and heated to a melting point or higher to produce a homogenizer or pressure discharge. A fine dispersion is obtained by applying strong shearing with a mold disperser to prepare a release agent particle dispersion of 1 μm or less, which can be used together with a resin particle dispersion, a colorant dispersion and the like.
The content of the release agent in the toner is preferably 1 to 20% by mass, and more preferably 1 to 10% by mass.

-Toner and other components-
The toner may contain other components such as an internal additive, a charge control agent, and inorganic fine particles. As said internal additive, magnetic bodies, such as metals, alloys, such as a ferrite, magnetite, reduced iron, cobalt, nickel, manganese, an alloy, or a compound containing these metals, can be used, for example.

  Examples of the charge control agent include various commonly used charge control agents such as quaternary ammonium salt compounds, nigrosine compounds, dyes composed of complexes of aluminum, iron, chromium, and triphenylmethane pigments. Can do. A material that is difficult to dissolve in water is preferable from the viewpoint of controlling the ionic strength that affects the stability during aggregation and melting and reducing wastewater contamination.

  Examples of the inorganic fine particles include silica, alumina, titania, calcium carbonate, magnesium carbonate, and tricalcium phosphate. Usually, all external additives on the toner surface can be used, and these can be used as ionic surfactants or polymer acids. It is preferable to use it dispersed in a polymer base.

  In addition, a surfactant can be used for emulsion polymerization, seed polymerization, pigment dispersion, resin particle dispersion, mold release dispersion, aggregation, and stabilization thereof. For example, anionic surfactants such as sulfate ester, sulfonate, phosphate, and soap, cationic surfactants such as amine salt type and quaternary ammonium salt type, polyethylene glycol type, alkylphenol It is also effective to use a nonionic surfactant such as an ethylene oxide adduct system or a polyhydric alcohol system in combination. As a dispersing means at that time, a general means such as a rotary shear type homogenizer, a ball mill having a media, a sand mill, a dyno mill or the like can be used.

An external additive may be further added to the toner as necessary. Examples of the external additive include inorganic particles and organic particles.
Examples of the inorganic particles include SiO ₂ , TiO ₂ , Al ₂ O ₃ , CuO, ZnO, SnO ₂ , Fe ₂ O ₃ , MgO, BaO, CaO, K ₂ O, Na ₂ O, ZrO ₂ , CaO. Examples thereof include SiO ₂ , K ₂ O. (TiO ₂ ) _n , Al ₂ O ₃ .2SiO ₂ , CaCO ₃ , MgCO ₃ , BaSO ₄ , MgSO _{4 and the} like.
As the organic particles, fatty acid or derivatives thereof, powders of these metal salts, and resin powders such as fluorine-based resins, polyethylene resins, and acrylic resins can be used. For example, the average particle size of these powders is preferably 0.01 to 5 μm, and more preferably 0.1 to 2 μm.

  The method for producing the toner is not particularly limited and may be appropriately selected depending on the purpose. (I) A step of forming aggregated particles in a dispersion obtained by dispersing resin particles to prepare an aggregated particle dispersion (Ii) adding and mixing a fine particle dispersion in which fine particles are dispersed in the aggregated particle dispersion to adhere the fine particles to the aggregated particles to form the adhered particles; and (iii) the attached particles. And a step of forming a toner particle by heating and fusing the toner.

-Toner physical properties-
The volume average particle diameter of the toner of the present invention is preferably from 0.5 μm to 10 μm.
If the volume average particle size of the toner is too small, there may be an adverse effect on toner handling (replenishability, cleaning properties, fluidity, etc.), and particle productivity may be reduced. On the other hand, if the volume average particle size of the toner is too large, the image quality and resolution due to graininess and transferability may be adversely affected.
Further, it is preferable that the toner of the present invention satisfies the volume average particle diameter range of the toner, and the volume average particle size distribution index (GSDv) is 1.3 or less.
The ratio (GSDv / GSDn) of the volume average particle size distribution index (GSDv) to the number average particle size distribution index (GSDn) is preferably 0.95 or more.
Further, the toner of the present invention preferably satisfies the range of the volume average particle diameter of the toner, and the average value of the shape factor represented by the following formula is preferably 1.00 to 1.50.
Shape factor = (π × L ² ) / (4 × S)
In the above formula, L represents the maximum length of toner particles. S represents the projected area of the toner particles.
When the toner satisfies the above conditions, it is effective for image quality, particularly graininess, and resolution, and it is difficult for transfer and omission to occur, and handling properties are not adversely affected even if the average particle size is not small. Become.

  The storage elastic modulus G ′ (measured at an angular frequency of 10 rad / sec) at 150 ° C. of the toner itself is suitably 10 to 200 Pa from the viewpoint of improving the image quality and preventing the offset property in the fixing process.

(Image forming method)
The image forming method of the present invention comprises a toner image forming step of forming a toner image on the electrophotographic image receiving sheet of the present invention, a belt fixing comprising a heating and pressing member, a belt member, and a cooling device. A fixing and smoothing step of heating and pressurizing using a mold smoothing processor, cooling and peeling, and further having other means as necessary.

-Toner image forming process-
The toner image forming step is not particularly limited as long as it can form a toner image on an electrophotographic image-receiving sheet, and can be appropriately selected according to the purpose. For example, a normal electrophotographic method can be used. The method used, for example, a direct transfer method in which a toner image formed on a developing roller is transferred to an electrophotographic image receiving sheet, or an intermediate transfer belt that is transferred to an electrophotographic image receiving sheet after primary transfer to an intermediate transfer belt or the like There is a method. From the viewpoint of environmental stability and high image quality, an intermediate transfer belt system is preferably used.

-Fixing smoothing process-
The fixing and smoothing step is a step of heating and pressurizing the toner image using a belt fixing type smoothing processor having a heating and pressing member, a belt member, and a cooling device, cooling and peeling the toner image.
The belt fixing type smoothing processor includes a heating / pressurizing member, a belt member, and a cooling device, and further includes a cooling separation portion and other members as necessary.

The heating and pressing member is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include a pair of heating rollers and a combination of a heating roller and a pressing roller.
There is no restriction | limiting in particular as said cooling device, Although it can select suitably according to the objective, For example, a cooling device, a heat sink, etc. which can blow cold air and can adjust cooling temperature etc. are used.
The cooling peeling portion is not particularly limited and may be appropriately selected depending on the purpose. The cooling peeling portion means a position in the vicinity of the tension roller that peels from the belt by the rigidity (waist strength) of the electrophotographic image receiving sheet itself.

It is preferable to apply pressure when contacting the heating and pressing member of the belt fixing type smoothing processor. There is no restriction | limiting in particular as this pressurization method, According to the objective, it can select suitably, It is preferable to apply nip pressure. The nip pressure is preferably 1 to 100 kgf / cm ^{2 and} more preferably 5 to 30 kgf / cm ² from the viewpoint of forming an image having excellent water resistance and surface smoothness and good gloss. Further, the heating in the heating and pressing member is a temperature equal to or higher than the softening point of the thermoplastic resin in the toner image receiving layer, and varies depending on the thermoplastic resin used, but is usually preferably 80 ° C. or higher and 200 ° C. or lower. The cooling temperature in the cooling device is preferably 80 ° C. or lower, more preferably 20 to 80 ° C., at which the thermoplastic resin in the toner image-receiving layer is sufficiently solidified.

The belt member includes a heat resistant support film and a release layer formed on the support film.
The support film is not particularly limited as long as it has heat resistance, and can be appropriately selected according to the purpose. For example, polyimide (PI), polyethylene naphthalate (PEN), polyethylene terephthalate (PET), Examples include polyetheretherketone (PEEK), polyethersulfone (PES), polyetherimide (PEI), polyparabanic acid (PPA), and the like.

  The release layer is preferably at least one selected from silicone rubber, fluorine rubber, fluorocarbon siloxane rubber, silicone resin and fluorine resin. Among these, a mode in which a fluorocarbon siloxane rubber layer is provided on the surface of the belt member and a mode in which a silicone rubber layer is provided on the surface of the belt member and a fluorocarbon siloxane rubber layer is provided on the surface of the silicone rubber layer are preferable.

The fluorocarbon siloxane rubber preferably has at least one of a perfluoroalkyl ether group and a perfluoroalkyl group in the main chain.
As said fluorocarbon siloxane rubber, the hardened | cured material of the fluorocarbon siloxane rubber composition containing the following (A)-(D) component is suitable.
(A) a fluorocarbon polymer having a fluorocarbon siloxane represented by the following general formula (1) as a main component and having an aliphatic unsaturated group; (B) containing two or more ≡SiH groups in one molecule; Organopolysiloxane and / or fluorocarbon siloxane having an ≡SiH group content of 1 to 4 times the molar amount of the aliphatic unsaturated group in the product, (C) a filler, and (D) an effective amount of catalyst.

  The (A) component fluorocarbon polymer is mainly composed of a fluorocarbon siloxane having a repeating unit represented by the following general formula (1) and has an aliphatic unsaturated group.

In the general formula (1), R ¹⁰ is an unsubstituted or substituted monovalent hydrocarbon group having 1 to 8 carbon atoms, preferably an alkyl group having 1 to 8 carbon atoms or alkenyl having 2 to 3 carbon atoms. And a methyl group is particularly preferable.
a and e each represents an integer of 0 or 1; b and d each represent an integer of 1 to 4. c represents an integer of 0 to 8. Further, x is preferably 1 or more, and more preferably 10-30.

  As said (A) component, what is shown by following General formula (2) can be mentioned.

  In the component (B), examples of the organopolysiloxane having an ≡SiH group include organohydrogenpolysiloxanes having at least two hydrogen atoms bonded to silicon atoms in the molecule.

  In the fluorocarbon siloxane rubber composition, when the fluorocarbon polymer of the component (A) has an aliphatic unsaturated group, the above-described organohydrogenpolysiloxane is preferably used as the curing agent. . That is, a cured product is formed by an addition reaction that occurs between an aliphatic unsaturated group in the fluorocarbon siloxane and a hydrogen atom bonded to a silicon atom in the organohydrogenpolysiloxane.

  As the organohydrogenpolysiloxane, various organohydrogenpolysiloxanes used in addition-curable silicone rubber compositions can be used.

  In general, the number of ≡SiH groups in the organohydrogenpolysiloxane is preferably at least one with respect to one aliphatic unsaturated hydrocarbon group in the fluorocarbon siloxane as the component (A). It is more preferable to mix | blend in the ratio which becomes an individual.

In addition, the fluorocarbon having a ≡SiH group includes the unit of the above general formula (1) or the above general formula (1), wherein R ¹⁰ is a dialkylhydrogensiloxy group and the terminal is a dialkylhydrogensiloxy group or a silyl group. What is SiH groups, such as group, is preferable, and what is shown by following General formula (3) can be mentioned.

  As the filler of the component (C), various fillers used in general silicone rubber compositions can be used. Examples of the filler include fumed silica, precipitated silica, carbon powder, titanium dioxide, aluminum oxide, quartz powder, reinforcing filler such as talc, sericite, bentonite, asbestos, glass fiber, organic fiber, and the like. Examples thereof include fibrous fillers.

  As the catalyst of the component (D), chloroplatinic acid, alcohol-modified chloroplatinic acid, complexes of chloroplatinic acid and olefin, platinum black or palladium, which are known as addition reaction catalysts, alumina, silica, carbon, etc. And a compound of group VIII of the periodic table such as a complex of rhodium and olefin, chlorotris (triphenylphosphine) rhodium (Wilkinson catalyst), rhodium (III) acetylacetonate or the like. However, these complexes are preferably used by dissolving in a solvent such as an alcohol compound, an ether compound, or a hydrocarbon compound.

  There is no restriction | limiting in particular in the said fluorocarbon siloxane rubber composition, Although it can select suitably according to the objective, Various compounding agents can be added. For example, diphenylsilane diol, low-polymerization degree molecular chain terminal hydroxyl-blocked dimethylpolysiloxane, dispersant such as hexamethyldisilazane, heat resistance improver such as ferrous oxide, ferric oxide, cerium oxide, iron octylate Further, colorants such as pigments can be blended as necessary.

  The belt member is obtained by coating the surface of the heat-resistant support film with the fluorocarbon siloxane rubber composition and heat-curing, but if necessary, m-xylene hexafluoride, benzotrifluoride, etc. It can be applied by a general coating method such as spray coating, dip coating and knife coating. Moreover, the temperature and time of heat-curing can be selected suitably, and are suitably selected according to the kind of a support film, a manufacturing method, etc. in the range of temperature 100-500 degreeC and 5 second-5 hours.

  The thickness of the release layer formed on the surface of the heat-resistant support film is not particularly limited, but is 1 to 200 μm in order to obtain good image fixability by preventing toner releasability or toner component offset. Is preferable, and 5-150 micrometers is more preferable.

Hereinafter, an example of an image forming apparatus having a typical fixing belt device will be described.
The belt fixing type smoothing processor as shown in FIG. 6 is modified as a belt-like fixing unit of the electrophotographic apparatus (for example, a full color laser printer (DCC-500) manufactured by Fuji Xerox Co., Ltd.) shown in FIG. Can be used.
In FIG. 5, reference numeral 200 denotes an image forming apparatus, 37 denotes a photosensitive drum, 19 denotes a developing device, 31 denotes an intermediate transfer belt, 18 denotes an electrophotographic image receiving sheet, and 25 denotes a fixing belt portion (belt fixing device).
FIG. 6 shows a fixing belt portion (belt fixing device) 25 disposed in the image forming apparatus 200 of FIG.
As shown in FIG. 6, the belt fixing device 25 includes a heating roller 71, a peeling roller 74 including the heating roller 71, an endless belt 73 rotatably supported by a tension roller 75, and the heating roller 71. And a pressure roller 72 that is in pressure contact with the endless belt 73.
A cooling heat sink 77 for forcibly cooling the endless belt 73 is disposed between the heating roller 71 and the peeling roller 74 on the inner surface side of the endless belt 73. 77 constitutes a cooling / sheet conveying section for cooling the electrophotographic image-receiving sheet and conveying the sheet.

  In the belt fixing device 25, as shown in FIG. 6, an electrophotographic transfer sheet having a color toner image transferred and fixed on its surface is pressed against the heating roller 71 and the heating roller 71 via an endless belt 73. The color toner image is introduced into the pressure contact portion (nip portion) with the pressure roller 72 to be positioned so as to be positioned on the heating roller 71 side, and passes through the pressure contact portion between the heating roller 71 and the pressure roller 72. The color toner image is heated and melted and fixed on the electrophotographic image receiving sheet.

  Thereafter, in the pressure contact portion (nip portion) between the heating roller 71 and the pressure roller 72, for example, the toner is heated to a temperature of about 120 to 130 ° C. and melted to form a color toner image on the image receiving layer. The fixed electrophotographic image-receiving sheet is conveyed together with the endless belt 73 while the image-receiving layer on the surface is in close contact with the surface of the endless belt 73. Meanwhile, the endless belt 73 is forcibly cooled by a cooling heat sink 77, and after the color toner image and the image receiving layer are cooled and solidified, the peeling roller 74 uses the waist (rigidity) of the electrophotographic image receiving sheet itself. It is peeled off.

  The surface of the endless belt 73 after the peeling process is completed is prepared for the next fixing process by removing residual toner and the like by a cleaner (not shown).

<Inkjet recording material>
Examples of the ink jet recording material include liquid inks such as water-based inks (using dyes or pigments as coloring materials) and oil-based inks on a support, solid inks at room temperature, and melt-liquefied printing. And the like having a colorant receiving layer capable of receiving solid ink or the like to be used in the above.

<Heat development material>
Examples of the heat developing material include a method in which at least a heat-meltable ink receiving layer is provided on a support, and the ink is melted and transferred from the heat-meltable ink layer to a heat transfer receiving sheet by heating with a thermal head. Is mentioned.

<Sublimation transfer sheet>
As the sublimation transfer sheet, for example, the support has at least a heat diffusible dye (sublimation dye) receiving layer, and is heated by a thermal head to transfer the heat diffusible dye from the ink layer onto the sublimation transfer sheet. The sublimation transfer method to perform is mentioned.

<Thermal recording material>
As the heat-sensitive recording material, for example, a thermoautochrome method (TA method) has a structure in which at least a thermochromic layer is provided on a support and forms an image by repeating heating with a heat-sensitive head and fixing with ultraviolet rays. And the like.

<Silver halide photographic materials>
The silver halide salt photographic material has, for example, a structure in which an image recording layer that develops color at least on YMC is provided on the image recording material support of the present invention, and is subjected to printing exposure. Examples include a silver halide photographic system in which a sheet is passed through a plurality of processing tanks while being immersed, and color development, bleach-fixing, washing with water and drying are performed.

(Method for producing image recording material)
The method for producing an image recording material of the present invention is a method for producing an image recording material having a support and at least one image recording layer on at least one surface of the support, and the preparation of a coating solution for an image recording layer A process and an image recording layer forming process, and further including other processes as necessary.

-Coating solution preparation process for image recording layer-
In the image recording layer coating liquid preparation step, an aggregation inhibitor having a portion capable of interacting with a surface functional group in the resin particles in the water-dispersible emulsion is added to the water-dispersible emulsion, In this step, a molecular compound is added to prepare an image recording layer coating solution.
In this image recording layer coating solution preparation step, first, an aggregation inhibitor is added to the water-dispersible emulsion to interact with surface functional groups (for example, carboxylic acid amide groups) in the resin particles in the water-dispersible emulsion. Thus, the water-soluble polymer compound is added in a state where aggregation of the resin particles in the water-dispersible emulsion is prevented. As a result, a coating solution for an image recording layer having no aggregation and having an appropriate viscosity and excellent coating suitability can be prepared.
In addition, as the water-dispersible emulsion, the aggregation inhibitor, and the water-soluble polymer compound, those similar to the coating liquid for the image recording layer can be appropriately selected and used.

-Image recording layer forming process-
The image recording layer forming step is a step of forming the image recording layer by coating the coating solution for the image recording layer on the support.
Examples of the coating method include a wire coater method, a spin coat method, a dip coat method, a kneader coat method, a curtain coat method, and a blade coat method. Among these, the spin coating method, the dip coating method, and the like are preferable in terms of coating efficiency.
There is no restriction | limiting in particular as an application quantity of the coating liquid for said image recording layers, According to the objective, it can select suitably, 2-10 g / m < ² > is preferable at a dry solid content.

  EXAMPLES Hereinafter, although an Example demonstrates this invention in detail, this invention is not limited to the following Example at all.

(Example 1)
-Preparation of coating solution for toner image-receiving layer-
To 8 g of water dispersible polyester emulsion (KZA-A464S, solid content: 30% by mass, manufactured by Unitika Ltd.), 0.08 g of a surfactant as an aggregation inhibitor (Rapisol A90, manufactured by Nippon Oil & Fats Co., Ltd.) was added and mixed. . Next, 0 to 5 g of polyethylene oxide (Alcox R1000, manufactured by Meisei Chemical Co., Ltd., 8% by mass aqueous solution) as a water-soluble polymer compound is mixed with the obtained mixed liquid, and the toner image-receiving layer of Example 1 is mixed. A coating solution was prepared.

(Example 2)
-Preparation of coating solution for toner image-receiving layer-
10 g of water dispersible polyester emulsion (KZA-A464S, solid content 30% by mass, manufactured by Unitika Co., Ltd.) 10 g was added and mixed with 0.16 g of a surfactant (Lapisol A90, manufactured by Nippon Oil & Fats Co., Ltd.) as an aggregation inhibitor. . Next, 0 to 5 g of polyethylene oxide (Alcox R1000, manufactured by Meisei Chemical Co., Ltd., 8% by mass aqueous solution) as a water-soluble polymer compound is mixed with the obtained mixed liquid, and the toner image-receiving layer of Example 2 is mixed. A coating solution was prepared.

(Example 3)
-Preparation of coating solution for toner image-receiving layer-
To 10 g of water-dispersible polyester emulsion (KZA-A464S, solid content 30% by mass, manufactured by Unitika Ltd.), 0.3 g of crown ether (18-crown-O-6-ether) as an aggregation inhibitor was added and mixed. . Next, 0 to 5 g of polyethylene oxide (Alcox R1000, manufactured by Meisei Chemical Co., Ltd., 8% by mass aqueous solution) as a water-soluble polymer compound is mixed with the obtained mixed liquid, and the toner image-receiving layer of Example 3 is mixed. A coating solution was prepared.

Example 4
-Preparation of coating solution for toner image-receiving layer-
To 10 g of water-dispersible polyester emulsion (KZA-A464S, solid content 30% by mass, manufactured by Unitika Ltd.), 0.3 g of crown ether (15-crown-O-5-ether) as an aggregation inhibitor was added and mixed. . Next, 0 to 5 g of polyethylene oxide (Alcox R1000, manufactured by Meisei Chemical Co., Ltd., 8% by mass aqueous solution) as a water-soluble polymer compound was mixed with the obtained mixed liquid, and the toner image-receiving layer of Example 4 was mixed. A coating solution was prepared.

(Comparative Example 1)
-Preparation of coating solution for toner image-receiving layer-
Polyethylene oxide as a water-soluble polymer compound (Alcox R1000, Meisei Chemical Co., Ltd., 8 mass% aqueous solution) in 10 g of water dispersible polyester emulsion (KZA-A464S, solid content 30 mass%, manufactured by Unitika Ltd.) Was mixed to prepare a toner image-receiving layer coating solution of Comparative Example 1.

(Comparative Example 2)
-Preparation of coating solution for toner image-receiving layer-
To 10 g of water dispersible polyester emulsion (KZA-A464S, solid content 30% by mass, manufactured by Unitika Co., Ltd.), 0.04 g of a surfactant (Lapisol A90, manufactured by Nippon Oil & Fats Co., Ltd.) as an aggregation inhibitor was added and mixed. . Next, 0 to 5 g of polyethylene oxide (Alcox R1000, manufactured by Meisei Chemical Co., Ltd., 8% by mass aqueous solution) as a water-soluble polymer compound is mixed with the obtained mixed solution, and the toner image-receiving layer of Comparative Example 2 is mixed. A coating solution was prepared.

(Comparative Example 3)
-Preparation of coating solution for toner image-receiving layer-
To 10 g of water-dispersible polyester emulsion (KZA-A464S, solid content 30% by mass, manufactured by Unitika Ltd.), 0.3 g of crown ether (12-crown-O-4-ether) as an aggregation inhibitor was added and mixed. . Next, 0 to 5 g of polyethylene oxide (Alcox R1000, manufactured by Meisei Chemical Industry Co., Ltd., 8% by mass aqueous solution) as a water-soluble polymer compound is mixed with the obtained mixed solution, and the toner image receiving of Comparative Example 3 is obtained. A layer coating solution was prepared.

<Evaluation of aggregation>
In each of the obtained toner image-receiving layer coating solutions, the viscosity was measured by changing the amount of polyethylene oxide added as a water-soluble polymer compound. The viscosity was measured with a rheometer (manufactured by Dynalyzer Rheologicalka) using a parallel plate (diameter 20 mm) while changing the shear rate from ¹ to 1000 s ⁻¹ at a gap interval of 0.5 mm and adjusting to 25 ° C. At that time, the viscosity A (Pa · s) at 25 ° C. of the coating liquid before adding the aggregation inhibitor into the water-dispersible emulsion and 1.0 mass of polyethylene oxide in solid content with respect to the mixed liquid. % The viscosity ratio (B / A) with the viscosity B (Pa · s) at 25 ° C. of the coating solution added was calculated. The presence or absence of aggregation was determined from a viscosity curve with respect to the added amount of polyethylene oxide. That is, in the rheometer, when the viscosity suddenly increased from a certain concentration of polyethylene oxide, it was judged that agglomeration had occurred, and evaluation was performed according to the following criteria. The results are shown in Table 1, FIG. 1 and FIG.
〔Evaluation criteria〕
X: Viscosity increased rapidly and aggregation occurred.
○: The same viscosity increase as when water was added (no aggregation).
△ ・ ・ ・ Intermediate between × and ○ (with some aggregation)

<NMR measurement>
An aqueous solution was prepared by adding 0.02 g of the crown ether used in Examples 3 and 4 and Comparative Example 3 to 1 ml of water-dispersible polyester emulsion (KZA-A464S, manufactured by Unitika Ltd.). This solution was transferred to the outer tube of a double tube NMR probe, and D ₂ O added with acetonitrile (CH ₃ CN) as an internal standard substance was injected into the inner tube. INOVA400 (manufactured by Varian Inc.) was used as a measuring apparatus, and the CH ₂ peak line width of crown ether near δ70 was measured by ¹ H-NMR and δ3.5 by ¹³ H-NMR. The results are shown in Table 2, FIG. 3 and FIG.

-Preparation of support-
Wood pulp made of LBKP (hardwood bleached pulp) was beaten to 300 ml of Canadian Freeness (CSF) with a double disc refiner to prepare a pulp material.
For 100 parts by weight of this pulp material, 1.0 part by weight of cationic starch, 0.5 part by weight of alkyl ketene dimer, 0.5 part by weight of epoxidized fatty acid amide, 0.3 part by weight of polyamine polyamide epichlorohydrin, high grade 0.03 parts by mass of fatty acid ester and 0.02 parts by mass of colloidal dull silica were added. This was adjusted to a basis weight of 165 g / m ² by a long paper machine and calendered to prepare a base paper having a thickness of 155 to 175 μm (a density of 0.94 to 1.06 g / cm ³ ).

A blend of high density polyethylene (HDPE) and low density polyethylene (LDPE) (HDPE / LDPE = 7/3 (mass ratio)) is extruded to the thickness of 15 μm by extrusion coating method (310 ° C.) on the back side of the obtained base paper. A back PE layer was formed so as to be.
Next, a surface PE layer was formed to a thickness of 31 μm by extrusion coating (310 ° C.) with low density polyethylene (LDPE) on the surface of the base paper. Thus, double-sided polyethylene laminated paper as a support was produced.

(Example 5)
-Production of electrophotographic image-receiving sheet-
On the surface PE layer of the support, a polymer layer composition having the following composition was applied and dried so as to have a coating thickness of 5 μm when dried with a wire coater to form a polymer layer. Next, the toner image-receiving layer coating solution (polyethylene oxide blending amount 1.3 g) of Example 1 was applied onto the polymer layer with a wire coater so that the coating thickness when dried was 5 μm, and dried to obtain a toner image. A layer was formed. Thus, an electrophotographic image receiving sheet of Example 1 was produced.
-Preparation of composition for polymer layer-
A composition for a polymer layer was prepared by mixing 100 g of acrylic latex (Hiloss HE1335, manufactured by Seiko Chemical Industry Co., Ltd.) and 210 g of water.

(Example 6)
-Production of electrophotographic image-receiving sheet-
Example 5 was the same as Example 5 except that the toner image-receiving layer coating solution of Example 2 (polyethylene oxide compounding amount 1.3 g) was used instead of the toner image-receiving layer coating solution of Example 1. Thus, an electrophotographic image-receiving sheet of Example 6 was produced.

(Example 7)
-Production of electrophotographic image-receiving sheet-
In Example 5, the same procedure as in Example 5 was used, except that the toner image-receiving layer coating solution of Example 3 (polyethylene oxide content 1.3 g) was used instead of the toner image-receiving layer coating solution of Example 1. Thus, an electrophotographic image-receiving sheet of Example 7 was produced.

(Example 8)
-Production of electrophotographic image-receiving sheet-
Example 5 was the same as Example 5 except that the toner image-receiving layer coating solution of Example 4 (polyethylene oxide content 1.3 g) was used instead of the toner image-receiving layer coating solution of Example 1. Thus, an electrophotographic image-receiving sheet of Example 8 was produced.

(Comparative Example 4)
-Production of electrophotographic image-receiving sheet-
In Example 5, the same procedure as in Example 5 was used, except that the toner image-receiving layer coating solution of Comparative Example 1 (polyethylene oxide content 1.3 g) was used instead of the toner image-receiving layer coating solution of Example 1. Thus, an electrophotographic image-receiving sheet of Comparative Example 4 was produced.

(Comparative Example 5)
-Production of electrophotographic image-receiving sheet-
Example 5 was the same as Example 5 except that the toner image-receiving layer coating solution of Comparative Example 2 (polyethylene oxide content 1.3 g) was used instead of the toner image-receiving layer coating solution of Example 1. Thus, an electrophotographic image-receiving sheet of Comparative Example 5 was produced.

(Comparative Example 6)
-Production of electrophotographic image-receiving sheet-
In Example 5, the same procedure as in Example 5 was used, except that the toner image-receiving layer coating solution of Comparative Example 3 (polyethylene oxide content 1.3 g) was used instead of the toner image-receiving layer coating solution of Example 1. Thus, an electrophotographic image-receiving sheet of Comparative Example 6 was produced.

(Comparative Example 7)
-Production of electrophotographic image-receiving sheet-
In Example 5, the same procedure as in Example 5 was used except that the toner image-receiving layer coating solution prepared as follows was used instead of the toner image-receiving layer coating solution of Example 1. A photographic image-receiving sheet was prepared.
--- Preparation of coating solution for toner image-receiving layer-
To 3 g of water dispersible polyester emulsion (KZA-A464S, manufactured by Unitika Co., Ltd.), 13 g of polyethylene oxide (Alcox R1000, manufactured by Meisei Chemical Co., Ltd., 8% by mass aqueous solution) as a water-soluble polymer compound was added and mixed. . To the obtained mixed solution, 0.08 g of a surfactant (Lapisol A90, manufactured by Nippon Oil & Fats Co., Ltd.) as an aggregation inhibitor and 7 g of water were mixed to prepare a toner image-receiving layer coating solution.

<Evaluation of coated surface>
In the production steps of the obtained electrophotographic image-receiving sheets of Examples 5 to 8 and Comparative Examples 4 to 7, the surface state after the toner image-receiving layer coating solution was coated on the support was visually determined according to the following criteria. . The results are shown in Table 3.
[Evaluation criteria]
○: No cracks, cracks, or irregularities are seen on the coated surface.
Δ: Slight cracks, cracks and irregularities on the coated surface.
X: Cracks, cracks and irregularities are seen on the coated surface.

<Image formation>
As an image forming apparatus, an image is formed using an apparatus in which the fixing unit of a full color laser printer (DCC-500) manufactured by Fuji Xerox Co., Ltd. as shown in FIG. 5 is modified to the belt fixing unit shown in FIG. The fixing process was performed under the following conditions.
−Belt−
Belt support: polyimide (PI) film, width = 50 cm,
Thickness = 80μm
Release layer material for belt: SIFEL610 (manufactured by Shin-Etsu Chemical Co., Ltd.), which is a fluorocarbonsiloxane rubber precursor, was vulcanized and cured to form a fluorocarbonsiloxane rubber with a film thickness of 50 μm.
-Heating and pressing process-
Heating roller temperature: 140 ° C
Nip pressure: 130 N / cm ²
-Cooling process-
Cooler: Heat sink length = 80mm
Conveyance speed: 53mm / sec

-Glossiness measurement method-
Each of the electrophotographic image-receiving sheets is printed in 10 cm squares in 6 levels (0%, 20%, 40%, 60%, 80%, 100%) under B / W conditions using the following printer. The glossiness (20 degree measurement) of each obtained image was measured using a digital variable angle glossiness meter (Suga Test Instruments, UGV-5G) according to JIS Z8741, and the minimum value was recorded. The results are shown in Table 3.

<Image quality>
Persons, characters, lines with different line widths, YMCK single color mixture lines, and patch images were transferred, and the glossiness and transferability of the obtained images were evaluated according to the following criteria.
〔Evaluation criteria〕
○ ・ ・ ・ Good (high image quality)
△ ・ ・ ・ Slightly inferior × ・ ・ ・ Poor (low image quality)

The image recording layer coating solution of the present invention is stable without aggregation and is at least one of an ink jet recording material, a thermal recording material, a heat developing material, an electrophotographic material, and a silver halide photographic material. It is suitably used for forming the image recording layer.
The image recording material of the present invention is an ink-jet recording material, a heat-sensitive recording material, a heat developing material, an electrophotographic material, and a silver halide photographic material without causing dropping or cracking of the coated recording material layer. It is suitably used as at least one of the following.

FIG. 1 is a graph showing the relationship between the amount of water-soluble polymer compound added and the viscosity in Examples. FIG. 2 is a graph showing the relationship between the amount of water-soluble polymer compound added and the viscosity in Examples. FIG. 3 is a graph showing the relationship between the type of crown ether and the line width of ¹ H-NMR in the examples. FIG. 4 is a graph showing the relationship between the type of crown ether and the line width of ¹³ C-NMR in the examples. FIG. 5 is a schematic view showing an example of the image forming apparatus of the present invention. FIG. 6 is a schematic view showing an example of the cooling and peeling type belt fixing type smoothing processor of the present invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 18 Electrophotographic image-receiving sheet 19 Developing device 25 Belt fixing device 31 Intermediate transfer belt 71 Heating roller 72 Pressure roller 74 Peeling roller 75 Tension roller 73 Endless belt 77 Cooling heat sink 200 Image forming apparatus

Claims (15)

  A coating liquid for an image recording layer comprising a water-dispersible emulsion, an aggregation inhibitor having a site capable of interacting with a surface functional group in resin particles in the water-dispersible emulsion, and a water-soluble polymer compound. The viscosity A (Pa at 25 ° C. of the coating solution before adding the water-soluble polymer compound to the mixed solution in which the aggregation inhibitor is added in an amount of 0.5% by mass or more in solid content in the water-dispersible emulsion S) and the viscosity B (Pa · s) at 25 ° C. of the coating solution obtained by adding 1.0% by mass of the water-soluble polymer compound to the mixed solution as a solid content is represented by the following formula: viscosity ratio ( B / A) ≦ 40, a coating solution for an image recording layer.   The coating solution for an image recording layer according to claim 1, wherein the surface functional group in the resin particles in the water-dispersible emulsion is an amine salt of carboxylic acid.   The image recording layer coating solution according to claim 1, wherein the water dispersible emulsion is a water dispersible polyester emulsion.   The image recording layer coating solution according to claim 1, wherein the aggregation inhibitor is at least one selected from a surfactant and an inclusion compound.   The coating solution for an image recording layer according to claim 4, wherein the surfactant comprises a dialkyl sulfosuccinate.   The image recording layer coating solution according to claim 4, wherein the clathrate compound is crown ether.   The coating liquid for an image recording layer according to claim 6, wherein the crown ether is represented by the following formula: x-crown-y-ether, x is 13 or more, and y is 5 or more. The line width of ¹ H-NMR representing the mobility of CH ₂ in a mixed liquid obtained by adding crown ether as an aggregation inhibitor in the water-dispersible emulsion is 4 Hz or more, and the line width of ¹³ C-NMR is 7 Hz. The coating liquid for an image recording layer according to any one of claims 6 to 7, which is as described above.   The coating solution for an image recording layer according to any one of claims 1 to 8, wherein the water-soluble polymer compound is polyethylene oxide having a weight average molecular weight (Mw) of 400,000 or less.   An image recording material comprising at least a support and an image recording layer obtained by coating the coating liquid for an image recording layer according to any one of claims 1 to 9 on the support.   The image recording material according to claim 10, wherein the image recording material is at least one selected from an ink jet recording material, a heat sensitive recording material, a heat developing material, an electrophotographic material, and a silver halide photographic material.   12. The image recording material according to claim 11, wherein the image recording material is an electrophotographic image receiving sheet having a support and at least one toner image receiving layer on the support.   A method for producing an image recording material having a support and at least one image recording layer on at least one surface of the support, the surface of the resin particles in the water-dispersible emulsion in the water-dispersible emulsion An image recording layer coating solution preparing step of adding a water-soluble polymer compound after adding an aggregation inhibitor having a site capable of interacting with a functional group to prepare an image recording layer coating solution, and the image recording layer And an image recording layer forming step of forming an image recording layer by applying a coating liquid on the support.   The method for producing an image recording material according to claim 13, wherein the aggregation inhibitor is at least one selected from a surfactant and an inclusion compound. 13. A belt fixing type smoothing machine comprising: a toner image forming step for forming a toner image on the electrophotographic image receiving sheet according to claim 12; a heating and pressing member for the toner image; a belt member; An image forming method comprising: a fixing and smoothing step of heating and pressurizing, cooling, and peeling.

Images